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By Vu Van Dong

Resource estimation is the science of determining the amount and quality of a given material in the ground that has the potential to be mined at a profit. This is because during this time computers have become more widely available and more powerful and software packages have become more comprehensive and user friendly. Over the past three years The Mining Geology Company with the support from Vinacomin Group has developed the Coal Geological Modelling and Reserve Estimation ? VMG system. The VMG system enables the geological and mining engineer to start at the reserve estimation for the mine design and planning. The VMG system enables the national and international standards (NI43-101, CIM-Canada; SAMREC Code, Africa, and JORC Code, Australia) and user friendly with menu driven thereby permitting the engineer with minimal computer training to rapidly learn and utilize the system. Geological and mining data input through digitized map files and drill-holes information files stored in the database that is an integral part of the VMG system with the main function for collection, validation, and recording, storing and processing of data will include both ?primary? (observation and measurement) and ?interpreted? data. It is recommend that data be stored digitally, using a documented, standard format and a reliable storage medium that allows for easy and complete retrieval of the data. The coal reserve estimation through standard polygon methods with the increased use of these mathematical techniques (geometrical modelling, geostatistical method, least square method, ?) over the last ten years corresponds, to some degree, to a decrease in both the amount of the coal deposit mapping and, in particular, coal seam structural interpretation and modelling, and permit rapidly evaluation of coal seam and overburden quality and quantity. The understanding of the relationship between the coal mineralization of interest and the likely related complicate geological processes and structure that govern its emplacement and geometry within the geological framework is essential to the establishment of the geological controls for coal mineralization. System outputs includes: drillholes summary reports, stratigraphy, cross-sections, isopach maps, structure, contour maps, premining and post mining topography maps, and 3D perspective view on coal seam structure.

Oct 1, 2009

By David F. Gearhart

The Burrell Can1 is a thin, steel, tubular shell filled with aerated concrete that is used as a roof support in coal mines. The Can height is always shorter than the mining entry, so it is capped with wooden timbers and wedges when it is installed. This combination of the Can and the wooden header is a standing support system that is designed to yield in a controlled manner and exhibit a constant yield, or elastic-plastic behavior. The Burrell Can is capable of withstanding 20 in or more of vertical convergence and 15 in or more of horizontal displacement. Because of this exceptional ability to sustain load through extended convergence and displacement, it is one of the most robust standing supports in use today. The National Institute for Occupational Safety and Health (NIOSH) conducted testing on seventeen Burrell Cans in 1995, during development of the support where the ratio of the height to the diameter, or the aspect ratio, was between 2:1 and 4:1. Based on the results of that testing, it was suggested that the standard aspect ratio of the Can be less than 5:1. This suggestion is intended to preserve the overall stability of the Can, which will help to maintain the initial stiffness and prevent load shedding. Recently, the necessity of the aspect ratio has been questioned, and this issue will be addressed in this paper. Since the initial development and introduction, more than 130 tests of the Can have been conducted at the NIOSH Mine Roof Simulator (MRS), and 25 of those specimens had aspect ratios greater than 5:1. The 18-in-diameter by 10-ft-tall specimens had the largest aspect ratio, 6.67:1.However, the aspect ratio is not the only parameter that affects the performance characteristics of the Can. Multiple factors, such as the use of different wood species, the use of different header or footer configurations, and the use of pedestals, as well as biaxial loading conditions can also decrease the stiffness and capacity of the Can. Data from full-scale tests that include these other factors are analyzed to show that the initial stiffness is primarily affected by the roof and floor contact configurations. Furthermore, load shedding is more likely to occur or begin earlier when the aspect ratio is greater than 5:1 and one or more of the other factors are present.

Jan 1, 2012

By B. S. Xakalashe

Keywords: Pyrometallurgy, silicon, solar cells Silicon has been the dominant material in the photovoltaic (PV) industry since its application in the space industry in 1958. This review focuses on crystalline silicon solar cells, primarily due to their dominance in the photovoltaic industry, omitting other photovoltaic cell technologies such as second generation (e.g. thin films) and third generation (e.g. nano-structured solar cells). The value chain for the production of crystalline silicon solar cells has been reviewed. The primary processing steps for the production of silicon solar cells from quartz are as follows: bulk production of metallurgical-grade silicon via carbothermic reduction in a submerged furnace, refining of metallurgical-grade silicon via the chemical means to polycrystalline silicon, or through the metallurgical route to solar-grade silicon, wafer manufacturing, and, lastly, silicon solar cell manufacturing. During downstream processing, solar cells are interconnected and encapsulated into solar modules (panels), which can be used individually or incorporated into a photovoltaic system for electricity generation and supply. The cost for crystalline silicon based solar cells is approaching one US dollar per watt peak ($1/Wp), while the most cost-effective solar modules in industry have reported costs below $1/Wp, and are based on CdTe thin films. Solar cell energy conversion efficiencies as high as 22% have been reported in industry for crystalline silicon solar cells.

Jan 1, 2011

By D Craw

The Rise and Shine Shear Zone is a mineralised low angle deformation zone traceable for at least 7 km through biotite zone schist of the Dunstan Range, central Otago. Rocks from the shear zone obtained from recent drillholes are unweathered and facilitate paragenetic studies. There is a progression of mineral deposition from semiductile foliation-parallel shearing, to subsequent folding, and brittle fracturing. Sheared rocks are dominated by microshears containing fine grained hydrothermal muscovite and rutile that has recrystallised from metamorphic muscovite and titanite respectively. Euhedral pyrite occurs within segregations in the schist and is locally brecciated by the shears.   Arsenopyrite occurs within microshears and is intergrown with hyrothermal muscovite. Fractures within relatively undeformed schist are filled with ankerite, siderite, chalcopyrite, sphalerite and galena and these veinlets also crosscut the microshears. Locally the schist is folded and zones of brecciation, silicification and vein deposition overprint the rock. Vein quartz and albite predominate and arsenopyrite and gold infill breccia matrix and crosscutting veinlets. Sulphide deposition began in the later stages of metamorphism with pyrite deposited in quartz-albite segregations. Subsequent shearing caused brecciation of some grains and accompanied deposition of arsenopyrite ¦ gold and rare sulphides along foliation-parallel microshears. Minor amounts of chalcopyrite, sphalerite and galena were then remobilised in ankerite veins that crosscut the shears. In areas of high strain, arsenopyrite was then deposited as euhedral grains in veins and breccias. Synmineralisation deformation caused the brecciation of some grains and gold was deposited infilling fractures in the arsenopyrite. The paragenetic sequence shows gold mineralisation occurred in two distinct sets of structures (semiductile and brittle) that formed at different times in the formation of the shear zone.

Jan 1, 2006

By R Stefansen

Stockyard operations are governed by the interaction between the different disciplines required to successfully schedule and control the supply chain of raw material through the stockyard in combination with the effectivity of the operation of the stockyard equipment. The system demonstrates a proven technology for implementing a centralised operation of full unmanned stockyard equipment, using a high precision absolute positioning system based on a Real-Time Kinematic (RTK) Global Navigation Satellite System (GNSS) receivers in combination with 3D rangefinders. The system implementation maps the surface profile of the stockyard inventory and allows in combination with proprietary algorithms for full operation of the stockyard machines without on-board operators. The operational impact of delayering the process by moving to a centralised operation is examined, together with the combined effect on the overall safety in the stockyard as a result of a change in reliance on operator skill dependencies. Average performance gains range from 10–20 per cent. The performance of the automation system is related to a consistency and reliability of uniform operation, which has an impact on the life expectancy and the effectiveness of the equipment. The effects of having instantaneous and correct information about the stockyard inventory volume measurement are investigated in relation towards spot price trading in current fast reacting markets.CITATION:Stefansen, R, 2017. Advanced automation for centralised stockyard operations, in Proceedings Iron Ore 2017, pp 105–110 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By G. Adachi, K. Machida, T. Ozaki, K. Murase

The chlorination rate with CCl4 was unexpectedly slower than carbochlorination using chlorine under the same reaction conditions. Chlorination with CCl4 was topochemical and the amount of monazite reacted after different periods suggested that the kinetic control step was the reaction between CCl4 and the monazite core at the interface. The kinetic order of the reaction was 0.5. The presence of a complex former, AlCl3, promoted the chemical vapour transport of rare-earth chlorides as complexes

Jun 18, 1905

By J. van Lookeren

In the case of a reservoir where the oil underlies a large gas cap and overlies bottom water, production can be inzproved considerably if wells are perforated below the water-oil contact rather than opposite the oil-bearing section. The theoretical arguments for this improvement, which in some cases may be tenfold, are supported by experimental evidence. INTRODUCTION Reservoirs frequently consist of one sand body containing an oil layer underlying a thick, gas-bearing section and overlying bottom water (Fig. 1). Wells in such reservoirs are customarily opened up opposite the oil-bearing interval or, rather, opposite the lower part of this interval (Fig. 2). More often than not, it is inefficient or prohibited to blow off large quantities of gas with the oil. This im-psses a severe limitation on the drawdown, which results in low oil-production rates. Because of the small difference in specific gravity between oil and water, the latter will easily cone upwards, so that the production of water together with the oil is not prevented by this completion method. In such a situation wells should be opened deeper, in the originally water-bearing zone. The gas can be shut off by not perforating over the upper part of the interval (Fig. 3) or by a tubing hung close to the bottom of the interval (Fig. 4). Initially much water will be produced, but when steady-state conditions have been established (as depicted in Figs. 3 and 4) larger drawdowns are permissible than in a conventionally completed well, and correspondingly higher oil-production rates will result. Water cuts are only slightly higher because of the small effect of gravity on the water-oil flow distribution. CALCULATIONS The ratio of improvement has been estimated by means of approximate calculations. The completion depicted in Fig. 4 is the most convenient basis for these calculations. By postulating that vertical flow gradients can be disregarded, the Appendix shows that the well-known Dupuit formula can be obtained except for some complication due to the presence of two fluids rather than one. The Appendix makes the reasonable assumption that, for suitable boundary conditions, the oil layer occupies a constant fraction of the total fluid height throughout the reservoir. The oil- and water-production rates can thus be related to the liquid levels in the borehole as follows:

Jan 1, 1966

By H. O. Hofman

At the Lake Superior meeting, September, 1904, Messrs. A. Gibb and R. C. Philp presented a paper entitled " The Constitution of Mattes Produced in Copper-Smelting,"' in which they concluded that ferrous and cuprous sulphides formed the chemical compound, 5 Cu2S, FeS. They arrived at this inference from the observed fact that a matte containing Cu,S, 90.4, and FcS, 9.6 per cent. (or, in round figures, Cu2S, 90, and FeS, 10 per cent.), did not contain any metallic copper, while one with more than 10 per cent. of FeS readily dissolved copper, and with less than this amount retained copper in mechanical suspension. Although they determined the melting-points of five mattes containing from 32.6 to 80.1 per cent. of copper, they did not draw a freezing-point curve, as the necessary apparatus was not available. A microscopical examination of 11 polished samples gave them a grayish-black field of very uniform appearance, except that five of the specimens showed the presence of metallic copper. The object of the present investigation was to supplement the above paper by drawing the freezing-point curve of the ferrous sulphide-cuprous sulphide series, and to see how the constitution could be further revealed by microscopical work. The results obtained lead to conclusions very different from those of Gibb and Philp. While their paper bears the date 1904, it was published only in 1906.2 In the meantime, Bolles3 had presented his paper, " The Concentration of Gold and Silver in Iron-Bottoms." The raw material which formed the basis of the research was a matte containing Fe, 61.68, and Cu, 11.20

Jan 1, 1908

By F F. Pitard, K J. Ehrig

The Olympic Dam iron-oxide copper-gold (IOCG) uranium-silver deposit is second in size only to Norilsk, the gigantic metalliferous deposit. Olympic Dam is the largest publicly declared uranium, fifth largest copper and third largest gold resource. The deposit is typified by texturally destructive brecciation and intense iron metasomatism of the Roxby Downs Granite, bedded clastic facies rocks and mafic-ultramafic dykes. The deposit contains over 100 minerals. Copper mineralisation consists of chalcopyrite, bornite and chalcocite. Uraninite, coffinite and brannerite are the dominant uranium-bearing minerals. Gold mineralisation consists of electrum, tellurides and Au-Cu alloys. Hessite is the major silver-bearing mineral. The economic minerals are disseminated throughout the breccia matrix where the average grain sizes of the Cu-sulfide, uranium, gold and silver minerals are ~50, 20, <5, <5 microns, respectively.A significant number of sampling theory-based test programs have been completed since the mid-1990s to establish sampling nomographs, select appropriate sampling (ie split versus chip and interval lengths) and sample preparation protocols, quantify the errors associated with each subsampling stage, determine the practical uncertainty limits of Olympic Dam matrix-matched standards, and identify improvement opportunities related to the ongoing assaying quality assurance / quality control (QA/QC) program. Invaluable knowledge and unexpected insights gained from sampling studies at Olympic Dam have helped to improve our understanding of the distribution of economic and deleterious elements within the Olympic Dam deposit.CITATION:Ehrig, K J and Pitard, F F, 2017. Underground bulk sampling, uniform conditioning and conditional simulation – unrealistic expectations?, in Proceedings Eighth World Conference on Sampling and Blending , pp 21–28 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

By M. N. Brodie

"The ability to adjust the speed of a SAG mill offers benefits to the process and to equipment maintenance. It can be provided with some slight effect on availability ranging from somewhat enhanced to somewhat reduced, depending on the particular equipment that is used. Several techniques have been developed for monitoring the magnitude of the contained charge, and several algorithms have been used to control mill feed rate and mill speed. The various benefits and the means by which they can be realized are examined and compared. Reasons for Variable SpeedProcess RequirementsThe recovery of minerals from ore is dependent on particle size and residence time in process. Separation in a given plant is most efficient at a particular rate and a particular size (e.g., 80% minus 200 mesh). If the particle size increases, less mineral will be liberated. If the particle size is significantly reduced, the process of choice may not be able to effect separation, and power, media, and maintenance costs would be increased.If a SAG mill-ball mill combination delivers the desired throughput at the correct size for efficient separation when processing ore of the design hardness, some adjustment must be made to maintain this condition when the ore changes. The processing of ore softer than design will result in overgrinding, unless:• the throughput is increased inversely to the change in hardness which lowers recovery by overloading the separation facilities;• or the SAG mill feed rate remains constant, but the speed is reduced to feed coarser material to the ball mill for finish grinding to the desired size.There is also the effect of changing milldiameter to consider. A nominal 36 ft diameter SAG mill will have an effective diameter of 35 ft with new liners and 35 ft 6 in. with worn liners. A mill designed to operate at 0.76 p.u. (per unit) of critical speed with new liners (9.84 rpm) will be changed to 0.765 p.u. with worn liners. If 0.76 p.u. is the desired value, the mill speed should be reduced to 9.77 rpm."

Jan 1, 2003

By P. Schilizzi, A. Jarosz, M. Karmis

This paper is concerned with subsidence prediction methods and in particular with two techniques, one based on profile functions and the other on influence functions. Profile function methods provide a tool for a fast calculation of subsidence on a line across a mine panel. Influence function methods, on the other hand, allow for a more detailed calculation of ground movements, in any mode and at any depth, on a grid or at any specific point. In more detail, the hyperbolic tangent profile function, as developed by VPI&SU from field data pertaining to the eastern U.S. coalfields, and an influence function method currently being adapted for the same region, are presented and discussed. The applicability, advantages and limitations of these techniques are examined and comparisons are presented with field measurements. Computer software developed for the application of these prediction methods, for two widely used personal computer systems, are also discussed and a number of examples are presented demonstrating the potential of such programs.

Jan 1, 1986

An understanding of the way that solutes are transported in mining or natural environments is essential to the development of sound strategies for managing waste disposal. Research on miscible pollutant movement in unsaturated porous media is carried out both experimentally and numerically. Results of numerical modelling are obtained by solving the groundwater flow equation and the solute transport equation. The finite element method is employed and comparisons between simulation results and experimental data are found in remarkable agreement.

Jan 1, 1995

Geophysical anomalies result from the passage of hydrothermal fluids through rocks. Interpretation of these anomalies, when integrated with available geological and geochemical data, assists the construction of a conceptual model of the original hydrology of the system. The original extent of a geothermal system is often indicated by the distribution of low resistivity argillic clay alteration. Quartz-adularia vein deposits, silica sinters or stockwork (often mineralised) cause local increases in resistivity. Appropriately chosen electrical techniques can therefore be used to help target such structures. Airborne magnetic surveys have also proven useful in New Zealand epithermal exploration, because hydrothermal fluids destroy magnetite causing extensive demagnetisation anomalies. Ground magnetic surveys can sometimes be useful for geological interpretation on a local scale. Positive gravity anomalies may occur as a result of mineral precipitation (silica or calcite) in high porosity host rocks, while negative gravity anomalies can result from hydrothermal fracturing and leaching of relatively dense host rocks. The relative merits of these geophysical techniques as used in the exploration of epithermal mineral prospects are discussed, with particular reference to the Hauraki Goldfield. The preferred method for defining zones of quartz veining/silicification is vector or tensor gradient resistivity. Exploration strategies and technique refinements are suggested as a means of improving the resolution of potentially mineralised target structures, in a more efficient and cost effective manner.

Jan 1, 1993

By M. R. Dion, K. Frenette, R. K. Jonas, S. Simard, F. Robichaud

"In 2011, a site study indicated that the application of Honeywell’s Multivariable Predictive Control Technology (MPC) to the Goldex processing facility would provide significant opportunities for improvement. Grinding MPC was implemented in the SAG Mill in June 2015. This pilot application, called Phase 1, featured one of the first Multivariable Predictive Controllers to be installed in a Canadian mineral processing plant. Since the implementation of MPC, gold recovery from the gravity circuit has increased. MPC contributed to a decrease in flotation feed particle size (120 to 112 µm) and an increase in the SAG feed tonnage (8.5% increase). MPC also increased and stabilized the % solids of the SAG feed, which can have an impact on cost reduction (mechanical maintenance). Additionally, MPC increased productivity, providing grinding operators with more time to perform other tasks. Further anticipated benefits include the standardization of the grinding circuit operation from one team to the next, thereby minimizing circuit disturbances resulting from different operating philosophies. This paper will discuss the advanced control project development and justification, the technology and rapid implementation process, the performance results and the benefits obtained.IntroductionGoldex is an underground mine located near Val-d’Or that is owned and operated by Agnico Eagle Mines Limited (AEM). Between 2008 and 2011, mining focused on the Goldex Extension Zone (GEZ). In 2011, the project was halted due to geotechnical problems; operations ceased until late 2013. Goldex operations resumed in September 2013 with the M and E zones, for which there were 0.7M gold ounces of proven and probable reserves, 2.1M ounces of measured and indicated resources and 1.2M ounces of inferred resources, totalizing 4M ounces. Life expectancy was extended until 2024."

Jan 1, 2017

By T. Banerjee, D. Felsher, G. Leavoy

"Lake Shore Gold is engaged in commercial gold production at both the Timmins West and Bell Creek mines, located in Timmins, Ontario. Run of mine ore is processed at the Bell Creek mill which consists of a conventional gold mill flow sheet involving crushing, grinding, gravity concentration and carbon-in-leach (CIL) for gold recovery. Since 2009, the operating capacity of the mill has been upgraded from 2000 tpd tonnes per day (tpd) to over 3,000 tpd. The most recent expansion involved the installation of a low aspect ratio SAG mill to replace the secondary crusher. Without operational data on the low aspect mill, combined with a site team that was new to SAG milling, there were many challenges in achieving the target throughput from the circuit. Through the implementation of AwaRE advanced controllers, running in closed loop with PRC fragmentation cameras as well as embedded PARC modules within the Allen Bradley PLC, the site was able to rapidly develop a best operating practise and has been successful in creating a stable and consistent operational environment. The process, lessons learned and eventual solution will be reviewed in this paper.INTRODUCTIONLake Shore Gold is engaged in commercial gold production at both the Timmins West and Bell Creek mines, located in Timmins, Ontario. Run of mine ore is processed at the Bell Creek mill which consists of a conventional gold mill flow sheet involving crushing, grinding, gravity concentration and carbon-in-leach (CIL) for gold recovery. Since 2009, the operating capacity of the mill has been upgraded from 2,000 tpd tonnes per day (tpd) to 3,150 tpd. The most recent expansion involved the installation of a low aspect ratio SAG mill to replace the secondary crusher. This endeavor was split into two phases: the expansion of the back-end (Phase 1) and the front-end (Phase 2) of the mill. Phase 1 of the expansion was completed at the end of 2012 and involved enhancements and capacity addition to the leaching and adsorption circuits, which increased the mill’s capacity to 2,500 tpd. Phase 2 of the expansion commenced at the end of July 2013 and involved the expansion of the crushing and grinding circuits. The expanded front-end of the mill now has a capacity of 5,500 tpd, and processes ore from both Bell Creek and Timmins West mines. The updated flow-sheet, as shown in Figure 1, illustrates the replacement of the two-stage crushing and ball milling circuit with a single stage crusher and a low aspect ratio SAG mill."

Jan 1, 2015

Laboratory scale equipment was developed to recover zinc as oxide fume from granulated lead blast furnace slag. The cyclone furnace process is characterised by high treatment rates combined with continuous and independent operation.Results were sufficiently encouraging to warrant pilot plant scale trials being undertaken.INTRODUCTIONSince granulation of lead blast furnace slag started at Port Pirie in 1921 the stockpile of this material has increased to nearly 5 million tons which averages 17·5 per cent zinc by weight. Although a number of processes for recovering the zinc have been examined, economic considerations indicate that a slag fuming process is likely to be most suitable.In the conventional slag fuming process zinc is extracted by injecting pulverized coal and air into a molten slag bath. By maintaining a suitable air to coal ratio the oxidised zinc contained in the slag is reduced to metal. Volatilization of the zinc is followed by reoxidation in the gaseous phase with the addition of further air above the bath. The zinc oxide fume so produced is collected by normal gas cleaning methods.By examination of the thermodynamics of this process Bell, Turner, and Peters (1955) determined the zinc oxide activity of the slag over the duration of the fuming cycle.A combination of high temperature and high carbon monoxide/carbon dioxide ratio was found necessary for rapid zinc elimination.Since melting of the slag is an essential step in the slag fuming process, only two treatment methods appeared possible at Port Pirie until recently...

Jan 1, 1964

By J. C. Edwards

A series of four coal combustion experiments (I)' was conducted at the National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory in the Safety Research Coal Mine to evaluate the response of optical and ionization smoke and CO sensors to a small 0.61 m square smoldering coal fire which transitions to flaming combustion in the presence of diesel emissions. With the increased utilization of diesel engines in underground coal mines, it is important to be able to discriminate fire products-of-combustion (POC) from diesel emissions. One proposed method to accomplish this is the deployment and interpretation of multiple sensors.

Jan 1, 2010

By W. Robert Thompson

Hurricane Katrina caused significant damage to transportation structures on the Gulf coast in August, 2005, including the destruction of the US 90 Bridge over Biloxi Bay, Mississippi. Part of the successful design/build proposal for the replacement bridge included a comprehensive test pile program of indicator piles and load test piles in the geotechnical investigation program. A total of 22 indicator piles were installed on the project using the pile driving analyzer to monitor the pile behavior. Five load tests were performed: two axial Statnamic, two lateral Statnamic, and one static axial. The results of the test pile program established driving criteria for production piles that included end-of-drive blow counts and pile tip elevations with an appropriate allowance for setup. The program also confirmed that the planned installation equipment and techniques of GC Constructors, a joint venture of Massman Construction Co., Kiewit Southern Co., and Traylor Bros., Inc., would install the piles to the design tip elevations before production piles began. An extensive program of restrike measurements at a range of times after initial driving of the indicator piles provided a systematic documentation of pile setup in the soil profiles on the site. These resistance values were used to develop a dimensionless setup factor ?S? as the ratio of the restrike resistance to the end of drive resistance. This factor varied from 1.5 for piles penetrating clays and tipped in sand to 3.0 for piles bearing completely in clay and helped establish an end-of drive blow count that included an allowance for setup. The CAPWAP analyses of restrike data with setup and the load test data were used to confirm the design unit side shear and end bearing values developed from the borings and static capacity calculations and to select the design pile lengths.

Jan 1, 2009

By M. Arvola, A. Mäkinen, N. Isomäki

Arsenic is a compound that has no significant market value. However, it needs to be removed from ores, concentrates and other process streams because of environmental or technical processing concerns. A wide range of arsenic containing minerals exists in nature, and in many instances these minerals are also associated with the ones that have commercial value. For example, sulfide copper ores are normally closely associated with minerals like enargite, Cu3AsS4 and tennantite Cu12As4S13. After mineral processing these arsenic sources can report to the waste waters and these effluents need to be treated before discharge or recycling. Ferric arsenate precipitation is a well-established method for stabilizing arsenic in effluents. Electrochemical arsenic removal utilizes the same adsorption/precipitation ideology as ferric arsenate precipitation. Electrochemical arsenic removal, even though it is a simple process in terms of equipment, is a complex system involving chemical and physical mechanisms taking place simultaneously to remove dissolved and/or solid arsenic components from wastewaters. The whole process can be described by the following three steps: 1) electrolytic oxidation at a sacrificial anode (dissolving electrode metal, iron for example), 2) chemical reaction between dissolved iron and arsenic to form a solid precipitate and 3) aggregation of the particles to form flocs, which can be removed by known solid/liquid separation methods. Electrochemical arsenic removal is a very efficient way to remove arsenic from different waters to very low residual concentrations.

Jan 1, 2016

This paper discusses how elemental analysis of conveyed bulk flows in real time using PGNAA (Prompt Gamma Neutron Activation Analysis) technology has resulted in significant improvements in advancing plant control in mineral processing operations. Basis of operation of the PGNAA through belt, full stream, continuous, multi-elemental, real time analysis technology is explained. Capabilities and limitations in plant operating environments are discussed including comparison with other real time, online technologies through review of published information available for on-conveyor minerals applications. Case studies demonstrate benefits provided by this technology in two operating mines. An iron ore company had prior experience with the PGNAA analyser technology, implementing an early model in a minerals application in 2003 to develop confidence in its measurement performance and usefulness of the data. A number of analysers were subsequently included throughout the new plant design for extensive measurement and control of conveyed bulk flows, from conveying after mining through to rail load-out. A copper-gold company installed an analyser to address copper ore blending issues where an on-belt system was the only viable option for the degree of control required. Analyser suitability was evaluated through test work on site samples to determine customised multi-element precision guarantees for each application. Analyser results from normal operation are compared against laboratory analyses of multiple cross stream samples collected from conveyed flows to assess performance. Both projects discussed were able to realise benefits previously unattainable for plant quality control, surpassing capabilities of traditional technologies which were either unsuitable for measuring conveyed flows with adequate accuracy or in real time. Equipment payback within a few months was achieved for both sites. Through proven performance in these applications, the companies consider the technology an essential component in advanced plant control necessary in new process flow sheet designs, rather than an optimisation tool.

Jan 1, 2014