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By Mehmet F. Taner

"Abstract - The East Sullivan Stock (ESS) is a small, composite felsic alkaline pluton of presumed late Archean age in the Val d’Or mining district. Three main facies have been distinguished: monzonite sensu stricto, porphyritic monzonite, and green trachytic porphyry. This monzonitic group of rocks is of relatively homogeneous composition with high abundances of Na2O, K2O, Ba, Sr, Rb, Zr, Mo and LREE. The alkaline ESS is distinguished from other igneous units in the Val d’Or mining district, such as the Bourlamaque Batholith, by relatively high concentrations of Ba, Sr, Rb, Mo, Cu and Au. The ESS hosts many base (Cu, Mo) and precious (Au) metal occurrences, including: (1) porphyry style Cu-Au-Mo disseminated sulfide deposits, (2) Cu-Au deposits in volcanic rocks near the ESS contact, and (3) pyritic gold mineralization in east-west trending shear zones. The ESS is well defined by concentrical zoning on the aeromagnetic vertical gradient color map, and displays four linear trends, which are assumed to be structural lineaments, at 035°-055°, 320°-300°, eastwest, and north-south. The main mineral occurrences related to the stock display a preferred spatial association with the east-west linear magnetic trends.The ESS is preferentially located along a major structure and was emplaced late in the evolution of the Abitibi subprovince like other felsic alkaline plutons. This stock is similar to late-tectonic mineralized felsic alkaline intrusions of the Kirkland Lake and Larder Lake mining districts in Ontario, and to the Allard stock in the U.S.A. which is associated with gold and base metal mineralization. Similarities also exist with younger alkaline plutons associated with Cu-Mo-Au porphyry deposits in the Canadian Cordillera, which formed in tensional tectonic environments. The felsic alkaline magma may have formed by partial melting of deeply buried supracrustal rocks, concomitant with the development of deep fractures such as the Cadillac Fault. In such an environment, hydrothermal solutions carrying remobilized metals from deep supracrustal rocks may have deposited gold and base metals in structural traps. Plutons similar to the ESS should be good targets for mineral exploration. Résumé - Le Stock de East Sullivan (SES) est une intrusion composite alcaline d’âge tardiarchéen, situé dans le camp minier de Val d’Or. Trois principaux faciès ont été identifiés: une monzonite sensu stricto, une monzonite porphyrique et un porphyre trachytique vert. Les données chimiques montrent que ce groupe des roches monzonitiques est relativement homogène en composition avec des concentrations élevées de Na2O, K2O, Ba, Sr, Rb, Zr, Mo et ETRL, définissant une suite alcaline typique. Cet alkalin stock peut être facilement distingué des autres unités géologiques de la région de Val d’Or, tel le batholite de Bourlamaque, par une concentration élevée de Ba, Sr, Rb, Mo, Cu et d’Au. Le SES contient plusieurs importants prospects de métal précieux (Au) et de métaux de base (Cu, Mo), incluant: (1) une minéralisation disséminée de type porphyre Cu-Mo-Au, (2) une minéralisation de Cu-Au dans les roches volcaniques encaissantes hôtesses près du contact et (3) une minéralisation d’or pyritique dans une zone de cisaillement de direction est-nordest. Le SES est bien défini sur la carte aéromagnétique en couleurs du gradient vertical par des zonages concentriques, où quatre linéaments structuraux ont été reconnus: 035°-55°, 320°-300°, est-ouest, et nord-sud. Les principales zones minéralisées spatialement associées au stock sont généralement situées soit près des linéaments magnétiques est-ouest, soit le long de ceux-ci.Le SES semble s’être mis en place le long d’une structure majeure, développée tardivement dans l’évolution de la Sous-province abitibienne, comme les autres plutons alcalins felsiques. Ce stock est similaire à la suite tardi-tectonique d’intrusions alcalines minéralisées des camps miniers de Kirkland Lake et de Larder Lake en Ontario, ou"

Jan 1, 1996

By J. Mark Richardson

The use of an integrated software package to simulate and optimize the performance of mineral processing circuits is illustrated by three examples. Each represents application of the software and associated techniques to optimization of an existing plant. In the first example, a South-western U. S. copper company employs the method to simulate and improve performance in crushing, screening and SAG milling. A second copper producer evaluates equipment changes and flowsheet alternatives in a closed-circuit ball mill-cyclone operation. A Southeastern U. S. aluminum refinery optimizes performance of a dry milling and classification circuit for production of carbon particles used in anode casting. Graphical and tabular data describe the circuits simulated and the results achieved in each example.

Jan 1, 1990

By Ulf S. Landergren

Diffusion coefficients and marker movements have been determined in brass using welded couples. Three different concentration ranges were employed at 750°C, while a fourth concentration range was measured at 500°, 600°, 700°, and 800°C. Marker displacements toward and porosity development in the high zinc side of the couple were observed in all cases. The results were interpreted as favoring a vacancy diffusion mechanism. IN the large amount of diffusion literature which has accumulated during the past half century, very few experimental data have been presented on body-centered-cubic metallic phases. The impressive combination of experimental and theoretical studies which has given the vacancy mechanism a fairly secure position as the preferred mechanism for most face-centered-cubic metals has no counterpart for body-centered-cubic phases, although the theoretical picture seems to be in a better state than the experimental work. The attempts to select diffusion mechanisms by the theoretical calculation of the activation energy for the various conceivable unit diffusion processes and the energy of formation of the type of lattice defect required have been based on models of two kinds. The first kind utilizes potential functions fitted for certain properties of pure crystalline copper; the second kind is fitted for sodium. The latter is an example of an open metal in which the metallic ion is small compared with interatomic distance,&apos; while the former is characteristic of the larger class of metals in which the ions have diameters about as large as the interatomic distance. brass should resemble copper in this fundamental property. It should be evident that results on the mechanism of diffusion obtained for one of these classes need not necessarily apply to the other. Huntington and Seitz, using a model of the copper type, showed that the activation energies to be expected for interstitial migration or a two-atom direct interchange were much higher than that for vacancy diffusion. Zener pointed out that a four-atom ring rotation would involve an activation energy considerably lower than the two unlikely mechanisms although still higher than the vacancy mechanism in the face-centered-cubic structure. Furthermore, he argued, the four-atom rotation would be relatively easier in a body-centered-cubic lattice and might be competitive with the vacancy mechanism. Paneth showed that a body-centered-cubic crystal-like sodium could form interstitial defects of special type, called a crowdion, by crowding an extra atom into < 111 > directions where the defects would affect a line of about eight atoms. The defect was constrained to move along the defining line. Unlike the face-centered-cubic case, therefore, the theoretical calculations for the body-centered-cubic mechanism do not provide a very clear-cut answer, and the absence of adequate experimental studies is the more serious. This investigation was undertaken for the purpose of obtaining useful information on diffusion in body-centered-cubic phases. brass was chosen for several reasons: 1—the phase field is sufficiently wide at high temperatures to permit the use of diffusion couples with adequate concentration ranges for satisfactory chemical analysis, 2-—thermodynamic activity data are available for the calculation of mobilities from diffusion coefficients, 3—the phase is as close to the theoretical model of the copper -type on which the calculations have been done as any body-centered-cubic metallic phase is likely to be. Measurements of the movements (if found) of inert markers during the diffusion process would indicate that a vacancy or Or mechanism played a major role in diffusion in brass. If no marker movement should be found, a ring mechanism would be indicated but not assured. Experimental Procedure The alloys used in these experiments, listed in Table I with analyses, were supplied by the Naval Research Laboratory. They were from ingots of 3x3 in. cross-section, heated to 760°C, reduced under a

Jan 1, 1957

By H. D. Hess

This report presents the results of laboratory mineral evaluations conducted by the federal Bureau of Mines under the joint sponsorship of the U.S. Atomic Energy Commission (AEC) and the Bureau a! Ships, U. S. Department of the Navy. The major purpose of this investigation was to examine and evaluate zirconium minerals representing sizeable deposits in an effort to locate com¬mercial sources of high-hafnium ores. Although determination of the hafnium content was the principal objective, each of the zirconium minerals also was analyzed for combined zirconium-hafnium oxide, silica, uranium, thorium, yttrium, and cerium. The general laboratory procedure involved microscopic examination of the test samples, concentration of the hafnium-bearing zirconium mineral by standard laboratory techniques, and analysis of the derived concentrate by quantitative microscopic, chemical, and X-ray spectrographic methods. Of the several hundred samples tested under this program, 147 are discussed in this report, including 94 from domestic occurrences and 53 from widespread foreign sources.

Jan 1, 1962

By R. H. Nafziger

Bureau of Mines research has shown that very low-sulfur pressure vessel steels with improved mechanical properties can be prepared by two melting processes. Four pressure vessel steels having sulfur contents ranging from 0.0008 to 0.0040 wt-pct, were produced by the electric-arc furnace or by the electroslag processes. Calcium carbide was used as a desulfurizer in the electricarc furnace. Fluxes containing at least 40 wt-pct CaO provided sufficient desulfurization during electroslag remelting. Element recoveries were higher for electroslag remelting than for metal melted in the electric-arc furnace. Bar rolled from electroslag-remelted ingots generally possessed higher tensile strengths and ductility than bar rolled from it t melted in the electric-arc furnace. Charpy V-Notch upper shelf energies were also improved as a result of electroslag remelting. The primary failure mode during impact testing was was microvoid coalescence. Sulfide inclusions were minimal, especially in the electroslag-remelted material.

Jan 1, 1979

By Daniels E. J, Morgan W. A

In response to the increase in consumption of galvanised steel for automobiles in the last decade and the problems associated with remelting larger quantities of galvanised steel scrap, a process is being developed to separate and recover the steel and zinc from galvanised ferrous scrap. The zinc is dissolved from the scrap in hot caustic using anodic assistance and is recovered electrolytically as dendritic powder. The dezinced ferrous scrap is rinsed and used directly. The process is effective for zinc, lead, and aluminum removal on loose and baled scrap and on all types of galvanised steel. The process has been pilot tested for batch treatment of 900 tonnes of mostly baled scrap. A pilot plant to treat continuously loose scrap, with a design capacity of 48 000 tonnes annually, has been in operation in East Chicago, Indiana since early in 1993. The first 450 t of scrap degalvanised in the pilot plant have residual zinc below 0.01 per cent and sodium dragout below 0.01 per cent. Use of degalvanised steel scrap decreases raw materials, environmental compliance costs, and opportunity costs to steel- and iron-makers. Availability of clean degalvanised scrap may enable integrated steel producers to recycle furnace dusts to the sinter plant and EAF shops to produce flat products without the use of high quality scrap alternatives such as DRI, pig iron, or iron carbide. Recycling the components of galvanised steel scrap saves primary energy, decreases zinc imports, and adds value to the scrap. The quantities of zinc available by the year 2000 from prompt and obsolete automotive scrap will approach 25 per cent of zinc consumed in the major automotive production centres of the world. Zinc recycling from galvanised steel scrap, either before or after scrap melting, will have to be Implemented.

Jan 1, 1993

By Lloyd A. Morley, Robert Stefanko

Before going directly to the analysis, it would be good to summar¬ize explosion-proof container approval methods. Both Magison (52) and Short (84) state that in general practice, the systems are certified for: 1. a rugged enclosure able to withstand an internal explosion but not allow explosively hot gases to escape, and 2. maximum surface temperature, with equipment operating inside, that will not ignite the surrounding atmosphere. Also, testing insures that any material in contact with the container surface will not be ignited by a hot spot. Associated with the first practice, the enclosures are inspected for: 1. a safe flange gap width, 2. a pressure increase during ignition, and 3. an hydrostatic pressure withstand level. The hydrostatic pressure level is almost always determined by a meas¬ured ignition-pressure test and is usually applied to prove the mechan¬ical design to some safety factor. Consequently, explosion-proof enclosure testing includes temper¬ature, permissible flame gap, and pressure. Specifications and prev¬ious research also can be similarly separated even though some interre¬lation exists between the flame gap size and internal enclosure pressure during an explosion. The Schedule 2G Sections applicable to these subjects are: 1. 18.2 Definitions; 2. 18.6 Applications;

Jan 1, 1974

By M. P. Ahola

This U.S. Bureau of Mines report presents an overview of the use of three unique numerical modeling methods to analyze cutter roof problems in underground coal mines. Cutter roof failures are common in coal mines where the immediate roof is comprised of thin laminae exposed to highly biaxial tectonic stress fields. The predominant mechanism for failure is assumed to be excessive shear stress at the entry corners exceeding the shear strength of the rock. Early work in this area utilized the finite-element method and then the boundary-element method to analyze several cutter roof control measures. Various stress control measures were simulated to estimate their respective effects on reducing the high levels of shear stress at the entry corners. More recent studies made use of the discrete-element method. This method was used to take the analyses beyond the elastic continuum limits to simulate the propagation of a shear fracture and subsequent redistribution of stress within the mine roof. A simple roof bolt model was implemented to show the benefits of bolting to increase the resistance to shearing and separation along horizontal bedding planes and maintain roof stability.

Jan 1, 1991

By Stephen L. Bolivar

The Prairie Creek intrusion, near Murfreesboro, Arkansas, is the site of the only commercial diamond mine in North America. Three major lithologies are associated with the intrusion, a hypabyssal peridotite, a volcanic breccia in .which the majority of diamonds occur, and associated tuff. Previous studies, including mining history, geological, geophysical, petrological and whole-rock and mineral chemistry are reviewed. The recent suggestion, by other workers, that this intrusion may be more correctly called a lamproite is examined and supported. This has serious implications for diamond exploration in Arkansas and elsewhere in the U.S.

Jan 1, 1984

By Cheung L. C C, Maconochie A. P

SIROFRAG is a computer-based imaging system that quantifies the post-blast rock fragment size distribution in a muckpile in a mine environment. Improvements in blast performance and blast modelling are being hampered by a lack of a quick and objective method to evaluate the major result of the blast: the fragment size distribution. This is usually done by hand digitising muckpile photographs: a labour intensive and tedious process. SIROFRAG is being developed to quickly, cheaply and objectively provide this information. SIROFRAG is based on active stereo image analysis. It uses a light stripe to illuminate a muckpile and a pair of video cameras to determine the 3D nature of the scanned objects. The imaging system is based on a novel prototype scanning projector that allows images to he captured in full daylight. The Microsoft Windows based software controls the projector and interprets the captured images to provide a size distribution of exposed rock fragments.

Jan 1, 1995

A wide range of drill holes and process streams are sampled for resource estimation, grade control and contractual purposes in the minerals industry. However, despite the availability of training courses, conferences and both national and international standards on correct sampling practices, it is still surprising how often little attention is given to ensuring that representative samples are collected for analysis. The reason for this is that the responsibility for sampling is often entrusted to personnel who do not appreciate the significance and importance of sampling, with cost being the main driving force rather than whether the sample is representative of the material from which it was extracted. This seriously undermines the precision and accuracy of the analyses subsequently generated and can render the analysis process a total waste of time and money and expose mining companies to serious, potential, financial losses. Company management needs to reverse this situation and ensure that sampling is given the attention it deserves to generate representative samples for analysis.

Jan 1, 2009

By Pattinaja MA

Mathematical modelling was carried out to determine the probable convergence and vertical stress patterns around a retreating longwall panel in an underground coal mine in New South Wales. An &apos;Electrical Resistance Analogue&apos; and a program called &apos;THREED&apos; based on the displacement discontinuity method were used for the modelling. Parts of the obtained results are presented here and compared with some measurements of convergence at the site. The modelled and measured data agree better qualitatively, than quantitatively.

Jan 1, 1986

By Howard W. Kilau

The U.S. Bureau of Mines is investigating surfactants added to water sprays to enhance the control of dust during coal mining operations. The objective of the present work was to establish the general applicability of adding sulfate ion to anionic surfactant solutions in order to improve wetting action. This was pursued through laboratory wettability testing of four anionic surfactants and one nonionic surfactant in combination with various concentrations of sulfate ion. The experimental results demonstrated that the addition of sulfate ion enhanced the wetting characteristics of all the anionic surfactants when applied to hard-to-wet coals, while easy-to-wet coal showed more complex wetting behavior. Sulfate ion in the presence of nonionic surfactant enhanced wetting only slightly or not at all. Surface tension measurements of the dilute aqueous surfactant-sulfate anion solutions indicated this property was not important in coal-wetting phenomena, as long as the value was below the critical value for coal. Sulfate ion helps surfactant reduce surface tension but primarily appears to affect wetting action by altering the adsorption characteristics of surfactant on the coal surface.

Jan 1, 1990

By F. Karakas

Organo-bentonite production enjoys important applications including solvent based paints and, more importantly, the production of polymer/bentonite nanocomposites. Quarternary ammonium salts in this regard are still considered as the most versatile reagents in the process of hydrophobization. In this study, a purified form of Resadiye region bentonites, which is one of the most significant sodium bentonite deposits in the world, was used. The raw Na-Bentonite was typically characterized by chemical analysis, XRD and DTA analysis and more importantly for its cation exchange capacity (CEC). Other technological properties such as swelling index, pH, apparent viscosity, water absorption, oil absorption were also conducted on the raw bentonite. The mineralogical analysis of the raw bentonite reveals that it contains about 80 % montmorillonite together with other associated gangue minerals including feldspar, quartz, calcite, dolomite, coloured impurities and other clay minerals. The raw bentonite was subjected to two stage processing involving a series of hydrocylones. Different apex and vortex diameters and different pressures were employed in order to produce a bentonite concentrate with 95 meq/100g CEC from a CEC of 71 meq/100 g. This high quality concentrate was used in the production of organo-bentontonite. The modification was performed with two different quaternary amines, i.e. Trimethyl Phenyl Ammonium Chloride (TPAC) and Hexadecyl Trimethyl Ammonium Bromide (HDTMA-Br). In the modification procedure, three parameters, i.e., adsorption density, zeta potential, swelling index and apparent viscosity were studied simultaneous-ly from the same suspension to identify both the mechanism of the process and also the degree of hydrophobicity. Adsorption measurements were made as a function of conditioning period, pH, and reagent concentration. Simultaneous examination of the adsorption density, zeta potential and apparent viscosity enabled us to pinpoint the optimum region of hydrophobicity which was subsequently tested by settling and critical coagulation concentration in both water as polar and toluene as nonpolar solvents. The results are analyzed in the light of experimental data.

Jan 1, 2014

By Fabjanczyk M. W

A limitation to present theoretical roof reinforcement design methods is the inability to derive accurate and quantitative information about the roof rock condition and the action of reinforcement at various excavation stages. To obtain the information required to assess roof rock stability, detailed monitoring of the in-situ behaviour of reinforcement and roof strata is required. Reliable instru- mentation and techniques have been developed for use in underground coal mines to identify the geometry and magnitude of displacements occurring in roof rock and the forces generated in reinforcement. The use of such instrumentation allows an accurate assessment of the in-situ capability of reinforcement and the mode of reinforcing action developed. In-situ monitoring can supply data required for the practical design of reinforce- ment and assess the potential stability of current designs. The use of such data together with mine wide appraisal of rock and stressfield considerations, can allow roof reinforcement to be designed on the basis of a predicted roof Response.

Jan 1, 1986

By David J. Morrison

Scarcity of truck tyres, increasing cost and decreasing availability of labour, increases in fuel costs and project budget blowouts have changed the paradigm behind mining equipment selections. The cycle of commodity changes have occurred in parallel with the increasing maturity of continuous mining machinery, mobile in-pit crushing systems and very large scale conveyor belt systems. This paper will consider the merits of operating continuous materials handling systems, mobile in pit crushing systems, relocatable crushing systems, relocatable conveyor systems and automated waste handling systems in place of the more conventional approach of truck haulage.

May 1, 2007

By Maria I. De Rosa

The U.S. Bureau of Mines conducted a study to determine if correlations exist between the chlorine or nitrogen contents of materials and the hydrogen chloride (HCI) or hydrogen cyanide (HCN) concentrations evolved during the thermal decomposition of these materials. Hydrogen chloride, hydrogen cyanide, and carbon monoxide (CO) were found to be the primary toxic gases evolved during the combustion process. The experiments were carried out in a 20-L furnace with 1-g samples. The furnace temperature, rising from ambient, was set at 1,000 °C with an airflow of 10 L/min. The variables measured were the gas loads (milligrams per gram) of HCI, HCN, CO, and CO2 (carbon dioxide); CO and CO2 concentrations as a function of time were also measured. Other variables included the average concentrations of submicrometer smoke particles and particles&apos; average diameter, mass of particulates, sample and furnace temperatures, and sample weight loss. The data indicate that there are significant correlations between the percentage of chlorine or nitrogen contained in the original samples and the HC1 or HCN concentrations evolved during the combustion of the materials. These correlations may be used to predict and evaluate a material&apos;s toxic hazard during combustion.

Jan 1, 2010

By Carson Sharp Beltch

The determination of aqueous cyanide is accomplished by either detection in the sample as collected or by removal of the cyanide of the collected sample, followed by detection. The direct determination of the cyanide content of a solution can only be used in the simplest of systems, since many interferences can result in errors. Thus the most widely used method for total cyanide determination involve the reflux distillation of the sample using heat, acid and vacuum or air flow. The basic theory underlying this analytical approach is that by reducing the pH, the quality of molecular hydrogen cyanide will be in- creased and can be removed from the solution by elevating the temperature. The hydrogen cyanide is then collected in a caustic solution and analyzed. The general approach of removing the cyanide from the sample by distillation represented a major advance in this area of analytical chemistry. It enabled the determination of cyanide in many additional types of samples. When it became apparent that the tightly bonded cyanide complexes were not being detected by this approach, many methods fox complex ion destruction were proposed. These methods usually involved low pH adjustment with oxidizing mineral acids, coupled with the catalytic decomposition of the tightly hound complexes. All off the complexes except the strongest could he broken by these methods. The catalytic reflux distillation step has been found to have some negative aspects, since many materials that can be distilled with hydrogen cyanide will interfere with the color development step and result in a false positive reading.

Jan 1, 1981

By J. R. Soule

"The fluorspar deposits in the Gallinas Mining District, Lincoln County, New Mexico, were examined early in February and again in April 1943 by the Bureau of Mines because of the possible importance of newly discovered deposits and of old mine workings showing fluorite-bearing material. There &re many of these deposits spread over a considerable area, and it appeared that exploration might indicate sufficient reserves to support a local mill that could contribute to the supply of fluorspar needed for war purposes. Accordingly, the Bureau initiated an exploratory program in June 1943, which was completed in August 1944.H. E. Rothrock, Roy Earhart, R. G. Smalley, and V. C. Kelly, geologists of the Federal Geological Survey, began mapping and studying the district in May 1943 and continued this work throughout the Bureau's exploration.David J. Stauffer, district ranger, U. S. Forest Service, and several claim owners assisted in the examinations and subsequent exploration.The fluorspar deposits in the Gallinas Mountains are reached by an unpaved forest road, which, leaves U. S. Highway 54 half a mile south of Gallinas station. The road runs due west for 3 miles, then turns due north just beyond the first cattleguard. This north branch is followed for 2 miles to a second cattleguard. There a left branch extends northwest up Red Cloud Canyon to the Red Cloud, and. All. American deposits; the right branch continues north for 2.miles past the Wade Porter ranch, to another left branch, which goes almost 2 miles west to the Hoosier Group deposits. The remaining deposits are reached by trail from either the Hoosier Group or, more easily, from the Red Cloud claim (fig. 1).The Hoosier Group is in sec. l9,, T.. 1S.,1 R. 12 E.; all of the other known ore occurrences are in secs. 13, 14, and 23 to 27, inclusive, T. IS., R. 11 E. All of the deposits are in the Lincoln National Forest and within the limits of a State game refuge. The nearest railroad loading point is Gallinas, Station on the Southern Pacific Railroad. Corona, the next station north of Gallinas, is a Mile or two farther from the deposits.Minor supplied, telegraph, telephone, freight, and express service, and limited living accommodations, Are, obtainable at Corona, 10 to 15 miles from the deposits of Carrizozo, N. Mex., 50 miles south."

Apr 1, 1946

By S. C. Termes, P. E. Richardson, R. L. Wilfong

"The Bureau of Mines conducted research on the flocculation of various minerals with insoluble cross-linked starch xanthate (ISX) to determine its potential as a beneficiation technique for low-grade, highly disseminated ores and for selective desliming. Covellite, chalcocite, pyrite, pyrrhotite, chalcopyrite, bornite, sphalerite, galena, and molybdenite fines flocculate with ISX. Floc formation, floc size, and settling rate are dependent on pH, with the pH dependence differing for each mineral. Quartz is not flocculated by ISX. Experiments to obtain selective flocculation of sulfides from quartz were attempted. Good selectivity was only obtained for the bornite-quartz system. Post flocculation separations resulted in flocculated bornite in grades as high as 92 pct. Evidence is presented that the flocculation of many of the sulfide minerals with ISX may involve covalent bonding of the xanthate group to lattice metal site(s). INTRODUCTIONBecause of the increasing interest in selective flocculation as a beneficiation technique for low-grade, highly disseminated ores and for selective desliming, the Bureau of Mines has been investigating the flocculation behavior of several cross-linked starch derivatives containing chelating groups. This report dis cusses the flocculation of sulfide mineral fines by insoluble cross-linked starch xanthate (ISX).Polymeric materials such as ISX, which contain a chelating group of known re¬activity towards specific mineral surfaces, were first proposed by Slater, Clark, and Kitchener (1), 3 Kitchener (2), and Attia and Kitchener (3) as selective flocculants for mineral fines with particle aggregation possible through a bridging mechanism. ISX appeared to be attractive as a sulfide mineral flocculant because (1) alkyl xanthates are known to react selectively with sulfide minerals"

Jan 1, 1983