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By Valeh Aghazadeh, Shima Barakan, Mina Soleymani, Ehsan Bidari, Morovvat Faridazad

Molybdenite is the most important molybdenum concentrate, which is mainly recovered as a by-product from porphyry copper deposits. Due to the low efficiency of purification processes such as flotation in the reduction of copper content of molybdenum concentrate to a standard level (i.e., less than 0.5 wt.%), further purification by a hydrometallurgical method is required. Although different types of chemical reagents were found to be effective in the leaching of copper minerals from molybdenum concentrate, the mechanisms of these processes remain largely unexplored. In this study, optimal conditions for maximum copper leaching (> 99%) were obtained at the concentration of HCl = 1 M, FeCl3 = 0.5 M, CuCl2 = 0.05 M, CaCl2 = 0.5 M at 75 °C, 500 rpm, and S:L = 1:10 during 60 min. CuCl2 was identified as the most effective leaching reagent for copper dissolution in agreement with Visual MINTEQ model results due to the formation of various types of copper chloride complexes. Furthermore, the electrochemical behaviors of FeCl3, CuCl2, and CaCl2 reagents before and after the leaching process were investigated by the cyclic voltammetry technique. The results of cyclic voltammograms at different scan rates verified the presence of copper chloride complexes, and ferric ions as the oxidizing reagents for better dissolution of copper sulfides. Based on kinetic study results of shrinking core models, both chemical and diffusion reactions controlled the copper leaching process with an obtained activation energy of 33.56 kJ/mol. For recovery of the leached copper, the precipitation process was done by the addition of Na2S at 45 °C, S/Cu = 1, and pH = 9.

Dec 26, 2022

By L. C. Graton

Introduction The Porcupine district of northern Ontario has yielded over $300,000,000 in gold during its twenty-three years of mining operations. It thus ranks among the foremost gold producing areas of the world. Of this $300,000,000 already produced from the District, the Hollinger mine has furnished over 60 per cent and stands as one of the greatest gold mines of all time. In 1929, the Hollinger Directors decided to supplement the current geological and development work by an intensive investigation of the geology of the mine. This special study, begun in June of that year, was completed in October, 1932. An account of the geology of the mine in a degree of detail commensurate with the intensity of the study is in course of preparation. But the widespread interest manifested at the present day in gold occurrence generally, in Canadian gold deposits, and in the specific results of the investigation at Hollinger, appears to justify the immediate presentation of a highly abridged summary of our principal findings, insofar as they relate to the more general and scientific phases of the geological situation. Those conclusions having direct bearing on operating and exploratory policy are not dealt with here. The present preliminary paper, therefore, records chiefly the conclusions reached, with little incorporation of supporting argument or evidence. While intended to give a reasonably balanced perspective of Hollinger geology, the condensed presentation naturally emphasizes those views which are not in complete accord with accounts hitherto published regarding this district.

Jan 1, 1933

By John D. Sullivan

The present article is one of a series which is being prepared by the Southwest Experiment Station of the United States Bureau of Mines in cooperation with the Department of Mining and Metallurgy, University of Arizona, Tucson, Ariz., of papers dealing with factors involved in the leaching of copper ores. A knowledge of the time required to dissolve the various copper minerals present in ores, as well as of the consumption of leaching reagents is very desirable, because with the decrease of the Nation's total tonnage of sulphide ores increasing attention is being given to the recovery of copper by leaching methods from low-grade disseminated ore containing both oxidized and sulphide minerals. As leaching has already been applied with success and profit, this study was undertaken to determine certain fundamental characteristics that are applicable to all ores suitable for leaching.

Jan 1, 1929

By L. R. Burdick

The Smokescope is an instrument recently developed for determining the density of smoke by shade comparison. The instrument is designed so that the smoke is seen adjacent to two shades of gray corresponding to Nos. 2 and 3 on the Ringelmann chart. Data on smoke density are important in the smoke-abatement field. The method that is specified and accepted as standard for smoke-density determination by the majority of city smoke regulations involves comparing the smoke shade with the four shades on the Ringelmann chart as published by the Bureau of Mines.2/ This investigation was made to determine the accuracy and convenience of the Smokescope. It was conducted as a part of the Bureau I s air-pollution work, which includes the study of techniques that will promote smoke abatement. The accuracy of the Smokescope was arbitrarily defined as the difference between the Smokescope determinations and the determinations by the accepted, standard method and was expressed as Smokescope correction. Although the corrections obtained were strictly correct only for the two observers and the Smokescope of the investigation, they indicate what might be expected from any observer who uses a Smokescope with reference shades that duplicate those of the test instrument. The report is devoted largely to the data on Smokescope correction, which were taken from a single stack under controlled smoke conditions. Field work, which was done at various locations with different stacks, is mentioned briefly in connection with the comparison of the convenience of the two methods. The data for estimating Smokescope correction were taken for the three variables that were expected to affect the results, namely, the density of the smoke, the amount of light, and the color of the sky behind the smoke.

Jan 1, 1955

By Zhengjie Chen, Wenhui Ma, Jijun Wu, Kuixian Wei

The gasification reactivity of PC (petroleum coke), strengthened by addition of different potassium carbonate proportions using different grinding medium, was investigated by using thermogravimetric analysis (TGA). Results showed that the gasification reactivity of PC not only increased with the increase of catalyst-loaded, but also showed the effective improvement by anhydrous alcohol. The PC was mixed with potassium carbonate [K2CO3] catalyst at 0.5%, 0.8%, 1.0% and 1.5%, and then ground wet with distilled water. The CO2-gasification rate of PC was only 77.35%, 80.55%, 84.07% and 85.88% under the gasification temperature 1100 °C and holding time 120 min, at different K2CO3 respectively. However, when the PC was ground in anhydrous alcohol at the same condition of catalyst-loading, the gasification rate of PC reached 95.43%, 96.63%, 95.50% and 95.61% at the holding time of 108 min, 101 min, 74 min and 35 min, respectively. It was shown by FTIR, SEM and EDX determinations that the anhydrous alcohol used as the grinding medium can further improve the gasification reactivity of PC when compared with the distilled water.

Jan 1, 2016

By C. Melvin Lepper

A solid-state amplifier for the bridge circuit of an atomic-absorption mercury detector is presented and described. Operational advantages over previously used circuitry include improved time and temperature stability, increased measurement accuracy, and simplified setup, calibration, and operation.

Jan 1, 1972

By Takeshi Nagano

"Prior to discussing future trends of non-ferrous metals smelting and refining, the past developments are looked back. Social and economic environments in Japan over the past two decades are reviewed. Technological developments to comply with these environments are explained, taking for examples the cases of the Mitsubishi continuous smelting and converting process and Onahama's jumbo tank system for copper tankhouse. After considering the factors which will influence the improvements in non-ferrous processing, future trends are forecasted generally for copper, zinc, lead, aluminum and rare earth metals. Recent development works in Japan for the future are also introduced. In the discussed area, it appears that the emergence of new innovative processes would be difficult. The progress will be made rather toward the sophistication of the existing technologies, utilizing the advancement of the related technologies such as computers, electronics, etc. IntroductionThis paper discusses the future trends of non-ferrous metals smelting and refining on the occasion of the international symposium, ""The Metallurgical Processes for the Year 2000 and Beyond"".It is considered that the improvement of technology is greatly influenced by the social and economic environments which surround it. From this standpoint, review was made of Japanese case over the past two decades. Various new technologies were developed also in the non-ferrous metal world to comply with the requirements under the above environments. The examples are described in the cases of the Mitsubishi continuous smelting and converting process and Onahama's jumbo tank system for copper electro-refining.After foreseeing the major factors which will affect the technological developments in the future, the trends are forecasted for copper, zinc, lead, aluminum and rare earth metals generally. Some development works in Japan, which will give suggestions for future trends, are also introduced in some detail."

Jan 1, 1988

By William R. Webster

At the Florida meeting of the Institute, in March, 1895, I presented a Note on a Proposed Scheme for the Study of the Physics of Cast-Iron,1 giving an outline which, for convenience of reference, I here repeat. Suggested Lines for DiScuSsion and IvestiGation. I.—Correspondence between chemical composition and melting-point, fluidity, shrinkage, fracture, chill, micro-structure, and other physical properties. II.—Influence of: 1. Cupola-mixture, use of steel and other scrap, oxidized or clean material, 2. Manner of melting, flux, etc., 3. Casting-temperature, A. Fracture. 4. Manner of handling melted metal and B. Micro-structure. method of casting, C. Physical properties. 5. Size and form of casting, D. Shrinkage. 6 Kind of mold, green sand (under dif- on E. Chill. ferent conditions of ramming, amount F. Residual strew of moisture, and skin-dried), dry sand, G. Condition and quan- loam, and chills, tity of carbon and 7. Rate and mode of cooling castings, other elements. 8. Manner and temperature of heating for annealing, 9. Additions of nickel or aluminum, III. —-Segregation as affected by : 1. Composition ; 2. Casting-temperature; 3. Rate of cooling ; 4. Size and shape of casting. IV. —Blow-holes, their volume and position as affected by: 1. Composition; 2. Casting-temperature; 3. Casting-pressure ; 4. Rate of cooling; 5. Size and ehape of casting ; 6. Special additions. It was hoped that a discussion might thus be elicited, similar in interest and value to the discussion of the physics of steel, which had been so widely and gratefully welcomed by students and practitioners in that department. That this hope was not

Jan 1, 1905

By Muhammad Kamran, NIAZ MUHAMMAD SHAHANI

This study elucidates a new idea to predict mine fire levels by employing several machine learning techniques. A total of 120 patterns of various mine fire influencing parameters, such as oxygen, nitrogen, carbon monoxide, and temperature, were compiled from the Adularya coal mine in Turkey. Techniques like t-distributed stochastic neighbor embedding (t-SNE) and k-means clustering were used to process the data, and support vector classification (SVC) was executed to predict various levels of the mine fire. The results revealed that the proposed model has higher credibility to predict the various levels of underground mine fires.

Feb 14, 2022

By N. P. Kripakov

The Bureau of Mines has developed a unique new mine design procedure to determine the changing static load distributions imposed on under-ground support structures during the mining cycle. The procedure reduces the complexities associated with analyzing a three-dimensional problem. A combination of the multiple-seam displacement-discontinuity model and a two-dimensional finite-element window model produces refined results for a specific area of interest by assuming displacement compat-ibility between models. Input to the procedure includes the geometry of mined-out areas in up to two adjacent seams, the rock mass characteris-tics of the surrounding geology, the in situ stress conditions, and the mining sequence. The displacement-discontinuity program calculates ex-pected loadings for mine structures affected by the mining cycle and/or by overlying or underlying seams. Pseudoelastic finite-element analysis using a yield-factor approach determines the stability of coal pillars by simulating the degree and extent of nrogressive rib failure and sub-sequent load transfer. Application of the procedure is demonstrated on a field problem. In-duced stress changes predicted from the numerical model analysis are in reasonably good agreement with stress measurements obtained from an instrumented chain pillar affected by remnant workings in an upper seam.

Jan 1, 1988

By M. T. Ityokumbul

The use of yield index, the product of the yield and gangue rejection, for the optimization of separation processes is presented. The characteristics of the yield index are contrasted with separation efficiency calculations and applied to laboratory froth flotation and washability data. Data from continuous froth flotation tests conducted to "optimize" froth flotation using process optimization software were also evaluated with the yield index procedure.

Jan 1, 1997

By Robert E. Barieau

This report describes a method for treating pressure-volume-temperature (PVT) data obtained with a Burnett compressibility apparatus. The method makes use of a general nonlinear least-squares technique developed at the Bureau of Mines Helium Research Center. It is assumed that an adequate functional form is available for the expression of the compressibility factor as a function of either the molal density or the pressure. The functional form of the compressibility factor can be either linear or nonlinear in the parameters to be evaluated. Formulas are given for calculating variances and covariances of all parameters evaluated and for calculating the variance of calculated quantities of interest.

Jan 1, 1967

Great strides have been made in recent years to reduce the disaster potential of underground mine fires. However, mines can still be caught unprepared for a fire emergency. Fires can grow too large before they are detected, warning systems can be too slow and uncertain to reliably signal the danger, and suppression systems can be inadequate to extinguish the flames. New mining systems and equipment may create unanticipated fire hazards, and new materials may generate highly toxic combustion products. This report contains papers that summarize recent significant developments from the Bureau of Mines mine fire protection research program relating to these problems. Certain of these findings are also applicable to surface mining operations. The papers fall into the general categories of fire detection and instrumentation, fire warning, fire suppression, diesel equipment, spontaneous combustion, and toxicity analysis of combustion products.

Jan 1, 1988

1. Book reviews Geostatistics for natural resources characterization, edited by G. Verly, M. David, A.G. Journel, and A. Marechal. Hingham (MA 02043, U.S.A.), D. Reidel Publishing Co., 1984. Pt I: 606 pp. Pt 11: 518 pp. U.S.$135,50 per set. Reviewer: D.G. Krige Magnesium, the international perspective, by Peter King. London, Financial Times Business Information Ltd, 1984. £120. 147 pp. Reviewer: D.G. Maxwell 2. Mintek reports Report M156 A kinetic study of the reactions of certain gaseous sulphur compounds with iron. Report MI57 Reaction mechanisms in the reduction of Winterveld chrome spinel with graphite and carbon. Report MI72 Computer programmes for the control and datamanipulation of a sequential X-rayfluorescence spectrometer. Report MI77 A proposed test for the determination of the grindabi/ity of fine materials. Report MI86 A survey of the erosion, corrosion, and abrasion of material-handling systems in the mining and mineralprocessing industry. 3. New journal Advanced materials & processes, issued monthly by American Society for Metals (Metals Park, Ohio 44073, U.S.A.). CIM conference The combined 24th Annual Conference of Metallurgists and the 15th Annual Hydrometallurgical Meeting will be held in Vancouver from 18th to 22nd August, 1985. Light metals The 8th International Light Metals Congress will take place from the 22nd to 26th June, 1987. These meetings, which take place traditionally every few years, are organized by the Austrian Metals Industry Association, the Austrian aluminium industry, and the University for Mining and Metallurgy in Leoben, in collaboration with the Aluminium-Zentrale Diisseldorf. President of AS&TS* Mr Arthur Woodington Reynolds (Sam) took office as President of The Associated Scientific and Technical Societies of South Africa on 28th November, 1984. Sam Reynolds was born in Boksburg on 27th December, 1930, and received his education at Christian Brothers College in Boksburg and at St John's College in Johannesburg. World mining Sweden, Finland, and Norway expect representatives of all mining countries in May-June 1987 to the 13th World Mining Congress in Stockholm. The Swedish Mining Association, the Finnish Association of Mining and Metallurgical Engineers, and The Association of Norwegian Mines will organize the Congress, together with the International Organizing Committee of the World Mining Congress. Sheet metal The German Group of the International Deep Drawing Research Group (IDDRG) will be organizing the 14th Biennial Congress of the IDDRG on 21st to 26th April, 1986, in Cologne and Munich. Safety in mines The 21st International Conference of Safety in Mines Research Institutes is to be held in Sydney from 20th to 25th October, 1985. ILAF A conferences The Instituto Latinoamericano del Fierro y el Acero (ILAFA) has scheduled the following congresses for 1985. Mechanical testing of materials The Deutsche Gesellschaft fiir Metallkunde, together with the Deutschen Verband fiir Materialpriifung and the Fachhochschule Osnabriick, is holding a course on the methods used for the mechanical testing of materials at Osnabriick from 9th to 11th September, 1985. Mine ventilation The Second U.S. Mine Ventilation Symposium will be presented from 23rd to 25th September, 1985, in Reno, Nevada, by the University of Nevada-Reno's Mackay School of Mines and Division of Continuing Education.

Jan 1, 1985

By George K. McCord

It is a pleasure to participate in this Fall meeting of the Society of Mining Engineers to discuss energy conservation trends in the cement industry. Energy is the "life blood" of American industry, and the ability to use available energy resources efficiently may well determine the future of our nation and of its industries. The Federal Energy Administration has classified cement manufacture as one of several energy-intensive industries in the U.S. and has selected the Portland Cement Association to make a detailed study of possible energy conservation measures. Member companies of the Portland Cement Association represent about 85% of the cement producing capacity of the United States and 100% of Canadian capacity. Stated briefly, the purpose of the Association is to extend the uses of portland cement and concrete through research and development, market promotion, education, and public affairs work. PCA's general offices and research laboratories are located in Skokie, Illinois. Our staff of engineers, scientists, and research personnel make the PCA uniquely qualified to perform an energy conservation study of the kind requested by FEA.

Jan 1, 1975

By R. H. King

A very simple cold-bend test was devised and tested for evaluating thermoplastic jackets used on mine-power-feeder cables. A test sample is bent into a semi-circle whose radius is equal to the minimum bend radius recommended by IPCEA and then cooled to the, desired test temperature (-35°C). While at temperature, the sample is straightened by pulling the cable ends with a winch arrangement. The results show that of the jackets tested, those which cannot withstand the test literally burst when the sample is straightened.

Jan 1, 1978

By Jamie Delgado, Marco Arelano

The changes of bench angles in an Open pit mine has a strong economical impact in the “mining business”, particularly in its cash flow related both to the decrease as well as to the increase of the global bench angle or the inter-ramp angle. The global vision of bench optimization process currently developed by Compafila Minera Zaldivar (CMZ), includes the interconnection of different processes driving to the completion of the designs. Thus five very influential areas are recognised such as: (1) The physical Surrounding terrain, (2) the strength parameters, (3) the observational model, (4) the acceptability criteria and (5) the operational considerations. One of the important variables affecting this process is Drilling and Blasting (D&B). Increasing the bench angle requires to optimisation of D&B. To achieve this efficiently controlled sub processes must be defined. Three (3) steps can be defined: (a) design parameters, (b) explosive energy distribution and (c) operation results. To control and improve said steps quantitative evaluations of D&B must be performed. One valid evaluation is the “near field vibration monitoring technique” (at bench level). With the application of damage criteria, measurements and modelling of particle velocity a proper definition and optimisation of stages (a), (b) and (c) was achieved, The use of this methodology has enabled to CMZ to successfully increase the inter-ramp angle in three degrees thus obtaining a saving of US$ 36 million in the waste material removed. Also, the efficient control of the bench slopes has resulted in the improvement of the fragmentation operational results. This has resulted in a 26Oh increase in the ore processing by saving energy in the primary crusher due to its performance improvement.

Jan 1, 2001

By S. K. Kawatra

In most operating coal-cleaning plants, a significant amount of pyrite is recovered in the froth during flotation of high-sulfur coal. Reducing the pyrite recovery first requires that the primary recovery mechanism should be Identified, as different measures are required for reducing entrainment, locked-particle flotation, or true hydrophobic flotation. In this paper, evidence is presented which suggests that hydrophobic flotation is not an important mechanism for recovery of liberated pyrite from freshly-ground coal when the collector is a neutral oil, and that the bulk of the floated pyrite occurs either as a result of simple entrainment or by mechanical locking with floatable coal particles. Column flotation results are also presented which show that significant sulfur reductions can be achieved by reducing levels of entrainment.

Jan 1, 1992

By Norbert L. Piret

From the copper smelter operation a various outputs are to exert negative impacts on the environment. Particularly, emissions like SO2 and dusts, solid wastes like contaminated gypsum and arsenic sludge, effluents and heated cooling water are generated. Most countries have sitipulated an environmental legislation to provide the framework for an efficient environmental management. As part of the planning activities for x major greenfield copper smelter, the Following elaborations are required and were drawn up. -The Environmental Impact Assessment which is the first step of environmental management and mandatory for every new project. - The Environmental Monitoring Plan, which describes the monitoring procedures for the main impacts identified and assessed. -The Environmental Management Plan, which deals with the minimization of environmental impacts, and the methods of its implementation.

Jan 1, 1996

By Arnold K. Reese

It is not the purpose of the writer to set forth in these notes anything new or surprising in blast-furnace practice, but simply to lay before the Institute the somewhat unusual results obtained during a period of six consecutive months, ending April 30, 1896, at the Dover furnace of the Penn Iron and Coal Co., and to give, with these results, the conditions under which they were obtained, and all figures pertaining to that period. This plant was entirely rebuilt, on thoroughly modern and improved plans, in the spring of 1895, by Frank C. Roberts & Co., of Philadelphia.

Jan 1, 1898