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By M. Maeda, H. Sasaki

"Precious metals such as platinum, palladium, and rhodium are commonly used for automotive catalyst converters. To recover these metals with lower environmental load and cost, exposure to zinc vapor was proposed as a pretreatment prior to acid leaching. Alloying with zinc is expected to enhance dissolution of precious metals and reduce the amount of toxic chemical agents required for the leaching. This study examined the effect of the alloying pretreatment using model catalysts. Catalysts were immersed in leaching solutions for a predefined time with or without zinc vapor pretreatment, and the amount of dissolved metals was then evaluated. INTRODUCTIONAutomotive catalysts account for large portions of the world consumption of platinum (Pt), palladium (Pd), and rhodium (Rh) (Butler, J., 2011). Because of their limited production and high prices, recovery of the precious metals from spent catalysts is obviously an important issue. A representative structure of an automotive catalytic converter can be described as a monolithic ceramic support with a honeycomb structure which is coated with porous oxides such as those of aluminum (Al2O3), cerium (CeO2), and zirconium (ZrO2) (Heck & Farrauto, 2001; Matsumoto & Shinjoh, 2007). Small particles of precious metals, originally several nanometers or less, adhere to the oxides.Typical recovery processes for precious metals from scraps are shown in Figure 1 (a)-(c) (Habashi, 1997; Yoo, 1998; Shibata & Okuda, 2002). Precious metals can be recovered by using non-ferrous smelters as Figure 1 (a) shows. Smelted along with metals such as copper (Cu), precious metals and ceramics in the scraps are absorbed into the metal phase and slag phase, respectively. Because the metals separate from Cu as anode slime in successive electro-refining, such a process can recover precious metals as co-products of Cu. However, in order to prevent negative effects on the principal process, a specialized procedure is needed. Figure 1 (b) is a specialized approach in which scraps are melted at elevated temperature with Cu called the Rose process. Here Cu works as a collector metal, and the absorbed precious metals are then concentrated by oxidation of Cu. Such a process can separate precious metals from ceramics constituting catalyst converters. Smelting at high temperature, however, requires extensive equipment as well as a high amount of energy. On the other hand, hydrometallurgical processes may be effective to separate precious metals from ceramics into an aqueous solution, because chemical agents can act on these metals selectively (Figure 1 (c)). Leaching of precious metals, however, requires strong acid and oxidizing agents because of their corrosion resistance; this makes liquid waste disposal and the large environmental load controversial. To solve the problem, a metal vapor pretreatment was proposed (Okabe, Yamamoto, Kayanuma, & Maeda, 2003a, 2003b; Kayanuma, Okabe, Mitsuda, & Maeda., 2004; Kayanuma, Okabe, & Maeda, 2004; Itoh, Kayanuma, Miyake, Kimura, & Maeda, 2005). A flow diagram of the process using zinc (Zn) vapor is shown by Fig. 1(d). Exposed to Zn vapor, precious metals are expected to form alloys which dissolve more easily than pure precious metals, thus reducing the use of chemical agents and environmental load involved with successive leaching. In previous research (Sasaki, Miyaki, & Maeda, 2010; Sasaki & Maeda, 2010, 2012), dissolutions of precious metal alloys formed by Zn vapor treatment were examined in hydrochloric acid (HCl) using an electrochemical method, and it was confirmed that these metals dissolved at higher rates from the alloys than from their pure states (Figure 2). In this study, the availability of the alloying pretreatment was demonstrated by testing on model catalysts in leaching solutions."

Jan 1, 2012

By H Bleuler

A new portal and access drift was constructed by Concrete Constructions for BHPÆs Elouera Colliery, south of Wollongong.The portal area at the base of the Illawarra Escarpment is in soft colluvium material, underlain by highly to moderately weathered sandstone. The area has a well documented history of slope movement or slope creep and one of the main criteria for the design was to minimise disturbance to the unstable slope by limiting the excavation for the portal establishment. This was achieved by incorporating a sloped headwall and gabion wingwalls to accommodate the anticipated creep and groundwater seepage.Main features of the design process also included the provision of both primary and secondary support in a single shell application and the use of canopy tubes to provide support ahead of the tunnel face.The active involvement of the designer during the construction phase and the flexibility of the design concept allowed changes to the support methodology to be carried out as excavation proceeded.This paper describes the design process undertaken for portal establishment and access drift to cater for the variability of the exposed ground conditions along the drift alignment.

Jan 1, 1999

By Marcela Silva Araujo dos Santos

O objetivo deste trabalho é apresentar um método para a reciclagem de embalagens blister, preservando as propriedades de polímeros e também do metal. A metodologia consiste em quatro etapas: moagem, quarteamento de amostras, tratamento com solvente e separação em meio denso. A matéria prima dos ensaios é proveniente de descarte e rebarbas de produção da indústria farmacêutica. Os equipamentos utilizados são um moinho de facas e agitadores mecânicos. Durante o tratamento com solvente, acetato de etila, as placas de alumínio do blister se destacam dos fragmentos poliméricos e, o conjunto forma um emaranhado, que posteriormente é separado em meio denso salino.

Aug 16, 2017

By Marco Silva

Underground mines are complex environments that require continuous control and monitoring actions in order to have a safe and efficient operation. At Nexa, the goal of achieving "zero harm" promotes the constant search for in its operational processes. Currently, there are manual activities that reduce the agility and precision when working with information from inside the mine, using mostly radio communication and management by sight of badges as an operational standard. This project was born in the context of increasing the operational safety of underground mines, bringing gains to the entire process involving the underground.

Sep 29, 2023

By R deMoraes, A Bobet

The last decade has seen a resurgence of interest in lunar exploration and the emergence of countries like China and India as space fairing nations. In 2004, the US announced a new Vision for Space Exploration, whose objectives focused on human missions to the Moon and then Mars. The near future is likely to see the emergence of a worldwide drive to revisit the Moon as the first step in investigating the Solar System. To date, the Apollo missions provide our only experience of human operations on the Moon or anywhere else beyond Low Earth Orbit. Much was learned from these missions. However, their short duration means that many of the environmental effects that will be important for longer-duration missions could not be quantified. In addition, long-duration missions and infrastructure on the Moon require new technologies and capabilities, which must operate successfully and reliably in this lunar environment. Developing these technologies poses significant challenges for the exploration program. The paper discusses the risks associated with the construction of lunar surface and underground structures and the challenges to adopting the standards and rock mass classification systems developed on Earth and their applicability to the Moon. Moreover, an exchange of views to explore near-surface geologic and geotechnical profiles of the Moon is emphasized and implications of the lack of knowledge on rock mass characterisation of the Moonrock mass, the lack of theoretical/empirical experience on the use of rock mass systems outside Earth, and uncertainties.

Nov 29, 2022

By Moacir Alves dos Reis

A fim de monitorar visualmente as condições de funcionamento em cada ventaneira do alto-forno 3, foi instalado um sistema de monitoração através de câmeras especiais de vídeo em cada ventaneira permitindo assim a inspeção visual para verificar as condições das ventaneiras. A inspeção na ventaneira é de particular importância quando carvão pulverizado é injetado através da mesma. Caso ocorra um bloqueio na injeção de uma ventaneira, o carvão pulverizado pode queimar no tubo reto ao invés de queimar no alto forno, resultando assim em danos consideráveis para o tubo reto, ocasionando também a parada do Alto Forno. Por segurança, o fornecimento de carvão pulverizado para uma ventaneira dever ser interrompida assim que for detectado o bloqueio. O bloqueio pode ser detectado tanto por olhando diretamente para a ventaneira através do visor ou continuamente através do sistema de monitoração.Principais facilidades deste sistema: Monitoração contínua das condições operacionais das ventaneiras e do Alto Forno; Monitoração visual e eletrônica simultaneamente; Totalmente isolado da pressão do Alto Forno; Fácil de ajustar; Fabricação especial para trabalhar em áreas agressivas; e Fácil adaptação nas ventaneiras existentes em um Alto Forno.

Aug 16, 2017

By Long An, Chao Wu, Yuanhui Li, Xing Sun, Shuai Xu, Changyu Jin

Stage open stope mining (SOSM) maintains the stability of excavation openings by leaving a large number of rib pillars. Affected by the strong unloading due to stage mining and the low width-to-height (w/h) ratio of the pillars remaining, large-scale destabilization disasters of rib pillars or excavation openings easily occur when the distribution of ground stress or the size of rib pillars is unreasonable. In view of these problems, a physical SOSM model test was carried out based on an underground metal mine in the city of Chifeng in China, revealing the deformation and failure characteristics of the SOSM pillar group by overloading.

Jul 1, 2023

By Nick Karlin

Dragados USA is constructing the LA Effluent Outfall Tunnel, a 7-mile, 18 ft internal diameter effluent discharge tunnel, utilizing a 21.6 ft (6.585 m) Herrenknecht Mixshield TBM. This paper highlights the means and methods used for TBM launch from a 55 ft diameter shaft excavated in wet with diaphragm wall support of excavation. This included SEM excavation of jet grout blocks for starter and tail tunnels, temporary concrete structures and steel installations, TBM sealing system, umbilical management for TBM hydraulic, electric and bentonite circuits as well as complex segment delivery logistics. The many launching challenges were overcome thanks to the innovative approaches from the project team.

Jun 13, 2023

By Eduardo Piassi Nicoli

Este trabalho tem a finalidade de apresentar projeto para melhoria de qualidade e redução do consumo de água em torres de resfriamento sem a utilização de produtos químicos e ainda eliminando problemas de incrustações e acúmulo de metais pesados, corrosão e formação biológica, através de solução inovadora (novo modelo mental).

Oct 30, 2017

By J. R. Patts, A. B. Cecala, E. J. Haas

Exposure to respirable crystalline silica (RCS) remains a serious health hazard to the U.S. mining workforce who are potentially exposed to RCS [1,2] as various ore bodies are drilled, blasted, hauled by truck, crushed, screened/sized and transported to their destinations. To examine a method for assessing RCS exposure using a NIOSH-developed video exposure monitoring (VEM) technology (referred to as Helmet-CAM), video and respirable dust concentration data were collected on 80 miners across seven unique mining sites. The data were then collated and partitioned using a thresholding scheme to determine exposures that were in excess of 10 times the mean exposure for that worker. Focusing on these short-duration, high-magnitude exposures can provide insight into implementing controls and interventions that can dramatically lower the employee’s overall average exposure. In 19 of the 80 cases analyzed, it was found that exposure could be significantly lowered by 20 percent or more by reducing exposures that occur during just 10 minutes of work per eight-hour shift. This approach provides a method to quickly analyze and determine which activities are creating the greatest health concerns. In most cases, once identified, focused control technologies or behavioral modifications can be applied to those tasks.

By Anthony Iannacchione, Tim Miller, Nicole Evanek

The Subtropolis Mine is a room-and-pillar mine extracting the Vanport Limestone near Petersburg, OH. In February 2018, mine management began implementing a new mine layout to better control the negative effects of excessive levels of horizontal stress. Almost immediately, the conditions in the headings improved. Conversely, and as expected, stress-related damage was concentrated within crosscuts. Over the last 18 months, the mine operator has diligently experimented with different techniques/methods to lessen the impact of the instabilities in the outby crosscuts. The range of controls used by the mine operator include angled crosscuts, crosscut offsets, increased distance between crosscuts, arched crosscuts, cable-bolted crosscuts, altered blasting pattern, and windows. A window is used to resist roof deformation by leaving a strong brow of roof rock within the crosscuts.

By R L. Koenig

Previous papers at Metplant conferences have covered the options for crushing and grinding circuit selection. High Pressure Grinding Rolls (HPGR) may have considerable advantages over autogenous milling circuits but test work and evaluating different grinding circuits must be done to establish which circuit provides the best option. The Hawsons low grade magnetite project provides a specific example in using thorough test work, careful simulations and detail in design to allow the evaluation of grinding circuit performance. Fortunately tools are available for this evaluation and the test work for the Hawsons iron ore is detailed in this paper. The results of the test work and simulation indicates that although the Hawsons iron ore is competent in terms of autogenous milling given the medium hardness of the ore in the Drop Tests, the HPGR testing indicates that the use of HPGR is likely to use half the energy requirement. This is a characteristic of the Hawsons iron ore and is likely to be valid for other iron ores in the Braemer Iron Formation which stretches from the Hawsons lease in New South Wales to Razor Back and South Dam in South Australia. The Hawsons magnetite iron ore resource has been known from the early 1960s when CRA explored the area. However, the Pilbara region was discovered in this era and this led to development of high grade direct shipping grade hematite ores. Carpentaria Exploration (Capex) rediscovered the magnetite whilst undertaking multi-commodity exploration in the Broken Hill district during 2009. The magnetite grade was found to be low at around 16% Davis Tube mass recovery (DTR) but despite this, the project provides a positive business case as a result of the following key factors:• The mineralisation is particularly soft for crushing and grinding with a Bond Work Index of 6.3.• The mineralised rock fractures easily preferentially along grain boundaries.• The location is close to mining infrastructure and a skilled workforce in Broken Hill, 60km to the North East.• It is close to road and rail infrastructure for access to the resource.• The only contaminant in concentrate is silica.• The resource contains many billions of tonnes of magnetite mineralisation.The low Bond Work index is a key characteristic of the Hawsons iron ore and the use of autogenous milling and HPGR circuits is compared to other iron ores indicating why the plant energy requirement may be just as important as iron ore grades.

Aug 8, 2011

By Sergio Neves Monteiro, Fabio Da Costa Garcia Filho, Dian Souza de Oliveira

The properties of the nickel based superalloys, in particular 718 nickel-based alloy, are mainly improved by the hardening mechanism, which is based on precipitation of second phases. This work aimed to compare the evolution of precipitation hardening in a 718 alloy microstructure for two different solubilization conditions: 1050 °C for 2 h and 970 °C for 2 h, followed by a period up to 120 h of aging at 800 °C and correlated to the values of hardness. The microstructure was analyzed by optical microscopy. Vickers hardness test was performed and the grain size was measured. It was verified an increase on the hardeness of this material up to 15 h of aging, after that the value decreased to a level that is maintained until 120 h for both solubilization conditions.

Mar 1, 2018

By Tianyou Huang, Yuan Lu, Haimin Long, Jinwu Kang, Gang Nie

"The distortion of metal parts during heat treatment process is one of the main obstacles in industry to ensure high-quality work and less or no machining allowance, especially for large but thin steel castings such as heavy turbine blades. In the paper, a method is proposed to control the distortion by adjusting heat transfer coefficient of metal parts during heat treatment process. Required heat transfer coefficients can be realized by getting the metal parts into contact with various media such as water spray, insulation felt or materials with different heat conductivity. The control method based on this idea is set up and achieved. By using insulation felt and water spray to change the heat transfer coefficient during the stages of heat treatment process, the results indicate that the proper control time and vary with materials.IntroductionThe distortion of metal parts during heat treatment process is one of the main obstacles in industry to ensure high-quality work and to realize less or no machining allowance [1]. For example, the Three Gorges turbine blade’s distortion is as large as 50mm during heat treatment process. The uneven heating and cooling during heat treatment process is the main reason for distortion [2]. By adjusting heat transfer coefficient of different areas of metal parts, the heat treatment process could be controlled. The temperature variation, direct cause for distortion, could be under control. Loeser Klaus used high pressure gas to achieve uniform heat transfer during gas quenching and proposed the possibility to use ""Dynamic Quenching"" processes where the quenching severity is varied during quenching by stepwise control of either gas velocity or gas pressure [3]. Li Zhichao also suggested minimizing distortion by marking a component into several areas and imposing different heat transfer coefficients on each area [4]. Heat transfer coefficient can be controlled by getting the metal parts into contact with different media such as water spray, insulation felt, air or different heat conduction materials. In addition, the exact time to adjust the heat transfer coefficient is another factor for distortion. A method is presented in this paper by actively adjusting heat transfer coefficient for different areas of metal parts and different stages of heat treatment process to control their distortion. The corresponding experiments have been made by using different metal materials."

Jan 1, 2012

By Patrick High Smith

The paper summarizes the results from geochemical orientation and project surveys in North and South America. The orientation surveys were designed to characterize the soil gas response over buried mineralization and compare soil gas geochemistry with other geochemical exploration techniques for overburden. In addition to successful tests in orientation surveys, soil gas geochemistry has been applied in large-scale exploration programs for gold, copper, and zinc. The studies includes results from several of these surveys, including the Crandon Zn-Cu massive sulfide deposit in Wisconsin, USA, and the Ruby Star skarn Cu deposit in Arizona, USA.

Apr 24, 2001

By H. A. Wentworth

The Central Manitoba mining district, as spoken of in Manitoba, refers to that portion of the country lying between lake Winnipeg on the west and the Ontario boundary on the east, and from a few miles north of the Wanipigow (or Hole) river on the north, to a few miles south of the Bird river. It embraces two known mineralized belts; the gold area in the north, extending from the shores of lake Winnipeg almost to the Ontario boundary (in a slightly southeasterly direction) a zone some eight or ten miles wide and perhaps forty miles long, lying (for the most part) north, and parallel to, the Manigotagan river; and the Bird river copper and coppernickel deposits, an area not yet clearly defined, but in general lying immediately north of, and roughly parallel to, the Bird river. To the south of the Bird river is a somewhat differently mineralized area, numerous pegmatite dykes being found, with minerals typically associated with such rocks. More specifically, the known gold deposits are largely segregated in the above belt; (1) around English brook; (2) along the north shore of Wanipigow lake; the Rice lake area (about midway of the belt); and the Long Lake-Bulldog lake area, at the eastern end of the belt. Not all the known gold occurences are found in these segregations, but the density of claim staking in these areas is perhaps an indication of the greater number of prospects found in them to date.

Jan 1, 1925

By Tim Deans

This paper will address methods to manage hydraulic hose and coupling inventory so that parts will be available to build assemblies for the vast majority of equipment with as little inventory as possible. Topics also to be covered will include some basic hose assembly tagging techniques that will help keep equipment running by tracking problem hoses and building ?band aid? kits, having problem hoses premade in stock, and inventory usage tracking (one of the biggest problems for any inventory manager is knowing which couplings have been used so they can re-order). Cradle to grave tracking of hydraulic and industrial hoses insures reliable service of vehicles and ethical disposal of old hoses and couplings. With accountability for disposal of hose products that may contain chlorine (neoprene tube material in some hydraulic hoses) and carbon black that will be scrutinized more closely in the future, a proactive approach should be adopted in order to minimize maintenance facility problems.

Aug 1, 2013

By K. D. Genn, A. Mucha

This paper deals with Hilton Mines' approach to the maintenance of wear items such as truck boxes, shovel buckets, tractor pads, crawler sprocket idlers and the drop-ball. Each will be given a brief. description as to application, design, kind of materials involved and type of wear. The maintenance procedure is then outlined in terms of materials used, preliminary preparation, and welding and machining practices. The service history of new and re-paired items and the relative economics of repair vs replacement will then be presented.

Jan 1, 1969

By S M. J Koleini, F Hedjazi

The purpose of this research was to study the calcination of lead-zinc flotation tailings from the Angouran lead and zinc flotation plant in Iran as a pre-concentration step prior to hydrometallurgical processing of the oxidised tailings. There is an abundance of these tailings in the Angouran region and making use of these tailings would help preserve national wealth and also reduce the serious problems of environmental pollution caused by the tailings. At the optimal conditions of calcining at 750 - 800¦C for 45 minutes, the sample showed a mass loss of about 19 per cent. Mineralogical analyses showed that under these conditions the carbonate minerals including smithsonite (ZnCO3), calcite (CaCO3) and dolomite (Ca Mg (CO3)2) decomposed to their respective oxides. Hemimorphite (Zn4Si2O7 (OH)2.H2O) converted into willemite (Zn2SiO4) and this transformation postponed the formation of silica gel in the leach solution. The grade of zinc increased from 22.20 per cent to 29 per cent. These mineralogical changes resulted in desirable reactions in the acid leach process.

Jan 1, 2004

By H. Vendette, N. R. Dando, A. Moras

The thorough analysis of results obtained from different testing campaigns performed on an alumina dry-scrubber pilot installation treating aluminum potline offgases, suggests a clear relationship between the emissions of gaseous fluoride and the fluoride saturation level of the alumina. The integration of this relationship into the development of a new generation of alumina dry scrubber represents an intriguing challenge regarding the design of more efficient air pollution control equipment. An innovative scheme challenging conventional industry practices was proposed. From theoretical simulations, the reduction in fluoride emissions can potentially be reduced by as much as 50% in the summer season. To validate this innovative approach, Solios in partnership with Alcoa Primary Metals, modified one of the Aluminerie de Deschambault's systems by adding new temporary equipment on the operating units and subjecting it to several test campaigns. This article presents the first results obtained in testing this new and innovative approach on alumina dry scrubbers used to capture fluoride emissions coming from aluminum electrolysis potlines.

Jan 1, 2006