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By L. L. McMurray

Ilmenite is the most important raw material for manufacture of titanium dioxide.' Industrially, several other products are made from ilmenite, the most important of which are: ferro titanium, ferro carbon-titanium, copper-titanium, titanium carbide and titanium nitride. The production of titanium metal is still in the laboratory stage because of the difficulty of extraction and as yet no important application for the metal has been found. Ilmenite has received considerable attention as an industrial raw material. Imports of ilmenite concentrates for the first nine months of 1941 were 156,737 short tons, the chief source being Travancore, India.2 Domestic produttion of ilmenite has heretofore been confined to Amherst and Nelson Counties, Virginia, where a complex rutile, ilmenite, and apatite ore is mined and treated to utilize all three of these minerals. A recent report3 has described development of the large titaniferous magnetite ore body at Tahawas, New York, where it is expected that 800 tons of ilmenite concentrates, containing 48 per cent TiO2 will be produced daily. Additional domestic production is expected from a large ilmenite deposit recently opened in caldwell county, North carolina. Flotation tests indicate that a high-grade concentrate containing 53 per cent TiO2 can be made from the North Carolina ore. Prospecting of domestic ores in other areas has been reported.' It appears that increased domestic production of ilmenite may well save considerable shipping space so vitally needed in these times. The composition and chemical structure of pure ilmenite is given by Dana as: FeO, TiO2; Ti, 31.6 per cent, Fe, 36.8 per cent, O2, 31.6 per cent. This composition is variable in that some iron or titanium may be replaced, giving a variable iron-titanium ratio. As an example, the iron-titanium weight ratio of ilmenite in Caldwell County, North Carolina, has been determined to be 0.94 (using 97.1 per cent ilmenite concentrate obtained by heavy liquids on minus Iso-mesh ore) compared with theoretical 1.16. No rutile was noted in this ore to account for the low value. This North Carolina ore is free of magnetite, which is a common associate of ilmenite ores. In view of a large potential production from North Carolina, the Tennessee Valley Authority conducted a study of methods of concentration of that ore, of which the results are reported herein. The Ore Five samples of Ore were taken from the deposit at various exposed locations and were mixed for the study and testing. An attempt was made to proportion the amount of weathered and unweathered portions in making the composite sample, so as to approximate actual operating conditions. An examination of representative specimens of the sample showed the following general facts: 1. The black mineral comprising nearly 70 per cent of the ore is ilmenite.

Jan 1, 1948

By William A. Griffith

The recent recession has severely impacted the performance and results of virtually all of our natural resource companies. The depressing climate continues to linger and recovery maybe sometime away. Problems remain for resource companies in the steel and petroleum industries as well as the mining business. In February, at the AIME Annual Meeting in New York, an All-Institute session presented a variety of views on the situation. A. T. Yu, chairman of ORBA Corp., Mountain Lakes, NJ, organized presentations by top management personnel of four natural resource companies. This well attended session heard management strategems for the present and views for the future. A compilation and synthesis of these presentations, gathered by Dr. Yu, are presented here for ME readers. Leading off will be William A. Griffith, president and chief executive officer of Hecla Mining Co., Wallace, ID. Other speakers presented here include Wilfred P. Schmoe, executive vice president of Du Pont Co., Wilmington, DE; Frank W. Luerssen, chairman and chief executive officer of Inland Steel Co., Chicago, IL; and Adam H. Zimmerman, president and chief operating officer of Noranda Mines Ltd., Toronto, Ontario. First, then Griffith's remarks. Introduction The key to successfully managing a natural resource company in austere times is good management in good times. In other words, position the company during prosperous times to survive the times when the well dries up. Although we know how to manage properly, for various reasons we sometimes do not do it. We forget the lessons of history. We allow ourselves to be carried away by our egos. We fail to position our companies properly in good times. As a result, in bad times we find ourselves in deep trouble. We need constant reeducation in the things we already know. In the natural resource industries, proper positioning in good times involves becoming a low-cost producer, retaining the flexibility to pull in our horns, developing a lean and effective organization, and maintaining a healthy balance sheet. Nothing improves the chance of survival during austere times as much as being able to produce at a lower cost than your competitors. In our business, that means having low-cost mines - low cost because the ore bodies are high grade or favorably located, and because they are efficiently operated. It also means recognizing the competition. The key numbers are the cost to produce an ounce of silver or gold. Nothing else really counts. And our competition is every other precious metal mine in the world. Flexibility is important when one gets stuck with a high-cost operation, often because things do not work out as we expect. It is important to be able to shut down an operation quickly and easily, without high holding costs, and without disrupting the corporate organization. A lean and mean, effective organization of competent people is vital during bad times. A company will not have that if it is not developed and maintained during good times. Finally, a natural resource company has to develop a healthy balance sheet during good times if it is to survive the bad. Money in the

Jan 6, 1985

By H. I. Aaronson, C. Wells

THIS is a preliminary report on a detailed metal- lographic investigation of the bainite reaction in a plain carbon hypoeutectoid steel. In view of the current interest in the bainite reaction and of the controversies which still exist about even the basic phenomenology of this mode of transformation, it was considered desirable to present a summary of the more important results obtained to date prior to the completion of this investigation. The steel used contained 0.29 pct C, 0.76 pct Mn, 0.25 pct Si, 0.005 pct P, and 0.007 pct S. The alloy was homogenized for 48 hr at 1250°C. Individual specimens were then austenitized for 30 min at 1300°C and isothermally transformed for various times at temperatures above and within the bainite region, ranging from 775" through 500°C at intervals of 25°C. These specimens were carefully examined on a research metallograph; a few specimens of especial interest were also studied electron microscopically.' Bainite may be defined as the aggregate structure resulting from the precipitation of carbides from supersaturated ferrite which formed by nucleation and diffusion-limited growth. Two groups of experimental observations made during the present study provide support for this mechanism of the bainite reaction: 1—at 625°C, partial conversion of pro-eutectoid ferrite to bainite began after more than 99 pct of the austenite had decomposed and 2—the precipitation of bainitic carbides occurred only within the ferrite phase. The proeutectoid ferrite and the bainite reactions in the steel studied were found to be morphologically continuous. Following the classification scheme of Mehl and Dube,2 three principal morphologies of proeutectoid ferrite were identified in the temperature region (625" to 550°C) in which the two reactions blend—grain boundary allotriomorphs," * Grain boundary allotriomorphs are crystals which nucleate at and grow preferentially along matrix grain boundaries. Widmanstaetten side plates, and intragranular plates. Carbide precipitation converted these morphologies into their bainitic equivalents with increasing isothermal reaction time. Conversion took place more rapidly as the reaction temperature was reduced. The replacement of supersaturated ferrite by bainite, however, did not occur uniformly even within individual austenite grains and was noticeably incomplete at higher transformation temperatures, e.g., 625° to 575°C. The ferritic and bainitic forms of a given morphology thus were frequently found to coexist, often inextricably intermixed, in a given specimen. At 625" and 600°C, the conversion of ferrite to bainite was clearly seen to have occurred entirely by the nucleation of carbides at ferrite/ferrite boundaries, as shown in Fig. 1. The nature of the loci at which carbides formed at lower temperatures was often difficult to ascertain with a light microscope, although the alignment in rows of many of the carbides, illustrated in Fig. 2, suggested that nucleation had again occurred at grain boundaries or subboundaries within the ferrite. Application of the electron microscope confirmed this deduction for bainitic structures formed at these temperatures, as shown in Fig. 3. The dense black appearance of bainite formed at very low reaction temperatures in higher carbon steels3 indicates, however, that isolated lattice defects within ferrite crystals prob-

Jan 1, 1956

Rossiter Worthington Raymond, Ph.D., LL. D-1840 to 1918.-Dr. Rossiter W. Raymond, Past President, Honorary Member and Secretary Emeritus, died suddenly of heart failure at his home, 123 Henry'St., Brooklyn, N. Y., on the evening of Tuesday, Dec. 31, 1918. He was one of the founders of the Institute and its second President. A Memorial 'Service will be held on Monday afternoon, Feb. 17. James Douglas.- The Institute suffered a second very severe loss by the death of Dr. James Douglas, Honorary Member, Past President (having served as President for two years), and in three separate respects the greatest benefactor of the Institute: first, in raising funds by volun¬tary subscription and his own personal gifts to pay the Institute's share of the money owed on the land on which the Engineering Societies Build¬ing now stands; second, as original donor to Engineering Societies Library; and third, by his bequest of $100,000 for the maintenance of the library of the American Institute of Mining Engineers. A resolution regarding the death of Dr. Douglas was passed by the Board of Directors and at the meeting of the Institute on Sept. 4, 1918, in Colorado, at which time a memorial service was held in the thea¬ter of the Hotel Broadmoor, attended by about 400 members and guests. A copy of the resolution was prepared and sent to the family. A bronze tablet is now being prepared and will be placed in the Members' Room and unveiled at the February meeting. A biography and portrait of Dr. Douglas was published in the September, 1918, Bulletin. There is also placed in the Engineering Societies Library an oil portrait of Dr. Douglas which had his own approval and was presented by him. American Institute of Metals.--During the Spring of the year, plans were completed with the American Institute of Metals whereby this society became the Institute of Metals Division of the American Insti¬tute of Mining Engineers. This body was a dignified aggregation of metallurgists which had been in existence for about 11 years. A bronze tablet commemorating the American Institute of Metals is now being placed in the Members' Room of the Institute, and during the year 1919 the Bulletin will bear the following title: "Bulletin of the American Institute of Mining Engineers, with which is consolidated the American Institute of Metals." Visits to Local Sections.-During the year President Jennings made visits to six of the Local Sections, on three of which occasions he was accompanied by the First Vice-president and the Secretary. First Vice-president Goodale made five visitations and the Secretary made eight.

Jan 1, 1923

By Miller D. R

The mineral exploration and extraction industries have gained major cost and efficiency benefits from the use of computers. However these industries are now at a cross-roads with two seemingly disparate developments - that of an increasing number of complex geoscience databases and, at the same time, the merging of all known data for the particular regions at minimal cost. These two developments can be managed by the development and of an industry accepted geoscience data model and dictionary. This will provide a common basis of understanding for geoscience data through a common language and a common structure for geoscience information. Integration of specialist systems and databases can then proceed efficiently. The development of a data model is going ahead with consensus from the mining industry. This is a joint government and industry funded project and managed through the Australian Mineral Industries Research Association, AMIRA. AMIRA is a well known research broker to the Australian mining industry obtaining sponsorship for projects both from private and government groups. The AMIRA project, P431, called the Geoscience Data Model, is to be the Australian standard data model for geoscience disciplines. The requirement for a standard geoscience data model has been recognised in Australia for some time. In October 1991, the Australian Government Geoscience Database Policy Advisory Committee (GGDPAC) established a Geoscience Data Standards Working Group which drafted a comprehensive list of data categories of the geoscience area. An AMIRA project called AMDEX was established to develop a transfer standard for the mining industry data at about the same time as this committee was in operation. The first AMDEX sponsors meeting was held in May 1991. It was proposed to use the US Spatial Data Transfer Standard (SDTS) as the basis to transfer mining data in AMDEX. A limited data model of mining data to be transferred was developed for the AMDEX standard under SDTS. The Australian Geological Survey Organisation (AGSO) saw the need to extend this and develop a complete data model for the geosciences and proposed this as a new project to AMIRA. This was strongly supported by GGDPAC which lead to sponsorship of the project from most state geological surveys. The Geoscience Data Model can be broken down into separate data models for a number of geoscience themes and sponsorship obtained so far will enable models to be developed for a comprehensive set of themes selected by the project sponsors. Further sponsorship is required to enable a more complete coverage of the geoscience area to be developed. Sponsorship for the Geoscience Data Model has been strong from the geological surveys and there was some effort by GGDPAC to promote the project in these organisations. An Australian geoscience data model is of immediate use to the geological surveys in assisting the standardising of huge quantities of geoscience data held by government agencies and it is preferable that this be an Australia-wide standard.

Jan 1, 1995

By Nóra Schreithofer, Zoltán Jávor, Kari Heiskanen

"One of the challenges the mineral processing industry is facing is caused by the fact that water resources in mining areas are becoming very limited and the cost of water is increasing. The water sources in arid regions often have high salt content. Environmental regulations are forcing plant operations towards completely closing the water cycles within plants. This means that impurities (salts, reagents, ions dissolved from minerals, etc.) accumulate within the circuit that will affect the flotation performance. Water purification can significantly increase the operating costs therefore it should be carefully considered weather the impurities need to be completely removed or is there a tolerable level of impurities that can still be left in the process water without significant deterioration of the flotation performance? Several additional questions arise: what are the tools that help identify what is a tolerable level of impurities? How do the different impurities interact and what is their effect on the process? The effect of frothers on the dynamic properties of air/liquid interface in different size-scales has been extensively studied by the authors in the past. Based on these studies a frother characterization framework was developed that systematically examines the dynamic surface properties of the air/liquid interface in relation to the bubble size. This work can be considered as tool that could be used for the above mentioned purpose. The present study investigates weather the same frother characterization framework can be applied for systems where both frother and different types of salts are present. Nasfroth 240 was used as a frother, in combination with structure-breaker KCl or structure-maker NaCl and CaCl2. Bubble size measurements in laboratory scale mechanical flotation cell and laboratory flotation column and dynamic surface property measurements (dynamic surface tension and dilatational elasticity) were performed. The results highlighted the addition of salt to the frother solutions significantly decrease the bubble size and increase the froth high. The coalescence behavior of bubbles showed correlation between the D32 and ionic strength of salts. The results highlighted that the studied structure maker and structure breaker salts effect the dynamic surface properties in different way."

Jan 1, 2014

By J. G. Tilton

While most of the Pittsburgh coal horizon is dependably regular, there are areas where it is dis-turbed by sandstone cutouts which can seriously hamper mining operations. Because these channel sandstones often cut out the coal abruptly, they are difficult to detect by core drilling; and mine operators, for want of a better way to discover them, have largely trusted to luck to avoid them. This paper, based on a study the author is presently conducting, is an attempt to point out some sources of information and signposts which might aid the operator in determining the presence of a cutout before he begins to mine. The presence of sandstone cutouts in the Pittsburgh coal has been known for many years. Some of these irregularities were observed at outcrops and others were discovered by drilling, but the majority were and are found during mining operations. These sandstone cutouts are commonly called "faults" and have been a bane to mining companies wherever they have been encountered. Profiles of some typical deposits appear in Fig. 1. The cutouts disrupt the normal system of mining, replace valuable coal reserves, create ventilation problems by emitting large quantities of gas and sometimes oil, limit the number of entries that can be economically driven, affect the quality of the coal, disrupt the normal structure of the coal, and create roof control problems. It might be expected that such severe disturbances in the structural regularity of the coal would instigate determined and extensive searches for possible cutouts prior to mining operations, but this apparently has not been so except in isolated cases. Two reasons may be cited to explain this lack of exploratory work. The first and probably the strongest reason is the over-all regularity of the Pittsburgh coal. No coal seam in the country exhibits the horizontal continuity and relative regularity of the Pittsburgh coal. It lies in an almost unbroken sheet across southwestern Pennsylvania, eastern Ohio and northern West Virginia, and has been recognized as far east as the Potomac Basin of western Maryland. Over 5729 square miles are underlain by this coal, of which 2077 square miles are in Pennsylvania, 2214 square miles in West Virginia, 1410 square miles in Ohio, and 28 square miles in Maryland. The area covered by this study is outlined by the map in Fig. 2. Over most of this territory the coal has the following characteristic structure as illustrated in Fig. 3: roof coal, draw slate, breast coal, parting, bearing in coal, parting, brick coal, parting, and bottom coal. With such regularity of thickness and structure, mines were opened and laid out with confidence that the coal would be present. Extensive drill testing was considered unwarranted and it was also quite expensive because the coal dipped to the west away from the Monongahela River. Consequently, drill holes were widely spaced and rarely encountered ad-

Jan 1, 1968

By L. B. Ticknor, M. B. Bever

An isothermal calorimeter suitable for measurements of heats of solution in liquid tin as solvent is described. Measurements of the heats of solution of gold, silver, copper, and a gold-silver alloy are reported. The heat of formation of this gold-silver alloy is also reported. HEATS of solution in liquids can be determined directly, but few such data have been published for metals as solvents. Knowledge of heats of solution is desirable because it contributes to the general understanding of energy relations in metallic solutions. Thermochemical measurements of this type also furnish answers to specific problems: For example, from the heats of solution of an alloy and of a mixture of its constituent elements in a given solvent, the heat of formation of the alloy may be found. Similarly, differences in the energy content of samples of the same metal in two different states, such as the annealed and cold worked states, may be determined. In the work reported here, gold, silver, and an alloy of gold and silver were dissolved in liquid tin at 240°C and gold, silver, and copper were dissolved in tin at 300 °C. The experiments yielded the heats of solution of these metals in tin. The heat of formation of the gold-silver alloy was also determined. The same calorimetric method is being used to measure the energy stored in metals during cold working and preliminary results have been published.' Equipment and Experimental Procedure The isothermal calorimeter used in this work, Fig. 1, consisted of a Dewar flask completely immersed in a constant-temperature salt bath. A long neck provided space for thermocouple leads and a stirrer shaft and permitted the injection of solute samples. The metal bath in the calorimeter flask was stirred at about 100 rpm by a small glass impeller driven by a constant-speed motor. The shaft of the stirrer passed through a Wilson vacuum seal.2 All measurements were made under vacuum in order to eliminate temperature disturbances resulting from gas convection and to prevent the oxidation of tin. The calorimeter flask was joined by an all-glass connecting line to a gas-control system which made possible the use of a protective atmosphere of deoxidized and dried hydrogen. At the operating temperature of the calorimeter tin oxide was not reduced by hydrogen, presumably because the reaction rate was too slow. Part of the closed system was a removable side tube through which the solute sample could be introduced and in which it was held at a temperature of 0°C prior to injection into the metal bath. The salt bath containing a mixture of sodium, lithium, and potassium nitrates was similar to that described by Beattie3 and was equipped with a stir-

Jan 1, 1953

By Thomas A. Boyce

Introduction Although innovative coal extraction technology can be approached from many angles, this paper focuses on three: innovation in response to rising costs, to changing mining conditions, and to regulatory issues. Before exploring these three subjects, however, a basic question needs to be raised. Why Innovation? Coal is widely heralded, and quite correctly so, as the United States' "ace in the hole." It has been said that the U.S. is to coal what the Arabs are to oil. The implication is that we have nearly inexhaustible reserves - that coal is cheap, plentiful, and easy to extract. Indeed, because our current productive capacity is estimated to be 15-20% greater than demand, we have been given a false sense of security about the ease of future coal extraction. Therefore, innovative measures are being concentrated on developing technologies for the demand side of coal, including power generation, synthetic fuels, and industrial applications. What is often forgotten is that the unit cost of producing energy from these new technologies depends critically on the cost of the coal feedstock -in some cases the coal consumed accounts for more than one-third the total cost. Thus, while the developers of the end-use technologies struggle to improve the overall thermal efficiency of their process by one or two per¬centage points to make the energy produced competitive in the marketplace, they often are unaware of the risk of a 3 to 6% increase in coal costs wiping out the expensive, hard-earned results of their research. Energy planners are just beginning to realize that coal is not a uniform commodity available at low cost in infinite quantities. Coal is a heterogeneous material whose cost and quality vary widely with local conditions. To produce the massive amounts of projected coal-based energy at reasonable costs, we urgently need devel¬opments in extraction technology, as well as in end-use technology. Thus, coal extraction, coal conversion and utilization, and end -use energy consumption must be viewed as highly interdependent parts of an energy supply network (Fig. 1). And current emphasis on conversion and utilization must be balanced by more emphasis on upstream technologies, including coal extraction. Even more important, the impacts of innovation (or the lack thereof) in any one technology area in the energy supply network need to be discussed and understood by those working in each of the other areas. Why innovation in coal ex¬traction technology? Figuratively, we are all in the "coal boat" together - geologists, miners, transporters, processors, power producers, distributors, and consumers. Innovation is required from each of these sectors to overcome the obstacles that prevent greater use of our most abundant national energy resource. All other links in the coal energy supply network depend on large volumes of coal produced at reasonable costs. Declines in productivity, therefore, must be reversed; the more difficult mining conditions that will be encountered call for new methods and equipment, and regulatory issues must be resolved if the coal ex¬traction link is to be a strength rather than a weakness in the planned U.S. transition to an economy based more on coal and less on imported petroleum. Innovation Tailored to Regional Conditions Once the importance and urgency of innovative coal extraction technology has been grasped, the next step - implementing a research program - becomes quite

Jan 1, 1980

By D. B. Robinson, J. Lukacs

A knowledge of the equilibrium water content of hydrocarbon systems under pressure is important to the natural gas industry. The information available on the solubility of water in hydrocarbon, hydrogen sulfide, and carbon dioxide systems is reviewed in this paper and the influence of the more important variables such as temperature, pressure and molecular structure on solubility in liquids and gases is discussed. A suitable cbromatographic technique has been developed for determining low concentrations of water. Tailing of the water peaks has been elim inated by adding water to the carrier gas stream The method is applicable for both gas or liquid samples and is effective in the presence of hydrogen sulfide. The experimental study of water solubility in methane-hydrogen sulfide systems at a temperature of 16oF has shown that the presence of hydrogen sulfide causes only a modest increase in water content at pressures up to 1,400 psia. Theoretical considerations and data on pure hydrogen sulfide and carbon dioxide suggest that the effect of both these compounds will be greater at higher pressures and in the liquid phase. INTRODUCTION Before transporting or processing natural gases and gas condensates, it is usually necessary to dry them using suitable dehydration equipment. The design and operation of this equipment requires a knowledge of the amount of water present in the fluid at the reservoir and operating conditions. This is influenced by temperature, pressure and composition, particular1y when certain non-hydrocarbon components are present. Field experience indicates that hydrogen sulfide and carbon dioxide, for example, alter the usual water solubility relationships appreciably. However, an extensive search of the literature does not reveal any quantitative data on such systems. For sweet natural gases, generalized empirical correlations such as the one proposed by Katz, et al,6 can be used to predict water solubility with confidence at most temperatures and pressures of interest. However, existing theoretical relationships do not permit a calculation of the deviation from these curves when polar substances like hydrogen sulfide are present in the system. Thus one must resort to an experimental approach to obtain the necessary information. The fact that laboratory experimental methods frequently involve the use of mercury which reacts with hydrogen sulfide in the presence of water, and that hydrogen sulfide interferes with many chemical reactions specific for water has contributed to the difficulty of studying water solubility in systems containing hydrogen sulfide. In this investigation the water content of a limited member of methane-hydrogen sulfide mixtures was determined using a special technique with gas chromatography. REVIEW OF PUBLISHED DATA Experimentally determined water solubility data have been reported for methane, 14 ethane, 15 propane, 9 n-butane, 16 1-butene, 11 hydrogen sulfide 18 and carbon dioxide. 19 These studies report the effect of pressure, temperature and molecular structure on water solubility in single component gases and liquids. Fig. 1 compares experimentally determined water solubilities in several hydrocarbons, carbon dioxide and hydrogen sulfide at l00F as taken from this

By R. A. Perry

A speiss is an artificial arsenide, sometimes an antimonide, formed in lead smelting, smelting of oxide copper ores, and in some lead-refining operations. The production of speiss is closely allied with the amount of arsenic and metallic iron in the blast-furnace charge, while dross is produced mostly from the copper and sulphur, with varying amounts of antimony, arsenic and nickel. Most speiss is essentially an iron arsenide containing some sulphur, copper and nickel, if these elements are present in the furnace. The recent introduction of the soda treatment of lead drosses has produced a speiss high in copper. Speiss is not miscible to any extent with molten copper, lead, matte or slag. Miscibility increases with temperature. This property of the speiss is clarified in the latter part of this paper. Most speisses are produced in conjunction with matte and their sulphur content points to the solubility of matte in speiss. . Some plants have insufficient speiss to warrant separate treatment. When arsenic is high in the blast-furllace charge, there may be sufficient speiss to tap separately from the first settler. Arsenic From the foregoing, it is obvious that a study of the treatment of speiss would not ,be complete without consideration of arsenic. Inasmuch as perhaps go per cent of the blast-furnace feed may be sinter, a definite knowledge of the properties of arsenical ores and compounds that go in to the roaster and sinter feeds is of value. Lcad smelters obtain their arsenic from ores and concentrates, as well as from flue dusts shipped from other plants, particularly copper smelters. The percentage of arsenic in ores is usually low, although occasional lots of high arsenical products are smelted. These crude ores may be sulphides, as arsenopyrite; or oxides like scoiodite, which carry gold or lead minerals. The small amount of arsenic in the original ores received is greatly increased by a circulating load of arsenic in secondary products at are resmelted for their lead or precious metals. More important than the arsenic present directly in the concentrates treated is that in fumes and dusts that may originate in the blast furnace or sinter plant of the lead smelter, or may come from a copper smelter as lead-bearing converter fume or roaster dust. Thus the lead smelter not only must treat its own arsenic but is compelled to handie that from some copper and perhaps other lead plants. Where copper and lead plants exchange products, each plant may be forced to re-treat part of the arsenic it has shipped ,outside its own confines. Speiss from the lead blast furnace contains chiefly iron and arsenic with some lead, copper and sulphur and often appreciable amounts of gold and silver. If its copper content is sufficient this speiss may be sent to the copper smelter where usually it is treated in the converter and the copper is separated as blister. Much of the arsenic and most of the lead are recovered as converter fumes

Jan 1, 1944

By R. J. Allio, C. H. Randall

An automatic system for the quantitative analysis of microstrulcture has been developed. The method is based upon a statistical model of microstructure and employs phase intercept fractions as fundamental random variables. Structure-sensitive properties can be related explicitly to parameters derived from the distribution of phase intercept fractions in a matevial. THE properties of mechanical dispersions and of multiphase alloys art: intimately related to the amount, distribution, and intrinsic properties of the dispersed material. In many instances, the amount and distribution of the dispersed substances have greater influence on the over-all system properties than do the properties of the dispersed substance-Such properties as average particle size, particle size distribution, homogeneity of dispersion, volume per cent of dispersed phase, and mean free path between dispersed particles thus become critical in any evaluation of the properties of a dispersion. Unfortunately, techniques for evaluating quantitatively the microstructural characteristics of dis~ersions rapidly and accurately have not been available. If necessary, qualitative or semiquantitative devices can be utilized. Some such devices are based merely upon comparison of the specimens in question with arbitrary standards. Other techniques involve superposition of grids and tabulation of particles observed in different portions of the grid. Still other methods based upon lineal analysis entail counting lines or points at random upon the specimen to be examined; the number of intersections of the line with a given phase, the proportion of line or number of points which are covered by given phase are variously recorded. The mathematical basis for most of the techniques of quantitative metallography have been amply reviewed in the literature.'l2 without exctption, however, the standard techniques for quantitative metallography are either imprecise or are exceedingly tedious to apply. For example, tranverse integrating stage for rapid manual areal fraction measurement has been designed by Smith.3 Howerer, as in the case of any device based upon visual eslimation, operator bias may cause appreciable error. Various flying spot devices, on the other hand register particle size distributions in 2-dimensions, from which it is difficult to derive other properties of the dispersion. Thus, e.g., the 3-dimensional distribution cannot be inferred unless certain rather broad assumptions are made concerning the randomness of distribution and geometrical configuration of dispersed phase. Many limitations to the application of quantitative structural analysis can be overcome by the use of the microdensitometer, which is essentially an automated areal analysis device. Data obtained in the form of a distribution of phase intercept values are

Jan 1, 1962

By H. Q. Golder

With the development of open-pit mines of ever increasing depth, the stability of the pit slopes in soil and rock is of growing economic importance. How is it, considering the newness of the problem that we know anything at all about the stability of man-made slopes? How much do we know and how did it all begin? We can make a reasonable estimate of the stability of a slope in soil, but we know as yet woefully little about slopes in rock because the problem is much more complex. It is only with the development of the capacity of the computer to handle wearisome calculations that any but the simplest of stability problems in rock have become possible of solution. But what we do know is a guide of immense value in the design of slopes in rock. But remember that the computer is a great elevator; it takes everyone's feet off the ground! So our study began with soils and what is now known as "Soil Mechanics", which is a translation of the German term "Bodenmechanik". It is a pity that the title of Terzaghi's book "Erdbaumechanik" was not used instead. But here the task of the translator is difficult because English lacks the facility of German to string together several words and make a new one whose meaning is unequivocal. Thus, we have the three German words 'Erde' 'Bau' and 'Mechanik'. 'Erde' means "earth" in almost all the English senses including "soil". 'Bau' and 'bauen' convey the meaning of building and construction, and 'Mechanik' means "mechanics" which includes statics and dynamics and the 'mechanics of materials', etc. So that a correct translation of the German is a phrase like "the mechanics of construction with, in or on, earth or soil." However we are stuck with 'Soil Mechanics' and that is where it all began. Now this study or subject did not begin with 'Terzaghi' although his contribution to the subject is unquestionably greater than that of any other single person. Every scientific discipline has its 'classical problem' and that of soil mechanics is 'the earth pressure problem' and it began in the 17th century. In fact, it probably began before this with the introduction of gunpowder to Western Europe in about the 15th century, but the first known reference to the problem was by Vauban, a distinguished French military engineer who lived from 1633 to 1707 and who gave rules for the dimensions of retaining walls from 6 to 80 ft. in height. The soil properties were not mentioned by Vauban probably because the rules were intended to be applied to fortifications only, but Poncelet (1840) claimed that Vauban's rules were based on a theory, and not simply on military and practical

Jan 1, 1972

By R. C. Emmett

Gravity sedimentation is one of the most widely used unit operations in mineral processing and hydrometallurgy. Properly selected and operated sedimentation equipment can provide probably the most economical means of concentrating solids or clarifying solutions. Because of the variety of different approaches possible, including the use of modern flocculants, it is easy to overlook the optimum approach in selecting equipment. The different types of sedimentation systems that can be used in the minerals field and the sizing methods that are currently employed will be discussed here. Sedimentation applications usually fall into two areas, clarification or thickening. While the two operations are basically similar, the difference in emphasis (a well-clarified overflow as opposed to a highly concentrated underflow) results in significant differences in testing, equipment design, and operation. Clarifiers may be merely simple settling vessels with no special features, other than ample volume to provide the detention time needed for suspended solids to settle out of the feed slurry. Or, they can be designed to employ elaborate solids-contact techniques utilizing coagulants or flocculants to achieve more rapid clarification through the growth of particle agglomerates. Thickeners also are available in a wide variety of designs, with the main differences concentrated in the design of the raking mechanism. Thickeners operating in series (continuous countercurrent decantation or CCD) are used to recover valuable solution or purify the insoluble solids. Tray thickeners are used for recovering fine particulate solids such as alumina seed, but in other applications have been supplanted largely by unit thickeners or inclined plate units. Thickeners and clarifiers sometimes are used for storage of either solids or overflow liquor, or employed as precipitating reactors, such as in desilication applications. The use of flocculants and coagulants is much more common in modern processing plants, primarily due to the reduction in capital costs rendered possible through the use of these reagents. The terms flocculant and coagulant are often used interchangeably; generally, it is understood that flocculants refer to organic, high molecular weight synthetic or natural polymers which are useful in flocculating most suspended solids, but generally are ineffective on colloidal suspensions. Coagulants refer to chemicals such as those commonly used in water treatment, alum, ferric salts, lime, etc., which are usually far more effective on colloidal solids but cannot achieve the degree of agglomeration that is possible with the polymers. In some cases, both coagulants and flocculants are used in order to achieve optimum results.

Jan 1, 1986

record with the Royal Flying Corps was considered a remarkable one, for he was at the front within two months of the date on which he was granted a commission, during which interval he took the prescribed technical course at Oxford, and aviation training at Netheravon and Bristol. On Sept. 14, 1916, he took his first flight over the German lines, when his engine stalled and he had to volplane down, fortunately landing on the French side of the lines. On Sept. 16, he went over the lines with six others, and not returning immediately with the others, was lost. He tried to make for the sea and come back following the course of a river, but when he did descend he found that he was 60 miles west of Paris and 100 miles south of his lines. He flew over to Paris and stayed there for the night, going back to his squadron the next morning. Then on Oct. 4, he was sent up at night for the first time, and in making a landing he passed the flares just as he struck the ground, which put him in total darkness. He struck something and his machine turned a complete somersault, which accident put him in the hospital for ten days. In December, 1916, he left the 21st Squadron and was transferred to the 24th, as the 21st was made an Artillery Squadron and he preferred to remain a fighting scout. In the same month, he was made Acting Flight Commander for about 6 weeks, and about April 3, 1917, his rank of Flight Commander was confirmed. The beginning of May he started to introduce a number of new machines for his squadron, these being of an entirely new type. On May 19, he was up with one of the machines in the evening, practising sharp turns and dives, when the wings suddenly crumpled up and he fell 700 ft., being killed instantly. He was buried in a French Cemetry at Monchy Lagache about 8 miles southeast of Perronne, and about 25 miles east of Amiens. Sergeant Herbert Moore Harbach Herbert Moore Harbach was born in Lebanon, Pa., Apr. 4, 1891, graduated from the Lebanon High School in 1911, and entered State College from which he received his degree of Bachelor of Science in Metallurgical Engineering in 1915. He was employed by the Lackawanna Iron Co., at Buffalo, W. Y., and was later transferred to their Lebanon plant to start up the newly erected benzol plant. He was later made foreman of the coke ovens, which position he held after it was bought by the Bethlehem Steel Co., and until he enlisted in the service of his country in September, 1917. He was stationed at Camp Meade, Md., until the spring of 1918, when he was transferred to the C. W.

Jan 1, 1920

By Daniel H. Knepper

Estimating the lithologic composition of gravel deposits for aggregate quality using standard field and laboratory techniques is costly and time-consuming. As an alternative, digital geologic maps and elevation models may provide a means for predicting the lithologic composition of channel and terrace deposits. Digital geologic maps can be used to evaluate the distribution of map units: their geomorphic setting, and the physical properties of the gravel source. To test this concept, the lithologies and topography of the upper drainage basin of the Big Thompson River along the Colorado Front Range were used to examine various factors that may control the final lithologic composition of channel and terrace gravels downstream. The simplest factor is the area of each of the map units in the upper drainage basin area, which can be easily measured from the digital geologic map. The percentage of each map unit within the total area provides a estimate of the pro- portions of each map unit that might be expected to occur in the downstream gravels. Published estimates of the hardness and durability of each map unit were used to calculate physical property-weighted areas; these areas are an estimate of the potential of each unit to be eroded and transported as gravel-sized particles. The areas of each map unit at 1-kilometer intervals from the drainage basin exit point were used to calculate a distance-weighted area for each map unit. For this study, a simple inverse relationship (area/distance) was used for distance weighting, but a more complicated distance function may ultimately be required. The topographic setting of exposed rock units should exert a significant influence on whether material will move slowly or rapidly through the drainage system. Two topographic factors were examined: gradient and slope. A simple gradient between map unit occurrences and the exit point of the drainage basin was used to calculate a gradient-weighted area estimate for each map unit. The slope-weighted area estimate uses the slope steepness (in degrees) in the immediate vicinity of each map unit occurrence as a measure of the tendency of material to begin moving into the sediment transport system. The primary intent of this study was to test the concept of using digital geologic map and elevation images to estimate gravel composition, rather than actually producing a useful analysis of a drainage basin. Each of the controlling factors was examined independently to gain an understanding of the magnitude of the effect of each factor. Ultimately, a comprehensive predictive model will be constructed using a combination of the various controlling factors.

Jan 1, 2001

The authors have succeeded in providing additional rigour and clarity to the formulation and execution of the dynamic programming algorithm for optimum open pit limit determination. The inclusion of the blocks on the J + 1 column in the search for Pmax, and constraining this search with blocks assigned a value of negative infinity, ensures an optimal solution within the defmed blocks. The effect of the negative infmity blocks is to preclude mining along the diagonal blocks from the first row that they occur in. Figure 1 graphically illustrates the effects of this on the calculation of P. A practical application for constraining mining with negative infmity blocks is the case where the pit outline is defined by lease boundaries and not by the value of blocks to be removed. Any legal, social or physical constraint could be accounted for in the same way.The danger in applying this technique is that the negative infinity blocks will override any other more profitable solutions that may exist. This is in fact what has happened in the example that the authors use. If a further column is added to the left hand side (column -1) and the calculation is carried out again, a more optimal x-section can be found. (If the negative infinity values are removed the same result is obtained.) This gives a pit value of 112 as against the 108 of the authors' optimal pit. This calculation is shown in Figure 2. Lerchs-Grossman optimization is reliable only if there are sufficient columns available to allow "mining" to optimum depth of the ore body and still allow the pit to break out at the surface within the confines of the columns.This author's approach is to create enough columns each side of the lateral limits of the ore to allow the pit to intersect the surface while still within the confines of the block model. Implementing the methods discussed by the authors helps to reduce the number of columns required to achieve this.

Jan 1, 1987

By G W. Wilson

Rehabilitation of tailings impoundments is one of the most challenging aspects in mine closure, as not only does the potential for producing leachate pose a challenge to the rehabilitation designer, but also other aspects such as stability and settlement must be considered. The water balance of a tailings impoundment is unique in the sense that it usually hosts a pond that in turn causes a phreatic surface in the impoundment. The position of the phreatic surface defines the saturated and unsaturated zones in the impoundment, which of course varies spatially and temporally. Predictive modelling for this hydrologic system becomes difficult, as numerical models capable of analysing the combined saturated/unsaturated zones are not adequately refined to accurately solve the flux boundary problem for infiltration at the surface of the tailings. This paper describes the development of a flux boundary model that enabled accurate modelling of the unsaturated zone in the tailings impoundment at Kidston Gold Mine, Queensland, Australia. The technique made it possible to accurately predict the spatial variation of infiltration to the tailings as a result of the presence of the phreatic table. The conceptual model defines the boundaries for the Kidston tailings dam, based on a generalised cross-section through the dam. Firstly the shape of the top boundary is described as a function of the particle size of the tailings associated with particle segregation that occurs due to the hydraulic placement of tailings. This function was rigorously tested using in situ infiltration tests and laboratory materials testing. Defining the bottom boundary of the section, ie the phreatic level was done by physically monitoring the phreatic level with 42 piezometers strategically located on the tailings dam. Analysis of this data led to the fixing of this bottom boundary through the introduction of a function that mimicked the shape of the phreatic level. The material properties of the surface layer, specifically the saturated permeability that would govern the infiltration/exfiltration rates of moisture through the top boundary layer were defined on the basis of extensive field and laboratory material testing. A function for the saturated permeability was developed on the principles of particle segregation. Finally a procedure is described for the application of the new conceptual model for the evaluation of the spatial infiltration to a tailings surface using the rigorous one dimensional surface flux boundary code SoilCover. The solution of the calculation described above was then used as the top boundary condition in conventional three dimensional saturated/ unsaturated flow codes, and verified against measured seepage rates from the tailings impoundment under drains. It was concluded that the developed spatial flux function was in deed a most rigorous representation of reality. Although the methodology presented here was applied to the Kidston tailings impoundment only, the authors believe that the principles are directly transferable to any tailings impoundment that has a varying phreatic zone thickness due to the presence of a pond. The mathematical equations describing the typical cross-section would be site specific, but the approach and ultimate solution methodology would be directly transferable.

Jan 1, 2003

By Cecil Desch

THIS annual lecture, under the auspices of the Institute of Metals Division, and which was illus- trated by lantern slides, has been printed in full and a limited number are available for distribution on request. Some excerpts from the lecture are given below: Ever since the simple geometrical relations of crystals were discovered, it has been recognized that their proper-ties are best explained by assuming that their ultimate particles are arranged on a space lattice, and that the char-acteristics of that lattice determine the shape of the crystal and its physical and mechanical properties. Modern ex-amination by means of X-rays has widened that concep-tion and given it greater; definiteness, and the atoms are now regarded as the particles forming the space lattice. The splendid achievements of investigators in this field have made it possible to state, for a large number of sub-stances, the form and dimensions of the lattice. The char-acteristic of a lattice is that a unit of simple geometrical form is repeated at regular intervals in three dimensions so as to fill the entire crystal. It follows that there must be certain planes in which the atoms are more closely packed than in planes drawn at any angle to them, and it is these planes of closest packing which play the greatest part in determining the growth and other properties of the crystal. There are actually two stages in crystallization, what-ever be the medium in which it occurs. The first is the ap-pearance of crystal nuclei; the second the growth of those nuclei to form crystals of appreciable .size. The first is clearly a kinetic phenomenon. In the molten mass, solu-tion, or vapor, the molecules are in a state of rapid motion and frequent collision. When the temperature has fallen so far. that it is possible for a crystal to exist, a few col-liding molecules may fail to rebound, and so become at-tached to one another, the balance between the attracting and repelling forces-between them causing them to arrange themselves on a space lattice, to which other molecules sub-sequently attach themselves. It was once maintained that the X-ray evidence demanded that the molecule should dis-appear in the solid crystal, but this was a wrong inference, and in many crystals, but not in all, the chemical molecule retains its identity in the solid state. In pure metals the atom and the molecule are identical, so that the conditions are unusually simple. How many. nuclei will be formed in a given mass is evi-dently a problem in probability. Experiments to deter-mine the relation between the temperature and the number of nuclei formed in a given time have been made with some success by using viscous organic substances, but metals offer much greater difficulties, and the few determinations which have been published are vitiated by serious errors. However, the examination of sections of ingots of the same composition and cast at 'the same temperature in similar molds will show, that the number of crystals does not vary widely.

Jan 3, 1927

Gentlemen.-The Institute was founded 54 years ago "with the object of promoting the arts and sciences connected with the economic production of the useful minerals and metals and the welfare of those employed in these industries by means of meetings for social intercourse and the reading and discussion of professional papers, and to circulate by means of publications among its members and associates the information thus obtained," At least once a year it is well to take stock of our assets, review our performance and determine how well we are now carrying out the purposes of our Founders. There can be no question as to the work the Institute has done and is doing in promoting the arts and sciences in the fields of mining and metallurgy. One needs only to contrast the methods, the labor and the costs of a half century ago with those now to visualize how far we have gone in the development of accurate technology and sound economics in mineral and metal production. The great mines, mills and smelters of the present, handling individually thousands of tons per day, would' have been impossible except for the accumulation of knowledge, the development of theory, and the improvement in practice that has characterized the period since the foundation of the Institute. The United States has prospered in the last half century greatly, and this has been due not merely to the possession of great natural resources, but to these resources being reduced to possession and put to work. The absence of customs barriers and the freedom of trade across the whole width of this great continent has been an important factor in the growth of our wealth. Unrestricted interchange of goods has permitted each citizen to draw on the resources of the whole country. However, these are but subsidiary causes of prosperity. The free interchange of scientific and technical data, by making the whole body of facts and theory available to each worker, has made this quick and unrivaled development possible. In promoting this free trade in knowledge the Institute may claim a large place without fear of denial. The .72 volumes of TRANSACTIONS, the special volumes, the bulletins and the other publications that have been issued, include a store of knowledge of the arts and sciences related to the production and use of metals and minerals not duplicated elsewhere. The large list of foreign members-1746 in number-few of whom ever have opportunity to attend meetings and all of whom derive their main benefits from membership through the pub-

Jan 1, 1928