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By I. Iwasaki, K. A. Nataratjan

In a previous paper, ozone was shown to remove residual xanthates in flotation pulp solutions as well as to destroy the xanthate coating on bulk copper-nickel sulfide concentrates before differential flotation (Iwasaki and Malicsi, 1985). The oxidation and decom- position mechanisms of xanthate solutions in the presence of commonly used oxidants such as oxygen, chlorine, hypochlorite, bromine, iodine, and hydrogen peroxide at different pH levels have been reported in the past (Rao, 1971). Most of these studies have been restricted to xanthate solutions of pH less than 10. Very few references are available on xanthate decomposition in highly alkaline (pH > 12) solutions (Jones and Woodcock, 1983; Philipp and Fichte, 1960; Tipman and Leja, 1975). No systematic study of xanthate oxidation by ozone has been reported, although its use in flotation has been recognized of late (Allegrini et al., IWO; Ishii et al., 1970; Matsubara et al., 1978). To improve the efficiency of ozone use in flotation, it is essential to understand the mechanisms involved in the decomposition of xanthates with ozone, more specifically, to establish the stoichiometry and decomposition rate. In the present work, a preliminary attempt was made to investigate the effect of pH on xanthate decomposition, and probable mechanisms of xanthate oxidation with ozone.

Jan 1, 1986

Although the bromo-cyanide or Diehl process for the extraction of gold from its ores is used on several of the Kalgoorlie mines, very little information has been published on the original process, and no details are available from the various mines now using it. The following description of the process as carried on at the Hannan's Star plant, where several modifications were introduced by the author, will therefore be of interest to mining men, and it is hoped that some discussion on this paper will provide further useful information to the mining community.The process was first installed on the Hannan's Star mine, where a full working plant was erected by the London-Hamburg Co. In their contract they guaranteed a 91 per cent. extraction on a sulphide ore of 15 dwt value. This was considered a very high extraction at the time, and the plant successfully carried out its work.The new features in the process were the finer grinding of the ore, for which purpose the tube mill was introduced, and the addition of a solution of bromo-cyanide to the vats under ordinary cyanide treatment, whereby a higher extraction was obtained in a shorter time. The main difficulty in the process was the easy manufacture of the bromo-cyanide solution, but this was eventually overcome. The mixed salts now supplied by the LondonHamburg Co. are in every way satisfactory, and are supplied at such a price that the process compares favourably with any other from a cost point of view.

Jan 1, 1907

By Jacques B. Wertz

Among the parameters to be considered in the continuous search for new base-metal deposits, there often is a stratigraphic controlling factor that seems instrumental in the localization of ore. In British Columbia, for instance, the Upper Triassic as well as Lower Jurassic volcanics mixed with sediments are a useful indication in the search for copper while, in some parts of Australia, rhyolite bodies seem to be the favorable indicator, and this always within the geosynclinal environment. In Arizona, this stratigraphic factor becomes highly significant and it will be shown here that a large number of ore deposits are to be located around the flanks of ancient calcareous basins or depressions, preferentially corresponding to a certain optimum thickness as revealed by isopachs. The Martin limestone, of Devonian age, is already known for its basal O'Carroll bed which coincides with mineralization at places, and this is a relatively minor control. However, several limestone basins outlined by isopachs are in reality of greater importance as they localize mining districts. Indeed, most mines are found to coincide with a specific thickness of limestone while occurring simultaneously close to major, regional fracture intersections. The regional fractures in question were interpolated and extrapolated from known, important fault expressions, integrating quite well with the existing geology and further confirmed by minor criteria such as contacts, igneous plugs, axes of elongation of batholiths, dikes, etc. Although elements of subjectivity remain, this grid of fractures can be used quite successfully as a working hypothesis in the search for ore. Results of the present study which superposes major structural

Jan 1, 1971

By Y. L. Su, R. Stefanko, Y. J. Wang

This chapter describes a new approach to the solution of stress distribution around underground openings utilizing the finite element method and employing stochastically simulated rock properties. It is well-known from extensive laboratory tests that the properties of rocks, e.g., Young's modulus and Poisson's ratio, are not single-valued but form some distribution. If the scatter of test data is attributed to the variability of the rock itself rather than due to an inadequacy in test procedure, then stress solutions have to consider these variations. Utilizing this basic philosophy, the present study was initiated. A long circular opening subjected to plane strain in a hydrostatic stress field was chosen as a specific example to illustrate this approach. The technique adopted in solving stress distributions was based on the finite element method. This method is essentially a generalization of standard structural analysis procedures in which the continuum is idealized as an assemblage of "elements," interconnected at a finite number of nodal points. It is capable therefore of handling different material properties for individual elements in the model, if desired. In this study, each individual element was assumed to be isotropic, homogeneous, and elastic. However, values for Young's modulus and Poisson's ratio were randomly varied from element to element according to an assumed frequency distribution.

Jan 1, 1970

By Earl Greiner

THE constitution of the iron-silicon alloys containing from 14 to 33.4 weight per cent silicon has been studied by a number of investigators, whose results have been reviewed in a monograph published by the Engineering Foundation1. In these previous researches, the solubility of silicon in iron was determined by thermal, microscopic or magnetic methods and the compound Fe3Si2 was reported to be stable at tempera-tures from 0 to approximately 1030° C. This paper describes the results of an X-ray investigation of the solubility of silicon in iron and gives data which prove that the Fe3Si2 phase is unstable below 825° C. In order to obtain the present results on the solubility of silicon in iron, the authors have utilized the lattice constants of the alpha-phase iron-silicon alloys given in a previous publication2, and also some addi-tional data which will subsequently be described.

Jan 1, 1936

By H. R. Weischedel

The art of wire rope inspection has advanced rapidly over the past decade. Present electromagnetic (EM) wire rope inspection instruments provide an important and often vital element of wire rope inspection. Some instruments are easy to operate and offer simple and clear data interpretation. Simultaneously, wire rope inspection and retirement standards are becoming simpler and more lucid. Future guidelines will he easy for inspectors to apply and for rope operators to fulfill. The thrust of evolving regulations is clearly toward periodic EM inspections supported by visual inspections. These development sallow even moderately skilled personnel to perform EM inspections of wire ropes. Therefore, it is now possible and cost effective for wire rope users to have EM and visual inspections performed by in-house personnel. In-house EM inspections have many advantages and offer an excellent return on the initial investment. Since EM inspections can detect rope deterioration in its beginning stage, wire rope users recognize that they are an effective preventive maintenance tool. For instance, the early detection of wear or corrosion allows immediate corrective action. This can easily double, or even triple or quadruple, the service life of a rope.

Jan 1, 1991

By S. K. Kawatra, R. A. Seitz

Various mathematical models and expressions to describe the behavior of a hydrocyclone have been presented in the literature (Lynch and Rao, 1977; Plitt, 1976; Plitt and Kawatra, 1977). Two of these models, by Lynch (1977) and by Plitt (1976), have been extensively used for process control studies (Kawatra and Thayer, 1879; Seitz and Kawatra, 1984). However, neither of these models relates the fineness of grind in a hydrocyclone overflow to the corrected efficiency curve of a hydrocyclone. If such a relationship were available, then one could relate fineness of grind to the operating variables using equation (1) or (2). A plant metallurgist is interested in knowing the fineness of grind rather than the dso(c) of a hydro- cyclone. As a consequence, several empirical relation- ships between fineness of grind and hydrocyclone operating variables are available. These relationships (Fewings, Wickham, and Wiseman, 1979; Manning, 1978; Watson, Cropton, and Brookes, 1970; Watts, Thompson, and White, 1978; Wiegal, 1973) have only a limited relationship with each other and have met with varying degrees of success. The object of this paper is to develop a fundamental relationship between fineness of grind and the efficiency curve of a hydro- cyclone

Jan 1, 1986

By R. H. King

The Automatic Extraction System (AES) was designed and built under a US Department of Energy Contract by the National Mine Service Co. in cooperation with the Lee Engineering Division of Consolidation Coal Co. The Pennsylvania State University, Mining Engineering Section, was contracted as an independent auditor of the AES performance. The AES had a rotating cutter drum like a continuous mining machine. But two hydraulically powered roof supports, four roof-bolting drills, a dust scrubber, a ventilation fan and ducting in the roof supports, semi-automatic control, an extensible chain conveyor, and other innovations led to the distinction "extraction system" as opposed to "miner-bolter" or continuous mining" machine. After design and assembly, the AES was field tested experimentally in an underground coal mine. The in-mine performance audit was preceded by a computer simulation of the potential production for a later comparison with the actual tonnage mined by the AES. This paper describes the results of an in-mine trial and assesses the production potential of the AES.

Jan 1, 1983

Heavy medium separation is widely used because of the precision of separation achievable and the flexibility of control. Good design is manifest in the eventual achievement of the operational objectives. These objectives which take account of the assessed quality of raw feed, market requirements and production cost levels need to be carefully prepared and realistic.

Jan 1, 1987

Cleaner Production stands for a proactive and preventive approach to industrial environmental management and aims for process- and/or product-integrated solutions that are both ecologically and economically efficient (æeco-efficiencyÆ). Pioneers in the field were large manufacturing and processing industries in the USA (since the late-1970s), but it took until the early-1990s before Cleaner Production was generally recognised as a valuable approach for large and medium sized enterprises. The application of Cleaner Production in mining and minerals, metals and energy production appears to lag behind other sectors, such as manufacturing and processing. This paper starts with a discussion of the Cleaner Production concept and provides examples of its application from a few selected Australian mining and minerals processing industries. This evidences that Cleaner Production can achieve significant reductions in environmental impact, in terms of reduced waste and emission generation and in terms of conservation of materials, energy and water, while simultaneously reducing operating costs. The paper then investigates a number of key issues pertaining to the implementation of Cleaner Production; ie organisation and management of Cleaner Production activities, effective tools for mastering the Cleaner Production concept as a way of life, and performance measurement.

Jan 1, 2002

WHOEVER has occasion to judge tin in its whiteness from the testimony of his eyes alone would surely believe it to be purest silver, or something that comes very near to it in nature. This is even more so when, on handling, it is found to be harder than lead, to which it can be said to have a greater and closer resemblance. But whoever has actual experience with tin knows that none of the other metals is less similar to it than silver. For silver mixes with every metal, as does gold; and they unite together, and the others do likewise; and except for their color they change their natures but little. But this metal tin, wherever it is found, acts like a powerful poison which envenoms and corrupts the others; and it does this not only with large quantities but also with every small amount; indeed just the trace remaining where it has been melted is enough to embrittle silver and gold as well as iron and copper. The greater the quantity of it in these, the greater are its effects. Speculators of natural causes say that this fact arises from its great wateriness, which is very subtle and poorly decocted and almost like that of quicksilver. This wateriness, then, by means of its subtlety which joins itself with metals, imposes itself into that unctuous and viscous material which renders them flexible, and thus deprives them of their toughness

Jan 1, 1942

By J. A. Rodgers, K. C. Whitaker

The time domain during which an explosive detonates and causes rock to fragment and displace is on the order of tens of milliseconds. Because of this, the dynamic processes that occur during this time frame often become a source of confusion when trying to analyze the performance of explosive products in decked blast designs. As an illustration, the authors have experimentally examined explosives malfunction in decked blasts through state-of-the-art measurement techniques. The interaction of explosive products and blast geometry was examined in detail using the analysis of a series of decked blastholes. Explosive and initiator malfunction in decked blasts is often considered to be entirely the result of insufficient inert decking material, however, it is shown that rock properties and dynamic burden conditions may have a significant impact on decking performance. The successful application of deck-blasting technique for control of ground vibration amplitude relies on an understanding of the true dynamic performance of the blasthole.

Jan 1, 2000

By Thomas R. Kuesel

In traditional construction contracting practice, the owner allocated almost all risks to the contractor, saying in effect, "you deal with all construction problems and all third parties, and don't bother me." In this same tradition, the architect or engineer designed a structure in its finished condition, and if he thought about the construction problems that might be involved in building it, he was careful not to express any opinions on these matters in the contract documents. This feudal attitude fostered two results: 1. Contractors added high contingencies to their bids to cover the costs of risks. 2. Litigation of construction contract claims blossomed. Broadly, the owners lost--the courts reallocated many risks the owners thought they had laid on the contractor. Thoughtful owners and engineers recognized that owners were paying for risks twice --once in bid contingencies and a second time in court. Meanwhile, contractors were not getting rich; they were losing money on delays and disputes, and just about getting even (if they were lucky) in court. And construction law was becoming an increasingly lucrative field--for lawyers. Furthermore, with the growing influx of lawyers onto the construction scene, the owner-contractor-engineer relationship became increasingly an adversary one. The emphasis came to be on culpability rather than capability--who could be held responsible for breaching some contract clause, not who might find a solution to some common problem. This game was played with equal vigor by owners and contractors.

Jan 1, 1979

By Chappell BW

A zone of northwest trending dykes extends for over 600 km in the hinterland from Cairns to Mackay. In sate regions the zone is up to 120 km wide. Figure 1 shows their approximate extent, compiled from published regional maps and from specific studies in more limited areas : Palm Islands, Cardwell Ranges, Jourama Falls, Townsville area and Burdekin Delta. The context of the dyke swarm is the Tasman Orogenic Zone, the region of Eastern Australia conprised of Palaeozoic metamorphic, sedimentary, volcanic and plutonic rocks which has experienced a complex history and evolution. In the Whitsunday region, the Tam-an Zone also involves Cretaceous volcanism and plutonism. Geological relationships indicated a wide span of ages for the intrusions in the dyke, swarm zone. They intrude a range of volcanic and sedimentary rocks, and in some areas plutonic rocks. Older dykes, apparently part of the same regional swarm are intruded by sate of the granites.

Jan 1, 1987

By John W. Bader

Probing a mineralized area with a core drill to find out what's there is fundamentally a simple task, but a costly one. Quite commonly it costs $10, and sometimes more, to extract and assay each foot of drill core obtained. Yet, it is not unusual today to drill hundreds of holes on one mineral property. The initial objective of such probing is almost always simply to determine the potential worth of the ore- body, if any exists, and the question naturally arises: How little sampling is enough for this determination? The mathematics of statistics infer accuracy of estimates largely from the sheer number of samples taken. Mineral exploration usually involves accumulation of large numbers of samples, and thus it is usually not difficult to place narrow confidence limits on either side of the estimated average grade of a sampled orebody. The determination may, or may not, be as accurate as the derivations imply. If it is not, the fault is probably one of misapplication and not with the statistical processes themselves. Un- fortunately, indications are strong that the ordinary statistics of sampling usually cannot be applied to orebody exploration samples with actual attainment of the accuracy of estimate that they express mathematically. For this reason, a more deductive, less mathematical analysis of the sampling may well be worthwhile.

Jan 1, 1970

By J. K. Jeyapalan, A. P. S. Selvadurai

Plate loading tests which use surficial loading of a rock mass are employed quite extensively for the determination of in situ deformability characteristics of rock masses. The cable jacking method is essentially a surficial plate load test in which the test load is provided by reaction against a cable anchored at some depth below the rock surface. The results of the test are usually evaluated within the framework of the classical theory of elasticity to generate estimates for the bulk deformability properties of the rock mass. In the conventional evaluation of this test it is assumed that the test plate is rigid and that the embedded anchor load has no influence on the test plate settlement. The purpose of this paper is to examine the possible influences of the plate flexibility and the anchor load location on the effective settlement of the test plate. The variational estimates presented in the paper are valid for moderately flexible test plates which are characterized by a relative rigidity parameter Numerical results are developed in the form of correction factors that should be applied to the cable jacking results to arrive at the deformability characteristics of the tested rock mass.

Jan 1, 1982

By J. Pang, S. Chander

The mechanisms of chalcopyrite oxidation in alkaline solutions have been studied using cyclic voltammetry and impedance spectroscopy techniques. The cyclic voltammetry was used to elucidate oxidation/reduction reactions, whereas impedance spectroscopy was used for in-situ characterization of the interface. To analyze the impedance spectra, equivalent circuit models were constructed based on a layer- wise growth of reaction products. Parameters of the equivalent circuit were calculated by comparing the experimental spectrum with that expected on the basis of equivalent circuit. From the value of equivalent circuit parameters, properties of the surface layers were inferred. These properties change substantially with the change in oxygen and/or collector concentration in solution. From such changes the effect of oxygen and collector concentration on the contact angle and flotation behavior of chalcopyrite were interpreted.

Jan 1, 1991

By V. J. Kecojevic, W. A. Wilkinson

Mining companies are increasingly looking at Global Positioning System (GPS) technology coupled with 3D mine planning and visualization systems to deliver increased productivity and reduction in operating costs in drilling and blasting operations. Leveraging GPS into drill and blast operations requires that a drilling plan be developed and imported into the GPS to guide the operation to a planned and desirable outcome. State-of-the-art mine planning software systems provide the engineer with a 3D environment in which to design and visualize drill and blast plans. This paper discusses producing and exporting 3D drill and blast plans to GPS and how some coal companies are utilizing GPS and mine planning software technology in the drill and blast process.

Jan 1, 2004

Pennsylvania has been a leader in the pageant of industrial America because of her natural mineral re- sources, geographical location, and the ingenuity and industry of her citizens. Brick and other clay products were manufactured in Philadelphia in William Penn's time. Ores of iron, zinc, lead, and copper were mined and smelted in eastern Pennsylvania long before the Revolution. Coal was mined on a commercial basis in the anthracite region as early as 1820 and in the bituminous fields in 1830. The first canals and railroads were constructed to transport minerals and mineral products. Oil was struck at Titusville in 1859. A significant event occurred in 1855-the establishment of the Farmers' High School-Pennsylvania's first attempt to provide higher education for its youth. The Farmers' High School included instruction in geology, mineralogy, and assaying. In 1859 the laws of Pennsylvania transferred to the School the state geological and mineralogical collections formerly located in Harrisburg. Well-informed people are familiar with the effects of the Land-Grant Act of 1862. With inspiring words it established state institutions of higher learning where "the leading object shall be, without excluding other scientific and classical studies . . . to teach such branches of learning as are related to agriculture and the mechanic arts . . . in order to promote the liberal and practical education of the industrial classes in the sev-

Jan 1, 1950

By G. Achurra

The products of the smelting of copper concentrates in an El Teniente Converter (CT) are a high grade matte, analyzing 74-76% Cu; and a highly oxidized slag, typically containing 15-20% Fe3O4 and 4-10% Cu. The El Teniente Division of CODELCO¬CHILE has developed a slag reduction-cleaning process, that is practised in a tilting, horizontal furnace, to recover copper from these slags. The El Teniente slag cleaning process has been successfully implemented at the El Teniente Caletones smelter and various other smelters in Chile: Today, eight such slag cleaning furnaces, each with a capacity of 800-1000 tonnes/day, are in operation in Chile. This paper discusses basic laboratory research and industrial tests that led to substantial reductions in the slag cleaning cycle time and the specific consumption of fuel and reductants. Simultaneously, the slag cleaning off-gas quality was improved. Based on the experimental results, recommendations were made to improve the practice of the El Teniente slag cleaning process. The recommended modifications have been fully implemented at the Caletones smelter.

Jan 1, 1999