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By Igor Teixeira da Costa

Os pós fluxantes são formados por escórias sintéticas que em contato com o aço líquido deve fundir e gerar uma escória líquida. Suas principais funções são: lubrificar e controlar a transferência de calor entre a casca sólida do metal e o molde. Eles possuem composições diferentes para diferentes condições de lingotamento, sendo formados, basicamente, por CaO, SiO2, Al2O3, Na2O, CaF2 e podem conter MgO, Li2O, K2O e B2O3. Como alguns componentes influenciam diretamente na cristalinidade dos fluxantes, como o CaO, o MgO, o CaF2, neste trabalho serão analisadas quatro misturas de pós fluxantes com leves variações na composição de modo que possa gerar cristalinidades diferentes. Para esta análise será utilizada o método de lâminas delgadas, com auxílio de um microscópio óptico de luz transmitida, que tem apresentado resultados bem satisfatório sobre o detalhamento da cristalinidade dos materiais.

Oct 30, 2017

By K. C. Corin, M. S. Manono

The drive to reduce water usage globally has led to the mining industry reassessing its water usage - owing to past environmental degradation due to effluent discharge, tailings disposal and process water seepage into the water-table (Haggard et al., 2015). Factors such as water scarcity and environmental restrictions have created the necessity for recycling of process water in mining and other industries. Water recycling, however, causes an accumulation of ions in the process water, which may affect the strength of reagent action on the target mineral and in turn critical aspects of flotation may be impacted. Prior studies have shown that certain ions have specific effects on flotation: for example, calcium and copper have been found to enhance the adsorption of depressant onto gangue (Feng et al., 2013, Wang et al., 2016). Calcium and sulfate ions have been seen to give a higher concentrate grade than other ions present in process water (Manono et al., 2012). An increase in ion concentration will increase the mineral grade due to a decrease in entrainment (Corin et al., 2011). This study considers the impact of ion accumulation on reagent action and flotation response. Keywords: Flotation chemistry, water quality, ionic strength

Jan 1, 2020

By C. Tokoro, T. Kato

The objective of this study is to improve the shrinking core model for particles with a particle size distribution and clarify the activation mechanism of rare earth elements dissolution by mechanochemical activation. To achieve this objective, the method, called the doubly integrated micromodel, was applied for a shrinking core model in this study. This method consists of integrating the batch leaching rate of a single particle over the distribution of both feed particle size and reactor residence time to arrive at the fraction unleached. The usefulness of the shrinking core model improved by doubly integrated micromodel was confirmed by comparing it with a shrinking core model. To apply the shrinking core model improved by doubly integrated micromodel to rare earth elements dissolution from weathered residual rare earth ores by mechanochemical activation, leaching experiments were performed for grinding samples by planetary ball milling. The reaction equation of mechanochemical reaction by planetary ball milling for weathered residual rare earth ores was investigated by x-ray absorption fine structure analysis. As a result of a kinetics study, the rate-determining process of leaching changed from reaction to diffusion reaction control by planetary ball milling. Based on these results, it was revealed that the main mechanism of activated rare earth elements dissolution from weathered residual rare earth ores was a mechanochemical reaction by planetary ball milling. Keywords: Mechanochemical reaction, particle size distribution, shrinking core model

Jan 1, 2020

By P. Gautier

Current feedstock in the aluminum hot forging processes can be used in the cast or extruded forms. The microstructural variation between as-cast and extruded materials could result in different mechanical properties and corrosion resistance for hot-forged products. Corrosion performances were examined for forged parts produced by two AA6082 feedstocks at different conditions using the following corrosion tests: open circuit potential, anodic polarization, salt spray exposure and corrosion fatigue. With the help of optical and scanning electron microscopes, metallographical investigations were carried out on cast-forged and extruded-forged materials before and after corrosion. The corrosion behavior of both materials was compared in both as-forged and aged tempers. Results show that there is no significant difference in the corrosion performance for final cast-forged and extruded-forged products.

Jan 1, 2011

By F. Calizaya

A booster fan is an underground ventilation device installed in the main airstream to handle the total quantity of air circulated to one or more working districts. It is installed in a permanent stopping and equipped with airlock doors, a monitoring system and interlocking devices between the main fan and the booster fan. When adequately installed, a booster fan can be used to reduce the main fan pressure, reduce leakage and decrease the power consumption. However, an inadequate installation can increase the likelihood of mine fies and recirculation of air contaminants. This study identifies hazards associated with the operation and maintenance of booster fans. It analyzes the accompanying risks and recommends control measures to reduce those risks to acceptable levels. The ventilation network of an existing coal mine was updated to include a booster fan. The hazards associated with the operation of this fan were identified, the risks analyzed and the esponse to each failure mode established.

Mar 1, 2014

By Timothy Batchler

"Standing roof supports help to provide a stable working environment in coal mine gateroads. NIOSH participates in the development of these support systems by conducting full-scale tests in their Mine Roof Simulator. These tests have established the performance characteristics of every coal mine support system currently in use in the United States. Through these tests, mine operators and regulatory officials have acquired a fundamental understanding of the various types of support performance that guides the assessment and use of these support systems. However, some little known factors that influence support behavior can lead to misconceptions and, perhaps, a poor assessment of support behavior at times. This paper highlights several of these factors and discusses their significance. The paper also examines a current longwall tailgate support and discusses the inefficiency with this approach. Finally, the NIOSH Mine Roof Simulator (MRS) is the world’s most powerful load frame built specifically to test full-scale roof supports, including longwall shields. are addressed in this paper to provide a more in-depth assessment of the limitations of the MRS and what the MRS testing protocol is designed to do. INTRODUCTION Over the years, considerable research has been conducted to develop standing support technologies and to evaluate their performance characteristics. The load and displacement characteristics of the standing supports have been determined from full-scale testing conducted using the National Institute for Occupational Safety and Health (NIOSH) Mine Roof Simulator (MRS) (Barczak and Tadolini, 2008) located in Bruceton, PA. Performance traits, installation patterns, and ground responses are observed in various geological and mining conditions and are evaluated to determine the support performance in the field (Dolinar, 2010; Campoli, 2015; Zhang et al., 2012). Despite widespread use of standing supports, not every aspect of their performance and resulting ground support capability are always well understood. This paper discusses 10 factors, several of which are surprising, that impact standing support performance."

Jan 1, 2017

By A Coulson, J Hussey

Noranda Inc is a Canadian mining and metallurgical company with its activities managed through businesses in copper and recycling, zinc, aluminum, magnesium and various metals through its interest in Falconbridge Ltd. Noranda operates three base metal mines, three copper smelters, one copper refinery, one zinc refinery, one lead smelter and refinery, three copper recycling and sampling facilities seven aluminum producing facilities and one magnesium production facility in the construction stage. The mining side of Noranda has a strong history of open stope, cut and fill and shrinkage mining. The 1999 Noranda Annual Report lists a 206 million tonne resource located at Porphyry Mountain in GaspT, QuTbec. Mont Porphyre is a large tonnage, low-grade porphyry style Cu-Mo deposit that was discovered in 1994. It is located at a depth between 1.0 and 1.7 km below surface and characterised by a very competent rock mass. The Mont Porphyre resource is located adjacent to the town of Murdochville, close to NorandaÆs Mines GaspT operations. Mines GaspT closed its open pit and underground operations in 1999 after approximately 45 years of mining, but still operates a copper smelter near Murdochville. The low-grade and great depth of the Mont Porphyre resource suggested that mine design could not be based on the conventional Noranda open stoping mining practice. This paper will review NorandaÆs approach to evaluating the Mont Porphyre deposit. The approach included two definition diamond drilling campaigns, a review of current caving practice, an in-house scope study, a geotechnical logging program for diamond drill core and participation in an international study on cave mining. One interesting component of NorandaÆs approach was the scope study that involved a team of multi-disciplinary personnel drawn together for a short period of time. The objective of the scope study was to determine what conditions would be necessary to mine the deposit and to assess the merits of continuing with further exploration work. A review of current worldwide underground bulk mining practices, and in particular an evaluation of the applicability of caving mining methods, were key components of the scope study. The scope study team concluded that derivatives of caving could be applied to the mining of Mont Porphyre, but additional diamond drilling was recommended to further define the deposit and improve the level of geotechnical information. Following the recommendations of the scope study team, a diamond drilling campaign was completed during the summer and fall of 1997. The 1997 drilling campaign had two secondary objectives, in addition to the primary objective of defining the limits of the orebody. The first objective was to improve the level of geotechnical information available for the characterisation of primary block cave fragmentation. The second objective was to improve the delineation of a lower grade intrusive core. A geomechanical investigation was conducted and included particular emphasis on geotechnical data collection and analysis. A review of the actual data collection process, including several trials of different core orientation techniques, will be included in the discussion.

Jan 1, 2000

By Phillips RN

Semi-confined, trachy-andesite sills which overlie the German Creek Seam, within the critical tensile strain zone, form major groundwater hazards to longwall mining at the German Creek underground mines. The water contained in these aquifers is normally neutral, but highly saline. Techniques used to detect aquifers include routine air-lift pumping in exploratory drill holes, downhole geophysical and geological logging and upstage packer testing. Hydraulic constants are calculated from pump-out and pump-in test results. Hydraulic parameters for the calculation of mine inflow rates are determined from pump-out test results because these tests appear to be more representative of aquifer drainage during goat dewatering than pump- in testing. During mining of the first longwall block at Central Colliery, caving fractures intersected overlying aquifers after the longwall had retreated 40m, and mine water inflow rate rapidly increased from less than one litre/sec to 25 litres/sec. The amount of water pumped out of the mine during first panel extraction was 140 megalitres with drawdown occurring over an area of 168 hectares. In the Southern Colliery area approximately 324 megalitres of highly saline water which is actively stored in the Aquila Sill area will be pre-drained from six well points prior to longwall mining. With effective pre-drainage from surface drill holes, maximum inflow rate into the mine during initial goafing can be reduced from 165 litres/sec to about 45 litres/sec.

Jan 1, 1988

In process industries, time-dependent random fluctuations of raw material characteristics and mass flow rates in bulk material or pulp flows cannot be always prevented for different reasons, eg because of the geological situation (no uniform formation of the deposit) or/and because of technological reasons (segregation in bunkers or on stockpiles). Since a long time, there has been practical experiences that such fluctuations can have negative consequences, eg: ò fluctuations of the final products characteristics, ò higher expenditure for process control, and ò worsening of technological characteristics (recovery, sharpness of separation etc). In the literature, there can be found a lot of details as to, eg the improvement of the sharpness of separation in a jig in dependence on the raw material blending (Kubitza, 1981; Gathen, 1983) or the decreasing flotation recovery with increasing raw material characteristics fluctuations in iron and potash ore processing plants (Bubnova, 1978). Up to now, however, these consequences of random fluctuations, eg on the separation efficiency were not predictable theoretically. It could be shown by means of the general model for mechanical macroprocesses (Graichen, 1989), that the reduction of input fluctuations passing a blending facility can be calculated in this way. In this example, the steady state of the process is the wanted one, but, in general, the model is able to describe also non-steady states of the process regarded. On the other hand, the general model of mechanical macroprocesses has been used successfully for modelling separation processes, eg cross-flow and air classification (Molerus, 1969; Neesse, 1991; Senden, 1979; Tichonov, 1973). That is why it was tried to model the influence of input fluctuations on the separation efficiency, that means, the impact of non-steady states - as a consequence of random fluctuations - on a separation process. The models discussed in the literature are related nearly exclusive to the steady state of the process. The reasons for that lie in the (relative) simplicity of the models and the fact that the steady state is aimed at by means of blending processes under practical conditions - because of the advantages mentioned above. These models cited have proved to be superior to other models, since the basic general model for mechanical macropocesses makes possible the consideration of turbulence acting in the process unit and influencing the separation process essentially. This is valid also for modelling the turbulent cross flow classification, applied to mechanical classifiers and hydrocyclones, where the correspondence between the separation characteristics (cut size, separation sharpness) calculated and determined experimentally is much better than for other models.

Jan 1, 1993

By John C. Calhoun, Frank T. Bethel

Glass beads have been surface treated with Dri-film to render them oil wet by n-octane to varying degrees, and capillary desaturation curves have been determined by the restored state method. The desaturation curves show a regularity of increasing displacement pressures as the oil wetness increases. This has been used to compute apparent contact angles between n-octane and water on glass. The family of desaturation curves also shows a regular crossover, such that the residual wetting liquid saturation values are in reverse order to the displacement pressures. A semi-logarithmic variation is shown between the apparent contact angle and the residual saturation. The desaturation data are interpreted to mean that the wetting liquid ceases to be a continuous phase within individual pores before the capillary pressure can be raised sufficiently to force out the wetting phase completely. The saturation of wetting liquid at which this break in liquid continuity occurs is higher as the oil wetness decreases. INTRODUCTION The petroleum industry has for some time been using measurements of capillary pressures on porous media for research correlations and engineering calculations. It has been generally recognized that the capillary desaturation curve reflects the character and arrangement of the pores within the media and the distribution of fluids within the pores. Methods have been proposed for computing pore size distributions, tortuosity factors. and relative permeabilities from capillary desaturation data.' There is little doubt that the interactions between porous rocks and their contained fluids resulting from surface forces play a dominant role in determining the magnitude and direction of capillary pressure measurements. There have been attempts to introduce as variables two quantities — inter-facial tension and contact angle — generally used to char- acterize surface forces, but in spile of the wide interest in these quantities as important variables, few definite conclusions have been drawn concerning their qualitative or quantitative significance. INTERFACIAL TENSION The interfacial tension appears in a capillary pressure function given by Leverett for correlating capillary desaturation type curves. Use of the interfacial tension in this function seems to be justified by other experiments reported. Apparently, interfacial tensions have little bearing on wetting phase residual by desaturation. CONTACT ANGLE The contact angle was utilized as a variable by Bartell and co-workers"." in tests on displacement pressures, later recognized as the initial point of capillary desaturation. Although Leverett did not include contact angle in his original formulation of the capillary pressure function, later workers suggested its addition. Few reports are available to show variation of residual liquid with contact angle as a result of capillary desaturation.' The problems attendant to measuring contact angle within a porous medium are great. As a consequence of the lack of a concrete approach to a measurement. the workers in this area of research have adopted the general expression of "wettability" to indicate the relative position of two liquids saturating a porous body. It has been shown that gross measurements on porous systems, including capillary desatura-tions, are sensitive to wettability. Attempts at giving a scale to wettability in terms of contact angle through capillary desaturation curves have been made and these apparently are steps in the right direction. In these attempts presence of many other variables precludes attainment of exactness. Also, as a result of other variables, it has been impossible to correlate changes in apparent contact angle with changes in other physical measurements of the systems in question. The present work is an attempt to eliminate as many variables as possible in measuring capillary desaturations resulting from changes in contact angle within a porous medium.

Jan 1, 1953

By Joseph Seibold, Kavin Khatri, Siobhan O'Reilly-Shah, Neel Neelakantan

San Francisco’s New Headworks Facility Project consists of the design and construction of a state-of-the-art Headworks Facility designed to treat up to 250 million gallons of wastewater a day. The site is located in the Bayview District of San Francisco, California and is subject to various geohazards, including liquefiable artificial fill, compressible Bay Mud, multiple aquifers (including a pressurized aquifer), and high seismicity. To mitigate these hazards, and to accommodate the anticipated structural load demands, the New Headworks Facility structures were designed to be supported on large diameter drilled shafts. Bi-directional load tests (BDLTs) were designed and carried out to calibrate the analysis and confirm the design. During pre-production construction, two 36-inch-diameter drilled shafts approximately 125 feet long were installed at the project site. Each drilled shaft was instrumented with a bi-directional load cell, Linear Vibrating Wire Displacement Transducers, and eight strain gauges at select locations. The BDLTs were carried out after shaft installation. With careful consideration of the geotechnical conditions, the upward and downward displacement of the shaft segments above and below the bi-directional load cell mobilized at about the same time, allowing for significant data acquisition that resulted optimization for the foundation design. Through the successful implementation of a BDLT program, the drilled shaft lengths were able to be reduced significantly, resulting in substantial cost savings to the San Francisco Public Utilities Commission (SFPUC). This paper presents a discussion of the BLDT program performed for the New Headworks Facility Project, and how BDLT can be implemented as an effective method for estimating capacities on large-scale public infrastructure projects. Keywords: Bi-directional load testing, load cell, drilled shafts

Oct 7, 2024

By P. Seethalakshmi, Yatakuri Yaswanth Naidu

The use of a single pile, group of piles with pile cap, piled raft foundation system, etc., are prevalent in transferring the superstructure load from the soft soil layers to the firm underground layers to reduce the settlement and improve the bearing capacity. The recent development of disconnected piled raft foundation has gained greater importance in improving the load transfer mechanism among the pile, raft, and subsoil by reducing the vulnerability of the greatest axial force on the pile head which leads to pile failure. The present study aims at analyzing the performance of unreinforced and Geogrid reinforced disconnected piled raft foundations under vertical loading using the commercially available finite element software PLAXIS-3D. A parametric study was conducted on unreinforced and reinforced disconnected piled raft foundations to explore the effect of varying pile stiffness as well as the inclusion of Geogrid layer on the load vs settlement, the load sharing ratio of piles and raft, and the distribution of axial load and bending moment along the length of the pile. The Mohr-Coulomb model was used for the granular cushion layer while the Modified Cam Clay model was used for soft clay underlain the sand layer. Raft and piles were assumed to be rigid and linear elastic. The results showed that axial force taken by piles with higher stiffness was maximum while settlement at the bottom tip of the pile with higher stiffness was maximum in both reinforced as well as unreinforced disconnected piled raft systems.

Sep 1, 2022

It is widely accepted that the type of grinding media has an impact on the grinding chemistry and subsequent flotation behaviour of the sulphide minerals being separated. There are countless laboratory investigations demonstrating that inert grinding media produces more oxidizing pulp potentials, reduced levels of grinding media corrosion products, and superior concentrate grades and valuable metal recoveries. However, taking these results to industrial scale has proved difficult. This paper provides details of the protocol developed and used during a high-chrome grinding media plant trial. It describes the test regime employed to measure changes in pulp chemistry as well as concentrate grades and recoveries to produce a statistically meaningful result. The work also highlighted the need for close cooperation between the metallurgists on site and the researchers conducting the trial. To demonstrate the protocol, data gathered during a plant trail in a PGM concentrate will be presented describing the changes in pulp chemistry and metallurgical response observed.

Jan 1, 2012

By Nils Eivind Kamfjord, Mari K. Næss, Gabriella M. Tranell

"In oxidative ladle refining (OLR) of silicon, the metal surface is oxidized resulting in the formation of a condensed silica fume (SiO2). In the current work, industrial measurement campaigns were performed aiming to measure the fume generation during OLR. A thorough discussion of the possible mechanisms has been included in order to improve our understanding of the Si(1)-O2(g) system.The measurement campaigns were performed at the Elkem Salten plant in Norway. In addition to fume generation from OLR, the metal temperatures and ladle purge gas amount were recorded. The results of this work suggest that fume generation during OLR results from splashing of the metal and/or oxidation of the metal surface, with oxygen transport to the metal surface being the limiting factor. Other mechanisms of SiO2 formation were investigated, however insignificant.IntroductionOne of the main environmental and economical challenges facing the metallurgical industry is fugitive emissions of both materials and energy. In the production of metallurgical grade silicon (MG-Si), refining of the silicon generally takes place through an oxidative ladle treatment (purging with an air-O2 mixture). In the refining process, exposure of silicon to air results in the formation of condensed silica fumes (SiO2) – one of the main sources of fugitive emissions in silicon production plants. The oxidation of liquid silicon, as opposed to solid silicon, has not been widely studied and described in the literature [1], thus a thorough investigation of the oxidation mechanisms, and factors affecting the oxidation reaction rate are essential in order to deal with the problem. In the current work, the rate of liquid silicon oxidation has been studied through industrial measurements of fume generation from refining adles, where the purge gas rate and composition have been varied. The results from these measurements were discussed in light of existing models describing the liquid silicon oxidation kinetics."

Jan 1, 2011

By C. Breeds, K. Jeremiah, E. Jennings

Washington State has a well developed set of blasting regulations which have been promulgated by the Department of Labor using extensive stakeholder input, not only from citizens but also from manufacturers and representatives of IME, blasters in charge, blasting engineers, blasting companies, local and federal law enforcement agencies, fire officials, and local and state government representatives. WAC 296-52 therefore provides a foundation or platform for developing city ordinances for Washington State cities should a City wish to do so. On the other hand, Oregon’s code is based on OSHA 1926, Subdivision U, Blasting and the Use of Explosives which provides scant direction regarding the modern use of explosives. Reference is also made to ODOT Section 00335 - Blasting Methods and Protection of Excavation Backslopes. This paper examines two separate programs that have been developed by two Cities, one in Washington State and one in Oregon to further regulate blasting inside City limits and discusses why the lack of a regulatory foundation made one approach more difficult than the other. One of the authors was retained by the City of Kennewick, WA to develop their ordinance and has more recently followed and reacted to a pending ordinance for the City of Redmond, Oregon. The paper will compare and contrast the different approaches and comment on the reaction from both Blasters and the public. We also present a case study that involved blasting in an urban area of Oregon to prepare a foundation for a water tank. Controlled Blasting was carried out within 70-ft of residencies and within a community that had expressed reservations regarding blasting even though the work would make a significant contribution to the betterment of the community. Pre-construction surveys of residencies located in a large area surrounding the site were performed and a well-planned blasting program was carried out. Residencies were subject to vibration levels that were monitored using six seismographs that surrounded the site and these units measured vibration levels that were significantly lower than allowed by statute. There were complaints triggered by individuals reactions to blast vibrations which validated commonly held models of human perception but no damage was caused by the Blasting.

Jan 1, 2024

By Nestor Ferreira Carvalho

Com o intuito de garantir a segurança das pessoas, meio ambiente e o patrimônio das empresas, os vasos de pressão e caldeiras instalados no Brasil devem ser protegidos por válvulas de segurança, cuja função é evitar que o equipamento seja pressurizado acima da pressão de projeto. A escolha do melhor local para instalação dessas válvulas deve levar em consideração, além dos itens usuais de projeto, os esforços gerados quando da abertura dessas válvulas. Esse artigo, faz uma análise da fratura, com o propósito de determinar as causas básicas da falha e evitar sua repetição. A análise foi realizada com o apoio de literaturas sobre fractografia e fadiga.

Aug 16, 2017

By Adriane Lopes Mougo

O efeito de escala é um fenômeno que ocorre durante o microfresamento e trata da relação entre o raio da aresta de corte, a espessura de corte e a microestrutura da peça. O aço superduplex UNS S32750 é um importante material usado na indústria petrolífera que pode ser destinado futuramente para a fabricação de microsensores e microatuadores. No entanto, ainda não existem publicações voltadas para a microusinagem deste aço, seja na análise das forças de corte, na vida útil da ferramenta ou na integridade da superfície usinada. O presente artigo trata do estudo da rugosidade de superfície e da formação de rebarbas após o microfresamento do aço superduplex, considerando diferentes níveis de velocidade de corte e de avanço da ferramenta. A análise dos resultados é realizada considerando que este aço possui microestrutura composta por grãos das fases ferrita e austenita com diferentes taxas de recuperação elástica.

Oct 30, 2017

By L Keeney

Cu-Au porphyry deposits are large tonnage low-grade resources dependent on processing large volumes of material. The ability to understand and predict comminution performance is critical, as it is frequently the rate-limiting step during processing. Parameters required from geometallurgical mapping and modelling of comminution performance are: A×b processing domains based on impact breakage variability, and BMWi processing domains showing grind response variability which lead to Mine throughput domains for a specific comminution circuit configuration. Due to the cost and/or large sample requirements of traditional comminution tests, insufficient data density and distribution of comminution indices commonly exist, making it difficult to model and map deposit scale variability. One method routinely applied to three dimensional domaining is to have an a priori zoning based on geological features (lithology, alteration, mineralogy, textures), and then apply to all material within a given domain the metallurgical values measured on a single sample or average of samples from that domain. The problem with this approach is that commonly the geological domains do not reflect comminution response, therefore compromising the quality of the average domain estimate. To resolve this problem an alternate integrated geometallurgical mapping and modelling method is applied to model and map comminution performance at Cadia East. This paper uses a data set of ~32 000 assay measurements and geological logging information, integrated with ~150 comminution measurements to analyse and develop proxy support models for comminution indices (ie A×b, BMWi, and throughput) based on inherent geological variability. Discrete downhole comminution processing domains are created, mapping orebody response while maintaining inherent variability.

Sep 5, 2011

By Alvaro Diaz

Introduction, who is Teck Red Dog and Quebrada Blanca Mines Uniqueness of environment Arctic versus High Altitude Conditions Logistical challenges People and Stakeholders Conclusions

May 1, 2013

By O. Lopez

"Stringent regulations and increased arsenic presence in ore bodies being exploited have created the need for cost effective and environmentally compliant technologies to remove selenium and arsenic from mine waters and metallurgical waste streams. Existing treatment methods have high life cycle costs and/or produce residues that, due to their unknown stability over the long-term, may represent future liabilities. This results in high compliance costs and uncertainties which negatively impact existing operations and projects in permitting. Selen-IX™ is a new ion exchange based process that selectively removes selenium from mine impacted waters down to 1 ppb while producing a stable inorganic iron-selenium product. Results of piloting completed on streams generated from coal and copper-gold deposits are presented along with preliminary equipment sizing and life cycle costs of full scale treatment. An example of a commercially available system for arsenic removal using sulphide precipitation is presented. The benefit of this treatment method is discussed based on recently completed technical feasibility assessment including laboratory testing and preliminary engineering design. INTRODUCTION Selenium Due to the chemical similarity between selenium and sulfur, selenium substitutes sulfur in many minerals that can be found in a wide range of deposits including coal, base metal, precious metal, phosphate, and uranium. One of the main environmental challenges facing the industry in North America today is related to the removal of hexavalent selenium, e.g. selenate, to ultralow levels, typically between 1 to 10 ppb, from large flows of often cold water containing less than 1,000 ppb of selenium. Recent studies commissioned by the industry identified biological selenium reduction systems as the best available technology. Although the biological selenium reduction process is commercially proven in certain applications to remove selenium to ultralow discharge levels, the technology has been primarily applied to relatively low and constant flows of warm water produced by the Flue Gas Desulfurization (FGD) scrubbers in the power generation industry. The wide spread adoption of this treatment method by the mining industry is hindered by high capital and operating costs associated with treating large flows of cold water, lack of data and knowledge about the long term stability of solid residues produced by this treatment, and limited capacity of biological systems to respond to sudden changes in flow and/or mass load of contaminants. Furthermore, it has been reported that reaching discharge limits less than 3 ppb could be a challenge and that polishing treatment for the removal of BOD and phosphate maybe required to avoid the impact of the biological treatment which requires organics and nutrients, on aquatic environment downstream of treatment plants. Alternate treatment systems are being developed to overcome and/or completely avoid some of the challenges of biological systems. One such treatment system is BioteQ’s Selen-IX™ process which is purely physico-chemical treatment system."

Jan 1, 2015