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By Terry Owen

Not since 1917 has a foreign company developed a standalone, grass roots gold mine in Russia. With Russia's political changes of the late 1980s, development of mineral prospects once again beckons foreign investors. Cyprus Amax's interest in Russia began before the mid-1991 breakup of the former Soviet Union. In 1990, Cyprus Amax began searching for such an opportunity. Early this year, production will begin at the Kubaka gold project located in the Russian Far East, near the Arctic Circle. The Kubaka project is a 1.75-kt/d (1,930-stpd) open-pit operation that will produce more than 9.3 t/a (300,000 oz/year) of gold. Identifying Russian mining opportunities In late 1990, the first Cyprus Amax people travelled to Russia. The trip was to determine the potential for western firms to develop profitable mines. This encouraging visit suggested that Cyprus Amax focus on the Russian Far East with its mineral riches and its easier access to the United States. The company's initial efforts thus focused on working with the Soviet Union's Northeast Geologic Expedition, the then government agency for exploration and geology in Russia's Far East. After the breakup of the Soviet Union, Cyprus Amax continued working with the same people, but they now represented new independent, nongovernmental entities. For three years, Cyprus Amax investigated numerous deposits. This resulted in the identification of two properties of significant interest, one of which was Kubaka. Location Kubaka is located in the Northern Evensk District of the Magadan Oblast in the Russian Far East. This is an area east of Siberia. The project is situated in a mountainous area of the Kolyma Range, about 300 km (985 miles) south of the Arctic Circle. It is 285 km (180 miles) north of the fishing village of Evensk and 380 km (235 miles) northeast of the silver-mining town Omsukchan. The site is 950 km (590 miles) northeast of the regional capital city of Magadan. Magadan, the political and economic center of the Oblast, has a population of about 150,000 people. It is served by a year-round deep-water port (with icebreaker assist) and an international airport with service to Moscow and Anchorage, AK. Access to the Magadan region

Jan 1, 1997

By William Hurst

This is a presentation of the diffusivity theory for the calculation of the water drive on an oil reservoir in which the history of reservoir pressure with time are the essential parameters for the determination of the rate and cumulative water encroachment into a field. The main body of the paper is essentially the application of the principles underlined here to actual field data. It consists of the work plots of the radial-flow case, and includes a discussion of an illustrated problem for which the water-drive calculations are treated in conjunction with the volumetric-balance equation. The appendix is a mathematical treatment of the linear, radial, and spherical cases of water influx into a reservoir. Introduction The evaluation of oil reserves and the prediction of pressure behavior with different rates of production are related to the volumetric balance of the fluids entering and leaving the space occupied by the oil and gas originally present in the formation; that is to say, important information can be gleaned from a volumetric study of the oil, gas, and water produced from a formation as it affects the extent of change in volume of oil zone, the gas cap, and the amount of water influx from the adjoining water sands. It is not the purpose of this paper to enter into a discussion of the equation of volumetric balance, in which such pertinent information as subsurface sampling and the measurement of reservoir pressures play a predominant part, as this has been discussed in detail by others.1,2 However, there is an inherent difficulty that has limited the general application of this equation to a study of oil reservoirs; that is, the insufficient knowledge of the analytics for expressing the water drive on a field as a function of reservoir pressure. This to a large degree has been overcome and it is the purpose of this paper to present this theory in such form as to be applicable for reservoir calculations. Water Drive If the amount of oil originally in place and the gas space are known, it is a relatively simple matter to determine, by the volumetric equation, the cumulative water influx into a reservoir from the adjoining water sands. Often, however, the oil reserve as well as water influx must be 'determined, and in order to be able to make this calculation it is essential to assign a mathematical relationship for the varying water term that is compatible with conditions known to exist in the formation and gives an accuracy acceptable for engineering calculations. Various equations have been employed empirically by different investigators in making reservoir studies of water drive. One form used by Schilthuis2 expresses the rate of water influx into a reservoir at any time as proportional to the pressure

Jan 1, 1943

In todayÆs demanding business landscape continual change and technological advancement is a given. With these changes there is now, more than ever, a need to ensure sustainable growth in respect of value protection and value adding whilst meeting the pressures and expectations of the societies in which we operate. Traditionally the management of safety has been a very reactive activity in the business, in some cases seen as an irritation and a disruptive process that demands a focus on preventing reoccurrences. This in turn has focused the measurement of safety performance on a range of lagging indicators û æafter the effect managementÆ. Gaining and maintaining a licence to operate is crucial to a sustainable business but as a prerequisite, organisations need to have a demonstrable ability to manage the safety of their people, as well as mitigating the people risk associated with the business activity. A major focus in the last decade has been on the implementation of enterprise risk management programs, where risk becomes embedded in all business systems and processes and the organisationsÆ genetic make up is programmed to analyse and integrate risk management into all facets of the business activity. The management of safety should be no different. One school of thought argues that there are no new accidents, but rather our inability to learn from the past. Others believe that as long as we have an appetite to achieve the unachievable, we will have to continue to push the boundaries, our safety comfort zones and inevitably take risks. Single reliance on highly evolved technical systems, elaborate processes, highly skilled people, safe equipment and safe work environments have shown one thing û they are not sustainable in providing adequate coverage in the business. In analysing a range of factors associated with some of the worst catastrophes of the 20th century, it can be suggested that they were in fact predictable and inevitable and that an integrated approach underpinned by sound risk management systems could have determined a different result. The key to a sustainable approach in the management of safety requires us to look at a multitude of aspects that collectively allow the performance of an organisation to be predictable. To have certainty in the business activities it is necessary to have controls in place that will mitigate the risks normally associated with unwanted events. It is ensuring that human factors effectively contribute to monitoring the planned approach and being able to safely adjust to any variability. In essence this is having the ability to proactively plan for the longer term. The sentiments articulated by organisational leaders echo that safety management is good business. Surely then a good business is a sustainable business, and a sustainable business is one that provides lasting benefits to its stakeholders.

Jan 1, 2006

By E. Topuz, Xing Wu

INTRODUCTION The air flow in the mine ventilation network can be categorized in three ways: natural splitting, controlled splitting, and semi-controlled splitting. In natural splitting, the air flow in branches of a ventilation network apportions itself according to the aerodynamic resistance of the branches. In controlled splitting, a prescribed quantity of air is circulated through each branch. In semi-controlled splitting, flow in some branches is fixed to a desired quantity while in other branches it is split naturally. In practice, the mine ventilation networks present the latter two situations. Usually, the resistance of each branch in the network is known and the quantity of air in the working place is predetermined by safety considerations. If the number of branches whose airflow quantities are known is equal to or larger than the number of the fundamental meshes in the network, then the network becomes a controlled splitting network (Wang, 1982 a). Otherwise, it is a semi-controlled splitting network. If no booster fans are used in the network, the problem can be solved as either controlled or semi-controlled splitting networks in order to determine the main fan pressure and regulator size and location. All techniques are based on Kirchoff's flow and energy conservation laws and Atkinson's Equation. Booster fans can be used in controlled and semi-controlled splitting networks. It has been proven both theoretically and practically that using booster fans in these ventilation systems can improve flow distribution and reduce consumption of power (McPherson et al., 1985). The current techniques used in determination of booster fan location and size include simulation, linear programming, CPM and cutset operation, out-of-kilter, and critical-path crashing. These techniques can be classified into two groups. The first group, including linear programming, CPM and cutset operation, out-of-kilter, and critical-path crashing techniques, deals with controlled flow networks. The second, simulation, can be applied to the handling of semi-controlled flow networks. Mathematically, the problem of controlled splitting networks can be solved more easily than that of semi-controlled splitting networks. This is because the controlled flow network can be formulated as a linear programming problem, for the solution of which there are several sophisticated algorithms. Moreover, the semi-controlled flow network is usually modeled through nonlinear programming, for which there are no universally applicable solutions. The procedure described by Wu and Topuz, 1986, can be used to convert a semi-controlled network to a controlled flow network, and the problem can then be easily solved by the techniques used for solution of a controlled flow network problem. In practice, a mine ventilation network may change from controlled splitting to semicontrolled splitting with advancement of mining. This dynamic nature of mine ventilation makes the problem more complicated and necessitates development of new solution procedures which will consider the overall economics of the system. CONTROLLED SPLITTING NETWORK The problem in controlled splitting networks with booster fans is to determine the operational characteristic of the main fans, and the location and size of booster fans and regulators. The objective is to satisfy the air flow rate requirement for each branch while minimizing consumption of energy. The techniques used for the controlled splitting network problem include linear programming, CPM and cutset operation, out-of-kilter, and critical-path crashing. The objective function and constraints can be expressed as follows (Wang and Pana, 1971): [ ]

Jan 1, 1989

By R Brake

The Enterprise Mine Project (EMP) is being developed by Mount IsaMines Limited as the future source of copper ore at the Mt Isa miningand processing complex. Environmental engineering is one of the majortechnical challenges facing the project because of the depth of theorebodies, high virgin rock temperatures and hot ambient surfacetemperatures in summer. This paper discusses the engineering principles adopted by EMP to manage the risks associated with working in these adverse thermal conditions.

Jan 1, 1998

By Raymond Rivera Cornejo

El presente trabajo describe los aspectos metalogenéticos de los pórfidos de oro, cobre, molibdeno y sus relaciones con la exploración minera en la región Cajamarca. En ese sentido, son los estudios de geoquímica isotópica (información geocronológica, geoquímica y estructural en los pórfidos de Minas Conga -(Au-Cu), El Galeno (Cu-Mo-Au) y Michiquillay (Cu-Mo), los que señalan que estos depósitos se encuentran relacionados entre sí, tanto en el espacio como en el tiempo. Asimismo, la geoquímica isotópica de plomo y la geoquímica de rocas indican que estos depósitos tienen una fuente de mineral común y la poca contaminación cortical señala la existencia de un sistema de fallas regionales (Punre Canchis – SFPC) que puede haber sido el canal para el emplazamiento de los sistemas porfiríticos ( Minas Conga, El Galeno y Michiquillay).

Sep 14, 2009

By James Stuart

A man died when the primed charge he was holding against his chest exploded. He was doing legitimate explosive work, and he was following all the safety procedures he had been taught. He and his colleagues had done this, thousands of times previously, with no ill effects.

Jan 1, 2007

By Hood M

Rock cutting excavation technologies and particularly continuous excavation technologies, can offer benefits in the areas of reduced costs, higher revenue and increased safety in a variety of mining situations. Non-explosive rock excavation technologies for example, can deliver significant benefits in the areas of dilution and improved ground support (no overbreak). This paper is an attempt to focus on the development and future of alternative rock breaking technologies and to provide some insights as to why and how we should proceed in this direction. The market size for underground hard rock excavation technologies is examined. A short review of the evolution of various rock excavation technologies in terms of cost and production rate is given and a summary of the state-of-the-art technology is presented. Mechanical excavation technologies (TBM) have very high production rates compared to D&B and the gap is widening, however, they have not been successfully applied to mining applications. Operating costs for mechanical and D&B systems have been dropping over time, however, D&B costs are the lowest. Given the current state of knowledge it appears that with regard to hard rock underground metalliferous mining that R&D efforts should be focussed in the following areas - disc cutter tool development (materials and design; operation; presentation to the rock surface), hybrid cutting systems (consisting of water jets and disc cutters) and development of pressurised hole breakage technologies. It is also possible that two techniques known as the pulsed laser and pulsed water jets may have some potential. The generally agreed specifications for a widely applicable underground hard rock excavating machine are - disc cutter based, a minimum production rate of 100 t/h, be flexible, manoeuvrable and deployable, weight of less than 100 tonnes and be economically competitive with D&B in rocks over 150 MPa UCS. Such a machine would seriously challenge the position of conventional D&B in a wide range applications and provide some of the benefits of mechanisation and automation that the mining industry is pushing so hard for. However, technology developments in the D&B area are not static and hence the target is moving and is increasingly difficult to overtake.

Jan 1, 1995

There is a well-known saying, variously attributed to the great King Solomon and other sages of antiquity, to the effect that 'there is nothing new under the sun'. The inventive genius of man, as far as it is personified in the metallurgist, has often had the truth of this statement poignantly brought to mind when investigating the priority of ideas in its own particular branch of science. Not infrequently some operation, at first inilocently taken for a novel procedure, has later been found to have had an irrefutable precedent in the more or less remote past.When confronted by a question of this kind the metallurgist can generally much simplify his search if he at once turns his scrutinising gaze towards that ancient home of metallurgy, Germany. Vast departments of the smelting art have originated there, and even when Germany has not been in position to claim priority of invention, it has at least been characterised by a distinction equally as worthy - ie that of the faithful and authoritative exposition of the theoretical grounds on which the invention rests.In the present instance, in endeavouring to trace the history of pyritic smelting, the writer has naturally turned in the abovementioned direction, and not without some result, although the recorded data are, as might have been expected, meagre. A complete history of the art of beneflciating ores by means of fire, in all its many ramifications, still remains to be written. Possibly it may never be written, for the extent of the subject is tremendous. It is even practically impossible to clearly trace the development of one of its most modest sub-branches in satisfactory detail, or to present that branch without going to a considerable extent into related matters of a merely general character. For the purpose of dealing with the subject it will be convenient to divide it into two concurrent heads, and to distinguish, for historical reasons as well as for metallurgical ones, between that branch of the general method of matte smelting, which, until about 1891, has been called 'pyritic smelting', and the more recent offshoot of the latter, which, by distinction, may be called 'pyrite smelting'. The nature of pyritic smelting was clearly defmed by Dr John Percy in 1880, and his interpretation3 may be accepted as well known. To recall the characteristics of the method we may perhaps paraphrase Dr Percy's meaning by describing the process as a special method for the smelting of lean or dry silver or gold ores, which do not contain sufficient lead or copper for these metals to act conveniently as collectors of the precious metals. The operation is conducted in a blast furnace, with an amount of carbonaceous fuel sufficing to produce an exclusively reducing atmosphere, and with the addition of pyrites, in order to form a regulus in which the precious metals shall be concentrated, the pyrites themselves being either argentiferous, auriferous, or cupriferous, or any combination of these three, or wholly barren of metal values. In the common acceptation of the term, it is understood that the use of the reverberatory furnace is excluded.

Jan 1, 1994

By Donald Jaffe, Michael B. Bever

The solidification of Al-Zn alloys (2 to 70 pct Zn was investigated at different rates of solidification. The resulting structures were studied; the amounts of nonequilibrium eutectic were measured and compared with the amounts calculated on the assumption of no diffusion in the solid. The compositions of the cored primary constituent were investigated by quantitative autoradiography after activation of the zinc by neutron irradiation. These compositions were also determined from microhardness values. IN a recent investigation of the soltdification of aluminum-rich AI-Cu alloys,' the amounts of non-equilibrium eutectic were measured and compared with the amounts calculated on the assumption of no diffusion in the solid. The compositions of the cored primary constituent were investigated by quantitative autoradiography. The work reported here extends the investigation of nonequilibrium solidification to the Al-Zn system in the range from 2 to 70 pct Zn. In addition to autoradiography, microhard-ness values were used to determine compositions on a micro scale. Solidification Experiments The alloys contained approximately 2. 6, 12, 20, 30, 50, and 70 wt pct Zn and the balance aluminum. According to published diagrams the eutectic reaction occurs at 382°C between the eutectic liquid (95 pct Zn), a (82.8 pet Zn), and $ 498.9 pct Zn). Solid-state reactions at lower temperatures (due to the miscibility gap between 350" and 275"C, the eutectoid at 275'C, and the precipitation from supcrsaturated a) did not affect this investigation. Even if they occurred to any appreciable extent, they did not alter the evidence pertaining to the solidification structures. The alloys had to be of high purity to avoid radioact~ve contamination during activation. The aluminum analyzed 0.015 pct Si, 0.009 pct Fe, less than 0.004 pct Cu, and less than 0.006 pct Mg with traces of sodium and titanium; the zinc was reported to be at least 99.99 pct pure with traces of iron and magnesium. The alloys were prepared under argon in an induction-heated, bottom-pouring furnace, and poured into a coated steel mold, which could be preheated to temperatures up to 700°C in order to control the rate of solidification. The pouring temperatures ranged from about 40" above the liquidus for 2 pct Zn alloys to about 130°C above the liquidus for 70 pct Zn alloys. As soon as the melt entered the mold, the readings of a thermocouple placed % in. above the bottom of the mold were recorded by a recording potentiometer. Cooling at the rate induced by the initial temperature of the mold was continued to a temperature 100°C below the liquidus; the mold with its contents was then quenched in icy brine. Quenching from a fixed interval below the liquidus was used to provide a standardized procedure, since the solidus and liquidus temperatures and the interval between them vary greatly over the composition range investigated. The temperatures from which the samples were quenched were below the equilibrium solidus, but under nonequilibrium conditions some liquid was still present. This residual liquid solidified during the quench. The samples measured 314 in. diam and 11, in. height. Drillings for chemical analysis were taken

Jan 1, 1957

By A. Siegmund, Gerhard Martin

The recycling of metal containing scrap is a common practice in the industry and has a long tradition. . In rec~nt years, this philosophy has been transferred to organic materials, in particular to thermoplastic polymers. BSB . Recycling GmbH, a company with a long experience in the treatment and recovery of lead from battery scrap,· had recognized this exploitation at an early stage and challenged it by a consequent continuation of the idea to recycle materials other than metals without degradation and maintaining the quality. These efforts resulted in an economic and environmentally acceptable solution producing high quality polypropylene compounds at BSB beside lead and lead alloys from battery scrap. The raw material fair the production of polypropylene compounds is shredded plastics from the separated casings of spent lead-acid batteries. The production of polypropylene with specific physical and mechanical properties is carried out by the accurate dosing of organic as well as inorganic additives. The result of the procedure is a novel product group "Seculene PP", a registered trademark of BSB Recycling GrnbH.

Jan 1, 2000

By William M. Sheehan

TRANSPORTATION is one of the most important problems of the mine operator and the possibilities of cost reduction in this field should not be overlooked. In the railroad industry, cars and locomotives have been improved greatly, and the progress there made is well worthy of study by the mine operator looking for maximum efficiency in every branch of his activities. One of the outstanding developments in the construction of railroad equipment in recent years has been the wide-spread adoption of large one-piece steel castings for the framework of locomotives, passenger and freight cars. Some of the advantages and applications of this type of construction will be outlined in this paper, with particular thought of the needs of the mining industry. The inherent qualities of cast steel: homogeneity, unrestricted size and shape, high tensile strength, flexibility of metal distribution, resistance to corrosion, and gracefulness of outline, make it the most versatile member of the ferrous group. Not only is it a strength-giving element, but it is corrosion resistant, a combination that makes for large economies in equipment maintenance. Flexibility of metal distribution allows the integral foundation to be in the shape best suited for the purpose. These cast structures are really assembled in the mold in liquid form and the metal can be placed in the right pro¬portion exactly where it is needed, thus securing weight economy and uniformity of fibre stress. Such a process permits the incorporation, with ease, of necessary brackets, utilizing them to provide not only greater strength for the derail part itself, but often to add to the value of the entire unit. Laps, seams, and joints, which are necessary in all fabricated forms, are eliminated.

Jan 1, 1933

By S. S. Arentz

An organized safety program has reduced accidents at Pioche because effort is first devoted to arousing and maintaining interest in safety, followed by training in accident prevention, assigning responsibility for the detection and removal of safety hazards, and finally, by keeping score through an adequate system of records. A health program is intergrated with the safety program.

Jan 1, 1950

By M Jahani, M Taji

For suitable production planning in an open pit mine, and also to carry out the optimisation process during the mining production cycle, prediction of fragment size distribution is required prior to carrying out the blasting operation. For this purpose, many prediction models, such as empirical models, were presented. The proficiency of these models differs in various conditions and mines. Therefore, in this paper the most important models, including SveDeFo, Kuz-Ram, CZM, Modified Kuz-Ram in 2005, Kuznestsov-Cunningham-Ouchterlony (KCO) and also Gheibie et al, were examined by the information of 20 blasts in Gol-Gohar iron ore mine. Fourteen images were taken on average for each blast. For image processing analysis Split-Desktop software was used. After examination, it was understood that none of the available empirical fragmentation models had presented acceptable performance, except the Kuz-Ram model for magnetite ore, which had somewhat acceptable results. However, this model for blasting patterns in hematite presented unsuitable results. Examination and comparison of two important distribution functions, Rosin-Rammler and Swebrec, were carried out and it was observed that the performance of Swebrec for fines was far better than Rosin-Rammler. This result for the upper part of fragment size distribution curve, coarse, is the reverse.CITATION:Jahani, M and Taji, M, 2015. Comparison of empirical fragmentation models at the Gol-Gohar iron ore mine, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 707–714 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By J. W. Devon

The coal mining industry is divided into two distinct economic segments based on Coal Supply Agreements. Coal supply agreements generally fall into two categories, spot or long-term, with the selected contract term being driven by the buyer's market expectations, security of supply considerations, fuel tonnage and quality requirements, and economics. Short-term or spot coal purchases are generally market driven and are highly competitive in today's marketplace. Long-term contracts, particularly those involving captive mines and mine-mouth power plants, are commonly driven by considerations other than economics. These other considerations, such as Reserve Conservation and Resource Recovery, Security of Supply, and Maintenance of Levelized Costs may increase the cost of coal, often needlessly and without benefit to the buyer or seller. The basic economic principles which guide the market driven metals industry and generally guide the spot coal sector of the coal industry should apply equally well to the long-term coal supply contract. The artificial constraints imposed as a result of regulated rates of return should be re-examined and in most cases, abandoned. There are many methods of surface and underground coal mining being used today such as, open-pit, contour, mountaintop, and area mining for surface mineable reserves; conventional, standard continuous and super-section continuous miners, and longwalls for deep reserves; and highwall miners, thin seam miners and augers in between. This discussion is primarily directed to surface mining, however the same principles of least cost mining on a Net Present Value basis must be considered in all cases.

Jan 1, 1994

"INTRODUCTION Foam, unless intentionally created, in any industrial process presents operational problems, or at a minimum, is a nuisance. Some foam problems are unique to a given industry and others are common across many industries. A few problems foam presents to any particular industry are: (a) Poor Housekeeping, (b) Environmental impact, (c) Safety Hazards, (d) Slower Production Rates and, (e) Reduced quality of the end product. Defoamers address these issues. Sadly, the assumption in most industries is all defoamers are alike. In reality, a lot of chemistry is involved in the manufacture of even the simplest defoamer sold today and rarely are any two defoamers “just alike”. Today’s defoamers can include polymer chemistry, fatty esters, alkoxylated alcohols, silicone chemistry, silicone surfactants, ethoxylated and propoxylated block polymers, and a tremendous amount of emulsion chemistry just to name a few. This paper will discuss the various types of defoamers, defoaming mechanisms, the advantages and disadvantages of defoamer selections, and how to choose the proper defoamer for your application. Before a discussion of defoamer can be brought about, foam generation and composition must be discussed. WHAT IS FOAM? Foam is a colloidal suspension of a gas dispersed in a liquid. Most often foam consists of air dispersed in water. If a stream of air is introduced into a liquid, the bubbles produced assume a spherical shape. As the density of the bubble is less than the liquid the bubble rises. When the individual bubbles reach and pass through a surfactant free liquid they collapse. Air from the bubble dissipates and the liquid previously surrounding the bubble flows back.It should be noted a pure liquid will not foam. In the case of air dispersed in water a surfactant is necessary to make the water support a stable foam. A surfactant is a term used to describe a surface active agent; a compound with a hydrophilic end and a hydrophobic end on the same molecule."

Jan 1, 2016

By Alexandre Rizek Schultz

Esse projeto visou à substituição do sistema de controle instalado no laminador de barras e fio-máquina, por um novo e moderno sistema de controle. Este novo sistema irá controlar o laminador de barras e de rolos instalado na Usina da Vetorial, no Paraguay. Juntamente com a atualização do sistema de controle, a RUSSULA irá substituir os antigos e descontinuados conversores de corrente contínua VERITRON, fornecendo kit’s de digitalização e aproveitando os tiristores antigos, porem confiáveis. Na cabine central serão instaladas ferramentas para facilitar a operação do laminador e equipamentos, com novas telas de operação, sistema de aquisição de dados de alta velocidade, sistema de gerenciamento de intertravamentos, dentre outros. O PLC existente, um BBC Procontic, será inteiramente substituído por novos S7-1500, nova linha de PLC’s Siemens. O novo sistema irá possibilitar aumento de produtividade, diminuição de paradas, diminuição de perdas metálicas e maior confiabilidade no controle.

Oct 30, 2017

By A. Phillips, D. H. Killpatrick, V. Kerlins

The tensile failure of two dispersion-strengthened Ni-20 Cr alloys was studied and compared to the fracture of a similar alloy with no dispersoid. The fracture characteristics were studied using electron fruc-tography and transmission electron microscopy. In all three cases, the mode of failure was found to be microvoid coalescence. The failure in the dispersion-strengthened alloys was found to have initiated at the particles. The size of the dimples in the fracto-graphs was found to be related to the spacing of the particles, but not to the total elongation before failure. The elongation before failure was found to be related only to the amount of dispersed phase. These results are compared to those predicted by a theoretical model of ductile failure. THE continually increasing strength requirements for creep-resistant materials capable of long life at service temperatures above 1600"F (875"C) have developed considerable interest in dispersion-strengthened nickel-base alloys. The high yield strength of these alloys results from the presence of a dispersion of fine particles of thoria which act to impede the normal motion of dislocations. Many theories have been presented to explain the role of the dispersion in the strengthening of these alloys. A good review of these theories is presented by Ansell.' The ultimate strength of such alloys is not only related to mechanisms raising the yield strength, but also to the amount of work-hardening which occurs. This work-hardening is determined by the work-hardening rate and the amount of plastic strain before failure. Since fracture limits the amount of plastic strain, a study was undertaken to gain a better understanding of the fracture mechanisms in these alloys. Electron fractography and transmission electron microscopy were used to study the fracture characteristics in two dispersion-strengthened alloys and one similar alloy containing no dispersoid. These results are related to the tensile properties of the dispersion-strengthened alloys at room temperature and at 2000°F (1095°C). The results are also related to a theory for ductile fracture. 1) PROCEDURE Standard tensile specimens were made from 0.020-in. (0.051-cm) sheets of three different Ni-Cr alloys. The alloys had nominal compositions of Ni-20Cr, Ni-20Cr-2Th0,, and Ni-2OCr-4Th0,. All alloys were supplied in an annealed condition. The specimens were fractured in tension at room temperature to determine the effect of the dispersed thoria on the fracture appearance. The tensile properties were determined from the average of a minimum of three ten- sile specimens for each condition tested. The fracture surface of all of the alloys was examined by electron microscopy using standard two-stage plastic-carbon replica techniques. Thin foils of the dispersion-strengthened alloys were used to investigate the size and spacings of the dispersion particles, and to investigate sections of the 2 pct thoria alloy taken from areas of the specimen adjacent to the fracture surface. The thin foils were mechanically ground to 0.010 in. (0.025 cm) and then chemically polished to approximately 0.001 in. (0.003 cm) in a solution of 29 g of ferric chloride and 10 ml hydrochloric acid in a liter of water. The polishing solution was maintained at 150"F (65°C) during the thinning operation. The final thinning of the foil was done electrolytically using a solution of 700 ml ethanol, 100 ml 2-butoxy eth-anol, 120 ml distilled water, and 78 ml perchloric acid (70 pct). The potential was maintained at 15 v and the bath temperature at -20°~ (-29°C) during the thinning operation. The final thickness of the foil was approximately l000A as determined from the width of twins boundaries observed in many of the foils. 2) RESULTS AND DISCUSSION The electron fractographs of the fracture surfaces of the alloys are shown in Figs. 1, 2, and 3. The normal interpretation of this type of fractographz is that, as a result of the difference between elastic and plastic properties of the matrix and the particles or other inhomogeneities in the alloy, microvoids are formed

Jan 1, 1969

By J. W. Leonard, B. A. Donahue

A method is described for incorporating coal petrography into mining and preparation plant quality control based on conventional analyses. Complete analyses are made of each of the uniform and relatively distinct petrographic bands in a coal face. With this information it is possible to develop petrographic standardization curves. These curves permit diverse coal characteristics to be rapidly monitored by application of a few standard coal tests. Single seam quality control is discussed in this paper. Inquiries continue to be made about coal petrography, and specifically, about whether coal petrography should be applied more extensively in the coal industry. Coal petrography is the study of the distinct physical, optical, and chemical increments which make up the organic rock mixture which we know as coal. Petrography can be applied by any coal company or at any coal mine where conventional coal analytical facilities are available and where additional resources can be allocated for an increased number of determinations. This first paper of a two part series includes (1) a proposed conventional approach to single seam petrography based on the development of petrographic standardization graphs and (2) some informative and supplemental interrelationships involving coal characteristics developed as a result of this research. In the second part of this series, to be published at a later date, those petrographic characteristics of bands taken from many different coal seams located over wide geographic areas which can be closely related to each other will be considered. These findings will be examined looking toward the development of a comprehensive, conventional approach to coal petrography which can be used as a common basis for multi-rank petrographic standardization graphs. Implicit to the understanding of coal petrography is the well established fact1,2 that the individual analyses of distinct petrographic bands often differ widely from the average analysis which is used to characterize a whole coal seam. In fact, a distinct and minor banded increment of coal in a high volatile seam may actually be a medium or low volatile coal with an analysis similar to the average analyses of seams located in distant coal fields. During the mining of coal, much degradation is caused which tends to randomly scatter coal bands. The degraded, scattered, and physically separated constituents of distinct petrographic bands are processed side by side in the coal preparation plant as distinct petrographic fractions with particles grouped according to a narrow size range (which derives in part from common hardness), specific gravity, and-or surface chemistry. Tile data obtained from numerous analyses made on each of the bands of any given coal seam, although diverse, can be readily interrelated. Indeed, these interrelationships can be developed into a series of nomographs or petrographic standardization graphs to serve as a basis for developing a conventional petrographic* program. Thus, by analyzing one property (for example, ash) of a selected petrographic fraction collected or separated from the flow of coal in a preparation plant, it should be possible to estimate the other physical, chemical, and thermal properties of this fraction by referring to the petrographic standardization graphs. It follows that any or all petrographic fractions in the total coal flow originating from a single coal seam can be rapidly monitored for many properties on the basis of a single analysis run on each fraction. In recent years coal petrographic research has concentrated heavily on that phase of this work which involves microscopic reflectance measurements made at many minute and selected points on a coal briquette surface.3,4 Thus, the percentage of the total number of reflectance measurements that fall into each of a consecutive series of arbitrarily chosen reflectance classes are used to characterize coal. This procedure is analagous to using the face of a coal briquette to represent the reflectance characteristics present at the face of a coal seam. Moreover, by analyzing petrographic fractions of known and uniform optical properties it is possible to closely relate reflectance to other coal characteristics. For example, reflectance has long been known to be related to such

Jan 1, 1968

By L. J. Erck, T. E. Ban

A discussion of laboratory procedures used to determine pellet quality and to simulate handling and firing conditions. Strength-temperature relationships in pelletizing; effect of chemical additives on agglomeration; and crushing, abrasion, and impact resistance of the pelletized products are discussed with respect to five different iron ore concentrates. IN most routine experimental work on products and processes, method:; of operation and product evaluation are established from accurately controlled laboratory tests. With particular emphasis on the pelletization of fine iron ore concentrates, standardized procedures of laboratory production and product testing have been established at Cleveland-Cliffs Iron Co. Research Laboratory at Ishpeming, Mich. A program of this nature was used for investigating the agglomeration characteristics of various iron ore concentrates. The factors which control the process were studied and subsequently controlled for these investigations. Pelletizing as applied to iron ore agglomeration involves the preparation of spheroidal masses from a fine moist concentrate, followed by high-tempera-ture firing to produce a final product. The preparation of moist spherorids is generally designated as balling. This produces the so-called green pellets or balls. After, these have been fired they are called pellets. Balling is accomplished by rolling moist concentrates in a revolving drum until small spheroids form by a snow-balling action. These balls are then heated in a shaft furnace, or a modification of this device, to a temperature high enough to cause agglomeration within the individual balls while they descend countercurrent to hot oxidizing gases. By this process the lour strength balls are converted through various chemical and physical-chemical processes into hard pellets. With correct balling and firing, the pellets are strong, resist abrasive action and handling treatments, and provide a suitable blast furnace and open hearth feed. In 1950 Tigerschiold and Ilmoni developed a working hypothesis to explain the formation and stability of green pellets.' Their work was presented on the basis of geologists' discoveries concerning the soil-water system and C. V. Firth's early postulates of green pellet formation.' Fundamental reactions oc-curing within fired pellets have been described by Cooke and Ban, who showed the microstructure changes caused by different firing temperatures." All these investigators have provided scientific clarifications of agglomeration by the pelletizing process and have opened avenues for greater development. Mineral grain growth and ceramic bond formation are the two basic phenomena imparting coherency to particles within a fired pellet of iron ore. Each of these is established by the transfer of thermal energy to the mineral particles. Grain growth mechanisms are chiefly physical reactions wherein smaller particles consolidate into larger ones, with resulting decrease in surface energy conforming with the second law of thermodynamics. Ceramic bond formation is a chemical reaction usually between basic and acid metallic oxides of the gangue and ore minerals. CaO, MgO, A1203, and FeO of Fe3O4, react in varying proportions with SiO, or Fe2O3, to form a great series of compounds or amorphous solid solutions. These product bond iron mineral particles together by a bridging action or by direct reaction with the surfaces of the particles. The result of the grain growth-ceramic bond formations is a consolidated, coherent compact of gangue and iron minerals formerly held together by much weaker bonds of interstitial water and forces common to dry, unconsolidated particles.4 With respect to iron ore agglomeration, these high temperature bonding reactions have been described by Schwartz, who referred to the bonds in sinters," and by Cooke and Ban, who referred to the bonds in fired pellets." The extent of the bonding phenomena and the consequent strength of fired pellets is governed by

Jan 1, 1954