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By D. L. Jones, S. Knoerr, J. Mansanti

The Buckhorn Mine in Nevada currently treats oxide ore using heap leach methods, but exploration has identified sulphide reserves which are refractory in nature. Preliminary testwork was conducted on the sulphide material to screen potential pre-cyanidation treatment methods. Processes evaluated included pressure oxidation, biological oxidation, nitric acid oxidation and roasting. An initial economic and process analysis of the results concluded that roasting was the only viable process, and only if the roaster off-gases were converted to soleable sulphuric acid. Further economic analysis indicated that roasting of the whole ore was more attractive than pre-concentrating by flotation, followed by roasting of the concentrate. These results were generalized to show that for high sulphur ore a roaster/acid plant combination is more attractive that either of the other options, ie. pressure leaching or bioleaching, provided the by-product acid is soleable.

Jan 1, 1990

By Staff

Concentrates at the rate of 1000 tons a day are being smelted by International Nickel Co.'s new commercial flash smelting furnace. Developed by Inco, the process is a radical departure from the former practice which involved conventional smelting in coal-fired reverberatory furnaces. In the new process copper flotation concentrate and flux are injected horizontally with oxygen into a specially designed reverberatory furnace, and smelting temperature is maintained solely by the flash combustion of iron and sulphur while the particles are in suspension. The major benefits of this new process stem from two sources: 1)-Substitution of energy from local resources for imported coal; and 2)-Production of liquid sulphur dioxide, replacing equivalent imported sulphur. A measure of these benefits is afforded by considering the saving, in 1954, of 60,000 tons of coal and the production of 70,000 tons of liquid sulphur dioxide, equivalent to 35,000 tons of sulphur.

Jun 1, 1955

By I. Ehie, Y. P. Chugh

Physical mine modeling and computer simulation techniques were used to conduct technical feasibility and economic analyses of selected pit configurations for surface mining a single coal seam dipping at about 15% to a maximum depth of 46 m (150 ft). Pit orientations along the true dip (dipline), along the strike (strikeline), and along an apparent dip were studied. Physical models of each pit configuration were prepared first to delineate potential operational problem areas and also to furnish data for the computer simulation models. A dragline microsimulation, a shovel/truck simulation, and a surface mine cost analysis models were used to conduct the study. Sensitivity analyses were conducted on variables such as the pit width, block length, and seam pitch. The productivity (m3/h) of the mining equipment (dragline or stripping shovel) under each set of conditions was used to optimize the pit configuration. Both block length and panel width were found to significantly affect the dragline productivity. Larger size trucks were preferable to smaller size trucks in the pit con¬figuration along an apparent dip. The cost analysis results showed that the pit configuration along the seam dip was more economical than the pit along the strike or along an apparent dip for the mining condition studied.

Jan 1, 1987

By W. H. Emerson

In the summer of 1894, a specimen of corundum from Acworth, Ga., which mas reputed to be of markedly inferior quality for the manufacture of corundum-wheels, was received by the Geological Survey of Georgia, with the request that it be analyzed, in order to ascertain whether this inferiority was associated with any peculiarity of composition. In its appearance there was nothing uncommon, though it seemed to be rather easily scratched with a knife, while, at the same time, it scratched agate easily. An analysis gave the following results: Alumina, 94.58; silica, 1.77; magnetic oxide of iron, 0.69; calcium oxide, 0.44; and water, 2.51 per cent. There is nothing unusual in this composition, except the amount of water, which is usually, in southern corundum at least, from 0.3 to about 1 per cent. Concerning this corundum, the Mineral Resources of the United States, 1893, pp. 676 and 677, Bays: "It is supposed that this variety of corundum contains a little water, as it is

Jan 1, 1900

By G. W. Hodges

The Basic Oxygen Process shop at Gary Works is a three vessel shop tapping 220 ton heats. The larger portion of the heats are teemed into ingot molds with the remaining heats being continuously cast in a single strand continuous slab caster. Ingot production includes a wide range of carbon, alloy, and high-strength steels in many ingot sizes for bar, structural, plate and sheet and tin products. Individual ingot weights vary with the number of ingots per heat ranging from a high of 48 to a low of five. Caster production is primarily Riband, a proprietary low carbon grade for sheet and tin applications developed by United States Steel for continuous casting; some Riband steel is vacuum degassed prior to casting. Maintaining a satisfactory level of ladle performance on both ingot and caster heats with a high production rate and widely varied product mix is a demanding and exacting job requiring the best of equipment, materials, and, most importantly, personnel. The improving trend in ladle performance in the No. 1 BOP shop at Gary is due to a combination of factors, which will be described in the following presentation.

Jan 1, 1972

By Kenneth S. Johnson

High-purity gypsum of Permian age crops out in three major gypsum districts of western Oklahoma. The northwest and southwest districts have important reserves in the Blaine Formation, whereas reserves of the west-central district are in the Cloud Chief Formation. Gypsum beds of the Blaine Formation typically are 10 to 30 feet thick, 95 to 99 percent pure, and interbedded with shales that are 2 to 30 feet thick. The base of the Cloud Chief Formation consists of a massive bed of gypsum that typically is 20 to 100 feet thick and is 92 to 97 percent pure. Anhydrite is present in the sulfate beds, beneath 20 to 100 feet of overburden, at a number of places in all three districts. Total gypsum reserves in the three districts are estimated at 48 billion short tons. These reserves are well suited for open-pit mining or quarrying, because gypsum typically forms hills in the semiarid climate of western Oklahoma, and the gypsum layers are nearly flat lying, without folds or faults. Seven companies currently mine a total of 1.0 to 1.4 million tons of Oklahoma gypsum each year for wallboard, for plaster, as a retarder in portland cement, and as a soil conditioner.

Jan 1, 1978

By Harry R. Cedergren

Properly designed drainage systems can be of great benefit to many kinds of Civil Engineering works, including embankments, and often are the most economical way to protect such works from the damaging effects of water. To function properly, drains must be able to remove water without also removing soil or becoming clogged with soil or erodible rocks. The first criterion to be used in designing drainage systems, called the filter criterion, can prevent all such problems (erosion and clogging) when properly fulfilled in design and construction. The second requirement of drains is that they must be capable of removing all of the incoming water without the build-up of large amounts of head that can damage the protected works. To insure this kind of perfomance, the discharge capabilities of drains should always be verified by appropriate hydraulic and seepage calculations. This paper describes these two basic drain design criteria and also gives examples of application of seepage principles to the evaluation of the potential benefits of drains and to the design of drains for mine waste embankments.

Jan 1, 1985

By J. J. Bourquin, S. H. Katz

"Three types of respiratory apparatus namely, gas masks, hose masks, and self-contained oxygen-breathing apparatus - are now commonly used for protection from noxious gases, vapors, and smokes or ristes, but no particular type can be selected as best for all conditions. Many factors must be considered in connection with each situation, so that each must be considered as a problem in itself. Following are concise statements for comparing the types:Gas masks are the simplest and easiest to wear, also the least cumber-sore; but they protect only in comparatively low concentrations of noxious gases and should never be used where the air contains less than 16 per cent of oxygen. Special masks give protection from one gas or class of gases, but may give no protection against another gas or class of gases.Hose masks protect in any irrespirable atmosphere, but are somewhat cumbersome, the length of hose limiting the distance a wearer may go from fresh air. They are serviceable also where a supply of pure air moves with the wearer, as where a locomotive engineer in a smoky tunnel is using a hose mask supplied with air from the compressed air line of the locomotive. Hose masks consume no chemicals or materials and so are not limited in the time they may be used.Self-contained oxygen-breathing apparatus protect in any irrespirable atmosphere, but their weight is cumbersome, they can be used only by trained men, and frequent attention must be given them to maintain good working condition. On the other band they are the only safe means for exploring mines and other places filled with irrespirable gases in high concentrations."

Jun 1, 1923

ALTHOUGH everybody is familiar with coal, few persons have an exact idea of, the great impor-tance of this precious fuel. Coal is the black bread of industry. Without it, industrial activity is much restrained; and so the great industrial countries of Europe and the United States of America are the great producers of coal. The 1913 production of coal in Belgium was 22,842,-000 tons, valued at 418,700,000 fr., nearly a half billion. In 1919, it was 18,483,000 tons, about 81 per cent. of the production before the war; in 1920, it had reached 22,414,000 tons, approximately the production before the war. To show the importance of coal production of Belgium, let us say that the coal industry employed 168,000 workers in the year of 1920, the metallurgical industry only 129,000 and the textile industry 103,000. The coal industry, then, employs the greatest number of workers. The value of the coal production in 1919 is estimated at 1,121,000,000 fr. On the basis of the production before the war, the value of the production of iron in 1919 would have been 701,000,000, of finished steel 1,086,000,000, and of zinc 415,000,000; therefore, in 1919 the value of the coal industry was greater than that of the metallurgical production.

Jan 8, 1922

By R. W. Titshall

WHAT IS SAMPLING? We are all involved in sampling almost every day of our lives, by tasting, feeling, or smelling. Most raw materials, food products or manufactured items are sampled several times at various stages of the production process before a commodity of suitable quality can be produced. Data obtained from sampling is used in establishing price, quality control, allocating production costs, or overall process efficiency. The area of sampling outlined in this article is the collection of a small quantity of material from large continuous bulk flows of solids and slurries. The concern in obtaining the sample is that the material obtained is truly representative of the main flow in every respect. The methods and equipment outlined are for the collection of a manageable sample. The sample has to be analyzed in a laboratory to determine its characteristics and compliance to set standards. SELECTING A SAMPLING SYSTEM When selecting a sampling system, it is essential to define the requirements, as to what the actual sample obtained will be used for and what degree of precision is required. Determine whether or not the system has to comply with any set standards such as A.S.T.M. (American Society for Testing and Materials) which have established methods for collection of a gross sample of coal. Sampling which is done for in-plant or process control is not generally governed by set procedures, but similar care should be taken during the selection process so that when the equipment is put into service it will operate reliably and produce a sample which is truly representative of the total material lot or consignment.

Jan 1, 1982

By Euler De Souza, Jason Chew, Aldrich Philip Dirige

Sillmats are structural elements upon which the safety and economics of underfill mining or sill pillar recovery in stopes of moderate width with steeply dipping ore zones, depend. The traditional stability design of cemented sillmats appears to have developed from experience and from standard static physical model tests such as uniaxial and triaxial compression. Such standard static physical model testing approach arrives at some approximate parameters, normally used to describe or predict the behaviour of sillmats in analytical or numerical models. This approach offers inherent limitations and generally results in conservative designs. Centrifuge modeling studies are combined with numerical modeling in this paper to provide insights into sillmat strength behaviour. The results of both modeling techniques suggest that, in stopes with smooth rock wall conditions, sillmat failure is driven by the fill self-weight and has minimum dependency on the fill binder content. In stopes with rough rock wall conditions, however, the wall roughness contributes significantly to the stability of the sillmat during underfill mining. This study indicates that the stability of paste fill sillmats can be designed with confidence using centrifuge physical modeling in combination with numerical modeling.

Jan 1, 2001

By I. E. Odom

The physiochemical properties and industrial uses of the clay mineral montmorillonite are reviewed. Montmorillonite is the most abundant species of the smectite clay mineral group and is the predominant mineral composing bentonite deposits. The crystal structure, chemical composition, exchangeable ion type, and small crystal size are responsible for several unique properties, including a large chemically active surface area, a high cation exchange capacity, and interlamellar surfaces having unusual hydration characteristics. The type of exchangeable ion, sodium (Na), calcium (Ca), and/or magnesium (Mg), has a major influence on industrial and chemical uses of montmorillonite because of their hydration characteristics. Natural occurrences of Na mont¬morillonite in commercial quantities are geographically limited, but Ca-Mg montmorillonite deposits are known worldwide. Foundry, well drilling, pelletizing, and civil engineering constitute the major uses of montmorillonite, but the total array of uses exceeds that of any other mineral.

Jan 1, 1988

By Maria Skyllas-Kazacos

The All-Vanadium Redox Flow Battery that was pioneered and has been developed at the University of New South Wales (UNSW) in Sydney since the mid-1980s is currently regarded as one of the most attractive energy storage systems for large-scale implementation in a wide range of grid-connected and offgrid applications. Several companies are now manufacturing and installing MW-scale VFBs in applications ranging from renewable energy storage, load-levelling, emergency back-up power and power arbitrage. The full-scale uptake of the VRB in commercial energy storage systems however, is heavily dependent on the availability and cost of vanadium used in the VRB electrolyte. Cost is also a function of purity requirements and although there is little scientific evidence on the effect of impurities on the VRB life and performance, VRB developers continue to demand high purity vanadium at considerable cost. This paper will provide a brief overview of the current understanding of electrolyte impurities on VRB performance together with an economic analysis of the impact of vanadium prices on overall VRB capital and levelised costs for a range of applications.

Jan 1, 2014

By R. Parada

In January 1995, Disputada Mining Company Ltd. (Compañia Minera Disputada de Las Condes) started up the Expansion Project for the Chagres Smelter, following an investment of US$M 2 15. The new smelter replaced the 44,000 tomes per year revervatory furnace with an Outokumpu Flash Smelting Furnace (FSF) designed to produce 118,000 tonnes per year of copper. Nowadays, this smelting unit has achieved a 40% over design performance. The landmarks of this modernization project are described. The start up period in 1995-1996 was characterized by the impacts of several restrictions that prevented the smelter from reach design production. The design performance was reached in 1997-1998 through the implementation of solutions designed to eliminate, or at least mitigate, the restrictions found early on. The smelter has been further optimized in the 1999-2000 period, leading to a new record anode copper production rate of 148,000 tonnes in 2000 while obtaining 98% approval for our different anode shapes. The objective of this paper is to discuss the consecutive processes of start-up, achievement of design capacity, and operational improvements to go well beyond the design capacity. These processes took place between early 1995 and late 2000, under the principles of Continuous Improvement that promotes the effective participation of the workers in the technology innovation and Enterprise Management.

Jan 1, 2002

By L. M. Petrie, D. C. Marozas, S. E. Paulson

The US Bureau of Mines (Bureau) is conducting research to evaluate the potential for developing an in situ leach mining process that will selectively extract manganese from oxide ores, leaving gangue relatively undisturbed. To accomplish this, a geochemical approach based on deposit-specific information, such as mineralogy and geology, is used to constrain the operating parameters of the system. Among the studies being conducted are: • leaching experiments to define reaction mechanisms and kinetics, • detailed petrologic characterization at the microscopic scale to assess manganese distribution and leaching efficiencies, • deposit characterization and evaluation, and • development of potential manganese recovery schemes. Data from these studies are being used to develop engineering design information for an in situ mining process. Specific details of the Bureau's research project are discussed, including results obtained to date.

Jan 1, 1993

By Ricketts N. J, Smith G. D J

A hydrometallurgical process was developed for recovery of copper from copper-lead matte formed as an intermediate product at the BHAS lead smelter at Port Pirie. A plant utilizing this process was commissioned in 1984. The leach step involves oxidation of the copper-lead matte in an oxygenated acidic chloride-sulphate leachant. The results of laboratory scale testwork from which the chemistry of leaching was deduced, are presented in this paper. The rate of recovery of copper to solution from copper-lead matte depends largely_on the availability of oxygen to the sulphide surface. The optimum leach temperature is approximately 85¦C. Free acid must be supplied according to the stoichiometry of the leach reaction: Cu1.91 S + PbS + 2.91 H2SO4 + 1.455 02 = 1.91 Cu2+ + 1.91 SOj- + PbSO4(s) + 2.91 H2O + S¦ The grind size of the matte is of minor significance. Chloride concentration in leachant should be at or above a minimum of 10.0 g/l. Chloride acts to complex cuprous ions formed during leaching.

Jan 1, 1987

By Tadao Nagai, Masao Sato

Electrochemical measurements have been carried out in an auto- clave to investigate the electrochemistry of hydrogen precipitation of nickel from acetate buffered solution. After having previously obtained the rate equation for this reaction we have now made a concentrated effort to explain the rate equation electrochemically. A saturated NaC1-type Ag/AgC1 reference electrode has been improved so that it can be used in an autoclave. Polarization curves for the reaction, [H2=2H+ + 2e,] on nickel electrode were measured in solutions free from nickel ions at 185°C, and the parallel curves were obtained by changing PH2 and pH for normal and reverse reactions, respectively. Polarization curves in nickel solutions were complex, probably because the potential of hydrogen electrode is close to that of nickel and of the nickel surface altered during polarization. Then the nickel electrode potential and the reaction rate were measured simultaneously during pressure reduction at various hydrogen pressures and at various nickel concentrations. The reaction rates in terms of current density were plotted to obtain the local polarization curves for reactions Ni2+ + 2e ? Ni and H2 ?2H+ + 2e. The anodic and cathodic local polarization curves exhibit potential dependency. Therefore it is likely that the pres- sure reduction can be regarded as a coupled electrodes reaction.

Jan 1, 1973

By Warren Blauvelt

IN VIEW of the enormous wastes of natural resources, of labor and of capital, due primarily to the economic environment, established by legislation, the general neglect of this phase of the problem of the elimination of waste is difficult to understand. In such a study, the engineering method of attacking a problem should be employed. The engineer does not try to solve his problem by disregarding natural laws, but by utilizing them. The successful engineer establishes an environ-ment in which forces, acting in harmony with natural laws upon an object or objects, will produce the desired results. The engineer who notices that the water level in a vessel, into which a gallon of water per minute is flowing, is two feet higher than the level in an adjacent vessel, connected therewith by a 6-in. pipe, does not assume that the law of gravity has ceased to work, or that water no longer seeks its level; he examines the connecting pipe for obstacles which prevent the free flow of water. Some editors, many reformers and most politicians tell us that the law of supply and demand no longer works; hence governmental control of commerce is necessary. Governmental control may temporarily-that is, until trial proves its futility- "insure domestic tranquility" and "promote the general welfare;" but it cannot "secure the blessings of liberty" which it cur-tails, nor can it "establish justice" which it violates.

Jan 9, 1922

Rajasthan of western India blessed with rich base metal and phosphorite deposits. The biogeochemical and geobotanical methods of mineral exploration are greatly used in parts of Rajasthan Zawar, Khetri and Ambaj multi-metal project Gujarat and Jhamarkotra phosphorite deposit. These principles are exclusively based on certain assumptions about the anomalous chemical composition in plants and distribution and migration of indicator elements. Biogeochemical studies for lead zinc deposit of Zawar group of mines were carried out to locate the probable accumulators which could help in prospecting for these metals. The important roots of Impatiens balsamia plants contain 735 mg. of cadmium and crotolaria linifolia 603 mg., melhania futteyporensis 626 mg. lindenbergia muraria 443, celosiu argentia 360 mg. In the Khetri copper belt the vegetation is scanty and the species includes Acacia arabica, zyzypus jujuba and cactus euphorbia.

Jan 1, 1988

By Ing. E. h. Martin Herrenknecht

The paper will describe a number of developments and innovations now in use in microtunnelling machines. These include the use of fuzzy logic steering systems, the proven ability to successfully undertake complex curved microtunnel drives, the ability to complete ultra long drives using microtunnelling techniques, and machines with access to the face of the machine from inside the machine. The ability to tunnel in relatively hard rock utilizing a rock head with back loaded cutters changeable from inside the microtunnel machine and the ability to utilize microtunnel machines in multi modes, such as hard rock mode, “open” mode, EPB mode, and slurry mode with the same base machine again with access to the face of the machine will be described. In addition, the latest computer technology gives the operator “full visualization” of machine functions together with the ability to data log machine operating parameters. Reference will be made to a number of projects worldwide recently completed or under way where these innovations have successfully been utilized.

Jan 1, 1999