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By Jr. Carmichael

"THE MAYO AREA was prospected as early as 1887. The first major activity started in 1898, when the Stewart River and its tributaries were examined for placer deposits, and in succeeding years the district became a small producer of placer gold. The first discovery of the lead-zinc-silver mineralization which has become the main interest of the district occurred in 1906, when a vein was found in the canyon of Galena Creek on the northwest slope of Galena Hill. This deposit was later known as the Silver King mine. In 1919 further discoveries were made on Keno Hill, approximately 15 miles east of the Silver King, the most important being the No.9 vein. Directly or indirectly, these finds are attributable to the search for placer gold, as galena was frequently found in the stream gravels.The 1919 Keno Hill discoveries were acquired by Yukon Gold Co. and operated through a subsidiary, Keno Hill Ltd., from 1920 to 1923. Most of the production came from No.9 vein. In 1921 Treadwell Yukon Corporation entered the field and acquired the Ladue mine. This company continued to operate for 21 years. It acquired in succession the Ladue, Sadie, Friendship, Lucky Queen, Elsa, Silver King, and Calumet mines. Its record of successful operations is very largely the achievement of the late Livingston Wernecke. Under his direction, the Treadwell Yukon Corp. produced metals with a gross value in excess of $21,000,000, in the face of greater transportation problems than exist today and with considerably lower metal prices.Treadwell Yukon ceased operations in 1942. Its entire assets were acquired in 1946 by United Keno Hill Mines Ltd., which has substantially increased the original holdings. It has drawn the bulk of its production from the Hector mine, adjacent to the Calumet. The Hector was not developed by Treadwell Yukon because of legal disputes among the vendors. It has proven to be the largest deposit yet discovered in the district."

Jan 1, 1949

By Tae Hwan Lee, Jun-Shin Lee, Daejin Kwag, Sangchul Bang, Gerard T. Houlahan, Moo Sung Ryu

"Geotechnical engineers have been installing innovative, permanent underwater foundation systems utilizing suction buckets for the offshore industry since the early 1980s (Senpere and Auvergne, 1982). This foundation system has been successfully used on numerous and various types of offshore structures in a wide range of environments. Suction buckets have numerous advantages compared to conventional underwater foundation systems. The more notable advantages include easy installation, large loading capacity, low noise and retrievability. The application of reduced water pressure inside the bucket facilitates the installation of the suction buckets, where a suction pump attached at the top of the bucket can accomplish the entire driving operation. Because of this efficient operation, very large suction buckets can be driven into the seafloor, which eliminates the use of a large number of small piles.In Korea, one of the most economical and reliable renewable energy sources is wind power; however, onshore wind power generation has encountered many problems, such as the lack of favorable sites and public concerns about noise and environmental damage. Consequently, offshore wind power generation has attracted increasing attention due to its abundant potential, high efficiency of grid connection, and availability of easy expansion.In November 2011, the government of Korea announced a national offshore wind power development roadmap, which targeted its offshore wind power generation with the goal of becoming one of the top three nations in the world for offshore wind power generation. Korea Electric Power Corporation Research Institute (KEPRI) is the main research arm of the Korea Electric Power Corporation (KEPCO) and conducts research and development on electricity, power generation, renewable energy and other energy-related matters. KEPRI ultimately provides forefront knowledge and leadership to KEPCO with respect to energy and related areas for its near- and long-term needs. Financial support for the overall project, of which the suction bucket foundation system installed for the pilot phase wind turbine is described below, was provided from the New and Renewable Energy Program of the Korea Institute of Energy Technology Evaluation and Planning funded by the Korean Government Ministry of Trade, Industry and Energy"

Jan 1, 2017

By Tae Hwan Lee, Jun-Shin Lee, Daejin Kwag, Sangchul Bang, Gerard T. Houlahan, Moo Sung Ryu

"Geotechnical engineers have been installing innovative, permanent underwater foundation systems utilizing suction buckets for the offshore industry since the early 1980s (Senpere and Auvergne, 1982). This foundation system has been successfully used on numerous and various types of offshore structures in a wide range of environments. Suction buckets have numerous advantages compared to conventional underwater foundation systems. The more notable advantages include easy installation, large loading capacity, low noise and retrievability. The application of reduced water pressure inside the bucket facilitates the installation of the suction buckets, where a suction pump attached at the top of the bucket can accomplish the entire driving operation. Because of this efficient operation, very large suction buckets can be driven into the seafloor, which eliminates the use of a large number of small piles.In Korea, one of the most economical and reliable renewable energy sources is wind power; however, onshore wind power generation has encountered many problems, such as the lack of favorable sites and public concerns about noise and environmental damage. Consequently, offshore wind power generation has attracted increasing attention due to its abundant potential, high efficiency of grid connection, and availability of easy expansion.In November 2011, the government of Korea announced a national offshore wind power development roadmap, which targeted its offshore wind power generation with the goal of becoming one of the top three nations in the world for offshore wind power generation. Korea Electric Power Corporation Research Institute (KEPRI) is the main research arm of the Korea Electric Power Corporation (KEPCO) and conducts research and development on electricity, power generation, renewable energy and other energy-related matters. KEPRI ultimately provides forefront knowledge and leadership to KEPCO with respect to energy and related areas for its near- and long-term needs. Financial support for the overall project, of which the suction bucket foundation system installed for the pilot phase wind turbine is described below, was provided from the New and Renewable Energy Program of the Korea Institute of Energy Technology Evaluation and Planning funded by the Korean Government Ministry of Trade, Industry and Energy."

Jan 1, 2017

By R. F. Krueger, L. C. Vogel, P. W. Fischer

Previous studies have shown that the permeabilities of sandstone cores are markedly reduced following exposure to drilling fluid and subsequent clean-up with oil at high-pressure gradients. Laboratory experiments reported in this paper indicate that permeability damage from drilling mud or water can be substantially avoided through use of an initial low-pressure gradient followed by gradually increasing gradients during clean-up by reverse oil flow. On the other hand, attempts to improve the permeability of damaged Berea and oil formation cores with high-rate oil backflush (simulated well stimulation) and low-rate clean-up gave erratic results. Essentfully complete permeability repair was achieved in most of the fresh water-damaged cores from Miocene and Pliocene oil-producing formations; only minor improvement was noted generally in tests with both water-and mud-damaged Berea sandstone. Field well stimulation treatments using high-rate back-flush resulted in long-term productivity improvement when production was brought in at gradually increasing production rates and then restricted to a steady value less than the maximum possible rate. Wellbore plugging at high production rates correlated with increasing solids content in the produced oil. Observations and results from these tests agree with current concepts that formation damage in water-sensitive rocks results from movement and bridging of formation fines, rather than from clay swelling alone. INTRODUCTION Many laboratory studies1-g have shown that the permeabilities of sandstone cores are often markedly reduced following exposure to fresh water or water-base drilling mud filtrate. However, work with cores in the restored state has demonstrated that, although permeabilities to water may be very low for sandstones containing hy-dratable clays, flow of oil can often restore a substantial portion of the effective permeabilities to oi1.Neverthe- less, water invasion into water-sensitive sandstone cores results in varying degrees of permanent reduction in permeability to oil.24' Based on field data, Wade's statistical study" of well completion effectiveness also indicated a correlation between productivity damage and water invasion during completion. Similar damage can result from fluid invasion during workover. Nowak and Krueger' and Bertness4 observed in their early work (1951-53) that formation damage in water-sensitive sandstones was associated not only with swelling of expandable clays but also with movement of dispersed particles. Subsequent work by Monaghan et al." (1959), Atwood'' (19641, Mungan" (1965) and Gray and Rex'" (1965) has led to general acceptance of the hypothesis that permeability damage in water-sensitive formations is caused by migration of finely dispersed minerals and bridging in "brush heap" arrangements at pore constructions. In laboratory studies, Monaghan et al.' found the use of chemicals to be of only minor value for repairing formation damage. Atwood? however, was successful in substantially repairing damage in a number of low-permeability cores using an n-hexanol flush. In the field, except for treatments with acids, the use of chemical washes to reduce wellbore damage has had limited and sporadic success and generally is unpredictable. A statistical analysis of stimulation treatments in silt-blocked wells has shown that physical manipulation of wash materials is more important than chemical composition." The recent work reported on formation damage in water-sensitive sands brings to mind the results of some unpublished exploratory work done in 1954 in connection with drilling fluid studies.' This laboratory work and subsequent field stimulation treatments indicated a beneficial effect of controlled pressure drawdown and the associated production rate on formation clean-up. This paper reports the results of this work and more recent supplemental experiments on the clean-up of water-sensitive sandstones damaged by water or filtrate invasion. PERMEABILITY RECOVERY AFTER DAMAGE BY DRILLING MUD APPARATUS AND TEST SAMPLES A drilling mud circulating system was used to expose cores to simulated wellbore conditions. The mud flow system is the same as that described by Krueger and Voge17 except that no provision was made for scraping

By W. E. Bearce

The recent concern for the recovery of even the finest fractions of coal preparation plant feeds has created needs for new equipment. Thermal dryers currently available have difficulty reducing the filter cake moisture on down to the desired point. This difficulty involves 1) the physical problem of handling this wet, sticky material and making each particle accessible to the hot gases, and 2) removing the extremely fine dried particles from the cooled gases. The dryer described in this paper handles the first of these problems, and eliminates the second by the substitution of steel balls for air as the heat transfer medium. As a general statement, the cost of preparing coal for market is inversely proportional to the size of the lumps or particles. In the not too distant past the finer sizes were discarded as being uneconomical to treat and this practice might be still continuing if it were not for the insistence of the public that this material be kept out of our streams. This being the only cost-free outlet, the disposal of fine refuse became a significant item of expense in every preparation plant. When this happened it was only reasonable to look to the recovery of the values in this material, not only to defray this expense, but to reduce the tonnage which had to be wasted. There seemed to be no device available suited to reducing the moisture in this material to what the market requires. All of the fine coal dryers commonly employed make use of air to bring the heat of combustion into contact with the coal particles. Any device employing air as a heat transfer medium, has the following two strikes against it in attempting to handle 28 mesh by 0 filter cake: 1) It is practically impossible to bring the hot air into intimate contact with the enormous number of fine particles stuck together in the cake. 2) Even if this can be effected, it is impossible to remove the dried coal from the air. A wet scrubber must be employed, the discharge of which must go back to the filter and dryer as a circulating load of the most objectionable sort, being the extreme fines. Various compromises have been used to cope with the problem of drying this relatively small tonnage of high moisture coal. Often some of the dried coal is mixed back with the feed to the dryer in an attempt to make the mixture more handleable and more available to contact with the hot air than the filter cake alone would be. This may help to some extent with the first problem but it does nothing about the second and a dryer operated in this way has to be oversized. Sometimes the filter cake is mixed with a coarser fraction for the same reason. Here again, while this may make a mixture (the particles of which are more readily brought into contact with the hot air), the problem of getting the fine coal out of the air remains and a larger percentage of the total coal to be dried is handled by the most expensive means. Mechanical dewatering has accounted for more and more of total coal drying lately and in many cases would satisfactorily handle the whole load, down to 28 mesh, if there were a means available for doing a good job on the —28 mesh by itself. The dryer which is the subject of this paper was designed expressly for doing this job — drying fine material by itself regardless of how wet it may be to start with, how fine it may be, or how gummy and sticky these properties in combination may make it. The essential features are depicted in Fig. 1. A rotating cylinder is supported on a frame in such a way that one end may be raised or lowered by hy-

Jan 1, 1968

By B. H. Caudle, A. B. Dyes

In a recent publication' it was shown that wells with a free surface in a homogeneous gravity-drainage reservoir have a hyperbolic decline with index n '. This paper reports efforts to extend this theory to practical field cases. As a first step in making the extension, a large number of lease production curves from gravity-drainage fields in the stripper stage were fitted with the general hyperbolic decline equation, q/q, = 1/(1 + y) y and n in each case being determined by statistical methods. It was found that this equation is reliable for decline curve extrapolation for periods up to at least 25 years. The resrilts obtained were disturbing in the sense that values for the index, n, were often smaller than one, which fact leads to the prediction that a well would produce all infinite amount of oil in infinite time. A theoretical investigation based on the results of the previous paper provides a suitable explanation for these low values of n. It suggests that these are obtained if production occurs from two or more layers of diflerent permeabilitv and thicktress or two lnyers having different skin effects. It is predicted that as the more permeable layers are exhausted, the index of decline, n, will rise from a value smaller than 2, to n = 2. A practical method is given for fitting the general hyperbolic decline Eq. 6 to production decline data. When this method is used, the index of decline observed in gravity-drainage reservoirs in the stripper stage when wing only data over early years 01 decline usually agrees quite closely with that determined using data over 25 years or more. This indicates that the hyperbolic decline equation is reliable for predicting behavior of such reservoirs. A method is also suggested for taking into account any changes in the value of the index INTRODUCTION As a result of both experimental work with models and theoretical deductions, it was recently concluded' that wells having a free surface in a homogeneous reservoir producing by pure gravity drainage should have a hyperbolic decline with n = 2. The present report details efforts to extend this work on ideal homogeneous reservoirs to actual field cases. It should be remembered that both the previous work and the present extension are based on the assumption that the reservoir is at very low pressure, and hence, nearly all the potential available for driving fluid to the well is the gravity head. Attempts to apply conclusions of this study to reservoirs which have considerable pressures supplementing the gravity drive may lead to difficulty. WELLS WITH NO FREE SURFACE In a dipping gravity-drainage reservoir such as that shown in Fig. 1, some of the down-dip wells have no free surface. The previous study' showed that the up-dip wells, which have a free surface, should follow Eq. 1. The following approximate analysis, of a type which was justified experimentally for up-dip wells in the work just mentioned, leads to results for the down-dip wells.

By Martin D. Larisch

The construction of diaphragm walls and most large-diameter bored piles (piers) is often carried out under drilling support fluids to temporarily stabilise the excavation prior to concrete placement. In most cases such fluids are either mineral-based slurries (bentonite) or polymer support fluids. The working mechanisms of these two fluid types are fundamentally different. Designers need to consider possible fluid-related impacts on the permanent design performance of the project-specific deep foundations as well as for the temporary excavation stage during construction. Robust design methods for bentonite slurry-supported excavations have been developed in the last few decades and the working principles and associated risks of such mineral-based slurries are understood reasonably well. However, such meth-ods have not been developed in detail for polymer-based drilling fluids. This document provides a brief overview of the main characteristics of bentonite- and polymer-based drilling fluids as a guide for construction practitioners and design engineers alike. The paper also high-lights some common construction risks related to casing installation and the selection of suitable fluid systems for different ground conditions. Typical defects caused by the incorrect application of drilling support fluids, and their pro-active mitigation, are discussed, too. In addition, the basic concepts of sta-bility calculations for bentonite fluid-supported deep excavations are briefly introduced and their ap-plicability for other fluid types such as polymer-based support fluids or water are reviewed.

Nov 1, 2022

By Laurance S. Reid, Joe A. Porter

Gas dehydration plays an important part in the production of natural gas. Effective dehydration prevents formation of gas hydrates and the accumulation of water in transmission Systems,2,6,7 insuring uninterrupted gas deliveries at maximum efficiency under the most adverse weather conditions. At the present time, most gas companies require a maximum water vapor content of seven lb per million standard cu ft of gas. so that virtually all gas tendered for sale must he dehydrated to meet this specification. For a number of years it has been common practice to produce gas and gather it at a common point for dehydration prior to discharge into the transmission system.1,3,11,16,17 However, higher transmission line pressures, long gathering lines and relatively low ground temperatures have made it necessary to dehydrate gas at. or near. individual. wells in order to gather gas from a number of newly developed fields without unusual difficulty. Where gas has been dehydrated at pressures ranging from 300 to 800 psi in the past. future trends indicate that these processes may be operated at pressures as high as 2,000 psi. Economics of gas dehydration are of great importance, partitularly where facilities must he provided to process relatively small quantities of gas, such as the production from an individual well. Although the adsorption of water vapor from gas on a granular sorbent material such as activated bauxite, activated alumina, or one of the alumina-silica gels is highly effective and produces virtually "bone dry" gas, the cost of a small unit of this type is substantially greater than that of an absorption process which, through proper selection of the absorbing liquid, will dehydrate the gas sufficiently to meet pipe line specifications. For this reason, a great deal of emphacis has been placed on the development of small, inexpensive dehydration units8,24 and the search for more effective absorb. ent liquids has been intensified. A wide variety of methods for dehydrating gas are known' and many of these have been used in industry. Earlier applications of the absorption process employed concentrated solutions of calcium and lithium chlorides as the absorbent. The severe corrosion problems inherent in handling these solutions and the relatively small dew point depressions obtained caused early abandonment in favor of, or conversion to. diethylene glycol when it was found that aqueous solutions of this organic liquid were more hygroscopic than the brines and were non-corrosive. Processes employing diethylene glycol-water solutions are widely used for gas dehydration at pressures ranging as high as 1,200 psi.13,14,15 At nominal pressures a dew point depression of 45° to 50°F may be be and the data of Russell et al." indicate that a minimum dew point is obtained from the effluent gas at a pressure of approximately 1,200 psi when the gas is in equilibrium contact with a 95 per cent by weight diethylene glycol solution. In a number of instances the dew point depression obtained with diethylene glycol-water solutions is not sufficient to produce a specification product without cooling the inlet gas. In a recent search for a better absorhent, triethylene glycol was used in a small commercial dehydration unit and subjected to rather exhaustive field tests.' The data obtained were encouraging and indicated that, at pressures ranging from 300 to 500 psi, triethylene glycol porduced a substantially greater dew point depression than diethylene glycol. These results led to an investigation of the system natural gas-water-triethylene glycol in an effort to obtain vapor-liquid equilibrium data, to determine pressure limitations, and to develop other data pertinent to the design of gas dehydration processes. A review of the literature has failed to reveal any data which permit reasonably accurate calculation of the vapor-liquid equilibrium conditions for a solution of water and triethylene glycol in contact with natural gas at high pressure. Since these constituents form a non-ideal system, the Poynting equation18,21 or the usual combination of Raoult's and Dalton's laws19,20,22 would not be valid. Correction of Raoult's and Dalton's laws by the use of activity coefficients2' is not feasible for available data are insufficient for the prediction of the actual increase in the ratio of the activity of one component in the vapor phase to its activity in the liquid. Therefore. experi-

Jan 1, 1950

By J. M. W. Mackenzie, C. J. Wood

In attempting to describe the size classification performance of a hydrocyclone, most workers have elected to use either an equilibrium orbit theory or an non-equilibrium orbit theory. The equilibrium orbit theory has been used by the majority of workers including Lilge,' Bradley; and Yoshioka and Hotta. In applying this theory, it is argued that particles in the body of a hydrocyclone attain an equilibrium radial position where the drag force on the particle resulting from the inward radial fluid velocity is balanced by the outward centrifugal force caused by the tangential component of fluid flow. When considered over the full height of the hydrocy-clone, attainment of this radial equilibrium orbit results in the particle following a conical equilibrium envelope. It is then argued that if this envelope lies outside the envelope of "zero vertical velocity," the particle will report to the underflow, while if the equilibrium envelope lies inside the envelope of "zero vertical velocity," the particle will report to the overflow or vortex finder product. The d50-sized particle which reports in equal quantities to the underflow and overflow is assumed to correspond to particles whose equilibrium envelope is coincident with the envelope of "zero vertical velocity." In considering the equilibrium orbit theory, it is apparent that the horizontal position of the particles in the feed inlet pipe should have no effect on their ultimate destination on the hydrocyclone. Each particle should attain an equilibrium position which depends on the density, size, and shape of the particle; the density and viscosity of the fluid; and the flow patterns within the hydrocy-clone. The nonequilibrium orbit or unsteady state theory has been largely developed by Rietema4 and Mizrahi.6 Mizrahi has listed four main objections to the equilibrium orbit theory. These objections center on the short residence time in the hydrocyclone, the fact that the experimental classification curve is much less sharp than is theoretically predicted, and the absence of negative efficiency conditions in hydro cyclones operating on a feed material which is much finer in size than d50. Proponents of the nonequilibrium orbit theory argue that for a particle to discharge with the underflow it must have sufficient outward radial velocity to reach the downward-flowing region close to the hydrocyclone wall in which the flow lines are parallel to the wall and the ratio of vertical to radial velocity is constant. It is then postulated that a d50 particle entering the cyclone at the center of the feed inlet will just reach this downward-flowing region as it reaches the apex. Thus for uniform distribution of particles across the feed inlet, half the d50 particles—that is, those injected in the half of the inlet area nearest the cyclone wall —will report to the underflow while those injected in the other half will not reach the downward-flowing region and will be carried inward to the center of the cyclone and thus report in the overflow. The exact thickness of the down-ward-flowing region of fluid adjacent to the outer wall of the hydrocyclone is uncertain but Mizrahi considers it to be equal to the apex radius minus the air core radius. Particles larger than d50 have a greater outward centrifugal force acting on them than the d50 particles and may reach the wall even if injected at a distance from the wall greater than Di/2 (Di is inlet diameter). Conversely, particles smaller than d50 may not reach the wall even if injected at a distance less than Di/2 from the cyclone wall. Since the equations put forward by the proponents of both theories yield approximately the same values of d50, it is not possible to decide between these theories by measurement of d50. It should be possible however to examine the theories by injecting a small stream of solids into the feed inlet of a hydrocyclone running on clear water. If the efficiency or classification curve is measured for various horizontal injection positions, then the curves should be coincident if the equilibrium orbit theory holds. If, however, the unsteady state theory describes the cyclone operation, then the classification curves should show finer d50 sizes for particles injected close to the cyclone wall. Experimental A 6-in.-diam hydrocyclone with geometry as in Figs. 1 and 2 was used. Quartz particles were injected as a 50% by wt pulp via an 1/8-in. steel probe. For each in-

Jan 1, 1971

By B. A. Wilcox, A. H. Clauer

The tensile and creep deformation characteristics of fiber reinforced composites have been studied, primarily at room temperature. The matrix was an alloy of Mg-14 wt pct Li-1 wt pct Al (LA141A alloy) and the reinforcing fiber consisted of continuous wires of a high strength precipitation hardening stainless steel (AFC-77 alloy). The ultimate tensile strength and strength-to-density ratio of composites were much improved over that of the mmix, both at room ternperatwe and up to 200°C. Creep studies at room temperature revealed logarithmic weep behavior for wires and composites and steady state creep for the nonreinforced matrix. It was concluded that creep of the fibers controlled composite creep. The instantaneous logarithmic weep rate of the composite, 6, was related to the average tensile stress on the fibers, where n = 3.4. Mg-Li alloys are the lightest structural metals commercially available, e.g., the alloy LA141A (Mg-14 wt pct Li-1 wt pct Al) is 27 pct less dense than beryllium Although Mg-Li alloys have moderate tensile strengths at normal strain rates and ambient temperature, their creep strength is relatively poor, even at room temperature. Reinforcement by fibers offers a means of increasing the tensile strength as well as overcoming the limitations of low creep strength. With a proper choice of reinforcing filament, composites could be designed with higher strength-to-density and modulus-to-density ratios than the matrix alloy. This communication reports a study on the tensile and creep characteristics of alloy LA141A reinforced with continuous wires of a high-strength precipitation hardening stainless steel (AFC-77 alloy). The matrix has a bcc structure, with possible precipitates of AlLi and MgLi2A1,3 and is ductile at room temperature Stainless steel wire was chosen as the -reinforcing filament since previous work at Battelle4 showed that a good bond between wire and matrix could be produced in this system. For all volume fractions of reinforcing wire, the theoretical composite strength-to-density ratio is greater than that of the matrix and the modulus-to-density ratio is somewhat lower than that of the matrix. EXPERIMENTAL PROCEDURES The 0.004-in. diam AFC-77 wire was obtained from two suppliers: National-Standard Co.* and Crucible 0.13 Si, 0.18 V, 0.011 P, 0.012 S, balance Fe. In the as-received condition, wires from both sources had room-temperature ultimate tensile strengths of 585,000 to 590,000 psi with approximately 2 pct total elongation and 40 pct reduction in area. Composite preparation was accomplished by the vacuum infiltration technique. This involved placing the continuous wires in a mild steel tube (1/8-in. ID), capping one end of the tube with a sheet of the matrix alloy, and evacuating the other end of the tube. When the capped end was placed in a crucible of the molten matrix alloy and held for 31/2 min at 70O°C, the liquid metal was drawn up the tube approximately 7 to 8 in. A cross-sectional view of a typical composite is shown in Fig. 1. This preparation technique promoted excellent bonding between the matrix and wires, and porosity was rarely observed. Test specimens for both creep and tension studies were prepared by machining off the steel tube. Tensile tests on the wires and composite specimens were made in an Instron using a cross-head speed of 0.01 in. per min. The composite specimens had no reduced section and were held in self-tightening grooved serrated grips. Most of the specimens broke in the effective 1-in. gage section. Even though several tests fractured in the grip section, their ultimate strengths were essentially the same as those of specimens which fractured in the gage section. Creep specimens of the composite were gripped in a similar manner, and

Jan 1, 1970

By P. Bolsaitis, L. Skolnick

A model of metallic solutions is postulated which explains the energy of formation of alloys on the basis of changes in electron density around solute and solvent atoms and changes in pairwise interactions between atoms. The model is based on the Wigner-Seitz cell model of metals, with the electronegativities of the metals as the parameter for the electron-attracting power of the constituent atoms. In contrast to models based on the description of cohesive energy in terms of pairwise interactions only, which require an empirical, adjustable correction parameter to the Berthe-lot relations in order to predict negative energies of formation, the electron cell model accounts for both negative and positive energies on the basis of parameters of the pure components. Calculated heats of mixing based on published parameters of the pure metals are found to compare favorably to experimental values, despite the absence of any adjustable parameters in the model. THE formulation of an "exact" quantum mechanical model for the energy of cohesion of metals reduces ultimately to the many-body problem and for a complete solution would require the knowledge of wave functions and energy levels of all the particles in the system. The case of alloys is further complicated by the fact that the potential fields around the constituent atoms are different and the matching of boundary conditions in terms of the resulting wave functions is still an unresolved mathematical problem. It appears that in spite of the numerous investigations that have led to an elucidation of many properties of the metallic state, the formulation of the Hume-Rothery rules in 1931 marks the lone accomplishment toward simple, qualitative prediction of the energy of formation of alloys. More recently Friedel'' and Arafa have utilized the modern concepts of the electronic structure in metals in combination with the Hume-Rothery rules to arrive at quantitative estimates of the energy of formation of alloys with low solute contents. The relative success of the Hume-Rothery rules and Friedel's and Arafa's studies encouraged broaching the subject of formulation of a model based on realistic physical parameters and of conceptual and mathematical simplicity that could be applied to alloys regardless of concentration. On the basis of the free-electron theory, the cohesive energy of pure metals can be expressed as a function of "valence" (number of free electrons per atom), lattice parameter (or density), and the ioniza-tion energy. In addition to the electronic contributions to cohesion, one has to consider the pairwise exchange interaction energy between neighboring ion cores and the contribution from van der Waals forces. The energy changes upon alloying are viewed as resulting primarily from a redistribution of electron densities around the ions (a simplification of the more basic concept of a change of the wave functions of the electrons in the presence of a perturbing potential field). In addition there is a change in the pairwise interactions between neighboring ions which is usually the only factor taken into account in commonly used adaptations of the quasichemical theory. The electronegativities of the metals forming the alloy are used as the measure of the electron-attracting power of the ions in the alloy and the difference in electronegativities as the driving force for changes in electron energy on alloying. The interplay of pairwise interactions and electronic forces results in positive or negative energies of formation of alloys. Results obtained for systems to which the free electron model is best applicable are in good agreement with experimental values. 1) COHESIVE ENERGY OF METALS IN TERMS OF THE ELECTRON CELL MODEL The simplest physical model of a metal is that of a lattice of positive charges immersed in a sea of uniform, negative charge distribution represented by the

Jan 1, 1969

By J. M. Mutmansky

Introduction Since the Hardy Cross numerical algorithm was applied to the solution of mine ventilation networks, numerous developments have taken place in ventilation network analysis procedures. The Newton-Raphson method, the linear theory method and the second-order approximation method are three of the additional approaches that have been applied. The efficiency of a ventilation network analysis procedure depends not only on the method of solving the system of equations derived from ventilation networks but also on the method of deriving the equations through selection of the meshes. This paper investigates the impacts of three mesh selection methods on the efficiencies of four ventilation network procedures. The minimum-resistance spanning tree method is the most popular procedure for selecting meshes. The shortest-path method was suggested by Epp and Fowler (1970) for improvement of the Newton-Raphson method. The minimum-resistance-path method is suggested here as the third method of selecting meshes. The effects of these three methods on the Hardy Cross method, the Newton-Raphson method, the linear theory method and the second-order approximation method are analyzed in this paper. These network analysis methods have been summarized in the paper by Kim and Mutmansky (1991). Mesh selection methods A procedure for mine ventilation network solution based on mesh equations typically consists of two steps: • the mesh selection step and • the network solution step. The mesh selection step establishes a set of independent equations to solve the network. The resulting equations are nonlinear. One method of solving nonlinear equations is to linearize the equations and iteratively solve these linear equations. The four analysis methods previously discussed in this paper use this approach. The linear equations required for solution can be written in matrix form as: P•dQ = dF (1) where P is the pseudo-resistance matrix, Q is the quantity matrix, and F is the Jacobian matrix (Kim and Mutmansky, 1991). The efficiency of the solution method depends on the characteristics of the P matrix, which in turn depend on the method of selecting meshes. To understand the impacts of the mesh selection methods on the efficiency of the ventilation network analysis procedures, the characteristics of the P matrix must be understood first. The diagonal elements of the P matrix, m in number, are the sums of the pseudo-resistances of the branches contained in the m meshes necessary for solution. The off-diagonal elements are the sums of the pseudo-resistances of the branches shared by two meshes. For example, P12 (first row, second column element of the P matrix) is the sum of the pseudo-resistances of the branches common to mesh 1 and mesh 2. When solving the system of equations expressed in Eq. (1), three of the iterative procedures (the Newton-Raphson, the linear theory and the second-order approximation methods) use the direct factorization method (Burden and Faires, 1985) on the P matrix. When the direct factorization method is used, the computational efficiency is enhanced by larger diagonal elements and a sparser P matrix. Generally, the sparsity of the P matrix is more important than the size of the diagonal elements. There is no known mathematical method of predicting the efficiency of these procedures, but heuristic methods can be used to study the efficiency. The Hardy Cross algorithm applies the Gauss-Seidel method of splitting the P matrix and applies the Newton-Raphson procedure. The efficiency of the Hardy Cross method depends on the spectral radius of the matrix[[D-L]-1U], where D is the diagonal, L is the lower triangle and U is the upper triangle of the P matrix for the Newton-Raphson method (Ortega, 1972). The smaller the value of the spectral radius, the faster the convergence. As with the other three methods, larger diagonal elements and a sparser matrix aid in faster convergence. With the Hardy Cross method, however, the size of the diagonal elements is more important than the sparsity of the matrix. Remembering that each of the diagonal elements of the P matrix is the sum of the pseudo-resistances of the branches in a mesh and that each off-diagonal element is the sum of the pseudo-resistances of the branches shared by two different meshes, the following strategies can be used: • Avoid having branches with larger resistance values shared by multiple meshes. This increases the size of the diagonal elements and reduces the chance of off-diagonal elements being large.

Jan 1, 1993

By Chang Wei, Zhigan Deng, Jiqiang Liao, Minting Li, Hongsheng Xu, Yan Song, Cunxiong Li, Xingbin Li

"Abstract: Direct ?otation of oxidized zinc-lead ore is characterized by recovery of zinc and lead only around 55% and 50%, respectively. Mineralogical analysis shows that the sample used in the present study is a carbonate hosted zinc-lead ore, with a zinc and lead carbonate content that accounts for 80.14% and 75.63% of the total minerals, respectively. The carbonate hosted zinc-lead ore was hydrothermally sulfidized with elemental sufur and the experimental data indicated that under the conditions employed up to 75% zinc and 82% lead sulfidation extent were achieved. As a result of pre-sulfidation followed by flotation, the recoveries of zinc and lead into flotation concentrate were over 90%. A flotation concentrate was obtained with 52% Zn and 37% Pb from the materials which was treated by sulfidation.IntroductionSulfide ores are the primary source of zinc and lead, and they are becoming depleted; thus, metallurgical investigators are interested in using abundant oxidized zinc-lead ore reserves. The high-grade zinc-lead oxidized ore, which normally has a zinc content higher than 15%, can be disposed of by acid leaching and electrolysis. However, the low-grade ore, which has a zinc content lower than 10%, is difficult to smelt with pyrometallurgy and hydrometallurgy, and the processes are very complicated and expensive in terms of production flow and energy consumption. Therefore, making the low-grade oxidized zinc-lead ore more beneficial has become more important in recent years. Flotation is the most common process, and the primary method of recovering zinc and lead from sulfide or oxide minerals. It is well known that there is a difference between sulfurized and oxidized minerals regarding their separation by flotation. Flotation of zinc and lead oxidized minerals is extremely complex because of the similarities in the physicochemical and surface chemistry of the constituent minerals. There are no known direct-acting collectors capable of producing single metal concentrates [1-3]."

Jan 1, 2012

By Louis Schaarschmidt, Helmut Mischo, Ibrahim Alsalamin

In order to store high-level radioactive waste underground, the German repository concept considers clay, crystalline and salt formations as suitable host rock materials (National Citizens’ Oversight Committee, 2024). The current research projects of the Chair Underground Mining Methods at TUBAF (Technical University Bergakademie Freiberg) in nuclear waste repositories mainly focus on storage within salt formations. In this scenario, the high-level radioactive waste is supposed to be packed into specifically designed containers and then transported underground and emplaced in horizontal storage drifts. The residual temperature of the radioactive waste leads to the question if there are optimization possibilities for waste handling, the storage and the long-term emplacement of such high temperature level waste. A deeper understanding of the heat transmission from the container into the host rock might lead both towards possibly shorter surface interim storage times as well as size optimization possibilities of the repository itself. TUBAF has conducted research that successfully proved that an optimized container positioning yields more favorable thermal patterns and can be achieved with conventional mining equipment.

Feb 1, 2025

By AIME AIME

FOR constructive research in copper and brass and other non-ferrous metals and their alloys, and his contributions to the establishment of the present accepted high standards of quality William H. Bassett, technical superintendent and metallurgist of the American Brass Co., has been awarded the James Douglas Gold Medal for 1925. Mr. Bassett was born in New Bedford, Mass., on March 7, 1868, and was graduated in chemistry at the - Massachusetts Institute of Technology in 1891. In the same year he went to Pope's Island Manufacturing Co., at New Bedford, as chemist where he remained until 1895, where he became a teacher in chemistry at the Swain Free School, which position he retained until 1900. He then became chemist for the New Jersey Zinc Co., at Newark N. J., and in 1902 went to the Coe Brass branch at Torrington, Conn., as Chemist. In 1903 he became chief chemist and metallurgist and since 1912 has been technical superintendent and metallurgist of the American Brass Co., with head- quarters at Waterbury, Conn.

Jan 1, 1924

By D. R. Parrish, K. W. Beaver, H. W. Wood, R. W. Rausch

A pilot test of forward combustion in the Shannon pool, Salt Creek field, Wyo., is described. The Shannon sand, 950-ft deep, contains a heavy (25" API), viscous (76 cp) oil. Natural reservoir energy is limited. Primary production, intermittent since 1889, recovered only about 2 per cent of the oil in place. The field is operated by Pan American Petroleum Corp. for the Midwest Oil Corp., the owner. The original pilot was a 1.32-acre five-spot. The expanded pilot has eight producing wells surrounding a roughly triangular area of about five acres with the injection well near the center. A control or comparison well was also recompleted in another part of the field. Operation of the pilot has been little different front an ordinary gas drive. Little special equipment was found to be absolutely necessary. Except for some use of a temperature-resistant cement, all wells were conventionally completed. In spite of poor oxygen consumption, the over-all performance of the pilot has been good. Total oil recovery to June 1, 1961, was 73,971 bbl. The wells of the original pilot alone had produced about 24,000 bbl, equivalent to 50 per cent of the oil in place, when fire breakthrough at the first well occurred. These wells have now produced oil equivalent to more than 74 per cent of the oil in place in the original pilot area and production is continuing. It appears that ultimate recovery will approach theoretical maximums before the wells must be abandoned. Performance of the pilot has been encouraging, and expansion to a fieldwide combustion operation is being investigated. INTRODUCTION The results of both laboratory investigations and field tests of underground combustion have been reported previously.' However, most of the field tests were primarily experimental. More information and experience are needed before forward-combustion operations can be engineered with confidence. The purpose of this paper is to present the results of a successful pilot test of forward combustion. These re- sults should increase confidence in forward combustion as a practical method for commercial oil recovery. HISTORY OF THE SHANNON POOL The Shannon pool is located on the north end of the Salt Creek field in Natrona County, Wyo. It is approximately 50-miles north of the city of Casper. The Shannon pool's3 discovery well was completed in 1889, making this one of the oldest oil fields in the Rocky Mountain region. Three more wells were drilled in 1890. First production was hauled in wooden barrels by horse and wagon to the railroad in Casper. In 1894 a small refinery, the first in Wyoming, was built in Casper to process the Shannon crude. In the following years the field changed hands several times. It appears that each new owner did some development drilling as several wells were completed in each of the years 1895, 1902, 1905 and 1912, with negligible development in the intervening years. Forty-eight wells were drilled in this period, but many were later abandoned. Discovery of the more prolific Salt Creek field proper ultimately forced suspension of operations at the Shannon pool. After 1915 there was only sporadic production, mostly to supply cheap boiler fuel to drilling rigs in the Salt Creek field. But even this was discontinued in 1931. Since then the pool had been dormant until the recent operations, which are the subject of this paper. The Shannon pool is now owned by the Midwest Oil Corp. Field operations are conducted for Midwest by Pan American Petroleum Corp. THE RESERVOIR Fig. 1 is a map showing subsurface contours of the Shannon pool. The reservoir is on a nose of the Salt Creek anticline dipping to the north at about 500 ft/mile. The trap is provided by a shallow fault on the updip side of the productive area. The downdip limits are bounded by water, but this water has not provided an effective source of reservoir energy. The Shannon sand outcrops at many places in the immediate vicinity, providing good surface indications of the Salt Creek anticline. At the Shannon pool the sand has been lowered by faulting and is overlain by about 900 ft of shale and other sands. The Shannon sand consists of two members. The upper, a water sand, is about 40-ft thick and is separated from the lower member by several feet of sandy shale. The oil pay occurs in the lower mem-

By J. D. Mote, J. E. Dorn

This investigation was undertaken to study the effects of piledup arrays of dislocations on inducing slip, twinning, and fracturing in magnesium bicrystals. A series of variously oriented bicrystals of magnesium having a vertical grain boundary were prepared and tested in tension. It was found that piled-up arrays of dislocations at the grain boundary could, under appropriate conditions, induce slip, twinning- and cracking. The results that were obtained substantiate, at least qualitatively, the general dislocation mechanism for transmission of strain across grain boundaries and the Petch-Stroh concept of fracturing. WHEREAS single crystals of magnesium generally exhibit extensive deformation, coarse-grained poly-crystalline magnesium at subatmospheric temperatures fractures after a few percent elongation.' Although a small amount of ductility is obtained, several features of this fracturing are characteristic of typical brittle behavior. Over a rather broad temperature range the fracture stress is insensitive to the test temperature and the fracture stress increases linearly with the reciprocal of the square root of the mean grain diameter. The course of fracturing is predominantly intergranular, but small fragments of adjacent grains frequently adhere to the fractured surface.2 The brittle behavior of polycrystalline magnesium is attributable to the limited number of facile deformation mechanisms it exhibits at low temperatures. For a general deformation of a randomly oriented polycrystalline aggregate, each grain must exhibit at least five independent mechanisms of deformation to permit accommodation of the imposed deformation from grain to grain.= Although minor amounts of prismatic slip occur in corners of grains where stress concentrations are known to be high, glide in polycrystalline magnesium at low temperatures takes place almost exclusively by basal slip.' The common type of twinning, which takes place on the (1012) pyramidal planes, can under the most favorable orientations, lead to a. strain of only 6.9 pet; the contribution of twinning to the tensile strain would indeed be much less than this in a randomly oriented polycrystalline aggregate of magnesium. Since the three mechanisms of basal slip are coplanar, they are equivalent to only two independent mechanisms, a number insufficient for a general deformation. Consequently, once the permissible twinning has taken place in conjunction with basal slip, no further plastic deformation is possible because of interference to slip at the boundaries of dissimilarly oriented grains. At this stage brittle fracturing takes place due to high stress concentrations at the juncture of slip bands with the grain boundaries; the predominance of intergranular fracturing in magnesium, in preference to transcrystalline fracturing which is prevalent in zinc, has not yet been rationalized. A more atomistic description of the plastic behavior and fracture characteristics of magnesium follows from the analyses made by stroh4 on the stresses induced by piledup arrays of dislocations. Slip first takes place by dislocation motion in the most favorably oriented grains. As the dislocations approach the boundary of a dissimilarly oriented adjacent grain they begin to form an array of dislocations with its attendant stress field. Piledup arrays of screw and edge dislocations introduce high localized shear stresses at the spur of the array; piledup arrays of edge dislocations also induce high tensile stresses localized in the vicinity of the grain boundary. Whereas the shear stresses can induce slip to take place, the tensile stresses, if sufficiently high, can cause fracturing. The localized shear stress will be relieved if sufficient numbers of mechanisms of deformation become operative in the original and the adjacent grain to permit accommodation of the dislocations in the grain boundary. In this event a ductile behavior will be obtained. But if the number of deformation mechanisms is insufficient for complete migration of dislocation arrays into the grain boundary, the tensile stresses due to the edge components of piledup dislocation arrays will continue to increase with increasing applied stress until fracturing takes place. Whereas face-centered-cubic metals have a sufficient number of mechanisms of slip for accommodation of dislocations in their grain boundaries to exhibit ductile behavior, hexagonal-close-packed metals, in general, do not. Consequently, hexagonal-close-packed metals are usually brittle except when conditions such as alloying or temperature permit facile slip by a number of mechanisms. The arguments presented above suggest that the mechanical behavior of magnesium depends on whether or not dislocation arrays in adjacent grains can enter the grain boundary. When such accommodation is possible, ductile behavior is expected; but when such accommodation is impossible, fracturing will ensue. To further test the validity of these arguments it was considered advisable to study the

Jan 1, 1961

Jan 1, 1963

By W Schauenburg

The increasing problems associated with the disposal of waste and the potential for use of by-products as underground filling material is a subject which is relevant not only to the coal-mining industry. The progressive scarcity of surface disposal facilities for by-products and waste has now become a problem in all sectors - not only for the mining industry. The considerable capacity offered by underground cavities which exists in various mining branches present an extremely promising potential in this context. The backfill process for coal mining developed by DMT in co-operation with Ruhrkohle AG make use of the cavities which are offered by the extraction of coal. It consists of several stages: The fine-grained by-products, such as sludge, filter cakes, fine refuse, ash and flue-gas cleaning residues are processed on the basis of specified formulations in metering, blending and pump facilities on the surface to produce pumpable pastes with precisely defined flow characteristics. On Walsum Colliery of Ruhrkohle AG up to 200 m3/h stowing paste is conveyed into the mine in pipes with diameter of 200 mm (8"). The delivery pressure of the pump operating on surface in conjunction with the hydrostatic pressure of the shaft pipe - amounting in total to as much as 25 MPa - makes it possible to convey the stowing material for a distance 12000 m underground up to the workings without any need for additional booster pumps. Via a pipe installed in the face, the paste is pressurised into the cavities in the specially fragmented rock in the mined-out zone well behind the support. Consistent use of stowage of caved-in goafs makes it possible to reduce surface settlement above the workings. Fires in the stowed rock are either smothered or completely prevented thanks to the exceptional air-tightness in the caved goaf and the cooling effects of the slurry stowage. The reduced danger of fire, the preventation of air-leakage and the positive effects on gas emission from the coal improve safety in the workings.

Jan 1, 1998

By W. Blake, J. Whyatt

Sixty years of rock bursting in the Coeur d'Alene district has taught painful lessons and led to a number of practical advances in controlling rock-burst hazards. This paper summarizes these lessons, concentrating on practical measures that have been successfully adopted to reduce hazards. These lessons are explained in the context of district mining history and current understanding of rock-burst phenomena. Overall, the paper provides the practicing mine engineer with an appreciation of rock-burst hazards and an overview of practical measures that can be used to control these hazards in the context of Coeur d'Alene district experience.

Jan 1, 2003