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By C. F. Mabery

So far as the elementary composition of petroleum is known, it may be briefly stated. Petroleum consists principally of a few series of hydrocarbons, with admixtures of sulfur, nitrogen, and oxygen derivatives in comparatively minute proportions, which may be regarded as impurities to be removed in the preparation of commercial products. But as each series is represented by many homologs, in the aggregate, crude petroleum is an extremely complex mixture of hydrocarbons and their derivatives. In part, these hydrocarbons individually conform in structure to the system of synthetic hydrocarbons whose structure is well defined and represented by the typical series CnH2n, + 2, C.H2n, the series CnH2n,-2, CnH2,-a, the members of which have not been sufficiently studied to establish their structure, and the series CnHz,e composed of the aromatic group, benzene and its homologs. Hydrocarbons of greater density contained in the portions of petroleum that cannot be distilled without decomposition doubtless have less hydrogen than is represented by these formulas. Since to every hydrocarbon there is a definite temperature, even in vacuum, at which its constituent carbon and hydrogen atoms fall apart, and since for the heavier bodies this temperature is not much above 360" C. in vacuum, it is evident that some other method than distillation must be devised for their separation if anything further is to be learned concerning their individual constitution. Classification of Petroleums There is such a wide variation in the composition of petroleum from Merent fields, it would seem possible to make a classification on this basis were it not that no single variety is entirely free from hydrocarbons contained in others. Such a classification has been suggested of the exceptionally pure Pennsylvania petroleum, the sulfur oil from Trenton limestone and other sources, the California oil with its large amount of nitrogen (quinoline) derivatives, and the Russian oil, composed chiefly of the naphthene hydrocarbons.' A commercial distinction is made

Jan 1, 1921

By Jack C. White

The purpose of this Bureau of Mines work was to develop information useful in improving copper recovery during copper milling operations. Eleven copper mill tailings from the Western United States were subjected to froth flotation and cyanide leaching to provide an experimental basis for comparing their beneficiation response. Recoveries in flotation concentrates made from mill tailings ranged from 65 to 15 percent, at copper grades of 13 and 2.2 percent, respectively. Liberated copper sulfide minerals present in two samples were readily recovered by laboratory froth flotation. Nine of the samples were less amenable to froth flotation because of physical locking between copper sulfide minerals and gangue. Correlations among tailings indicated that recovery of sulfide copper by flotation was directly related to the sulfide copper content. Empirical equations derived from flotation data provided average values for unrecoverable copper and for recovery efficiency. Flotation response of copper mill tailings may be predicted from the equations. Data from cyanide leaching provides an equation describing the limiting high values for removal of copper by this method.

Jan 1, 1974

By H. Ries

THE term "clay" is applied usually to certain earthy rocks whose most prominent property is that of plasticity when wet. This permits them to be molded into almost any shape, which they retain when dry. Furthermore, they harden under fire. Clays contain hydrous aluminum silicates-the clay minerals-in appreciable amounts, but aside from this a number of other mineral grains, particularly quartz, may be present. Texturally clays are fine grained, and the so-called true clay particles are usually under 2µ in diameter. MINERALS IN CLAY Certain hydrous aluminum silicates that predominate in many clays are known as the clay minerals"." and are grouped by Kerr41 as follows: [ ] The kaolin group has been found to consist of a number of minerals with the same chemical composition but different crystalline structures .83 Kaolinite is commonly formed by the weathering of other mineral particles, particularly feldspar, but some deposits, like those in Cornwall, England,36 and others in the Washington-Idaho district, are thought by some to be of hydrothermal origin. Dickite and nacrite are thought to be due usually to waters of

Jan 1, 1949

By Charles H. Behre

UNDER the caption "fault," geologists intend to include all mass movements of solid rocks over adjacent rock masses. When these are studied long after their origin, however, circumstances make it possible to recognize as "fault" only formations showing clear evidence of actual movement of one side with respect to the other. Necessarily the chief evidence consists of the offset of a vein, bed, or other key structure. Planes of movement parallel to the bedding, or nearly so, are recognized with difficulty or are overlooked and hence many important faults are wholly unrecorded. Indeed, among standard American references on structural geology, one alone emphasizes the importance of bedding-plane movements and that one only briefly1. For some time the writer, cognizant of this difficulty, has paid special attention to such movements, both as observed in the field and as recorded in the literature. It is believed that enough data are now at hand to justify a short discussion. Its purposes are fivefold. It is desired first to briefly classify and describe at least the more common kinds of bedding-plane faults, and second, to examine the causes and manner of their formation, at least in instances where the subject has not yet been well covered by other investigators. Third, certain by-products of bedding- lane movements are of such conspicuous importance to the economic geologist and mining engineer as to merit mention. Fourth, concrete illustrations should be placed before the reader in order to lend reality and to furnish a basis of comparison with his experience; such illustrations will necessarily be scattered through the text of this paper. They are only in part from the writer's own field observations. The fifth and prime objective of this paper is to direct attention to the great importance of movements on the bedding planes, in the hope that the recognition of such movements and their significance may simplify mining problems.

Jan 1, 1937

By M. Vasudevan

In sulfide mineral flotation, the efficiency of separation is severely affected by the presence of non-sulfide gangue minerals, such as altered silicates and serpentines. Although this is an acknowledged fact, most studies in mineral processing have focused on value minerals, and studies on gangue minerals affecting flotation performance are quite rare, and even those that do are limited in scope. This paper is an attempt to highlight the use of grade-recovery curves in studying the effects of gangue minerals. Specifically, we present the flotation response of problematic Ni and Cu ores which show highly uncharacteristic but similar grade-recovery characteristics despite the very different mineralogy and try to understand this behavior and the underlying mechanism. Finally, we propose chemical modifiers as solutions to overcome the detrimental effects of these gangue minerals and improve efficiency of flotation performance. Keywords: Non-sulfide gangue, grade-recovery, sulfide minerals, serpentines, talc, shale, slimes, spiking, modifiers

Sep 1, 2012

By L. M. Pidgeon, P. G. Thornhill

A LTHOUGH a considerable number of experi--ti mental investigations dealing with the roasting of sulfide minerals have been reported in the past,'"" the behavior of the single roasting particle does not appear to have received the attention it perhaps deserves. This is understandable in that the natural sulfide counterpart of the slab or sheet of metal normally used in high temperature oxidation studies is difficult to obtain and prepare, and is, in most cases, virtually impossible to maintain in one piece at roasting temperatures. The employment, on the other hand, of static aggregations of small particles in masses great enough to permit evaluation of the roasting reactions by means of thermobalances or gas analyses introduces other complications, such as localized overheating, sintering, and variable gas-solid contact. In this investigation a compromise between the above extremes was attempted. Closely sized (e.g., 30 to 40 mesh) particles of natural sulfide minerals were isothermally roasted, out of contact with one another, in an air-swept system. The progress of the roasting reactions was followed by examination in polished section of the treated particles and by X-ray and chemical analysis of their residual sulfide kernels. In this way some conclusions respecting the mechanism of roasting reactions were drawn. Roasting Furnace—The vertical tube furnace used for roasting the sulfide particles had a heated zone 10 1/2 in. long in which four retractable light gage stainless steel trays were suspended. Each tray, and an accompanying baffle, was mounted on a 2 in. lengtn of 3/8 in. stainless steel tubing. These assemblies were axially suspended on a 30 in. length of ¼ in. stainless tubing, by means of which they could be lifted from the hot zone to a water-cooled brass chamber at the top of the furnace. Since each tray unit could slide freely on the 30 in. tube, any desired number of the trays could be retained in the cooling chamber by the manipulation of a horizontal plunger during a momentary withdrawal of the four trays from the hot zone. Although three heating coils, each equipped with variable external resistance, were employed, it was found impossible to avoid a drop of 10o to 15oC between the temperature at the top tray and that of the lower three. Consequently, only the bottom three trays were used for roasting. Temperature readings inside the furnace were made by means of a thermocouple inserted down the tray support tube at tray levels, and a separate thermocouple, inserted adjacent to the middle heating coil, was connected to a Micromax temperature control unit. Experimental Method—The sulfide minerals were obtained in a form as free as possible from gangue and contaminating sulfides, and were crushed and screened to the required particle size range. The tray assembly was kept inside the furnace during the heating-up period and, when a steady temperature had been reached, the trays were withdrawn. Each tray was sprinkled with from 200 to 500 mg of the sulfide grains, and the assembly was lowered into the furnace without delay in order to minimize the time required to achieve the operating temperature. The furnace top was then clamped into position and the thermocouple inserted down the center tube to the required level. It was found that, when this procedure was used, the trays achieved their former temperature within 2 min, after which time the flow of dry air was begun at a rate of 1 liter per min, and timing of the run was started. At the required intervals of time the trays were successively withdrawn from the hot zone and stored in the cooling chamber by means of the retention plunger. On completion of the run the treated particles were removed from the trays to be set aside for examination. The roasted particles were mounted in Lucite on a Buehler press Operating at a temperature of 140°C

Jan 1, 1958

By J. H. Wernick, D. Dorsi, K. E. Benson

A LTHOUGH a considerable number of experi--ti mental investigations dealing with the roasting of sulfide minerals have been reported in the past,'"" the behavior of the single roasting particle does not appear to have received the attention it perhaps deserves. This is understandable in that the natural sulfide counterpart of the slab or sheet of metal normally used in high temperature oxidation studies is difficult to obtain and prepare, and is, in most cases, virtually impossible to maintain in one piece at roasting temperatures. The employment, on the other hand, of static aggregations of small particles in masses great enough to permit evaluation of the roasting reactions by means of thermobalances or gas analyses introduces other complications, such as localized overheating, sintering, and variable gas-solid contact. In this investigation a compromise between the above extremes was attempted. Closely sized (e.g., 30 to 40 mesh) particles of natural sulfide minerals were isothermally roasted, out of contact with one another, in an air-swept system. The progress of the roasting reactions was followed by examination in polished section of the treated particles and by X-ray and chemical analysis of their residual sulfide kernels. In this way some conclusions respecting the mechanism of roasting reactions were drawn. Roasting Furnace—The vertical tube furnace used for roasting the sulfide particles had a heated zone 10 1/2 in. long in which four retractable light gage stainless steel trays were suspended. Each tray, and an accompanying baffle, was mounted on a 2 in. iength of 3/8 in. stainless steel tubing. These assemblies were axially suspended on a 30 in. length of in. stainless tubing, by means of which they could be lifted from the hot zone to a water-cooled brass chamber at the top of the furnace. Since each tray unit could slide freely on the 30 in. tube, any desired number of the trays could be retained in the cooling chamber by the manipulation of a horizontal plunger during a momentary withdrawal of the four trays from the hot zone. Although three heating coils, each equipped with variable external resistance, were employed, it was found impossible to avoid a drop of 10O to 15OC between the temperature at the top tray and that of the lower three. Consequently, only the bottom three trays were used for roasting. Temperature readings inside the furnace were made by means of a thermocouple inserted down the tray support tube at tray levels, and a separate thermocouple, inserted adjacent to the middle heating coil, was connected to a Micromax temperature control unit. Experimental Method—The sulfide minerals were obtained in a form as free as possible from gangue and contaminating sulfides, and were crushed and screened to the required particle size range. The tray assembly was kept inside the furnace during the heating-up period and, when a steady temperature had been reached, the trays were withdrawn. Each tray was sprinkled with from 200 to 500 mg of the sulfide grains, and the assembly was lowered into the furnace without delay in order to minimize the time required to achieve the operating temperature. The furnace top was then clamped into position and the thermocouple inserted down the center tube to the required level. It was found that, when this procedure was used, the trays achieved their former temperature within 2 min, after which time the flow of dry air was begun at a rate of 1 liter per min, and timing of the run was started. At the required intervals of time the trays were successively withdrawn from the hot zone and stored in the cooling chamber by means of the retention plunger. On completion of the run the treated particles were removed from the trays to be set aside for examination. The roasted particles were mounted in Lucite on a Buehler press operating at a temperature of 146°C

Jan 1, 1958

By C. Blawert

In spite of various corrosion studies on HPDC AZ91, there is no clear indication which microstructure gives the best corrosion performance. The skin with its fine microstructure is sometimes reported to have the best corrosion resistance, but there is no clear definition of the skin. If the skin is the outermost part of the casting and nothing is removed from it, then it is contaminated and the corrosion resistance is low. If the outermost skin is removed (about 25 µm) then a better corrosion resistance can be obtained. However this does not automatically mean that there is no other region in the bulk of the casting which could have a similar or even better corrosion resistance. Indeed, the corrosion measurements including potentiodynamic polarization and long term electrochemical impedance spectroscopy (EIS) revealed a lower corrosion resistance of the original as-cast skin about 100 pm thick. The thickness of this region is more or less independent from the thickness of the casting section. The surface region is free from any dendritic grain growth which influences the amount and distribution of the 13-phase and therefore the distribution of the most important alloying element Al. This could explain the different corrosion behavior. Further reason can be found in the enrichment of some impurities such as Fe in the near surface.

Jan 1, 2006

By George E. Niewiadomski

The exposure of miners to radon gas and its airborne daughter products is a serious health problem which has long been recognized in the uranium mining industry. The association of high exposure to alpha particle emitters with incidence of lung cancer is well established. There continues to be a pressing need to reduce and eventually eliminate the high incidence of occupational lung cancer among uranium miners through the development of new and improved measurement and control technologies. This paper highlights the current efforts of the Bureau of Mines radiation hazards research program. It is aimed at obtaining a fundamental understanding of the behavior and transport of radon and radon daughters, developing more accurate and reliable instruments and measurement methods and developing cost-effective control techniques. Also discussed are the most recent accomplishments and the future research plans of the program.

Jan 1, 1981

Wabush Mines is the largest single supplier of iron ore to the Canadian steel industry, with 42% of its 6 million tpy of iron ore production going to the company's two Canadian owners-The Steel Co. of Canada and Dominion Foundries and Steel Ltd. Six other companies hold interests in Wabush Iron Co. Ltd. These are Lykes-Youngstown, Inland Steel Co., Intrerlake Steel Corp., Wheeling-Pittsburgh Steel Co., Finsider of Italy and Pickands Mather & Co. Field work on Wabush began in mid-1957 when a long-range program of economic, geologic, and metallurgical investigations started. This work was followed in 1959 by the construction of a temporary camp and a 700-tpd pilot plant. At the same time, work was also started on a 38-mi railway connection to Ross Bay, Newfoundland.

Jan 1, 1970

By R. M. Porter

The Sullivan mine of Consolidated Mining and Smelting Co. of Canada Ltd. is located one mile west of Kimberley. With its daily production of 10,000 tons, the mine is the largest in British Columbia and one of the outstanding mines of the world. The Sullivan orebody dips from nearly horizontal to 45". The ore zone is a bedded replacement de- posit in argillite with a width varying from a few inches up to 300 ft. The main sulfide minerals are pyrrhotite, pyrite, galena, and sphalerite. The chief metals produced are lead and zinc, with less important qualities of iron, silver, tin, antimony, bismuth, cadmium, indium and sulfur.

Jan 12, 1963

By R. Hemp

This paper describes work carried out to obtain a heat balance in the B3 shaft longwall stope at Blyvooruitzicht gold mine. Recordings were made of the temperature of the air and chilled water entering and leaving the section during three periods, August 1 September 1977, November 1 December 1977 and March 1978. These recordings, together with numerous other measurements were used to determine the rate at which heat was being removed from the section by the various fluids flowing through the section. The rate at which heat was entering the section was then calculated, by considering each source in turn. These two sets of figures made it possible to draw up a heat balance, and also obviously gave vital information on the magnitudes of the various heat sources and on the methods used to remove heat. In general reasonable heat balances were obtained, the errors being in the range -6 per cent to +22 per cent.

Jan 1, 1980

Just three years after researchers announced its development, Dravo is putting the finishing touches on a new $60-million Thiosorhic lime mine/kiln complex near Maysville, Ky. Electric utilities in western Pennsylvania and Ohio have already signed long-term contracts for over three-quarters of the projected 907 000-t/v (1-million-stpy) production. Thiosorbic lime, a flue gas desulfurizing agent, proved in industrial testing that at high emission levels (greater than 3000ppm SO2) it could be twice as effective in SO2 capture as conventional lime, while eliminating the major problem of scaling and plugging of scrubber equipment.

Jan 4, 1977

All coal preparation unit operations in which fine coal is handled depend to some extent on wettability of coal surface by water. The wetting results from interactions between the coal surface and water molecules that are determined by the composition of coal matrix (interrelated with coal rank) and heterogeneous constituents such as oxygen functional groups, mineral impurities and pores. The contact angle of water on an unoxidized, homogeneous coal hydrocarbon matrix is calculated to be 100o, and much lower values measured on real coal specimens result from contributions from the heterogeneous constituents. While the effect of wettability is critical in flotation and oil agglomeration, suppression of respirable dust, and coal water fuels, it has been shown to play a significant role also in coal flocculation with semi-hydrophobic and totally hydrophobic flocculants.

Jan 1, 1995

By Collin Stewart, Greg Hunt, Christopher Mark

Bowie Resources maintains one of the most pro-active ground control programs in the U.S. mining industry today. Its guiding philosophy is that everyone in the organization, from the miners at the face all the way through the top management, are involved in ground control. Some of the unique elements of the Bowie ground control program include: • Roof bolt operators log the stratigraphy of test holes in nearly every cut. These “lith-graphs” are used by section foremen to determine the need for additional roof support, and they are entered into the geologic data base for use in geologic modeling and mapping. • Underground core drilling is conducted to obtain data for CMRR and stability maps. • Weekly “Quality” meetings, involving mine management and technical staff, are held to ensure that ground control information is integrated into production operations. The paper will describe the program in detail, discussing the involvement of roof bolters, section foremen, surveyors, technical staff, and production managers. It will also show how the program has contributed to the mine planning process. Case histories of successful ground control interventions will be discussed.

By Earle E. Schumacher

THE elements silicon and germanium are not metals within the usual, intuitive association of the word, nor are they so within a stricter definition based on the electronic binding. Two properties associated with metals are plasticity and high electrical conductivity. These elements crystallize in the diamond cubic structure, an arrangement apparently not very favorable to slip, and are therefore brittle rather than ductile. Their electrical conductivity is not like that of metals the atoms are locked together by the covalent bond, which in pure and perfectly arranged material leaves but few electrons free to act as electrical carriers.† In further contrast to metals, their electrical conductivity can be greatly increased by raising the temperature. Yet silicon and germanium are not ideally nonmetallic. They are hard, solid, and possess a metallic luster. They exhibit that peculiar brand of electrical conductivity conveniently termed "semi- conduction," wherein, as shall be seen, lies much of their importance. Both, but silicon in particular, are important components in real metallic alloys and the methods of their reduction and preparation lie clearly in the province of the metallurgist. From their duality of physical and chemical properties, silicon and germanium, along with such elements as boron, diamond, gray tin, selenium, antimony, and arsenic, are considered semimetals or metalloids. Because of their importance to metallurgy and the im-

Jan 1, 1953

By R E. Langston, S M. Gazioglu

A preconstruction inventory program was conducted to determine the existing conditions of residential, non-residential and all other structures within 2,000 feet of the blasting limits for a highway excavation site in Asheville, North Carolina. Prior to major production blasting, eleven test blasts were detonated to establish site specific propagation parameters in order to develop contours of maximum allowable explosive charge weights per delay. The method of scaling distance by the square root of charge weight per delay was utilized in developing the contours of allowable charge weights. The charge weight contours were revised during blasting operations as additional vibration data became available. The effects of blast induced vibrations on a nearby water storage reservoir, a nearby vehicular tunnel and other adjacent residential and non-residential structures were observed and monitored over a period of two years of blasting operations.

Jan 1, 1980

By G. H. Roybal, J. M. Barker

Humate mining in New Mexico is a small industry [455 m3 (16,079 cu yd) valued at $395,894 for 1983] with three mines active in 1985. Either humate (carbonaceous claystones rich in organic matter) or weathered coal ("leonardite") high in humic acid are mined. The humic acid content needed to meet consumer specifications determines which type is mined. The humate and "leonardite" now mined in New Mexico are used primarily as soil conditioners or as drilling mud additives. The potential resource for both are very extensive within the coal-bearing formations of the San Juan Basin in northwest New Mexico.

Jan 1, 1987

By David B. Dreisinger

The total pressure oxidation treatment of arsenical copper ore and concentrate from the El Indio mine of Banick Gold was tested in benchtop autoclave treatment. The concentrate oxidation typically achieved ~95% copper extraction. Copper extraction was limited by the reprecipitation of a complex precipitate containing arsenic. Gold extraction by cyanidation of the oxidation residue was around 95%. Silver extractions were less than 10% due to the formation of argentojarosite in the autoclave. The total pressure oxidation of the whole ore sample was more successful. Copper extractions of 98-99% were routine achieved. Gold extraction by cyanidation was +95%. Silver extraction could be increased to as high as 95% by using the lime boil treatment. A process flowsheet was proposed based on the results achieved. Copper recovery was proposed by direct solvent extraction and electrowinning of copper by treating the dilute solution from the autoclave discharge.

Jan 1, 1999

By John H. Stewart, Daniel R. Shawe

Major transverse structural zones in the western U.S. such as the Lewis and Clark line, Walker Lane, Texas lineament, and Colorado mineral belt, have localized important mineral districts. In Nevada and Utah the alinement of Cretaceous and Tertiary mineral deposits, such as in the Pioche, Eureka, Manhattan, and other mineral belts, may be related to similar tectonic features. All the mineral belts in Nevada and Utah have produced precious and base metals and tungsten; the Manhattan belt in addition has produced magnesite and brucite; and the Pioche belt, uranium, fluorspar, and alunite. Specific types of ore deposits seem related spatially to major belts of the Paleozoic Cordilleran geosyncline and compositionally to the intrusive bodies with which they are associated.

Jan 1, 1977