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Roasting treatments were investigated to remove arsenic from a nickel concentrate. The main arsenic minerals and their proportions in the concentrate were niccolite (NiAs)-50%, gersdorffite (NiAsS)-40% and arsenopyrite (FeAsS)-10%. Thermal analysis showed that gersdorffite and niccolite began decomposing when heated above 640 and 830°C respectively. The maximum roasting temperature was limited by agglomeration of the concentrate above 900°C. A small vibrated bed reactor was used to investigate the effects of temperature and gas flowrate, the latter to sweep away evolved arsenic. At 900°C, 24% of the original arsenic remained in the concentrate. SEM examination of the calcine showed that the residual arsenic was associated with the calcium in the gangue minerals. Additions of sulphur (either as elemental sulphur or from pyrite) facilitated the decomposition of the arsenic-containing minerals, decreased reaction with calcium in the gangue and produced calcine containing 4-6% of the original arsenic. Treatment with chlorine during roasting was effective in reducing the arsenic content to similar levels. Generation of chlorine in the bed by sulphation of CaC12 also produced encouraging results. Arsenic, Nickel Concentrate, Roasting, Chlorine, Sulphur, Gersdorffite, Niccolite

Jan 1, 2005

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from theUniversity of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

The Government Mining Engineer of South Africa has decided to legislate that Self Contained Self Rescuers (S.C.S.R.) become a mandatory piece of equipment for all those persons proceeding underground. It is envisaged that: * employees in underground coal mines will be fully equipped with S.C.S.R.s during 1988; * those persons employed in gold mines during 1988/89; and * personnel in all other mines by the end of 1990. It is the intention of this paper to discuss the introduction of these auxiliary life support systems, and to give an update on current market developments.

Jan 1, 1988

By S. Skowronski

OvErpolEd copper, as commonly defined,- is copper which has been excessively reduced during the poling period of the refining process. Owing to its porosity, such coppcr is unfit for commercial purposes. The cause of this phenomenon is undoubtedly the lack of oxides in the copper, yet this does not completely explain it. Refined copper of the same "pitch" and "set" varies considerably in oxygen contents, and analyses of overpoled bars also show similar wide differences; moreover, it is possible to melt copper in 'crucibles so as to obtain bars that are practically free from oxygen although they show a "tough pitch" and "level set" surface. Frederick Johnson advances the following theory: The regulation of the quantity of oxygen in copper is the keynote of all copper refining. It is the presence of a well defined proportion of oxygen in the form of cuprous oxide, forming a copper-cuprous oxide eutectic, which enablcs copper to be cast free from blowholes. It seems that when oxygen is present, other gases are less soluble in molten copper; when oxygen is absent, or is present in insufficient quantity, the copper dissolves other gases, such as hydrogen and carbon monoxide, which are insoluble in the copper when solid, and, being rejected during the process of solidification, causes internal porosity and external ridges and excrescences.1 The "level set" of wire bars, etc., is entirely the result of a compromise between the occluded gases and cuprous oxide. With excess of the former the metal would be "overpitch" and spongy, while an excess of the latter would result in the metal being "underpitch" and brittle.2 The result of the absorption and subsequent expulsion of reducing gases, carbon monoxide and hydrogen,' and the effect of this action on the overpoling of copper are in dispute; the literature on the subject is full of contradictory statements and will continue to be so until better analytical methods have been developed. Sulfur, however, is tangible. The refiner can see it in his button sample and consequently attributes to it any trouble that may happen during the melting of the copper.

Jan 1, 1919

By Warner N. A

There is an inherent problem in producing simultaneously lead, zinc and copper as metals in a single polymetallic smelting furnace. It relates to the condensation of lead and zinc from the gas phase under vacuum conditions such that metals in bulk form, either solid or liquid, are obtained as products rather than a fume or dust containing both metallic and non-metallic components. To understand this phenomenon, it has been necessary to establish mathematical models with computer simulation to identify the process requirements for effecting the objective of maximum bulk metal production with minimum fog formation. The theoretical framework of simultaneous heat and mass transfer involved in condensation from gas mixtures containing a non-condensable gas has been extended to the high temperature and reduced pressure conditions. These apply to new technology for polymetallic smelting now being developed in a project currently funded jointly by the Commission of the European Communities and the Mineral Industry Research Organisation. Under the right conditions it is theoretically possible to condense out both lead and zinc with minimal fume formation, but in all practical cases it is anticipated that some circulating load for reversion back to the smelter will be needed.

Jan 1, 1989

By D Craw

Quaternary warping and uplift of antiformal schist ranges in Central Otago, New Zealand, has resulted in recycling of alluvial gold from widespread, generally weakly auriferous, Miocene fluvial gravels that unconformably overlie the schist, into aprons of fan sediments along the range margins. Basement erosion during uplift has been limited and so gold input from sparse gold-bearing quartz veins in the schist has been relatively minor. In an eluvial cycle on the slopes of the ranges, chemical remobilization of gold occurs during oxidation and erosion of the Miocene sediments. The typically fine-grained (300 - 400 ¦m) gold undergoes chemical modification and grain size enhancement of up to two orders of magnitude, and much of it is redeposited in a large number of relatively small alluvial fans along the range margins. Groundwater mobility within the fans results in minor additional gold mobility and grain size enhancement. During range uplift, a small number of relatively large axial streams and rivers have developed in structural lows between growing antiformal folds. Axial streams 'gather' their flow from consequent streams draining the folds, and flow parallel to a range axis for some distance before cutting across it in an antecedent gorge. The axial streams rework alluvial fan sediments along the range margins, and transport mainly fine-grained gold from the fans along the ranges. This gold is redeposited where the axial streams emerge from a range in the neighbouring structural basin. Axial streams drain relatively large areas of range surface, and thus reconcentrate significant quantities of gold in a small number of relatively large fans and fluvial deposits. The processes of gold collection and re-deposition by axial streams are essentially the same, regardless of stream size. Coarse-grained gold produced by chemical remobilization, is more difficult to transport in fluvial systems, and thus remains in close proximity to eluvial environment where it was formed.

Jan 1, 1995

By Hatherly P, Luo X, Balusu R, Gale W

Ongoing, collaborative research between CSIRO's Exploration and Mining and Strata Control Technology has resulted in a better understanding of rock failure mechanisms around longwall extraction. Failure has occurred further ahead of the retreating face than predicted by conventional longwall geomechanics theory. In some cases significant failure has been detected several hundred metres ahead of the face position with demonstrated influences of minor geological discontinuities. Shear, rather than tensile failure has been the predominant failure mechanism in the environments monitored. Validating technologies of microseismic monitoring and new face monitoring techniques have assisted the development of predictive 2D computational modelling tools. The demonstrated 3D consequences of failure has assisted in the ongoing direction of the project to further investigate these effects.

Jan 1, 1998

By Liming Yuan

In order to reduce fire hazards caused by spontaneous combustion in longwall gob areas, a computational fluid dynamics (CFD) study is being conducted by National Institute for Occupational Safety and Health (NIOSH) to simulate the spontaneous heating of coal in longwall gob areas. A CFD model was first developed to model the spontaneous heating process in a two longwall panel district using a bleeder ventilation system with a stationary longwall face. The spontaneous heating is modeled as the low-temperature oxidation of coal in the gob using kinetic data obtained from previous laboratory-scale spontaneous combustion studies. Heat generated from coal oxidation is dissipated by convection and conduction, while oxygen and oxidation products are transported by convection and diffusion. CFD simulations were then conducted to model the spontaneous heating in longwall gob area with a bleederless ventilation system. A single longwall panel with a bleederless ventilation system was simulated. The effect of gob permeability on the spontaneous heating was also investigated.

Jan 1, 2009

By D. Letzig

Wrought magnesium alloys are of special interest as lightweight structural components as a result of their more homogeneous microstructures and improved mechanical properties compared to cast components. Extrusion as a shaping technology offers the possibility to produce a wide variety of magnesium alloy profiles. In this contribution we describe the role of extrusion parameters such as extrusion speed, ratio and temperature as well as the type of extrusion process on the microstructural development of AZ-series magnesium alloys and the resulting mechanical properties. The effect of microstructure on the tensile/compression deformation behavior of the alloys has also been investigated. Aspects of process optimization designed to overcome technical and economic limitations and thus establish magnesium alloy profiles for industrial applications will also be discussed.

Jan 1, 2006

By W. E. Uren

The Dominion Coal Board was created by Statute passed on July 17th, 1947, and was brought into effect by proclamation on October 21st, 1947. It is, consequently, a comparatively young body, having been in existence for only eighteen months. Before dealing with the constitution and duties of the Board, it may be well to answer the unspoken question of why it has been considered necessary to single out coal as one specific mineral requiring the continuous attention of a specially created permanent Board. In Canada, coal has been the neglected sister of the more spectacular minerals and it comes as a surprise co many to note that in 1948 the value of the coal produced in Canada was higher than that of any other mineral with the one exception of gold. Coal touches upon our daily lives in many different places of which the public are not generally conscious. As household fuel, it is a necessity of life in this northern climate; as a source of steam, it provides the heat for most of our industries; it is the food of the 'iron horse' chat shuttles our persons and our goods across the land; it is the source of power in many parts of the country; it is the chemical reducing agent chat, in our furnaces, transmutes the metallic oxides to the virgin metal. Coal is, in fact, the indispensable mineral chat forms the corner-stone of our present structure of industrial civilization. Is it, then, such an odd thing that the provision of an adequate supply of coal should be a matter of national interest or that measures should have been taken by government co provide for a constant watch, by a permanent Board, on the supply of co al? ? The Board is the result of the recommendations of the Royal Commission on coal which made a long and detailed study of the Canadian coal problem. It is composed of a permanent Chairman and six part-time members, most of whom have had intimate contact with various phases of the industry.

Jan 1, 1949

By Eric Reale

The New York City Department of Environmental Protection (DEP) is currently building City Water Tunnel #3 beneath the city. The purpose of this tunnel is to improve water distribution to the city and to allow the DEP to inspect the older tunnels and make the necessary repairs. These older tunnels have been in continuous operation since the early 1900's. Construction on the Third Tunnel is planned in four stages. The Nelson Street Shaft, which is the focus of this paper, is part of the second stage.

Jan 1, 1989

By P. Mendoza, R. Siwale, H. Amini, R. Silva, M. Richards, V. Ngcoza, D. Rivera, C. Canaza, R. van Reenen

Development of a realistic flotation model to predict its performance is of paramount importance to the processing plant and operators, a model that accounts for predictive and no-predictive maintenance simulating individual equipment downtime and the effect of it in the metallurgical performance on the flotation bank with final recoveries and grades has a huge advantage on optimizing the flotation circuit/bank in terms of mechanical and metallurgical side. The Model was developed in a dynamic environment that allows for a better and more realistic simulation of the flotation bank. The maintenance model accounts for the Failure rate, Mean Time Between Failures (MTBF), Mean Time to Failure (MTTF) and Reliability (R(t)) those characteristics are combined to a multi-compartment process model that consists of a slurry recovery model, two options of froth recovery models, entrainment and carry capacity as a final check for the system. In addition to the maintenance and process model, a dynamic dart valve model was added to the simulation in order to have a realistic model to control the slurry level at the flotation cell. The paper goes over a study case for a current flotation operation trying to explore all the elements and the simulator to optimize the Rougher flotation bank.

Mar 2, 2022

By Joseph A. Meyers

NYC has always been a high-profile target for both foreign and domestic terrorists. Explosives have always been the go-to tool for terrorists to bring about serious physical injury, death, and property damage in our society. Today with the anti-police movement gaining traction in the United States and anarchists groups using homemade explosives against law enforcement and municipalities, it is the responsibility of the explosives industry to ensure that every explosive product on a blasting site is secure. We must prevent the theft of these energetic materials used on projects and sold by vendors so they are not used by these terrorists. We have learned many lessons here in NYC which began with the theft of explosives used for blasting projects in NYC to supply the IRA (Irish Republican Army) 50 years ago. The liability is too significant to take short cuts in securing energetic materials. Over the years through cooperation with all agencies and the industry we in NYC have developed certain proven protocol and procedures we would like to share with the industry. An efficient and effective security plan for the logistic movement of explosives, as well as for the blast site is imperative to keeping the good name of the industry from negative repercussions and possible additional bureaucratic oversight of an industry that is highly regulated and still recovering from the pandemic. Communication, security assessments and transparency with all stakeholders and the Authority Having Jurisdiction (AHJ) will greatly improve the overall security for the blasting project. This SOP (standard operating procedure) will allow the AHJ to become a proactive partner in the security of the blasting project. If the AHJ is not a law enforcement agency, the law enforcement agency specialty unit must be notified and included in all phases of the project. The security for a blasting project with AHJ and law enforcement input starts at the inception of the project when the memorandum of understanding (MOU) is obtained, and involves the AHJ through all steps of the approval process. This includes threat assessments on new and existing structures. SME’s (Subject Matter Experts) must be present at all stages. The blasting industry and regulators must work collaboratively to improve safety, security, and create a dialogue with law enforcement and the AHJ. Relationships are built through trust, teamwork, transparency, and communication and greatly improve the safety of our great country.

Jan 21, 2025

By M. R. Tek, K. H. Coats, D. L. Katz

In natural gas storage operations, seasonal pressure fluctuations in the gas reservoir cause the water from the surrounding aquifer to flow into and out of the gas sand. The theory of unsteady-state liquid flow through porous media developed by Van Everdingen and Hurst' has been applied to predict the water movement into and out of the gar bubble for .several .postulated pressure cycles. Those cycles with as many pound-days above the original aquifer pressure as pound-days below, may cause the gas reservoir to slowly grow or shrink rather than hold to a constant volume. Applications to an actual field case study give the predicted gas reservoir monthly pressures and volumes as compared with the observed monthly pressures and volumes. INTRODUCTION A large number of natural gas storage reservoirs are bounded by or adjacent to large water-saturated formations called aquifers. The presence of these aquifers is usually evidenced by the production of water from wells delineating the gas-hearing sands. Some gas storage reservoirs in use today have been purposely developed on aquifers. Cyclic pressure variations in a gas storage reservoir cause water influx and efflux from the surrounding aquifer. This, in turn, results in a varying gas reservoir volume. The prediction of the effect of this aquifer fluid movement on the size and size variation of the gas reservoir can provide information valuable in the study of several reservoir engineering problems. The economics of gas storage operations are directly influenced by the influx of aquifer fluid into the reservoir since a shrinking storage reservoir requires increasing pressures for the storage of the same quantity of gas. Material balance and reserve or recovery calculations also obviously require knowledge of reservoir volume. Various other reservoir engineering calculations such as interpretation of well interference data, evaluation of physical characteristics of porous media, water coning, gas injection and pressure maintenance studies are typical problems where variations of volume due to edge or bottom-water encroachment becomes important. The solution of equations describing influx and efflux of water in the gas sand, application to gas storage reservoir behavior and interpretation of results are the main objectives of this paper. While this work was directed toward gas storage reservoirs, it applies equally well to repressuring of partially depleted oil reservoirs with an active water drive. MATHEMATICAL ANALYSIS As just mentioned, the cyclic pressure variations in an aquifer-surrounded gas storage reservoir cause water movement and varying gas reservoir volume. Prediction of this volume variation from the reservoir pressure cycles or the injection-production schedule requires adoption of a flow model, certain assumptions concerning reservoir and fluid properties, and formulation and solution of the governing differential equation. The flow model used in this study is a gas bubble located on a very large aquifer (Fig. la). Gas bubble radius and aquifer sand thickness are denoted by rr and h, respectively. Fig. lb shows the horizontal, radial two-dimensional porous reservoir attended by the unsteady, compressible motion of the aquifer liquid. Volume variation of the gas bubble is determined from aquifer water flow across the cylindrical boundary, r = r0

By L. K. Mireku

"Abstract - The Halfmile Lake South Deep zone, Bathurst Mining Camp, New Brunswick, was discovered by Noranda Inc. (Exploration) as a result of a 3-D seismic survey in 1998 and the subsequent drilling of ten diamond-drill cores. The deposit consists of massive, breccia, and stockwork Pb-Zn-Cu sulfide minerals, and is hosted by a volcano-sedimentary sequence belonging to the overturned Ordovician Tetagouche Group. Epiclastic rocks and interbedded fine-grained felsic pyroclastic rocks dominate the stratigraphic footwall. Locally, crystal-rich felsic tuffs and subordinate epiclastic rocks comprise the immediate stratigraphic hanging wall. The entire stratigraphic sequence was intruded by quartz-feldspar porphyritic intrusions, and cut by intermediate and basic dikes. The volcanic and sedimentary rocks can be discriminated geochemically using trace element ratios such as Zr/TiO2 and Nb/TiO2, despite intensive alteration and cleavage development. These ratios indicate that four protolith volcanic compositions exist: rhyolite, dacite, andesite, and basalt. The aphyric and feldspar- and quartz-phyric volcanic rocks are dacitic and rhyolitic in composition; epiclastic rocks have trace element ratios consistent with dacitic compositions. Pearce element ratio diagrams, general element ratio diagrams, and petrographic observations demonstrate that the rhyolitic volcanic rocks exhibit evidence of albite, potassium feldspar, and quartz fractionation, dacitic volcanic rocks exhibit little evidence of any fractionation, and epiclastic sedimentary rocks exhibit evidence of quartz sorting only. Hydrothermal alteration is best represented by the presence of phengitic muscovite and daphnitic chlorite. Minor calcite occurs in the stratigraphic hanging wall, deep in the stratigraphic footwall, and in post-mineralization dikes, and thus is not interpreted to be part of the causative hydrothermal event. Element additions and losses during alteration have been used to determine net alteration reactions, and these have been used to identify alteration parameters that are independent of other forms of alteration and fractionation/sorting, and which can be used to guide exploration. These parameters include: a bulk hydrolysis measure, (2Ca+Na+K-2CO2)/Al; a muscovite alteration measure, K/Al; an albite destruction measure, Na/Al; a chlorite alteration measure, (Fe+Mg-S/2)/Al; a chlorite composition measure, (Fe-S/2)/Mg; a sulfidization measure, S/Ti; and a carbonatization measure, CO2/Ti. With the exception of the carbonatization measure, these alteration parameters define a distinct lateral and vertical zone of intense hydrothermal alteration in the stratigraphic footwall of the deposit, and demonstrate that the epiclastic rocks are predominantly chlorite altered, and the volcanic rocks are predominantly muscovite altered. Within the alteration halo, element additions of Fe and H, and element losses of Na are characteristic. Potassium was added to muscovite-altered rocks, but subsequently removed from chlorite-altered rocks. The results from this study demonstrate that metamorphism and deformation have not significantly obscured hydrothermal alteration signatures."

Jan 1, 2006

For Australian mining projects, sustainable groundwater use is typically defined as a groundwater extraction regime, measured over a specified planning time frame, which allows acceptable levels of stress and protects dependent economic, social and environmental values (DEH, 2004). This principle is compatible with most stakeholdersÆ understanding of our national environmental objectives, yet the application of this policy on a project-specific scale is not always straightforward. Three examples of sustainability issues in the management of groundwater in mining are presented. These examples highlight each of the three dependent values: environmental, economic and social.

Jan 1, 2006

By George Rice

TEN years ago, October, 1914, the author had the privilege of giving an-illustrated address on investigations of coal-dust explosions1 to this Institute at one session of its fall meeting in Pittsburgh, Pa. On the following day, the members had the opportunity of seeing a large-scale explosion test at the Experimental Mine near Bruceton, in which the explosion was made to follow a predetermined path by means of rock-dust barriers of various types, which had prevented the explosive waves from reaching the outlets of, the mine by the shortest paths.2 There was also shown a "home-made rock-dusting machine discharging the dust from a flexible nozzle, and a cement gun operated for the quick erection of a fire or ventilation stopping, such as might be put up after an explosion. Following that paper, there was presented a paper by J. Taffanel, Director of the Lievin testing station in the Pas de Calais, which reviewed the French coal-dust investigations.3 Another important paper was by Howard N. Eavenson, on Coal-mine Explosions Caused by Gas or Dust.4 This paper contains complete lists of explosions that occurred in North America and Great Britain, from early in the 19th century to 1912; in France to 1903, and in Belgium to 1909. No one can look over these lists without being struck by the great number of explosions and the, appalling aggregate of lives lost by them. Although they still happen, we-are hopeful that we have entered on a happier period of freedom from these dreaded visitations, as the result of great increase in knowledge; of the causes and means of prevention. Looking back over coal-dust investigations, there appear to have been periods of advance and of stagnation.

Jan 3, 1925

The MIMDAS geophysical data acquisition system developed and tested by the former MIM Exploration Pty Ltd (MIMEX) is now commercially available worldwide through Geophysical Resources and Services Pty Ltd (GRS). The system implements several new features in its design that give it significant advantages over conventional systems and allows for new approaches to electrical exploration. In particular, the achievable signal to noise levels permit exploration to depths once thought beyond the range of electrical exploration. The flexible multi-channel configuration lends itself to truly 3D surveys in the style of modern seismic techniques. Each of these aspects is illustrated with a number of case histories from both Australia and South America.

Jan 1, 2004

By de Vaux. Deryck, Natalie J. Shackleton, Vratislav Malysiak Cyril T. O. Connor

"The major losses of PGM and base metals in the beneficiation of platinum group deposits occur during the separation of gangue from the value minerals by selective flotation. A number of studies have shown that this negative impact on flotation is due to surface passivation, caused by various ions that may originate from the external water supply or, as is likely in the majority of cases, from the oxidation of the mineral surfaces and the grinding media. This investigation aimed at reducing surface passivation of pentlandite and inadvertent activation of pyroxene, thereby improving ultimate valuable mineral recovery and selectivity. Both synthetic minerals and plant ores were studied in order to determine the effect surface passivation and inadvertent activation have on mineral surface alteration and floatability. Zeta potential determinations, microflotation, ToF-SIMS (Time of Flight Secondary Ion Mass Spectrometry) analyses, laboratory batch flotation tests and continuous flotation testwork were used as tools to study the surface alteration and/or floatability.Zeta potential determinations and ToF-SIMS analyses showed that copper adsorption is non-selective. Both pentlandite and pyroxene become copper (II)-activated in the presence of copper sulphate and subsequently, in the presence of xanthate, adsorption of the collector will occur onto copper activated mineral surfaces. Zeta potential determinations also showed an alteration of the surface charge in the presence of polyphosphate, thereby inhibiting surface passivation of sulphides by slime coatings due to surface repulsion.The addition of diethylenetriamine (DETA) reduces the copper concentration on both minerals, predominantly on the pyroxene surfaces and polyphosphate further enhances the selectivity at pH 6.The microflotation and batch flotation data obtained has shown a significant improvement in the ultimate flotation response of valuable mineral recovery and concentrate grade compared to the standard reagent regime, while the continuous flotation results significantly improved the selectivity, however, at a similar ultimate recovery."

Jan 1, 2003

By A. Newman, A. Brickey

Although some of the prevalence of openpit production scheduling software can be explained by the predominance of openpit mining throughout the world, other factors have led to a lag in corresponding underground software. We explain mathematically why underground production scheduling is more difficult than its openpit counterpart and provide directions for research in the underground scheduling arena.

Jan 1, 2014