Search Documents

By John L. Lamont, Walter Crafts

An investigation has been made of the multiplying factors for some of the more common alloying and deoxidizing elements for use in calculating hardenability of steel according to Grossmann's method. The factors for manganese, silicon, and aluminum that were reported in an earlier communication2 have been confirmed by microscopic determination of the half-martensite structure rather than on the basis of an empirically determined hardness corresponding to a half-martensite structure. Measurement of ideal critical diameter by microscopic examination was found to be necessary for other alloying elements, and multiplying factors for nickel, chromium, molybdenum, zirconium, vanadium, titanium, and boron have been determined. The nature and order of magnitude of the multiplying factors reflect the effect of the alloying elements on the structural character of the steel. Except for nickel and vanadium, the multiplying factors agree fairly well with previously published results. Good correlation between actual and calculated ideal critical diameters has been found in developing the multiplying factors and in checking the results against fairly simple steels. However, some discrepancies have suggested the need for a more thorough study of low-carbon and complex steels. Testing Procedure The investigation was conducted principally on steels made at the Union Car- bide and Carbon Research Laboratories, Inc., in high-frequency induction furnaces using Armco iron and standard alloying materials. However, a few open-hearth steels were used in establishing the effect of nickel, and the hardenability factor for boron was based primarily on open-hearth steels. All bars were normalized prior to the machining of Jominy hardenability specimens. The Jominy test was carried out under conditions standard for the test.3 Austenitizing temperatures judged to be appropriate for the compositions of the steels were used. Chemical analysis was determined on a sample taken adjacent to the Jominy specimen. Residual amounts of phosphorus, sulphur, nickel, chromium, molybdenum, and copper were determined on only one heat of each group made with the same materials during the same period. "Acid-soluble" aluminum and zirconium rather than total amounts were determined, as it is considered probable that the acid-soluble amount is more representative of the effective alloy. As tin was present to the extent of only 0.002 per cent, its effect was neglected. The method used to determine boron in the steels shown in Table 9* was developed by Galen Porter, Vincent Napoleon, and Thomas R. Cunningham, of the Union Carbide and Carbon Research Laboratories, Inc., and is a modification of J. Naftel's procedure for boron in soils

Jan 1, 1944

By Charles R. Keyes

Prefatory,........323 Foundation of classificatory schemes in general..325 Past opinion on the classification of ore-bodies,.326 Nature of ore-deposits,....... 326 Definition........326 Fundamental law of origin.... 327 Significance of ore-bodies,.... 327 Date of origin........328 Original source of ores..... 328 Alteration of ore-bodies,....329 General methods of ore-formation.... 330 Ascension verm lateral secretion... 330 Replacement.......330 General factors in classification....332 Genesis in ore-classification....332 Literature of ore-deposits...... . 333 Criteria of ore-classification,..... 335 Primary grouping of ore-deposits..... 338 Hypotaxic deposits......341 Eutaxic deposits...... 341 Ataxic deposits....... 313 Secondary categories of ore-bodies....343 Ternary phases of ore-deposition.....344 Types of hypotaxic or surface deposits..... 344 Illustrations of eutaxic ore-bodies.... 347 Examples of ataxic ore-bodies.....352 Recapitulation.. .. .. .. 355 Prefatory. Much has been written on the genesis and classification of ore-deposits. Much remains yet to be written on the subject

Jan 1, 1901

Rock bolting has become the most important method of ground support at Mount Isa. Various types of rock bolts are used to suit the different applications and requirements. To apply rock bolting techniques satisfactorily, it is necessary to have some knowledge of the nature of the rock, the type of rock failure, any stress redistribution which may occur during the intended life of the rock bolt and the time for which ground support is required. At Mount Isa there are a number of dif- ferent applications of rock bolts for ground support, and some trends in rock bolting techniques.

Jan 1, 1971

By A. Davaliev, K. Hrkovic, V. Pavlovic

On the territory of Macedonia in South Yugoslavia primary and dory gold occurences were known since ancient times. Remnants of numerous goafs and remainders of washaries on river terraces and alluviums date right back to the times of Phillip II and his son Alexander of Macedonia and from Roman times, as well as from the Middle Ages witness exploitation of primary and secondary gold. More recent explorations on primary and secondary gold occurrences date from the period between two World Wars. Over that period a number of private companies, each on their own jointly, carried out gold exploration, particularly of alluvial occurrences on rivers emptying into River Vardar, starting from Skopje to the Greek frontier. The latest gold explorations carried out In the alluvium of River Konjska date back in 1976, and in 1978 old terraces of River Konjska were explored. The Visibility Study was prepared on possibilities of exploitation of gold from River Konjska alluvium. In the paper are collected the basic date an all known primary and secondary occurrences of gold, the results of the latest explorations, and the study itself. To-date geological explorations and analyses show very interesting potentionality of River Konjska and River Vardar alluvium, which proves continuing of he further explorations. For the moment, it is necessary to re-explore more complete view of the deposit. After that it will be possible to make complete techno-economical estimation of the auriferious alluviums and the conditions of the evaluations of the alluvial gold. 1. REVIEW OF PRIMARY AND SECONDARY GOLD DEPOSITS IN MAOEDONIA,YUGOSLAVIA 1.1. Primary deposits Scarse data are available for primary gold deposits in Macedonia` being unadequate for clear

Jan 1, 1988

By John C. F. Randolph

(Read at the Amenia Meeting, October, 1877.) Tits establishment being now in full working order, it has seemed of considerable professional interest to collect together, in a concise form, the various points as to its plan, method of dressing, and equipment. The data contained in this paper have been largely drawn from the able paper of E. Kutscher, constructing engineer. of the works, contained in the Zeitschrift fur Berg-Hütten-und Salinenuesen im Preussischen Staate, 1873, supplemented by some personal memoranda made while the works were under construction and by memoranda on the works appearing in various German technical papers from their completion up to date. This is probably the largest dressing works in the world devoted to the beneficiation of argentiferous lead ores, and it is doubtful if any establishment for the concentration of mineral of any description can compare with it in size. As showing the final practice adopted in an old and very conservative mining region, in which the concentration of ores has been a matter of constant practice and experiment for a very long period, these works are of peculiar interest. The fact that the Clausthal ores strongly resemble a very large and abundant class of ores found in the United States has always attracted the attention of American mining engineers and mine owners to the methods employed in dressing and smelting them. The study of their methods of concentration of ores has, however, always been full of difficulty,

Jan 1, 1878

By Chen Bang, Xia Xiao’ou, Zhang Feng

"Ores with compressive strength lower than 150 MPa are usually easy to be crushed by conventional jaw crushers and cone crushers. However, for hard ores with compressive strength exceeding 150 MPa and 200 MPa and even up to 250 MPa, such as andesite, hard basalt and olivine, it is difficult to reach satisfactory crushing size and yield or difficult to meet service life and stability use requirements of quick-wear parts by using conventional crushers. As continued increase in ore mining depth and constant generation of new type materials, equipment demand for crushing hard ores becomes increasing high. A new type inertia vibrating crusher is designed. It is powered by a high-speed rotating vibration exciter and can obtain required crushing force by adjusting eccentric mass, eccentricity and rotating speed so as to crush various ores with high hardness. This paper introduces the design process of its structure and working principle, discusses the design calculation methods of vibration excitation system, vibration damping and energy storage system and other key mechanism and provides technical references for this type of vibrating crusher.DESIGN PHILOSOPHYThe conventional jaw crusher mainly acquires extrusion force from crank motion to realize crushing. The motor drives the eccentric shaft via the transmission device to bring the moving jaw to swing relative to the stationary jaw. When the moving jaw moves close to the stationary jaw, ores between them are crushed by extrusion; when the moving jaw moves away from the stationary jaw, crushed ores are discharged from the discharge gate at the lower end between the moving jaw and the stationary jaw.The conventional spring cone crusher and the hydraulic cone crusher mainly acquire extrusion force from cranking motion to realize crushing. The motor drives the eccentric sleeve via the transmission device, the moving cone shaft generates an eccentric distance to make cranking motion under the action of the eccentric sleeve. When the moving cone moves close to the stationary cone, ores between them are crushed by extrusion. When the moving cone moves away from the stationary jaw, crushed ores are discharged from the discharge gate at the lower end between the moving cone and the stationary cone under the action of dead weight."

Jan 1, 2016

By N. I. Fisher, J. Shepherd

Statistical studies have been carried out on structural geological data collected across a large zone of roof failure 600 m (1968 ft) wide and at least 800 m (2642 ft) long in the Greta coal seam at Aberdare East Colliery. Two swarms of hundreds of minor, normal faults with throws commonly between 3 and 300 mm in the room and pillar workings are broadly coincident with roof failure. The faults have been classified into dip slip and oblique and strike slip types. Roof conditions have been classified into good; troublesome with subclasses scaly, heavy, gutter falls and wide, flat-roofed falls; and severely failed with subclasses very heavy roof, gutter falls and dome falls. Troublesome conditions are defined as those in which the height of the fall is less than or equal to 0.3 m, and severely failed conditions as those in which the fall height is greater than 0.3 m. Comparison of faults, roof condition and mining rate on a shift basis indicates that faults and roof failure are much more important than machine breakdowns in reducing mining rate. The effect of faults on roof conditions has been quantified using a concept called the "zone of influence," a rectangular area around a fault in which the fault has potentially deleterious effects. The spatial comparison of fault "zones of influence" with areas of roof failure wing Spearman's rank correlation coefficient shows that, while normal dip slip faults do not appear to be associated with roof failure, oblique slip and strike slip faults appear to be associated with roof classed as severely failed. The "zone of influence" of an oblique slip fault may extend up to 3 m on each side of it in the headings and up to 1.14 m in the cut-throughs. The fault "zone of influence" has geomechanical implications for the design of mine openings and Possibly represents the maximum length of a cantilevered roof beam likely to fail during mining, owing to a fault. Roof conditions could Possibly be predicted in blocks of &gin coal if the type of fault could be identified in oriented drill cores.

Jan 1, 1979

By Godwin M. Beene

Large scale mining operations started in Zambia in 1913 and rapidly expanded during the post 1930 period with the opening of several mining and processing plants on the present Zambian Copperbelt. As a consequence of poor tailings dumps design methods at the start of the mines, and in view of stringent Government Legislation pertaining to environment in the recent years, Nkana Mine has developed a unique method of dump construction at its current tailings depository, Tailings Dam 15A. This method has enabled the revegetation of the dump retaining walls while construction is still in progress, a situation which was not possible on the older dumps. Cowdung has proved to be a superior fertilizer for providing plant nutrients on the tailings. The new method of dump walls construction and walls rainwater runoff drainage system has almost eliminated tendency of gully formation which is common on older dumps, as rainfall on the Zambian Copperbelt comes in intense thunderstorms. The decanted water from the dump is discharged to the natural environment in a controlled fashion after ensuring that it meets the Zambian Government Statutory requirements.

Jan 1, 1999

By C Gunther

In the examination of an undeveloped prospect a decision must be arrived at from an inspection of the outcrops and the exposures in a few shallow pits. Prospects that are offered for sale rarely expose any important quantity of good ore, work having usually been stopped when the immediate exploration no longer yielded favorable results. It should be borne in mind, furthermore, that a great majority of prospects have been examined many times, and if of conspicuous promise, would have been acquired for development. In most cases the problem for the engineer, therefore, is to discover the traces of a valuable mineralization that has disappeared through solution, or the conditions that indicate the possibility, or probability, of underlying secondary enrichments. The available data being meager, every feature should be the subject of careful study-the condition of the outcrop, the structural relationships, the associations of minerals, the alterations of wall rocks, the chances for underlying enrichments, and so forth, as well as the actual assay value of the material exposed. It is frequently advisable to spend the time and money necessary to have trenches dug at various significant points along a promising outcrop; such exposures, even if the depth attained is slight, often disclose conditions that are not apparent at the actual surface, as for example, the existence of soft minerals and the distribution of the various minerals through the mass of the deposit. Trenches also permit samples to be taken from points that were not accessible during former examinations. Strong, persistent outcrops of uniform width may be taken to indicate the probable size and character of the underlying vein,

Jan 1, 1932

By K Biegaj

The paper describes challenges the author has encountered on Australian underground gold and nickel mines over the last eight years, when recovering high-grade gold/nickel bearing mine floor material with a mobile supersucker/giant vacuum cleaner and other equipment. Whilst for a number of years the mine floor vacuuming and other mine floor clean-down technologies have been accepted/adopted and are working well in other parts of the world and on the South Australian opal mines, regrettably, they have not yet gained acceptance of mining executives and mine managers of gold and metal mines in Australia, who still elect to leave the never to be recovered gold/metal behind or to put it plainly - waste it.For reporting purposes during the mining process, the portion of gold/metal included in calculation of ore reserves prior to obtaining capital funds for their development, continues to be camouflaged in various reconciliation and call factors. This approach, ie wasting of capitally developed and already broken ore stocks should be viewed by the shareholders as totally inappropriate to say the least, especially with the current gold and other metals prices.The author attempts to provide answers as to why the technology referred to above has not yet been accepted on Australian gold and metal mines and outlines the way forward.CITATION:Biegaj, K, 2012. Why do shareholders and mining executives allow mine managers to leave behind high-grade broken ore underground?, in Proceedings Narrow Vein Mining 2012 , pp 197-206 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

By Edmund M. Wise

NATURE has provided us with many metals, but with few really good ones, and frequently the better metals are the rarer. It is to this circumstance that many physical metallurgists, inventors, and just plain experimenters owe their employment, for much of their work is directed, consciously or otherwise, toward the alleviation of some of the more serious shortcomings of the cheaper, less noble, and weaker metals; by alloying, age-hardening, passivating, cladding, plating, and other useful dodges, which sometimes permit the substitution of one of the less gifted metals for one of the really good ones. As a matter of fact, the varied needs of our complex civilization could be quite well met with only five metals, if they were sufficiently abundant, and one of the five would certainly be platinum, the most noble and versatile that nature provides. Many metals are difficult to handle and seem to take pleasure in defying their investigators to find good uses for them, and finally when a use is found it is frequently quite a specific one; in other words, a hole has to be found--or perhaps made-to fit the peg. It is for this reason that a large amount of research must be con- ducted before the more recalcitrant metals become really useful. In platinum, however, we have a metal that inherently possesses so many valuable attributes that it became useful as soon as methods for producing it in massive ductile form were devised, and once its complicated chemical behavior was understood it became principally an aid to research rather than the subject thereof. In recent years, much research has been done to further improve

Jan 1, 1953

By M. L. Fuller

DURING the last several years many papers have appeared dealing with the structure of highly polished metal surfaces The awakening of interest in this subject is due to the applicability of the electron diffraction technique to the study of surfaces The original theory of Beilby1 considered the surface of polished metals as of the nature of a super-cooled liquid or a vitreous, amorphous solid The electron diffraction effects from polished metals have been interpreted by many to be a direct experimental proof of the correctness of the Beilby theory This interpretation has been strongly opposed by others, so that at the present time the subject is in an uncertain and controversial state In the present paper new, and hitherto unpublished, electron diffraction effects from polished zinc are described These observations indicate that the polished surface of zinc is crystalline PUBLISHED WORK Many papers2-10 have interpreted the electron diffraction evidence as proof of the Beilby amorphous theory All investigators agree that highly polished metals give rise to two diffuse diffraction haloes, similar to those obtained by the diffraction of X-rays in liquids and vitreous solids It is this similarity that leads to the amorphous-layer interpretation of polished metals Strangely, the interatomic distances calculated from these haloes are very similar for the various metals investigated, in spite of a rather wide range of such distances in the crystalline and liquid states The calculated atomic sizes are, furthermore, smaller than are experienced in the normal states of the metals In spite of these anomalies, the amorphous-layer interpretation has been adhered to by many One investigator, S Dobmski,11 differs from the others in his experimental results By polishing under benzene in order to avoid the possibility of oxidation, Dobinski obtains diffuse haloes of [radire] different from those previously obtained He thus obtains a more rational quantitative correlation of-the diffuse haloes with the amorphous-layer theory

Jan 1, 1938

By T. B. Counselman

AN iron blast furnace of 1000 tons daily capacity will produce about 100,000 cu; ft. per minute of blast-furnace gas. This contains about 25 per cent of carbon monoxide, and has a B.t.u. value of about 95. This gas-is used primarily for heating the stoves of the blast furnace, and secondarily, under boilers, for steam production. Occasionally it is also used in gas engines. The raw gas coming out of the furnace carries about 10 grains of flue dust per cubic foot of gas, under best operating conditions. With the furnace "rolling" or slipping, this quantity may temporarily be greatly increased. This dust would, of course, deposit on the checkers of the stoves, or plug the burners under the boilers; therefore the gas must be cleaned.

Jan 1, 1936

By K. V. Raj

"The development and advancement of computational fluid dynamics (CFD) has made it possible to better understand pollutant flow and distribution in deep open pit mines. Open pits located at higher latitudes, especially in the Arctic and sub-Arctic, face a unique problem due to atmospheric temperature inversion, which is prevalent during much of the winter. A three-dimensional CFD model of an actual open pit mine in the Arctic was developed to analyze the problem of pollutant growth during inversion, and mitigation of the pollutants through improved ventilation schemes. Due to the availability of mine-specific data, such as contaminant concentrations and coordinates of sampling locations, the actual 2013 pit geometry was used for model validation Concentrations predicted by the selected realizable ?-e turbulent model are compared to measured pollutant concentrations at the open pit. Pollutant concentrations at selected locations showed differences, but remained within the same order of magnitude in most cases. INTRODUCTION Computational fluid dynamics (CFD) has emerged as a useful tool for ventilation modeling in underground mines (Edwards and Hwang 1999, Purushotham and Bandopadhyay 2009, Wala et al. 1998, Xu et al. 2011). Application of CFD in open pit mines has been limited, however, since most open pit mines located at lower latitudes do not encounter considerable ventilation problems. Open pits located at higher latitudes, especially the Arctic and sub-Arctic, face a unique problem due to atmospheric temperature inversion, which is prevalent during winter. A number of Russian researchers have tried to understand the air inversion and resulting pollutant transport problem by modeling air flow phenomena in open pit mines (Baklanov and Burman 1996, Baklanov 1984, Baklanov 1995, Belousov 1985, 1989, 1995). Much of their work, however, was based on numerical models and methods of finite difference. Baklanov (2000) applied a modified ?-e and a ?-l CFD model to air flow phenomena on various terrains. More recently, Choudhury (2011) used the COMSOL CFD package for modeling pollutant transport for an idealized open pit mine. Collingwood et al. (2012a, 2012b) used a two-dimensional model for fluid flow and contaminant transport at an Arctic open pit mine. The authors have also previously presented work on CFD modeling of an actual open pit mine at high latitude (Bandopadhyay et al. 2014, Raj et al. 2015a). However, the CFD work done by the above-cited researchers lacked model validation with field-measured data. Validation of a developed model is important in assessing the quality and accuracy of the predicted results. In general, experiments are done numerous times in controlled environments to assess the validity of collected data. There are two types of assessments used in CFD simulations: (1) verification and (2) validation. Model verification is checking the accuracy of the computer codes during the implementation phase of a real-world problem, within the specific limits of accuracy (Oberkampf and Trucano 2002). Since, the pollution transport model presented in this paper used the commercial ANSYS-FLUENT CFD package, verification is not needed as the program has been tested widely, and verified numerous times."

Jan 1, 2016

"Sink-float analysis is often used to obtain yield-ash and density partition curves in the coal industry. These provide a valuable tool for evaluating the performance of a separation process. However, for dense minerals, obtaining complete grade-recovery and density partition curves is more difficult due to the lack of heavy liquids available with the required densities. This paper examines a potential solution to this problem which is to perform batch fractionation of mineral samples in a laboratory-scale REFLUX™ Classifier using high viscosity fluidising liquids. The REFLUX™ Classifier is a gravity separation unit consisting of a system of parallel inclined channels positioned above a vertical fluidised bed. Operated in semi-batch mode, a charge of particles is fluidised from below and particles up to a certain density are elutriated from the top of the system. The fluidisation rate is then increased incrementally to fractionate the sample at progressively increasing densities. Previous work by Hunter et al. (2014) and Iveson et al. (2015) has shown that this method provides excellent agreement with yield-ash and partition curves for coal, especially when glycerol solutions are used as the fluidising liquid. This approach has now been extended to obtain the grade-recovery and density partition curves of high density mineral samples. This method has the potential to provide the minerals industry with an effective tool to evaluate the performance of unit operations separating at cut points higher than the available heavy liquids.INTRODUCTIONMeasuring efficiency and effectiveness is of key importance in the continuous improvement of mineral processing plants. For density based separation, one way the performance of a process can be evaluated is the measurement of density-based partition curves. Currently, this is done in the coal industry using the sink-float method, where heavy liquids are used to fractionate particles into discrete density intervals. However, with high density minerals such as iron ore, liquids of sufficient density are rare, and in most cases also pose serious health and safety concerns to laboratory operators. Most commercial laboratories do not perform sink-float separations above a density of about 4400 kg/m3, the maximum density of Clerici solution without operating at excessive temperatures (Koroznikova, Klutke, McKnight & Hall, 2007; Rosenblum, 1974)."

Jan 1, 2016

By Stephen B. Castor

The rare earth elements (REE) which include the 15 lanthanide elements (Z = 57 through 71) and yttrium (Z = 39) are so called because the elements were originally isolated in the late 18th and early 19th centuries as oxides from rare minerals. Most REE are not as uncommon in nature as the name implies. Cerium, the most abundant REE (Table 1), comprises more of the earth's crust than copper or lead. Many REE are more common than tin and molyb¬denum, and all but promethium are more common than silver or mercury (Taylor, 1964). Promethium (Z = 61) is best known as an artificial element, but has been reported in very minute quantities in natural materials. Lanthanide elements with low atomic numbers are generally more abundant in the earth's crust than those with high atomic numbers. In addition, lanthanide elements with even atomic numbers are two to seven times more abundant than adjacent lan¬thanides (Table 1) with odd atomic numbers. The lanthanide elements traditionally have been divided into two groups: the light rare earths (LREE), lanthanum through eu¬ropium (Z = 57 through 63); and the heavy rare earths (HREE), gadolinium through lutetium (Z = 64 through 71). Although yttrium is the lightest REE, it is usually grouped with the HREE to which it is chemically and physically similar. The REE are lithophile elements (elements enriched in the earth's crust) that invariably occur together naturally because all are trivalent (except for Ce+4 and Eu+2 in some environments) and have similar ionic radii. Increase in atomic number in the lanthanide group is accompanied by addition of electrons to an inner level rather than the outer shell. Consequently, there is no change in valence with change in atomic number, and the lanthanide elements all fall into the same cell of the periodic table. The chemical and physical differences that do exist within the REE group are caused by small differences in ionic radius, and generally result in segre¬gation of REE into deposits enriched in either light lanthanides or heavy lanthanides plus yttrium. The relative abundance of individual lanthanide elements has been found useful in the modelling of rock-forming processes. Comparisons are generally made using a logarithmic plot of lanthanide abundances normalized to abundances in chondritic (stony) meteorites. The use of this method eliminates the abundance vari¬ation between lanthanides of odd and even atomic number, and allows determination of the extent of fractionation between the lanthanides because such fractionation is not considered to have taken place during chondrite formation. The method is also useful because chondrites are thought to be compositionally similar to the original earth's mantle. Europium anomalies (positive or negative departures of europium from chondrite-normalized plots) have been found to be particularly effective for petrogenetic modelling. REE were originally produced in minor amounts from small deposits in granite pegmatite, the geologic environment in which they were discovered. During the second half of the 19th century and the first half of the 20th century, REE came mainly from placer deposits. With the exception of the most abundant lanthanide el¬ements (cerium, lanthanum, and neodymium), individual REE were not commercially available until the 1940s. Since 1965, most of the world's REE have come from two hard rock deposits: Mountain Pass, United States, and Bayan Obo, China. GEOGRAPHIC DISTRIBUTION OF REE DEPOSITS More than 70% of the world's REE raw materials come from three countries: China, the United States, and Australia. China emerged as a major producer of REE raw materials during the 1980s, while Australian and United States market share decreased dramatically (Fig. 1). Table 2 gives recent annual production figures along with estimated reserves by country, and Fig. 2 shows loca¬tions of significant REE mining. MINERALS THAT CONTAIN REE Although REE comprise significant amounts of many minerals, almost all production has come from less than ten minerals. Table 3 lists minerals that have yielded REE commercially or have po¬tential for production in the future. Extraction from a potentially economic REE resource is strongly dependant on its REE miner¬alogy. Minerals that are easily broken down, such as bastnasite, are more desirable than those that are difficult to dissociate, such as allanite. In general, producing deposits contain REE-bearing min¬erals that are relatively easy to concentrate because of coarse grain size or other attributes. For more thorough discussions of REE¬bearing minerals see Mariano (1989a) and Cesbron (1989).

Jan 1, 1994

By J. A. Berger, G. W. Wiener

Several transition metal nitrides have been prepared and their saturation magnetization determined. On the basis of an atomic model of ferromagnetism involving a consideration of nearest neighbor interactions and the assumption that all atomic moments of the metal point in the same direction, it appears that the nitrogen interacts with d-shell of the transition metal in such a way as to reduce the magnetic moment. THERE is a large class of materials having metallic properties which are formed by a combination of hydrogen, boron, carbon, oxygen, or nitrogen with the transition metals. Several attempts have been made to establish the type of metal-nonmetal bonding in these interstitial alloys because it is believed that many of the physical properties of these materials are determined by the characteristics of this bond. Several of these alloys are ferromagnetic, and thus a powerful method is available for investigating the structures in a direct manner by measuring the saturation magnetization. The latter is a fundamental property of ferromagnetic metals and alloys which depends primarily on the electron distribution surrounding the atom. For the first row of transition metals, this refers specifically to the 3 d-shell. Since bonding involves the electronic configuration between atoms, there is reason to suppose that a relationship exists between ferromagnetism and bond type. In the case of the interstitial structures studied in this work, bonding will refer to the distribution of electrons between the transition metal and the nonmetal. Since these alloys have metallic properties, it is further proposed that any bonding interactions will involve the outer p-shell of the interstitial element and the incomplete d-shell of the transition metal. If this is the case, then the relationship between ferromagnetism and metal-non-metal bonding is established qualitatively. In order to investigate the subject quantitatively, certain transition metal nitrides were chosen because they have simple crystal structures, are ordered alloys, and are ferromagnetic. They also have sufficiently high saturation magnetization to be of technical interest. Currently there are two major theories of ferromagnetism, each of which has been applied to the interpretation of the saturation magnetization in terms of atomic structure. They are usually referred to as the band theory and the atomic theory. The former has found widespread application to the study of pure metals and certain solid-solution allays. However, it has not been applied to the interstitial structures or ordered alloys because it does not interpret the properties directly in terms of the crystal structure. The atomic theory on the other hand is especially suited to the study of interstitial structures because it permits an interpretation of ferromagnetic phenomena in terms of the crystal geometry. As has been pointed out previously, the nitrides have simple ordered crystal structures and, therefore, the choice of the atomic theory for the interpretation of the data is a natural one. One of the prime difficulties with the atomistic theory is that its mathematical justification is much more difficult, and for this reason its general acceptance will depend to a large extent on the value it has in explaining and predicting the results of experiment. Before the presentation of the theoretical basis for understanding the metal-nonmetal bond, it is useful to review the ideas existing prior to this work. Four different interpretations have been given to the metal-nonmetal bond. These are summarized as follows: 1—acceptance of electrons by the nonmetal from the incomplete d-shell of the transition metal, 2—transfer of electrons from the nonmetal to the incomplete shell of the transition metal, 3—no exchange of electrons between the two atoms, and 4— a resonating type of bond involving the p electrons of the interstitial atom giving rise to half bonds. Zener'-4 in a recent series of papers has proposed a new theory of ferromagnetism and has developed an explanation of the observed saturation magnetization of iron nitride (Fe,N) using the concept that nitrogen accepts electrons from the 3d-shell of iron. Jack," on the basis of atom size considerations in iron carbonitrides, has proposed that nitrogen transfers or donates electrons to the inner 3d-shell. He found that the effective size of the carbon atom was less than that of nitrogen and thus suggested that the interstitial atoms give up electrons. Kiessling" has studied the borides of several transition metal atoms and proposed that boron loses one p electron to the transition metal. He postulated that the additional electron added to the metal lattice compensates for the loss in metallic properties which results from the increased metal-metal atom separation. GuillaudT3" has proposed similar arguments from some recent magnetic studies he had made on manganese nitride. However, he did not base his conclusions on a quantitative argument. Pauling," in a recent paper, discussed electron transfer in in-termetallic compounds. He classified nitrogen as a hyperelectronic atom which can increase its valence by giving up electrons. He classified the transition metals as buffer atoms which are capable of either accepting or giving UP an electron. He pointed out that two factors are operating which promote electron transfer because they lead to increased stability. The first is an increase in the number of bonds, and the second is a decrease in the electric charges on the atoms. These ideas when applied to the interstitial nitrides would indicate a viewpoint favoring electron transfer by nitrogen to the transition metal. Hagg7s arguments in favor of no exchange are adequately summarized by Wells." Implicitly, Hagg

Jan 1, 1956

By P. C. M. Knops, K. Rijnsburger, R. M. Santos

To overcome the challenges of mineral CO2 sequestration, this work utilizes a unique proprietary Gravity Pressure Vessel (GPV) reactor technology, and focuses on reaction products of high economic value. The GPV provides intense process conditions through hydrostatic pressurization and heat exchange integration that harvests exothermic reaction energy. Here, laboratory-scale tests of the envisioned process was performed in tubular and continuously stirred tank reactor (CSTR) autoclave reactors. The mineral used was Olivine (~Mg1.6Fe2+0.4(SiO4) + ppm Ni/Cr), although asbestos, steel slags and oil shale residues are also under investigation. The effect of several process parameters on reaction extent and product properties was tested: CO2 pressure, temperature, residence time, additives (buffers, lixiviants, chelators, oxidizers), solids loading, and mixing rate. The products (carbonates, amorphous silica and Chromite) were physically separated (based on size, density and magnetic properties), characterized (for chemistry, mineralogy and morphology) and tested in intended applications (e.g. as pozzolanic carbon-negative building material). Economically, it is found that product value is the main driver for mineral carbonation, rather than, or in addition to, the sequestered CO2. The approach of using a GPV and focusing on valuable reaction products could thus make CO2 mineralization a feasible and sustainable hydrometallurgical process.

Jan 1, 2015

By R M. Hough, G Duclaux, M A. Pearce, M F. Gazley

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Microcharacterisation, such as that described in this paper, provides understanding of a mineral system at multiple scales, and understanding microscale variations is the key to understanding the large-scale variations in a mineral system. More than 50 high-grade lode samples from across Plutonic Gold Mine (Plutonic), Marymia Inlier, Western Australia were analysed by a variety of techniques, including micro X-ray fluorescence (µXRF) mapping, micro X-ray computed tomography (µCT), scanning electron microscopy (SEM), field emission gun SEM, electron back-scatter detector (EBSD), proton-induced X-ray emission microprobe and synchrotron XRF mapping. These data demonstrate that competency contrasts are the key to governing the location of Au mineralisation at Plutonic. Micro CT imaging of high-grade samples shows the Au filling in voids and pore-space in the rock, after having travelled along more permeable layers and already existing or reaction-induced pores formed during hydrothermal circulation. Using 3D visualisation, the Au is seen to form a connected network that appears undisturbed at the scale of the samples, and a high-grade Au deposition event was one of the last events to affect the rock. This interpretation is supported by SEM analyses on high-grade samples that reveal calc-silicate (epidote-clinozoisite) alteration that is not present in lower Au grade samples, which are typically dominated by potassic alteration, and that sulfides are typically less abundant close to the Au. The replacement of biotite by chlorite is an alteration associated with the high-grade Au-mineralising fluid. Gold is coarsest where Au particles are located on the margins of minerals, typically sulfide and quartz grains, suggesting the importance of rheological contrast at the microscale. Furthermore, EBSD data reveals that Au is undeformed and overprints peak metamorphic and retrograde minerals. Data confirm recent deposit-scale observations, suggesting that deposition of high-grade, visible Au was related to a hydrothermal fluid circulation event late in the geological history of Plutonic.CITATION:Gazley, M F, Duclaux, G, Fisher, L A, Hough, R M and Pearce, M A, 2015. High-resolution characterisation of gold mineralisation at Plutonic Gold Mine, Western Australia – evidence for the late-stage deposition of high-grade gold , in Proceedings PACRIM 2015 Congress, pp 51–58 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By R. B. Shu

A moderate thermophilic microorganisms, has been isolated (45?) from a typical sulphide mine in the region of Mo Jiang located in the southwest of China. The culture has been used to extract copper from chalcopyrite concentrates obtained from De Xing copper mine. The majority of experiments were carried out in 300mL Erlenmeyer flasks containing 150mL volumes of mineral suspension. Effects of some variable parameters such as solids concentration, pH and the concentrations of inorganic nutrients on the bioleaching of chalcopyrite obtained from De Xing copper mine were investigated. For a given concentrate the most important factor affecting the fractional copper extraction was the size of the mineral particles. The overall rate of leaching was found to be limited by the area of mineral surface. The attack started in cracks and genetic defects and finally reached the whole chalcopyrite surface. As a consequence of this, the ore showed strongly cracks. The additive of ferrous sulfate increases the bacteria activity, but did not improve chalcopyrite bioleaching. The results indicate that the nature and relative proportions of the various minerals present have been shown to be important factors.

Jan 1, 2014