Search Documents

By D. W. Park

A vast majority of longwall operations in the United States use shield-type hydraulic supports to provide ground control along the longwall face. The three-dimensional finite-element technique combined with a progressive failure approach was utilized to simulate interaction between shields and surrounding strata and determine various loading conditions. In addition, a separate finite element model of the shield structure was made to study responses of each long wall shield to the different loading conditions. Shield responses under various loading conditions and the shield characteristics, such as shield stiffness, the ability of resisting horizontal forces, and the effect of shield height, were studied based on the results from finite-element analyses. The results can provide the basis of effective shield design and be used for evaluation of the shield performance. It is suggested to develop a technique incorporating the finite-element method to evaluate the real-time shield performance for the purpose of effective ground control.

Jan 1, 1992

By K. Musgrave, E. Solis

"This paper tells the story of how the Dome Mine in South Porcupine increased its maintenance effectiveness and reduced its maintenance costs in two phases. In the first phase, a maintenance audit was conducted, and the results led to some changes that improved maintenance, especially in the underground equipment area. The audit methods, and the changes made will be reviewed. In the second phase, management made changes in the maintenance organization and methods, following a prolonged strike during which management operated the mine. These changes were in part the result of insights learned from their hands-on operating experience. IntroductionEarly in 1989 the Dome Mine of Placer Dome Inc. in South Porcupine, Ontario, decided to improve the effectiveness of the Plant Department. The Plant Department was centralized, except for a mill mechanical crew, and serviced all operations, a townsite of 120 houses, a curling rink, and an arena. The department also operated the powerhouse, the hoists, the mine dry and provided mechanical/ electrical engineer services.At that time the Dome Mine, located in the east end of the city of Timmins and Canada's first large gold mine originally discovered in 1909, was producing about 3500 tons of ore per day with about 742 employees. Over the 83 years of continuous operation of Dome over 50 million short tons of gold ore have been processed. The Plant Department consisted of 156 hourly and 24 staff employees. At present, the mine is producing 4000 tons of ore per day with a total of 341 employees on the payroll. The Plant Department consists of 80 hourly-rated and 18 staff employees."

Jan 1, 1993

By H. R. Manouchehri, A. Weh

"High voltage electric pulse comminution (SELFRAG) relies on inducing electrical breakdown that occurs when the resistivity of a dielectric is insufficient to completely block all transfer of electricity while the conductivity is not high enough to fully accommodate the flow of electricity without considerable changes to the crystal lattice. The technology is based on introducing the electrical discharges into solids immersed in water and placed between two electrodes. The technology has received significant attention since investigations have revealed the potential for fully fragmenting particles or pre-weakening rocks in order to reduce the energy consumption in comminution practices, improve liberation and potentially increase the recovery in mineral processing. Mineralogical analysis of samples showed possible liberation at coarser sizes by high voltage breakage in comparison with conventional mechanical comminution.This study explored the potential of implementing SELFRAG to treat the Sandvik’s Mittersill mine tungsten ore (scheelite) for recovery improvement. Accordingly, standard SELFRAG tests were conducted on four samples from the tungsten process plant to evaluate the energy-breakage relation and potential to liberate the value minerals at coarser size fraction for recovery improvement. The size reduction of the ore after processing with SELFRAG revealed that size deportment occurs at 0.4, 0.2, and 0.1 mm, which indicated potential liberation of gangue and target minerals at respective sizes. In comparison with conventional milling, the difference is the deportment of values into 0.4 mm sizes, which was, to some extent, confirmed by SEM liberation analysis. However, more tests are needed to proof the concept. The study has indicated that, despite consuming more energy in comparison with conventional mechanical comminution, there are promising prospects in liberating the values at coarser fraction and improve recovery by making use of SELFRAG. The energy consumption can be reduced through customized generator and equipment setup, which must be further investigated."

Jan 1, 2016

By Hani Henein

"Heat transfer between droplets/particles and a gas phase plays an important role in the transport of numerous materials processing operations. These include rapid solidification operations such as gas atomization and spray forming, as well as chemical systems such flash furnaces. Chemical reaction rates and solidification are dependent on the rate of gas-particle or gasdroplet heat transport. Using a heat transport model validated using single fluid atomization of molten droplets; the effect of process variables on heat losses from droplets was examined. In this work, the effect of type of gas, droplet size, gas temperature, gas-droplet relative velocity on the heat transport from AA606 l droplets was examined. The most critical of these process variables to heat transfer is identified and will be presented.IntroductionIn materials processing, droplets are often encountered and used in processing a wide range of liquids and slurries. The small size of the droplet enables high reaction rates or high solidification rates in many systems. In order to capitalize on these high rates of transport processes, sprays are· also developed to maximize throughput. The design of these sprays, however, does not account for the transport steps and rate limiting mechanisms at the droplet surface. Rather, spray design focuses on maximizing the break-up of a stream or slurry into small size droplets or controlling the spread of the spray. Spray systems in industrial use typically generate droplets of wide size distribution leading to a wide range of reaction times for each of the droplets. Often the generation of a spray involves a number of coupled phenomena such as stream break-up, droplet-gas transport, droplet size distribution and spray geometry. Using gas generated sprays, it is not possible to identify how individual process variables contribute and control each of these coupled phenomena. While many mathematical models have been developed of sprays and they attempt to simulate coupled droplet transport, they do not provide insight into the contributions of different mechanisms in heat transfer. This is primarily because the basic fundamental heat transport between droplet and gas cannot be isolated from other gas spray phenomena experimentally such as two-way thermal coupling [l]. Thus, experimental validation of heart transfer of large and complex industrial spray models is not carried out. Hence, the validity of spray models remains in question and the approach required to optimize spray processes cannot be clearly identified"

Jan 1, 2004

By Ralph T. Buscarello

For practical purposes, the terms "natural frequency," "resonance" and "critical speed" are synonymous. A part passing though its "critical" or "critical speed" may also be said to be "resonant" or "resonating." The vibrations of a precisely balanced part can be magnified by the structure in which it is assembled. Anyone who has driven an automobile knows that it will vibrate more at a certain speed than at others. According to the formula for centrifugal force, vibration should increase steadily with a rise in rpm. What happens instead is that the vibration not only in- creases with r m. but suddenly rises at a much higher rate through the critical speed, and then apparently smooths out as the rpm passes beyond it. To visualize what happens, consider a simple flat spring with a weight mounted at one end. When the spring is deflected by pulling down on the weight and then letting it go, the spring will oscillate, and the spring-and-weight system will vibrate at its natural frequency. If the timing or direction bf the impulses imparted to the spring did not coincide with its natural frequency, the result would be an irregular vibration that would not build up. If, on the other hand, the timing and direction of the impulses did coincide with the spring's natural frequency, the result would be a larger and larger amplitude. If the impulses were continued indefinitely, the amplitude of the spring's vibrations would go on rising [while its frequency stayed the same] until the spring broke or the amplitude of the vibrations reached an equilibrium [because frictional or other forces would tend to damp it]. Resonance magnifies the amplitude of vibrations in a relatively undamped system between 100 to 200 times over that of nonresonant vibrations. Frictional or viscous damping often reduces the magnification [from 10 to 20 times], but even with this reduction the amplitude would still be large enough to cause excessive wear, and sometimes even fractures. For example, a blower might show only 0.001 in. of vibration on the manufacturer's test stand. Installed, the blower could pass into its critical speed [the speed at which the frequency of the vibrations caused by the rotor coincides with the supporting structure's natural frequency], and the 0.001 in. of vibration could be resonated to 0.010 in., or as much as 0.020 in. The cure for such a condition would not be to lower the vibration of the blower by further balancing or better alignment but to separate the two frequencies by at least 20 to 30%.

Jan 1, 1970

Longwall mining has historically been considered an application for only deep reserves. This has changed in the recent past as longwall has become competitive with surface mining. Many resources marked for stripping now he in the domain of longwall. Today, the best longwall mines compete with strip mines operating in even the lowest stripping ratios. Longwall mining has become more widely applicable than it ever has been in the past and it is now generally considered the method of choice in situations where high levels of coal production are required. But the best way to use longwall mining has become less certain with the opportunities that highwall access provides. Wall-to-wall mining is the use of retreating longwall developed from and retreating toward a highwall. As a surface mine reaches its ultimate highwall, the opportunity for longwall punch mining or wall-to-wall mining is obvious. There are several clear operating advantages to operating a longwall in this way and where highwalls are available, the best economic decision will generally favor planning a direct approach. Yet wall-to-wall is not applicable in every situation even when highwalls are available. Moreover, the advantages of wall-to-wall mining do not always justify the cost of trenching or box cuts to access coal . However, many tactical advantages of operating from the highwall can be realized with the use of specially equipped blind drilled or raised bored shafts. This paper discusses novel techniques for a shaft assisted mining system which permits the addition of conveyor structure and mine systems from the surface to the face for advance and retreat mining with longwall, shortwall or room and pillar panels.

Jan 1, 1998

By Karl Brandt

Longwall panel 580 has recently been retreated in the Zollverein 1/2 seam at a depth of approximately 1000m at Auguste Victoria mine with rectangular rockbolted roadways used for both the maingate and tailgate. Although Auguste Victoria mine has been increasingly using rockbolted support since the mid 1990's. this has previously been restricted to tailgates for single use. This panel represents the first use of a rectangular rockbolted roadway as a maingate at Auguste Victoria mine. As such, it represents a significant change in support strategy. As part of the strategy numerical modelling was used to examine expected behaviour of rockbolted roadways at the site, stress changes during face retreat, the feasibility of adopting rockbolted support for the maingate and the reinforcement pattern required. Monitoring instrumentation was installed in both gates to confirm that the support systems were performing satisfactorily as the gates were driven and as the face was retreated. Although the panel is isolated from others in the Zollverein 1/2 seam, markedly different roadway conditions have been experienced in the two gate roads. Favourable conditions were obtained in the maingate, but particularly difficult conditions were encountered in the tailgate. Previous work for the mine had examined interaction with old workings in other seams and shown a vertical stress of 28MPa for the maingate and up to 45MPa for the tailgate. The values from the earlier work were used in the modelling work described, which showed contrasting results given the different stresses. The difference between the gates can be attributed to the interaction. The paper describes the numerical modelling work, the reinforcement systems adopted, the monitoring results, the interaction effects and the comparison between expectations from the numerical modelling results and the conditions actually experienced.

Jan 1, 2002

By J. M. W. Mackenzie

A microelectrophoresis technique has been used to measure the zeta potential of quartz over a range of pH and ferric iron concentration. The results have been discussed in terms of the adsorption of ferric cations and ferric hydroxide to the quartz surface. Possible relationships between the experimental results and the flotation of quartz have been examined. The adsorption of multivalent cations at the surface of quartz has been studied by many investigators who have used a variety of experimental techniques ranging from streaming potential 1 to radiometric2 measurements. Two possible mechanisms of cation activation of quartz have emerged from the results of these investigations viz: the adsorption of the cation to the negatively charged quartz surface, followed by adsorption of the collector anion to the adsorbed cation site, or: formation of a cation-collector complex which is then adsorbed to the quartz surface. In many natural and industrial systems one of the most prevalent activating species for quartz is ferric iron, this is especially so in the acid-circuit, anionic flotation of iron ore. The adsorption of ferric iron to the quartz surface is complicated by the ability of ferric iron to form complexes with anions, a phenomena which is of minor importance in one of the most widely studied quartz activation processes, ca ++ activation.* *The pK value for [ca(oH)+]/ [ca2+] [oh-] is 1.46 indicating that the influence of Ca (OH)+ ions will be minor in all but strongly alkaline solutions. In order to obtain a better understanding of quartz activation by ferric iron the zeta potential of quartz in the presence of ferric iron has been measured over a range of pH and ferric iron concentration. EXPERIMENTAL METHODS Materials: Selected samples of "rock clystal" quartz from New England, N.S.W., were ground in a pebble mill, washed for three hours in boiling concentrated hydrochloric acid, washed in hot chromic acid and then washed repeatedly with distilled water until the washing water gave no trace of chloride ion.

Jan 1, 1967

By Charles Fettke

The deposits described occur in a belt starting 1 ½ miles east of Juncos and extending 6 miles in a southeasterly direction. They are of the contact metamorphic type, being associated with a limestone and calcareous tuff that is interbedded with andesite tuffs and andesites which have been invaded by a quartz diorite intrusion. Of the fire occurrences examined, the largest can be traced for a horizontal distance of 2000 ft. No mining has, been done, but some of the outcrops lead to the belief that deposits of commercial size are present. IN CONNECTION with the gathering of data for a report on the geology of the Humacao district of southeastern Porto Rico during the summer of 1916, under the auspices of the Scientific Survey of Porto Rico and the Virgin Islands, conducted by the New York Academy of Sciences, the writer had an opportunity to make a brief examination of the magnetite deposits of the eastern portion of the island. Inasmuch as these deposits have attracted some attention as possible future sources of iron ore, and as there is only scanty reference made to them in literature,1 a short description based on this reconnaissance survey was deemed to be worthy of record. The magnetite deposits of eastern Porto Rico occur in association with a belt of limestone, trending approximately S 53° E, which begins 1 ½ miles east of Juncos and can be traced for about 6 miles toward the coast. Four outcrops of magnetite were observed, which are designated

Jan 2, 1924

By Stephen P. Signer

This paper presents the results of a case study conducted in a two-entry gateroad in a coal mine where excessive roof deformation and bolt loading resulted in failure of many roof supports. The instruments consisted of 16 fully grouted, strain gaged resin bolts, load cells on both full and partially grouted cable bolts, and vertical deflection multipoint extensometers. These instruments were installed on-cycle to measure loading on bolts in an existing support pattern and to determine if cable bolts could be used to improve roof stability. Results showed significant amounts of movement within the bolted zone. In sonic cases, these movements were enough to load the supports past their ultimate strength. Geology appeared to be a significant factor in localized roof degradation; that is, a very weak rock layer in the immediate roof overlain by a very strong rock layer contributed to the development of shear planes. Only one instrumented bolt had a maximum strain of less than 2,000 microstrain, which was the yield point of the steel. The average maximum strain on all bolts was 20.000 microstrain. However, electrical continuity to many gages was lost, and a pattern was noted that would indicate possible bolt failure. Wire mesh and concrete cans installed as secondary support performed very effectively.

Jan 1, 1998

By J. O. Marsden

The Candelaria copper-gold mine is located approximately 25 km south and east of Copiapo in Region III, Chile. The original concentrator was designed to treat 28,000 t/d (30,800 stpd) of chalcopyrite-bearing ore through a circuit consisting of a single 11.0 m (36 ft) diameter SAG mill, two ball mills, conventional rougher and scavenger flotation, column cell cleaner flotation, and ceramic disc filtration. The plant was commissioned in August 1994 and quickly reached capacity and expected levels of metallurgical performance. In May 1996, a decision was made to double the capacity of the concentrator by the addition of a second line of equipment. The expanded facilities were commissioned in October 1997, less than 18 months after the decision to proceed, and well within the budget. The original concentrator facilities were replicated or duplicated as much as possible, however, a number of important equipment changes were made to take advantage of industry developments since the original concentrator was designed. These included the use of Eimco 120 m3 (4,200 ft3) cells for rougher and scavenger flotation and the installation of a Svedala VTM -800 Vertimill for regrinding. This paper describes the rationale behind these changes and explores the reasons for the success of the project.

Jan 1, 1999

By James P. Kimball

Jan 1, 1885

By KNona C. Liddell

"Many metal recovery processes involve heterogeneous reactions in porous media accompanied by fluid flow and mass transfer. Modeling such systems is difficult because of the number of rate processes involved and is complicated even further by effects due to the structure of the porous medium. Data on even bulk properties of the medium are often severely limited or unavailable. For many such systems, a cell model may provide an attractive alternative to models based on transport mechanisms in a differential volume. A cell model requires less input data and is computationally efficient. Identical residence time distributions can be obtained with models of both types, and both allow conversion and concentration profiles and histories to be calculated. The formulation and properties of cell models for metals recovery are described in detail.INTRODUCTIONSubsurface mineral leaching, metal ion recovery and environmental remediation are significant modeling challenges. They involve one-, two-, or three-dimensional reactive flow in multi reaction open systems. Dissolution, adsorption, and ion exchange occur at reactive mineral surfaces, and these heterogeneous reactions are accompanied by acid-base, complexation, and redox reactions in the solution phase.Two approaches have been taken to reactive flow problems in geologic media: mixing cell and transport models. Mixing cell models, the subject of this review, are based on a network of connected cells, each with a specified number of input and output streams. Mixing cells are assumed to have no internal solute concentration gradients, that is, each cell behaves like a well-stirred tank. Gradients are represented by step changes between connected cells; this results in a model that is spatially discretized at the outset. Different methods of discretizing the model equations are considered more fully below. Although this is not strictly necessary, it has usually been assumed in subsurface flow applications that all cells in the network have the same volume and identical initial properties."

Jan 1, 1996

By L. A. Rapoport, W. J. Leas, C. W. Carpenter

A program of scaled flow model experiments has been undertaken to study the performance of five-spot water floods. The modeling procedures are discussed and the construction and operation of the flow models are described. The tests were specifically designed to investigate the effects of injection rate and of oil-to-water viscosity ratio on oil recovery. The areal sweep of five-spot water floods was also studied, and direct comparisons between five-spot and linear flooding behavior have been established to permir better utilizatfon of core analysis results for purposes of field waterflood evaluations. INTRODUCTION For a long time reservoir engineering procedures have been confined to the consideration of idealized, one-dimensional or linear systems.11* However, direct application of the linear waterflood mechanism to the evaluation of actual field performance is justifiable only for the purposes of rough approximation. To obtain a realistic analysis of field behavior, it is necessary to account for reservoir geometry and well distribution, and to take into consideration the configuration of the flow of fluids between injection and producing wells. In the past it has been attempted to account for the complex nature of the fluid movement in the reservoir by associating each well pattern with a certain "sweep-efficiency constant", e.g., a sweep efficiency of 72 per cent for the conventional five-spot pattern.' More recently, methods of waterflood evaluation have been improved by the introduction of variable sweep-efficiency factors, defining the areal coverage as a function of cumulative water injection and viscosity or "mobility" ' ratio.""' These variable sweep-efficiency factors, derived from miscible fluid displacement experiments, require the assumption of piston-like displacement of oil by water. This implies that only one fluid, either oil or water, is moving at any one point of the reservoir ht any moment. Such an assumption, however, is incompatible with the bulk of the experimental evidence and also theoretical considerations which indicate that usually in the area invaded by water, both oil and water are flowing in varying proportions, in accordance with the relative permeability characteristics of the porous medium. Another recent approach toward the evaluation of five-spot flooding behavior involves correlations of the areal sweep efficiency (observed in immiscible fluid experiments) with a "mobility ratio," based on the consideration of the "average" relative permeability to the displacing fluid. Combination of these correlations with a modification of the Buckley-Leverett frontal-drive equation leads to a computational procedure for predicting the recovery performance of areal water floods. While of considerable interest, this approach has no complete theoretical justification and, therefore, does not entirely clarify the features of five-spot water floods. Rigorous, theoretical treatment of waterflood behavior in two- or three-dimensional systems as encountered in the reservoir, including proper consideration of relative permeability and capillary-pressure functions, is as yet beyond the scope of analytical or computational methods. The, behavior of such water floods can, however, be studied by means of scaled flow model ekperiments, which is the approach followed in these investigations. The flow model experiments described in this paper simulate a uniform, horizontal formation of constant thickness with fully penetrating wells. The system under consideration is entirely liquid saturated and not influenced by compressibility effects, which is representative of the situation achieved after gas fill-up under practical conditions. Gravity segregation effects are assumed to be negligible, which implies a relatively thin reservoir formation and/or low vertical permeability. THEORETICAL CONSIDERATIONS For a flow system of uniform thickness with no appreciable effects of gravity segregation, the analysis of water-oil displacement can be confined to a two-dimensional treatment based on the consideration of a "slice" of unit thickness. Referring to previously established derivations," the displacement of oil by water in such a system can be described by the following, dimen-sionless equations:

By E. C. Reed

Drilling activity in Nebraska during 1945 continued to decline slightly over that of the previous year. Eight tests for oil and gas were completed during the year, of which seven were wildcats and resulted in dry holes. The eighth test, an inside location in the Dawson field of Richardson County, yielded an initial production of about 3o bbl. per day with 86 per cent water from the Hunton formation. Five wells were drilling at the end of the year, two of which were wildcats. Two of the drilling wells were deepening operations in the Dawson and Falls City fields and the third was an inside location in the Falls City field, which appears likely to result in a producer. Most of the operations were in Richardson County but two wells were drilled in Dawes and Gage Counties and one each was drilling in Holt and Washington Counties at the end of the year. There were no new discoveries of oil or gas.

Jan 1, 1946

By W. B. Price

AT the New York meeting of the American Institute of Mining and Metallurgical Engineers held in February, 1926, W. H. Bassett and J. C. Bradley presented a paper entitled "Exudations on Copper Castings."' The purpose of the present paper, as the title suggests, is to call attention to somewhat similar phenomena which the authors have encountered in brass and bronze. From a study of the examples given, a more-or-less speculative theory of "inverse segregation" is advanced. Protuberances on Admiralty Brass In the rolling mill of the Scovill Manufacturing Co., there have been found quite commonly bars of certain alloys which had a sort of shaggy roughness on the surface due to slight metallic protuberances. No special attention was paid to these until some bars were found on which these protuberances were heavy enough at the bottom of the bars to produce a blistered appearance. A sample of the protuberances was milled off the surface of the bar illustrated (Fig. la) and upon analysis was found to contain 66.66 per cent. copper, 4.02 per cent. tin and 0.03 per cent. lead, whereas the average composition of the bar was 70.21 per cent. copper, 1.21 per cent. tin, and 0.01 per cent. lead. A sample of the shaggy-rough protuberances at the very top of a bar was also analyzed and was found to contain 2.45 per cent. tin, indicating that it was probably of the same origin as the blistered areas. These results were not entirely unexpected for previous analyses of this alloy had revealed that the surface was richer in tin than the rest of the bar. This, of course, is contrary to what we would expect from a consideration of the equilibrium diagram and has been called "inverse segregation." Fig. 16 is a cross-section of a bar through the protuberances on the surface. It reveals that there is a decidedly different structure through the raised areas and seems to indicate that the bar originally solidified

Jan 1, 1927

By H Mansouri, M A. Ebrahimi Farsangi, F Faramarzi

A blast fragmentation model is developed based on the gamma function to describe the run-of-mine fragmentation distribution. The model presented is aimed to benefit from simplicity in application and also to be efficient in description of the fine to coarse part of the blast rock fragments. In fact, the gamma based model (KC-KUM), gives a unit distribution curve, which is made up of two separate equations, covering different fragment sizes in the muck pile. The generated values of the fines to central part of the equation and the central to coarse part of the equation are connected at the 40 per cent grafting point. For validation, eight production blasts, which were specially designed for this purpose, were carried out at an iron ore mine (Jalal-Abad iron ore mine/Iran). Results achieved by KC-KUM and two of the most well-known models. Kuz-Ram and Swebrec, are compared with measured data. Moreover, to assess the models’ efficiency in presenting the best distribution curve, a Logarithmic error method is chosen. Based on the achievements. KC-KUM has the least deviations by the least absolute log error of 0.52, whereas the values obtained for the Swebrec and Kuz-Ram models were 0.79 and 1.34 respectively. Furthermore, the models were applied to predict X80 for 12 production blasts carried out at Gol-e-Gohar iron ore mine/Iran. These predictions were compared with the results from these trials. The coefficient of determination (R2) and root mean square error (RMSE) are calculated. Consequently, the highest R2 was obtained for KC-KUM at 0.837 with the least RMSE of 11.31. On the other hand, R2 and RMSE are equal to 0.832 and 20.19 for Swebrec; and 0.813 and 19.75 for Kuz-Ram respectively. The results obtained suggest the superiority of the KC-KUM model over the other two models in assessment and prediction of blast fragmentation in a reliable way.CITATION:Faramarzi, F, Ebrahimi Farsangi, M A and Mansouri, H, 2015. Prediction of rock fragmentation using a gamma-based blast fragmentation distribution model, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 685–692 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By A. Anderko, V. G. Papangelakis, G. Moldoveanu, G. Azimi, M. Carlos

"OLI Analyzer is a software package that uses the powerful Mixed Solvent Electrolyte (MSE) model to simulate the behavior of multicomponent electrolyte solutions from infinite dilution to the limit of fused salt, and from temperatures below the freezing point up to near critical temperature of the mixture. The software also allows the creation of thermodynamic parameters for new chemical systems unavailable yet in public-domain or commercial software databanks. This communication reviews the basics of the model and provides some examples of modeling hydrometallurgical applications with emphasis on high temperature applications, including calcium sulfate scale formation in autoclaves, high temperature pH inference and iron control. INTRODUCTIONModeling of electrolyte systems has been of particular interest to various industrial processes, such as separation processes (e.g., solution crystallization, extractive distillation, seawater desalination or bio-separations), environmental applications (e.g., gas treatment, wastewater treatment or chemical waste disposal) and hydrometallurgy (e.g., pH control and neutralization, iron control, scaling and fouling of equipment). Using a chemical model, time-effective predictions of various properties of electrolytes can be obtained, which is beneficial not only during process monitoring, but also during process optimization and process scale up. As a result, pilot scale studies can sometimes be eliminated where budgetary constraints exist. Development of such a powerful model requires the use of a speciation-based model, in which solution chemistry is explicitly addressed (as compared with some models that treat electrolytes either as undissociated or fully dissociated systems), despite being computationally challenging. In addition, as a feature of electrolyte systems, speciation equilibria inherently influence the phase equilibria due to complex formation, ion pairing, and acid-base reactions. Therefore, how the electrolyte solutions behave at various conditions may differ significantly due to the non-ideality, which must be carefully addressed to obtain a model that is applicable to a wide range of conditions such as concentration, temperature, pressure and solvent system."

Jan 1, 2012

[Queensland :-(Continued.) petrography of the Mount Morgan mine, LV, 263. Queensland tin mine and mill, Santa Barbara, Guanajuato, Mex., XXXVI, 227. Quenner disintegrator, XLI, 801; XLII, 15011. Quenstedt, F.: petroleum deposits, Suabia, XLVIII, 14881. Queretaro, Mex., silver mines, XXXIX, 360. Quicksilver: mining and reduction, LI, 110. Oceanic mine, Cambria, Cal., LI, 110. Quicksilver and iron decompose silver sulphide, XL, 872. Quicksilver deposits: China, -XL111, 49. Pacific slope, XXXVI, 1311.. Siberia, Vhdivostok district, XLIV, 16001.]

Jan 1, 1918

By Y. P. Chugh

The paper discusses laboratory and field studies to analyze time-dependent deformation behavior of immediate weak floor strata in an Illinois coal mine. In the laboratory, core samples of the immediate floor strata were subjected to incremental creep tests under unconfined compressive stress. Both axial and lateral creep deformations were recorded. Time-dependent behavior was reasonably characterized by a Burger model with one Kelvin-Voigt unit. The elastic and viscous parameter8 of the model were found to be stress-dependent, but in the range of 40% to 80% of the failure stress, the effect of stress was relatively small. Therefore, a linear visco-elastic model was developed to represent the laboratory time-dependent behavior of immediate floor strata. Such a model may be acceptable for the design of partial extraction mining systems having extraction ratios of 40% to 60%. Field observations of roof-floor convergence (floor heave) at the mine also indicated a time-dependent behavior similar to that observed in the laboratory. Field time-dependent behavior was also characterized in terms of a Burger model with one Kelvin-Voigt unit to obtain scaling factors between the field and laboratory parameters. This approach should help in predicting likely floor heave in the mine based on laboratory creep tests. It was concluded that additional studies in the field are required to arrive at more reliable correlations between the two sets of parameters.

Jan 1, 1987