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By M. Loan

The Zinifex's Hobart Smelter uses the paragoethite process to remove dissolved Fe(III) from concentrated zinc leach liquors. This produces a residue consisting primarily of 6-line ferrihydrite (a hydrated Fe(III) oxyhydroxide), several insoluble components derived from the calcined zinc concentrate neutralization agent and other precipitated phases, such as jarosite and silica. The precipitation of 6-line ferrihydrite in the paragoethite process was studied using a laboratory-scale continuous crystallizer, and the conditions were selected to limit high levels of dissolved silica and jarosite. This approach allowed the reactor pH and the rate of precipitation to be correlated with residue solid-liquid separation, particle size, morphology, residual zinc and sulfate concentrations, and phase formation (e.g., goethite, jarosite, schwertmannite, and 2- and 6-line ferrihydrite). These studies delineated the mechanism of 6-line ferrihydrite precipitation in the kinetically controlled paragoethite process, and its inter-relationship with goethite and jarosite precipitation under conditions where 6-line ferrihydrite is favoured. Unexpectedly, the generation of a more crystalline goethite precipitate with larger "primary" particle size did not produce a residue of improved properties, as bulk aggregates dictate the physical properties of the residue and not the crystallinity. Furthermore, it is difficult to precipitate 2-line ferrihydrite or schwertmannite under existing paragoethite process conditions.

Jan 1, 2006

By C. H. Mathewson

COPPER and the copper-base solid solutions readily form twin crystals when plastically deformed at a suitably elevated temperature or annealed after cold deformation. In fact, no feature of the microstructure of these materials is more prominent or characteristic than these straight-sided bands or simple lines of division which sometimes come from groups of thin polysynthetic lamellae, penetrating part way or wholly through the parent grain substance, but often divide the grain into a few or perhaps only two crystallographically related parts. Nearly always the bands as seen in the usual microscopic examination of a specimen come into vivid contrast with the adjacent crystalline material owing to the inherent difference in orientation. Bands which under special conditions of orientation cannot be seen with vertically incident light are often visible under oblique illumination and, when this fails, contrasting effects usually may be obtained by using polarized light. There is no longer any doubt that these synthetic banded structures obtained in the ordinary course of working and annealing are due to twinning of the spinel type which was observed long ago in a number of metals crystallizing in the isometric system.1 It has been customary in metallurgical literature to designate these synthetic twins, which grow into prominence during an annealing process, as "annealing twins" without regard to the actual mode of their formation, which is, indeed, obscure and with scant recognition of the fact that prior deformation is essential, no twins having been observed in metal of known unstrained history. This is questionable; especially in view of. the fact that in a number of metals and minerals, reorientation into the twin configuration is known to occur as a result of a simple shearing mechanism along the recognized twinning planes and the

Jan 1, 1930

By Yinchang Wang

1. INTRODUCTION 1. Subject, and Scope The formation of the oxidized ores of zinc has been recognized as a subject of great importance in economic geology. For many years these ores have been much sought, partly because they are more desirable for metallurgical treatment and partly because they are apt to be freer from gangue than is the sulphide of zinc. Up to very recent years the oxidized ores were the principal source of the metal and at present they still furnish a large portion of the commercial production. . The oxidized ores of zinc include six minerals, as shown in the-following table

Jan 9, 1915

By A. Adams

The Bureau of Mines determined the composition of the vapors liberated during thermal decomposition of aluminium nitrate nonahydrate. Small samples were heated from room temperature to 5500 C with initial heating rates from 500 to 2000 C/min. Gases were rapidly swept away from the heated chamber with Ar and subjected to immediate analysis in order to minimize reaction between the components. In addition to H20, four N-containing compounds were identified: HN03, N02, NO, and N20. Nz could not be determined in the presence of the nitrogen oxides, and at-tempted separation from the oxides led to the formation of more nitrogen. Relative amounts of each component were found to vary over a period of time; however, total amounts measured with different heating rates were reasonably constant and were typically as follows: 84.2 pct HN03, 7.1 pct N02, 4.3 pct NO, and 4.2 pct N20. HN03 and NO were determined from chemical reactions with a permanganate solution, N20 was measured with a mass spectrometer, and NO2 was measured with a spectro-photometer. Details of the methods used are described. Since NO2 and NO can readily be converted to HN03, about 96 pct of the N from the decomposition can be recovered as HN03

Jan 1, 1987

By Chaluvadi K. Sridhar, Prashanta K. Chatterjee

"IntroductionThe planning of an underground coal mine requires a complex blend of technical expertise, experience and subjective design criteria implemented by the mining engineer. Currently the procedure is largely manual and requires considerable resources to generate a single mine plan. Often three or four people are assigned to work in the development of a single draft layout. Evaluation of the layouts is also tedious as it requires many repetitive calculations. The evaluation of layouts developed manually generally attempts to derive a single economically feasible solution. Operational constraints in underground coal mining such as manpower, time, equipment, etc., do not allow the generations of more than one alternative layout. As a result, the first plan is generally the only one considered.Computer-aided mine planning can automate many of the manual procedures and calculations involved in mine planning thus allowing to evaluate man y layouts and mining strategies and to select the optimum plan with confidence. An optimized planning procedure will also provide the capability to evaluate mine performance continuously and critically, thereby helping to maximize return on investment. Although recent advances in computer graphics have provided the hardware necessary for developing and evaluating min e plans rapidly, software that will allow the mining engineer to make use of the new technology is slow in developing. The need for such software packages has been recognized and ackowledged.At several sessions in recent conferences on the applications of computers in the mining industry, the use and benefit s of computer-aided mine planning were discussed. However, there were few papers presented that referred to actual applications of interactive graphics to underground mine planning. The emphasis of this study is toward the development of a completely integrated computer-aided underground mine planning package that integrates geological modeling, engineering design and planning"

Jan 1, 1986

By A. Arik

1his paper presents a modified ordinary kriging technique referred to as the "Nearest Neighbor Kriging" (NNK). The method is a simple and practical tool to use when the ordinary kriging (OK) results are unreasonably smooth, especially when estimating recoverable ore reserves for deposits with skewed grade distributions. NNK is robust and globally unbiased like OK. However, it is more advantageous over OK because it can control some of the smoothing and conditional bias which have been the major pitfalls of OK in many grade estimation cases. The paper details the methodology of NNK and its application to a gold deposit.

Jan 1, 1998

By Jafar Safarian

Bauxite is the main raw material used for the production of alumina (Al2O3) through the well-known commercial Bayer process. This process has significant challenges such as limitation in using low-grade bauxites as they contain significant amounts of impurities such as Fe, Si, Ti. The Bayer process residue, which is known as red mud, is also a global environmental challenge due to huge amount of this low value residue production. An alternative sustainable process with high potential to solve these problems and produce valuable and consumable by-products is a pyrometallurgical-hydrometallurgical process in which the low-grade bauxite ore is treated through a smelting-reduction process, yielding iron alloys and a calcium-aluminate slag. Alumina is then produced from the slag by hydrometallurgical treatment. In the present work, the reduction of pellets produced from different bauxite ores by hydrogen is studied and it is shown that complete iron oxides reduction is possible. Further smelting and smelting-aluminothermic reduction of the reduced pellets show that iron and silicon ferroalloys can be produced, in addition to a proper slag for alumina extraction.

Mill #4 processes mildly refractory ore from Carlin Trend deposits. Diagnostic analysis of plant operating data was used to generate a mathematical model containing the important parameters influencing gold recovery. The model was used to direct modifications to plant operating practice. The cyanide-dosing strategy was changed to reduce gold losses from preg-robbing and to cut reagent consumption. A finer grind was achieved without capital investment. The density in the carbon-in-leach circuit was lowered, and tighter control was exercised over the plant throughput. These changes resulted in a recovery increase of at least 2%, worth $111,000/month at $300/oz ($9.64/g) gold, and concomitant reagent cost savings of $55,000/ month.

Jan 1, 2000

By George H. Schnakenberg

Automation of coal mining activities at the face offers improvements in worker safety, health, and productivity. Introduction of integrated computer-sensor systems to current mining machines will enable these machines to perform some of the most hazardous tasks through supervised teleoperation. The U.S. Bureau of Mines is pursuing the development of the enabling technology necessary to achieve this goal. The research program consists of both basic and applied research, each focused on the fundamental issues of computer and sensor technologies. Short-term research is directed to providing computer-assisted, remote supervisory operation of present underground equipment; the long-term goal is the development of progressively more intelligent mining systems. The research program includes a review of robotic machine and autonomous vehicle technologies and of current mining technology, which provides a base for developing innovative mining methods; research in navigation and guidance technology, emphasizing control of a continuous mining machine; research on coal-rock interface sensing technology for horizon control, and rib thickness control in highwall mining; the development of computer systems and hierarchical architectures for real-time control; and development of expert systems for machine system fault diagnostics and predictive maintenance. This report presents a brief background and the current status for each of these research areas.

Jan 1, 1989

By Y. Luo

Surface subsidence process due to underground coal mining often has the potential to cause problems to buried pipelines. In this paper, a technique for assessing the stress level on a subsidence-affected pipeline is introduced. The main contributors for the stresses on the pipelines are identified. Mitigation techniques for reducing the stress on the pipeline have been proposed and successfully tested.

Jan 1, 1997

By B. T. Brady

Rock mechanics, like all engineering disciplines, must have a theoretical foundation. The subject of this chapter is the formulation of analytical methods that may aid in the rational design and determination of the stability of engineering structures in competent brittle rock materials. By an engineering structure in rock, we mean any (1) excavated sub- surface opening, (2) open surface structure, or (3) system of openings in rock that is virtually self-supporting-that is, not requiring artificial systems to carry structural stresses.

Jan 1, 1970

By Leonard B. Rothfeld

For many years, pulverized coal (PC) boilers in utility power plants have been the dominant market for domestic coal. Today, two new coal utilization technologies challenge the PC boiler's dominance. Atmospheric fluidized bed combustion (AFBC) and "coal gasification/combined cycle" (GCC) stand on the verge of commercial demonstration in the utility environment at a scale of 100 MW. Developed over the past decade, these technologies respond to the demands for cleaner ways to burn coal and for more flexibility in fuel supply. In the near term, these are the "clean coal" technologies most likely to have a significant impact, because they are ready for commercial application. As for environmental acceptability, consider that just a few years ago one of the environmental slogans was "no coal in California." Indeed, the only large quantities of coal above ground in California at that time were in transit on the way to Asia. Today, thanks to new technology, we can point to two operational coal-burning plants in California and one in the works: * Cool Water GCC demonstration plant (100 MW) * California Portland Cement AFBC commercial cogeneration, near Riverside (190 000 lb/hr steam) * Energy Factors AFBC commercial cogeneration at Stockton, to be operational 1988 (44 MW)

Jan 1, 1987

By David C. Mulder

As a result of the dramatic growth of Edmonton, Alberta during the past decade and the rapidly increasing price of natural gas, Edmonton Power has received provincial government approval to construct and operate an 8O0-megawatt- capacity coal-fired thermal generating station at Genesee, about 50 km southwest of Edmonton. The power plant will consist of two 400-megawatt steam-driven thermal generators, with provision in the future for two or more additional units. The coal will be hauled by truck from the nearby three-million-tonnes- per-year strip mine, with economically recoverable reserves exceeding two hundred million tonnes. Edmonton Power controls a major part of the coal leases in the area, and is working with other lease holders in developing the most efficient mining plan. A natural depression was selected as the site for the 600-hectare cooling pond to provide water for the power plant. Edmonton Power is working closely with the people in the area to ensure that their rights and concerns are communicated and recognized by all parties.

Jan 1, 1981

By Y. Lizotte

The purpose of this paper is to describe a stochastic simulation program used to assess several dispatching rules applicable to small scale computerized systems for optimizing truck/shovel productivity. The system studied is semi-automated with a dispatcher communicating instructions by two-way radio. The simulation program is structured on an advance clock approach which enables the insertion of dispatching rules at various points in the haulage net- work. The rules tested include minimize shovel idle time, maximizing immediate truck use and assigning trucks to shovels to meet specific production objectives. A variation of the traditional "Match Factor" is implemented to maintain fleet balance throughout the shift. A mine case study demonstrates how the dispatching rules increase productivity of such semi-automated dispatching systems. Practical problems involved in the implementation of small computerized dispatching systems are also discussed.

Jan 1, 1986

By M. Venkatraman

The limit of Hall - Petch relationship in ultra fine grained steels has been examined based on dislocation pile-up mechanism. When the grain size becomes small the dislocation multiplicity ceases resulting in very low work hardening rate in these materials. An approximate analysis of the theories of hardening indicates that H-P relation is obeyed up to 100nm. It appears that grain refinement is not the suggested approach to improve toughness as well as strength below a critical size.

Jan 1, 2004

By C. A. Stetefeldt

Jan 1, 1892

By J. H. Schuenemeyer

Consider a set of points, some of which are anomalous (larger than a specified cutoff value), located on a plane. Whether some or all of these points are clustered to form one anomaly or more or, alternatively whether these points are scattered at random, may be investigated by measuring perimeters of convex hulls. A convex hull is the smallest convex polygon that will encompass a group of points. (Examples of convex polygons are triangles, rectangles, and all other regular polygons.) A set of anomalous points is selected and the perimeters of the convex hulls of this set and all its subsets are measured and compared with tabulated values of perimeters for each subset size. For a given subset size consider those perimeters which are less than the tabulated perimeter. If the number of convex hulls is greater than the maximum number expected by chance, then the chance that any one of the observed-hulls-is a nonrandom cluster is the ratio of the observed number to the sum of the observed and the maximum number expected by chance. Otherwise, the points are evidently not clustered. If many sample points are anomalous, an alternate model defines various configurations of contiguous points and compares the observed number of configurations per unit area with the expected number. Applications are discussed in several fields of geology and geochemistry-including geochemical exploration surveys and heavy mineral spatial distributions--as well as in mining (dust control) and medical geography.

Jan 1, 1972

By T. Orupold

This paper covers the commercial development of gravity separation of fine particles using a Lamella High Shear Rate REFLUX? Classifier (REFLUX? Classifier), focusing primarily on coal applications. The REFLUX? Classifier is a fluidized bed device that incorporates a system of closely spaced parallel inclined channels located above the fluidized bed. These channels make it possible to achieve a significant suppression of the effects of particle size, resulting in a highly effective separation on the basis of density. The improved gravity separation performance is shown to be remarkably high, with a significant reduction in the variation of separation density with particle size, and a significant reduction in the change in Ecart probable error (Ep) with size. The first full commercial-sized units of the REFLUX? Classifier were field-tested in late 2009 in coal applications. More recently, the technology has been applied in fine particle separation in minerals applications and there are a number of full-sized units operating in chrome applications in South Africa. Initially, pilot-scaled units (typically the RC?300) were trialled in iron ore, mineral sands, and manganese plants amongst other minerals, typically after other technologies failed to achieve the desired results. Currently a number of laboratories globally are carrying out more testing in minerals applications. More than 50 RC? units are now operating in coal and minerals applications. This paper introduces the REFLUX? Classifier technology, identifies commercial applications, and gives some commercial results.

Jan 1, 2014

By Henry S. Rawdon

Any laboratory corrosion test, as judged from the practical point of view, is valuable only to the extent that it foretells what will, in all probability, occur in service. Such a test is most properly to be considered as a "pilot test," that is, a test which indicates the direction along which action may be expected to occur rather than as a truly quantitative test which would be expected to tell just how and to what extent the action would proceed. It is generally recognized that laboratory corrosion tests should be chosen with particular reference to the character of service expected for any particular type of metal, so far as it can be foreseen. Even when this requirement has been fulfilled, however, the question whether the actual service behavior of the material is in accordance and general agreement with predictions based upon such laboratory tests is always a pertinent one. The information available in the technical literature bearing on the correlation between the service behavior of metals from the corrosion standpoint, and the results obtained with the same metals in laboratory corrosion tests is very meager, indeed. The results which have been obtained in weather-exposure tests of sheet duralumin which form the body of this discussion are presented here for their bearing on this particular phase of the problem of the corrosion resistance of duralumin. Although the exposure tests described have not been completed, in the sense that all of the tests, in the series initially laid down, have been accomplished, still the general trend shown by the results is so clear that a number of definite conclusions at this stage (subject, of course, to possible modification in the light of later results) are believed to be warranted. The tests reported upon here form one phase of the much broader study of this subject which has been under way for several years in which the National Advisory Committee for Aeronautics, the Bureau of Aeronautics of the Navy Department, the Army Air Corps and the Bureau of Standards have cooperated. Without the very helpful cooperation of the manufacturers in furnishing the

Jan 1, 1929

By O. W. Ellis

THE question of the influence of gases upon the properties of copper has received the attention of a number of investigators, among whom Sieverts,1 Iwasé,2 Lobley and Jepson3 stand preeminent. SOLUBILITY OF . GASES IN. COPPER Sieverts and Iwasé concerned themselves with the solubility of a variety of gases in the metal in the solid and liquid states. They determined the absorption coefficients of these gases and in all cases found a sharp change in solubility at the melting point of the metal. In this respect they disagree with Lobley and Jepson, who have based their opinions upon the appearance of small ingots of the metal which had been fused in an atmosphere of one or other of three gases and had then been rapidly cooled, while surrounded by gas, to the freezing point (rate-possibly 30° to 60° C. per sec.). The ingots that had been fused and cooled under nitrogen and carbon monoxide were free from blowholes and it was assumed that these gases were not absorbed in amounts much in excess of those which would dissolve in the solid metal; the ingots similarly treated under hydrogen were full of blowholes and it was assumed in this case that gas was ejected on solidification of the copper. The effect of varying the rate of freezing upon the character of the test ingots was not examined by these investigators; otherwise, it is felt, their views might have been subject to modification. Sieverts' most important contribution is that the solubility of a gas in any metal is proportional to the square root of its pressure or concentration. Knowing then the absorption coefficients of the various gases in copper, it should be possible to determine the analysis of the

Jan 1, 1928