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By Steve Rogers

Nautilus Minerals was listed on the Toronto Stock Exchange in May 2006. The company now has major mining companies Anglo America (5.7%), Teck Cominco (7.2%) and Epion Holdings (22.4%) as significant shareholders, and has raised approximately $US346 million dollars to develop the world's first deep-water mine. The company is currently targeting high-grade copper and gold in seafloor massive sulphide mineralization, located near plate boundaries in back-arch basins of the Western Pacific. The first mine scheduled to be developed by the company is located in 1,600 meters of water at Solwara 1, in the relatively quite waters of the Bismarck Sea approximately 50 km from the port of Rabaul, within the Territorial Waters of Papua New Guinea. During 2006 and 2007 the company completed detailed environmental and geological studies, culminating in a number of world firsts, including the world?s first NI 43-101 compliant resource statement and environmental impact study for a seafloor massive sulphide system. Permitting is well advanced for the project, with initial production scheduled for late 2010, subject to timely grant of the permits. Extensive government and stakeholder liaison and engagement has been undertaken throughout the projects life, and is a core feature of Nautilus' desire to "do it right" in all aspects of this new industry.

Jan 1, 2008

By Roy Norcross

For the past few years Caro's acid has been used for the treatment of cyanide containing slurry effluents, providing a feasible alter­ naive to other slurry treatment processes including !NCO SO2 / Arr and ferrous sulfate. Presently, mines using Caro's acid gen­erate their own Caro's acid onsite making a relatively low quali­ty product. It was at this point where we, at Degussa Corporation, decided to focus our efforts on engineering a Caro's acid genera­tor capable of cost effectively producing a high quality Caro's acid solution, thus reducing operating costs significantly. Caro's acid or peroxymonosulfuric acid is not a new chem­ical nor is it new to Degussa. The product was named after Heinrich Caro (1834-1910), a German chemist who first described its synthesis and its oxidizing properties in 1898. Degussa has been producing the potassium salt of Caro's acid as the triple salt, 2KHSO5 - 2KHSO4 - K2SO4, called Caroat®, for over 30 years. Caroat® is used for household and denture cleansers, as a bleaching agent in dish washing detergents, in printed circuit board etching and for cyanide destruction in the plating industry. From our experience in producing Caroat® Degussa developed its new Caro's acid based DegOX™ technology for the treat­ment of cyanide containing effluents from gold and silver mines.

Jan 1, 1996

By K. Oishi

We have developed a 76Cu-3Si-21Zn alloy "ECOBRASS®" containing no lead. When 3% Si is added to a 78Cu-22Zn alloy, kappa and gamma phases participate uniformly in the alpha matrix. When being machined, stress concentrates on these hard phases, namely kappa and gamma, and thereby lowering the required cutting force and yielding segmentalized chips without lubricant. Kappa and gamma phases transform into beta phase under high temperature, which makes it easier to extrude and/or forge the alloy. When 0.08% P and 50 ppm Zr are co-added, the grains of ECOBRASS® castings are refined significantly to become as small as several dozens of micrometers. The grain refinement by the co-addition of P and Zr improves castability, tensile strength and elongation of ECOBRASS® castings. Meanwhile, the lead leachate from an ECOBRASS® water meter, field-tested in pH 6.8 drinking water for one year, was less than 5 ppb without correction. No indication of dezincification corrosion was observed, either. ECOBRASS® is equally suitable for rods, forgings and castings, and makes it possible to produce a complete set of plumbing parts (valves, faucets, etc.) by its own. This way, not only improving recyclability, ECOBRASS® also realizes size and weight reduction due to its good corrosion resistance and high strength.

Jan 1, 2007

By R. P. Vinson, D. P. Tuchman

The personal dust monitor (PDM) is a sampling device developed for measuring the personal exposure to coal mine dust of mine workers. The device is based on proprietary technology known as the tapered element oscillating microbalance (TEOM) originally developed as a fixed- site environmental particulate mass monitor by Rupprecht and Patashnick Co., Inc., Albany, NY. Currently, the monitoring of exposure to coal mine dust relies on periodic samples taken by traditional coal mine dust sampling units that use a cyclone, filter, pump, and laboratory measurement of the filter mass. Better measurement of mine dust levels has been the goal of industry and labor for nearly two decades. PDM technology offers accurate, end-of-shift and near real time assessment of worker dust exposure. Laboratory and underground tests compared measurements taken by a prototype PDM-2 (a two-piece TEOM) to the average of multiple personal dust samplers monitoring the same space. In the range of mass loadings P between 0.5 and 4.0 mg/m the PDM met a 25% accuracy criterion 95% of the time with 95% confidence. However, some questions still exist about potential bias between types of coal. The prototype two-piece device is in the process of being combined into a single unit that also contains the miners' cap lamp creating a more ergonomic dust sampling system.

In the Renison Bell area of western Tas mania, a series of Lower Cambrian quartzites, shales, carbonate beds ("dolomites"), cong- lomerates, tuffs and argillites have been folded into a broad monocline whose general strike is NW-SE, plunging slightly north and dipping NE. The downwarped eastern side of the monocline is disrupted by a steep (50-800) east dipping normal fault, known as the Bassett Structure, whose throw is in excess of 500 m. A series of flat north dipping normal faults, each with a throw of approximately 50 m, further disrupts the sequence. All major faulting was pre-mineralization. A cassiterite- bearing Devonian quartz porphyry body intrudes this Cambrian sequence 2 km south of the currently operating mine. Of economic importance is the presence of three carbonate beds in the sequence. These carbonates consist of a mixture of calcite, dolomite and siderite. The No. 1 (youngest) and No. 2 carbonate beds are each approximately 15 m thick and are separated by 20 m of hematitic conglomerates and tuffs. The No. 3 (oldest) carbonate bed is approximately 5 m thick and is separated from the No. 2 horizon by 50 m of dark grey, finely laminated shales and quart- zites. Whilst the carbonates are remarkably persistent over at least 30 km2, facies changes are common and as a result of these changes, the carbonates vary considerably in

Jan 1, 1973

By Esperidiana A. B. Moura, Michelle Gomes, Cordelia M. F. Escanhoela, Francisco R. V. Diaz, Angel Ortiz, Rene R. Oliveira

"This work evaluates changes in morphological, mechanical and thermo-mechanical properties of electron-beam irradiated HDPE/nanoclay and HDPE/Piassava fiber/nanoclay. Material samples irradiated with 100 and 200 kGy using a 1.5 Me V electron beam accelerator (room temperature, presence of air) were submitted to tensile, flexural, and HDT tests. MFI, SEM and XRD analyses were carried out. Correlation between properties was discussed. Results showed that incorporation of piassava (Attalea funifera Mart) fiber and nanoclay, followed by irradiation represented significant gain in thermo-mechanical properties. Changes in surface morphology and reduction in MFI were observed. In conclusion, it may be claimed that the incorporation of piassava fiber in small size particles and nanoclay in the HDPE followed by electron-beam irradiation effectively improved the polymer properties and led to materials with superior properties suitable for several industrial applications.1. IntroductionIn recent years, the preference for using natural fibers instead of synthetic ones in polymer composites has been growing significantly. In Brazil, due to the great diversity of woody and fibrous plants of our forests, a vast potential of natural fibers is found, presenting good mechanical strength properties, chemical and biological stability, fire resistance, abrasion resistance, shear strength and lightness, among other which may contribute to the development of new materials for different applications such as automotive, aerospace, construction, food segment, cosmetics and others [ 1]."

Jan 1, 2013

By Wilbur I. Duvall, Thomas C. Atchison, David E. Fogelson

The breakage of rock by explosives depends largely on the ability of an explosive to transfer its stored potential energy to the rock as strain en- ergy. Therefore, the relative rock-breaking abilities of explosives can be determined indirectly by determining the relative amounts of strain energy transferred to the rock at the time of detonation. This report presents experimental data on the strain energy contained in explosion-generated strain pulses in a granite gneiss. Six explosives were tested. The scaled total radial strain energy E/W flowing outward through a spherical shell of scaled radius R/W1/3 surrounding the point of detonation was found to follow an exponential decay propagation law of the form Analysis of the data showed that the intercept parameter H depended upon the type of explosive used but that the absorption coefficient B was practi- cally independent of the type of explosive. Comparison of the intercept pa- rameter H and the calculated energy of the explosive showed that the percent- age of explosive energy transferred to the rock increased linearly as the ratio of the characteristic impedance (product of density and propagation velocity) of the explosive to that of the rock increased toward unity. From 5 to 9 percent of the calculated total energy released by the explosive was transferred to the rock as radial strain energy.

Dec 1, 1959

By A. Founie

The United States continues to be the world’s leading producer and consumer of diatomite. Production of diatomite in the United States during 2005 was estimated to be 653 kt (720,000 st). This was a 5-percent increase compared with 2004. The value of processed diatomite in the U.S. was about $179 million in 2005. Production was from six companies with 12 processing facilities in four states. California and Nevada were the principal producing states. They accounted for about 70 percent of U.S. production in 2005. U.S. diatomite exports were about 144 kt (159,000 st). Imports were negligible. The internal structure and chemical inertness make diatomite an excellent raw material for filtration, absorbent and filler applications. Filtration, especially the purification of beer, liquors and wine and the cleansing of greases and oils, continued to be the largest end use for diatomite. Other applications include the removal of microbial contaminants, such as bacteria, protozoa and viruses in public water systems, and the filtration of human blood plasma. The use of diatomite as fillers and in pharmaceutical applications, including the filtration of human blood plasma, continues to increase as has its use as an insecticide base and as pozzolan. The relative rank of end uses of diatomite were filter aids, 75 percent; fillers, 11 percent; absorbents, 7 percent and other (mostly cement manufacture), 7 percent.

Jan 1, 2006

By Joachim von Scheele

An oxyfuel-based technology - OXYFINES - has been introduced for in-plant recycling. It provides fines, dust, sludge (without any drying-step) and other by-products arising in the steel and metal producing industries to be recycled directly back into existing processes or a separate unit on-site. Results from full-scale installation (20,000 tpy) for dust treatment, full-scale and pilot-scale trials with dry and wet materials in the steel and ferroalloy industries are presented. Processing rates at 3.5 t/h have been demonstrated. The product is agglomerates or lumpy pieces, the latter if the product has passed an all-liquid stage and thereafter been crushed. The technology does not only provide a solution to the problems connected to dust and sludge generated in metal production. It also turns these materials into a low-cost raw material useful for the production in question, thus replacing part of the raw material input in electric arc furnaces, blast furnaces, etc. Elements harmful to re-use of the processed dust or sludge, e.g., zinc and alkaline components in steel production, are removed as secondary dust, and material yield of main components for re-use is very high, about 98%. The paper reviews the concept, the results obtained and its status; its use for sludge recycling is emphasized.

Jan 1, 2004

By A. Iordanidis

Ieropigi Fe-Ni deposit is located in northern Greece, in Kastoria?s prefecture near Albania?s borders. A laterite profile exposed by opencast mining and placed near the basement of the mine was chosen for sampling. Ten samples, representing ?pure? Fe-Ni ore, ophiolite-bedrock, ?red? ophiolite and ?enriched? ophiolite were collected, based on macroscopic observation. The samples were analysed by X-Ray powder Diffraction (XRD) for the determination of the mineral phases. Iron and Nickel concentrations of the same samples were also determined by X-Ray Fluorescence (XRF) methodology. The Fe-Ni ore samples consists predomi-nantly of hematite, goethite, chrysotile (serpentine), saponite and quartz. ?Red? ophiolite samples consists mainly of chrysotile, hematite, quartz, calcite and small amounts of paragonite and goethite. Bedrock and ?enriched ophiolite samples are comprised of chrysotile, hematite, calcite, quartz, nontronite, paragonite and sepiolite. The Fe content ranges between 13% and 49% in Fe-Ni ore samples and between 7% and 10% in ophiolite samples. The Ni content ranges between 1% and 3% in Fe-Ni ore samples and between 0.3% and 4.5% in ophiolite samples (the higher content is observed in the so-called ?enriched? ophiolite). A correlation between Fe-Ni concentrations and mineral assemblages is being attempted in order to evaluate the nickel-rich mineral phases. It is shown that the nickeliferous minerals are serpentine, hematite, goethite and saponite.

Jan 1, 2006

By Jeffrey P. Chanton

A specialized Pore-Fluid Array sampler (PFA) was designed to collect and store pore-fluids to monitor temporal changes of ions and gases in gas hydrate bearing sediments. We tested the hypothesis that pore-fluid chemistry records hydrate formation or decomposition events and reflects local seismic activity. The PFA is a seafloor probe that consists of an interchangeable instrument package that houses OsmoSamplers, long-term pore-fluid samplers; a specialized low-dead volume fluid coupler; and eight sample ports along a 10-meter sediment probe shaft. The PFA was deployed at Mississippi Canyon 118, a Gulf of Mexico hydrate site. A 160-day record was acquired from the overlying water (OLW) and 1.3 meters below seafloor (mbsf). Fluids were measured for dissolved chloride, sulfate, and methane concentrations and dissolved inorganic carbon and methane stable carbon and deuterium isotope ratios. Chloride and sulfate did not change significantly over time, suggesting the absence of gas hydrate formation or decomposition events. Over the temporal record, methane concentrations averaged 4 mM at 1.3 mbsf and was thermogenic in origin (d13C-CH4 = -32.4±3.4?). The timing of an anomalous 14 mM methane spike coincided with a nearby earthquake (Mw=5.8), consistent with the hypothesis that pore-fluid chemistry reflects seismic events. Keywords: Osmosampler, gas hydrate, methane, stable isotopes

Jan 1, 2008

By J. O. Marsden

Over the past eight years, Phelps Dodge (a division of Freeport-McMoRan Copper and Gold, Inc.) has developed a suite of proprietary hydrometallurgical processes for the treatment of copper concentrates as an alternative to conventional smelting and refining technology. The technical viability of two processes has been commercially demonstrated in a large scale plant at Bagdad, Arizona, designed to process approximately 52,500 metric tons per year of concentrate containing 30.5% copper. The first process utilizes high temperature (225°C) pressure leaching, followed by countercurrent solid-liquid separation, and then blending of the copper-bearing solution with low grade stockpile leach solution for subsequent treatment by SXlEW for copper recovery. The second process uses super-fine grinding, medium temperature (l60°C) pressure leaching, followed by solid-liquid separation, and treatment of high grade copper-bearing solution by direct electrowinning to recover the bulk of the copper values. The latter process will be utilized at Morenci in a commercial facility designed to treat mixed chalcopyrite-chalcocite-covellite concentrates. This facility is scheduled to start up in 2007. Other flowsheet options have been developed by Phelps Dodge for application to a variety of concentrate materials in specific situations. Examples of various flow sheet options are presented in this paper, and the advantages and disadvantages associated with each are discussed in detail.

Jan 1, 2007

By K. Hodgson, J. P. M. Hojem, N. G. W. Cook

Already about one-third of South Africa's coal is mined at depths exceeding 100 metres. Almost all this mining is done by the bord and pillar method. Conventional design procedures call for ever larger pillars as depths of workings increase, resulting in the loss of large amounts of coal and reductions in productivity. Barrier pillars are in general use to ensure against large collapses. The presence of these strong pillars would allow a more efficient design of the bord and pillar layout to yield improved extraction ratios by using smaller, yielding, pillars between the bords. Knowledge of the complete load- displacement curves for such pillars is a prerequisite for the design of such a system. A 100-MN, stiff jacking system for measuring the complete load-displacement curves of pillars with cross-sections of up to 2 m X 2 m is described. The jacks are installed in a slot cut across the central plane of symmetry of a pillar, thereby ensuring that the stress distribution in the pillar during a test, especially at its contacts with the roof and floor, is identical to that caused in a similar pillar by convergence across the seam. Preliminary results in the form of complete load-displacement curves for test pillars of about 1.5 metre square section are given.

By S. Hicks

This technical note describes an alternative procedure that can be used in linear programming calculations where the compliance limit of lbs SO2/million Btu for the blending coal is subject to change. Dr. Mateer in his technical note titled "Coal blending for sulfur compliance" (ME, September 1994, p. 1103) defined an "excess sulfur" parameter that provides a valid constraint equation for a linear program optimization. The coals used by Dr. Mateer in his examples are shown in Table 1. To create the parameters for the constraint equations to blend to an SO2 content of 1.2 lbs SO2/million Btu, the excess sulfur for Coal A was defined as Sulfur excess% = 0.5 - 0.6*13,000/10,000 = -0.28 This equation was used to create the constraint equation -0.28A + 0.44B + 1.36C[<] 0.0 Another way to create the parameters for the constraint equation is given below. In these equations: •W is the total weight; •A, B and C are the fractional proportions of each potential blend stocks; •Sa, Sb and Sc represent the percent sulfur content of the blend stocks; •Ha, Hb and Hc represent the calorific content of the blend stocks in Btu/lb; and •H and S represent calorific and sulfur contents of the composite blend. The weight of blend to produce one million Btu is [ ]

Jan 1, 1998

By Shun-ichi Satoh

A NEW method of treating steel by ammonia has recently been intro¬duced into the metallurgical industry, by means of which piston cylinders of internal combustion engines, shafts and other similar steel products can be made more resistant to wear than formerly. In 1929 the writer&apos; published the historical notes and some experiments upon nitrification. He believes that the corrosion of nitrified steel is a matter of importance and worth studying; and as there have been few studies thereof, he has conducted experiments in this respect. L. Guillet,2 in 1927, reported corrosion tests made on nitrified and cemented steels with acid and salt solutions. In 1928, 0. Hengstenberg3 reported the high resistance of nitrified steel to water vapor and air. V. 0. Homerberg4 stated that nitrified steel has high resistance to water, air and salt solution; and G. Hagg5 studied nitrified layers of iron by means of the X-ray. Though F. Hanaman6 in 1913, measured the single potential difference of steel treated with ammonia at above 650° C., no one, it seems, has ever measured the single potential difference of the so-called nitrified steels having extraordinary hardness. The writer measured the single potential differences of nitrified special steels in various solutions with the object of studying the corrosion problem and, if possible, of knowing whether any new physical property would be caused by nitrification.

Jan 1, 1932

The Raymond Memorial Volume, which the Members of the In-stitute have been so anxiously awaiting since the beloved man&apos;s death, is nearly ready for publication. It will contain about 45,000 words and some illustrations and a frontispiece portrait. This book promises to fill every expectation of the contributors to the volume and the host of admirers of the genius who so long guided the destiny of the Institute. It will contain one of Doctor Raymond&apos;s best stories, entitled "James and Jim;" his famous article on "Job on Mining;" and one of his poems entitled "The Grand Canyon." A biography of Doctor Raymond has been written by his daughter, who is the wife of a member of the Institute. The memorial addresses delivered by Dr. Henry F. Drinker and T. A. Rickard at the annual meeting in New York in 1919 will be included. There will also be very interesting reminiscences by H. M. Howe, A. S. Dwight, C. W. Goodale, R. W. Hunt, Lyman Abbott, J. F. hemp, T. A. Rickard. The volume has been edited by T. A. Rickard, which promises all that can be wished for the volume from a literary standpoint. The edition will he limited so that it is very desirable that orders for this volume be sent in to the Institute as promptly as possible. The price will be $5.00.

Jan 12, 1919

By I. A. Ibrahim

Ilmenite, in its natural form, is an inactive mineral from which the selective removal of iron is rather difficult. The reactivity of ilmenite. so that it can be leached with dilute hydrochloric acid, can be enhanced by chemical reduction in solution using a suitable metal as a reducing agent. The present paper aims at the evaluation of an Egyptian ilmenite ore for the production of synthetic rutile by direct leaching with hydrochloric acid in presence of iron powder. In this process, the titanium and iron contents are dissolved; meanwhile, the dissolved titanium is hydrolyzed and re-precipitated leaving mainly iron in solution. Leaching conditions were optimized to obtain less iron in the final solid product. Addition of sufficient amount of iron powder during leaching reduces the dissolved Fe3+ to Fe2+ and reduces the dissolved Ti4+ to Ti3+. The creation of Ti3+ in solution is assumed to have a role in dissolving the ferric iron and hence increasing the reactivity of the ilmenite ore. Synthetic rutile of about 90% TiO2 and 0.77% Fe2O3 was obtained from ore with a grain size 100% passing 200 mesh and a 5-hour leach time with 20% HCl at boiling temperature (110°C) and 0.11 g iron powder / g ore.

Jan 1, 2003

By José Carlos A. Cintra

This paper addresses a new experimental procedure to measure the shaft friction and the base resistance of bored piles during static load tests. It is proposed that a set of polystyrene foam discs, placed between the shaft and the base of the pile, be used instead of the usual instrumentation. Throughout the initial stages of the loading test, the foam discs will allow only the mobilization of the shaft friction. The load x settlement curve clearly shows that the shaft friction vanishes at low settlement values. As the load test proceeds, the base resistance is also mobilized. This procedure was used in two belled piles bored at the Experimental Foundation Field of the University of São Paulo, at São Carlos, Brazil. Both piles were 8 m long and had a shaft diameter of 0.6 m. The enlarged base had a diameter of 1.5 m and a height of 0.9 m. Twenty foam discs with a thickness of 20 mm each were placed between the enlarged base and the shaft of the pile. The load tests indicated ultimate shaft frictions of 28 and 30 kPa for measured settlements of 8.98 and 7.39 mm. Base resistance values at failure were 617 and 499 kPa, for a chosen settlement of 10% of the pile base diameter. The proposed approach seems to be straightforward, efficient and inexpensive.

Jan 1, 2002

By Óscar Cantorín

El presente texto describe las ventajas del sistema de relleno utilizado en la compañía minera Ares de Arequipa. La metodología del relleno se inicia en el tajo de una chimenea, la cual contiene las tuberías bicapa. Luego se conecta mediante un niple las tuberías de una sola chapa, y se instalan hacia el tope del ala del tajo que entrará en relleno. Entonces, se prepara una barrera con tablas y puntales en el límite señalado para rellenar, y la parte interior se forra con tela prolipropileno. Al estar preparado el tajo, se comunica al personal de Planta de Relleno el inicio de la operación, donde se hace una mezcla de agua y cemento para lubricar la tubería. Luego se procede a bombear la mezcla con las proporciones de diseño y un slump promedio de 8 pulgadas. El tajo de 60 m de longitud, se rellena hasta en 3 etapas, ya que las tuberías son recuperadas en su totalidad y finalmente el relleno queda a 0.5 m del techo de la labor. Entre los principales beneficios de este tipo de relleno tenemos que: no tiene excedente de agua, no necesita sistema de drenaje, permite la continuidad del minado ya que no es necesario esperar más de un día para reiniciar las operaciones, recuce el costo del relleno con la disminución de cemento y prolonga la vida de la cancha de relaves.

Sep 13, 2001

By R. Karl Zipf

MULSIM/NL (multiple scams, nonlinear) is a three-dimensional boundary-element method (BEM) program developed at the U.S. Bureau of Mines for stress and displacement analysis of coal mines and thin metalliferous veins. It can analyze one to four parallel seams that can have any orientation with respect to the Earth&apos;s surface. Three main new features distinguish MULSIM/NL from its predecessors: (1) nonlinear material models, (2) multiple mining steps, and (3) energy release and strain energy computations. MULSIM/NL has six material models for the in-seam material: (1) linear elastic for coal, (2) strain softening, (3) elastic plastic, (4) bilinear hardening, (5) strain hardening, and (6) linear elastic for gob. Detailed checks show that numerical stress and displacement calculations compare well to known analytic solutions for simple problems. The total energy release calculated by MULSIM/NL is comprised of three basic terms: (1) strain energy release from the mined-out material, (2) linear kinetic energy release due to change in gravitational potential over the mined-out area, and (3) nonlinear kinetic energy release due to nonlinear materials in the total backfill and gob area. The strain energy release term is modified to account for nonlinear stress-strain behavior in the unmined materials. Comparisons of these numerical energy release rate calculations with known analytic solutions show excellent agreement.

Jan 1, 1992