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In the leaching and recovery of gold from copper containing gold ores using cyanidation, some copper minerals also dissolve which can have a detrimental effect on the process efficiency and economics. There are also environmental concerns with current operations discharging cyanide and copper cyanide species into tailings dams, and strict regulations prohibit this for greenfield plants. Cyanide destruction however is not an economic option for new plants treating copper-gold ores. This paper evaluates a potential recovery process to overcome the copper cyanide problem. Despite gold dissolution occurring in copper cyanide solutions having no free cyanide, gold recovery from ores is lower compared to free cyanide. Thus, cyanide addition has to be optimised to maximise the gold recovery whilst endeavouring to eliminate free cyanide at the completion of leaching (CN:Cu less than 3:1). Subsequently, copper cyanide can be recovered using activated carbon. The loaded copper cyanide is easily recovered from the carbon with a cyanide soak and distilled water wash such that the eluted CN :Cu ratio is less than 4:1. The copper could be recovered efficiently by electrowinning, by decreasing the pH of the eluant to 5. The remaining cyanide solution, after electrowinning, is then neutralised to form NaCN and recycled.

Jan 1, 2005

By E. M. Haynsworth

The disposal of phosphatic clays has presented a problem to the phosphate industry since the mining of phosphate rock first began. As the flotation process was introduced in the late 1920's, the problem of clay disposal was increased significantly since clay is present in proportionally greater quantities in reserves yielding flotation concentrates. Because of their physical character and the tremendous surface area per unit volume, these clays have the characteristic of retaining large volumes of water as they are slurried during processing. The phosphatic clays with which we are dealing consist primarily of apatite, wavellite and montmorillonite. In the beneficiation process, we remove the -150 mesh material as waste. However, the particles are essentially smaller than -325 mesh, and more than 70% are smaller than three microns. The disposal of clay and the recovery of a portion of the water require settling areas with a capacity ranging up to 2 cubic feet for each cubic foot of phosphate matrix mined. According to a recent study by the Bureau of Mines, the average cost for disposal of these wastes is 24.5 cents per ton of, product (U. S. Bureau of Mines Circular 8404). This is a major cost of phosphate rock production.

Jan 1, 1970

By Michael von Seebach

High-pressure grinding rolls subject the feed material to pressures of 200 N/mm? During this process considerable size reduction and the Formation of flakes occur. This paper describes the basic consideration For design and operating of this type of mill. It is also shown that the particle size distribution resulting from this process is typical for grinding processes but untypical for crushing processes. High pressure grinding rolls are designed in size of up to 2.8 m roll diameter allowing feed material top sizes of 250 mm. The rigid frame, bearing and drive - train design allows a broad application of the high-pressure grinding rolls operating the machine in open or semi-closed and closed circuit for dry and moist feed materials. Operating results show that capacity increases of up to 100 % can be accomplished with this technology. The high-pressure grinding roll also, allows for lower operating and maintenance costs due to energy savings of up to 20 L and reduction of wear to less than 1 76 for dry and less than 0.1 5 for wet grinding. Other advantages of the high-pressure grinding rolls are smaller equipment sizes than a ball or SAG-mill for a given capacity resulting in lower building sizes with reduced capital in- vestment costs.

Jan 1, 1987

By H. William Zeller

The Bureau of Mines performed laboratory research into the effects of a barium-based fuel additive (the "postflame" type) on diesel particulate matter (DPM) emissions. The 5.6-L, six-cylinder test engine is typical of types certifiable for use in underground mines. Test parameters consisted of additive concentration and engine loads, speed, and air intake restriction. DPM emissions, including condensed volatiles, were measured gravimetrically. Also measured were gaseous emissions including carbon monoxide, nitrogen oxides, and hydrocarbons. The fuel additive was effective, reducing DPM up to 75 pct, when used at a concentration of 0.09 wt pct (one-fourth of the concentration recommended by the manufacturer). The additive was most effective at the highest fuel-air ratios, reducing DPM from 400 mg/m3 for untreated fuel to 120 mg/m3. At light loads, 25 pct of full rated, no DPM reductions were measured. Based on these results, the additive is recommended for use in diesel fuel, at a concentration of 0.09 wt pct, to power underground mining equipment as long as certain conditions are met: that a beneficial DPM reduction is verified, that the minimum required quantity of additive is used, and that potential adverse effects such as increased nitrogen oxides are checked.

Jan 1, 1990

By Li. Jiarong, Zuojian Liang, Qingyan Xu, Baicheng Liu, Shizhong Liu, Hailong Yuan

Single crystal solidification of turbine blades is a key technology for the production of reliable and high efficiency gas turbines. The solidification process of single crystal investment castings causes a number of problems that have to be solved such as the increase of casting defects and complexity of production process. Computer modeling and simulation is helpful to predict the defects and improve the process design. In the paper, a mathematical model for three dimensional simulation of solidification and single crystal growth of investment castings was developed based on CA, mechanism of crystal growth and basic transfer equations such as heat, mass transfer equations. Many factors including constitutional undercooling, curvature undercooling and anisotropy, which had vital influences on microstructure evolution, were considered in the model. Temperature, crystal growth interface and structure defects of investment castings of single crystal superalloy were investigated at withdrawal rates of 4.5mm/min and 7mm/min. Simulated results showed that microstructure evolution and structure defects were predicted reasonably and calculated results were coincident with experimental ones. The study indicated that three dimensional solidification simulation technique is a powerful tool for understanding the fundamental of solidification and the formation of structure defects in single crystal investment castings and finally for optimizing process design.

Jan 1, 2004

By W. Cholewa, T. S. Golosinski, J. Wedzicha

"Power requirements of belt conveyor drives are usually estimated based on the calculated belt tension which equals the sum of unit resistances to motion which the belt has to overcome. In most situations, the value of various unit resistances can be accurately predicted using published information (5,6,8,12). A simpler approach calls for use of standard formula and tabulated values of related factors which reflect various features of both the conveyor and the transported material (2,3,7) . None of these approaches is reliable when materials with unique properties are conveyed, nor if applied to conveyors working in extreme climatic conditions. Such is the case of oil sand mines in northern Alberta.There the bitumen content of oil sand causes it to behave in a unique manner. Furthermore the conveyors operate year around, with winter temperatures often lower than - 40°C. It was the objective of presented investigations to quantify the power requirements of conveyors, and related resistance to motion for the conveyors used in oil sand mines during winter operations.The other objective was to quantify the drive power requirements of oil sand conveyors during start-up. These requirements are usually much higher than those during norm al operation, and their quantification is of paramount importance for operation of large conveyors."

Jan 1, 1992

By M. Misra

The coral contaminated with plutonium at Johnston Atoll UA) was subjected to gravity and flotation separation processes at the Soil Washing Laboratory (SWL) and also at the Johnston Atoll UA) site. Tests were conducted with the contaminated coral fractions referred to as the "HP-l" ( hot particles) and the "sludge". The gravity process tested was centrifugal gravity separation and the flotation processes were conventional Denver mechanical flotation and tall column flotation. Flotation tests were conducted using both fresh and sea water. Industrial fatty acid (anionic collector) was chosen as collector to make plutonium-enriched particles hydrophobic. The use of flurosilicic acid and sodium silicate made the clean coral hydrophilic. The results show that each of the processed when tested with appropriate size fraction and operating conditions resulted in passing the success criteria. It was possible to obtain more than 80% weight of the original coral as "clean sand" having activity below the JA site "soil screening level" of 13.5 pCi/gm. The field tests spiked with plutonium particles showed remarkable success. The effect of depressants, flotation medium and the coral pretreatmentis described. Finally, a flowsheet developed by the University of Nevada, Reno to treat 8000 tons of HP-l pile presently stored at JA is presented.

Jan 1, 1996

By M. C. Irani

The Bureau of Mines has designed and put into operation a fail-safe control system for use in underground coal mines equipped with methane drainage pipelines. This control system can detect certain unsafe conditions and respond by automatically shutting off the flow of methane from the degasification borehole to the drainage pipeline. Methane flow is shut off when the methane content in the return airways reaches a predetermined level (typically 1.5 pct), when the methane drainage pipeline is ruptured by roof fall, or when there is an electric power failure. The fail-safe control system was designed using commercially available components and a methane analyzer system previously developed by the Bureau. The fail-safe system consists of a unit that combines a shutoff valve and pneumatic valve actuator, and electronic and mechanical equipment designed to detect hazards and effect shutdown. The fail-safe control system was designed to meet regulatory requirements issued by the Mine Safety and Health Administration (MSHA), U.S. Department of Labor, and State regulatory bodies for the safe operation of underground methane pipelines used for mine degasification. MSHA has inspected and tested this system and permitted its use in two mines. The Bureau installed the fail-safe system in two working coal mines, where successful performance has been demonstrated.

Jan 1, 1979

By L. Freitag

"The Dollard oil field in southwestern Saskatchewan is a stratigraphic trap of irregular shaped perimeter. The reservoir is a low-angle monoclinal structure with a dip of approximately 100 feet in 5 miles from west to east across the long axis of the reservoir. Production of. 23° API gravity crude is obtained from a Jurassic sand referred to as the J-2-A, at an approximate depth of 4,500 feet. Reservoir studies and fluid analyses revealed that the crude is highly undersaturated, having a solution GOR of approximately 130 cubic feet of gas per barrel, that the reservoir has no definable water table, and that it appears to be of a closed-boundary type. Oil production was marked by a rapid pressure decline and it was soon evident that the greatest ultimate recovery would be best obtained if the natural driving energy of the reservoir were augmented by some artificial energy source. In support of a pressure maintenance programme, studies were conducted on flood-pot recoveries of large-diameter cores, and a potentiometric model study of the field was made. These studies indicated that a successful water flood would be obtained. The Dollard field was unitized in 1955 and pressure maintenance started in March 1956."

Jan 1, 1959

By R. T. Johansen

The wettability of petroleum reservoir materials by water and crude oil has been recognized as an important factor in determining waterflood behavior. The problem of simulating and studying reservoir conditions and characteristics, to produce laboratory results congruous with field experience, has been examined by many methods. (1, 2, 3, 4).4/ The most generally accepted approach to this problem is determining wettability of the porous medium by imbibition methods; or, after solvent extraction, predetermining the wettability of the samples by coating the surface of the medium to render it preferentially oil-or water-wet (3, 5). The emphasis of wettability studies has been placed on the characteristics of the reservoir materials with little consideration being given to the fluids themselves. Therefore, the wetting tendencies of crude oils have been investigated by a recently developed method (6). Imbibition and the more general phenomena of capillary pressure are the most direct ways to measure wettability. The simplest type of capillary pressure observations involves the use of an interfacial-tension capillarimeter, which does not produce as separate values either interfacial tension or contact angle. Actually, these quantities do not have independent significance in reservoir engineering, and the property of wettability they are intended to evaluate is given, immediately by capillarimetric measurements.

Jan 1, 1961

By M. Fairman

The effect of welding speed on the microstructure of friction stir processed (FSPed) AZ31B-H24 magnesium alloy was studied using light microscopy, image analysis, and microhardness tests. The grain size of the magnesium alloy was observed to increase after FSP from about 3.5 µm in the base alloy to about 8 µm in the stir zone. The aspect ratio decreased from 1.60 to 1.55 towards the center of the stir zone. The changes in the grain size and shape caused the microhardness of the samples to drop significantly across the FSPed region from 75 HV in the base alloy to below 55 HV in the stir zone. Decreasing the welding speed increased the grain size due to a greater input of heat energy. The faster heating rate due to the lower welding speed caused a deeper penetration of the annealing effects of FSP. It was also observed that the annealing effects caused by FSP were less pronounced with increasing distance from the interface between the sample and pin tool shoulder. The Hall-Petch type relationship of the micro-indentation hardness as a function of the grain size was observed to hold true after FSP.

Jan 1, 2007

By A. Yamik

This research study includes studies carried out on the recovery of unburned carbon in the ashes of Tuncbilek Thermal Power Plant. Bottom ashes have been identified by X-ray diffraction and X-ray fluorescence. These samples are potentially of class F type and have significant amounts of unburned coal. According to the ash amount that units in the thermal power plant produce, and the analyses of the samples mixed, which used certain amounts in flotation tests, it was found that the bottom ash includes 91.47% ash in dry form and 8.53% combustible matter, and the lower calorific value is 491 kcal/kg. Optimum flotation conditions to get the unburned carbon were subsequently determined by examination of the optimum flotation grain size, pulp density, collector type and amount, depressant type and amount, frother type and amount, agitation speed, and froth-taking time. While the lower calorific value of the thermal power plant bottom ashes of the 3rd , 4th and 5th units and the mixed bottom ash sample was, respectively, 959, 469, 279 and 491 kcal/kg in dry form, it increased to 2490, 1312, 786 and 1348 kcal/kg in the product obtained as a result of flotation in optimum conditions. Key words: ash, conventional flotation, unburned carbon

Jan 1, 2008

By A. W. Jacobs

SHORTLY after Denny, Robson, and Irwin(l) published their first paper, in 1937, on the prevention of silicosis by metallic aluminium, experiments were begun on the practical application of the discovery. It was thought at that time that aluminium powder, to be effective in aluminium therapy, would have to be intimately admixed with siliceous dust at the latter's source. There followed several years of experimental work underground, during which the application of aluminium powder was tested in: (1) Shakers on machine columns, vibrated? by drills (2) Vials placed in drill holes to be blasted (3) Both homogeneous and heterogeneous. mixture with explosives ( 4) Packages with tamping (5) Compressed-air lines (6) Special compressed-air ejectors for use while drilling and after blasting (7) The discharge of ventilation fans (8) The filters of respirators It was concluded from this research that any adequate method of introducing aluminium powder into a mine atmosphere would require too much extra gear, supervision, and aluminium powder, and would interfere unduly with underground routine. Later, animal experiments by Denny, Robson, and Irwin(2) showed that aluminium powder provided effective therapy when inhaled independent of silica dust. Therefore, some means of surface treatment was deemed more practical.

Jan 1, 1944

By W. L. Ott, J. E. Hawley, C. L. Lewis

"IntroductionTHE APPLICATION of spectrochemical analysis to metals of the platinum group was advocated by Harvey (3) as follows: ""The spectra of the platinum group metals have been studied less than many of the more common metals. The rarity of occurrence of these elements makes the analysis relatively unusual. Potentially, the analysis of this group is an excellent application of spectrographic methods, particularly in contrast to the tedious chemical procedure"".Wichers (8) divides platinum-metal analysis into three broad divisions as follows :( 1) The detection and estimation of these metals in other materials, e.g., ores, where the amounts present are very small.(2) The detection and estimation of impurities in the refined metals themselves ....(3) The analysis of alloys of the platinum metals .....The present paper deals with the second division: analysis of refined rhodium.Research on spectrochemical techniques for determination of trace contaminants in refined platinum metals was begun at Queen's University in 1949, under the supervision of Professor J. E. Hawley. Since 1953, the work has been continued in the Metallurgical Laboratories of Falconbridge Nickel Mines, Limited. Techniques for spectrochemical analysis of refined platinum and palladium have been published ( 4, 5). A technique for analysis of refined iridium has been developed but not yet published."

Jan 1, 1955

By K. Niboucha, M. Zergoug, S. Brick-Chaouch, H. Houali

"Corrosion is an electrochemical process that causes degradation and deterioration of various steel works (pipelines, drains, cisterns) whether they are buried, immersed, or not. Worldwide, we estimate that corrosion destroys a quarter of the annual production of steel at a rate of 5 tons per second. Several techniques are used to protect against corrosion. Among these processes, Cathodic protection, which is regarded as the best technique to assure the protection of steel, works against this phenomenon. This is achieved either by a system of reactive anodes, or by the technique of impressed current protection or other techniques. Before any installation of cathodic protection, a preliminary study and pre-evaluation of certain parameters must be made. In the present work, we will present an example of dimensioning of an installation of cathodic protection by imposed current of a pipeline using solar energy, where we discuss the following items:•,Evolutions of the potential as well as current along the pipeline and their respective expressions deduced from the laws known as telegraphists;•,Range of protection (potential of protection along the pipeline);•,Influence of the isolation resistance of the coating on the range of protection;•,Effect of the aging of the coating and its influence on the current of protection."

Jan 1, 2005

By H. Houali

Corrosion is an electrochemical process that causes degradation and deterioration of various steel works (pipelines, drains, cisterns) whether they are buried, immersed, or not. Worldwide, we estimate that corrosion destroys a quarter of the annual production of steel at a rate of 5 tons per second. Several techniques are used to protect against corrosion. Among these processes, Cathodic protection, which is regarded as the best technique to assure the protection of steel, works against this phenomenon. This is achieved either by a system of reactive anodes, or by the technique of impressed current protection or other techniques. Before any installation of cathodic protection, a preliminary study and pre-evaluation of certain parameters must be made. In the present work, we will present an example of dimensioning of an installation of cathodic protection by imposed current of a pipeline using solar energy, where we discuss the following items: ? Evolutions of the potential as well as current along the pipeline and their respective expressions deduced from the laws known as telegraphists; ? Range of protection (potential of protection along the pipeline); ? Influence of the isolation resistance of the coating on the range of protection; Effect of the aging of the coating and its influence on the current of protection

Jan 1, 2005

By Bruce W. Jack

An extensive underground roof-monitoring program was conducted in order to determine the roof strata behavior under various conditions. In total 29 sites at 5 different collieries were monitored using the sonic probe extensometer. Results showed that, in drill and blast sections, there are often pre-existing openings in the roof prior to the installation of the support. An estimated 42 per cent of the total roof displacement monitored in drill and blast sections took place prior to the installation of support. A comparison between roadways and intersections indicated that, for a 40 per cent increase in the span, taken across the diagonal of art intersection, relative to the roadway width, the magnitude of the displacement in the roof increased by a factor of 3. Total displacements measured were relatively small, only 2 reaching double figures of 12 mm. The remainder were all less than 7 mm. The results also showed no evidence of a substantial increase in the height of the bed separated, potentially unstable roof strata, as is the case in the high horizontal stress-driven beam-buckling mechanism experienced in for instance some Australian coal nines. Therefore, it was concluded that, in South African collieries, the effects of horizontal stresses is generally relatively small compared to overseas collieries.

Jan 1, 2000

By D. J. McAdam

Results of investigation of corrosion-fatigue of metals at the U. S. Naval Engineering Experiment Station have been presented by the author in four papers.1, 2, 3, 4 In those papers references were given to the work of Haigh in 1917.5 The investigation at Annapolis included a variety of ferrous and non-ferrous alloys. The experiments showed that even slight corrosion simultaneous with fatigue may cause failure at stresses far below the ordinary endurance limit. The experiments also showed that, for most metals, severe stressless corrosion prior to fatigue is much less damaging than even slight corrosion simultaneous with fatigue. The term "corrosion-fatigue" was restricted to mean the simultaneous action of corrosion and fatigue. The combined effect of corrosion followed by fatigue was called "prior-corrosion fatigue." A stress-cycle graph representing corrosion-fatigue is a curve approaching a horizontal asymptote, the ordinate of which may be called a "corrosion-fatigue limit." To avoid confusion in later discussion, the term "endurance limit" will be restricted to mean the fatigue limit obtained by tests in air with specimens as free as possible from stress concentration and from corrosion. The cndursnce limit as thus obtained presumably represents an inherent property of the metal.

Jan 1, 1929

By D. J. McAdam

Results of investigation of corrosion-fatigue of metals at the U. S. Naval Engineering Experiment Station have been presented by the author in four papers.1, 2, 3, 4 In those papers references were given to the work of Haigh in 1917.5 The investigation at Annapolis included a variety of ferrous and non-ferrous alloys. The experiments showed that even slight corrosion simultaneous with fatigue may cause failure at stresses far below the ordinary endurance limit. The experiments also showed that, for most metals, severe stressless corrosion prior to fatigue is much less damaging than even slight corrosion simultaneous with fatigue. The term "corrosion-fatigue" was restricted to mean the simultaneous action of corrosion and fatigue. The combined effect of corrosion followed by fatigue was called "prior-corrosion fatigue." A stress-cycle graph representing corrosion-fatigue is a curve approaching a horizontal asymptote, the ordinate of which may be called a "corrosion-fatigue limit." To avoid confusion in later discussion, the term "endurance limit" will be restricted to mean the fatigue limit obtained by tests in air with specimens as free as possible from stress concentration and from corrosion. The cndursnce limit as thus obtained presumably represents an inherent property of the metal.

Jan 1, 1929

By Lanre M. Oshinowo, André Bakker

"An understanding of the parameters that govern the just-suspended impeller speed, Njs, and the distribution of solids, is critical to the efficient operation of hydrometallurgical and other processes involving solid-liquid suspensions. In this paper, the distribution of solids in stirred tanks under a range of solids loadings (0.5 to 50 vol%) was predicted using CFD and validated against experimental data obtained from the literature. The multiphase flow is modeled using the Eulerian Granular Multiphase model. This paper will also review the established design parameter Njs in the context of scale-up and compare it to the quality of solids dispersion as a means of assessing correct scale-up in suspension tank design. The results of this study will describe a straightforward procedure to obtaining comprehensive information about reactor behavior with complex CFD models.The performance of hydrofoil impellers and a 45° pitched-blade turbine at suspending solids under different agitation speeds was studied. Both single and dual impeller operation have been evaluated. The settled solids fraction for speeds below N js, and the cloud height for impeller speeds above Njs were predicted. The CFD predictions are in good agreement with experimental literature data on velocity distribution and cloud height."

Jan 1, 2001