Search Documents

By Oliver Bowles

The United States Bureau of Mines has within its ranks a group of engi- neers who are engaged in working out quarry problems, the solution of which will be of general benefit to the industries involved. The problems undertaken are approached in a systematic and thorough manner, all the evidence for and against any proposed change or new development being collected as carefully as an attor- ney would prepare his data on an important case. Unlike the attorney, however, the Bureau engineer does not take sides; his judgment is based entirely and in- partially on the array of facts presented. In order to gain the desired infor- mation he visits many plants, consults with the leaders in the industry, works out experiments in his laboratory, and supplements this information with a stu- dy of all available literature already published on the subject in any part of the world. As an engineer who has for eight years conducted such inquiries in the stone industry, I propose to discuss the Bureau of Mines viewpoint; and it may be of interest to consider with me in a brief and general way the engineer's method of looking at quarry problems, and some of the results attained through past and present labors. While the Bureau has conducted no investigation directly for the crushed- st one industries, two years of investigative work at cement-plant quarries, and work now being conducted at lire-plant quarries, has a very direct bearing on the problems of the crushed-stone industry, since stripping, drilling, blasting, loading, and transportation are similar in many respects in all stone quarries. The results of cement-plant quarry investigations are to be found in Bureau of Mines Bulletin #160. (b) Two short papers on lime-plant quarry problems have been issued in mimeographed form as Serial #01 (c) and Serial 3 (d).

Jan 1, 1923

By A. H. Geisler

INTRODUCTION THE correlation of property changes during precipitation with structure has progressed, sometimes rapidly but other times more slowly, since the fundamental discovery of Merica, Waltenberg and Scott.1 The predominent factor that hampered the progress has been limitations imposed by the various detection methods. Refinements in X ray diffraction techniques and in metallographic methods, which have been extended by the electron microscope, have contributed new information within the last few years. These permit an extension of the theory as proposed by Mehl and fetter in 1940.2 Now that a suffcient number of alloys has been investigated to establish a general mechanism of the precipitation process, a correlation of the facts into a generally applicable theory of age-hardening is both warranted and desirable. 'I he purpose of the paper is to provide an orderly correlation of the phenomenological facts of precipitation hardening. Speculation on mechanism of hardening will be confined to that consistent with existing theories of hardening. Age-hardening accompanies the formation of a new structure, the precipitate, as provided by an alloy system in which solid solubility decreases with decreasing temperature. Upon this premise alone all such systems would be expected to include age-hardenable alloys. Alas, this is not always the case. Few attempts have been made to explain the variable degree of age-hardening among different alloys or to explain the influence of small alloying additions upon the hardening. Dispersion hardening as originally postulated3 is not adequate.* Coherency hardening-the term that will be used to distinguish the properties of a two-phase mixture in the unique and unstable transition state at which the phases are strained into precise atomic registry (continuity or coherency) in planes

Jan 1, 1948

By N Clarke, J Hunt, A Barros, N Guerrero, L Keeney

Grade Engineering® (GE) involves a range of integrated technologies and operating protocols for improving effective feed grade through early rejection of low value material prior to costly processing activities and has the potential to transform the economics of large, low grade, mining operations. Extensive GE test work by AngloGold Ashanti (AGA) and the Cooperative Resource Centre for Optimising Resource Extraction (CRCORE) determined that the Gramalote gold deposit in Colombia is highly amenable to implementation of grade-by-size screening to upgrade the ore at a production scale. To understand the relationships between geology and the upgrade response drill core and bulk samples were analysed at the Centre for Ore Deposit and Earth Sciences (CODES) as part of a larger CRCORE project to understand geological controls on grade-by-size deportment, i.e., the tendency for specific mineral phases to preferentially fractionate during breakage into different size fractions. This work is focussed on understanding the role of mineralogy and texture in influencing rock breakage and natural fractionation at a range of scales. Detailed logging of Gramalote drill core and mineralogical analyses including hyperspectral logging, portable and bench-scale X-ray fluorescence (XRF), plus low resolution Laser Ablation of intact drill core pieces, combined with data from site (drill logs, geochemistry, petrophysics) were used to evaluate the ore and alteration mineralogy, vein paragenesis and textural variability. This provided information on gold deportment and allowed the identification of favourable host veins. Bulk sample material from different ore grade zones was also analysed. A comparison with the results of GE testing shows that positive upgrade results are produced by rocks with abundant veins, particularly those associated with potassic and/or white mica alteration. This work indicates upgrade response can be predicted from drill core using data collected by a combination of automated systems including hyperspectral data, XRF, and detailed drill core logging.

Nov 10, 2020

By Frank Firmstone

In the summer of 1842 my father, William Firmstone, was engaged by Charles Jackson, Jr., of Boston, to examine the conditions in the Lehigh valley as a site for blast-furnaces using anthracite for fuel. In consequence of his report, he was further engaged by Mr. Jackson to build a furnace for him and his partners on the Lehigh canal, 2 miles above the mouth of the river at Easton. Work was begun in the fall of 1842, and the first furnace blown-in in 1844. The history of the works, therefore, from 1844 to 1887, when my own connection with them ceased, covers only four years less than the whole period of the rise, culmination, and commencement of the decline in the smelting of iron with anthracite in America, the beginning of which, in a commercial sense, may be put in 1839.' Although this paper, as the title indicates, is concerned almost exclusively with the furnaces at Glendon, still what was done there was more or less influenced by current opinion in the district, and even reflects, to some extent, the changes in opinion and practice with mineral fuel the world over. No. 1 Furnace was built of red brick, on four piers, had three tuyeres and fore-hearth and tymp, as was universal with furnaces using mineral fuel until the introduction of Lurmann's cinder-tuyere. The dimensions and profile are shown in Figs. 1 and 2. The first hearth (Fig. 1) was of sandstone; all after were of fire-brick (Fig. 2). The profile was no doubt derived directly from Gibbons's furnace,2 for it appears from W. Firmstone's note-books that in October, 1840, he visited " Gibbons' new furnaces building at Corbyn Hall," and I have an old drawing,

Jan 1, 1910

By H. L. Hopkins, OHIO, L. W. Kemph, CLEVEL AND, E. V. Ivanso

A balanced system of internal stress is set up in any metallic structure by plastic deformation below the annealing temperature. The internaI stress induced by cold rolling or other fabricating processes is generally recognized and its magnitude is known to be, within certain limits, a function of the degree of cold deformation. The plastic deformation that may accompany rapid cooling from elevated temperatures may not materially change the form of the product. The internal stresses so induced are not, therefore, so evident and nonrecognition of their presence has at times led to engineering failures. The heat treatment of aluminum alloys is a relatively new art and little information is available regarding the magnitude of stresses induced during the commercial heat treatment of aluminum alloy products. As the industrial use of aluminum increases, it is inevitable that products of increasingly large volume will be required. It has become necessary in the present commercial utilization of aluminum to heat-treat castings and forgings weighing hundreds of pounds. One of the factors governing the magnitude of internal stresses arising from rapid cooling from elevated temperatures is that of the size of the structure being treated. Some of the other factors are: cooling rate, elastic properties of the alloy, thermal expansivity, thermal conductivity, and the presence or absence of phase changes. Practically all aluminum alloys have a high coefficient of thermal expansion and some are capable of developing relatively high elastic limits. On the other hand, all commercial aluminum alloys have relatively high thermal conductivities, no invariant phase changes, and the quenching temperatures are comparatively low. In the absence of invariant phase changes involving change in the type of crystallographic lattice, the fundamental basis for the development of internal stress

Jan 1, 1934

By J. O. G. Sanderson

Introduction In this paper it is proposed to review the history of petroleum geology in western Canada, to discuss some of the main events which have affected its progress, to mention its relationship to the petroleum industry, and, finally, to appraise its present status and possible future importance. It will be useful first to consider the meanings of the terms petroleum geology, petroleum geologist, and the petroleum geology of a terrain. Petroleum Geology. - In simplest terms, geology is the science of the earth. Hence petroleum geology is the science of that portion of the earth that encloses pools of petroleum. The systematic delineation and study of stratigraphic geology began about 1820. The systematic development and study of petroleum geology started about 1910. It is a relatively immature branch of geology. Petroleum Geologist. - This term may be applied to a fully qualified geologist who is engaged for a time, be it a job, a contract, or a lifetime, in the work of finding and developing deposits of petroleum and related substances. No man may properly be called a petroleum geologist who is not first a fully qualified geologist.

Jan 1, 1946

By E. J. McCaustland

The behavior of steel after overstrain and at moderate temperatures is fairly well known. It has been made the subject of much investigation, and our knowledge is clear and definite on many points. The ultimate raising of the elastic limit, after moderate overstrain, and the consequent lowering of the ductility, seem to be well established. It is also well understood that the immediate effect of overstrain is to lower the elastic limit, possibly to zero, but that if not interfered with, this limit will subsequently rise higher than before. The " tests after moderate temperature," reported in this paper, were undertaken to verify the above statements for the particular steel under investigation, and also to determine, if possible, the total time required for complete recovery from this state of overstrain. The behavior of overstrained steel at temperatures at or below 32" F. is not so well known. Tests made by Prof. E. G. Coker, at McGill University,' show that steel, overstrained and subjected to cold, will remain in a state of overstrain for an indefinite period. I am not aware of any other published results of tests along this particular line. The effect of time and temperature on the recovery of steel from overstrain was made in 1902-3 the subject of some investigation in the laboratories of the College of Civil Engineering of Cornell University. A general plan was outlined in connection with the regular courses of instruction in testing of materials; but the press of routine work and the demands of the schedules on the time of the students were so great as to presage long delay in the completion of the work. Not much had been accomplished up to 1904-05, when Messrs. E. C.

Jan 1, 1907

By C. A. Stetefeldt

The purpose of this paper is to convince the managers of silvermills that their customary reports in regard to the percentage of silver saved are far from the truth. It may be unpleasant for them to have the proofs of this fact brought before the public, and for this rezson the author refrains from giving the names of the mines and mills from which the statistics here recorded were obtained. It may be asked: What is gained by informing the stockholders of our silver-mines that they receive incorrect reports? Will this increase their dividends or lessen their assessments? In the first place, it is always better to publish honest facts than fiction. In the second place, many superintendents believe in the correctness of their reports, and have no idea how much they deceive themselves. Finally, the knowledge that hitherto unexpected losses of silver take place may lead to the adoption of methods by which these losses are greatly reduced. These remarks refer also to smelting-works. The present paper, however, is concerned exclusively with amalgamation and lixiviation. The first and most important error is found in the inaccuracy of the commercial assay; the second in the incorrect sampling of tailings in amalgamation. Further, mills not doing custom-work, but reducing exclusively ores from mines to which the mills belong, are in the habit of weighing the ore only approximately and without making moisture-tests. Thus, a correct basis for calculating the actual percentage of silver extracted is lacking. The superintendent, then, finds it convenient to report the apparent extraction, i.e., the extraction indicated by comparing the value of the roasted ore, minus soluble salts, with the value of the tailings. How many errors are thereby committed it is not necessary to point out.

Jan 1, 1895

By J. E. Lawver, F. S. Knoll

Introduction Electrostatic separation is the selective sorting of solid species by means of utilizing forces acting on charged or polarized bodies under the influence of an electric field. Electrostatic separation is effected by adjusting those forces acting on particles due to the electric field as well as co-acting forces such as gravity or centrifugal forces so that the different species will have different trajectories at some predetermined time. Electrostatic separations can be broadly defined as being either electrophoretic or dielectrophoretic. Electrophoresis is the separation of charged particles in an electric field, whereas dielectrophoresis is the separation of neutral particles in an electric field1. Examples of an electrophoretic separation can be found with sepa¬rations that use corona charging (ion bombardment), contact charging (triboelectric) and conductive induction. Dielectrophoresis motions are due to the stress and repositioning of charges, i.e. polarization of a neutral particle when exposed to a non-uniform electric field. Separations made using corona discharge devices are often called high-tension, electrodynamic or ion bombardment separations. These are the most prevalent in use today in mineral processing. Dielectrophoretic separation of most minerals is based on differences in dielectric constants of the solid species and usually requires the use of expensive intermediate dielectric fluids. Dielectrophoresis has not been employed for industrial mineral separations, though its effects pose interesting possibilities1, and pilot-plant units developed by the U.S.B.M. are available for testing2. Our discussion will be limited to the three forms of electrophoresis found in commercial practice. Typical Industrial Separations Typical industrial applications of electrostatic separation are: 1. Dry concentration of heavy minerals: ilmenite, rutile, zircon, monazite, xenotime, columbite-tantalite, cassiterite, hematite, scheelite and others. 2. Separation of salts: halite-sylvite, etc. 3. Purifications of foodstuffs such as the removal of impurities and

Jan 1, 1986

By Alexander V. Derevyanko, Victor P. Popov, Alexander I. Raitchenko

"If an electric current flows along some electroconductive suspension in columnar form the solid particles are 'experienced thermal, mechanical, and electromagnetic influences.The objects were suspension Sn (liquid) - Ni-Cr-Mo-W alloy (solid particles). This is refractory alloy on the Ni base. The direct constant current (with density -106 A/m2 ) flowed through the named suspension during 180+300 sec. At the beginning of experiments samples were ones containing particles suspended uniformly in volume. Although density of solid particles was ~9x103 kg/m3 , i. e. higher than density of liquid Sn (-6.8x103 kg/m3 ), after end of this processing, the non-uniform distribution of particles in volume of samples was observed: concentration of Ni-alloy particles in lower part was smaller than their concentration in upper part of samples, and simultaneously their concentration is increased near outer surface. There was probably the natural convection of Benard-Rayleigh type which had carried, so lid particles upwards, and, in same time, there was the action of spatial Lorentz-forces directed to center forcing the radial movement.The knowledge of named phenomena can be useful for elaboration of technology of gradient dispersed materials and development of some materials science fields.IntroductionThe liquid metal with the electric current or under the alternating magnetic field is experienced compression. This action causes the pressure within metal and the change of the surface of the metal column (see, for example, [1-4]). One of results of such an electromagnetic compression is extraction of the foreign solid particles from a cylindrical liquid sample to surface in the radial directions. However, more complicated paths of the inclusions are observed under some conditions of electric treatment."

Jan 1, 1999

By Harold S. Davis

SURROUNDING the nuclear core of an atomic energy plant there are usually one or more thick walls of concrete, as required to protect instruments and personnel from the harmful effects of nuclear radiations. Sometimes these massive walls are of ordinary concrete weighing about 150 pcf. To reduce wall thicknesses, concrete weighing 200 to 350 pcf may be used. Such high densities are obtained by using natural aggregate processed from heavy ore, or by using steel slugs or iron shot in concrete. Mix data for a number of high-density concretes are summarized in Table I.1 High density at low cost is of prime importance in shields designed to absorb gamma rays. On the other hand, biological shields located near the reactor core must attenuate neutrons as well as gamma rays. In general, a biological shield should contain: 1) heavy elements to slow down high energy neutrons and to absorb gamma rays, 2) either light elements or hydrogenous materials to moderate neutrons of intermediate energy, and 3) materials to absorb neutrons once they have been slowed down to thermal energies. Some shield materials, iron and water for example, are effective in one or more of the above ways. On the other hand, some otherwise excellent shield materials have certain undesirable radiation properties that limit the ways or number of places they can be used. For example, when iron absorbs neutrons it emits secondary gamma rays of high energy. On the other hand, boron absorbs neutrons avidly without producing high energy gamma rays. In spite of its high cost, boron is sometimes used in concrete to minimize production of secondary gamma rays. In some shielding applications it is necessary to avoid materials that become radioactive when subjected to neutron bombardment, continuing to give off high energy gamma rays for long periods after being removed from a neutron field.

Jan 5, 1957

By T. Tsutsumi, S. Kukino

"During the diametrical compression test, the tensile stress generated near the loading plate is influenced by the contact area between the loading plates and specimen. However, very few studies have determined the contact area. Theoretical or analytical models have shown that for an orthotropic material (i.e., with material properties that differ along each of three mutually orthogonal twofold axes), the maximum tensile stress is generated at the center of disk when the angle of the principal material direction to the loading direction is close to ?/4. The maximum value is almost constant, regardless of the contact area. Conversely, the maximum tensile stress is generated near the loading plate when the angle between the principal material direction and loading direction is small. The maximum value decreases as the contact area increases. Therefore, in the latter case, the influence of the contact area on tensile strength measurement of is significant.In previous studies, the distribution of stresses applied on the loading plate is assumed to be a uniform load. In reality, the applied stress is highest at the center of loading plate and seems to decrease with distance from center. The applied load disappears at the edge of loading plates. In this study, in order to satisfy this boundary condition on the loading plate, the cosine curve is adopted as the distribution of load applied on the loading plates in a theoretical model of the diametrical compression test. Furthermore, the elastic solution using boundary conditions shown in this study is used to obtain the tensile stress distributions on the loading axis for an orthotropic circular plane. These distributions are compared with empirical results obtained under uniform loading with a loading plate or concentrated loading in previous studies."

Jan 1, 2015

By G. R. Kotler, W. A. Tiller, H. V. Ashcom, S. O&apos, Hara, W. C. Johnston

The grain-refinement effect of electromagnetic stirring of Sn-Pb alloys during solidification is investigated at higher field strength and in larger-sized samples. It is found that the grain-refining effect is due to a crystal multiplication phenomenon rather than a nucleation phenomenon. The effect increases with sample size for a fixed field strength and a fixed supercooling bath temperatures. The effect in other alloys was investigated. IN a recent publication1 it was reported that significant grain refinement could be produced during the solidification of a supercooled melt of Sn-Pb alloy when a critical degree of electromagnetic stirring was present in the melt. Thus, for a particular supercooling, AT, a critical magnetic field, Hc, existed at which the number of grains per unit volume, n, increased rather abruptly by a factor of 103 to 104 as the field, H, was increased by a small amount. It was further found that the undercooling at which the melt spontaneously nucleated, ?Tn, was independent of the magnetic field. These authors matched their experimental results against the qualitative expectations of existing theories and found each theory somewhat unsatisfactory. One important question that was not answered in this previous work was "should the effect be classed as a nucleation phenomenon or as a crystal-multiplication phenomenon?" Other valid questions that need answering are: i) do higher magnetic field strengths alter the nature of the results?; ii) what is the effect of higher lead content in the alloy?; iii) what changes occur when one extends the experiments to larger-diameter samples?; and iv) is this a universal effect applicable to the grain refinement of all materials? The present work directs its attention to answering these five questions. The

Jan 1, 1965

By L. G. Westgate

PART I.-AREAL GEOLOGY§ PIOCHE lies 240 mi. southwest of Salt Lake City, in southeastern Nevada, 19 in. west of the Nevada-Utah line. It is at the end of a branch line (33 m.), which connects at Caliente with the Los Angeles and Salt Lake division of the Union Pacific System. Its commercial relations are with Salt Lake City and Los Angeles, chiefly with the former. The surrounding area is part of the Great Basin, an arid region of alternating mountain range and intermont plain, the latter floored with outwash from the mountains. About Pioche the plain varies between 4700 and 6000 ft. above sea level. The town lies in a valley at the east base of a low northwest-southeast range (the Pioche Hills) 12 miles in length, which rises about 1000 ft. above the adjacent flat. West of the. Pioche Hills is a higher north-south range consisting of two parts: to the south the Highland Range, between Bennett Pass and Stampede Gap; to the north the Bristol Range, from Stampede Gap to Bristol Pass. This double range reaches altitudes of 8000 to 9000 ft., or more, (the highest point, Highland Peak, is 9395 ft.) and rises some 2500 ft. above the surrounding plain. It is continued in lower hills to north and south. Smaller ranges rise from the flat west of the Highland and Bristol ranges. The area studied and shown on the map (Fig. 1) is covered by 3 one inch to the-mile topographic sheets: the Highland Range, the. Bristol Range, and the Panaca, the latter mapped in part only. The sedimentary rocks of the district include Paleozoic limestones, sandstones and shales, Pliocene tuffs, and modern wash. Igneous rocks are represented by intrusive dikes and stocks and by extensive lava flows of mid-Tertiary time.

Jan 1, 1927

By Juhani Pulkkinen, Pekka Lappalainen

Preplaced cable bolts - fully grouted old hoisting cables or stress relieved steel strands - have been used succesfully to pre- reinforce ore contact zones and pillars in sublevel stoping at Outo- kumpu Oy mines for ten years. The purpose is to make open stoping methods possible even in "poor'' conditions and to decrease waste rock dilution. Since 1971 more than 120 km cable bolting has been done, and plans for this year in five mines amount to 33 km. In order to understand the function of cable bolt, pull-out tests have been done both in the laboratory and in situ. Bond strength between cable and cement is highly dependent on cable structure and cable surface dirtiness. Steel cables with steel core and rough surface structure have highest bond strength ( 6 MP~). A cable bolt is a friction bolt. After losing its peak bond strength - after starting to move - a cable bolt still has a high loading capacity due to the friction caused by the uneven surface of the cable. Cable bolting is done before actual stoping from existing drifts, sublevel drifts, e.g. or from special bolting drifts. In general stress relieved steel strands are used; 2 x 15.2 mm dia per hole. FEM or BEM calculation is utilized in cable bolting design. Bolts 2 are in fan shape, 10 m ... 50 m long and are spaced 1/20 m ... 1/50 m2 at stope walls. Pretensioning of cable is not needed, when bolting is done before rock deformations. Bolting costs vary between 0.3 USD ... 1.0 USD/ore ton. In the beginning only manual cable installing technique bras used. Now bolting can be done as fully mechanized with the developed cable bolting machine; i.e. drilling of the hole, installing and cutting of cables and grouting of hole.

Jan 1, 1983

Introduction A Hypothetical Scenario: Suppose that your company's research department has developed a new device which represents a significant innovation. You would like to begin selling it as soon as possible. The new device has not been publicly disclosed. You're not sure about what type of intellectual property protection you should be seeking, or when you should be seeking it. As discussed below, assuming that the costs are worth it, a patent application probably should be filed before any public disclosure is made. In general, if you do not file a patent application prior to a public disclosure, you will lose rights. Major Types of Intellectual Property In this paper, intellectual property protection is broadly discussed. Practical steps which can be taken to minimize the possibility of losing intellectual property rights (and maximizing the possibility of benefiting from your company's intellectual property) are outlined at the end of this paper. The issues discussed in this paper are somewhat complex, because a number of outcomes are possible, depending on the facts. It is strongly recommended that you seek legal advice in your jurisdiction in connection with any particular circumstances relating to intellectual property rights. "Intellectual property" refers to a number of different types of rights. The major types of intellectual property are: (i) patents; (ii) trademarks; and (iii) copyright. Trade secrets are also usually considered to be a type of intellectual property, and they are also discussed in this paper because of their importance. In general, each of these types of intellectual property protects different subject matter, although there can be some overlap. Intellectual property rights are generally territorial in nature. The scope of protection of a type of intellectual property in a country (e.g., patent protection) depends on whether the specific national requirements for protection have been met.

Feb 1, 2008

By Clare B. Carlson, C. P. Proctor

THE history of the froth flotation of coal is relatively short. The flotation process was applied to fine-coal cleaning about the time of the end of World War I. Coal flotation finds more widespread use in Europe than in the United States and is used on a commercial scale in nearly all major coal-producing countries in the world. In Fig. 1 the general arrangement of a froth-flotation plant at a British colliery is shown. GENERAL FEATIJIEES OF THE PROCESS Application The flotation process is applicable to the cleaning of the fine sizes, particularly minus 48-mesh coal, although it may be used on sizes as coarse as 1/8 in. Since most cleaning processes usually are not effective on sizes smaller than 48-mesh and certainly not effective on minus 100- mesh, the froth-flotation process offers a solution to the problem of cleaning these sizes. This process consists-of agitating the feed pulp with a small amount of reagents, usually 1.0 to 2 ½ lb. per ton of feed in the presence of water and air; the reagents help to form small bubbles that collect on the particles having a greater affinity for the bubble surface than for the water surface, in this case the fine coal, and the bubbles buoy these particles to the surface to form the frothor concentrate. Slate and shale particles remain wetted and suspended in the water to be drawn off as tailing. The frothers commonly used in coal flotation are cresylic acid, pine oil, and alcohols. More expensive frothers, used in ore flotation, work satisfactorily but do not compare with these cheaper reagents for over-all cost. Collectors- used are low-grade petroleum fractions, such as cheap, partly refined fuel oil, or lubricating oil, sometimes mixed with small amounts of kerosene. Other collectors used are the fatty acids and their

Jan 1, 1943

By C. C. E. Pretorius, V. M. Mathoho, A. van Zyl, R. J. Mostert

The in-service degradation of the mechanical properties of steel components through the damage mechanism of high temperature hydrogen attack (HTHA), is a topic of concern in the refining and green hydrogen industry. This damage mechanism occurs in susceptible steels operating in environments at high temperatures and hydrogen pressures. The current investigation deals with the indirect monitoring of mechanical degradation via tracking of the swelling strain in affected structures. An autoclave with an AISI 316 shell was utilized to simulate accelerated HTHA damage at 550 °C and 46 bar for exposure times ranging from zero to 700 hours. The progress of the HTHA damage was tracked using encapsulated high-temperature strain gauges. The correlation between the swelling strain and mechanical property degradation was studied to develop a methodology for the continuous monitoring of embrittlement. The tensile sample orientation of the carbon steel plate was included as a variable, i.e., samples parallel, transverse, or perpendicular to the plate rolling direction were included, since it has been shown that the sample orientation influences the HTHA damage features. For the through-thickness orientation, and upon exceeding a threshold value of exposure time, all tensile properties were severely degraded, with values in the order of a 90 per cent reduction being observed. It was found that the degradation of carbon steel mechanical properties can be correlated to the swelling strain measured during exposure. The critical point for mechanical property degradation in the plate through-thickness orientation, whereafter a severe decrease in the ductility of the material occurs, was found to be in the order of 1% of the total swelling strain measured during exposure, equivalent to 65 microstrain. This threshold was found to be significantly lower than that expected from the literature, where limits of 400 to 1000 microstrain were postulated.

Nov 27, 2024

By E. Buehler, R. H. Willens

A Hew melting technique has hem adapted to the rapid quenching of- alloys from the liquid state. The inelting method has no limitations on the alloys investigated for there is no reaction with crucible materials and the most refractory materials are easily melted. The vate of heating is so rapid that alloys which have a high vapor pressure constituent can be melted with a minimal loss in material. Several new superconductovs have been discoveved by vapid quenching of lolten alloys. THE rapid quenching of alloys from the liquid state has led to the discovery of many new metastable phases. The methods initially used were limited to alloys which did not react with crucible materials.1,2 There was also the unmentioned limitation in tem- perature. Alloys with melting points much greater than 2000°C could not be melted in the rapid-quench apparatus. Recently, there have been successful attempts to rapidly quench reactive alloys by Moss et at. and Matthias Moss et al. injected powdered material (325 mesh) into a high-temperature plasma and the high-velocity molten droplets impinged on a cooled copper plate. The technique innovated by Matthias was to melt the alloy in an arc furnace and splatter it against a copper plate by means of a high-velocity gas jet aimed at the melt. I) FAST COOLING APPARATUS The creation of a metastable phase in a given alloy system by rapid cooling from the melt is contingent on the quenching rate. Some alloys require very slow rates while other alloys require the ultimate in quenching rate. At the present time, the vertical-gun technique of Duwez and willens' has demonstrated, in practice, the highest quenching rates and thus the best

Jan 1, 1967

By M. Lahtinen, B. Saxén, M. Latva-Kokko

The conventional jarosite precipitation process with neutralization by zinc calcine is widely utilized in the zinc industry. However, it has a significant drawback of causing losses of valuable metals like zinc, lead and silver to the jarosite. This comes mainly from the content of these metals in the calcine used for neutralization. As the zinc plants today want to maximize metal recoveries and minimize the amount of residues, this matter has become more and more relevant for zinc producers. Outotec developed and patented in early 2000 an improved version of the jarosite precipitation process in which the need for neutralization can be minimized, thus the metal losses to the jarosite also can be minimized. At the same time, the iron content of the jarosite increases and the amount of produced jarosite is smaller. The main feature of this process is to start the precipitation from ferrous iron after having reduced all the iron by zinc concentrate in a separate step before jarosite precipitation. Iron is then oxidised back to the ferric form simultaneously with jarosite precipitation. By this method, the formation of sulphuric acid is only half that compared to the conventional method and the need for calcine for neutralization can be avoided. High mixing and oxygen dispersion capability are needed in this jarosite precipitation process. Such capabilities are found in the Outotec OKTOP® reactor series. High performance reactors are not only needed to generate high quality precipitates, but also to maximize oxygen utilization; i.e., to minimize operation costs. Outotec’s latest development in this area is the OKTOP® plant product in which not only the reactors, but also all the accessories are designed, manufactured and delivered by Outotec. One responsible supplier ensures efficient and fast delivery and can provide mechanical and performance guarantees for the entire plant unit.

Jan 1, 2016