Search Documents

By Hanlu Xie, Liang Yu, Ping Wang, Yuanchi Dong

"The leaching process is the first step when recycling BF slag as raw material for some other products. While studying the kinetics of the BF slag leaching process, a fractal phenomenon was found, which indicated some interesting mechanism in the process. The result suggested a new understanding of the leaching process in detail which useful for the industrial applicationIntroductionTypical composition (wt. %) of blast furnace slag varied in a pretty wide range: SiO2 30–40, Al2O3 10–20, CaO 30–40, MgO 5–10.The ground granulated slag is commonly used as base of roadway (mixed with natural inert for paving, soil stabilization, etc.) or one of the resources of Portland cements because of its good hydraulic activity [1]. To recycle the slag economically, the selective recovery of some components of the slag may be considered. As main components exist in the slag, silica [2, 3 and 4] and alumina [4] recovery was first considered.While recovering of silica from the slag, silica gels are recovered selectively from the leaching solution deriving from the treatment of the slag with waste sulfuric acid. After separation of the exhausted solid of leaching, the silica gel is precipitated from the solution at pH 3.2. Although the silica gels obtained by this procedure contain many impurities and need some more work afterward, it is the first and important step for the process.In the prior work [5], silica extraction using blast furnace slag had been investigated, focused on the pH value of selectively silica extraction. In the present work, kinetics of the leaching process was focused. It is important to design an economical process.ExperimentalThe composition of the slag and the calcined gels has been determined by a LINK860 (Oxford Instruments, Oak Ridge, TN) energy dispersive spectrometer (EDS) in conjunction with a CAMBRIDGE S250-M2 (Cambridge Instrument Ltd., Cambridge, U.K.) scanning electron microscope(SEM). The leaching of slag and the precipitation of silica gels have been conducted at atmospheric pressure in a stirred reactor placed at temperature controlled by a heated water bath."

Jan 1, 2008

By Michael Karmis

"In December 2011, the U.S. Attorney’s Office for the Southern District of West Virginia, the U.S. Department of Justice, Alpha Natural Resources (ANR) and Alpha Appalachia Holdings entered into a nonprosecution agreement related to the explosion at the Upper Big Branch Mine (UBB) that killed 29 miners. This coal operation was owned by Performance Coal Co., an affiliate of Massey Energy Co., which was acquired by ANR in June 2011, more than a year after the UBB explosion. Pursuant to the agreement, ANR agreed to:• Establish a trust within 120 days.• Pay a total of US$48 million into the trust to be used solely to fund and administer research and development (R&D) projects to improve mine health and safety.• Administer the trust by three highly qualified individuals with academic and/or professional backgrounds in mine health and safety.In April 2012, the Alpha Foundation for the Improvement of Mine Safety and Health was created. The three directors - Michael Karmis, president; David Wegman, vice presidenttreasurer, and Keith Heasley, vice presidentsecretary - approved a plan to expend both the interest and principal of the trust, aiming at an 8-10 year research horizon. The foundation also appointed David Belden, an experienced manager of nonprofits and professional associations, as the first executive director of the foundation. The IRS approved the foundation’s tax-exempt application, as described in Section 501c(3) of the Internal Revenue Code, on Dec. 18, 2012. The board established guiding principles of the foundation, which are as follows:• Mission: to improve mine health and safety through funding R&D projects to qualified academic institutions and other not-for-profit organizations.• Vision: to enable miners in the future to be free of work related injury or disease by the implementation of the results of the projects funded by the foundation and undertaken by the best researchers from any discipline that can contribute. The foundation is now approaching its third year and regularly posts updates, including semi-annual reports, to its website (www.http.alpha-foundation.org/), which serves as the main medium for communication with the broader stakeholder community"

Jan 1, 2014

By C. L. Glorioso

As an introduction and credentials for our talk, let me take a moment to introduce you to Wimpey Worldwide and specifically to Wimpey Minerals, USA, Inc.

Jan 1, 1995

By P Craig, A Crosky, P C. Hagan, E Elias, B Hebblewhite, S Saydam, D Vandermaat

"Premature failure of rock bolts has been recorded at twelve underground coalmines over the past 15 years in Australia. Over the last four years, UNSW Australia has been conducting an Australian Research Council (ARC) and Industry funded linkage research project into premature failure of rock bolts. The extent of the problem was investigated by underground surveys of mines with known prematurely failed bolts using visual mapping, non-destructive load and ultrasound testing. A major component of this project was to define the environmental factors responsible for corrosion of rock bolts. The environment to which a rock bolt is exposed will include groundwater chemistry, the mineralogy of the strata, atmosphere within the drill hole and even microbial activity. This paper focuses on the groundwater survey and analysis findings to date along with in-hole bolt corrosion coupons installed into field sites. Corrosivity classification systems exist for general corrosion but do not apply to the rock bolt stress corrosion cracking (SCC) problem found in Australian underground coal. The method of in situ investigations is leading towards the building of a corrosivity classification model to assist mines in prediction of premature rock bolt failure. An ‘in-hole bolt corrosion coupon’ development by the project may have multiple benefits of: helping quantify any corrosivity classification system providing an in situ ground support corrosion monitoring tool for testing possible corrosion protection solutions.CITATION:Craig, P, Saydam, S, Hagan, P C, Hebblewhite, B, Vandermaat, D, Crosky, A and Elias, E, 2014. An investigation of the corrosive impact of groundwater on rock bolts in underground coalmines, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference, pp 277–286 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 5, 2014

By L. Alagha, O. Molatlhegi, S. Khatibi

"In the present study, the effect of organic/inorganic (hybrid) polyacrylamide polymer on fine coal flotation was investigated. Raw coal samples contain about 37% of ash-forming mineral at a feed size of -75 + 38 um were subjected to flotation tests in the presence of in-house synthesized hybrid Al(OH)3-PAM at different polymer dosages and pH values. Results show a significant improvement in both combustible recovery and ash rejection at 1 ppm polymer dosage. Further improvement of combustible recovery was obtained when flotation was performed at pH 5. Interfacial properties of coal particles before and after flotation were examined through electrokinetic (zeta potential) measurements of coal/water slurries. Zeta potential vs. pH curve were established and compared. In the case of raw coal/water slurry, zeta potential-pH curve resembles the ash-forming minerals (silica and clays) more than coal. After Al(OH)3-PAM-assisted flotation, the zeta potential of froth/water slurry shifted to more positive values point which strongly indicates significant removal of ash-forming minerals from coal by Al(OH)3-PAM. INTRODUCTION Coal has been a major commodity in meeting the world energy demand during the past several decades (Milici et al., 2013). According to the international energy agency, global coal demand will continue to increase for the coming decades. With increasing world population, the global electricity demand would also increase as more people would get access to basic electricity especially in developing countries (Maggio & Cacciola, 2012). Due to this increase in energy consumption, operations in coal mining and beneficiation processes have been highly mechanized to meet the demands. This mechanization has increased the quantity of raw fine coal particles produced which contain high amount of ash-forming mineral matter (slimes). Aplan et al., have reported that the major constituents of ash-forming minerals in U.S.A coal are clay minerals such as kaolinite, montmorillonite and illite (Aplan, 1997). Conventional froth flotation for fine coal cleaning suffers mainly from two major problems: 1) Low recovery of ultrafine coal particles due to slime coating by ash-forming minerals, and 2) The lack of selectivity, which results in the flotation of middlings and entrainment of mineral fines in the froth (Polat et al., 2003). Slime coating on both valuable and air bubbles have been proposed to explain the observed reduction in flotation recovery especially when fine grinding is required. In this case mineral matter may be degraded to extremely fine or colloidal sizes thereby creating difficulty in the water clarification process such as flotation. Slimes inhibit bubble-particle attachment, and increases reagent consumption due to the increase in solid/liquid interfacial area, resulting in low coal recovery."

Jan 1, 2015

By André Luis de Oliveira

O Alto Forno 3 (AF3) da Companhia Siderúrgica Nacional (CSN) é o equipamento muito importante no processo siderúrgico da Usina Presidente Vargas (UPV), situada em Volta Redonda (RJ), por responder por mais de 70% da produção de gusa da UPV. Na produção de gusa é gerado o Gás de Alto Forno (GAF), subproduto de alta relevância, pois este gás sai do topo do AF3 com grande pressão e cinética, energia essa passível de utilização. Em 2007 a CSN, optou por adquirir um equipamento denominado “Top Pressure Recovery Turbine” (TRT), capaz de aproveitar tal energia para gerar energia elétrica. Em 2013, a equipe de supervisores da KHI – Kawasaki Heavy Industrie, fabricante da turbina, veio para o Brasil para realizar no equipamento os testes a frio e a quente para na seqüência vir a operá-lo. Ocorre que fatores alheios ao objetivo desta apresentação impediram a equipe da KHI de partir o equipamento no tempo previsto, bem como de retornar ao Brasil para dar seqüência nas atividades. Em novembro de 2013 a CSN definiu por partir o equipamento com recursos próprios, sendo este o foco do trabalho. A presente contribuição técnica vem mostrar o trabalho desenvolvido internamente pelo grupo técnico a fim de finalizar o projeto e colocar a Turbina de Topo (TRT) em operação, fato este dado total ênfase pela direção da empresa devido ao cenário nacional de crise energética em que os valores de energia estavam no limite máximo permitido pela legislação e impactando diretamente nos custos da empresa.

Sep 25, 2017

Problems caused by water discharge from surface mine ventilation shafts can be significant and are usually unforseen. The discharged water is often hyper-saline or acidic and can cause environmental degradation over a wide radius. It can also lead to recurring power pole fires and primary fan breakdowns. A range of solutions to the water discharge problem has been implemented in many Australian mines. In most cases the solutions have been ad hoc, with the overall cost and effectiveness varying tremendously. This paper reviews and contrasts the practicality and effectiveness of the various available remedial options.

Jan 1, 2002

By José Wilmar Calderón-Hernández

Aços inoxidáveis supermartensíticos (AISM) surgiram em meados dos anos 1990, após algumas empresas petroleiras e centros de pesquisa empreenderem projetos para desenvolver aços inoxidáveis com boa resistência mecânica e resistência à corrosão. A força motriz destes projetos foi a procura de aços inoxidáveis alternativos para os aços duplex e superduplex na extração de reservas de petróleo “offshore”, devido a seu alto custo e a problemas de produção naquela época. Os AISM são derivados dos aços martensíticos inoxidáveis convencionais, possuem menor teor de carbono, para permitir melhor soldabilidade e melhorar a resistência à corrosão, adição de níquel para evitar a presencia de ferrita delta (d) e adição de Mo, que também aumenta a resistência à corrosão. Através de ensaios de polarização potenciodinâmica foi avaliada a resistência à corrosão de um AISM 13Cr-5Ni-2Mo, denominado neste trabalho como AIS_2Mo, para três diferentes ambientes, NaCl, NaCl+CO2 e NaCl+H2S (soluções desaeradas). O material foi recebido como chapas laminadas a quente, as quais foram normalizadas a 1.050°C (½ hora/ar) e posteriormente revenidas a 600°C (2 horas/óleo). O melhor desempenho foi observado no eletrólito contendo apenas NaCl, com potencial de pite ao redor de 40 mV (ECS); o ambiente mais agressivo foi a mistura NaCl+H2S, com potencial de pite ao redor de -300mV (ECS), a mistura NaCl+CO2 teve potencial de pite intermediário, com valor 60 mV (ECS) abaixo do eletrólito contendo só NaCl.

Aug 8, 2018

By M. Shevchenko

Integrated experimental and modelling research program on the phase equilibria and development of thermodynamic databases of the lead and copper metallurgical gas/ slag-matte-metal-solids systems (PbO-“Cu2O”-FeO-Fe2O3- ZnO-CaO-SiO2) is being undertaken to support improvements in the pyrometallurgical smelting and recycling processes. This is the first systematic investigation of phase equilibria of slag systems in equilibrium with Pb metal, providing information for systems in which copper coexists in slag with lead or zinc as major components. The experimental studies involve high-temperature equilibration of synthetic samples, rapid quenching, and measurement of the compositions of equilibrium phases using electron probe X-ray microanalysis (EPMA). FactSage-based thermodynamic database development is integrated with experimental research. Initial thermodynamic assessments are used to identify priority compositions and conditions for experiments, which are planned to provide specific data to assist thermodynamic optimisation. Significant improvement in the accuracy of the phase equilibria description is achieved. Continuous database improvement and extension to include new elements are targeted. Example of industrial application is given.

By R. T. Hukki

The paper describes a two-stage industrial hydraulic classification system including hydrocyclones for primary classification and newly developed cone classifiers for secondary classification. Performance data based on large scale grinding and classification tests are presented.

Jan 1, 1981

By R. G. Johnston

Minerals have many uses in paint systems. These roles include use as primary and extender pigments, sheen control, film durability enhancement, and rheology control. These and other uses of minerals in paints, and the effects of mineral quality variations on coatings performance are discussed. As coatings performance requirements become more demanding, tighter consistency of important mineral properties, such as particle size distribution and purity, is becoming increasingly vital. Future directions of mineral use to meet projected environmental restrictions and performance demands on coatings, including the use of advanced minerals technologies, are examined.

Jan 1, 1993

By S. J. Schatzel, R. B. Krog, H. Dougherty

Longwall face ventilation is an important component of the overall coal mine ventilation system. Increased production rates due to higher-capacity mining equipment tend to also increase methane emission rates from the coal face, which must be diluted by the face ventilation. Increases in panel length, with some mines exceeding 6,100 m (20,000 ft), and panel width provide additional challenges to face ventilation designs. To assess the effectiveness of current face ventilation practices at a study site, a face monitoring study with continuous monitoring of methane concentrations and automated recording of longwall shearer activity was combined with a tracer gas test on a longwall face. The study was conducted at a U.S. longwall mine operating in a thick, bituminous coal seam and using a U-type, bleederless ventilation system. Multiple gob gas ventholes were located near the longwall face. These boreholes had some unusual design concepts, including a system of manifolds to modify borehole vacuum and flow and completion depths close to the horizon of the mined coalbed that enabled direct communication with the mine atmosphere. The mine operator also had the capacity to inject nitrogen into the longwall gob, which occurred during the monitoring study. The results show that emission rates on the longwall face showed a very limited increase in methane concentrations from headgate to tailgate despite the occurrence of methane delays during monitoring. Average face air velocities were 3.03 m/s (596 fpm) at shield 57 and 2.20 m/s (433 fpm) at shield 165. The time required for the sulfur hexafluoride (SF6 ) peak to occur at each monitoring location has been interpreted as being representative of the movement of the tracer slug. The rate of movement of the slug was much slower in reaching the first monitoring location at shield 57 compared with the other face locations. This lower rate of movement, compared with the main face ventilation, is thought to be the product of a flow path within and behind the shields that is moving in the general direction of the headgate to the tailgate. Barometric pressure variations were pronounced over the course of the study and varied on a diurnal basis.

Jan 1, 2018

By S. J. Schatzel, R. B. Krog, H. Dougherty

Longwall face ventilation is an important component of the overall coal mine ventilation system. Increased production rates due to higher-capacity mining equipment tend to also increase methane emission rates from the coal face, which must be diluted by the face ventilation. Increases in panel length, with some mines exceeding 6,100 m (20,000 ft), and panel width provide additional challenges to face ventilation designs. To assess the effectiveness of current face ventilation practices at a study site, a face monitoring study with continuous monitoring of methane concentrations and automated recording of longwall shearer activity was combined with a tracer gas test on a longwall face. The study was conducted at a U.S. longwall mine operating in a thick, bituminous coal seam and using a U-type, bleederless ventilation system. Multiple gob gas ventholes were located near the longwall face. These boreholes had some unusual design concepts, including a system of manifolds to modify borehole vacuum and flow and completion depths close to the horizon of the mined coalbed that enabled direct communication with the mine atmosphere. The mine operator also had the capacity to inject nitrogen into the longwall gob, which occurred during the monitoring study. The results show that emission rates on the longwall face showed a very limited increase in methane concentrations from headgate to tailgate despite the occurrence of methane delays during monitoring. Average face air velocities were 3.03 m/s (596 fpm) at shield 57 and 2.20 m/s (433 fpm) at shield 165. The time required for the sulfur hexafluoride (SF6 ) peak to occur at each monitoring location has been interpreted as being representative of the movement of the tracer slug. The rate of movement of the slug was much slower in reaching the first monitoring location at shield 57 compared with the other face locations. This lower rate of movement, compared with the main face ventilation, is thought to be the product of a flow path within and behind the shields that is moving in the general direction of the headgate to the tailgate. Barometric pressure variations were pronounced over the course of the study and varied on a diurnal basis.

Jan 1, 2017

By Julian Malnic

Various natural, commercial, engineering and operational factors govern the evolution of approaches taken in the exploration for Seafloor Massive Sulphides (SMS) and in delineating the resource. These stages are prerequisites to the proposed mining of SMS deposits. This paper presents and analyses these factors from the view of an SMS exploration company that is pioneering the exploration of this rich alternative source of zinc, copper and gold. Current exploration practices developed by Marine Scientific Research (MSR) workers for SMS deposits are expected to give way to industry-generated methods as the SMS exploration industry gathers momentum. The exploration process falls into three phases that are described below: Prospecting (locating targets), Indicating Resources, and Measuring Mineral Resources Considerable streamlining of the SMS exploration process will accelerate the rate of discovery. The economics of SMS mining are projected to be superior to comparable terrestrial mining operations in both operating cash cost and capital terms.

Jan 1, 2001

By R. J. Leary, W. M. Mahan, F. X. Tartaron

A new type of apparatus for prerefining molten blast furnace iron and to reduce the cost of subsequent steelmaking consists of a funnel - shaped device lined with firebrick into which a horizontal stream of molten pig iron is directed tangentially at the top . The rotary motion thus induced causes the stream to flatten itself upon the wall and flow in a spiral path to the outlet ; thus , the device was termed " vortex cone .' Oxygen and other refining agents are impinged upon the flowing metal in the cone where reaction is facilitated by the large metal surface exposed and the turbulent flow pattern . Experiments with water in 1 - foot - diameter funnels provided an idealization of the flow patterns to be expected with molten iron . A brick - lined reactor 3 feet in diameter was built for desiliconizing molten pig iron in lots of 1 to 2 tons . At flow rates of 0.3 to 0.5 ton min - 1 (430 to 720 tons per day ) this apparatus was 64- to 90 - pct effective in desiliconization with oxygen efficiencies of 19 to 41 pct . Detailed experiments to develop basic engineering data are underway , and adaptation of this principle to other reactions and reactants is planned .

Jan 1, 1964

By R Wheeler, E Stalenberg, J Lemon, M S. Crowther, D Lunney, K Ross

Gunnedah, in north-western New South Wales (NSW), including the town, the surrounding Liverpool Plains and the Pilliga forests to the west, are currently the subject of intense mining interest for coal and coal seam gas. Achieving positive outcomes for koala conservation on mined landscapes will require a sound grasp of koala ecology; and local knowledge of koala movements, tree choice and associated threats to the continued survival of koalas, particularly roadkill from increased mining infrastructure. This requires a research-oriented approach to testing ideas applicable to the long-term survival of koala populations. Our recent koala research in NSW has shown that, in 2006, Gunnedah had the largest koala population west of the Great Dividing Range, and the only population in NSW that was expanding. That prompted us to instigate a detailed study in 2008 - 2011 to determine, inter alia, whether the koalas were using trees that were planted in the 1990s to cope with rising soil salinity. Our GPS-tracking has shown that regrowth trees as young as ten years old can attract koalas. In 2009, the demise of about a quarter of the local koala population from an intense heatwave gave us a foretaste of how habitat and climate change interrelate at the landscape scale. We are now examining the optimal combinations of tree choice, and patch size and shape, for habitat restoration. This will be relevant to local coal seam gas and coal mine proposals, and ongoing mitigation actions. The Senate enquiry of September 2011 on the koala and demonstrated the intense public interest in the survival of this iconic species. Its subsequent listing for Queensland and NSW under the Commonwealth Environmental Protection and Biodiversity Conservation Act 1999 further raises its profile and obligations for management of koalas and their habitat. It will take considerable effort to manage the Liverpool Plains koala population for the next 50 years in the face of extensive land-use changes from mining, and the attendant threats from road kill, compounded by the new threat of climate change manifesting itself as an increased frequency of heatwaves and more severe droughts. This paper describes the research that underpins these conclusions, identifies some of the research approaches needed, argues for working strategically now, rather than try to patch up matters after the event, and presents a set of guides for environmental plantings. CITATION:Lunney, D, Lemon, J, Crowther, M S, Stalenberg, E, Ross, K and Wheeler, R, 2012. An ecological approach to koala conservation in a mined landscape, in Proceedings Life-of-Mine 2012 , pp 343-352 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By F. Burat

The present research covers the results of experiments carried out with high frequency vibration screen on dewatering of coal fines. In the tests, the addition of surface active reagents was studied employing a high frequency vibrating screen. To increase the efficiency of mechanical dewatering processes, ultrasonic treatment was applied along with surfactants and optimum dewatering conditions were obtained. The moisture content of the feed material was from 82.5% to 41% by the optimization of operation parameters including the angle of the screen, vibration frequency, feed rate and screen opening size. Optimum parameters obtained in dewatering processes carried out with the vibrating screen were kept constant and the effects of surface active reagents and ultrasonic treatment on dewatering were investigated. Finally, the moisture level of the material was further reduced from 41.0% to 37.66%.

Sep 1, 2012

By Thomas A. Cook

The effectiveness of tensioned roof bolt systems has been well researched and documented over the years (Stankus, 1990, 1991, 1997; Guo, 1997; Denton, 2000; Su, 2007). Higher and more consistent installed tension has been shown to improve the beaming effect and associated roof stability especially in highly-stressed, weak, laminated roof strata. To accomplish higher and more consistent bolt-installed tensions, various types of anti-friction washers have been developed and applied to many types of tensioned roof bolt systems. In addition to increasing bolt-installed tension, these washers also provide a lubricating effect that minimizes sparking during the bolt torqueing cycle. The most popular and widely used anti-friction washer configuration consists of a plastic washer that is used in conjunction with a standard hardened steel washer. This washer configuration has performed well in the field in terms of increasing the bolt-installed tension (or plate load) and the related tension/torque ratio (the amount of tension achieved per one ft-lb of applied torque). However, the installed tension does not always maintain consistency. One reason for this inconsistency is that the plastic anti-friction washer sometimes dislodges and shreds or tears before the bolt torqueing cycle is complete. This condition prevents the plastic washer from acting as an anti-friction medium for the entire torqueing cycle. Jennmar Corporation and Keystone Mining Services, LLC, developed the ?TT? washer in early 2012. The ?TT? anti-friction washer is comprised of two zinc-coated (galvanized) hardened steel washers that are joined together with an exclusive polymer. The ?TT? washer has been extensively tested and applied in the Sewickley, Pittsburgh, and Indiana #5 coal seams. The test results indicate an average increase in installed load and tension/torque ratio of 20%. More importantly, the installed load consistency improved, with a significant reduction in the standard deviation of values. This paper will detail the development and testing of the ?TT? anti-friction washer with case studies of actual mine applications.

Jan 1, 2014

By A Atkins

Six recent case studies were selected based on the eight main causes of mine disasters (Table 1; Quinlan, 2014) and where credible information sources, such as Royal Commission Reports, Coronial Investigations and textbooks, were available. The six case studies are listed below. Details are available via this link or the conference PowerPoint accompanying this paper. 1. Beaconsfield, Tasmania – 2006 Fall of Ground/Seismic Event (Chandler, 2009; Melick, 2007; Wright, 2012). 2. Bingham Canyon, USA – 2013 Manefay Slide (Ross, 2017). 3. Bronzewing, WA – 2000 Hydraulic Fill Inrush (Hope, 2002). 4. Brumadinho and Samarco, Brazil – 2015 and 2019 Tailings Storage Facility (TSF) failures (Bowker, 2019; Darlington et al, 2019; Demajorovic, Lopes and Santiago, 2019; Morgenstern, 2016). 5. Northparkes, NSW – 1999 Cave Air-blast (Bailey, 2003; Hebblewhite, 2003). 6. Pike River, NZ – 2010 Methane Gas Explosion (Macfie, 2013; Panckhurst, Bell and Henry, 2012.

May 5, 2022

By J. Petersen, H. Naderi, M. H. Nikzad, M. Karimi

In this research, the thermodynamic study of sodium persulfate (Na2S2O8) solution in the presence and absence of H2SO4 and Fe3(SO4)3 was done. Eh-pH and equilibrium distribution diagrams were constructed using Outotec HSC Chemistry Software and the main stable ionic species were determined. Also, the mean activity coefficient and Pitzer model coefficients were evaluated. Effects of system composition, sodium persulfate concentration and temperature were investigated. According to the results, HS2O7 -, HS2O8 -, S5O3 2-, S4O3 2-, S3O3 2-, HS- and NaSO4 - are the main stable species in these three systems. Increasing of sodium persulfate concentration resulted in disappearing of SO4 2- and the appearance of NaSO4 -. The main effect of increasing the temperature from 25 to 75oC, is changing the stability regions of HS2O7 -, NaSO4 -, SO4 2- and S2-. From equilibrium studies, it was concluded that at 25 and 50oC, increasing the persulfate concentration results in a 55-60% decrease for HS2O7 - and an 20- 30% increase for HS2O8 -. At 75oC, HS2O8 - becomes the main species and its percentage decreases with increasing the persulfate concentration. Keywords: Thermodynamic, sodium persulfate, activity coefficient

Jan 1, 2020