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By Kim Chan, Bryn Thomas, Ben Dening

"Increased rail capacity is required into Kooragang Coal Terminal near Newcastle, NSW, Australia to relieve rail traffic congestion and improve management of train arrivals. An additional arrivals track is proposed on new embankment within a heavily constrained site located between existing railway tracks, a high pressure gas pipeline located 7m beyond the toe of the embankment and an environmentally sensitive wetland area. Ground conditions at the site consist of deep soft estuarine clays, a soil profile which is consistently encountered throughout this part of the east coast of Australia. Upon determining that a ground improvement solution was required to ensure global embankment stability, various solutions were considered including a piled viaduct, retaining walls, dry deep soil mix (DSM) columns and concrete injected columns (CICs). DSM columns were adopted as the design solution, a decision which was driven by the presence of sensitive infrastructure and a confined site. DSM offered further advantages including reduced impacts on temporary working platform design, where the use of a thinner platform could be justified owing to the lower track loads of a DSM rig relative to other ground improvement techniques.INTRODUCTIONThis paper presents a case study of the design of DSM ground improvement works to provide support for and enable safe construction of a new railway embankment over deep soft soils with a number of nearby infrastructure and other constraints. The project site is approximately 1km long and is constrained by existing railway tracks, a high pressure gas pipeline and a wetland area of ecological significance. Due to the site constraints and ground conditions, a number of ground improvement techniques were considered during the design process, with DSM columns eventually adopted. This paper discusses the design development and the particular suitability of the technique for use in this application.SITE DESCRIPTIONLandformThe site is located along the northern boundary of the Kooragang Coal Terminal (KCT) at Kooragang Island (KI), a collection of former islands located near the mouth of the Hunter River, north of Newcastle, NSW. The topography of the original area was generally flat with mudflats, swamps and mangroves existing along tidal water courses. Subsequent dredged fill reclamation and development has amalgamated the previous islands into the current KI. The site area extends over numerous channel infills including the buried former course of the Moschetto Channel (paleochannel).Figure 1 shows the proposed 1km long new rail corridor construction area in relation to the various natural and man-made site constraints including existing tracks, the high pressure gas pipeline, the wetland area and the existing reclaimed area."

Jan 1, 2015

By Henrique Hipolito, Caio Alves

Waelz process is a method applied in the zinc oxide production and is one of the largest sources of carbon emissions within the zinc industry. The solid carbon used for heating and for reduction reactions is provided mainly by the coke fed with the EAFD in the Waelz kiln. Both chemical composition and physical properties of the coke are important to transportation and to the process. Decarbonizing the Waelz process by replacing the traditional fuel source using alternative biogenic fuel, for example, offers a potential solution to reduce the carbon footprint, which is aligned with the ESG perspective.

Sep 29, 2023

By K. van Warmerdam, M. Pearson, C. Kember, D. McMullen, M. Thayer, C. Ugarenko

In July 2012, Hatch Ltd. and Air Products & Chemicals Inc. completed construction and commissioning of a 4000 tpd O2 cryogenic air separation unit (ASU) for Barrick Gold’s Pueblo Viejo Project located in central Dominican Republic. The ASU produces high pressure gaseous oxygen, which is used for the oxidation of refractory sulphide ore within the pressure oxidation (POX) circuit. As a result of the project’s remote location and tropical climate, many challenges were faced over the course of construction, commissioning and start-up of the ASU. These challenges included adequate preservation of equipment due to dusty and humid site conditions, final assembly and erection of the cryogenic distillation columns on site, limited spare parts inventory/availability, and an unfinished power source for plant commissioning. This paper discusses the steps taken by Hatch and Air Products to successfully design, construct, commission and start up the largest stand-alone ASU plant for a POX application in the metallurgical industry.

Jan 1, 2014

By M. H. Waxman, M. Gondouin, H. J. Hill

Streaming-potential experiments were conducted within the Muddy- and Dakota-sandstone interval of a Denver basin well. Analysis of the data shows that, for this case, streaming potentials opposite sands were higher than those opposite shales when the mud was fresh. Streaming potentials opposite shales, however, were of sufficient magniiIlde to be important in SP interpretation. They were linearly dependent upon pressure differential, and they increased with mud filtrate resistivity. The magnitude of streaming potentials opposite sands was influenced by the characteristics of the original mud cake formed at the time of drilling. Use of mud samples taken at the time of logging may not always be satisfactory for determining streaming-potential corrections. Both the streaming and electrochemical potentials were found to be affected by the previous history of the borehole system. Following a change in mud characteristics, several days were required for SP stabilization. This was, in part, due to the mud cake acting as an imperfect shale membrane. INTRODUCTION Laboratory investigations by Wyllie,1 Salisch,2 Moore," Sen Gupta and Bannerjee,0 and Hill and Anderson' have shown that streaming potentials developed across mud cakes deposited on permeable filter beds are of sufficient magnitude to be critically important in SP interpretation. Streaming potentials across shales have been reported by Schenck,' Gondouin and Scala; and Hill and Anderson." The magnitude of the shale streaming potentials obtained by Schenck and by Gondouin et a1 led these authors to conclude that in many cases the shale streaming potential would approximately equal the mud-cake streaming potential. Hill and Anderson, however, obtained somewhat lower magnitudes of shale streaming potential. The field experiment described in the present paper was a cooperative project carried out by the respective operations and research departments of Schlumberger Well Surveying Corp., Shell Development Co. and Shell Oil Co. The primary objective of the experiment was to determine in the borehole the streaming-potential behavior of both shales and mud cakes under conditions approaching, as nearly as possible, those normally encountered in logging practice. METHODS AND EQUIPMENT WELL A Muddy- and Dakota-sandstone vie11 in the Denver basin was chosen for the experiment. Both sandstones were water-bearing and, since reservoir pressures in these sandstones are abnormally low (gradient of approximately 0.25 psi/ft), it was expected that studies of streaming potential could be conducted from low-pressure differentials (approximately 200 psi) to about 27000 psi by bailing mud from the hole, filling up and then applying wellhead pressure. The selected well encountered the Muddy sand-

By V. E. Dementyev

This paper presents a brief overview of some IRGIREDMET advances in gold hydrometallurgy. Original impulse-percolation technology and equipment for intensive cyanidation of gravity concentrates have been developed and introduced into industrial practice by IRGIREDMET since 1980s (RF Patents N1593250). The process is based on leaching using special hydrodynamic and reagent conditions providing high dissolution rate for coarse gold particles. Gold and silver are precipitated from pregnant solution by cementation or electrowinning. There was also proposed an im-proved cementation method using zinc in a contact with electrically conductive material. The units including closed water recirculation, tails detoxification and semi-dry tails IRGIREDMET is well experienced in gold adsorption technology using ion exchange resins and activated carbons. The comparison of CIL and RIL processes were done for a number of gold mines, for example for Sukhoi Log gold deposit. The properties of prospective foreign and domestic ad-sorbents including strong-base, bi-functional and weak-base resins as well as activated carbons were studied. The Institute has developed some adsorption/elution technologies and equipment, such as a two stage RIP adsorption technology for gold/silver ores, an improved technology for gold elution from loaded resin and carbon, electrowinning cells for gold recovery from RIP and CIP eluates etc. Large scale ?Resin In Pulp? tests using weak-base resin were finalized and process design criteria were developed. Gold plant design is on progress at the moment. Improved technology for carbonaceous (preg-robbing) gold ores was developed. It was tested for some gold deposits including Sukhoi Log. It allows to overcome preg-robbing activities of ores treated and to improve dramatically performance of cyanidation and adsorption circuits. The studies on refractory gold ore treatment including bio-oxidation, pressure oxidation, roasting and ultra-fine grinding were conducted. Heap leach technology was tested and introduced by Irgiredmet for a number of Russian mines. Zinc cementation, activated carbon and ion-exchange resin adsorption were used for gold recovery from pregnant heap leach solutions. The options including combined technology ?Heap leach/ RIL or CIP? for clay ores were also developed and tested. The plant using developed technology is at construction stage now. The study on In-Situ gold leaching was conducted. The comparison of different gold lixiviants for this purpose was carried out. Gold recovery from pregnant leach solution by activated carbon and anionite including gold elution from loaded adsorbents etc. was also studied. In 2000 the In-Situ leaching technology was commissioned at Maminskoye gold deposit (Ural). The technologies for treatment of complex ores and by-products were proposed. For example, the technology of gold, silver, copper and zinc recovery from calcines after sulphuric acid production was developed.

Jan 1, 2014

Palabora Mining Company (PMC) processes a multi-component ore body using a circuit consisting of two AG mills in parallel, closed with vibrating double deck screens and hydrocyclones. The bottom screen undersize feeds the hydrocyclones, but the screen oversize products can be treated in a variety of ways. The top deck screen pebbles can be crushed and then combined with the bottom deck oversize and recycled to the AG mill. Alternatively both the top and bottom deck screen oversize can by-pass the recycle crusher and be recycled directly to the mill. A full tap-off is a configuration when both the top and bottom deck screen oversize streams are stockpiled. The other configuration is when the bottom deck screen oversize is recycled to the mill while the top deck screen oversize is stockpiled - termed partial tap-off. This article reports the findings from the surveys performed to evaluate the performance of the PMC auto mill circuit when operated under the four different configurations discussed. Ore characterisation tests were performed to assess the deportment of the key ore components for the different configuration.

Jan 1, 2012

By Rodrigo Camargos Barroso

Os fenômenos de solidificação no lingotamento contínuo são altamente dependentes da velocidade de lingotamento e das condições de extração de calor do molde. Por sua vez, equipamentos como os agitadores eletromagnéticos, alteram significativamente o escoamento na região do molde, influenciando o perfil térmico e ajudando na redução do calor de superheat. Simular simultaneamente o escoamento, o transporte de energia e a solidificação é um dos objetivos deste trabalho. O modelo emprega o software Ansys/Fluent e é aplicado ao lingotamento contínuo de moldes redondos. Como resultado, obteve-se os mapas de temperatura e a espessura de casca na saída do molde para diferentes velocidades de lingotamento e correntes de agitação. Experimentos realizados em planta buscam comprovar as previsões do modelo. Espera-se, por fim, criar um padrão operacional no lingotamento contínuo buscando otimizar o uso do agitador eletromagnético em função da velocidade de lingotamento e da temperatura de superheat.

Jul 30, 2018

By P A. Kirsch, A Hine

Mining is a major global industry that requires the moving of considerable volumes of earth and rock (overburden) to win the valuable ore prior to mineral extraction and processing. As a result of this process, new landscapes are created, both extracted voids and overburden piles, as well as infrastructure for management of mine operations, wastewater, tailings, other raw materials, transportation and extreme rainfall events. Resource companies must develop and obtain regulatory approval for detailed plans that manage this displaced material through all phases of the life-of-mine and rehabilitate the site at the time of closure (including landform stability, revegetation and ongoing management).Individual mine sites operate in long time frames (ten to 50 years), with several mines often operating in the same region, generating cumulative overburden volumes and heavily altering the original landscape. These impacts are universally framed as a negative consequence of the industry, especially by modern society that values natural (and some agricultural) landscapes as pristine and almost sacred. Overburden and tailings are also seen as a problem, and are a significant business cost to mining practice.This paper looks to investigate perceptions of mining and post-mining landscapes, questioning the aesthetically driven emphasis on the ‘natural’. It proposes instead an opportunity to reframe the way we look at overburden and landscape impacts from mining, exploring the possibility of imagined post-mine landscapes unburdened by traditional aesthetic expectations. These landscapes, to be conceived by regional stakeholder roundtables, have the capacity to be built by regional mining consortia as a foundation for sustainable post-mining economies.Post-mine regeneration offers both the motivation and the basic materials to create an altogether new environment from a blank slate. Few circumstances allow the opportunity to truly explore a re-envisioning of the land on a huge scale, and the possibilities merit serious consideration.CITATION:Hine, A?and Kirsch, P?A, 2014. Dreams of futures past – curating post-mining landscapes, in Proceedings Life-of-Mine 2014 , pp 121–138 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

By F Ouchterlony

Soviet precursors to Cunningham’s Kuz-Ram model from 1983 are described. They are rooted in the mean fragment size and Rosin-Rammler (RR) fits to sieving data and rely on approximations. Three versions of the Kuz-Ram model are presented and all three are de facto based on the median fragment size x50, even if the term mean is used in the papers. This discrepancy caused Spathis in 2004 to suggest a correction procedure for the Kuz-Ram rock factor A, which was said to explain some of the missing fines in the model. This correction, while applicable to Cunningham’s 1983 paper, does not apply to his 1987 paper, in which he presents his own A factor.Common fixes of the Kuz-Ram model’s fines issue are fragmentation models where the fines are mainly generated in a crushed zone around a blasthole. This is contradicted by careful model blasting tests. The lack of a largest block size in the RR function may lead to spurious values of the uniformity coefficient n, eg in conjunction with image-based fragmentation measurements or crusher modelling. These issues may be solved by using the transformed RR function, which has a largest block size xmax or its replacement by the Swebrec function, such as in the KCO model.The mean to median issue is investigated in some detail and it is found that using x50 instead of the mean:has a sounder theoretical backgroundis less prone to errorsis not contradicted by the original Soviet data.It is finally suggested that future work on fragmentation prediction equations focus on the use of distribution independent quantities like percentiles, eg x50, x20 and x80. Some previous work in this direction is briefly analysed and one consequence is that the n-value of the Kuz-Ram model should depend on specific charge.CITATION:Ouchterlony, F, 2015. The median versus the mean fragment size and other issues with the Kuz-Ram model, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 109–120 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By D G. Rantucci

Organic carbon is a major ore contaminant at MMG’s Century mine. This carbonaceous matter is associated with shale hosted sphalerite mineralisation. It occurs as elongated lamellae and as inclusions in porous sphalerite aggregates which are fine grained and difficult to liberate from sphalerite. The carbon prefloat circuit was designed to remove the liberated organic carbon in order to mitigate excessive reagent consumption, contamination of the lead and zinc concentrates and poor flotation performance in the primary zinc circuit. The consequence of organic carbon removal is that sphalerite and galena minerals are lost to the prefloat concentrate. A Jameson Cell was installed in late 2005 as a prefloat cleaner cell. Operational experience showed that the cell became capacity limited during periods of high amounts of organic carbon in the feed and was subsequently bypassed.Reactive style operating strategies were implemented to manage the effects of insufficient organic carbon removal by the prefloat circuit but due to the relatively large circuit residence time, upstream changes meant hours before the downstream circuits were stabilised following a disturbance from excess carbon.This paper describes the modifications and testwork undertaken to enable the Jameson Cell to be operated during periods of high organic carbon in the float feed and the implementation of process control initiatives to proactively remove the required prefloat mass from the float feed to eliminate the reactive style operating strategy.The process control modifications centred on dynamically targeting a prefloat mass recovery determined by an equation relating the carbon to zinc ratio to the carbon prefloat mass as a percentage of the float feed. The equation was developed by analysing historical data. These improvements served to optimise the prefloat circuit and consequently stabilise the downstream lead and zinc circuits.

Aug 8, 2011

By T Huynh, K Tungpalan, E Wightman, M Edraki, S Palaniandy

Most preventive environmental management practices promote proactive integrated approaches to waste management. For example, life cycle assessment is often used to find the ‘hot spots’ of environmental burdens. This kind of approach is often based on generic data and has rarely been used for tailings. Besides, life cycle assessments are less useful for designing operations or simulating changes in the process and consequent environmental outcomes. It is evident that an integrated approach for tailings research linked to better processing options is needed.The aim of this Nextmine™ project is to develop new tailings management models by streamlining orebody characterisation, process optimisation and rehabilitation. We present an integrated tailings management approach and preliminary results from a case study. Combined grinding and flotation models were developed using geometallurgical data from the orebody, to predict the properties of tailings produced under various processing conditions. The modelling scenarios based on the case study data provide the capacity to predict the composition of tailings and the resulting environmental management implications. For example, the type and content of clay minerals in tailings will affect the geotechnical stability and water recovery. Clay content will also influence decisions made for paste or thickened tailings and underground backfilling.CITATION:Edraki, M, Huynh, T, Wightman, E, Tungpalan, K and Palaniandy, S, 2015. An integrated approach to proactive tailings management, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 323–332 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By Ray Nivens, Umit Turunc, Caroline Sui, Nick Morrison, Douglas Steiner

"In most copper mines and concentrators, mill water is continuously recovered and reused, with fresh water added to make up for losses. When mixed, these water chemistries can lead to severe scaling, especially in pipes, tanks and pumps on the mill water supply side, reducing flows and causing significant production losses.At KGHM Robinson Nevada Mining Company, increases in the fresh water addition ratios resulted in severe scaling problems and premature pump failures thereby jeopardizing plant production. What initially appeared to be a few isolated scaling events eventually unfolded into a recurring pattern of water supply-related production losses with increasing severity. Through completion of detailed root cause analysis, chemistry modeling, laboratory work, in-plant testing and system engineering, the mechanisms of scaling were identified and addressed.Advancements in fresh water addition practices and antiscalant application methods resulted in a stepwise reduction of the mill water scaling. Cost savings and production benefits were significant to the plant’s financial metrics.IntroductionThe production of mineral and metal concentrates using the flotation process requires large quantities of water. Flotation is utilized as the primary means for beneficiation with sulfide ores. Mined ores are crushed and ground into a slurry of 20-55% solids. For each ton of ore, 400-900 gallons of water1 are needed to supply the grinding mill. Additional water is needed in the flotation circuit as well. With many modern mills operating at2 11,000-165,000 tons/day, water supply volumes can be upwards of 3,000 gpm to 100,000 gpm of flow.For plants operating at or above capacity, disruptions and restrictions in water supply flow can have a direct impact on the production and recovery of the metal. Water supply flow can be limited for a wide variety of reasons but of interest are those limitations that are due to mineral scaling. Mineral scaling is the selective point precipitation of inorganic species above saturation concentrations. Precipitated species form flow-restricting deposits in the mill water system (tanks, pumps, pipe and valves), that will eventually impact water supply to the concentrator."

Jan 1, 2017

By Karin Bäppler

Mechanized tunnelling is undoubtedly one of the most innovative disciplines in the international construction industry. Technological progress in the planning and production of most modern infrastructure is constantly striving for new records on basis of highly specialized solutions and know-how. Humans and technology have accomplished excellent achievements over the past few years in varied, difficult terrain. New length records are being set with the 64 km long Brenner Base Tunnel and the HS2 Railway system currently under construction in Europe. Cities are building ever longer and more demanding sewer tunnels. The paper highlights some of the challenges, trends and innovations of long-distance tunnelling projects.

Dec 1, 2022

By Andrew Palangio, Blessing Taiwo

Understanding rock mass structural features is essential for optimizing blast design, highwall control, and evaluating post-blast performance in both surface and underground mining operations. This paper presents a comprehensive methodology utilizing image-based structural mapping to accurately characterize geological discontinuities including joints, faults, and lineations captured from both terrestrial and aerial imagery at varying scales. Key structural parameters such as joint orientation, spacing, and apparent in-situ block size are extracted to understand rock mass classification and enhance blast design inputs with greater geotechnical precision. The study introduces a significant enhancement to the existing discontinuity assessment algorithm by integrating a deep learning-assisted detection process. This improvement enables more accurate, quantitative and consistent identification of pre-existing cracks and surface features across complex bench free faces. The enhanced system facilitates better evaluation of how structural features influence blast fragmentation, energy distribution, and slope stability. A case study from a limestone quarry illustrates the use of a derived comminution factor based on the relationship between joint-controlled pre-blast block sizes and post-blast fragmentation to evaluate blast performance and optimize future design strategies. The results highlight the value of structural analysis in reducing overbreak, minimizing underbreak, and improving fragmentation predictability. This paper emphasizes the importance of integrating structural assessments into the blasting workflow to enable a more data-driven, geotechnically informed, and performance-optimized approach to modern blast design and evaluation.

Jan 26, 2026

By L. S. Darken

Measurements of the electrical conductivity, the thermal electromotive force, and the deviation from stoichiometry by thermogravimetry were made on ferrous oxide (wüstite) single crystals as well as on poly-crystalline samples in the temperature range of -900" to 1330°C. In the region defined by T 2 1000°C and 1.05 5 O/Fe 5 1.10 the electrical conductivity was shown to be proportional to the sixth root of- the oxygen partial pressure and to be linearly dependent on the deviation from stoichiometry. The absolute Seebeck coefficient of single and polycrystalline wüstite was shown to be independent of temperature in the above region and a p to n transition of the Seebeck coefficient was observed at O/Fe = 1.09 in polycrystalline wüstite. Analysis of the results showed that the predominant defects in wüstite in the above region were doubly ionized cation vacancies. The analysis also ruled out the existence of complexes of the type postulated by Roth, except that below 1000°C there is some evidence of 'association of defects. Of the three oxides of iron (FeO, Fe3O4, Fe2O3) only FeO (wüstite) can exist within a wide range of the ratio O/Fe. This has been shown by several investigations of the phase diagram using for instance chemical analysis of quenched samples'-4 or thermogravimetric measurements. 5,8 Darken and Gurry's1 data for example in the temper- ature range 1100o to 1400°C show that the lowest O/Fe ratio obtainable for FeOl +. is about 1.045 and that the existence range extends to O/Fe = 1.20 at 1400oC. On the basis of detailed analysis of thermogravimetric measurements made by Vallet and Raccah6 the existence of three varieties of wüstite at elevated temperatures was suggested by these authors and by Kleman. It is well-established that wüstite has a NaCl structure with vacant cation sites.3, 8 From a neutron-diffraction study of wüstite samples quenched to room temperature Roth9 concluded that defects in wüstite are mostly complexes composed of two cation vacancies and one interstitial cation in a tetrahedral site. The atomic arrangement in the vicinity of such a defect is similar to that in magnetite, where each occupied tetrahedral site is surrounded by four vacant octahedral positions disposed at the corners of a tetrahedron, so arranged that each vacancy is shared by two tetrahedral cations. Thus there is an average of two vacancies per interstitial. Recent X-ray diffraction measurements made by Smuts10 on quenched wüstite samples confirmed the results of Roth's neutron-diffraction experiments. Roth's model of defects in FeO can be regarded as a solid solution of Fe3O4 in FeO; salmon1' used this defect model to calculate the activity of Fe3O1 in FeO at high temperature and claimed good agreement with the results obtained experimentally by Darken and Gurry.' Each missing cation in wüstite is accompanied by two trivalent cations, thus preserving charge neutrality. The "holes" which differentiate between the Fe 2+ and Fe3' states of the ions in octahedral positions can overcome the attractive field of the cation vacancies, and are then free to move through the crystal as charge carriers. A similar picture holds for COO, NiO, andMnO.l2, 13 Localization of the charge carriers in transition

Jan 1, 1968

By D. T. Peters

To better understand the Co-Mo interaction in maraging steels, the precipitate reversion behavior of two alloys closely related to the 18 Ni-250 grade has been studied. The reversion experiment is carried out by aging at a low temperature, T1 (preaging temperature), for some period of time and then aging at a higher temperature, T2, called the reversion tetnperature. Aging and reversion tmzperatures used were in the range 679 to 1050°F. Reversion is marked by an increase in resistivity and a decrease in hardness. It teas found that some reversion took place at all cornbinations of T1 and T2 but that pronounced rei3ersion resulfed for an Fe-18 pct Ni-5 pct Mo-8 pcl Co alloy exposed to preagz'ng' temperatures at or below 850°F. A similar alloy not containing cobalt exhibited no such discontinuity in reversion behazior with TI. The results are interpreted in terms of two types of molybdenum-rich precipitates, one nucleated at dislocations and the other in the matrix. The increased supersaturation resulting from the presence oj- cobalt evidently provides sufficient energy to nucleate the matrix phase. Anotnalies in the temperature dependence of the resistivity decrease and peak hurdness in the Fe-18 pct Ni-5 pct Mo-8 pct Co alloy as a junction of aging temperature noted in an earlier study are explained on this basis. SEVERAL investigatorsl-9 have studied the details of the precipitation-hardening reaction of the maraging steels. The great majority of conclusions have been drawn from transmission electron microscopy. Although much has been learned by this method, alternate techniques which will give information earlier in the aging process are needed for a more complete understanding of the series of precipitation steps probably involved in the aging reaction. Peters and cupp'' have recently shown, by measurements of the kinetics of precipitation, that an 18 pct Ni-Co-Mo maraging steel shows a distinct change in precipitation behavior at aging temperatures below 850°F. The results were interpreted in terms of the existence of two types of precipitates at low aging temperatures. Only one precipitate type is present at higher aging temperatures. The low-temperature precipitate was found to be a particularly effective strengthener. No evidence for the additional low-temperature precipitate was found in the 18 pct Ni-5 pct Mo ternary alloy. The object of this investigation was to study further the characteristics of the two types of precipitates and the interaction between cobalt and molybdenum characterizing this system. Some preliminary experiments indicated a difference in reversion behavior in specimens aged above and below 850°F. This suggested that knowledge of the reversion behavior might shed some light on these two questions. Hardy and Heal11 have defined reversion as the loss of hardness, electrical conductivity, or other properties caused by heating for a very short time at temperatures above the aging temperature. The precipitate reversion referred to in this paper is entirely distinct from "austenite reversion" often referred to in maraging steel literature. This latter phenomenon could more accurately be called the diffusion-controlled formation of austenite. Much has been written about reversion in several of the aluminum-base binary and ternary alloys.'2-16 Two explanations for reversion have been advanced. Based on the classical nucleation theory of Volmer-Weber-Becker-Doring,17 Konobeevski18 suggested that reversion was due to the size of the precipitate particles

Jan 1, 1968

By E. Bane Kroeger

For many years, researchers around the world have been investigating coal pillar stability. Many have focused on trying to optimize the size of the pillars by examining stable and failed pillars in underground coal mines. For mines that are already in operation or companies that are opening a new mine adjacent to an existing mine where the pillar dimensions and stability can easily be determined, this is the preferred technique. However, when a new mine is planned for an area where there has been relatively little mining, then samples of the coal need to be drilled and tested for strength. Because of the fractured nature of coal, this lab testing is often problematic and may often yield poor results because of the limited size and number of samples that can be obtained from the core. To remedy this problem, research was conducted in the labs at SIUC to determine if improvements could be made when optimizing the size of pillars for underground coal mining in Illinois. Through a greater understanding of the relationship between dimensions and strengths of coal samples tested in the lab, it was hoped the in situ strength of coal pillars could be determined with greater accuracy. This could allow the extraction ratio to be increased and more of the coal resources in Illinois recovered without impacting the safety of the mine workers. Many different agencies around the world have published recommended minimum numbers of samples for strength determination based on the size of the coal samples. For two inch cubes, uniaxial testing of at least seven samples is recommended and this minimum number decreases to four when testing four inch cubes. However, the laboratory testing of coal from two seams thus far has suggested this number should be almost doubled to accurately determine the coal strength. Testing also showed there is a pronounced decrease in the variation in the strength of the samples tested as the dimensions of the sample were increased. From the testing results thus far, it is recommended that a sample size versus strength curve be constructed for every coal seam for Illinois. Creating such a curve will better determine both the minimum number of samples and minimum sample dimensions for that seam or region of a particular scam. A second set of tests were conducted in the laboratory to determine the increase in strength with reduction in height for samples with the same width and length. In Illinois, typical pillar dimensions are 40 to 80 feet (12.2 to 24.4 m) wide and long, with coal thickness varying from about 4 to 9 feet (1.22 to 2.74 m). This provides width/height ratios ranging from 4.5 to 17.5. Coal samples having width/height ratios ranging from 0.5 to 13 have been tested thus far. As with most pillar design formulae, the strength of the Murphysboro coal versus width/height ratio was linear and closely matched shape factors published by other researchers. The laboratory testing thus far has identified three factors that affect the strength of laboratory samples, the number of discontinuities, the angles of critical discontinuities, and the shape of the samples. The factor that probably had the most pronounced effect on the strength of the coal samples was the angle of critical discontinuities. This testing has confirmed that there is still a gap that needs to be bridged between the strength obtained from laboratory testing and the in situ coal strength predicted.

Jan 1, 2004

By A. Steiner, E. Miller, K. L. Komarek

Equations have been derived to calculate the chemical potentials of the components of liquid binary alloys from liquidus and enthalpy data. The equations are applicable to systems with intermetal-lic compounds of limited solid solubility. The liquidus curve of the Mg-Sn system was accurately redetermined, and the melting point of the compound Mg2Sn was found to be 770.5° * 0.3°C. The thermo-dynamic properties of the liquid alloys were calcu -lated from the liquidus data. The activity of tin shows both positive and negative deviations from Raoult&apos;s law and the relative integral entropy is positive. THE phase boundaries in an equilibrium phase diagram are functions of the thermodynamic properties of the coexisting phases. Specifically, the shape of the liquidus curve near an intermediate compound is determined by the properties of the compound and the liquid phase. Hauffe and wagnerl have derived an equation for the chemical potential differences (ui) of the liquid alloys near the congruent melting point when the heat of fusion of the compound and the liquidus curve are known. In their derivation the temperature dependence of the ui value was neglected, and liquid of stoichio-metric composition was chosen as the reference state. To obtain chemical potentials over the ntire composition range of the phase diagram with the pure components as the reference state, equations have been derived which incorporate the temperature dependence of the chemical potentials. Such a thermodynamic analysis can be carried out when the liquidus curve and the enthalpy values are known. The equations have been applied to the redetermined liquidus curve of the Mg-Sn system to obtain the thermodynamic properties of liquid Mg-Sn alloys. The Mg-Sn phase diagram has been studied by various investigators and the results have been compiled and critically assessed by Hansen.2 Preliminary thermal analyses showed that the basic features of the diagram were correct. The system has one congruent melting compound, Mg2Sn, two eutectics, and some solid solubility of tin in magnesium. However, the published liquidus temperatures show considerable scatter. In order to perform an accurate thermodynamic analysis, the liquidus curve between the magnesium-rich and tin-rich eutectic compositions was therefore redetermined by careful thermal analysis using highest-purity starting materials. EXPERIMENTAL PROCEDURE The magnesium metal (Dominion Magnesium Ltd, Toronto, Canada) had a purity of 99.99+ pct with the following impurities (in ppm): 20 Al, 30 Zn, 10 Si, <1 Ni, <1 Cu, <10 Fe; tin (Cominco Products, Spokane, Wash.) contained 99.999+ pct Sn. The graphite crucibles were machined from graphite rods (United Carbon Products Corp., Bay City, Mich.) which had an average total ash content of less than 30 ppm. All the graphite parts were baked out in vacuum at 950" to 1000°C for a minimum of 24 hr to remove volatile organic materials. The graphite crucibles (3 in. long, 1-5/8 in. OD, 1-3/8 in. ID) were tightly closed with a threaded cover (1/2 in. thick) which had a central thermocouple well (2-1/4 in. long, 5/16 in. OD, 3/16 in. ID). Cover and thermocouple well were machined from one piece of graphite. A thin sheath of quartz was inserted in the well to protect the thermocouple

Jan 1, 1964

By D. S. Tannhauser, I. Bransky

Measurements of the electrical conductivity, the thermal electromotive force, and the deviation from stoichiometry by thermogravimetry were made on ferrous oxide (wüstite) single crystals as well as on poly-crystalline samples in the temperature range of -900" to 1330°C. In the region defined by T 2 1000°C and 1.05 5 O/Fe 5 1.10 the electrical conductivity was shown to be proportional to the sixth root of- the oxygen partial pressure and to be linearly dependent on the deviation from stoichiometry. The absolute Seebeck coefficient of single and polycrystalline wüstite was shown to be independent of temperature in the above region and a p to n transition of the Seebeck coefficient was observed at O/Fe = 1.09 in polycrystalline wüstite. Analysis of the results showed that the predominant defects in wüstite in the above region were doubly ionized cation vacancies. The analysis also ruled out the existence of complexes of the type postulated by Roth, except that below 1000°C there is some evidence of &apos;association of defects. Of the three oxides of iron (FeO, Fe3O4, Fe2O3) only FeO (wüstite) can exist within a wide range of the ratio O/Fe. This has been shown by several investigations of the phase diagram using for instance chemical analysis of quenched samples&apos;-4 or thermogravimetric measurements. 5,8 Darken and Gurry&apos;s1 data for example in the temper- ature range 1100o to 1400°C show that the lowest O/Fe ratio obtainable for FeOl +. is about 1.045 and that the existence range extends to O/Fe = 1.20 at 1400oC. On the basis of detailed analysis of thermogravimetric measurements made by Vallet and Raccah6 the existence of three varieties of wüstite at elevated temperatures was suggested by these authors and by Kleman. It is well-established that wüstite has a NaCl structure with vacant cation sites.3, 8 From a neutron-diffraction study of wüstite samples quenched to room temperature Roth9 concluded that defects in wüstite are mostly complexes composed of two cation vacancies and one interstitial cation in a tetrahedral site. The atomic arrangement in the vicinity of such a defect is similar to that in magnetite, where each occupied tetrahedral site is surrounded by four vacant octahedral positions disposed at the corners of a tetrahedron, so arranged that each vacancy is shared by two tetrahedral cations. Thus there is an average of two vacancies per interstitial. Recent X-ray diffraction measurements made by Smuts10 on quenched wüstite samples confirmed the results of Roth&apos;s neutron-diffraction experiments. Roth&apos;s model of defects in FeO can be regarded as a solid solution of Fe3O4 in FeO; salmon1&apos; used this defect model to calculate the activity of Fe3O1 in FeO at high temperature and claimed good agreement with the results obtained experimentally by Darken and Gurry.&apos; Each missing cation in wüstite is accompanied by two trivalent cations, thus preserving charge neutrality. The "holes" which differentiate between the Fe 2+ and Fe3&apos; states of the ions in octahedral positions can overcome the attractive field of the cation vacancies, and are then free to move through the crystal as charge carriers. A similar picture holds for COO, NiO, andMnO.l2, 13 Localization of the charge carriers in transition

Jan 1, 1968

By M Watson, A V. Engelbrecht, E Murray-Hayden

Whereas mine reconciliation is a well-established month-end process for most modern mining operations, the resource sector has yet to endorse uniform reporting factors against which model accuracy and metal recovery can be formally assessed. Logically, any comprehensive reconciliation framework should facilitate comparison between period reserve, mine and mill and production figures. Historically, Parker’s F Series ratios (Parker, 2012) are often used in some form by mine operators, although they are rarely shared externally, as formal definitions have yet to be accepted. This paper presents a structural extension to the reconciliation process, wherein resource ratios (R Series factors) are used to quantify the long-term impact of the information effect, together with dilution and ore loss. A case study from the El Limón Guajes (ELG) Mine Complex in Mexico is used to demonstrate how an R Factor Series can be implemented to facilitate operation optimisation, over and above conventional F Series reconciliation treatments. This approach is applicable to any mining operation.

Mar 22, 2022