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By G. Roderick Eggert

Material criticality reflects the degree to which a raw material is both necessary and subject to supply-chain risks. This study compares the criticality of selected raw materials from the differing perspectives of the manufacturing sectors of China, the European Union, Japan and the United States.

By A. U. Seybolt

The solubility of oxygen in a iron has been determined in the range between 700° and 900°C. The solubility is a function of temperature and varies from about 0.008 pct oxygen at 700°C to atureandabout 0.03 pct at 900°C. The heat of solution is approximately +15,500 cal per mol. AS pointed out in a recent paper by Kitchener et al.,1 there has been a lack of agreement among many investigators even as to the order of magnitude of the solid solubility of oxygen in the various forms of iron. This lack of agreement is attributable in large part to the difficulties in the determination of a small oxygen solubility; but because the problem has remained so long unsettled, it also indicates a lack of interest which is rather surprising when the demonstrated importance of small amounts of soluble nonmetallic impurities in iron is considered. The work of Kitchener et al. apparently leaves the solubility of oxygen in iron in a satisfactory state, but no attempt was made to investigate the solubility in a iron. The solubility of oxygen in a iron is actually of greater interest, since it is in this form that iron and mild steels are employed ordinarily. That the effect of oxygen in iron is of more than theoretical interest has been well established by Fast,' and more recently by Rees and Hopkins," who demonstrated that oxygen in the range between 0.0008 and 0.27 wt pct has a pronounced effect upon the mechanical properties. Previous Work and Methods Used To report in detail the literature relating to the solubility of oxygen in a iron would require an inordinate amount of space. For those interested in reviewing this work, a bibliography4-13 of the more significant papers is appended. In general, two methods of studying this problem have been used. One is the gas-metal equilibrium method where the H2O-H2-Fe or the CO2-CO-Fe equilibria have been used. The other is the more direct approach of the oxidation of thin strips of pure iron by packing in mill scale or by air or gaseous oxygen at some desired temperature. In this method oxygen is allowed to oxidize the surface and then to diffuse inward until saturation is obtained. In the gas-metal equilibrium method the oxygen dissolved in solid iron at a given temperature is proportional to the ratio of the water vapor-hydrogen pressures or the CO2-CO pressures over the sample for small ratio values. If the ratio becomes higher than a critical value, then an oxide phase makes its appearance (the solution becomes supersaturated). In principle, it is possible to use a series of H2O/H2 or CO2/CO ratios and to find by analysis the corresponding amounts of oxygen in solid solution at constant temperature. At the point where a very small increase in the gas ratio (increase in oxidizing powder) produces a large increase in oxygen content, the solid solubility limit is reached. Alternately, if the critical ratio is known, it is possible to use the procedure of Kitchener et al.1 and to use a ratio which is near but below the critical one. The solubility corresponding to this lower ratio will not be the saturation solubility at the temperature employed, but the saturation solubility can be calculated by multiplying the measured solubility by the critical ratio over the ratio used. However, in the case where oxygen gas is the oxidizing medium, the saturation solubility is not a function of pressure, providing the pressure exceeds the dissociation pressure of FeO in equilibrium with iron. This is 1.2x10-16 mm at 800 °C, according to Dushman." As pointed out by Darken17 in discussing the FeO phase diagram, most of the possible errors tend to yield high values of oxygen solubility. For example, one circumstance which evidently caused the reporting of many high values was the use of finely divided or powdered iron in the gas equilibrium method. Because of the large surface area of such a sample, and the likelihood of some surface contamination if only by exposure to air, the results tended to be high. The direct oxidation method which was used in this work has the advantage in that it is simple and direct, but it suffers from one disadvantage: equilibrium can only be approached from the low oxygen side. The important factors to be kept under control are the following: 1—use of high purity iron to avoid internal oxidation (oxidation of readily

Jan 1, 1955

By G. Guzman, L. Sevilla, M. Botz

"Newmont Mining Corporation operates the Yanacocha mine in Perú and the gold milling section of the property includes a Sulfidization-Acidification-Recycle-Thickening (SART) plant to remove copper from pregnant leach solution. Since its commissioning in 2008, the plant has been intermittently operated as needed to remove copper upstream of a carbon adsorption circuit. However, starting in 2015 Newmont expects the plant to operate on a more continuous basis in response to higher copper ores that will be processed in the gold mill. In anticipation of this, Newmont conducted a campaign in May 2014 with stockpiled high-copper ore to evaluate performance of the SART plant with elevated levels of copper in feed solution. Results from the campaign demonstrated the SART plant is capable of efficiently treating high-copper leach solution. During the campaign, leach solution copper levels ranged from about 100 to 700 mg/L, and copper removals ranging from about 56% to +99% were achieved. The median copper removal efficiency observed during the campaign was about 94%. The primary plant modification determined necessary following the campaign was the need to improve consistency with sulfide dosing. INTRODUCTION Copper removal from cyanide leach solution can be affected through the addition of sulfide at acidic pH to precipitate copper sulfide as a solid. There has been renewed interest in the process in the past several years due to the increasingly common issue of high copper levels in cyanide leach solutions. The term Sulfidization- Acidification-Recycle-Thickening (SART) is used as an acronym for the process according to the primary unit operations utilized. At a pH of approximately 4.0 to 5.0, the addition of soluble sulfide to a copper-bearing leach solution will result in the precipitation of copper sulfide (Cu2S) solid. The overall acidification and sulfidization reaction is (assuming the use of sulfuric acid for pH adjustment): 2Cu(CN)3-2 + 3H2SO4 + S-2 ? Cu2S(s) + 6HCN(aq) + 3SO4-2 The above reaction is written relative to the copper-cyanide complex 2Cu(CN)3-2, though analogous reactions also take place with the other common copper-cyanide complexes Cu(CN)2- and Cu(CN)4-3. Sulfide in the above reaction (S-2) is normally supplied as sodium hydrosulfide (NaHS) purchased in solid or concentrated liquid form. Two characteristics of this reaction that are beneficial to a leaching operation are: 1. Copper is removed from solution as Cu2S (synthetic chalcocite) solid, which can then be sold to a smelter for its copper value. 2. Cyanide that is complexed with copper in the leach solution is released as free cyanide, thereby regenerating cyanide that can be recycled to the leaching operation for continued use."

Jan 1, 2015

By Charles M. Packer, Oleg D. Sherby, Roy H. Johnson

Originally round tensile specimens of a eutectic Zn-A1 alloy develop elliptical cross sections during superplastic deformation. This observation, coupled with a detailed study of the microstructure and preferred orieniation, suggests that crystallographic slip and continuous grain boundary migration or re-crystallization are important processes during super-plastic deformation. In spite of the extensive activity in superplasticity1-15 and the numerous explanations proposed, no single model has had universal acceptance. It has been established, however, that the general requirements for superplastic extension of two-phase alloys include an extremely fine, stabilized grain size of the order of a few microns, a temperature about equal to or greater than one-half the melting point, a critical range of strain rate, and a similarity in the mechanical strength of the major phases. The proposed models can perhaps best be characterized in terms of the important phenomena associated with them. These phenomena include: phase instability,1 diffusional creep by volume diffusion3 or grain boundary diffusion4,5 slip and continuous grain boundary migration or recrystalliza-tion,= grain boundary Sliding,7-9,13,14 and dislocation glide.'5 In this paper, experimental observations will be reported which support a model involving slip and continuous grain boundary migration or recrystalliza-tion. Specifically, a correlation will be made between this model and the development of elliptical cross sections as originally round specimens are superplas-tically deformed. For the most part, superplasticity studies have been conducted with eutectic or eutectoid alloys. Probably the most thoroughly studied material has been the monotectoid Zn-A1 alloy.1,2,6,12,13,15 No attention to the eutectic Zn-A1 alloy has previously been reported, and the results discussed in this paper represent part of a general study of the superplastic properties of this alloy. MATERIALS The alloys used in this investigation were prepared by melting appropriate quantities of 99.99+ pct A1 and 99.999 pct Zn in air, mixing, and pouring into a water- cooled stainless-steel mold. Wet-chemical analysis was conducted with each heat of alloy prepared, using the procedure of Fish and smith.16 The composition of the eutectic alloy was 95.1 wt pct Zn. Ingots about 2 in. thick were rolled to 0.4-in. plate at about 300°C with a reduction of 5 to 10 pct per pass. Specimens were machined from the plate with the tensile axis parallel to the rolling direction. The specimens were round, with 0.150-in.-diam, 1.25-in.-long gage length, and 0.25-in.-diam threaded grip sections. EXPERIMENTAL PROCEDURE Specimens were mounted inside a uniform-temperature quartz tube which was surrounded by a double elliptical radiant furnace with a 12-in.-long uniform-temperature hot zone and a low thermal capacity. The tube extended through the top and bottom of the furnace and permitted rapid quenching of the loaded specimens when quickly filled with cold water at the conclusion of the test. The quench precluded any effects on specimen microstructure from a normal, slow cool. Constant stress was applied to test specimens by suspending a load on a constant stress cam of the type described by Hopkin.17 The design of this cam permitted application of a constant stress for elongations up to 200 pct. For greater elongation, approximately constant stress conditions were maintained by systematically reducing the load manually. RESULTS As part of an investigation of the superplastic properties of the eutectic Zn-A1 alloy, evidence was obtained for the development of elliptically shaped cross sections as originally round specimens were extended. For example, after an elongation of about 100 pct, a round specimen with an initial diameter of 0.150 in. became elliptical with major and minor axis of 0.128 and 0.88 in., respectively. Photographs are presented to illustrate the ellipticity developed during superplastic deformation, Fig. 1. The specimen shown was deformed at a stress of 500 psi, at a temperature of 285°C, and a strain rate of 2.28 x 10-2 min-1. The strain-rate sensitivity exponent* was measured at *The strain-rate sensitivity exponent, m, is defined as d In o/d In c where o is the steady-state flow stress and E is the strain rate. this temperature and in the strain rate range 10"3 to 10-1 min-1 was found to be about 0.5. This value is typical of those observed with superplastic materials. The material studied exhibited negligible strain hardening during superplastic deformation, the creep rate remaining constant under constant stress and temper-

Jan 1, 1969

By Nobuharu Isago, Atsushi Kusaka, Kosuke Kawata, Dohta Awaji

"The immediate ring closure method, in which the entire periphery of the excavation area is closed immediately with an initial support within a short distance from the excavation face, has been increasingly used in Japan, especially, as one of the most effective countermeasures against difficult ground conditions in conventional tunneling. For reasonable design of this method, the performance requirements for the initial support should be clearly stated. The analysis of construction data of 30 road tunnels and the three-dimensional numerical modeling based on real data suggest that the immediate ring closure stabilizes the tunnel structure and the ground around it because of the inner pressure effect of the initial support, especially, for low ground competence factor and small internal friction angle. Finally, the bending compressive strength and the cross-sectional geometry of the initial support have to be considered in the tunnel design while considering the earth pressure and ground properties. INTRODUCTION Conventional tunneling methods often deal with difficult ground conditions such as soft ground or squeezing ground conditions. The immediate ring closure method, in which the entire periphery of the excavation area is immediately supported within a short distance from the excavation face (Figure 1), has been increasingly used in Japan as one of the most effective countermeasures against difficult ground conditions in conventional tunneling (e.g. Takahashi et al., 2011; Nakaoka et al., 2013). The immediate ring closure method was empirically identified as effective for reducing ground surface subsidence and tunnel deformation. However, the working effects of the method have not been clarified sufficiently. To improve the design of this method, the working effects of this method and the performance requirements for the initial support need to be clarified. The relation between the effect of immediate ring closure and earth cover has been clarified (Mashimo et al., 2008; Awaji et al., 2013),"

Jan 1, 2016

By William D. Mayercheck

The introduction of continuous mining machines in the late 1940's prompted the mining industry to reassess shuttle car batch-type haulage. Between place changes, the continuous miner could cut and load coal on a nearly continuous basis, but after loading a shuttle car, the high-capacity machine had to wait until the second shuttle car came inby and spotted itself under the miner tail boom. Thus, the wait-for-shuttle-car delay periods became the new bottleneck for increased coal production from the mine section. Recent studies have shown that nearly 25 pct of the continuous miner cycle time is consumed by delays in the haulage system, usually waiting for shuttle cars. Computer simulations of a face operation indicate that up to a 45 pct increase in coal production may be realized through the use of a continuous haulage system, assuming of course that the outby haulage system can handle this increased capacity. Coincidently, there are recent claims by some mines using continuous face haulage of a production increase of 45 pct compared with shuttle car haulage. These documented production records, computer simulations, and common sense indicate the potential of continuous face haulage in underground coal. The late 1960's and early 1970's saw several mining machinery manufacturers market mobile bridge carrier and piggyback bridge conveyor continuous haulage systems for use in underground coal mines. These systems have shown limited potential in some mines and outstanding success in others. It appears that no one system can be universally applicable to all underground mining conditions; thus, the Bureau of Mines has conducted extensive research over the last few years to investigate different types of continuous haulage systems for use in high and low coal seams that will advance the state of the art.

Jan 1, 1977

By T. Acton

The Zarafshan/Newmont Joint Venture is currently operating in the Republic of Uzbekistan producing in excess of 400,000 oz. of gold per year from low grade oxide ore stockpiles adjacent to the Muruntau open pit gold mine located in the Kyzylkum desert of central Uzbekistan. Four stage crushing and screening produces a final product for heap leaching, Merrill-Crowe processing, and local refining for International market export. The Zarafshan/Newmont Joint Venture is the first major commercial project of its kind in the former Soviet Union to be successfully negotiated, engineered & constructed, and placed into continuous operation,

Jan 1, 1997

By J. R. Heberger

"“Safety Pays in Mining” web application developed by the U.S. National Institute for Occupational Safety and Health Mining Program, helps mines determine the potential costs associated with mining injuries. This web app groups injuries by type, either by the cause of the injury or by the nature of the injury. When the user selects one of more than 30 common types of mining injuries, the app provides information on the distribution of costs of workers’ compensation claims for that type of injury. Based on other user inputs, the app will estimate the total costs of the selected injuries, including an estimate of additional indirect costs, the estimated impact of total injury costs on mining company profits, and provide some examples of other items, such as services or equipment, on which companies could spend the savings that result from the prevention of injuries. This paper reviews the app by discussing its development, how it is used to show the true costs of mining injuries, and how mines can benefit from using it.IntroductionInjuries on the job cause pain and suffering. They can also profoundly affect profits and daily operations. In addition to paying direct costs or increased premiums for workers’ compensation insurance, a company might need to pay overtime for other workers to fill an injured worker’s job role, cover training costs for a replacement worker or divert administrative resources in the wake of an injury. “Safety Pays in Mining” is a web app that estimates the distribution of these injury costs and assesses the impact that occupational injuries have on a company’s profits.The costs of specific types of occupational injuries in mining are not readily available as mining and insurance companies do not usually share this information. As a consequence, companies only have cost information based on previous experience with their own employees. Therefore, if a mine never experienced a finger amputation for one of its miners, for example, it would not be aware of the possible costs associated with this type of injury. In addition, injury costs are unique in that the cost distribution is so wide that just using the average cost of a specific injury type does not provide adequate information. Some injuries involve immensely high costs, and even though the risk of these high-cost injuries occurring is low, mines need to be aware of the potential impact on their company’s financial health."

Dec 1, 2018

By G Burton, S Fityus, J Li, S Vaughan, D Payne

Daunia and Caval Ridge coal mines, owned and operated by BHP, have been co-disposing rejects and dewatered tailings within spoil dumps from the beginning of their operations in 2013 and 2014, with the purpose of minimising environmental impact and geotechnical risk. Following the recent large failures of tailings dams around the world, BHP Coal, through its Coal Tailings Program, plans to transition other coal mines to deliver “dry” tailings and produce mixed plant rejects (MPR) for inpit co-disposal. This will materially reduce future tailings dam risk exposure. Previous laboratory shear strength testing was conducted on rejects with a maximum particles size of 20 mm, and some concerns were raised that this might not represent the mechanical properties of the actual full particle size distribution (PSD) rejects. BHP was also aware that using different technologies to dewater the tailings, such as belt press filters (BPF) and solid bowl centrifuge (SBC), could produce thickened tailings which could significantly modify the physical behaviours of the MPRs, particularly the bonding between particles. Therefore, laboratory testing on both coarse rejects and mixtures of the coarse rejects and dewatered tailings (MPRs), with full PSDs, was carried out. Testing was performed using the large direct shear machine developed by the Australian Coal Association Research Program (ACARP) project C20019 in 2017, as well as a 300 mm diameter triaxial apparatus at the University of Newcastle (UoN). This paper presents details of the laboratory testing program and results for the rejects from the first studied mine of the BHP Coal Tailings Program. It compares the shear strengths measured at full scale with those tested on modified (scalped or crushed) specimens in the past; and discusses the tailings dewatering technique selection from geotechnical aspects based on the testing results, and finally presents some dump and tip head stability analysis results using the testing results.

Jul 1, 2021

By Max Friedemann, Franziska Günther, Helmut Mischo

Ensuring adequate ventilation is a critical aspect of safety in underground mining operations. In small-scale mines in particular, key ventilation parameters such as temperature, humidity, and air velocity are often measured manually and only at infrequent intervals, typically using analog instruments. As a result, real-time monitoring of environmental changes, timely detection of hazardous situations, and demand-driven ventilation control are not feasible. This presentation discusses the selection and evaluation of modern digital ventilation measurement devices, including handheld instruments with digital data logging capabilities and continuously operating sensors with potential for real-time data transmission. The investigations focus on the challenges posed by underground environments with extremely high humidity levels, which can adversely affect sensor performance and electronic components. The results are based on testing conducted at the Research and Teaching Mine of TU Bergakademie Freiberg—an underground ore mine characterized by humidity levels exceeding 95%. Findings include assessments of measurement accuracy, reliability, and practical applicability under these demanding conditions.

Feb 22, 2026

By J Young, S Yu, P Moyo, M Powell, A Musunuri, B Bonfils, S Kanchibotla, P Yaroshak, V Jokovic

The appropriate design of liners continues to be an issue on many mills worldwide. Loss of milling capacity especially at liner change, uneven wear lives along the mill, substantial scrap on worn liners, excess mill down-time, undesirably short and unreliable wear lives are all common issues. This paper presents a designed approach to liner optimisation that follows a logical path of initial design and step-wise improvements based on liner wear monitoring. The target is to have a good liner design from start-up, then tune the profiles, heights and thicknesses based on wear monitoring. This is conducted as a team of liner specialist, site personnel and liner supplier. The application to the Pustynnoye SAG mill of JSC Altynalmas in Kazakhstan is presented. The increase in liner life by around 50% along with increased mill throughput of over 20% illustrate the huge benefit of the cooperative triumvirate approach through the gains that can be made in productivity and reduced liner costs.CITATION:Powell, M, Kanchibotla, S, Jokovic, V, Hilden, M, Bonfils, B, Musunuri, A, Moyo, P, Yu, S, Young, J, Yaroshak, P, Yalcin, E and Gorain, B, 2018. Advanced mine to mill application at the Barrick Cortez mine, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 177–196 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By J. Desroches, J. Burghardt, N. Whitney, B. Lecampion, A. Surdi, M. Houston, S. Stanchits

There is accepted evidence that multistage fracturing of horizontal wells in shale reservoirs results in significant production variation from perforation cluster to perforation cluster. In fact, only a fraction of the perforation clusters seem to contribute to production in many shale gas and shale oil plays. In many cases, the orientation of the lateral section of these wells is determined by lease boundaries rather than principal stress directions, and these often do not coincide. When horizontal wells are misaligned from the far-field principal stress directions, the fracture must reorient from the near-wellbore principal stress directions, which are aligned with the wellbore, to the far-field principal stress directions. The primary objective of this study is to learn how various completion designs influence the near-wellbore fracture geometry when such a misalignment exists. A secondary objective is to understand the influence of rock fabric features, such as mineralized natural fractures, on this reorientation process. To understand these effects, eight laboratory hydraulic fracturing tests were conducted using a true triaxial vessel with 914 mm × 762 mm × 762 mm samples of Niobrara shale. Several different completion designs were studied, including the use of fracture initiation slots with several different orientations and the use of perforations selectively located to encourage a smooth transition from the near- to far-wellbore region. The tests were carefully scaled as accurately as possible to provide insight into the field near-wellbore phenomena. Pressure and fluid flux at the wellbore, deformation of the block, acoustic velocity, and induced acoustic emissions were acquired during the tests. Additionally, sized particles were also injected to gauge the fracture width away from the wellbore. After the test, the blocks were dismantled, and the fracture geometry was mapped in 3D. These measurements allow one to clearly differentiate the fracture initiation and the breakdown—meaning the peak pressure—to be clearly differentiated; the fracture was already well developed when the maximum pressure was reached. The study reveals non-negligible tortuosity and aperture restriction in the near-wellbore region. In the field, this would translate to high treating pressures, uneven proppant distribution, and possibly near-wellbore screenouts. The test results show that, of the configurations tested, the best approach is to use deep slots that are aligned with the far-field principal stress directions. The oriented perforation design did not achieve the simple, smooth transition that was hoped for, and instead produced multiple competing near-wellbore fractures and considerable tortuosity. The study also demonstrated that the presence of planes of weakness, such as mineralized natural fractures, near the slot tip can result in poor near-wellbore fracture geometries, even for the best completion configuration. We conclude from these tests that the misalignment of the well with a principal stress direction creates near-wellbore complexity that, in turn, creates uncertainty in proppant distribution and, therefore, production; proppant might avoid up to a half of the created fracture. Regardless of the wellbore orientation, this uncertainty is further increased by the presence of mineralized features in the rock fabric that can strongly alter or stop the growth of the hydraulic fracture. Preventing those effects by changing the completion alone proves difficult, and new strategies are required to ensure a reliable stimulation of shales.

Jan 1, 2015

By Michael Bauer

Increases in productivity and improvements in mining occupational safety and health are intrinsically linked. Over the past years, the German Hard Coal Mining Industry has been able to accomplish both: an increase in coal production and, at the same time, a significantly reduction of accidents. This success has been achieved by advances in technology, better organization and investment in people. Since 1990 productivity has more than doubled, while the total number of accidents has been reduced by more than 90%. Further development started initially with the mechanisation of the winning and drivage technology. Innovative technology and standardisation of the mining equipment were one reason for the increase in productivity and reduction of the accident rate. Therefore this technical development was not only one important pillar of the TOM model explicated later but also the requirement for the successful development of the other pillars. In addition to further developing this innovative technology it was possible to realise procedural and organisational improvements. As a result, the above achievement is based on implementing the three pillars of the so-called "TOM" model (technology, organization, ?Mensch? = human). To increase safety, improve performance, raise awareness and change of employees? attitude, the following technical and organizational requirements have been introduced: ??New innovative technology and procedures, standardized techniques and better equipment. ??Measures to revise or redefine the organizational structure, processes and systems of work, which were then integrated into the company policy and procedures as a company management tool. ??Personnel measures (investment in people). These include, improving motivation and behaviour, training, communication to raise and to change awareness of safety issues. Success in Occupational Health and Safety is not an automatic or self-regulating process. It needs hard work to make improvements and it must be treated as a recurring cyclic process. As a result of the above, occupational health and safety has become a natural part of daily work in the German Hard Coal Mining Industry. This could only be achieved by the unconditional "commitment" of all managers and employees to the issues, coupled with discipline and responsible action. Further improvements towards the ultimate aim of "zero" accidents are only possible by mutual involvement in implementing the ?TOM? (technology, organization and ?Mensch? human) model.

Aug 1, 2013

By Andrew B. Allen, Charles W. Robinson, Robert L. Schneider

In April, the US Synthetic Fuels Corp. broke a three-year silence and made its first financial award by approving a $820,750 loan for the First Colony peat-to-methanol project in North Carolina (ME, May, page 403). Peat Methanol Associates (PMA), a partnership between Koppers Co., ETCO Methanol Inc., Transco, Peat Methanol Co., and l. B. Sunderland, broke ground at First Colony last year and plans to begin production in Dec. 1985. Although the award is only a small part of Synthetic Fuels Corp.'s $15-billion budget, it does signal the corporation's intention to move aggressively ahead. It also is a positive indication that First Colony will be completed and operated successfully. This article describes the methods and equipment that will be used to harvest peat at First Colony, as well as how the peat will be converted to methanol. Introduction Peat deposits found along North Carolina's coastal plain contain high-quality fuel-grade peat with an average heating value of more than 23.3 MJ/kg (10,000 Btu/lb) (dry), with a low sulfur and ash content. The deposits differ from other US peats in that they contain large, sound Atlantic White Cedar and Cypress logs, stumps, and roots that may extend throughout the full depth of the deposit. A second difference is that these deposits are much more highly decomposed and, in the raw state, have the appearance and feel of a heavy, reddish-brown grease. These factors make it impractical to use standard production equipment so a new line was developed. Also, because of these conditions, techniques were modified to facilitate production. First Colony Farms, located near Creswell, NC, developed and evaluated a milled peat program. Equipment for this production method was designed and built, production rates were established from field operations, drying rates were established, weather data were analyzed, and total operating and capital costs were estimated. The method depends on the sun and wind for drying peat to the desired moisture content, in this case around 40%. Therefore, field preparation is actually the construction of a large solar collector to dry the peat so it can be harvested and stockpiled. It is essential that this collector be properly profiled initially and maintained during production to prevent precipitation from ponding. Initial Field Preparation Initial field preparation includes cleaning existing canals and constructing ditches and water control structures for proper drainage of rainwater run-off, building adequate roads for site access, removing surface vegetation, and profiling and sloping the fields. At First Colony, the 60.7-km2 (15,000-acre) harvesting area was divided into 129.5-hm2 (320-acre) blocks about 1.6 km (1 mile) long and 805 m (0.5 mile) wide. This was accomplished by cleaning main outfall canals with adjacent roads built from canal spoil at 1.6-km (1-mile) intervals. Existing intermediate canals that feed into main outfall canals at 805-m (0.5-mile) intervals also are cleaned. Headland roads are constructed from canal spoil along each side of each intermediate canal. This 129.5-hm2 (320-acre) block is then divided into 32 harvest strips by small V-ditches constructed at 50-m (165-ft) intervals. At the end of the field with the lowest elevation, corrugated steel pipe culverts are installed under the headland road in each V-ditch to control rainwater runoff into intermediate canals. Runoff water from the fields is diverted to a holding pond to prevent any increase in peak water runoff rates and to allow for more uniform drainage rate than experienced to date. After the drainage system is installed, harvest strips are ready for grinding and sloping operations. Surface vegetation, made up of small, waxy-leafed shrubs such as Gallberry, Bayberry, Magnolia, and scattered pond pine, can be effectively ground and incorporated into the upper surface of the peat layer. Here, it will rapidly decompose and have little effect on overall peat quality, thus eliminating the standard practice of pushing the vegetation and upper wood layer into long windrows with bulldozers and hauling this debris from the fields. Incorporating vegetation into the upper surface is known as the initial 102-mm (4-in.) surface vegetation grind and is accomplished by using a modified Bros Rota Mixer. Following this operation, and by using the same unit, a sec¬ond grind with a depth of 200-255 mm (8-10 in.) is made. This reduces the debris to a finer consistency, mixes it with the upper peat layer, and grinds any wood found in the upper 200-255 mm (8-10 in.). After initial grinding operations are completed, the augering or sloping operations can be accomplished with little or no hin-

Jan 7, 1983

By V. M. Karve, K. K. Majundar, K. V. Viswanathan, J. Y. Somnay

The effect of calcium, magnesium, iron (both ferrous and ferric) and aluminum ions, which are commonly encountered in a typical beryl ore, was studied in the flotation of pure beryl, soda-feldspar and quartz. The vacuumatic flotation technique was employed. With sodium oleate as collector and in the absence of any activator, beryl floated in a pH range of 3 to 7.5, whereas feldspar and quartz did not float at any pH up to 11.5. The pH range of flotation increased in the presence of the ions studied. With calcium and magnesium ions beryl floated from 3 to 11.5 pH and beyond, soda-feldspar floated beyond pH 6 and quartz floated beyond pH 8. Ferrous ion activation was found to be similar to that of calcium and magnesium. Activation by ferric and aluminium ions was found to be complex and the lower and upper critical pH for all the three minerals was around 2 and 10 respectively. These studies indicated the possibility of separation of beryl from feldspar and quartz even in the presence of calcium, magnesium and ferrous ions between pH 4 and 6. Flotation tests on a mixed feed of pure minerals in a 10 g cell revealed that beryl can be selectively floated from feldspar and quartz if ferric ion is reduced to ferrous state or if it is complexed. Beryl occurs mostly in pegmatites, and hence is associated with feldspar, quartz and micas and small amounts of other minerals such as apatite and tourmaline. The separation of beryl from these minerals is difficult because all the silicates accompanying beryl have more or less the same physical properties. Specific gravities of beryl, feldspar and quartz are 2.70, 2.56 and 2.66 respectively. Electrostatic separation has been suggested but no work has been reported. ' The adsorption of sodium tri-decylate tagged with Cl4 on beryl, feldspar and quartz reveal similarity in surface properties. Much work has been reported on the flotation of beryl from ores, either directly or indirectly as a by-product, but little is known about the fundamental aspects of beryl flotation. Kennedy and O'Meara3 laid emphasis on prior cleaning of the mineral surfaces with HF. Mica is removed first by flotation of beryl with oleic acid, around neutral pH. Runke4 introduced calcium hypochlorite conditioning in a final separation stage for activating beryl in a mixed beryl-feldspar concentrate, and after washing to remove the hypochlorite, floated beryl with petroleum sulphonate. The Snedden and Gibbs5 procedure is somewhat similar to that of Kennedy and O'Meara. Emulsified oleic acid is used as collector. Recently Fuerstenau and Bhappu6 studied the flotation of beryl, feldspar and quartz with petroleum sulfonate in the presence of activators and stressed the importance of iron in the flotation of beryl. From the studies conducted in this laboratory, it was found that feldspar and quartz as such do not float with sodium oleate, but in practice selective flotation of beryl from feldspar and quartz in an ore is found to be impossible with sodium oleate as collector. A glance at the chemical analysis of typical beryl ore indicates the presence of several ions like Ca ++, Mg++, Al + + + and Fe+++ in abundance and Ti++++ and Mn++ in traces. Hence, in an attempt to explain the behaviour of feldspar in the beryl flotation, the effect of Ca++, Mg++, Al+++ and Fe+++, which are known as gangue mineral activators7'8 has been investigated. Materials and Methods: Lumps of beryl ore (hand picked) were boiled with 10% sodium hydroxide and washed with distilled water. They were further boiled many times with 10% hydrochloric acid till no positive test for iron was obtained with ammonium thio cyanate. This was followed by thorough flushing with double distilled water. The lumps were crushed in a porcelain mortar and pestle under water. The minus 65 + 100 mesh fraction was used for testing and was always stored under distilled water. Pure feldspar and quartz were similarly prepared and the minus 65 + 100 mesh fractions collected. Inorganic ions tried as activators were ca++, Mg++ , Fe++, Fe ++ and A1 +++ . Calcium nitrate, magnesium chloride, ferrous ammonium sulfate, ferric ammonium sulfate and aluminum nitrate of G.R.E. Merck grade were used. B.D.H. technical grade sodium oleate was used as a collector. The vacuumatic flotation technique developed by Schuhmann and Prakash was used for studying the effect of pH on flotability. 7 The indications given by this work were confirmed by using 10 g miniature cell.'

Jan 1, 1965

By P. Dhar, H. R. Kota, M. Thornhill

A very high-grade calcite deposit located in northern Norway consists of CaCO3 ore with minor silicate and sulphide impurities. Cationic (Tallow-1,3-diaminopropane, Duomeen T) collector has been used in the purification of calcite by flotation with an aim of achieving calcite concentrate for its use in value-added products in a variety of industries. The feasibility of sulphide flotation from calcite by this cationic collector has been initially judged from Hallimond flotation and zeta potential on pure mineral systems and the results illustrate the removal of sulphide from calcite ore at neutral pH region. The adsorption mechanism of diamine on both the sulphide minerals was found to be the same by zeta potential studies. The variations in zeta potential are in good agreement with the adsorption of diamine molecular and ionic species as a function of pH. FTIR studies also showed the adsorption of diamine species in agreement with the zeta potential and Hallimond flotation results. Furthermore, the removal of sulphide impurities with selective flotation by diamine collector was performed in bench-scale flotation with the calcite ore and the results indeed showed that the calcite concentrate could meet the quality requirements for its use in the paper industry for coating and filler purposes.

By R. T. Hukki

This paper presents a series of equations for mechanical ball wear, relating parameters of ball size, mill speed, and mill diameter. The fundamental equation, Eq. 12, presented here is introduced to correlate these basic parameters and thus define and clarify the concept of ball wear. This equation is offered as a general rule, which may be modified to apply to individual problems of grinding. BALL wear as observed in grinding installations is the combined result of mechanical wear and corrosion. Corrosion should be a linear function of the ball surface available. Ball corrosion, however, has been studied so little that its effect, although of great importance, cannot be included in the analyses given here. In a separate paper' it is shown that 1 n = 0.7663 np----=— rpm [1] vD P = c, np D kw [2] T=c²(np)n De tph [3] In these equations n — actual mill speed, rpm np = calculated percentage critical speed D = ID of mill in feet P = power required to operate a mill, kw T = capacity of a mill, tph C¹ and c² - appropriate constants in = exponent of numerical value of 1 5 m 1.5 Exponent m is the slope of a straight line on logarithmic paper relating mill speed (on the abscissa) and mill capacity (on the ordinate). It is generally accepted, although not sharply defined, that ball wear in mills running at low (cascading) speeds is a function of the ball surface available. Accordingly, the wear of a single ball may be considered to be a homogeneous, linear function of its surface and of the distance traveled. Thus dw = f¹(d2) . f2(ds) [4] where dw is the wear of a single ball in time dt, d the diameter of the average ball in ball charge, and ds the distance traveled by the ball in time dt. Indicating that ds - a D n dt, the wear of the average ball in time dt becomes dw = f¹(d2) . f2(Dn dt) 1 --- f¹ (d1) f² (D c3 np-----— dt) \/D = c,d² n, D dt The rate of wear of the average ball is given by dw/dt. dw/dt = c, d² np D lb per hr [5] The weight of the ball charge per unit of mill length is a function of D The number of balls of size d in the ball charge is = f³(D2)/f4(d³). The rate of wear of the total ball charge equals the number of balls times rate of wear of the average ball. Thus rate of total ball wear = — . (dw/dt) w. c, . (l/d) . n,, D lb per hr [6] which is the equation of ball wear in low speed mills. In a mill running at a low speed, grinding is the result of rubbing action within the ball mass and between the ball mass and mill liners. When the speed of the mill is gradually increased toward the critical, the impacting effect of freely falling balls becomes increasingly prominent in comparison with the rubbing action. Reduction of ore takes place partly by rubbing, partly by impact. The share of the freely falling balls in the reduction of ore reaches its practical maximum at a speed somewhat less than the critical; at that speed grinding by rubbing has decreased to a low value. It may be reasonable to think that size reduction by freely falling balls should reach its theoretical maximum at the critical speed, if the fall of the balls were not hindered by the shell of the mill beyond the top point; grinding by rubbing would cease at the critical speed. As a first approximation, wear of freely falling balls may be considered to be a homogeneous, linear function of the force at which they strike pieces of rock and other balls at the toe of the ball charge. The force equals mass times acceleration. The mass of a ball is a function of d3 and its acceleration is a function of the peripheral speed of the mill. The wear of a single ball of size d representing the average ball in a ball charge will therefore be w¹ = f3(F) = f (d3) f7 (v). [7] Indicating that v = D n, and n = c³ np 1/vD, Eq. 7 becomes W1 = cn d3 np Do.5 lb per hr. [8] Total wear of the ball charge equals number of balls times the wear of the average ball. Number of

Jan 1, 1955

By D. Moses, J. A. Onyango

Carbonatites are generally competent rock masses with rock mass rating class II rating 60–74. In spite of their competency, they tend to be affected by weak features like manganese-iron veins and/or in situ rock damage due to brecciation associated with carbonatite complexes. Rock slope failure in such hard rocks is complex since such structures within the rock mass form weak links that could potentially control slope instability. In this contribution, a numerical simulation using phase2 v 7.0 was carried out to investigate the influence of in situ rock damage on the stability of mine pit walls. The outcome reveals that, the existence of breccia in the competent rock mass has the capability to reduce the slope stability performance particularly at gentle dipping angles of emplacement in close range to the slope toe. However, as the emplacement position of breccia moves away from the pit wall, the stability performance increases at gentle dipping angle <50º. On the contrary, at the dipping angle of 50° the performance of slope reduced, and at steeper angles >50° the impact becomes negligible. Thus, from a series of analyses, mine design in brecciated rock masses, the ratio of 1:5 between the breccia distance from slope toe and pit depth should be implemented to counter its impact, and if the breccia is within or close to the pit limit, a deliberate effort must be made to mine it out.

Sep 1, 2025

By T. H. Patching, D. F. Coates

The Sub-Committee on Rock Classification, Canadian Advisory Committee on Rock Mechanics, has evolved a classification of rocks which should prove useful in studies of rock mechanics. Considered in two stages -actual rock substance and rock mass -the five-point classification involves the geological name of the rock, the rock strength and rock deformation, and, in the second stage, the gross homogeneity of the rock mass and the formation continuity.

Jan 1, 1968

By A. Martins, L. Goulart, E. Araujo, R. Batista, A. Costa e Silva

Steel cleanness is of great importance to the performance of almost all steel products. From very clean steel for bearings to long products used in civil construction, processing variables – in special those in steelmaking operations- must be properly balanced to achieve adequate cleanness for the desired performance. With the present complexity of steels as alloy systems, it is not efficient nor appropriate to develop these processes on empirical basis alone. Computational thermodynamics can greatly improve process development to achieve the desired cleanness level at reasonable costs. In this work, examples of these calculations and their applications to real steel processing are presented and discussed. The advantages, limitations and areas in which improvement in these calculations is desired are highlighted and discussed.

Jan 1, 2015