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By Roy L. Wilfong, LeRoy R. Furlong, Louis P. Domingues

The bulk and apparent densities , particle size , and surface area of ceria powders derived from the ammonium sulfate , carbonate , nitrate , oxalate , and sulfate salts and heated at 950 ° to 1,500 ° C for 1 to 24 hours were studied . The bulk and apparent densities and particle size generally increased , and surface area decreased with increase in temperature and time of heating ; surface area was more sensitive to changes in temperature and time than the other properties studied . These properties of the ceria powders had a marked dependence on temperature and a lesser dependence on duration of heating at a given temperature ; and the source of oxide and thermal treatment cannot be considered optional in the preparation of refractory powders by thermal decomposition . The ammonium sulfate and sulfate salts heated at 950 ° and 1,200 ° C produced oxide powders with the lowest bulk density , the smallest particle size , and the highest surface area . The highest apparent densities were achieved for oxides resulting from the carbonate and the sulfate but the carbonate - derived material was considerably coarser . The surface areas of ceria powders derived from cerium salts decrease in the order of sulfate , ammonium sulfate , nitrate , oxalate , and carbonate . The observation of these physical properties are useful in predicting the sintering behavior of various oxide powders .

Jan 1, 1964

By W. S. Fyfe

The future environment of our planet, with the concept of sustainable development, has moved to centre stage of all future plans for development. This global view is new. It presents great opportunities and challenges for the Earth Sciences. We have the tools to describe our environment on all scales - planetary to molecular levels. We must respond to this great demand by world society.

Jan 1, 1990

By M. Holuszko, I. Mikhalev

"Previous studies described by Galvin et al. (2017) have shown that for Australian bituminous coal fines, both in batch and in continuous process, the new improved oil agglomeration procedure based on the use of high-internal-phase (HIP) emulsions, as compared to the conventional “pure oil” agglomeration process, enables a significant reduction in the amount of oil while reaching a high yield of clean coal (approximately 90% of agglomerates greater than 355 µm in size) in a significantly shorter time. The HIP emulsion used in these experiments comprised up to 95% vol. aqueous solution of sodium chloride (3% wt. concentration) and for the rest, a mixture of kerosene (oil) and sorbitan monooleate (SMO emulsifier) in a 1:1 ratio as a binder. This study evaluates the applicability of the new HIP-oil agglomeration process to treat Canadian bituminous ultra-fine coal and Russian sub-bituminous coal fines and compares results from agglomeration to the flotation response of both coals. Oil agglomeration is known to be sensitive to surface properties of coal. Since surface properties of coals depend not only on the rank of coal but also on their origin (depositional environment) and mineralogical composition, both the applicability of this new improved agglomeration process to the non-Australian coals and its efficiency became the motivation for this study. To evaluate the applicability of the new process to both Canadian bituminous and Russian sub-bituminous coals, a series of bench-scale tests were carried out under conditions similar to those described by van Netten et al. (2016) for the Australian coals. Based on the results obtained in this research, new boundary conditions for the application of the HIP emulsion-based oil agglomeration process have been outlined and conclusions on the viability of the new process to treat ultra-fine coal from Western Canada and Russian sub-bituminous coal fines have been reached.INTRODUCTION In most cases, to meet the market requirements, the mined coal has to be processed to reduce the ash content by the removal of mineral matter and thus to increase the quality of the coal products (van Netten et al., 2016). Generally, flotation is used for processing fines from high rank coals; however, there are high losses of very fine coal due to the inefficiency of this process. Furthermore, difficulty in dewatering the fine coal results in excessive moisture levels causing coal handleability issues, which increases costs in the coal-cleaning industry (Capes & Darcovich, 1984). Much of the development that has occurred in fine coal cleaning has taken place with higher-value coal, often metallurgical (Klima et al., 2012). If the fine coal is deemed to be too difficult or expensive to process, it may be discarded as waste (van Netten et al, 2014). Such disposal not only creates an environmental liability but may also result in the loss of a valuable, high quality product that is better liberated than the coarser fractions of coal."

Jan 1, 2018

By Ausenco Engineering Canada

"This paper demonstrates the selection of grinding circuit technology for a number of recent projects including discussion of the key drivers and the role of energy efficiency. Decreasing head grades combined with a strong and sustained increase in operating costs has forced miners to examine increased project size, increased equipment capacity and efficiency improvements in order to reduce their unit operating costs and improve overall project economics. Comminution energy consumption, safety and capital cost considerations play a critical role in the success of projects. This paper presents some key guidelines for a successful and cost effective comminution circuit design and includes a case study on three projects, outlining the issues and the drivers which led to the ultimate circuit selection and the critical role that energy efficiency played.INTRODUCTIONComminution circuits for minerals processing are selected based on their suitability and efficiency in reducing run-of-mine ore to the desired feed size for the downstream process. The input material (ore) properties and downstream process requirements are the key determinants and there are standard approaches for each circumstance.The minerals processing industry has been a fast adaptor of efficiency improvements based on increasing capacity of equipment (e.g. trucks, crushers, mills, pumps) but less successful in adapting radically new technologies that disrupt incumbent flowsheets or processes.The installed power of grinding mills has increased linearly over the past 25 years (Meka & Lane, 2010) and pumps and classification equipment have kept pace. The autogenous grinding (AG) and semiautogenous grinding (SAG) mills displaced stage crushing as a dominant method of coarse rock breakage in many applications causing crusher manufactures to increase the capacity of cone crushers to meet the competitive demand.Examples of new comminution technology in the 20th and 21st centuries are the development and adoption of cyclone classification in the 1940s (Newtech, 2016), AG milling in the late 1950s, vertical grinding mills in the 1980s, high pressure grinding rolls (HPGRs) also in the 1980s and ultrafine milling technology in the 1990s (Meka & Lane, 2010)."

Jan 1, 2016

By Nasri Munfah, Steffen Matthei, Vojtech Gall

"Conventional tunneling as defined by ITA WG19 is also known as the New Austrian Tunneling Method (NATM) or Sequential Excavation Method (SEM) was transformed in the US to deal with challenging tunneling conditions as an alternative to the more traditional tunneling methods. It is being used more often in urban areas, under difficult ground and ground water conditions, and with limited cover. Often the tunnel is of a large and non-uniform cross section in soft soils or weak rocks. The intent of using this tunneling method is to minimize impact on traffic and utilities and reduce disruption of everyday life of people and businesses. To meet these challenges, the industry developed technical approaches and implementation techniques and established sophisticated contractual relationships and collaboration in the field among various parties for successful implementation. This paper examines the development of conventional tunneling (NATM/SEM) in the US to deal with these challenges using recent examples such as Russia Wharf in Boston, Northern Boulevard Crossing, in New York, and Chinatown Station in San Francisco. INTRODUCTION / HISTORY Conventional tunneling or NATM/SEM is a concept that is based on the understanding of the behavior of the ground as it reacts to the creation of an underground opening. In its classic form the SEM/NATM attempts to mobilize the self-supporting capability of the ground to an optimum thus achieving economy in ground support. Initially formulated for application in rock tunneling in the early 1960’s, NATM has found application in soft ground in urban tunneling in the late 60’s and has since then enjoyed a broad, international utilization in both rural and urban settings. In the US the NATM/SEM tunneling method has been used successfully to address challenging tunneling conditions in urban areas. A large number of tunnels have been built around the world using a construction approach which was loosely termed NATM. During the years of discussions and the application of NATM a variety of terms have been used for the same construction approach. These terms were primarily aimed at describing the construction approach rather than the region of its reported origin."

Jan 1, 2016

By Leena Suopajärvi, Karin Käär, Marcin Szumny, Jari Joutsenvaara, Md Ariful Islam, Helmut Mischo, Georg Meissner, Ossi Kotavaara, Catalina Vrabie

This study outlines implemented tactics and results for community empowerment through participation in questionnaire surveys, educational programs, and discussion on sustainable sourcing from new critical raw materials (CRMs) projects. Utilising questionnaire surveys, including the Public Participation Geographic Information System (PPGIS), the research gathered public opinions from Estonia, Germany, Poland, and Zambia, receiving 1,068 responses. These responses addressed various social, economic, and environmental issues related to CRM projects. Feedback from educational courses with participants from over 25 nations and public events provided additional insights. The collected data and feedback offer crucial input for advancing sustainable and responsible CRM sourcing strategies in these regions.

Feb 1, 2025

By Stephen Darmawan, Mahdi M. Disfani, Arul Arulrajah, Alireza Mohammadinia

Deep mixing using cementitious compounds is an in-situ method of ground improvement for improving the strength, compressibility of loose sand. Artificial light cementation can increase the stiffness of loose sands significantly and reduce the settlement of loose deposits. The increase in contact area between the particles with a thin layer of cementitious agent depends on the confinement and void ratio of the soil mass. Hence, the stiffening effect of cementation not only depends on the type and amount of cementing agent and inter-particular force chain of loose deposit but also depends on the stress level at the time of cementation. In addition, the cementation effect in loose deposits can be deteriorated at relatively low strain levels. Decementation softening can cause detrimental and irreversible impacts on the soil deposit. This study investigates the effect of initial confinement and subsequently the initial void ratio at the time of cementation on small strain behaviour and decementation softening of cemented loose sand under ko loading. The effect of inter-particular contact of sand particles based on the specific surface area and also soil density was also investigated by means of shear wave propagation. This study present insightful information on effect of primary consolidation stress levels, density of soil and cementation level on softening and collapse of loose deposits improved using deep soil mixing technique. Better understanding of soil-cement interaction by optimization of binder content for deep mixing activation can lead to increasing the level of confidence in using this technique in ground improvement applications.

Jan 1, 1900

By Nirlane Cristiane Silva, Leonardo Gonçalves Pedroti, Ana Augusta Passos Rezende, Anna Paula Sartori, Benício Costa Ribeiro, Andreiva Lauren Vital do Carmo, Wellington Emílio Hilarino Fernandes

The final disposal of sludge from recycled paper mill effluent treatment plants is costly and demands large areas for landfilling. Environmentally sound alternative uses of the sludge, enabling economic valoration of this material appear to be advantageous to industry and to the environment. This paper evaluates the feasibility of the incorporation of paper mill sludge in manufacturing of ceramic bodies. The combination of different proportions of weak clay, strong clay and sludge from recycled paper effluent treatment plant for the production of ceramic bodies was determined by using the Network Simplex method planning of mixtures. Samples were prepared and burnt in oven at temperatures of 750, 850 and 950 °C. Physical, mechanical and environmental tests were carried out, in addition to chemical, microscopic and thermic analysis. The results demonstrated that the flexion resistance increased with the increase in temperature, while the absorption decreased at higher temperatures. The mixture design is efficient combining sludge addition at small fractions with large amount of clay, which demonstrate the viability of sludge incorporation for ceramic bodies manufacture, since the desired characteristics are observed.

Mar 1, 2017

By K Lee, L Mann, J Bygrave, G Sheldon

Ausmelt is supplying commercial quantities of an alkyl hydroxamate flotation collector AM28 for flotation of oxide and supergene base metal ores and tailings. AM28 is a non-hazardous product used as a ten per cent to 50 per cent solution in dilute potassium hydroxide. It is a selective flotation collector for oxide or oxidised base metal minerals and replaces conventional sulfidisation for oxide mineral flotation. At Radio Hill, the AM28 is used in conjunction with traditional sulfide collectors, which allows simultaneous flotation of oxide and sulfide copper minerals. The Fox Resources Radio Hill copper concentrator near Karratha, Western Australia, is currently configured to treat supergene copper ore sourced from the West Whundo open pit. This Archean VMS type copper deposit has been deformed and remobilised with uplift, erosion and weathering to form a significant supergene zone. The sulfide copper minerals present in the upper zone are digenite and chalcocite with lesser chalcopyrite and covellite. Oxide copper minerals present include cuprite, with lesser malachite and azurite. Gangue minerals include quartz, talc and chlorite. Plant trials at Radio Hill are reported for supergene West Whundo ore, where the AM28 was stage added into the circuit at nominally 80 g/t. Plant data over three months shows the copper recovery increased consistently from around 50 - 60 per cent to above 70 per cent when AM28 was added. This has been proven statistically. The grade of the concentrate was consistent with and without AM28, at nominally 22 - 24 per cent copper.

Jan 1, 2007

By Rafaela Pacheco Malvão dos Santos, Rafaela Pereira Batista Carvalho, Flávio Monteiro de Souza, Bruno Moura de Jesus, Rodrigo da Silva Magalhães

Dentre as impurezas do gusa, o fósforo se destaca por promover fragilidade a frio ao aço, uma propriedade normalmente indesejada. A sua adequação a teores aceitáveis ocorre no Conversor LD, através da oxidação do banho e adição de fundentes. O modelo proposto objetiva determinar a adição de fundentes de forma dinâmica: com base na termodinâmica e ajustes com dados históricos visando promover uma escória adequada a proteção do revestimento refratário e a desfosforação. O modelo está em uso nos Conversores LD da Aciaria da Companhia Siderúrgica Nacional e demonstrou resultados satisfatórios.

Oct 1, 2019

By Shawn P. Coughlin, Michael A. Schimmenti, Juan Leonardo Tello del Pino

"The Sistema de Potabilización Área Norte project (Northern Area Purification System) was a major expansion of the potable water system in Buenos Aires Province, Argentina. The aim of the project was to transport and purify raw water from the Paraná River to provide potable water for five communities in the northern part of the province, benefitting up to two million people. The project was constructed by a joint venture (JV) of four South American contractors and consisted of the following key components:• Treatment plant: A 16-ha (39-acre) area was cleared for the construction of a treatment plant to purify 900,000 m3/day (1.2 million cu ft/d) of raw water from the Paraná River and distribute it to the surrounding communities.• Bored tunnel: Nearly 15 km (9 miles) of 3.6 m (12 ft) inner diameter tunnel, ranging from 18 to 22 m (59 ft to 72 ft) below grade, was bored with two earth pressure balance (EPB) tunnel boring machines (TBM) to draw the raw water from the river. The TBMs started from a central launch shaft and proceeded in opposite directions. Cristina advanced northbound to the Paraná River Intake System, and Liliana advanced southbound to the new treatment plant.• Access and ventilation shafts: Five access shafts and eight ventilation shafts were installed along the length of the tunnel. The access shafts were designed to provide entry points for inspection and maintenance of the final tunnel. The five shafts consisted of one central launch shaft in the middle of the tunnel alignment, one retrieval shaft at each end of the tunnel (intake and treatment plant, respectively) and two intermediate shafts. The intermediate shafts were installed before the TBM passed, with a final liner to be installedafterward."

Sep 1, 2016

By E. You

The concentrator at Kennecott Utah Copper currently has 4 lines with a configuration of one SAG mill feeding two ball mills. The slurry that reports to each ball mill will vary resulting in an unequal load of material. This configuration contains two separate sumps that receive material from a distribution box relying solely on natural slurry flow to feed each sump. The unequal split to each mill results in one mill receiving a greater amount of material. This will result in the equipment on one mill reaching limitations that may affect product quality and the operation of the equipment near maximum. The parallel mill in this condition will often have additional capacity that can be used but cannot be utilized due to the unequal split. The major consequences of this issue result in reduced throughputs and metal recovery. To resolve this condition an advanced control strategy was implemented to control the split in April of 2002 using equipment that was in place.

Jan 1, 2007

By D. E. Hirsch, J. W. Davis, Norman G. Foster, F. G. Schwartz

This investigation was undertaken to identify nitrogen , oxygen , and sulfur compounds (polar components ) found in catalytically cracked distillate fuel . It is significant that these compounds concentrate in the sediments and gum that form when the fuel is stored . The polar components were divided in three portions by elution from a chromatographic column filled with alumina . After the hydrocarbons were washed through the column with pentane , a benzene eluted extract was removed followed by an ether eluted extract and then an alcohol desorbed fraction . These extracts were individually distilled in a molecular still and the fractions were analyzed by gas chromatography , mass spectrometry , infrared spectrometry , and elemental and functional analyses . Naphthalene and its homologs , phenanthrene and its homologs , and other compounds such as methyl indene , C₂ quinolines , phenyl indan , and the benzothiophenes , appear in the benzene extracts . Quinolines are the major components of the lower boiling fraction of the ether extract , although carbazoles , acridans , and indoles are present in some concentration . Elemental and functional group analyses of the alcohol fraction indicated 10 percent of the distillate portion was nonhydrocarbon , and in this portion the average molecule contained more than one nonhydrocarbon element . Compounds of such complexity are not well known , and standards for positive identification are limited .

Jan 1, 1963

By D. R. Hay, E. Scala

Electrotransport has been superimposed on the rate-limiling- step in zone refining which is the impurity diffusion through the liquid at the solid/liquid interface. The efficiency of zone refining is increased and relative resistivity ratios (P300°k/P4 2°K) he increased by 50 pel in tungsten for a given number of posses using- the electrotransport field-aided method. The effiect of zotze refining in the presence of an electric field on the relative resistivity ratio is examined as a function of its intensity and polarity. THE effect of electrodiffusion on the effective distribution coefficient of zone refining has been discussed by Pfann and Wagner.' Control of the distribution coefficient in zone refining is of twofold interest. A distribution coefficient of unity can be increased or decreased, making possible the transfer of some previously inseparable solutes. The general efficiency of zone refining can also be increased. In the conventional zone-refining process impurities are removed by their retention in the molten zone and subsequent deposition at the end of the rod after a complete passage of the zone. In higher-melting-point systems a second mechanism may also operate, the volatilization of impurities from the molten zone. It has been suggested by schadler2 that, in refractory metals, vacuum distillation plays the predominant role in purification. In Koo's results,3 the resistivity ratio decreased beyond a zone-refined length of 6 in. from the starting end, indicating that some purification does in fact occur by true zone-refining action. Hay and scala4 showed that the degree of purity as measured by the relative resistivity ratio method depends on the square root of time in the molten zone (number of passes) and thus appears to be limited by diffusion in the boundary layer at the solidifying interface assuming good mixing in the body of the molten zone where a linear rate would prevail. The final concentration of impurities in electron-beam floating-zone purification depends very much on the operating conditions and results obtained by various investigators2,3,5 are difficult to correlate. The diameter of the starting material, operating vacuum, and rate of traverse are among the factors to be considered. There are, nevertheless, some general observations to be obtained from the literature. Lawley5 reviewed the literature up to 1962 and concluded that the major contaminants generally remaining in tungsten after electron-beam zone refining are molybdenum and carbon. Molybdenum due to its high melting point and distribution coefficient of nearly unity would be expected to be difficult to remove by either volatilization or zone refining. Carbon is not only a common contaminant in vacuum systems, but is also very difficult to remove by conventional vacuum melting. even with vacuums of 10-7 mm Hg. For each of those impurities removed by zone refining the equation of Pfann and Wagner may be applied: It relates the effective distribution coefficient k to a superimposed driving force which accelerates the solute away from the interface with a terminal velocity L" and to the more conventional zone-refining parameters; v = rate of traverse, t = thickness of the diffusion layer at the solidifying interface, D = diffusivity of the solute in the molten zone, and ko = equilibrium distribution coefficient of the impurity.

Jan 1, 1965

By L. J. Hoover

The objective of this study was to assess the health and environmental impacts of fluidized-bed combustion (FBC) of coal, specifically as applied to baseload generation of electrical energy by utilities. The study* was a short-term effort that based its analyses on information derived from the experience of the group or quickly obtained from the literature. The approach was to compare Atmospheric Fluidized-Bed Combustion (AFBC) and Pressurized Fluidized-Bed Combustion (PFBC) with two current technologies: low-sulfur coal combustion (LSC) and flue gas desulfurization (FGD) used with high-sulfur coals. A wet-limestone process was selected as the FGD technology. The impacts compared involved not only health and environment but also sociology, resource use, and dollar cost. Conditions for comparison were centered around a nominal date of 1988, when initial operation of commercial AFBC plants may occur. The PFBC has a later introductory date, a nominal 1995 (its impacts relative to other competitive technologies now in the R&D stages were not compared.)

Jan 1, 1978

By J. M. Kuchta

Ignition and flammability test methods were developed by the Bureau of Mines for use in the classification of flammable solids by the Department of Transportation. A rotating disk ignition apparatus and a flame-spread-rate apparatus are proposed for determining the ignitability and flammability, respectively, of most flammable solids. Extremely flammable solids, such as pyrophoric materials, are evaluated by determining their ease of spontaneous ignition in an environmental chamber at high-humidity conditions. Data are presented for various representative solids to show the reliability of the test methods for classifying the materials. A classification system is also proposed for use in government transportation regulations.

Jan 1, 1972

By J. L. Lamon, W. Crafts

P. Coheur and L. Habraken—We read this paper with great interest and are glad to congratulate the authors for their valuable work, supplying an important contribution to the mechanism of tempering on the carbides in vanadium steels. We are in a good position to appreciate this work since we have been studying, for more than a year, Cr-Mo steels of a composition similar, but less highly alloyed (namely 0.1 pct C, 3 pct Cr, 1 pct Mo). Our results are quite in concordance with the authors', however, we wish to point out that it is very interesting to use equally the electron microscope in order to observe the variations of microstructure in steels. We have studied simultaneouslv the evolution of the carbides in situ with the electron microscope, and, after extraction, again with the electron microscope, and then with X-rays. The first results which we have obtained have been communicated at the Congress of Delft (July 1949) and at the "Journbes de la Metallurgie" in Paris (October 1949). These may be summarized as follows: After tempering with varying either the tempering temperatures or the tempering times, the carbides show two evolutions. The first one is connected to the carbides existing in the steels, principally in the boundaries of the grains. For some groups of steels these carbides may coalesce and for other groups they may

Jan 1, 1951

By T Weldon

In the last 15 years, it has become increasingly popular to win gold and silver from carbon strip solutions with electrolytic æsludgeÆ cells. The precious metal sludges produced in the cells are washed to the cell bottom and pumped into filters. Most new operations are specifying sludging cells, and many older operations are being retrofitted with up-to-date electrolytic sludge cells and filters. The new sludging cells are generally more energy efficient than older cells, but more importantly, the cell operations to remove product are much less labour intensive, cleaner, and the operator need not have physical contact with the electrolytically produced metal. A case study of a major North American gold producer (50 000 kg/yr) that removed old style stainless steel wool cathode cells and installed new sludging cells and sludge filters is presented. The effect of various impurities is discussed.

Jan 1, 2005

By Enrique Zápata

"El presente trabajo describe la influencia de los nuevos métodos y herramientas en la ocurrencia de accidentes incapacitantes que se han registrado durante los últimos años en Milpo. Para ello, se considera las condiciones de terreno y la profundización de la mina, las estadísticas de accidentes capacitantes, la comparación de métodos y resultados, la síntesis comparativa de costo por método, las herramientas nuevas (raise borer, sistema de descarga), tecnología y la exposición al riesgo de accidentes, y la frecuencia lógica de ocurrencia de accidentes. En este sentido, el diseño de nuevas herramientas otorga a los operadores una ubicación panorámica y segura,comodidad y control de un panel de fácil manejo, reduciendo la frecuencia de la frecuencia de ocurrencia de accidentes incapacitantes y fatales."

Oct 6, 1999

By John L. Didlinger

We all hate the paper work in keeping accurate blasting records. Nevertheless, have you ever thought what those records could show you? Think about it. Those records could show you vibrations, noise, and safety problems. They could show you the ratio of powder used and tons produced, the cost per foot, even help negotiations for pricing.

Jan 1, 1997