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By Mário César Mantovani

Um dos principais problemas enfrentados pelas aciarias é o descarte dos resíduos gerados durante a produção do aço. Além de se pagar pelo descarte em aterros monitorados, ocorre também a perda de elementos de liga, tais como Cr, Ni, Mo, V, etc. O objetivo deste trabalho é estudar a viabilidade de se aglomerar alguns resíduos gerados durante a produção do aço (lama de VOD/VD, poeira de forno panela e carepa de forjaria) na forma de pelotas autorredutoras e adiciona-las ao forno elétrico a arco (FEA). Primeiramente os resíduos foram misturados com finos de coque de petróleo e cimento. Após a pelotização e o período de cura, as pelotas autorredutoras foram fundidas num forno de indução (teste laboratorial), visando avaliar o nível de recuperação dos elementos de liga a partir dos resíduos. O rendimento dos elementos Cr, Ni e Mo variaram de 84% a 99% nos teste laboratoriais. Nos testes industriais envolvendo as pelotas autorredutoras de carepa de forjaria (aço ferramenta H13), os rendimentos dos elementos Cr, Mo e V variaram de 51%-92%, 94%-99% e 27,5%-88%, respectivamente.

Jul 30, 2018

By Lj. D. Andric

By the micronization-milling of the material, the size and the structure of its particles are changed and it comes to the increasing of the potential energy of the system as well as to the chem-ical activity of the material what is the result of an increased free surface and of the concentration of the grate defects, that is of the internal energy of the system. All these changes that are reached, show that new characteristics of treated materials are got by micronization process. Controlling the process of the micronization and by purpose directing of the new characteristics of the activated materials, we can have the positive effects and use them in more technologies. Talc is important nonmetallic mineral raw material that is widely used as either the basic raw material, or as filler. This has stimulated its technological investigation, as well as the investigation of its physical-chemical characteristics. In this paper are shown experimentally reached results of the physical-chemical characteristics of the talc during the process of the micronization in high energetic mill. In this paper, the optimum conditions of miconization of talc in high-energy-speed rotary mill and its influence micronization on a degree of Fe2O3recovery by hydrometallurgical methodes, are presented. The X-ray analysis of the obtained products showed that high quality talc with low content of can be obtained by these physical-chemical processes In this paper, the principles and application or fine and ultra-fine grinding high-energy attriton mill with small balls, enabling fast, efficient grinding, low energy consumption, short grinding time and easy handling will be described.

Jan 1, 2014

By B. Qiu

The large surface ground movements induced by underground mining could threaten the safety of the pipelines laid across the subsidence-prone area. Existing analytical methods for the stress analysis of buried pipeline over mine subsidence area were based on the assumption of ?thin? pipeline, which limited their applicability. This paper presents the improved model with the capability to determine the stress distribution of the ?thick? pipeline. The pipe-soil interaction in this model was also updated to adapt various pipe soil contact conditions. In addition, the time-dependent effects of dynamic subsidence effects were also added to the model. A case of protecting a long section of a buried large-diameter pipeline over two longwall panels in a shallow mine is shown. The stress distribution along the pipeline is determined and the overstressed sections are identified. A partial uncovering plan was developed based on the predicted stress and complicated terrain at the site.

Aug 1, 2013

By P. Arz

With a total of five basement levels, ground floor and a further six levels above grade, construction of the Kö-Galerie building, on the Königsallee, in the centre of Düsseldorf, was completed with all the difficulties which accompany property development today in the inner city. To meet the intermediate and final deadlines, ad­vanced building techniques were used. Notable among them are the top/down method for simultaneous construction upwards and downwards from an intermediate level, and the use of pre-fabricated composite columns in drilled shafts for the main load-bearing foundations as well as diaphragm walls designed as permanent structural wall of the basement.

Jan 1, 1989

By B. Hosseini

Considering the subtractive trend of the sulfide and high-grade zinc ores in worldwide and also in Iran, Nowadays special attentions have been drawn to the extraction of zinc from its other resources such as low-grade oxide ores and secondary resources. Oxide ore of the eastern part of Mehdi-abad lead and zinc mine is silicate and has an average grade of 7% (with cut off grade of 4%). Main mineral of the Mehdi-abad ore is Hemimorphite and this mineral is associated with Goethite, Hematite, Ferrous Dolomite, and Manganese oxide mineral so that oxides of Iron, manganese and silica include almost 50% of the total ore. In this paper, the results obtained from the leaching kinetic study of the low-grade zinc oxide ore using Sulfuric acid are presented. The effects of particle size, reaction temperature, acid concentration, and solid percent on the dissolution rate have been investigated. The results obtained from the Taghochi approach showed that the zinc recovery is about 78% under the following optimized conditions: particle size: 106µm, leaching time: one hour, temperature: 45°C, acid concentration: 15% and solid percent: 15%. Kinetics study was revealed that zinc minerals leaching controlled by diffusion rate through the product layer during leaching time with the activation energy of 5 KJ/mol and compliance with the 1- (2/3. x) ? (1- x) 2/3 = k. t model. Keywords: leaching kinetics, kinetics models, sulfuric acid leaching, taguchi methods, low grade zinc ore, mehdi-abad mine

Sep 1, 2012

By Jing Zhan

The fibrous precursor can be obtained by coordination precipitation process, using oxalate, cobalt chloride and ammonia. The composition and morphology of fibrous precursor were characterized by XRD, IR, DTA/TGA and SEM analysis. The results show that XRD pattern and composition of the precursor with fibrous morphology precipitated at pH=9.0 were different from that of ß-CoC2O4?2H2O precipitated at pH=1.0. The mechanism on the thermal decomposition of fibrous precursor was addressed. The influences of various conditions in pyrolysis, including the temperature, time, atmosphere, and the morphology of the precursor, on the morphology, average size and specific surface area of the Co powders were investigated in detailed. At last, the final product, fibrous cobalt powders with diameter about 0.3~0.5µm in size and 40~60 in aspect ratio, were produced by thermal decomposition at 400~500? in the weak reducing atmosphere. The structure of pores in cobalt powders was capillary tube with open ports and the majority was mesoporous.

Jan 1, 2009

By J. de Korte, Z. Loubser

"SynopsisThe aim of a blending stockpile is to minimize the natural variation in properties of a material. Two simulation models were written, for coneshell and chevcon stacking, and used to investigate the influence of different stockpile parameters on blending efficiency. The coneshell model is used to show that blending efficiency is highly sensitive to stacked height, with lower output variances observed for higher capacities. Output variance in both models also decreased when the stacker movement increment was decreased. For chevcon stacking, increasing stacker speed significantly increases the blending efficiencies. Increasing the length of the blending tail also reduces output variation, but this parameter would need to be weighed against the accompanying decrease in buffer capacity.IntroductionEven in the most uniform deposit of materials in nature, material properties will vary. The degree of variation can be measured, and usually resembles a normal distribution. The aim of blending and homogenization operations is to minimize the standard deviation of this normal distribution (De Wet, 1994). In general, the reduction in variation will result in a more efficient and cost-effective downstream process. Cement plants need a precise blend of raw materials to ensure desired kiln performance; boilers used in power generation are optimized for fuels of a constant specification; and even though the separation density in a coal washing plant can be adjusted, a constant product quality cannot be produced from highly variable feed (Denny and Harper, 1962). The process efficiency, product quality, and environmental compliance depend on consistency of characteristics in the material fed (Kumral, 2005) Many industries involved in"

Jan 1, 2015

By I. Yutronic

Compañía Minera Doña Inés de Collahuasi's (CMDIC) Concentrator Plant is located at 4300 meters above sea level, approximately 2000 kms north from Santiago, Chile. The concentrator has three grinding lines. Each one, Lines 1 and 2, have one SAG mill at the primary grinding stage followed by a secondary grinding and classification stage consisting of one ball mill, two hydrocyclone batteries and a sump with two pumps. Line 3 has one SAG mill (Gearless Mill Drive), followed by a secondary grinding and classification consisting two ball mills, four hydrocyclone batteries and a sump with four pumps. Average throughput for these three lines is 150 Ktons per day. Peak values of 180 ktons per day have been achieved. Since late 2008 and throughout 2009 and 2010, Operations and Automation areas developed an optimization program for the grinding process, considering the implementation of Model Predictive Controllers (MPC) for the three SAG mills, and later, extending MPC to the secondary grinding and classification stages. The implementation of a MPC solution was based on stability considerations (high variability of the SAG process, high interaction between sump level control and classification efficiency, etc), requirements for an automated and consistent operation, the need to maximize throughput under timevarying scenarios and, in the long term, optimization of grinding process considering Specific Energy Consumption, among other parameters. MPC solutions had proven control robustness and strong optimizing capabilities in terms of helping in discovering new operational points and so achieving all of the aforementioned goals. On the first stage of the program, MPC implementation considered identification of dynamical process control models based mainly on historical data, in order to know the impact of a group of Manipulated Variables over Controlled Variables. Also, the impact of measured Disturbance Variables was modeled in order to take into account the high impact and interaction of these variables over the processes. At the end of this stage, 4 controllers were successfully operating for the 3 SAG mills and the secondary grinding and classification process. In response to challenges made by the working group, the second stage of the development of control applications in the grinding process required to achieve a design and implementation of a solution capable of governing the milling process, in addition to stabilization and optimization of both processes (SAG milling and secondary grinding), to integrate from a point of view of process control and automation. Therefore, in the second stage, MPC performance was continuously monitored and optimized through advanced tuning, inclusion of more process models (with proper step tests), redefinition of specific optimization criteria and adjustment to new process needs. Finally, successful MPC implementation at Collahuasi has proved that fast development and deployment of process control solutions is possible and allows immediate process stability, higher throughput, specific energy consumption reduction, and successful product size control, among many others.

Jan 1, 2012

By C. B. Espag de Klerk, J. de Goede, M. Le Roux, Q. P. Campbell

"Excessive amounts of moisture in product coal can influence the efficiency of downstream utilization processes due to a decreased calorific value and handling problems. Stockpiles can be used to decrease the moisture content of coal by means of gravity drainage and evaporation. This paper is focused on the evaporation of moisture from a coal stockpile surface with the aim of investigating the effect of particle size on the rate of evaporation as well as the depth to which evaporation extends.It was observed that moisture initially evaporates at a higher rate from a stockpile consisting of fine particles (-6.7 mm) than from coarser particles (-13.2 mm +6.7 mm). This high rate of evaporation is restricted to the outer shell of the fine coal stockpile. However, for coarse coal, the porous nature increases the depth at which evaporation occurs. Evaporation of moisture was observed up to the fourth day of each experimental run, after which steady state was obtained. It was shown the water can evaporate from the surface into the body of the stockpile, depending on the coal particle size and void spacing. An experimental reclaim depth of 0.4 m was achieved after 4 days. IntroductionCoal stockpiles serve as surge capacity for downstream utilization processes and can also be used for moisture reduction by means of gravity drainage and evaporation. Excessive amounts of moisture in coal can cause handling problems and, most importantly, will decrease the calorific value, leading to inefficient combustion.Research has shown that evaporation by means of wind and solar action is considerably more effective than gravity drainage(Williams, D.J. 2006), but the effect is limited to a restricted depth from the exterior of the stockpile (Boyapati, E. and Oates, A. 1994; CSEM-UAE, 2010). The effectiveness of wind and solar action can be improved by orienting the stockpile perpendicular to the predominant wind direction, maximizing the surface area of the pile, and reclaiming the coal from the pile gradually in shallow cuts over a large area (Williams, D.J. 2006)."

Jan 1, 2016

By N. Duru, C. Nesbitt

During the cyanide leaching process, gold and silver ores that come from the transition zones, which typically contains low levels of sulfide, may produce one or more of the following reduced sulfur species: sulfide ( HS−), polysulfides ( Sn 2−), thiocyanate ( SCN−), thiosulfate ( S2O3 2−), trithionate ( S3O6 2−), tetrathionate ( S4O6 2−), pentathionate ( S5O6 2−), hexathionate ( S6O6 2−). The actual speciation of the reduced sulfur species in the circuits will primarily depend on the redox potential, pH, cyanide levels, and existing sulfur species in recycled process water, as well as the presence of other reactive metal species. The development of an accurate analytical method for sulfur species in cyanide leaching units of gold ores where sulfur speciation occurs has an important role in explaining the metal recovery deviations. This study presents the speciation of sulfur species and the development of ion chromatography method to analyze reduced sulfur species thiocyanate ( SCN−), thiosulfate ( S2O3 2−), trithionate ( S3O6 2−), tetrathionate ( S4O6 2−) in cyanide leaching circuits for gold ores. The method developed has resulted in precise quantification of target sulfur species in leach solutions. Method development and validation results were illustrated on analytical graphs containing each species’ peak number, retention time (min), type, width (min), area (mAU*s), height (mAU), and area distribution (%) of the peak.

Mar 2, 2024

The accurate calculation of ore reserves is one of the most important functions under- taken at a potential or operating mine. In recent years there has been a trend towards recommending more and more complex techniques for the calculation of reserves. However these are not always necessary and many improvements could be made by the use of all potential data and a heavier geological input. An ore reserve should be the result of geological not mathe- matical or engineering reasoning. All ore reserve estimates are wrong and the important thing is to.recognise why they-are wrong and to take action to minimize the errors. Geostatistics and other complex mathematical techniques may appear to answer all our needs for ore reserve accuracy but there are many drawbacks, not least of which is the communi- cation gap which may develop between the operator and both management and production Personnel.

Jan 1, 1979

By Jacobs M

After a methane explosion in a coal mine a pre-determined crisis management procedure is instigated. As the process rapidly evolves the inevitable question arises - are personnel trapped underground, are they alive and can they be rescued without putting the lives of the rescue crew at risk? This is a very emotive question with many sub-questions such as; could anybody have survived, is there the potential for a secondary explosion and is there a `window of opportunity' before that secondary explosion occurs?To determine if that window of opportunity exists two fundamental elements must be in place; a method of determining the atmosphere at key points in the mine and a method of predicting the course of change of that atmosphere with respect to time. The first element can be achieved if the tube bundle system is intact and drawing samples from known points, alternatively boreholes can be drilled from the surface. The second element can be realised by utilising a sequence of computer generated control charts which have a time axis, a percentage combustibles axis, the upper and lower explosive limits of the current atmosphere and a prediction option which allows the user to look at the potential changes in the atmosphere over a set period of time. These control charts would be part of the mines on-going crisis management system rather than a tool to be used after an explosion had occurred.

Jan 1, 1998

By Ann M. Hagni

Microscopic and sub-microscopic gold commonly occurs in the sulfides pyrite (FeS2) and arsenopyrite (FeAsS). To recover refractory gold from pyrite and arsenopyrite, these sulfides are roasted to create porosity and permeability prior to cyanide leaching. A new technique of adding Ca(OH)2 and roasting. lime roasting. is being tested for retention of contaminant sulfur and arsenic and effectiveness of gold extraction. The lime roasting of pyrite at 500°C contains anhydrite (CaS04). oldhamite (CaS). calcium sulfite (CaS03). hematite (Fe2O:J), magnetite (Fe304). and minor amounts of pyrrhotite (Fe1.xS) and pyrite. At 600°C. 650°C and 700°C. the main constituents are anhydrite. oldhamite. and hematite. At 750°C. 800°C. and 850°C. anhydrite and hematite are the predominant phases with minor oldhamite. The roasted arsenopyrite at 450°C contains arsenic sulfides. calcium sulfite. hematite. and minor oldhamite. magnetite. and pyrrhotite. At 650°C. 700°C, 750°C. and 800°C, anhydrite, oldhamite. arsenic sulfides, and hematite are present. At 850°C. the same minerals are present with only minor oldhamite. The textures indicate excellent porosity and permeability at high temperatures. At lower temperatures, rims of low porosity and permeability surround many of the pyrite and arsenopyrite particles, and the complete oxidation process from pyrite to pyrrhotite to magnetite to hematite can be observed in individual particles. Additional process mineralogy techniques employed in this study are electron spectroscopy for chemical analysis (ESCA) and cathodoluminescence microscopy (CIM) in the determination of the calcium-sulfur-oxygen phases. Automated scanning electron microscopy-energy dispersive spectroscopy was utilized to analyze particles for gold content. Reflected light microscopy (RIM) revealed arsenopyrite and pyrite encapsulated in quartz particles of the gold-bearing concentrate, gold roast calcine, and cyanide leach residue.

Jan 1, 1991

By Mingfei He, Xianyang Qiu, Hongling Wang, Yude Gao, Qingbo Meng, Xiaoping Xu, Hao Bu, Guosheng Wang

"By the “HGMS-gravity separation-Flotation” combined technology, a Ta-Nb-Sn concentrates with the grades of Ta2O5 10.00%, Nb2O5 9.13% and Sn 42.62% at the recovery of 44.73% , 9.13% and 14.62% respectively , a Li concentrate with Li2O 3.11% at the recovery of 51.83% and a feldspar product are obtained. All the value elements are recovered. INTRODUCTION Tantalum and niobium widely used in electronics, atomic energy, aerospace and chemical industries with the advantages of high melting point, good ductility, low vapor pressure, strong corrosion resistance and high thermal conductivity are important strategic resources which occupy a special position in rare metals (Crockettand, 1993; GAO and Zou, 2004; LI and HUANG, 2012). China's tantalum and niobium resources are poor, and most of them are low grade, fine grain size, complex composition, and polymetallic associated with refractory mineral resources (GAO and Qiu,2013; Liang and Li, 2016). The Yifeng Lion Ore containing lithium and other rare metals (tantalum, niobium and tin) is an important lithium polymetallic deposit in China Jangxi province. While extensive previous studies have settled on the recovery of lithium minerals by flotation only for the extremely low grade of Ta, Nb and Sn. The regular gravity concentration is used, and the recovery of tantalum niobium is low. This paper sets out to investigate a combined flowsheet of “high gradient magnetic separation (HGMS),-gravity separation-flotation” to effectively comprehensively recover the Li, Ta, Nb, Sn and the feldspar resources in the Yifeng Lion Ore.ORE PROPERTIES Chemical analysis The run of mine comes from Jiangxi Yifeng Lion ore. The main elements of the ore chemical analysis results shows in Table 1. From Table 1, the grades of lithium and rubidium are relatively high, but the grades of tantalum and niobium are lower than the industrial grade; feldspar with high content of potassium and sodium and low content of iron can be used as high-quality ceramic raw materials."

Jan 1, 2018

By P. A. Roberts

A proposal for a modified in situ leaching method for extracting gold from oxidized gold ores using a non-cyanide lixiviant is described. A non-cyanide lixiviant is suggested because of the obvious concerns posed by injecting cyanide-bearing solutions into the subsurface. Oxidized gold ores were chosen as a focus because earlier research on the use of sodium thiosulfate as a lixiviant under anaerobic conditions indicated that the presence of pyrite led to rapid thiosulfate breakdown. A reconnaissance research program involving ore characterization and hydrometallurgical test work on samples from four Australian ore deposits and preliminary reactive transport modeling studies was carried out. This work showed that lixiviant-oxidant combinations of sodium thiosulfate and ferric EDTA and iodide and iodine are both capable of extracting high percentages of accessible gold from the selected samples in bottle roll tests under anaerobic conditions. The ore characterization and reactive transport studies suggested that both physical and chemical methods of permeability enhancement may be required to lift bulk permeability and the availability of gold for dissolution to sufficiently high levels to obtain adequate gold recoveries. Assuming that such methods prove to be both necessary and economically viable, the mining method would no longer be regarded as simple in situ leaching. Therefore, the term ?in-place leaching? has been adopted for the proposed gold extraction system.

Jan 1, 2010

By P. L. Sibrell

The U.S. Bureau of Mines has tested cyanide leaching for recovery of palladium (Pd) from spent petroleum processing catalysts. Three different catalyst samples were supplied by a spent-catalyst processor. These catalysts consisted of a zeolite base and contained 0.4 to 0.7 pct Pd. During alkaline cyanide leaching, the catalysts exhibited ion-exchange properties due to their zeolite matrices. Hydrogen ions were released from the zeolite in exchange for sodium ions in solution, resulting in a significant decrease in solution pH. This could present a safety hazard because of the potential for release of toxic hydrogen cyanide gas. A pretreatment step where the catalysts were contacted with a 1.0M sodium hydroxide solution was found to prevent the pH shift from occurring. Following the sodium hydroxide pretreatment, two stages of leaching at 160 °C with solution containing 1 pct sodium cyanide and 0.1[M] sodium hydroxide gave at least 75 and up to 95 pct Pd recovery. The Pd was quantitatively recovered from the leach solution by thermal decomposition in an autoclave at 250°C for 1 h. The Pd content of the precipitate was over 50 pct. Thermal decomposition also decreased the total cyanide content of the barren solution to less than 0.2 mg/L. The catalyst leach residues passed the Federal Toxicity Characteristic Leaching Procedure and the California Waste Extraction Test, indicating that landfill disposal of the leach residues would be acceptable.

Jan 1, 2010

By Y Peng, C Burns, Y Mu, R A. Lauten

In both laboratory flotation experiments and from analysing the composition of the lead concentrate at the Boliden Tara lead-zinc mine in Ireland, it has been found that F-250 may replace cyanide as a pyrite depressant. Replacement or reduction of the cyanide consumption is highly desirable from a safety perspective given the toxicity of cyanide. Scrutiny of results from the plant trial indicate that F-250 is less efficient as a cyanide depressant when the flotation feed contains high levels of pyrite. Statistical analysis of the results does not capture this trend, illustrating a need to collect more data at higher pyrite ore levels. A recent model proposed for biopolymer-induced pyrite depression is reviewed and discussed next to the suggested mechanism for pyrite depression via cyanide. Review of the interactions causing pyrite depression point to different manners in achieving depression. In light of the less efficient F-250 pyrite depression at high pyrite levels, it is speculated if the two depressants may act synergistically at high levels of pyrite in the feed. CITATION:Lauten, R A, Burns, C, Mu, Y and Peng, Y, 2018. Pyrite depression at Boliden Tara using F-250 – a biopolymer, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 385–392 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By Giulia M. B., Ferruccio Cribari, Alessandro Bertero, Eliano Romani, Roberto Sorge, Francesca Casini

"The use of Artificial Ground Freezing (AGF) to form earth support and seepage control barrier systems has had applications worldwide. These cover a variety of construction problems, including the formation of frozen earth walls to support deep excavations, structural underpinning for foundation improvement, and temporary control of ground water in construction processes. An application of AGF during construction of Line C of Rome underground is described in detail.The new line “C” of San Giovanni metro station was constructed adjacent to the existing line “A” of San Giovanni station; the new metro line “C” is deeper than line “A” and runs below the existing station. The underpass project envisages an Artificial Ground Freezing in order to create a structural and waterproof temporary cut-off suitable to the two new tunnels excavation, while keeping trains running in the safest possible condition. The excavation of tunnels under the water table, with a hydraulic head of over 10 m in not homogeneous soils having different mechanical properties and permeability and below existing sensitive structures, involves special ground freezing sequences and methods, as well as peculiar drilling systems and operations, such as TDDT (Trevi Directional Drilling Technology).Artifical Ground Freezing IntroductionNatural freezing occurs seasonally in many areas of the globe and can affect negatively the engineering performance of geotechnical structures; on the other hand, man-made freezing is a controllable process that can be used by civil engineers to stabilise temporarily the ground in order to support and/or exclude groundwater from an excavation until the final retaining and lining structures are constructed. Freezing and thawing of the pore fluid within soils involve complex thermal, hydraulic and mechanical processes that have significant mutual interactions. For example, phase changes of the pore fluid caused by temperature variations can modify the pore water pressure in the soil, which, in turn, can induce mechanical deformation. At the same time, any changes in the hydraulic and mechanical conditions affect the thermal processes by advection and changes of ice and water contents.An application of AGF which will be presented in the paper, refers to the construction works of Line C of Rome underground. In this case AGF was carried out to provide temporary support during excavation of the two Line C running tunnels directly underneath the existing S. Giovanni station of Line A, in the safest possible condition. In order to keep the trains of Line A operational during excavation, a temporary structure was installed and a real-time monitoring system was conceived in order to control the temperatures of the soil during freezing and the response of the structures of the existing station."

Jan 1, 2016

By B Wu, B W. Lei, B J. Duan

When a coalmine fire occurs, it is crucial to judge the developing trends inside the fire area by analysing the changes of gas concentration in order to formulate the proper rescue measures. At present, few researchers have focused on the relationship between the changing trend of gas product and basic characteristics of fire in the coal fire extinguishing process. To study the relationship of basic characteristics of coalmine fire during the extinguishing process, an experimental platform for coal combustion in a confined space was built, and gas production, flame image and coal temperature during the extinguishing process were monitored and analysed by an online continuous gas analysis instrument, camera and thermocouple. Research shows that during the burning phase of the coal sample in the confined space, the flame zone decreases gradually due to insufficient gas supply. The size of the flame zone fluctuates and shares a positive correlation with CO concentration, while sharing a negative correlation with O2 and CO2 concentrations. Then, in the extinguishing phase, the increasing rate of CO2 concentration and the decreasing rate of O2 concentration both decrease gradually, but CO concentration would rise for a period before it eventually decreases. Coal temperature continues to rise in the open flame stage and does not go down until the flame is extinguished.CITATION:Lei, B W, Wu, B and Duan, B J, 2015. Experimental study on extinguishing characteristics of coal fire in confined space, in Proceedings The Australian Mine Ventilation Conference, pp 279–284 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By Behzad Vaziri Hassas, Firat Karakas, Mehmet Celik, Onur Guven

Since dewatering is a costly process, removal of moisture from relatively fine size lignites is an important industrial problem. As the lignite gets finer, the presence of micropores and relatively low hydrophobic nature of lignite lead to trapping of large quantities of water in the coal matrix. Lignites used in power stations need to be dried to a certain degree of humidity before it is transferred to the combustion chamber. It is generally wise to dewater coal as much as possible by physical means before it is dried. However, dewatering cost in some cases may be prohibitive. Thus, sometimes removal of even little percent moisture may be of great help in such operations. Surfactants have been used to increase the efficiency of coal dewatering. It is crucial to select appropriate type and amount of surfactants in order to get higher efficiency. Since the hydrophobic characteristic of coals increases with increasing the coal rank, dewatering of bituminous and anthracite can be accomplished using low HLB surfactants (Oily), however, these surfactants are not efficient in the case of low rank coals like lignites and brown coals. It is suggested that adsorption of low HLB surfactants on high rank coals is governed by Acid-Base interactions rather than electrostatic and van der Waals forces. Since this characteristic in lignites is not strong enough, low HLB surfactants could not be effectively adsorbed on low rank coals to make surface more hydrophobic. In this paper, a special set-up has been designed to study the effect of high HLB surfactants on dewatering of fine lignite particles. It is shown that high HLB surfactants function more efficiently on low rank coals than low HLB ones.

Jan 1, 2014