Search Documents

By G. Upadhya

Considerable success has been achieved recently in modeling microstructural evolution during solidification of castings bthrough the coupling of macroscopic heat transfer with microscopic solidification kinetics models. However, a complete model for simulation of solidification in complex shaped castings involves: (i) the description of fluid flow, during and after mold filling, coupled with (ii) heat transfer to the mold and surroundings by use of a macro model, followed by (iii) a description of subsequent solidification of liquid metal by use of a micro model for solidification of the alloy under consideration. This paper describes the coupling of solidification kinetics model to a 3D, transient, fully coupled fluid flow and heat transfer model. Coupling between the macremicro models is achieved by using the latent heat method. Micro models for the eutectics of gray, white and ductile iron are discussed. This coupled code has been used for predicting the thermal history and microstructural data for shaped castings. Various applications of the model, including prediction of shrinkage defects, grain density contours, and graylwhite transition region in the casting, are presented for a relatively complex casting geometry.

Jan 1, 1992

By H. Kreye, E. Hornbogen

An increase in electrical resistivity during aging or after quenching from high temperatures is known in a large number of alloys. Plastic deformation of alloys in this condition leads to a decrease in resistivity. This anomaly has been called the K effect. This effect has been reported in Ni-A1 alloys by several authors.'-4 The nickel-rich solid solution y is in equilibrium with Ni,A1 (y') with CkAu structure. With this alloy it is therefore possible to produce a homogeneous solid solution as well as a coherent mixture of y and y. The changes in resistivity should be determined for these two conditions. In the present literature on the K effect no distinction is made between them, because of experimental difficulties to determine small coherent particles. In the present work transmission electron microscopy and image formation by (100) and (110) superlattice reflection of the y' phase was employed for a detailed determination of the temperature dependence of solubility of aluminum in nickel and the resulting microstructures with alloys up to 15 at. pct Al. The solubility line follows the equation indicating a smaller solubility than given in the literature at temperatures below 700°C. X-ray scattering was used to get evidence for short-range ordering in the homogeneous solid solutions.5 Parallel to the determination of the microstructure electrical resistivity was measured as a function of aging tempera- ture, time, and aluminum content, which led to the following results: 1) Resistivity increases slightly during aging of a homogeneous solid solution which was quenched from a high temperature as a consequence of short-range order, Fig. 1, curve c,. 2) Resistivity shows a maximum during aging of all alloys which are heterogeneous according to the phase diagram, but which were obtained as a supersaturated solid solution by quenching, Fig. 1, curve c,. The increase in resistivity is mainly due to coherent precipitation of y'. In Fig. 2 the effects due to short-range order pN and due to precipitation of particles APT are shown for an aging temperature of 450°C and different aluminum contents. 3) The increase in resistivity depends on the size !f the coherent particles. A critical diameter of 15 5A for the maximum was found for all alloys and aging treatments by extrapolating particle sizes determined by electron microscopy. 4) The maximum of resistivity of the heterogeneous conditions does not occur if particles, larger than the critical size, have formed already during quenching. 5) Plastic deformation destroys short-range order as well as small coherent particles. Therefore a decrease in resistivity is observed if the increase in resistivity caused originally by these phenomena is

Jan 1, 1967

By F. Twyman

PART I.-QUALITATIVE, SPECTRUM ANALYSIS THOSE chemists (they are still greatly in the minority) who use the spectroscope, use it very often, and find it almost indispensable. As a means of detecting minute quantities of the metals it is unrivalled. A metal can be readily distinguished in the presence of any other element, compound, or mixture without the necessity of separation. The qualitative analysis of the metallic constituents of a substance, which, the spectroscope gives so easily, is a sure basis for planning a chemical analysis. As the determination of each element proceeds the purity of precipitates maybe checked as often as desired. If, possessing these advantages; the spectroscope has been neglected in general chemistry, it is not surprising that it was neglected in metallurgical chemistry; for many of the impurities which are of industrial interest, even when they are present in a metal or alloy in small quantities, are not then always easily detected by the examination of their visible spectrum. The history of the development of the art has been given in Bureau of Standards Scientific Paper No. 444.

Jan 1, 1928

By F. H. Samuel, P. Burke, F. Mucciardi, J. Gruzleski, S. A. Musmar

A new thermal analysis technique has been developed and tested. It utilizes the enhancement in heat transfer characteristics associated with a recent advancement in heat pipe technology. Heat is extracted from a liquid sample of a melt taken in-situ within a vessel or furnace. The rate of heat extraction is such as to cause the sample to solidify. The technique was tested in both laboratory scale and industrial scale (Grenville Castings, Perth, Ontario). A 356 Al Alloy, subjected to various melt treatments was used to perform the tests. Classical thermal analysis was also performed simultaneously using a preheated graphite cup and at the same melt conditions. The comparison showed the potential of the new technique over classical thermal analysis. The major advantages of the new method are that it conducts the analysis inside the melt (i.e. a physical sample is not removed from the melt), it consumes less time and the cooling rate can be precisely controlled during the solidification process. Moreover, the resolution of the results is better than that of conventional techniques. Aluminium

Jan 1, 2006

By X. Cao, B. S. Naik, D. L. Chen, P. Wanjara

AZ31B-H24 Mg alloy sheets with a thickness of 2 mm were friction stir lap welded (FSLWed) at two tool rotational rates of 1000 and 1500 rpm and two welding speeds of 10 and 20 mm/s. The tensile behavior of the FSLWed AZ31B-H24 Mg alloy was then evaluated at low (-40°C), room (25°C), and high (180°C) temperatures. It was observed that the failure load increased with decreasing tool rotational rate and increasing welding speed. The maximum failure load occurred at a tool rotational speed of 1000 rpm and a welding speed of 20 mm/s at all temperatures tested. It was also noticed that at the high test temperature, the samples failed along the sheet interface, i.e. shear fracture. At the low and room temperatures, the samples failed on the advancing side (AS) of the top sheet near the interface between thermo-mechanically affected zone (TMAZ) and stir zone (SZ). The different modes of fracture observed are associated with the hooking defect.

Jan 1, 2014

By Patrick Tassot

Increased worldwide highly competition in steel market imposes innovative measure for the steelmaker targeting cost reduction and climate-friendly steelmaking process in order to have the ability to withstand the pressure of the market. At the same time the demand for high purity and highest quality steels continues to grow from year to year, especially in the sector automotive in transportation of oil and gas, in the construction Industry and in the manufacture of heavy plate. As they allow producers to be up to the requirements while allowing expanding their product mix, new secondary metallurgical treatments have become a must additionally to standard equipment elements of steel plants modern. Most of these treatments occurs in the steel ladle increasing the pressure to ensure a reliable and as possible neutral reactor. Intelligent solutions for refractory lining ladles should integrate better adaptation to the operational process parameters and the high reliability/availability at the best cost/performance. This challenge has conducted Refratechnik to develop new concepts to overcome the frontier between shaped and unshaped materials and that’s what will be covered in this paper.

Aug 17, 2017

By P. S. Arthur

The copper I SAS MELT? process is a submerged lance bath smelting technology. In the 20 years since the process was first demonstrated on a semicommercial scale at Mount Isa in north-west Queensland, Australia, copper ISASMELT? plants have been constructed to treat concentrates or secondary raw materials around the world. The process is operating in smelters in Australia, the USA, Belgium, India, Germany, China and Zambia. ISASMELT? plants have been installed to improve the environmental performance of operating smelters and reduce costs for smelting companies. A new copper furnace is being commissioned at Southern Peru Copper Corporation in early 2007, while more furnaces are under design for installation in Kazakhstan and Peru. Copper ISASMEL T? plants are supplied as complete technology packages including engineering design services for the furnace and key ancillaries, supply of core equipment, provision of intensive training programs in operating plant environments and commissioning assistance services. The proven technology transfer process ensures successful implementation of submerged lance bath smelting into large scale plants. This paper summarises developments at recently constructed copper ISASMELT? plants.

Jan 1, 2007

By J Hartnett, B Tarrant, A Rayner, D O’Toole, P Davies

Since 2009, the Northern Territory and Australian governments have been working under a national partnership arrangement to inform a rehabilitation plan for the former Rum Jungle uranium mine. Part of the rehabilitation strategy is to backfill a flooded former pit (Pit), which extends down to 100m below the current pit lake surface and was historically partially backfilled with uranium tailings. It is proposed to utilise the remaining pit volume below water level to sub-aqueously store Potentially Acid Forming (PAF-I) waste rock which currently occupies large stockpiles across the site. The rehabilitation design and planning process undertaken to develop a strategy commensurate to project objectives and construction constraints involved the establishment of key constraints derived from the analysis of historic data sources and preliminary design efforts. Tabled strategies were balanced against dependent project tasks and project objectives, especially surrounding minimising disturbance of highly contaminated materials within the Pit. Ideas were developed in conjunction with industry input and review of case histories to develop a remediation solution that is constructible within the project timeframe and constraints.

Jul 1, 2021

By T. Saksala

In this paper, the embedded discontinuity approach is applied to finite element modeling of rock fracture. A rate-dependent constitutive model based on the embedded displacement discontinuity theory is developed to describe the mode I, mode II and mixed mode fracture of rock in tension and compression. The bulk material is described as linear elastic until reaching the elastic limit. Beyond this limit, a ratedependent exponential softening law governs the evolution of the embedded displacement jump. The present approach incorporates the rock heterogeneity by random description of the mineral texture of rock. Moreover, the inherent initial microcrack populations of natural rocks are accounted for as randomly oriented embedded discontinuities. Numerical examples demonstrate the model behavior in uniaxial compression and tension. The effect of loading rate and confining pressure is tested as well in 2D numerical simulations. These simulations show that the model captures the main features of rock in confined compression and uniaxial tension. The developed method has the computational efficiency of continuum plasticity models. However, it has an important advantage of accounting for the orientation of introduced microcracks.

Jan 1, 2015

By E. Ghali, A. D. Bas

There is a lack of electrochemical studies of oxidized gold ores since the majority of previous studies were conducted with sulphidic gold ores. In this study, the influence of agitation and iron oxide minerals, i.e. magnetite, hematite, and maghemite on gold leaching was investigated by means of galvanic and passivation phenomena. Cyclic voltammetry studies of Roasted Gold Ore (RGO) in de-aerated electrolyte have shown one oxidation and one reduction reaction while three oxidation and one reduction peaks were observed with gold electrode. Galvanic coupling results by Zero Resistance Ammeter (ZRA) mode indicated that magnetite showed a negative effect on gold dissolution while maghemite and hematite showed a positive effect, relatively, as a result of higher galvanic corrosion rates. Generally, gold dissolution was found to increase in the initial 15 minutes. Increasing agitation speed from 100 to 400 rpm resulted in higher galvanic corrosion rates for RGO, magnetite, and maghemite electrodes, while 250 rpm was found to be optimum for hematite electrode. Passive products such as silver and iron-oxide were identified by XPS and SEM-EDS analysis, respectively.

Jan 1, 2015

By M. Afsari Nejad

A Transversely Elasto-Plastic Model was configured in FLAC (Fact Lagrangian Analysis of Continua) as a more realistic simulation of stratified and inclined strata behaviour examining surface subsidence above the inclined longwall panels (I ). The failure criterion employed was a modified Mohr-Coulomb failure criterion that assumed a variable cohesion, which changed with respect to the orientation of the plane of anisotropy . Using the proposed numerical modelling technique several longwall panels with different configurations were simulated. The results of both surface subsidence and horizontal displacements were validated against UK data using the Subsidence Engineer's Handbook (S.E.H) subsidence prediction method and the Influence Function Method (2). It was found from the research that the incite properties as well as laboratory to field reduction factors arc depth dependent. A set of relationships for calculation of anicotropic stiffness and strength parameters have been derived. The proposed modelling approach has been successfully applied to surface subsidence prediction for 3 collieries in the UK allowing the results of the simulation to he validated directly against measured data.

Jan 1, 1998

By R. E. Murray

"It is a gloomy moment in the history of our country. Not in the lifetime of most men has there been so much grave and deep apprehension; never has the future seemed so incalculable as at this time. The domestic economic situation is in chaos. Our dollar is weak throughout the world. Prices are so high as to be utterly impossible. The political cauldron seethes and bubbles with uncertainty. Russia hangs, as usual, like a cloud, dark and silent, upon the horizon. It is a solemn moment. Of our troubles, no man can see the end." By now you, no doubt, are asking, 'Where did Murray get this bit of philosophy?' Well, I obtained it from an editorial entitled. "The Worst of Times", which was published in the Harper's Magazine in 1847. That's right, 1847! The parallelism between the situation in our country at this time and in 1847 is un- canny. But wait, there is one major exception the size of government. To my knowledge, the citizens of 1847 were not stifled by the extreme governmental excesses that we are experiencing today.

Jan 1, 1980

By E. Legault-Seguin

The current industrial practice in the processing of nickeliferous laterites involves the precipitation and releaching of Ni and Co to allow separation from the major impurities of Mn, Mg and Ca. A direct solvent extraction process has significant advantages over this practice, which suffers from difficult and costly precipitation steps, lower recovery and inherently complex flowsheets. The present investigation involves the examination of Cyanex 272, Cyanex 301 and Cyanex 302 as extractants for the direct extraction of Ni and Co from major impurities associated with laterite leaching, i.e. Mn, Mg and Ca. For Co extraction, Cyanex 301 and Cyanex 302 are superior to Cyanex 272, because they are able to selectively separate Co from Mn, Mg and Ca. Cyanex 272 offers complete extraction of Co from Ni and Ca, but Mn and Mg pose difficulty. Ni can only be extracted selectively with Cyanex 301, thus another extractant selective for Ni, such as Versatic 10 or Cyanex 301, is needed to recover Ni if Cyanex 302 or Cyanex 272 is used for the initial extraction.

Jan 1, 2004

By C. C. Walden, D. W. Duncan, P. C. Trussell

Thiobacillus ferrooxidans released copper from -400-mesh chalcopyrite at a rate of 54 mg/I/hr. Any flotation chemicals remaining on the concentrate did not inhibit the leach rate. Zinc rougher tailings were also leachable. With bacteria, 75 per cent of the zinc and 68 per cent of the copper came into solution. In the sterile controls, only 16 per cent of the zinc and 10 per cent of the copper were released; 100 per cent of the copper and 36 per cent of the zinc were leached from pyrite cinders through the action of bacteria, and 17 per cent of the copper and 10 per cent of the zinc were solubilized in the sterile controls. Less than 0.027 per cent of ~he iron came into solution. The majority of the copper in a converter slag was acid-soluble, but a reverberatory slag responded to microbiological leaching. About 62 per cent of the copper came into solution, compared to 12 per cent in the sterile control. The various factors influencing the rate and extent of microbiological leaching are discussed.

Jan 1, 1966

By C. W. George, Bruce Chalmers

The authors enumerate the factors which appear, from their observations and practical experience of failure of aircraft components in Great Britain, to be responsible for causing a metal or alloy to fail by stress corrosion. The essential conditions for promoting failure by stress corrosion are: (I) tensile stress at the surface of the component, (either residual or applied), and (2) an attacking medium that may be a solution or a liquid metal. Particular attacking agents are effective only on certain metals. In all instances of stress-corrosion failure experienced, cracking of an intercrystalline form has occurred and examples of such failure in aluminum alloy, steel and copper alloys are described and illustrated. The relation between microstructure and stress corrosion is mentioned and methods of investigating the susceptibility to stress-corrosion failure of metallic materials are described. The precautions to be taken in selecting materials for particular aircraft components and the importance of adequate protection against chemical attack are considered. The authors have given a factual survey of stress corrosion and have made no attempt to advance any scientific explanation of the phenomenon.

Jan 1, 1945

By Ann M. Hagni

Electric arc furnace (EAF) dust from the secondary steel industry contains lead, cadmium, and chromium that causes it to be classified as a hazardous waste. Pyrometallurgical treatment of EAF dust is directed at recovering zinc and simultaneously rendering the dust non-hazardous. The mineralogy of the EAF dust is important in determining the occurrence and phase relationships of the zinc, lead, cadmium, and chromium contents. The principle phases in EAF dust as determined by reflected light microscopy, SEM-EDS, and XRD are solid solutions of the iron spinels (franklinite, magnetite, and jacobsite), zincite, hematite, and Ca-Fe-Si glass. Chromium is present in small amounts in solid solution in the spinels. Cyclone sizing of the minus 53 pm particles shows that more than 50% of this size fraction are less than 10 pm in diameter. The <I0 pm particles contain zinc as both franklinite in solid solution with magnetite and jacobsite, and zincite as determined by transmission electron microscopy and XRD. Auger electron spectroscopy did not detect coatings of volatile phases on the surfaces of EAF dust particles.

Jan 1, 1994

By S. Angioletti

This paper addresses strategic investment decisions when they are nested in a project development format where each project is implemented in phases and each phase is approved to move on to the next phase only if certain technical and economic requirements are met. This configuration is sometimes referred to as a ?Project Portfolio?. Mining companies maintain project portfolios in their exploration investment plan. This study proposes a procedure to best manage an exploration project portfolio including technical and economic uncertainties. The procedure may support decision makers in a simple and intuitive way, while maintaining the rigor and precision required by the rather large amount of financial resources typically called for by mining projects. The procedure was tested in a real case study of a gold mining company and its exploration projects portfolio. The procedure uses the following approaches: i) investment valuation methods under technical and market uncertainties based on Option Pricing Model, Real Option Theory and Option Space; ii) portfolio management and Stage Gate®1 method; iii) Monte Carlo simulation.

Jan 1, 2010

By David A. Newman

Strength and physical property testing of coal is conducted regularly by the Arch Mineral Corporation as part of reserve exploration. Pillar design and mine layout are the primary applications for the coal strength data. Distinct differences in pillar behavior were observed during longwall mining at a mine in Southeastern Kentucky. Horizontal and vertical variation in both triaxial and uniaxial compressive strength was observed within the four (4) benches of the Harlan seam. Similarly, geographical variations in coal strength were noted across the Harlan seam reserve. During the past three decades substantial research efforts have been focused upon coal pillar behavior and the refinement of pillar design methodologies. Ironically, little attention was directed to integrating the variability of coal strength into pillar design. The authors examine, through the presentation of case history data, i) typical industrial practice with respect to establishing a database of coal strength for use in pillar design and stability analysis, ii) approaches in which the observed variation in strength in the Harlan seam is integrated into pillar design and stability analyses, and to iii) propose standards for coal cube testing

Jan 1, 1993

By Wei Zhang, Jinhong Zhang

An atomic force microscopy (AFM) image analysis has been applied to study in situ the adsorption of hydroxamic acid collector, i.e., octanohydroxamic acid (OHA), on malachite in aqueous solutions. AFM images show that hydroxamic acid collector adsorbs strongly on malachite mainly in the form of insoluble copper hydroxamate complex. Increasing the collectors’ concentration and the adsorption time both increase the adsorption of hydroxamic collectors on malachite. Results from the attenuated total reflectance–Fourier transform infrared spectrometry (ATR-FTIR) also show that the collector adsorbs strongly onto malachite, with strong absorbance spectra being detected, and the ATR-FTIR results confirm those as obtained by AFM. This specific adsorption mechanism explains that a high selectivity with a moderate collectivity will be achieved with a hydroxamic acid collector for the flotation of malachite. The findings of present study also show that AFM image analysis is a powerful tool for the study of the hydroxamic acid collectors’ adsorption on malachite surface and it can help with the development of novel collectors for malachite flotation.

Feb 1, 2025

By Russell G. Hood

Rock bolting or anchoring are methods of stabilization which are not being fully utilized in California and probably in other parts of the world due to lack of understanding of the principles, or due to poor results in actual installation. The problem is greater in California because so much of the rock is either soft or badly fractured and broken. Almost any recognized type of rock bolt or anchor will perform successfully is hard, fresh rock, but the problems become many-fold when working in decomposed granites, shales, soft sandstones or other soft, highly-broken rock. There has been an enormous amount of research by manufacturers, consultants, private organizations, and governmental agencies on rock bolting. It would be impossible to discuss all the methods and philosophies of rock bolting in this paper. Therefore, with the indulgence of the experts, I will give only a very generalized coverage on rock bolting techniques. However, My main purpose is to point out some of the problems of rock bolting in soft rock.

Jan 1, 1967