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By Edwaldo Ferreira Brandão

Os aços avançados de alta resistência (Advanced High Strength Steels - AHSS) vêm sendo uma solução atrativa na construção de estruturas automotivas mais leves e seguras, pois combinam alta resistência e boa conformabilidade. Neste trabalho, foram realizadas simulações numéricas e experimentos em escala industrial, com aços fornecidos pela Usiminas, da estampagem de uma travessa dianteira de suspensão automotiva. O objetivo desses experimentos foi avaliar a estampabilidade deste componente, que atualmente é fabricado com o aço de alta resistência baixa liga (HSLA340, 2,0 mm), quando substituído pelos aços Dual Phase (DP600, 1,6 e 1,8 mm) e Transformation Induced Plasticity (TRIP700, 1,6 mm). As simulações numéricas reproduziram o padrão de deformação destes materiais durante os processos de conformação e o perfil geométrico do componente. A travessa de suspensão automotiva foi estampada com sucesso com os AHSS propostos.

Aug 16, 2017

By Iván Salas

Los bofedales (humedales altoandinos) son considerados ecosistemas frágiles, con características y recursos singulares, con baja resiliencia ante eventos naturales y presión antropogénica los cuales producen una profunda alteración en su estructura, composición y funciones, estas características hacen que la protección de estos ecosistemas sea legislada a nivel nacional e internacional. Hudbay Perú viene ejecutando el Plan de Manejo de Bofedales como parte de su compromiso de compensación ambiental el cual tiene como objetivo mejorar las condiciones del ecosistema del Bofedal de Cochapampa ubicado en territorio de la comunidad campesina de Chilloroya a 4300 m.s.n.m (comunidad de influencia directa de la Unidad Minera Constancia).

Sep 30, 2022

By Mei Long, Tawum Juvert Mbah, Jianhua Zhang, Haiwang Ye

There have been many improvements and advancements in the application of neural networks in the mining industry. In this study, two advanced deep learning neural networks called recurrent neural network (RNN) and autoregressive integrated moving average (ARIMA) were implemented in the simulation and prediction of limestone price variation. The RNN uses long shortterm memory layers (LSTM), dropout regularization, activation functions, mean square error (MSE), and the Adam optimizer to simulate the predictions. The LSTM stores previous data over time and uses it in simulating future prices based on defined parameters and algorithms. The ARIMA model is a statistical method that captures different time series based on the level, trend, and seasonality of the data. The auto ARIMA function searches for the best parameters that fit the model. Different layers and parameters are added to the model to simulate the price prediction. The performance of both network models is remarkable in terms of trend variability and factors affecting limestone price. The ARIMA model has an accuracy of 95.7% while RNN has an accuracy of 91.8%. This shows that the ARIMA model outperforms the RNN model. In addition, the time required to train the ARIMA is than that of the RNN. Predicting limestone prices may help both investors and industries in making economical and technical decisions, for example, when to invest, buy, sell, increase, and decrease production.

Jan 6, 2021

By Peter R. Drummond

THE final casting of refined copper has been re-J- stricted for generations by the following sequence of operations: Filling the reverberatory furnace, melting, skimming, blowing or flapping, and poling. The hoped-for 24 hr cycle, producing 300 tons or more, has been taken up largely with the necessary bat time-consuming tasks of cleaning the bath, sulphur elimination, and in turn removal of excess oxygen to produce tough-pitch copper. Incidental to comparatively slow melting under combustion gases, copper oxides react with the furnace lining, and the slag so-formed must be completely recycled. The three-phase arc furnace has eliminated some of the cycle stages, and telescoped the remainder into a continuous operation. Electrical energy, supplied to graphite electrodes enclosed in high grade refractories, rapidly melts copper cathodes and sustains a stream of metal, containing approximately 0.01 pct oxygen, without contamination from fuel. The arc was struck on the first large electric furnace for melting copper in the United States on April 13, 1949. The earliest use of this type of furnace was at Copper Cliff, Ont., in 1936, and an admirable description of their installation has been published? Copper, melted in the Baltimore furnace, is used to cast billets, and the installation differs somewhat from the Canadian, as will be described. The arc furnace is a heavy-duty, three-phase furnace, holding 50 tons, the general outline of which appears on Fig. 1. The steel shell is 15 ft ID with a bottom radius of 14 ft 2 in. The roof, separate and distinct from the body, consists of a 15-ft water-cooled, cast-steel ring of the same outside diameter as the furnace. The center line of the furnace lies 9 ft 6 in. from that of the trunnions, permitting a 5" backward tilt for skimming, and a 40" maximum nose tilt forward for complete draining. Normally, the furnace overflows by displacement, and the use of the forward tilt arrangement is restricted to covering charging delays. The charging slot, 3 ft 8 in. x 5 in., lies on the north center line, the tap hole on the south, and the 30x30 in. skim door 45" to the west of the slot. The original 20-in. graphite electrodes were replaced with 14 in. in December 1949. Three conventional direct current winch drives, governed by electrical controls, position each electrode which has individual mast supports and counterweights. An independent circulation supplies cooling water for the electrode glands, the roof ring, charge slot, and the skim door frame. Arc Furnace Refractories Hearth: Fused-in monolithic bottoms had been used in copper arc furnaces, installed prior to April 1949. These consisted of thin layers of periclase, successively fused in place over preliminary brick courses. Heat was obtained from the arc, using a T-like arrangement of broken electrodes resting directly on the periclase to be fused. The operation, taking weeks to perform, was very expensive. The chemically-bonded magnesite-brick bottom, installed at Baltimore, was the first of its kind and a radical departure from previous practice. It consists of a 1 to 6-in. layer of castable refractory laid on the steel shell, modifying it to a 12 ft 2 in. bottom radius. Two courses of 9x2 % -in. fireclay straights and keys follow. The third course is made of 9-in. magnesite blocks of special shape to form circles of an inverted arch. It was started by a four piece keystone with skew-backs forming the outer course. The fourth course also started on a central keystone, or button, of four 90" segments, 12 in. diam x 13 Vz in. deep, and continued with 13%-in. blocks. Skewbacks at the shell completed the course to produce a horizontal surface for the side walls with a single course of No. 2 arch fireclay against the steel. Dry chrome-magnesite cement was brushed over each course after laying, and a 1-in. expansion space between the brick and the shell was filled with the same mixture. The total bottom thickness, excluding the castable material, was 5 in. of clay plus 22% in. of chemically-bonded magnesite. Tap Hole: A 5-in. OD and 3-in. ID silicon-carbide tube constitutes the tap hole and is set tangential to the upper course of the furnace bottom. Molten metal fills the tube when the furnace is level and filled to capacity. Side Walls: The lining, against the shell, consists of a 9x4Y2x3 in. soldier course of fireclay, using straights and No. 1 arches to turn the circles. A second soldier course of 9x4'/2x2'/2-in. fireclay was laid in a somewhat similar fashion. Three courses of 13Y2x6x3 in. and 9x6~3 in. of final magnesite, laid flat, completed the lining, using Nos. 1 and 2 keys to turn the circles. Cardboard spacers were placed between every two bricks in horizontal courses, and a thin coat of chrome-magnesite cement filled the joints between the firebrick and magnesite. A sprung-arch spanned the skim door with jambs of suitable magnesite shapes. Charge Slot: The slot is 3 ft 8 in. wide x 5 in. high. A silicon-carbide sill of special shapes has a 30" slope to allow cathodes to slide easily into the bath. The original arch was flat, and composed of Nos. 1 and 2 wedge magnesite with a 6-ft radius. It projected 5 in. over the sill, and, being a flat arch, gave an 18 15/16-in. opening between the inner edge and the metal line. The whole assembly was later raised 9 in., and the flat arch replaced with an arch, the lower edge of which maintained the 5-in, width from the outer to inner edges as shown in Fig. 2. A water-cooled, cast-copper jacket protects the steel shell behind the slot.

Jan 1, 1952

By Broggi Andrea

Condensates produced by SiO(g) and CO(g) have a crucial importance in silicon production. Condensation will follow the reactions 3 SiOðgÞ+COðgÞ→ 2 SiO2 + SiC and 2 SiO ðgÞ→Si+SiO2. Solid compounds generated during silicon production contain Si, SiO2 and SiC in different microstructures and amounts. In industrial systems, condensates limit the SiO(g) escape to the off-gas system. On the other hand, they can block the gas flowing from the high temperature zone, hence the necessity of studying an optimized condensation process. This review discusses SiO(g) condensation and its interaction with CO(g). The report gives an overview of the condensates found both at laboratory and at industrial scale. The two main compounds are the Si–SiO2 and the SiOx–SiC mixtures. The hypothesis on the mechanism of formation of SiC–SiOx condensates is presented through a wide selection of performed works. The advantages and disadvantages of the former experimental procedures are discussed.

By R N. Lamb, A N. Buckley

Experiments have been carried out to establish whether time-of-flight secondary ion mass spectrometry (ToF-SIMS) is able to differentiate monolayer and multilayer coverage of thiol collectors on sulfide minerals. The systems investigated were those for which x-ray photoelectron spectroscopy is able to provide an independent determination of the extent of coverage, and included diethyldithiophosphate (DTP) and 2-mercaptobenzothiazole (MBT) on chalcocite, DTP on Ag2+MS prepared by sulfidising metallic silver, and isobutyl xanthate (BX) and MBT on galena. For monolayer adsorption of MBT on chalcocite, peaks from MBTû but not Cu(MBT)û ions were evident. For multilayer coverage, Cu(MBT)2û ions were clearly present, notwithstanding the fact that other data had identified the principal multilayer species as Cu(MBT). For adsorbed DTP on copper and silver sulfides, DTPû and metal(DTP)Hû peaks were observed for monolayer and multilayer coverage. Although the multilayer species was expected to be predominantly metal(DTP), metal(DTP)2û ions were evident for multilayer (but not monolayer) coverage. For the PbS/BX system, intact Pb(BX)2 or Pb(OH)BX ions were not detected for multilayer coverage, although Pb-containing ions heavier than PbBX were. Indeed, for all the systems studied, ToF-SIMS was able to differentiate monolayer from multilayer coverage. In general, however, the SIMS evidence alone might not be sufficiently definitive to effect the differentiation. In the case of collector adsorption on copper and silver sulfides, if the multilayer species detected had been the metal monothiolate only, and had not involved the formation of some metal dithiolate, then ToF-SIMS might not have been able to provide an unequivocal differentiation of the two coverage conditions.

Jan 1, 2005

By M I. Pownceby, A Guiraud, S Purohit

Sticking and breakage of iron ore pellets during high temperature reduction can result in several operational challenges during shaft furnace ironmaking. With the shift to H2-based DRI processes and decreasing iron ore quality, this issue becomes more prominent. It is therefore important to understand how the iron ore chemistry and mineralogy affects the sticking and breakage of pellets inside the shaft furnace. This study provides a review of the mechanisms that lead to sticking and breakage of pellets inside the shaft furnace. The sticking index of pellets is related to the rate of metallic iron production as well as the precipitation morphology of product iron. Sticking of pellets is also enhanced by the formation of low-melting slag phases. The breakage of pellets inside the shaft furnace is often associated with the mechanical load of burden and pellet swelling, which is caused due to iron whisker or protruded iron formation. This paper investigates how the composition of iron ore, particularly the presence of different impurity oxides such as SiO2, Al2O3, MgO, CaO and alkali oxides in the pellets, influences the sticking and swelling indices. The effect of ore mineralogy on these adverse behaviours is also discussed.

Sep 18, 2023

By L. V. Bell

THE object in prospecting is to find ore. With the exception of certain discoveries of more or less accidental nature, intelligent prospecting as conducted today is, whether consciously or not, based upon a process of elimination. In the following discuss on it is proposed to evaluate those factors that enter into the eliminating of certain tracts of ground and, conyersely, the concentrating of attention upon others. The danger of generalizations as to the barrenness of cer.ain areas, without having due regard for all such factors, is emphasized. The fact that our conception as to what areas or rock formations are to be regarded as favourable or unfavourable is, in some measure at least, changing with new discoveries under diverse and unexpected circumstances, adds more point to the discussion. The criticism might be raised that the subject is treated largely from the standpoint of geology, but that may be met by stating that it is, and must continue to remain, precisely from this standpoint that the prospecror directs his activities. Briefly, the geologist may render the greatest service to the prospector in the early steps of selecting (a) the general territory in which to prospect; (b) the area to be intensively prospected; and, finally, (c) those parts of the claim or claims to be prospected in detail. Although certain phases of the discussion will be, in some measure, of general application, we shall here concern ourselves essentially with prospecting in the pre-Cambrian shield. Furthermore, the subject is so large that it has been decided to limit it to a consideration of that portion of the pre-Cambrian rocks in which is situated the mining district of western Quebec, of which the writer can speak with more personal knowledge. This limitation need not, however, seriously detract from whatever merit the discussion may possess, since the deposits concerned cover a fairly wide range of metallic ores, including gold, copper with associated zinc, and, lastly, molybdenum.

Jan 1, 1936

By Jürgen. F. Brune, CLAIRE STREBINGER, ADITYA JUGANDA, Gregory E. Bogin Jr

The abstract highlights the risk of methane gas explosions in underground coal mines and the potential of computational fluid dynamics (CFD) modeling to simulate such events and assess their impact on mine ventilation. The study focuses on developing CFD models for large-scale explosions in longwall mines, specifically simulating methane gas explosions resulting from face ignition during coal cutting. The research demonstrates the integration of a combustion model into a longwall mine ventilation model and shows how the availability of explosive gas mixtures significantly affects flame propagation and explosion pressure.

Mar 27, 2022

Adsorption of guar gum was investigated on model minerals typically found in water-insoluble slimes of potash ores. The ionic strength of the adsorption mixtures was varied from distilled water to saturated NaC1 and KC1. The tests were also performed using a saturated brine. The adsorption density of guar gum on illite, dolomite, and kaolinite was found to be not only a function of total ionic strength but also of the type of electrolyte present in solution. Generally, the adsorption of the polymer on the clay minerals was higher in KC1 solutions than in NaCI, but the differences gradually disappeared when the electrolyte concentration approached saturation. The results were analyzed in terms of chaotropic (K ) or kosmotropic (Na') properties of background counter-ions and their different behaviors at the hydrated mineral-water interface. Guar gum adsorption on dolomite was related to the presence of calcium and magnesium sites on the mineral surface, and to the cis-configuration of OH groups of mannose units. Based on viscosity measurements, it was suggested that guar gum macromolecules form entanglements in NaCI solutions (and distilled water), but individual molecules exist in KC1 solutions thus creating different modes of adsorption of guar gum from concentrated NaCl and KCl solutions.

Jan 1, 2006

By B. T. Lusk, Q. Q. Huang, R. Q. Honaker, K. A. Perry

Rock dust is applied in underground coal mines to prevent the propagation of coal dust explosions. It is applied either dry or wet. Both methods have advantages and disadvantages, but the formation of caked rock dust particles is cited as a significant concern for wet applications. We conducted a study to evaluate the effect of modifying the rock dust particle surfaces to repel water and each other by the addition of oleic acid and sodium oleate. At a sodium oleate dosage of 1 kg/t, a contact angle of 112o was measured, indicating strong surface hydrophobicity and thus the ability to repel water. Fourier transform infrared spectroscopy (FTIR) studies indicated a chemisorption mechanism, which is necessary for long-term stability of the surface modification. The dispersibility of the modified rock dust samples was elevated by the application of both oleic acid and sodium oleate, thereby indicating a significant reduction or elimination of the detrimental effect of caking. Tests in an explosion chamber showed an 82.8 percent reduction in the dust explosion potential relative to untreated rock test applied by the wet technique.

Jan 1, 2015

By Thomas Pallua, William C. Gates

"Two major railroad companies have identified several segments along the railroad corridor betweenTehachapi and Bakersfield, Kern County in California that require construction of a second track to improve operations in this area. The total project proposes an upgrade of five segments along the Tehachapi-Bakersfield route. The authors focused on two segments: Walong to Marcel and Cliff Siding Extension. The second track project comprised design of a through-cut adjacent to an existing tunnel and up to 120-feet-high (36m) side-hill cuts (both in granitic rock). The authors characterized the geologic ground conditions and ground behavior, including rock mass quality and strength using a combination of rock core drilling and rock slope mapping. The rock mass is generally characterized as granitic tonalite with strong core stones surrounded by a matrix of decomposed granite (DG)."

Jan 1, 2017

By Tuula Mäkinen, Lauri Pesonen, Peter Björklund, Jouni Pihlasalo, Mikko Korpi

Outotec Direct Blister Flash Smelting technology has proved to be an efficient and environmentally friendly way to treat copper concentrates from the Zambian Copperbelt at Konkola Copper Mines' (KCM) Nchanga smelter in Zambia. The modeling of slag chemistry and thermodynamics with MTDATA software played a central role in deciding the operation parameters for the smelter. Outotec FSF Online Process Advisor is used to calculate the process parameters and to give valuable information of the process state for the operating personnel. The pre-calculated slag liquidus graphs are also integrated to the Online Advisor.

Jan 1, 2011

By J. D. Miller, C. L. Lin

"The use of 3D X-ray tomography analysis for plant-site characterization of coarse particles at a sampling rate of about 3 kg/min for particles ranging in size from 150 mm to 1 mm at a voxel resolution of about 150 µm is now possible. This is quite a significant advance in X-ray tomography technology and promises to be useful for plant-site coarse particle characterization—size, shape, composition, density, texture, grain exposure and mineral liberation—with a response time of minutes after receiving the sample. This paper discusses applications in the mineral industries, including the coal industry, aggregates industry, metal mining and the processing of industrial minerals.IntroductionPlant-site characterization of coarse particles at coal preparation plants, crushed stone/aggregate plants and mineral processing plants is needed to improve plant capacity, product quality and/or process efficiency. Not much online coarse particle characterization is being done at these plants. Only some limited information regarding particle size is obtained online from reflected light images using analyzers such as the OPSA, Split and WipFrag™ analyzers. Even the laboratory analysis of coarse particles has been difficult because of the large amount of sample required to ensure statistical significance of the results. During the past several decades, laboratory 3D characterization of particles from energy and mineral resources by X-ray tomography has been demonstrated and used to good advantage (Miller and Lin, 2004, 2009).Three-dimensional X-ray tomographic analysis has its origins in the medical services industry, where it is used to provide internal images of the human body. It has since been developed for nonmedical applications as well (Banholzer et al., 1987). Figure 1 shows a schematic diagram of the cone-beam geometry micro-CT system. In our case, X-rays from a microfocus X-ray generator are partially attenuated by the sample (a packed bed of particles) that is made to rotate in equal steps in a full circle about a single axis of the particle sample. At each rotational position, the surviving X-ray photons are detected by a planar two-dimensional array (image intensifier) large enough to contain the shadow of the specimen. These two-dimensional projection images are collected using conventional video technology. The video signal for each projection is then converted to a two-dimensional digital array by an image processing system. Finally, a threedimensional image is reconstructed from the collected set of projection images."

Jan 1, 2016

By Felipe Costa Broseghini

O objetivo deste trabalho é estudar a influência das fases sólidas e líquidas formadas na desfosforação de ferro gusa. As escórias foram feitas a bases de Cal, resíduo de mármore e carepa. Neste trabalho também foi investigada a utilização de fluorita e barrilha nas escórias produzidas, objetivando avaliar as melhores condições para o processo de desfosforação de ferro-gusa. Experimentos em escala laboratorial foram realizados com a adição das misturas desfosforantes iniciais, na forma in natura, a temperatura de 1.400ºC e de composição química conhecida. Para efeitos comparativos das adições, os experimentos foram realizados com agitação mecânica. Foram utilizados cadinhos de MgO para a fusão do ferro-gusa. Amostras do ferro-gusa foram retiradas em intervalos apropriados, para o monitoramento de sua composição química e, após o tratamento, foram obtidas amostras da escória final, sendo comparadas as composições finais as iniciais. Os resultados foram comparados com vista na análise da eficiência das escórias e no processo de desfosforação, com o uso dos programas ThermoCalc e FactSage.

Jul 30, 2018

By Paolo Cavalcoli, Federico Pagliacci

"As opposed to the static functional recovery of existing structures, the construction of infrastructures in an urban environment, when combined with complex geological situations, often involves building foundation structures, whether circular or rectangular in section, through rock formations or chaotic strata (sand and gravel with cobbles). Until a few years ago, these formations or strata were sometimes an insurmountable constraint on traditional foundation installation techniques. The difficulty in overcoming these geological situations is sometimes added to the increasingly frequent need to reach depths that were unimaginable just a decade ago. These are real challenges for those carrying out these works and for those manufacturing the necessary equipment. There are two main methodological approaches to these problems, that can be summed up in the rhetorical figure of ""David and Goliath"": cunning versus force. In reference to the case studies in this article: the permanent retaining walls for the Copenhagen Metro, and the structural repairs to the Arapuni Dam in New Zealand and the Wolf Creek Dam in the U.S., we will describe the foundations constructed in presence of rock using combined small-diameter direction drilling solutions, associated with their enlargement up to the project’s size, at depths exceeding 300 feet. Finally, a case study will be presented on the implementation of a large cross-section of an excavation in the rock, at depths greater than 800 feet.IntroductionAs opposed to the functional recovery of existing structures, the construction of infrastructures in an urban environment, when combined with complex geological situations, often involves building foundation structures, whether circular or rectangular in section, through rock formations or chaotic strata (sand and gravel with cobbles).Until a few years ago, these formations or strata were sometimes an insurmountable constraint on traditional foundation installation techniques. The difficulty in overcoming these geological situations is sometimes added to the increasingly frequent need to reach depths that were unimaginable just a decade ago.These are real challenges for those building these works and for those manufacturing the necessary equipment. There are two main methodological approaches to these problems, that can be summed up in the biblical figures of ""David and Goliath"": cunning versus force. In the engineering field, the force is summarized in the use of ever-larger drilling equipment in terms of installed power, weight in working conditions, winch and rotary capacity."

Jan 1, 2015

By Aloísio Simões Ribeiro

Para a preservação e extensão da campanha do Alto-Forno é de fundamental importância o monitoramento, controle e estabilização da temperatura de pontos quentes na parede do cadinho do forno, possíveis de serem gerados durante a sua campanha operacional. Já são bem conhecidas diversas práticas operacionais para controle dos pontos quentes sendo que, uma das mais usuais, é o uso na carga do forno ou injeção via ventaneiras de fontes de óxido de titânio para formar, junto à parede do cadinho, uma camada protetora composta por carbonitreto de titânio. Neste trabalho será apresentado o desenvolvimento de uma nova concepção de massa de tamponamento contendo dióxido de titânio sintético, para auxiliar em problemas de pontos quentes em regiões do cadinho próximas aos furos de corrida.

Aug 16, 2017

By Onuralp Yucel, Ahmet Turan, Murat Alkan, Hasan Ozer

SHS (Self-propagating High-temperature Synthesis) is one of the important methods to synthesize B4C powders. The process contains the reaction of boron oxide powders (B2O3) with magnesium reducing agent and carbon black carburizer. SHS products are leached in HCl media to purify synthesized B4C powders in the following step. In the present study, effects of various functional additives (KClO3, KHSO4, MgSO4.7H2O, NaCl, MgO and Na2SO4) in the SHS stage were carried out. Various proportions of the additives were mixed with the initial SHS charge mixtures. Two different molar ratios were employed in the initial SHS mixtures as 1:3:0.8 B2O3:Mg:C and 1:2.5:0.8 B2O3:Mg:C. After the SHS step, HCl leaching process was applied to the SHS products. Filter cakes were dried and characterized by using X-Ray Diffraction Spectroscopy, BET and chemical analysis techniques.

Jan 1, 2015

By Thomas N. Walthier

This paper will review world trends that are increasingly restrictive of mineral exploration and mining throughout the Free World This is occurring in the face of projected huge increases in demand for mineral products Some of the impediments are direct and absolute; others are indirect, but nevertheless effective; still others represent merely hostile attitudes Many of the world governments have a reputation for lack of integrity in dealing with existing foreign investments within their borders, and consequently are quite uninviting places for new investments, especially in the capital intensive natural resources industry. Compared with even 35 odd years ago (and pre-World War II is not that long ago) there are few places left where private mining investments are both wanted and where investors are willing, to go. We shall begin with an analysis of conditions in the U. S., shift to neighboring Canada and Flexico, and then have a look around the world. As the world grows smaller for the private mining sector, the function of exploration, development, and operation is passing over to government. We'll conclude with a view of what this holds for the future

Jan 1, 1976

By R. Hogg, S. Chander

"INTRODUCTION The behavior of particulate systems in general is determined by the properties of the solid and fluid phases and of the interfaces between them. As particle size is reduced, the inter facial effects become increasingly important until, in colloidal systems, they become completely dominant. Interfacial phenomena are especially important in coal processing for a variety of reasons. Because coal is naturally hydrophobic and its density is low, surface forces begin to dominate over gravity at relatively coarse sizes. Coal is thermodynamically unstable in the presence of air, so that surface oxidation occurs readily leading to important variations in surface properties with time and environment. These effects are further compounded by the inherent heterogeneity of the material.Surface characteristics and properties play a significant role in most aspects of coal processing. Comminution, for example, is a process of creating new surface, while agglomeration involves the reduction of surface area and is usually controlled by surface forces. Both solid-solid and solid-liquid separations are influenced by interracial phenomena, Gravity separations are usually performed in a liquid phase and are affected by the wetting characteristics of the various solids present and by the need to ensure proper dispersion of the individual particles. Froth notation, of course, separates particles on the basis of differences in surface characteristics. Chemical processes such as leaching generally involve interfacial reactions whose rates depend on surface area and may be influenced by electrochemical effects in the electrical double layer at the solid-liquid interface, or by adsorption of reactant and/or product species from solution. Solid-liquid separations and associated processes such as flocculation are strongly dependent on the nature and properties of the solid-liquid interface.In characterizing solid surfaces, it is important to consider first the surface area, since this determines the relative importance of the interfacial effects. The structure and chemical composition of the surface may depend on the distribution of different petrographic constituents and impurities such as finely disseminated mineral matter, on the extent of surface oxidation, and on adsorption from the environment. These, in turn, will generally determine the surface properties which define particle behavior. Since the relationships between structure etc. , and properties are not generally known, it is usually necessary to measure properties such as wettability and electrical charge directly."

Jan 1, 1989