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By G. S. Hume

THE discovery of natural gas with naphtha in 1924 in the Upper Palaeozoic limestone of Turner Valley, 35 miles southwest of Calgary, has led to continuous developments in this field. Drilling undertaken soon after this discovery demonstrated that the anticlinal structure was in reality a major drag-fold cut off on the east side by a westerly inclined fault of large displacement. The faulted edge of the .limestone at depth determines the eastern limits of the field, which between 1924 and 1936 was shown to have a gas area 14 miles long by about 1 mile wide. Since the strata dip westerly, away from the axis of the fold, drilling becomes progressively deeper to the west and, with the advent of deeper drilling, crude oil was discovered in 1936 on the west flank of the structure but in the same porous reservoir rocks as the gas on the crest and upper parts of the fold. Since 1936, drilling has been undertaken wholly for the production of crude-oil and at present two producing areas have been found within the Turner Valley structure. The larger of these, at the south end of the field, in the vicinity of Highwood river, has a length of about 4 3/4 miles and a proved width of one mile, whereas the smaller, in the north end of the field, south of the north fork of Sheep river, has only a few producing wells.

Jan 1, 1939

By W. Z. Yin

It is investigated systemically in this paper that the granularity of the precursor, ZnC2O4?2H2O, is influenced by synthetic conditions. Instantaneously adding of precipitation agent is able to control the mean size of precursor ZnC2O4?2H2O under 300nm, which has great function to obtain well-dispersed ZnO nanoparticles in the next step, pyrolysis. The pyrolysis kinetics model of ZnC2O4?2H2O powder is obtained. Two steps take place during the pyrolysis. The first is dehydration, which the pyrolysis kinetic model is 2(1-a)2/3(chemical reaction), A=8.3×108s-1, E=(75.82±3.00) KJ/mol. The second is formation of ZnO, which the pyrolysis kinetic model is (1-a) (random nucleation and latter growth), A=8.45×1028s-1, E=(360.54±12.00)KJ/mol. ZnO nanoparticles obtained by pyrolysis take on self-growth behavior. It is resulted that for precursor ZnC2O4?2H2O pyrolysis time takes obvious influence on the partilces size under 420?, 500? and 600?. Finally, a new flow sheet for synthesis of ZnO nanoparticles is investigated, in which blendes is used as raw material and hydrometallurgy is introduced into it. The whole flow sheet has no industrial wastes, that is all byproducts can be used in the flow sheet recycled, resulted in the de-crease of productive cost and industrial wastes.

Jan 1, 2014

By Z. Pokrajcic

The traditional comminution circuit is a major consumer of energy ? both as electrical energy and through consumption of media and wear resistant liners. Up to 40% of electrical energy con-sumed at a mine site is attributed to comminution however only a few percent of this energy is used in the generation of new surfaces from size reduction. This paper describes the evaluation of modifications using simulation models based on two operating comminution circuits. The aim of these modifications is to decrease both the amount of electrical energy consumed in the size reduction process, known as direct energy, as well as to decrease the consumption of grinding consumables such as steel grinding media and mill liners, designated as indirect energy. The approach is two-fold: ??Employ, where possible, autogenous grinding techniques to eliminate the need for grinding media and reduce mill liner wear. ??Optimise the use of the grinding energy distribution in the comminution circuit by using more energy efficient grinding devices to target typically problematic features of a comminution circuit such as critical size material from the primary mill and overgrinding in the secondary mill. The investigations show that significant total energy savings, as high as 50% in some cases, can be achieved by employing the techniques described while maintaining circuit throughput and product size. Investigations also show potential benefits in downstream flotation processes as the product size distribution generated from the eco-efficient circuit is generally ?narrower? in shape for improved flotation performance and containing less material in the coarse fraction for overall better liberation.

Jan 1, 2014

By I. M. R. Duarte, J. A. Rodrigues-Carvalho, F. R. S. Rosa, A. B. Pinho

"This paper aims to contribute to the knowledge of the mechanical properties of the shales and greywackes which constitute the flysch-type deposits of the Baixo Alentejo Flysch Group, in the south of Portugal. These formations are flysch-type deposits constituted by sequences of usually thick greywacke beds alternating with thin shale beds, which include sometimes intercalations of conglomerate beds. All the sedimentation of these flysch formations was controlled by tectonics. At the same time, should have occurred along with the first Hercynian deformation phase, a low-grade metamorphic event (chlorite zone), that affected these flysch deposits. This study highlights the influence of anisotropy and heterogeneity of these flysch rocks on their physical and mechanical characteristics. The anisotropy verified in some physical properties and on mechanical properties, due to the foliation makes difficult the sample preparation for the laboratory tests. Besides, it induces a scattering of the properties values measured, as for example, the strength and the deformability. The heterogeneity is related to the main features of these geological formations, which are constituted mostly by thinly stratified greywackes and shale beds, which sometimes may affect the results of the laboratory tests making them less representative. The study is made by using both shales and greywackes that constitute these flysch-type deposits in order to evaluate their geotechnical properties, mainly of the shales. Samples of these two rock materials, are tested accordingly a laboratory testing programme, which includes which included mineralogical analysis (X-ray diffraction), physical tests (bulk density, porosity, and void index) and mechanical tests (uniaxial compression, and deformability tests). INTRODUCTIONOne of the factors that most influence the geomechanical behavior of rocks, as well as rock masses is the anisotropy. The word anisotropy comes from two Greek words ""anisos"" (meaning uneven) and ""tropos"" (meaning direction). A body or material is considered to be anisotropic, where the same property has different values depending in which direction it is measured, therefore, an anisotropic material is one whose magnitude of the properties depends on the direction in which these are studied or measured. Otherwise, it is about an isotropic material. However, the fully isotropic materials are quite rare in nature."

Jan 1, 2015

By Walter C, Smith

Metallic bismuth was known in the Middle Ages and the name is supposed to come from the German Wismut. The origin of the German name is uncertain. References to bismuth are found in the writings of Valentine, Paracelsus, and Agricola between 1450 and 1550. Early specimens of bismuth were very impure and often were confused with antimony, tin, and zinc. About the middle of the eighteenth century, J. H. Pott, C. J. Geoffroy, and Torbern Bergman succeeded in producing fairly pure bismuth and showed it to be an elementary metal similar in many respects to lead.

Jan 1, 1953

By Vijaya Bhushan Rao, Jason Redgers

The typical Vibrocompaction projects undertaken in the UAE are on reclaimed Sands. These Sands which are predominantly the crushable, calcareous, carbonate sands found locally as opposed to the more common quartz or silica sands that are featured in most design literature. The famous reclamations such as the iconic Palm Jumeirah in Dubai, often have specification for mitigation of liquefaction induced settlements, bearing capacity increases and total and differential settlement requirements. Often these performance targets are achieved by the means of achieving a particular relative density that are generally measured by a defined Cone Penetration Test, CPT targeting values of cone resistance (Qc), MPa at respective depth zones. In this paper some case studies are presented, where soil suitability for deep compaction by vibratory methods was firstly assessed for suitability using the Massarsch, 1991 compactability chart prior to the application of vibrocompaction and its subsequent evaluation. One such project named the Island Development required 17 to 23m depth of penetration only to treat the lower 5 to 6m of sand above rockhead as eventually the top 15m of sand will be further excavated to allow for the construction of basement. The paper will present pre and post CPT results, the results of initial site calibration trials and evaluation of the completed works.

Oct 1, 2022

By Camille Fleuriault

Continuous development of lead recycling technologies has driven the increasing contribution of secondary lead in battery manufacturing over the years. This review presents and compares the different technologies available for pyrometallurgical processing of secondary lead materials. Smelting is most often achieved in reverberatory, blast, rotary or electric arc furnaces, using single or two stage routes. Thermal re fining is the most common technique used for the production of lead and its alloys. Some improvements in battery breaking technologies and emission control have also specifically contributed to improve the performance of the smelting and refining units. Recycling lead is facing the challenge of increasing production while meeting more and more stringent regulations. This review will also include an analysis of the current secondary lead market as well as an economic outlook for the years to come in regards to rapidly changing environmental standards.

Mar 1, 2018

Jan 1, 1884

By L. Li

Backfill is increasingly used in underground mines, as it can help reduce the environmental impact from mining operations. However, the primary objective of backfilling is to provide safe working space for miners, by improving ground stability conditions. As cement is often added to the backfill, a critical issue is the determination of the required backfill strength (cohesion) due to the binder. This value is usually obtained from a solution proposed by Mitchell and co-workers, in the early 1980?s, for stopes with an exposed backfill face. This paper presents a brief review of the Mitchell et al. solution, with some of its main limitations. Some of the recently developed solutions for backfill design are then summarized and discussed.

Aug 1, 2013

By A. S. Hall

Significant pyrite often does not dissolve in the Sobek (1978) nitric acid extraction; therefore, the standard conservative approach is to estimate pyrite using sulfur present in the sum of the nitric acid and residual sulfur fractions. Alunite, when present, appears as residual sulfur. Because alunite does not generate acidic effluents, overestimation of AGP can occur if all residual sulfur is assumed to be undigested pyrite. Evaluation of 16 samples from the Florida Canyon Mine revealed that petrographic examination coupled with a modification of the Sobek method to include a 6 hour hot (250°F) 'nitric acid extraction resulted in a more accurate estimation of AGP.

Jan 1, 1999

By W. D. Keller

Scanning electron microscopy (SEM) accompanied by X-ray energy dispersive analysis (XES) is a useful tool in process clay mineralogy. The texture of kaolin, illustrated by SEM, gives a clue to its mode of genesis and probable industrial application. One type of kaolin, originating dominantly by weathering, has an open texture, slakes readily, and is used for filling and coating paper. Another type, in contrast, originates by diagenesis of Al-silicate sediments, and spectacularly resists slaking, thereby enabling it to maintain its bulk density and controlled size and shape of particles after crushing and moistening; this meets an important requirement for the manufacture of refractories. Ratios of elemental Al:Si that may be rapidly determined by SEM and XES yield information on the origin and purity of bauxite and bauxitic clays, and aid in quality control and processing of them. SEM of dissimilar textures of quartz, as in chert and novaculite, are evidence for geothermometry on a stratigraphic scale that is potentially useful in delimiting thermally favorable or unfavorable areas for hydrocarbon exploration, and possibly for unexposed metallic ore deposits.

Jan 1, 1982

By T. H. Patching

This paper provides a review of the available information on the origin and mechanisms of the release of gas from coal seams. With the opening up of new mines in Western Canada and the increased mechanization of underground coal mines, the study of gas emissions is of increasing importance in providing safe working places underground.

Jan 1, 1970

By J. O. Wheeler

"DEFINITION OF THE REGION, ITS BOUNDARIES, AND PHYSICAL AND GE'OLOGICAL CHARACTERISTICSTHIS PAPER concerns the Western Cordilleran region, embracing most of British Columbia, the southern half of Yukon Territory and the southwesternmost part of the District of MacKenzie. It excludes Vancouver Island and the Queen Charlotte Islands, which are discussed in a background paper on the Pacific Continental Shelf. The region is bounded on the south by the northwestern United States, on the west by the continental shelf and Alaska, on the north by the front of the Ogilvie Mountains, on the northeast by the axis of the MacKenzie Mountains and on the east by the Rocky Mountain Trench.The region is dominated by two mountain chains that con tain icefields and glaciers: the St. Elias, Coast and Cascade Mountains in the west; the Selwyn, Pelly, Cassiar, Omineca and Columbia Mountains in the east. The Intermontane region between these mountain chains consists of lower mountains and plateaus. In the mountains, the region above the timberline and many of the steep valley-walls provide good exposures of rock, but these areas are subject to rockslides and landslides and in winter to snow avalanches. Much of the Western Cordillera was covered by ice-sheets at various times during the Pleistocene epoch. Consequently, the larger valleys in the mountains and much of the Intermontane region contain much glacial drift and alluvium and only limited exposures of rock. This same terrain in the Southern Cordillera, however, is the most favourable for agriculture. Parts of the region, particularly in the two mountain chains, are heavily forested. Elsewhere, the forest cover is less, with grassland prevailing in the south and tundra in the north."

Jan 1, 1970

By C. H. Lau, I. T. Ng

Uniaxial Compressive Strength (UCS) of rocks is an important mechanical parameter for many civil engineering and rock engineering applications such as tunnel excavation, slope stability and foundation design. Macau is one of the world's fastest growing and most densely populated cities, many large and important infrastructures have been being continuously built using pile foundations which are designed to be supported by granitic bedrock. In Macau, the UCS of the granitic bedrock is required almost for every project involving pile foundations and is always measured directly from UCS test in the laboratory. However, direct measurement of UCS requires high quality rock core sample which is not only time-consuming and expensive but also requires high level of operating skill. In view of this fact, estimation of UCS using some empirical correlations will be more practical and efficient because they are relatively fast and economical compared to the direct measurement from UCS test. In the past, some empirical correlations had been established and widely used for estimating UCS of rocks in common engineering practice. However, it has been well recognized that the rock properties are generally varied with sites or geological regions in other words an empirical correlation developed from one region or one country may not be applicable for other regions or countries. Due to the reason that the empirical correlations for predicting UCS for granite are scarce in practice, in this study an extensive experimental program has been performed and a large database containing data such as UCS, Point Load Index (Is50), Schmidt Rebound Hardness (RL), porosity (?), water absorption (S), specific gravity (Gs) and dry density (?d) has been developed. An attempt has been made for developing a new empirical correlation for estimating the UCS of Macau granite. Accordingly, a comprehensive statistical analysis for correlating UCS with Is50, RL, ?, S, Gs and ?d has been performed and a local empirical relationship based on the developed database is proposed for obtaining reliable estimation of UCS for the granite of Macau. Finally, the performance of the proposed correlation is accessed by using another independent testing database developed in this study. It indicates that Is50, RL, ? and S have strong correlation with UCS whereas Gs, ?d have poor correlation with UCS. This study not only proposed a proper predictive empirical correlation for UCS determination for Macau granite but also provides detailed statistical information which is beneficial to engineers for obtaining better characterization of Macau granite.

Jan 1, 2015

By Luzheng Chen

The study aimed to evaluate the separation performance of a full-scale continuous centrifugal concentrator in the reconcentration of fine hematite from high-gradient magnetic separation (HGMS) concentrate in a tailings recovery plant, and to investigate the usefulness of the technology in industrial applications. The effect of changing the operating variables on concentrate grade and recovery was studied. The results indicate that among the variables considered in the study (water spray pressure, centrifugal acceleration, feed volume flow rate, feed percent solids and the reciprocation and spacing of water sprays), the change in centrifugal acceleration affects the recovery the most and continuous concentration can be achieved only when the water spray has a sufficient pressure. In addition, the reciprocation and spacing of the water sprays have a significant influence on the concentrate grade. Although performance of the full-scale concentrator is slightly inferior to pilot-scale trials, due to limitations in the scale-up design and the fluctuations of feed material characteristics, this concentrator provides a potential way to achieve continuous concentration and obtain a high-grade concentrate from tailings.

Jan 1, 2010

By E. Morrice

High-purity neodymium, praseodymium, and didymium (a cerium-free mixture of light rare-earth elements) were prepared by electrolysis of the oxides in a medium consisting of the respective rare-earth fluorides and lithium fluoride. The metals were electrodeposited in the liquid state and collected as nodules on a skull of frozen electrolyte. Cells were operated from 1,000° to 1,100° C. The requisite temperature was maintained by passing alternating and direct currents through the bath. Graphite was used for the anodes and tungsten for the cathode. The metal products contained <0.02 percent each carbon and oxygen and <0.025 percent tungsten as major impurities. Analysis of typical didymium metal nodules showed an approximately twofold enrichment in neodymium and praseodymium over their respective concentrations in the cell feed. The lanthanum content of the metal was about one-half its content in the oxide.

Jan 1, 1967

By Lee R. Buhagiar

As a result of the increased seismic risk and the highly variable geology of Christchurch, finding costeffective foundation solutions has been a challenge for the Canterbury rebuild. The soil profile in Christchurch comprises both terrestrial (Springston Formation) and marine (Christchurch Formation) alluvial deposits with a high groundwater table. The result is a highly variable and interbedded soil profile which is prone to liquefaction and static settlement. Vibro-replacement stone columns are very effective in mitigating liquefaction in clean sand. However, the author’s experience has shown that vibro-replacement stone columns are also effective for treating silty and soft soil layers. Vibroreplacement stone columns can be used to treat these soft soils by increasing the composite soil stiffness and providing a load transfer path to the underlying dense soils. Another challenge encountered in the Canterbury rebuild is the cost of redevelopment of brownfield sites with contaminated fill. The costs of disposing this fill often make projects too expensive. Vibro-replacement stone columns have been used successfully to treat contaminated fill, providing a treated soil profile with uniform performance and reducing the cost of disposing of contaminated fill. This paper looks at several case studies in Christchurch, with highly variable soil profiles, where vibro-replacement stone columns have been used successfully to treat multiple soil layers, from contaminated fill to silty soils and soft and non-liquefiable silt.

Nov 1, 2022

By JAMES J. PURDY

The great majority of stokers used in residential heating installations are of the clinkering type. Because of inherent characteristics of the under- feed combustion process as it occurs in these small stokers, and because of the wide range of operating conditions encountered in residential heating schedules, not all bituminous coals can be used successfully in residential underfeed units. The problem of providing consumer satisfaction has been attacked by the joint efforts of the stoker manufacturers and the coal industry; the stoker manufacturers have been concerned with improving their product to permit the use of a wider range of coals, and coal operators have made every effort to market selected and better prepared coals. In view of the wide range of physical characteristics and chemical properties of bituminous coals, the problems are real and are receiving increased attention.

Jan 1, 1949

By D. Lui, B. G. Thomas, B. Ho

"Results from mathematical models and plant experiments are combined to quantify the effect of transverse depressions and oscillation marks on heat transfer in the continuous casting mold. A heat transfer model has been developed to calculate transient heat conduction within the solidifying steel, coupled with the steady-state heat conduction with the continuous casting mold wall. The model features a detailed treatment of the interfacial gap between the shell and mold, including mass and momentum balances on the solid and liquid powder layers. The model predicts the solidified shell thickness down the mold, temperature in the mold and shell, thickness of the resolidified and liquid powder layers, heat flux distribution down the mold, mold water temperature rise, ideal taper of the mold walls, and other related phenomena. The important effect of non-uniform distribution of superheat is incorporated using the results from previous 3-D turbulent fluid flow calculations within the liquid cavity. Results from plant experiments confirm that transverse surface depressions and oscillation marks form at the meniscus and move down the mold. Measurements of mold thermocouple temperatures and breakout shell thickness were used to calibrate the models. The results indicate that the surface depressions and oscillation marks are filled with mold flux, but still have a significant effect on decreasing heat transfer. The predicted mold temperature fluctuations are consistent with measurements. If the depressions become filled with air, their effect is greatly increased. These results should be useful in the difficult task of interpreting transient mold thermocouple signals for on-line quality monitoring.IntroductionMany different types of intermittent surface defects on steel slabs arise during initial solidification in the mold of the. continuous casting machine. These defects include deep oscillation marks, surface depressions, and cracks. They may lead to quality problems, such as slivers, in the final rolled product. In severe cases, breakouts may occur, where liquid steel bursts through a thin section of the shell and drains over the casting machine below the mold."

Jan 1, 1997

By C DahnTr-Lindqvist

The Kiruna mine produced about 19 Mt processed iron ore in 1999 using sublevel caving. General failure in the hangingwall has been widely studied and its mechanism is rather well understood. Failure in the footwall is more recent and not perfectly explained. Plane shear failure and Hoek and BrayÆs circular failure charts were successfully used to match the first surveyed failure surfaces. The footwall is not free yet but covered by a caved waste rock abutment whose exact behaviour is poorly known. Based on new field data and numerical models (FLAC), the following paper presents recent improvements in understanding the Kiruna mineÆs footwall failure process.

Jan 1, 2000