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By Amar Prakash, V. M. S. R. Murthy, VIVEK KUMAR HIMANSHU, Sufal Mehrotra, Ashish Kumar Vishwakarma

Raises are vertical or inclined openings made to connect two levels of an underground metalliferous mine. They are developed using drilling and blasting-based technique or by mechanical means. Raise boring machines (RBM) have evolved in recent years, which provide quicker and safer raise excavation. The penetration rate using RBM has influenced applied thrust. The required thrust to enhance penetration rate with optimal use of energy would be different under varying geological and geotechnical conditions. In this study, the influence of applied thrust on penetration rate using RBM has been investigated. The investigation has been made for two different rock types, amphibolite (AMP) and garnet-biotite-sillimanite-gneiss (GBSG). The numerical simulation model was developed for this purpose using Ansys-Explicit Dynamics. The induced tensile stress under different conditions of applied thrust has been analysed in the calibrated numerical model. The model output shows the power trend between the parameters. The experimental data on penetration rate was also collected along with the respective operational parameters. A statistical analysis has been carried out for the gathered data. The analysis of data also shows a power trend between thrust per cutter and penetration rate in both rock types and hence validates the numerical simulation-based output. Based on the outputs of the numerical simulation and empirical study of the experimental data, the optimum thrust per cutter for excavation in both rock types is in the range of 12–14 tons. The approach used in this study can be helpful for predicting the optimal operational parameters of raise boring machines under different geological/geotechnical conditions.

May 29, 2023

By XING Xiangdong, Zhang Jianliang, MA Jinfang, WANG Zhenyang

The non-equilibrium reflux reaction behavior of phosphorus was studied with synthetic slags formed by using the AR chemical reagents and changing the initial condition of basicity, FeO, MgO and Al2O3. Due to increase of viscosity, the dephosphorization slag with high basicity inhibits the full contact of slag with iron, which leads to the low reaction rate in the early stage. However, since the high basicity improves the activity coefficient of CaO, the dephosphorization rate and phosphorus capacity goes up in late reaction stage. FeO promotes the increase of reaction rate in early dephosphorization stage. But the polarization force of Fe2+ is stronger than Ca2+, which hinders the reaction between phosphate ion and CaO and reduces the stability of PO4 3-. Thus, high content of FeO will adversely impact on dephosphorization reaction. In addition, MgO has a promoting effect to the dephosphorization, whereas Al2O3 has a negative influence.

Jan 1, 2016

By G. L. F. Powell

g samples of Cu-20 wt pct Ag alloy have been mdercooled to a maximum of 197°C by melting under a slag of commercial soda-lime glass in a vitreous silica crucible. No grain refinement of the primary copper was observed in samples undercooled to the maximum of 197°C. When the samples contained a small amount of oxygen, the copper dendrites were partially recrystallized at undercoolings greater than 97°C. In previous papers'-3 reporting the grain structure of undercooled silver and copper, it was observed that grain refinement was dependent on both undercooling and oxygen content. Grain refinement occurred in undercooled silver when the degree of undercooling exceeded the range 153" to 175"C, while in Ag-0 alloys (0.12 wt pct) fine equiaxed grains were exhibited when undercooling was greater than 50°C. Similarly, copper samples undercooled as much as 208°C displayed fan-shaped growth from a single nucleation site, while the grain structure of Cu-O alloys (0.08 wt pct) was fine and equiaxed at undercoolings larger than 150°C. Thus the presence of oxygen greatly reduced the undercooling at which grain refinement occurred. It was also observed that the change in grain size resulted from recrystallization and was not due to an enhanced nucleation rate in the liquid-solid transformation. It is possible that the influence of oxygen on recrystallization is due primarily to its presence as a solute element. walker4,' reported that, although a grain size change did not occur in pure nickel until the undercooling exceeded 150°C, small grains were observed in samples of Ni-Cu alloy solidified at small and large degrees of undercooling. Jackson et al.6 suggested that the fine grained structure of the Ni-Cu alloy resulted from the melting off of dendrite arms during recalescence. This remelting process may occur in alloys as a result of segregation during freezing which causes a variation in liquidus temperature from point to point within a dendrite. It was therefore decided to undercool copper with a metallic alloying element to ascertain whether the presence of a metallic solute would have a similar effect to oxygen in inducing grain refinement. A Cu-Ag alloy was chosen, since both metals had been shown to behave similarly on undercooling. The alloy Cu-20 wt pct Ag was selected since the eutectic constituent outlines the initial growth form of the primary copper, so that the as-frozen grain structure is not obscured if subsequent recrystallization occurs. This paper describes the results of undercooling experiments carried out with Cu-20 pct Ag samples undercooled to a maximum of 197°C and the effect of oxygen content on the grain structure of the undercooled samples. EXPERIMENTAL Melting was carried out in a small cylindrical resistance furnace using "fine" silver granulate and oxygen-free high conductivity copper. The procedure adopted was to melt the required quantity of silver in air in a clean vitreous silica crucible for approximately 15 min, freeze, and add granulated commercial soda-lime glass to form a complete surface slag cover, after which the sample was melted and frozen several times to reduce the oxygen content. The glass slag cover was approximately 3 in. thick. Pieces of copper (=50 g) were added to the crucible until the required quantity to make 350-g samples of alloy had been charged. Each piece was added quickly to the crucible which was held at a temperature slightly above the melting point of silver. The piece was quickly pushed beneath the glass to minimize oxidation and any oxide coating usually decomposed before the piece had settled down into the silver. After the full quantity of copper had been added, the melt was stirred with a silica rod to hasten homogenization and a Pt/Pt 13 pct Rh thermocouple enclosed in a vitreous silica sheath inserted for temperature measurement. Heating and cooling curves were recorded on a potentiometric chart recorder fitted with a zero suppression unit. The milli-voltage range of the recorder was adjusted so that temperatures could be read to 1°C. Heating and cooling curves were taken every hour until three consecutive readings gave the same solidus-liquidus range, consistent with the solidus-liquidus range for this alloy composition by reference to Hansen and Anderko.7 Metallographic examination of samples frozen at this stage, failed to show any variation in composition from bottom to top of the ingot. Consequently, it was considered that the melt was homogeneous at this stage and undercooling experiments were then car-

Jan 1, 1970

By Zainab Nasrullah, MontanaFrank Agyemang, Mehran Sadat, Richard LaDouceur

Rare earth elements (REEs) are valuable for various modern technological applications, including metallurgy, machine building, radio electronics, instrument engineering, nuclear engineering, and manufacturing. The extraction and separa-tion of rare earth elements (REEs) from their complex ores is challenging due to their distinct physical and chemical properties, contributing to their market scarcity. At present, REE recovery utilizes traditional pyro- or hydrometallurgi-cal processes. The overall process in the recovery and sepa-ration of individual elements from complex REE systems suffers from high energy demands and the use of many haz-ardous chemicals that negatively impact the environment. With the growing trend toward a circular economy aim-ing to balance sustainability, efficiency, and environmental impacts, this research is focused on using deep eutectic sol-vents (DESs): a combination of a quaternary salt: Choline Chloride and five organic acids: Oxalic Acid, Urea, and Ethylene Glycol, Lactic acid and Glycerol for the selective leaching of REEs from their complex ore which is proven to be green, selective, non-toxic, biodegradable, and cheap. The effects of different DESs and leaching time on the REE leaching efficiency were determined, and the optimum DES media were found to be Oxaline and Lactic Acid at which a leaching efficiency of 25% and 15% was achieved at 80°C respectively for cerium.

Feb 1, 2025

By J. P. Grau, J. Z. Lu

"Thickeners/clarifiers are widely used in coal preparation plants, potash processing and other mineral processing facilities. Thickeners play a very important role in slurry treatment systems to accomplish solid/liquid separation. The demand for larger plants and the increased thickener handling capacities sometime require thickener diameters as large as 200m. The development and use of high capacity thickeners makes it possible to increase the handling capacity of these thickeners by several to more than 10 times compared to conventional thickeners. Hence, for a given slurry rate, selection of a high capacity thickener will significantly reduce the footprint of the thickener. Much higher handling rate, higher concentration of underflow, clearer overflow and lower capital cost are obvious advantages of high capacity thickeners; however, some process requirements and the concerns of operational cost, especially the flocculant cost of a high capacity thickener operation, keep some engineers selecting conventional thickeners and staying away from the high capacity thickeners. Forty years after the first high capacity thickener was developed, there are still arguments in the selection of conventional thickeners or high capacity thickeners in mineral processing. The arguments will continue unless there is a clear picture of capital cost vs. operational cost for each of the thickener types. The purpose of this paper is to analyze these costs and to provide guidelines for selection of thickeners. INTRODUCTIONThickeners/clarifiers are widely used in various slurry treatment systems. For mining and mineral processing, thickeners are an integral part of the solid/liquid separation system. The feed to the thickeners are processing slurries. The fundamental mechanism for the solids/liquid separation is for the solid particles in the slurry to gravity settle inside the thickener tank. The clear water overflows from the top of the thickener tank and is typically reused in the processing circuit, and the concentrated underflow is discharged to different downstream process systems depending on the application of the thickeners. The general requirements for a thickener operation include high density of underflow and clear overflow. Since thickener operation consists of continuous feeding, overflow and discharge of underflow, the solid particles will gravity settle against an upward flow with its velocity dependent on the feed rate and the underflow discharge rate. Higher feed rates to a given thickener produce higher upward velocities. Underflow discharge is typically relatively small compared to the amount of overflow. The upward flow tends to take particles up to the overflow. Only those particles having a settling velocity greater than the upward flow velocity will possibly settle out. Hence, thickener feed rate has to be controlled so that the required overflow water clarity can be achieved."

Jan 1, 2012

By Sunil K. Tripathy

Particle characteristics such as size, density, liberation and magnetic susceptibility play vital role in magnetic separation technique. To understand the performance of magnetic separation process for chromite beneficiation industry, particle characteristics need to be analysed. However, to date, this has been an expensive and time consuming task, thus only minimal amounts of this type of data are available in the literature. Several new methods are being developed, that will produce the required mineralogical and liberation data to provide processing information rapidly and inexpensively. Among these, QEMSCAN is a unique and advanced characterisation equipment used for liberation analysis for different ore whereas S.G. Franz Isodynamic Separator for determining the magnetic susceptibility. In Indian chromite deposits, the content of iron bearing minerals in the ore is typical which controls the Cr:Fe ratio in the product while treating in gravity based beneficiation plant. In the present investigation, detailed characterisation of two distinct chromite ore samples from Sukinda chromite deposit, India, was investigated which includes advanced mineral characterisation using QEMSCANand magnetic susceptibility measurement by using Frantz Isodynamic separator, etc.. Presence of haematite and gibbsite along with chromite mineral were identified as major gangue minerals in the high grade ore from XRD pattern whereas Goethite, Quartz, Haematite, Kaolinite, Ringwoodite identified in the low grade ore. The mass magnetic susceptibility of low grade ore is very high 5.2 cm3/g compared to 2.7 cm3/g for high grade ore, due to the presence of abundant quantity of iron bearing minerals. Subsequently, these two types of ore were subjected for magnetic separation for improving Cr:Fe ratio by using different magnetic separators viz. induced roll magnetic separator, wet high intensity magnetic separator, rare earth roll magnetic separator, rare earth drum magnetic separator. The results of magnetic separation studies indicated that, Cr: Fe ratio of the chromite ores can be improved to 3.99 and 1.97 from the feed assaying 3.09 and 1.29 respectively. Studies on rare earth roll magnetic separator indicated that both the ores were upgraded to a maximum Cr:Fe ratio level at optimised condition. Keywords: characterization, QEMSCAN, magnetic separation, rare earth roll magnetic separator, industrial mineral, chromite

Sep 1, 2012

By R. A. Allwes

In-plane bending and torsion tests were conducted on full-scale masonry walls to evaluate three post-reinforcement designs. The designs were developed to minimize longwall mine subsidence damage to existing residential masonry foundations. The bending tests show that vertical and horizontal post tensioned tendons significantly increase the resistance of a masonry wall' to in-plane bending. The torsion tests reveal that post tensioned tendons increase a masonry wall's limit of deformation but do not increase its torsional stiffness. The torsion tests also show that the masonry units minimally contribute to the torsional stiffness of a masonry wall.

Jan 1, 1995

By S. Malopheyev, I. Vysotskiy, R. Kaibyshev, S. Mironov

"In this work, the effect of pre-strain rolling on the annealing behavior of friction-stir welded 6061-T6 aluminum alloy was studied. To this end, the as-welded material was rolled to 10 or 20 pct. of thickness reduction prior to the standard post-weld T6 heat treatment. Three rolling directions were the 3-mm thick sheet were considered: along the welding direction, perpendicular to the welding direction, and at the angle of 45° to the welding direction. At relatively low pre-strains (10 pct.), the annealing behavior was found to be very sensitive to the rolling path, and rolling along the welding direction was most effective in suppressing abnormal grain growth. On the other hand, increasing the pre-strains to 20 pct. of thickness reduction inhibited abnormal grain growth irrespective of the rolling path.INTRODUCTION Heat-treatable wrought Al-Mg-Si alloys are widely used due to attractive combination of strength, ductility, excellent corrosion resistance and low cost (Polmear, 2006). To provide the optimal balance of mechanical properties, these materials are typically commercially available in appropriately work- and precipitation-hardened conditions (Polmear, 2006). During conventional fusion welding, however, the prior strengthening effect is totally lost due to elimination of the work hardened structure and dissolution of the strengthening precipitations. An innovative friction-stir welding (FSW) technology may partially overcome this problem. Due to the solid-state character of this process, which involves very large strains, the welded material is characterized by fine-grained microstructure with moderate-to-high dislocation density, and thus the prior work hardening effect may be preserved or even enhanced (Threadgill et al., 2009; Mishra & Ma, 2005). However, heat input associated with FSW inevitably leads to dissolution and/or coarsening of strengthening precipitates, thus giving rise to the undesirable material softening. In an attempt to restore the strength of the friction-stir welded material, the standard T6 post-weld heat treatment has been applied, but this approach was found to lead to abnormal grain growth (Malopheyev et al., 2016; Mironov, 2013, Mironov et al., 2015)."

Jan 1, 2018

By Jimenez Leon, Christopher Newman, Boede Gabriel, Zacharias Agioutantis

"Ground movements due to longwall mining operations have the potential to damage the hydrological balance within as well as outside the mine permit area in the form of increased surface ponding and changes to hydrogeological properties. Recently, the Office of Surface Mining, Reclamation and Enforcement has completed a public comment period on a newly proposed rule for the protection of streams and groundwater from adverse impacts of surface and underground mining operations (80 FR 44435). With increased community and regulatory focus on mining operations and their potential to adversely affect streams and groundwater, there is now a greater need for better prediction of the possible effects mining has on both surface and sub surface bodies of water.As mining induced stress and strain within the overburden is correlated to changes in the hydrogeological properties of rock and soil, this paper investigates the evaluation of the hydrogeological system within the vicinity of an underground mining operation based on strain VALUES (calculated through a surface deformation prediction model. Through accurate modeling of the pre- and post-mining hydrogeological system, industry personnel can better depict mining induced effects on ground water flows through the overburden material aiding in the optimization underground extraction sequences while maintaining the integrity of surface and subsurface bodies of water.INTRODUCTIONThe utilization of high-recovery underground mining methods, such as longwall or high-extraction room-and-pillar operations, have the potential to cause adverse impacts to both surface and subsurface bodies of water as strata movement and deformations propagate from the mined seam through the overburden to the surface (Peng, 2008).Previous research has indicated that mining induced strains are the most damaging to surface streams (Singh, 1992) as well as greatly affecting the integrity of subsurface bodies of water and groundwater flow conditions (Booth, 1986). On the surface, adverse effects to the stream can occur due to the development of either tensile or compressive strain in the stream bed. The development of tensile cracks along the bedrock allows for a potential loss of stream flow through developed fissures. In fact, water flow in the Cataract River of Australia ceased in 1994 as a result of mining-induced strains from longwall operations in the Bulli seam 430 meters (1320 feet) below the river gorge (McNally and Evans, 2007). On the other hand, the development of compressive strains within the rock layers can cause rupturing or buckling of the stream bed, blocking stream flow and/or diverting flow into the fractures at the base (Iannacchione et al, 2010). While these localized fractures can contribute to the loss of stream flows, given time, damaged streams have the ability to self-heal through the regeneration of near-surface aquifers as well as the sealing of mining-induced fractures with rock debris, gravel, sand, clay or other soil particles carried from upstream sources and deposited in the river bed (Waddington and Kay, 2002)."

Jan 1, 2016

By Thomas M. Barczak

This US. Bureau of Mines report examines the roof and floor contact pressure provided by the interaction of a shield with the surrounding strata. Controlled forces were applied to an 800-ton two-leg shield in the Bureau's mine roof simulator; the distribution of forces acting on the canopy and base of the shield were measured with 24 hydraulic pressure cells. Several influential factors that affect the load distribution were investigated: (1) the magnitude of loading (leg pressure); (2) the profile of the canopy, principally the upward-sloping tip; (3) the base-lifting device; (4) horizontal load acting on the shield; and (5) compliancy of the immediate roof and floor. It was concluded that the shield does not develop full canopy or base contact without deformation of the strata. Maximum contact pressures are developed at the rear of the canopy and on the toes of the base. Less than 10 pct of the available shield capacity is developed at the canopy tip despite the design intention to ensure tip contact. Horizontal loading reduced the toe pressure acting on the base by as much as 75 pct. The base-lifting device exaggerated the inherently high toe loading, increasing the contact pressure by more than 200 pct.

Jan 1, 2010

By K. Szczesny

This paper considers the integration of uncertain real-time logistics data for reactive construction scheduling. In order to manage a construction project efficiently, an accurate schedule representing the current project progress is inevitable. The quality and up-to-dateness of such a schedule depends on the availability of real-time data. Typically, real-time logistics data contain information about the availability of material, equipment and personnel as well as delivery dates and site conditions. The accuracy and inherent uncertainty depends on the location where the real-time data was acquired. Currently, the integration of such data into a construction schedule is a very time-consuming, manual and, thus, errorprone process. Therefore, this paper proposes a methodology that enables an automatic integration of such uncertain data into construction schedules. By integrating uncertainties into the existing schedule their impacts on the construction work can be evaluated. For this, discrete event simulation is applied. In order to model uncertain input parameters for simulation models this methodology applies the fuzzy sets theory. In combination with alpha-cut sampling technique, discrete model input parameters are obtained. By applying reactive scheduling with several discrete event simulation experiments, the results can be used to modify construction schedules according to agreed timeframes and costs. In order to demonstrate and validate the presented approach an example is conducted.

Aug 1, 2013

By Dirige. A. P. E.

A study was conducted for an operating mine to determine the appropriateness of its tailings material to be used for the preparation of a low modulus, high density backfill. The research was initiated due to issues arising from increased observations of compressive failure of backfill placed in stopes and inconsistent backfill behaviour (i.e. increased backfill brittleness and modulus). Backfill materials investigated were classified tailings and de-slimed tailings. Characterization of the physical properties of the classified and de-slimed tailings materials was conducted to assess the effect that these material properties would have on the strength and deformation behaviour of high density backfill products made using them. Such behaviour was investigated to determine whether differences in tailings physical properties would influence the strength and modulus character of the backfill materials. Uniaxial (UCS) and consolidated-undrained triaxial compression strength tests were conducted to determine strength performance and deformation behaviour of backfill. This paper presents the results of the backfill material characterization study and how different particle size distributions affected the strength performance and deformation behaviour of the different backfill mixes. It also demonstrates how stress-strain curves generated from material strength tests were used to evaluate variation in high density backfill mix response when such materials were subjected to unconfined and confined (triaxial) compression loading.

Aug 1, 2013

By G J. Lyman

Sampling of grain for mycotoxins is challenging in that some mycotoxins, such as Ochratoxin A (OTA), have very low permitted levels and the kernels carrying the mycotoxin may be highly localised within the bulk of the grain as ‘hot spots’. Sampling for genetically modified organisms (GMOs) can be fraught with similar problems, especially if the contamination is adventitious and random. Incremental sampling under these circumstances can be shown to lead to a high variance in the sampling result.A new design of sampler for grain and other free-flowing particulates has been developed that is effective in practically eliminating the sampling variance due to distributional heterogeneity (DH).This paper introduces the design and argues that the sampler should be free of sampling variance due to DH.CITATION:Lyman, G J, 2017. A new sampler for grain and other free-flowing particulates, in Proceedings Eighth World Conference on Sampling and Blending , pp 277–280 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

By Jerome A. Westphal

The Middle Mississippi River extends from the mouth of the Ohio River to the mouth of the Missouri River, a distance of about 310 kilometers (km) measured along the river. From its founding in 1764 to the first steamboat arrival in 1817, the City of St. Louis was little more than a trading post. However, with the advent of the shallow-draft steamboat, the Middle Mississippi River rapidly became a major thoroughfare of commerce. In this regard, its importance has been reflected by the development of port facilities at St. Louis and by Federal activity relating to channel maintenance and improvement. First Federal work on the Middle Mississippi River was autho¬rized by Congress in 1824. This work was for snag removal and bank clearing and was directed at reducing the hazards to steamboat traffic, particularly during low-flow periods. During the 1820's and early 1830's, the main channel threatened to move toward the Illinois shore and abandon the St. Louis port facilities. In 1836 and 1837, Congress authorized construction of permanent improvements to keep-the river next to St. Louis (Missouri shore). By 1880, it was recognized that bank clearing activities had resulted in a wider and shallower river which exacerbated navigation

Jan 1, 1977

By V. A. Leão, A. M. Silva, S. M. Bertolino, B. C. S. Ferreira, D. Guimarães

Although not considered a high risk pollutant as compared to toxic metals and acidity, environmental agencies worldwide are proposing regulations to control sulphate in effluents and drainages by setting a threshold value varying between 250 mg/L and 500 mg/L. The aim of this study was thus to compare four different techniques for removing sulphate ions from mining/metallurgy effluents. The first alternative studied was sulphate removal by precipitation as ettringite. Treating a synthetic solution containing 1650 mg/L sulphate at 22±1 ºC resulted in removals close to 85% during continuous precipitation. Sulphate sorption was also investigated using three different ion exchange resins as well as limestone. Fixed bed experiments produced sulphate loadings of up to 70 mg SO4 2-/L resin, at pH 2.0. In neutral wastewaters, limestone is also a potential adsorbent producing a maximum particle loading of 19 mg/g. Sulphate sorption on limestone seems to be an alternative to treating mine waters with sulphate concentrations below the 1200-2000 mg/L range, where lime precipitation is not effective. Subsequently, sulphate removal by sulphate reducing bacteria was also investigated and it was observed that reactor’s hydrodynamic conditions and the choice of substrate are important factors for the process. The different technical aspects of each technology are addressed.

Jan 1, 2014

By F. Calizaya

This study summarizes the results of various numerical and laboratory experiments per-formed to study the effect of airflow recirculation on gas concentration. The numerical exercises were carried out on a simulated mine ventilation net-work. The laboratory experiments were conducted at the Mackay School of Mines' airflow monitoring system in Reno, Nevada. In both cases, the airflow was recirculated through the system by means of a main fan and a set of booster fans. The booster fans were positioned to produce two types of recirculation: In line and Cross-cut. For each type, various recirculation conditions were generated by changing the booster fan pressure. During each test, the gas emission rate at the simulated working face was kept constant. The study illustrates the conditions under which controlled airflow recirculation may be used to solve a district ventilation problem.

Jan 1, 1991

By Giles D, Wegmann D

The Mt Todd Gold Project is located 42 km northwest of the township of Katherine within the Northern Territory of Australia. It is situated in the southeastern portion of the Pine Creek Geosyncline. The Batman gold deposit, the largest of several deposits at Mt Todd, hosts an identified mineral resource of 92.9 million tonnes (Mt) grading 1.4 grams/tonne (g/t) as at 31 December 1993. Host rocks at Batman are assigned to the Early Proterozoic Burrell Creek Formation, comprising greywacke and siltstone interbedded with shale. Gold mineralisation is associated with a very broad zone of sheeted and stockwork quartz-sulphide veins that occupy a corridor of intense brittle fracture and faulting. A conceptual model of formation involves the dilation of joints and micro-faults within overlying sediments during sinistral movement along a basement shear zone. Synchronous granite intrusion generated convective circulation of crustal fluids through the sedimentary pile resulting in the formation of auriferous quartz veins within favourable structures. The Batman zone of mineralisation is not directly related to fold structures which typify several other major gold deposits within the Pine Creek Geosyncline.

Jan 1, 1994

By M. Z. Mubarok, Z. T. Ichlas, A. T. Sugiarto, K. Sukamto

The use of ozone as an oxidant for the direct leaching of zinc sulfide (sphalerite) concentrate in sulfuric acid medium under atmospheric pressure was explored. The influence of acid concentration, feed gas injection rate, particle size distribution, stirring speed, temperature and slurry density on zinc extraction efficiency was examined. The experimental results showed that the leaching efficiency depends on all of these operating parameters except for stirring speed. It was found that essentially complete dissolution of zinc from the concentrate with the present method can be achieved in only about seven hours under the conditions of sulfuric acid concentration of 2 mol/L, particle size smaller than 74 µm, slurry density of 50 g/L, stirring speed of 420 rpm and feed gas injection rate of 1 L/min at ambient temperature. The experimental results suggest that the dissolution reactions produce independent elemental sulfur that is readily floated and can be easily separated rather than forming a layer on the surface of the reacted particle, as usually observed in a system with ferric-sulfate as oxidizing agent. It was therefore determined that the dissolved ozone play a key role in improving the rate of zinc dissolution from the concentrate. Analysis of the leaching kinetics indicate that the leaching rate follows the shrinking particle model, and the overall dissolution rate of zinc is controlled by a surface reaction.

By S. F. Kaplan, A. S. Dolotov, V. N. Kovalev

"The proportion of refractory sulphide ores and concentrates in world gold mining industry is growing every year. Pressure oxidation of these materials (in autoclave) allows to oxidize gold hosting minerals. Traces of halides and pseudohalides present in the slurry liquids contribute to formation of complex gold compounds. Sorption-active carbon present in ores leads to irreversible adsorption of complex gold compounds and their loss. The objective of the research is to study gold extraction dependence on the concentration of chloride-, cyanide- and thiocyanate-ions in the slurry liquids during pressure oxidation. Double refractory flotation concentrate of the Bakyrchik deposit was used for the testwork. The research was planned on the basis of a full factorial experimental design with additional refining experiments. Ligand concentrations (0 – 1000 mg/l Cl-, 0 – 600 mg/l CN-, 0 – 1200 mg/l of SCN-), temperature (200 – 240 °?) and retention time (1 – 6 h) were used as variables of pressure oxidation process. It was determined that sulfide minerals oxidize much faster than ""organic"" carbon. Under the conditions of T = 240 ?C, t = 2 h, sulphide sulfur oxidation was 95.6%, while ""organic"" carbon oxidation was 46.1 %. Each of the examined ligands has a significant adverse impact on gold extraction. Analysis of the experimental data demonstrated that with a high degree of confidence (R2 = 0.883) gold extraction does not depend on the ligand type, but only on its concentration and the ""organic"" carbon oxidation degree. In case of complete oxidation of ""organic"" carbon, the presence of the ligand (L = Cl-, CNS-, CN-) in the liquids at a concentration of up to 20 millimole/L does not significantly affect gold extraction. The assumption that the main factor of preg-robbing in ???-CIL treatment of double refractory concentrates is the natural ""organic"" carbon sorption-active to gold has been confirmed. INTRODUCTION In recent decades, placer gold mining has been gradually declining and hardrock gold mining, including ""refractory"" gold mining, has been growing all over the world, as well as in the Russian Federation (http://www.miningworld.ru, 2015). One of the main reasons why gold ores are refractory is gold adsorption on natural carbonaceous materials (""organic carbon""). Only a few technologies are suitable for processing such ore concentrates (a significant amount of gold is contained in refractory hardrock ore both in Russia and worldwide) (Vorob'yev-Desyatovskiy N.V., Yepifanov A.V., 2014)."

Jan 1, 2018

By S Maritsa, E K. Chiw, S M. Masuka, ika, T Chisahwira

The challenges facing the iron and steel industry on a global scale include depletion of resources, excessive energy consumption and CO2 emissions. The demand for iron products in Zimbabwe is increasing due to massive infrastructural development like the expansion and improvement of mines, transportation systems and water reticulation systems. In Zimbabwe, cast iron is mainly produced from recycling scrap metals. However, there is currently a shortage of scrap, which has resulted in the vandalism of state-owned properties such as bus terminals and railway wagons and lines. Nevertheless, Zimbabwe is rich in limonite ores, which are idle, and it is the aim of this research that this ore be effectively used to produce feed for the blast furnace. The Blast furnace is still the dominant route for producing cast iron where sintering and coking processes are the main routes for preparing the Blast furnace feed. Sintering limonite ore fines produce a product of poor grade because of the high value of loss on ignition that has a negative impact on Blast furnace efficiency. Furthermore, the sinter plant and the coke making plant are a source of huge environmental pollutants. Since low-grade Zimbabwean coal fines are also available in abundance, they were used in the preparation of the composite materials ensuring maximum utilisation of this resource. Results showed that the limonite ore-carbon composite pellets sample with the binary basicity ratio (CaO/SiO2) of about 0.27 and coal addition of 2.5 wt per cent achieved above the minimum physical quality requirements for pellet of drop number of at least 4, a dry compression strength greater than 2.2 kg/pellet and an indurated compression strength greater than 250 kg/pellet. Limestone was used as the binder avoiding the addition of more impurities from bentonite since the limonite ore has a high SiO2 content of about 8.78 wt per cent.

Sep 18, 2023