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By A. M. Hall

Sulphur, even in small amounts, may often be harmful to nickel and high-nickel alloys, causing impairment of mechanical strength and destruction of malleability and ductility, as shown by Merica and Waltenberg.l,2 It may act either in the form of nonmetallic inclusions produced in the liquid state during furnacing or as reaction products resulting from its diffusion into the solid metal. In recognizing the action of this element, ability to identify its various forms by means of the microscope is often of considerable importance, especially when direct quantitative methods are inapplicable. Of the sulphur compounds associated with nickel and high-nickel alloys, the sulphides that may be found in malleable nickel, Monelt and Inconel are an important group. These sulphides were investi- gated by metallographic methods in order to provide descriptive data by which to identify them. The nominal compositions of malleable nickel, Monel and Inconel are given in Table I. The term "sulphide" is employed here in a very general sense, to designate a substance in which sulphur and one or more metallic elements are combined. The term includes any combinations of compounds and solid solutions. Method of Investigation Three groups of small laboratory melts were made, one group to represent each of the three types of alloy under investigation. Within each group, a number of ingots with a sufficient variety of chemical analyses were prepared so that the effect of each of the elements entering the complete commercial alloy could be isolated and observed. In most cases, to facilitate metallographic study by exaggerating the number and size of the resulting sulphides, somewhat greater amounts of the minor elements were added than are present in the commercial alloys. Likewise, considerably more sulphur was added than is normal, but not enough to complicate the system. Transverse sections were cut at a point one third of the distance from the butt to the head of each ingot, polished and examined with an inverted stage metallo-graph equipped with a combination polar -izing-analyzing vertical illuminator. The light source was a tungsten-mercury vapor arc lamp.

Jan 1, 1943

By U B. Pal

Downsizing and decommissioning of nuclear facility operations is increasing the stockpile of various different grades of Radioactive Scrap Iron (RSI). Disposal of this material not only represents significant resource and value lost, but also necessitates long term monitoring for environmental compliance. The latter results in additional recurring expense. It is desirable to be able to decontaminate the RSI to a very low level that can be recycled or used for fabrication of containers for RSI disposal instead of using virgin metal to fabricate the container. Electro-Slag Remelting and Refining (ESR) is often used for decontaminating radioactive contaminated sources of scrap iron such as stainless steel. Non-radioactive oxides of cerium are used to simulate the radioactive oxide contaminants of Uranium and Plutonium. The success of the ESR process is strongly dependent on the capacity of the slag to rapidly incorporate the radioactive contaminant (simulant). In this study we have measured the slag-metal partition coefficient for cerium and investigated the reaction mechanism for the dissolution CeO, in the slag.

Jan 1, 2002

By D. McElhinney, J. Winfield, G. Buchan, B. Slaker, A. Iannacchione, T. Minoski, G. Rashed, M. Van Dyke, M. Murphy

"The National Institute for Occupational Safety and Health (NIOSH) has previously established pillar design guidelines for the underground stone mining industry. These guidelines were created from an empirical database of pillar observations and were largely drawn from shallow, flat-lying mining operations. Current trends forecast a great amount of underground stone mines developing under deeper cover, higher seam dips, and more frequent multiple-seam mining configurations than in the past. The complex loading conditions and limited experience in these environments presents a substantial increased risk of ground failure. To investigate these loading conditions, NIOSH has installed a pillar and roof monitoring system at an underground limestone mine in central Pennsylvania. The mine is operating in a seam with dips ranging from 13 to 18 degrees and overburdens ranging from 275 m (900 ft) to 425 m (1,400 ft). Instrumentation installed in an undeveloped pillar and in surrounding strata is currently measuring pillar and roof behavior in response to stress redistribution during excavation. Laser scans are being used to measure ground displacement and changes in conditions associated with local mining conditions and significant geological features. Initial stress measurements show a gradual increase in stress in response to mining, and stress changes that correspond with blasts. The seismic system is operational, with calibration events signaling on each of the 18 sensors. INTRODUCTION Improving mine-wide ground control stability can help reduce the potential for catastrophic failure of underground structures. The National Institute for Occupational Safety and Health (NIOSH) has conducted prior research in stone pillar design and has established fundamental pillar design guidelines for the underground stone mining industry, which resulted in the development of the S-Pillar program (Esterhuizen et al., 2011; Esterhuizen and Murphy, 2015). The data that constitute the S-Pillar program were derived from past mining experience that was almost exclusively drawn from shallow, flat-lying, single-level mining operations1. Stakeholder interactions with NIOSH researchers have indicated that increased numbers of underground stone operations are expected to mine under significantly deeper cover, with greater seam dips, and under multi-level operating conditions (Slaker and Murphy, 2016). The complex loading conditions and limited experience in these challenging environments present a substantial increased risk of ground failure. Inadequate pillar design in these new and challenging environments could result in catastrophic wide-area pillar collapses and an increased safety burden to miners working in the U.S. limestone mining industry. To develop design guidelines and prevent inadequate pillar designs for these challenging environments, NIOSH is currently conducting detailed pillar response investigations at case-study mine sites operating in challenging environments."

Jan 1, 2018

By B. McFadzean, M. Tadie, T. Dzingai, M. Becker

Ores from a single deposit may exhibit extensive variability in their mineralogy and texture. The ability to quantify this variability and link it to mineral processing performance is one of the primary goals of process mineralogy. This study focuses on the effect of alteration in three platinum group element ore samples from the Great Dyke in Zimbabwe – two of which were more pristine compared to the third, which was locally classified as ‘oxidized’ ore. These ores are known to be characterized by varying degrees of alteration, resulting in numerous challenges in flotation and affecting both grade and recovery. Alteration, by near-surface oxidation, of the valuable base metal sulphides and platinum group minerals resulted in lower flotation recoveries of Cu, Ni, Pt, and Pd. Evidence of incipient oxidation was more readily observed in the base metal sulphide assemblage than the platinum group mineral assemblage, even though the loss in recovery (because of oxidation) was most significant for Pd. Alteration through hydration resulted in a significant increase in mass pull and dilution of concentrate grade through the inadvertent recovery of naturally floating gangue comprising composite orthopyroxene and talc particles. In this study, the amount of naturally floating gangue was more strongly correlated with the talc grain size distribution than the grade of talc in the flotation feed. The oxidation and hydration alteration reactions are not necessarily mutually exclusive, although one may be more dominant than the other, giving rise to ore variability.

Sep 1, 2021

By J. M. Stuve

Calorimetric data for the dissolution of scandium sesquioxide and scandium trichloride in 4.360 molal hydrochloric acid were used to evaluate the standard heat of formation of ScCl3(c). The heat of reaction for Sc(c) + 1.5Cl2(g) = ScCl3(c) at 298.15° K was computed as -225,440 ±340 cal/mole.

Jan 1, 1965

By T. R. Rehak

Blasting operations are an essential element in the recovery of our Nation?s mineral resources. The mining industry uses billions of pounds of explosives annually. The majority of blasting occurs in surface mining operations. Blasting results in the fragmentation and often the projection of rocks. Frequently, the rocks are thrown beyond the expected limits. Flyrock and failure to secure the blasting area dominate blasting-related accidents in mining, especially in surface mining. Blasting accidents in the mining industry tend to result in critical injuries or fatalities. Accident reports and information collected from the Mine Safety and Health Administration (MSHA) and other government agencies provide supporting evidence. According to the data collected, blasting-related accidents (in mining) were 11 times more severe than all other types of mining accidents. Blasting accidents are not unique to mining operations - the same situation exists in the construction field. In this paper the authors have compiled a list of the primary causes of flyrock and the failure to secure the blast area. In the next phase of this project, typical blasting scenarios will be reviewed which will highlight the main reasons flyrock and/or lack of blast area security occur. This will alert miners and construction workers to the current problems/hazards associated with blasting and to identify other safety measures to protect personnel.

Jan 1, 2000

By T. Hofbauer, M. J. Dry, G. B. Harris, C. W. White

"Urban Mining is a term that is increasingly being used, and represents an appreciable source of secondary materials for the metals extraction industry, a source that does not incur mining costs, but does, at present, incur considerable disposal costs. Electric Arc Furnace Dust (EAFD) is probably the most common of these materials, with an estimated global production of 8 million tonnes annually, of which 1 million tonnes is generated in North America. The contained annual metal value in EAFD at current prices is of the order of $6 billion, yet, apart from the zinc, virtually none of this is recovered.Despite many attempts over the years, with pyrometallurgical, hydrometallurgical or hybrid processes, currently the only commercially viable method of treating these materials is smelting in a Waelz Kiln (or a Rotary Hearth Furnace), which essentially recovers only the zinc, in an impure oxide form, and generates a secondary slag waste, which is still toxic and requires disposal. This paper describes the development of a chloride-based treatment process to recover all components of the EAFD in a marketable form, which centres around the novel hydrochloric acid recovery and recycle operation. Laboratory, miniplant and pilot plant data are presented, leading to the definition of a viable process flowsheet enabling the recovery of pure iron and zinc products (the principal components of EAFD), together with secondary products such as copper, silver, lead, cadmium, magnesium and manganese. A rigorous mass-energy balance is used to examine the preliminary economics involved."

Jan 1, 2014

By D. P. McDonald

"IntroductionTHE PURPOSE of this paper is to present .a summary of the evidence given before the Petroleum and Natural Gas Conservation Board in support of applications to it for permits to export natural gas from Alberta.I will attempt to be objective in my statements, despite the fact that my main interest in the hearings before the Board was to advance the interests of my own clients, the Westcoast Transmission Company, Limited.The hearing of the export applications •commenced before the Board in January, 1950, with the .application of the Westcoast Transmission Company. Joint hearings were commenced in September, 1950, and completed on December 14th, 1951. The Board heard evidence in support of six applications for export, one application to build a gathering system in Alberta, and three interveners, the .latter being the City of Calgary, the local gas companies, .and the coal interests, including both operators of coal mines and the Unions.The evidence comprised better than 8,400 pages, over two million words, and occupied 92 days before the Board.The Interest in Natural GasThe natural gas industry is one of the newer industries. It is not yet twenty years •old. In the United States, the expansion •of pipeline facilities has been phenomenal in the last fifteen years, and particularly in the last three years, when a total of over two billion dollars was invested in pipeline facilities. There are approximately 250,000 miles of gas transmission pipelines in the United States at this time, with additional lines constantly being pressed."

Jan 1, 1952

By Heribert F. Broicher

As of 1998 German companies have been engaged in research and development of LIF analyzers for rock identification, i.e. for the fingerprinting of rock by the analysis of laser-induced fluorescence (LIF). Test work in Germany, Sweden and South Africa showed the potential of this new technique, which operates online and in realtime (1). In 2003 the Finnish company IMA Engineering Ltd Oy commenced building and marketing LIF analyzers under the trade name OreSpex. Today, one OreSpex analyzer has been installed in the Kiruna Mine, Sweden to check the phosphorus content of train loads. In 2004 a second OreSpex analyzer was built for dilution control in the Argyle Diamond mine, Australia. In 2005 another LIF analyzer will be used for test work in various mines in the US. The principles of the technology and status of ongoing work are presented.

Jan 1, 2005

By W. Z. Yin

With increasing of mining depth, many iron ores in Liaoning Province contain carbonates such as siderite and ankerite. The emergence of these carbonates in ores creates a fatal impact on the running producing process of anionic reverse flotation in Dong Anshan Sintering Plant, which leads to ?concentrate and tailing no separated?. And its reason is still unknown. Moreover, siderite, despite that its ferric theoretic grade is only 48.2%, however, do not affect the blast furnace utilization factor, therefore, can be used as raw materials in ironmaking. In order to solve the separate problem of iron ore containing carbonates, five pure minerals, martite, magnetite, quartz, siderite and ankerite, were selected for a series single flotation experiment. The aim was to discover the flotation difference of these minerals, furthermore, to explore a new flow sheet for the iron ore containing carbonates. The results of single mineral flotation experiment reveal that the combination regulators, starch and CaCl2, in different pH extent, can make these minerals taking on obvious flotation difference, which make it possible to process the iron ore containing carbonates. A new flow sheet, step-flotation, to process iron ore containing carbonates is explored, that is, first step, direct-flotation processing, is to eliminate the bad effect that the carbonates bring in flotation system by collecting carbonates under neutral condition; the second step, reverse?flotation processing, is to get qualified iron concentrate by collecting quartz under alkaline condition. Manual mixed ore sample were processed successfully through this new flowsheet under proper reagent system, which has absolute advantage compared with routine flowsheet. Actual ore sample of compound magnetic separation concentrate were processed successfully both open and closed circuit experiment through this new flowsheet. SEM and EDS were used to probe the reason why carbonates affect the regular processing. It is analyzed that moderate floatability of siderite and its coating on the surface of hematite and quartz make the phenomenon ?concentrate and tailing no separated?. This research provides a reasonable processing scheme for iron ores containing carbonates and can be used for reference in processing other complicated, refractory iron ore.

Jan 1, 2014

By Willy Ank de Morais

Pontos estratégicos de solos foram analisados com o objetivo de estudar a possível contaminação de água pluvial, por difusividade, mantidas em reservatórios existentes na Ilha dos Arvoredos, localizada no Guarujá, litoral de São Paulo, Brasil. Iniciou-se o procedimento com a preparação das amostras (homogeneização e quarteamento), seguida das análises físicas (granulometria e umidade). A caracterização foi realizada por espectrometria de fluorescência de Raio-X e por espectrometria de absorção atômica. As concentrações de enxofre foram quantificadas por forno de combustão e as cinzas e matéria volátil por TGA (Analisador Termogravimétrico). As análises realizadas em Raio –X mostraram composição química de solo argiloso com altas concentrações de SiO2 e Al2O3 e as realizadas no equipamento de combustão mostraram concentrações de enxofre menores que 0,03%. Os resultados se apresentaram negativos para metais pesados ou outro tipo de elemento que poderia comprometer a potabilidade das águas contidas nos reservatórios.

Oct 30, 2017

By Rogerio Martelli

Os mancais de rolamento dos rolos secadores da linha de estanhamento eletrolítico da CSN são expostos a severa contaminação por água e ácido sulfúrico. O tempo médio entre falhas (MTBF) de cada rolamento da linha é de apenas 30 dias. A CSN aceitou realização de teste com um par de rolamentos autocompensadores de rolos vedados que foram montados em um rolo, com a supervisão da SKF. Os rolamentos do teste operaram por mais de 150 dias, apresentando sobrevida superior a 400% até o momento, sendo que ainda continuam em operação. Há cerca de 60 rolamentos operando simultaneamente na linha, sendo que a solução poderá ser replicada para os demais pontos, aumentando a vida em serviço dos rolamentos e reduzindo custos de manutenção.

Oct 30, 2017

By Alisson Rodrigo dos Santos

O presente trabalho objetiva analisar a viabilidade técnica de recuperar parte do pó de balão, composto por finos de carvão e hematita, submetido primeiramente a tratamento termoquímico e posteriormente a campo magnético uniforme. Foram analisadas amostras oriundas de pó de balão de alto forno funcionando com carvão mineral e alto forno com carvão vegetal. Os finos de carvão, recuperados na separação magnética, podem ser utilizados na sinterização, pelotização e até mesmo reinjetados nas ventaneiras. Essa reutilização tem um efeito muito importante, pois cada tonelada de fino carregado pela ventaneira corresponde a uma economia de carvão que não será carregado pelo topo, deixando mais volume útil livre para a carga de minério. O pó de balão foi submetido a um processo de redução da hematita em magnetita, em atmosfera adequada para a preservação de carbono, a fim de aumentar a susceptibilidade magnética e permitir a separação magnética. Os finos de minério residuais da recuperação dos finos de carvão não são perdidos, podem ser utilizados na fabricação de briquetes ou reutilizado na sinterização e pelotização. Após a redução, o material foi submetido à separação magnética, mostrando-se assim viável tecnicamente a separação e reaproveitamento dos finos de carvão e minério.

Oct 30, 2017

By V. E. Edlund

As part of its efforts to devise new and improved methods for recovering lithium from unconventional resources , the Bureau of Mines investigated a lime -gypsum- roast , water- leach technique for processing lithiumenriched ( 0.01-0.68 pct Li ) clays . This report presents the results of a study of the technical feasibility of extracting lithium from raw material representative of clay beds associated with the McDermitt Caldera complex in Nevada and Oregon . prepared from water used Pellets suitable for bench-scale roasting studies were mixtures of minus 200 -mesh clay , limestone , and gypsum , with as the pelletizing agent . Roasting pelletized charges at 900 ° to 1,000° C temperatures for 1- to 4-h periods produced calcines that leached readily , yielding water - soluble lithium sulfate ( Li₂SO4 ) . A 5-3-3 ( weight ratio ) mix of clay , limestone , and gypsum produced calcines with the best leaching characteristics . More than 91 pct of the contained lithium was extracted from pelletized mix batches roasted in covered refractory boats . Lithium recovery decreased to about 87 pct when the mix was roasted under dynamic conditions in a gas - fired rotary furnace . A reaction mechanism was postulated which indicated that dilution and loss of SO2 and oxygen in the combustion exhaust adversely affected the leachability of the dynamically roasted calcine .

Jan 1, 1983

"The North Star and Don Jon copper deposits lie beneath the waters of Thompson Lake, which is 12 miles east of Flin Flon, Manitoba. The deposits were discovered during the years 1949 and 1951 by diamond drilling done in the vicinity of pyritic showings on the shores of two small islands in the lake. The Don Jon ore body lies 1, 700 feet southeast of the North Star orebody and is connected with the North Star mine workings by a crosscut on the 600-foot level (Figure 1 ).Production began on January 1, 1955, at a combined rate of 200 tons per day. The ore is trucked, on 24 miles of highway, to the Hudson Bay Mining and Smelting Co., Limited mill at Flin Flon.Regional GeologyRocks in the Thompson Lake area are Precambrian volcanics, ranging in composition from andesite to rhyolite, with related tuffs and breccia. These rocks have a general north-south trend and are steeply dipping. The area is part of the Lac Aimee fault block, which probably is the southward extension of a south-plunging syncline now thrust some miles to the north. This regional deformation has produced many subsidiary zones of intense shearing and crumpling. It is in two of these zones of shearing and drag-folding that the orebodies occur. The only recognizable intrusive is a narrow diorite sill which trends northeasterly near the west shore of Thompson Lake.The North Star MineA pyritic showing, carrying some chalcopyrite, was discovered around the year 1930 on the west side of a small island near the west shore of Thompson Lake. This ground was included in a group of claims acquired by the Hudson Bay Exploration and Development Co., Limited in 1947.In the years 1949 to 1951, a diamond drilling program outlined a copper sulphide orebody. This ore zone comes to surface beneath the lake, about 300 feet north of the pyritic showing on the island."

Jan 1, 1949

By Nicolas Moscoso, Gerald Verbeek, Marcel Bielefeld, Rob van Dorp

Upon recently, most offshore foundations were based on a number of driven piles that were installed with an impact hammer. With the increase in offshore windfarms two major developments have occurred: the shift from jackets to monopiles, leading to increase of the diameter of the foundation piles, and a shift from impact hammers to vibro hammers. As the use of vibratory hammers is becoming more and more common practice, the need for accurate vibro-driving simulation software has increased, which requires that the soil modelling is enhanced to address soil fatigue during pile driving and to predict reliably the soil behavior and resistance during pile driving. In addition pile driving monitoring, which is routine for piles driven with an impact hammer, needs to become common practice. This paper addresses advances in soil modelling that allows more accurate pile driving simulation as well as the application of Vibro Driving Analysis (VDA) or Monitoring (VDM) to validate the simulation results. This is illustrated by a case study of the test pile for the Delft Offshore Turbine project, a 28 m long monopile with a diameter of 4 m that was driven 15 m into dense sand layers using a vibro hammer. After some 6 months the pile was extracted, and pile driving simulations and VDA were done both for the installation and extraction phase. 1. INTRODUCTION At the end of 2017, the total worldwide offshore wind power capacity was 18.8 GW [1]. The vast majority of offshore wind farms are currently in Northern Europe, which together account for over two thirds of the total offshore wind power installed worldwide, followed by East Asia, while developments in North America are still in very early stages.

Jan 1, 2019

By Tatiane Haskel

A utilização de ligas Al-Si tem se expandido industrialmente principalmente no setor automobilístico. Cabeçotes, blocos de motor, rodas entre outros são exemplos de componentes produzidos com essas ligas. Estes componentes normalmente estão sujeitos a carregamento cíclico. O objetivo desse trabalho foi estudar o comportamento da liga A356 utilizando corpos de provas submetidos à fadiga por flexão rotativa nas condições brutas de fundição e tratadas termicamente por T6. Corpos de prova para ensaios de tração e de fadiga foram obtidos por fundição por gravidade em coquilhas. A comparação dos resultados foi realizada com os resultados do limite de resistência, do limite de escoamento, do alongamento e das curvas S-N. Adicionalmente análises fractográficas foram realizadas para verificar o comportamento de fratura. A liga tratada termicamente apresentou melhores resultados no ensaio de tração e de fadiga na faixa de 103<N<107.

Aug 16, 2017

By Luís Carlos da Silva

Apresenta-se uma revisão das características e propriedades do nitreto cúbico de boro (cBN) bem como de diferentes tipos de processamento. A influência da adição de ligantes e a formação de compósitos com outras cerâmicas são também revistas. Finalmente, destaca-se a grande importância prática do cBN como cerâmica de elevada dureza na substituição do diamante em ferramentas de corte.

Oct 30, 2017

By Heinrich CA, Wall VJ, Walshe JL

The Porgera Gold Mine, located in the highlands of Papua New Guinea, has produced over 5 million ounces of Au, since its opening in late 1990. The deposit is located within Upper Cretaceous Papuan Platform sediments approximately 25 km south of the Lagaip Fault, and is spatially and temporally associated with the 6 Ma alkaline Porgera Intrusive Complex.

Jan 1, 1995

By Ali Nadir Khan

Depleting copper resources and advancing technologies have challenged industries to develop more viable, adaptable and cost efficient processes using also secondary raw materials in copper production. This study is targeting to that goal by dynamic modelling of flow and heat transfer coupled with chemical kinetics in an industrial scale flash smelting furnace settler using commercial CFD software ANSYS Fluent. First, different physical phenomena occurring inside the settler, for example, settling and separation of the matte/slag phases, and heat transfer between slag/matte phases and settler walls are studied. Secondly, reaction kinetics between matte and slag, and between slag/matte and settler walls, and impurity element distribution will be studied. This would also include phase changes phenomena due to these reactions and the flow of the reaction gases inside the settler. Settling of polydispersed droplets, their coagulation, breakage, and WEEE particle behavior are further targets of the modelling work.