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By Myron A. Pugacz, Frank S. McKenna, Clarence E. Jackson

The notched-bar impact test has proved worth while in certain applications as a test for control of the quality or the heat-treatment of steel. In view of the serious thought that even so simple a test as the tensile test has evoked during the past years, it is not surprising that the notched-bar impact test should have inspired much experimental work. The correlation of the great number of data has not been successful, although steady progress has been made toward a better understanding of this test. Progress has been made, especially, in the isolation of the effects of the many variables that control the results. The stress system imposed on a specimen with a notch is so complicated and unpredictable that no simple evaluation of the test has been possible. Because of this uncertainty, many engineers hesitate to use the notched-bar impact test, and this attitude may well continue until a better understanding of the effects of the variables in the test are available. Without doubt, any additional data that may be presented should be accompanied by as complete a description of the - details of test as possible, so that it may be added to the general fund of information that is to serve as the basis for the theory of the notched-bar impact test. The many factors that may control the test results have been pointed out repeatedly. The importance of the effect of the type and dimensions of the specimen has been recognized. Most of the work reported by American investigators has been limited to small-size (Charpy) specimens tested as a simple beam; two types of notches (Fig. I) have been commonly used. Considerable data have also been presented by many investigators using a small specimen tested as a cantilever beam; this commonly being called the Izod test. Here, however, a shear component of stress makes the stress system even more complex than that present in the simple beam type of test, hence a critical analysis is difficult. Much work has also been reported by investigators using the tension type of specimen. A second variable that must be controlled is the testing temperature. An indication that the tests were performed at room temperature is not sufficient, since in many steels a variation of a few degrees in the actual testing temperature may be sufficient to give an entirely different range of results. Other factors, such as the composition and condition of the material being tested and the speed of test, should also be considered. Many investigators have contributed data and theoretical discussions on the problems encountered in notched-bar test-

Jan 1, 1944

By Frank S. McKenna, Myron A. Pugacz, Clarence E. Jackson

The notched-bar impact test has proved worth while in certain applications as a test for control of the quality or the heat-treatment of steel. In view of the serious thought that even so simple a test as the tensile test has evoked during the past years, it is not surprising that the notched-bar impact test should have inspired much experimental work. The correlation of the great number of data has not been successful, although steady progress has been made toward a better understanding of this test. Progress has been made, especially, in the isolation of the effects of the many variables that control the results. The stress system imposed on a specimen with a notch is so complicated and unpredictable that no simple evaluation of the test has been possible. Because of this uncertainty, many engineers hesitate to use the notched-bar impact test, and this attitude may well continue until a better understanding of the effects of the variables in the test are available. Without doubt, any additional data that may be presented should be accompanied by as complete a description of the - details of test as possible, so that it may be added to the general fund of information that is to serve as the basis for the theory of the notched-bar impact test. The many factors that may control the test results have been pointed out repeatedly. The importance of the effect of the type and dimensions of the specimen has been recognized. Most of the work reported by American investigators has been limited to small-size (Charpy) specimens tested as a simple beam; two types of notches (Fig. I) have been commonly used. Considerable data have also been presented by many investigators using a small specimen tested as a cantilever beam; this commonly being called the Izod test. Here, however, a shear component of stress makes the stress system even more complex than that present in the simple beam type of test, hence a critical analysis is difficult. Much work has also been reported by investigators using the tension type of specimen. A second variable that must be controlled is the testing temperature. An indication that the tests were performed at room temperature is not sufficient, since in many steels a variation of a few degrees in the actual testing temperature may be sufficient to give an entirely different range of results. Other factors, such as the composition and condition of the material being tested and the speed of test, should also be considered. Many investigators have contributed data and theoretical discussions on the problems encountered in notched-bar test-

Jan 1, 1944

By D. L. Wood

This investigation was concerned with the aluminum-oxide particle dispersions, the mechanical properties, and the re-c,uystallization characteristics of some internally oxidized copper-aluminum alloys. Obserued hardness vaviations are in agreement with variations in oxide particle size revealed by electron metallographic studies. The increase in yield strength caused by internal oxidation is quite sensitive to matrix grain size and is accompanied by a loss of ductility, particularly at higher temperatures. Elevated temperature ductility is con-side,vably improved if major grain reorientation is accomplished by ve recrystallization prior to testing. The oxide particles offer a considerable restraint to softening during annealing after cold deformation. THE diffusion of oxygen under appropriate conditions into a suitable alloy causes solute oxide particles to be precipitated at an inward moving interface.1,2 Previous work has shown that the hardness

Jan 1, 1960

By Carlos Sánchez

El presente trabajo señala la experiencia de Southern Perú en la implementación de herramientas hidro informáticas para la gestión de recursos hídricos en minería. En ese sentido, se muestra la implementación de las redes de estaciones meteorológicas y limingráficas, los sistemas de SCADA para el control de la distribución de agua, así como la integración de la información dentro de un sistema de información geográfica y como parte de las herramientas se describe la integración de modelos matemáticos al sistema de gestión. Por ello, los actuales cuestionamientos a la minería relacionados con el manejo del agua, requieren que las empresas del sector minero realicen una adecuada gestión de los recursos hídricos mediante la implementación de tecnologías de punta.

Sep 21, 2013

By Andrew Cushing, Joe Carvalho, Jon Hurt

"INTRODUCTIONThe shales of the Greater Toronto Area (GTA) have been known to experience time-dependent deformations (TDD); those initiated by excavation-induced stress relief which progress with time as a function of rock porewater salinity, access to freshwater (or air) of lower salinity, clay and calcite content, and the buildup of swelling pressures within the rock mass. These deformations can induce long-term pressures on shaft walls and tunnel linings, especially if the permanent works are constructed soon after excavation, with very little time delay. This paper presents measurements of time dependent deformation of recent shaft and tunnel projects constructed in the GTA, and draws conclusions regarding the main influences on the TDD. The key input parameters for the numerical predictive model are critically assessed. Projects which are discussed include the Billy Bishop Airport Pedestrian Tunnel, Hydro One Midtown Tunnel and Hanlan Feedermain (Contract 3).MECHANISM OF TIME DEPENDENT DEFORMATIONExplanation of MechanismThe Georgian Bay Shale unit consists of typically moderately weathered to fresh, grey to dark grey, fine to very fine grained fissile shale interbedded with slightly weathered to fresh grey, fine grained calcareous siltstone and limestone interbeds. There are two distinctive features of the shale in the Greater Toronto Area (GTA). One is a high horizontal stress regime, and the second is long-term time dependent swelling behavior which develops when the following factors occur (Lo and Micic, 2010):• Stress relief of the rock mass• Outward salt concentration gradient from pore fluid of the rock to the ambient fluid• Availability of fresh waterThe swelling is a consequence of the reduction in confined stress in the rock which occurs upon excavation in combination with a differential gradient in salinity between the saline rock porewater and freshwater or even humid air. Osmotic and diffusive processes result in a decrease in the salinity of the rock porewater achieved by an overall increase in the water content, resulting in volumetric expansion of the shale rock over time. The development of this time dependent deformation (TDD) relative to the time"

Jan 1, 2016

By A. M. Gaudin

THIS paper presents, with the help of colored photomicrographs, the new method of mineral identification termed "selective iridescent filming." This method pertains to the field of determinative mineralogy, which it provides with tools for: (1) phase identification, (2) solid solution analysis. The method should be particularly useful in the applied fields of: (1) paragenesis of ore deposits, (2) mineral dressing, (3) mineral synthesis and study of phase equilibria.

Jan 1, 1938

Discovered in 1896, the Sons of Gwalia orebody is located in a ductile mylonite zone within a sequence of Archaean pillow metabasalts and minor metasediments of greenschist facies which are variably sheared.The ore zone has good continuity, being 110 m wide and 500 m long, dipping 45 degrees east and plunging 70 degrees to the south to a depth of 1500 m downplunge. A strongly-developed foliation is present together with a prominent lineation paralleling the plunge. The mylonite zone consists of unmineralised chlorite schist and a 'U' shaped mineralised zone of chlorite-sericite schist with varying amounts of quartz-carbonate as veins parallel to foliation, boudins, and locally as massive quartz-carbonate. Pyrite is the dominant sulphide present.Grade control utilises RC holes on a 10 m x 10 m pattern, with infill blast rig holes 5 m deep where necessary.Some visual control of ore boundaries is present and, combined with good ore continuity and a knowledge of the structure of the orebody, enables cost-effective grade control to be achieved. To-date, over three million ounces of gold have been produced from the orebody.

Jan 1, 1993

By G. J. de Korte

South Africa is reliant on coal for the generation of almost all the electricity used in the country, and several large industrial concerns such as Sasol are also coal based. Research relating to the mining, beneficiation and utilization of coal is important in order to ensure the optimal exploitation and use of coal within the country. The Fuel Research Institute (FRI) of South Africa was established in 1930 to investigate all aspects of coal beneficiation and utilization in South Africa. The FRI went on to conduct world-class research and in 1957 a pilot coal preparation plant was constructed in Pretoria to enable large-scale practical experimentation. The pilot plant played a pivotal role in the establishment of South Africa?s low ash coal export project. Political and economic factors contributed to the eventual closure of the FRI and South Africa experienced a period of about 10 years between 1990 and 1999 during which very little public coal preparation research was done. This changed for the better towards the end of 1999 when Coaltech 2020, a collaborative research program was established. Participants included the CSIR, universities, the government and the major coal producers. Coal preparation research conducted under Coaltech thus far include dewatering and drying of fine coal, size classification of ultra-fine coal and dense-medium fine coal beneficiation. Currently, the Coaltech focus is on the beneficiation of low-grade coal reserves and is investigating existing as well as new techniques that can be utilized to provide cost-effective beneficiation of low-grade raw coals and reject coals.

Jan 1, 2010

By L. E. Schultze

Experiments were conducted by the U.S. Bureau of Mines to verify enhancements due to chloride and surfactant additions in the leaching system of chalcopyrite with ferric sulfate and sulfuric acid. A statistical experimental design was used and equipment was designed to eliminate contributions from changes in solution electrochemical potential during the course of the measurements. Results confirmed that chloride additions increased chalcopyrite leaching by as much as 94 pct over the electrochemical potential versus hydrogen electrode range of 630 to 750 mV at pH 1.7 and 50°C. Total iron concentration had no effect over the range of 1 to 5 g/L. The effect of surfactant addition was less well defined. While additions of LA 790 (a polyoxyethylene lauryl ether) resulted in increased copper leaching in several of the tests, the differences were too small to be statistically significant. No interaction effect could be verified.

Jan 1, 2010

By J. V. Richards

(Canal Zone Meeting, November, 1910,) THE Altar district, State of Sonora, Mexico, is for the most part a desert with but little rain-fall and few running streams. On account of this scarcity of water it is necessary for the natives to " dry-wash" the placer-gravel, and the object of the present paper is to describe some of the more common Mexican dry-washing devices. My observations were confined to a property known as Las Palomas placers, 15 miles from the Gulf of California and about 150 miles south of the United States border; a brief description of which property may be of interest as illustrating what is, perhaps, a typical Sonora dry placer. It is said that as long as a century ago the Yaqui Indians discovered rich cement-gravel, known as argo masa, at Las Palomas, and that there has been a more or less steady production of gold from the property ever since. The argo masa is a fairly-coarse gravel, the pebbles being quite firmly held together with a lime cement. Gold is scattered through this cement in particles ranging from fine specks to pieces several grams in weight, and occasional large nuggets are encountered. The contents vary so widely that it is difficult to estimate the average value, but returns of from $10 to $50 per cubic yard are common, and it is doubtful if the Indians considered anything less than from $4 to $5 a yard as "pay dirt." This argo masa occurs in channels varying in thickness from a few inches to several feet, and in width up to 300 ft.. These channels are continuous and are probably ancient stream-beds. They are for the most part covered with an over-burden of a more recent gravel, varying from 30 to 50 ft. thick, and the fact that this over-burden contains values as high as $1.50 per cubic yard, and yet was not worked by the Indians, shows that their idea of what constituted pay-ground was high.

Apr 1, 1911

By Scott Hommema

? Bitumen in the oil sand averages Bitumen 12 wt%; water makes up 4 wt% ? Imperial Oil (operator) and ExxonMobil developing Kearl Leases #6, 36, 87 (~200 sq. km) ? Target resource > 4 Billion Barrels ? 3 Phase development, ~100 kbd per phase High-quality resource ? Surface mineable bitumen ? Average properties (full lease) ? TV:BIP < 8 ? Grade > 12 wt% bitumen ? Ore thickness of 40 m ? Overburden thickness of 20 m Status ? Phase 1 ? Front end engineering and design underway ? Detailed engineering to start 2008

May 1, 2008

By W. F., Netzeband

SEVERAL criteria have been used more or less successfully in finding and developing orebodies in this district. Among them is the relation of the fracture to the orebodies. It has been known for some time that there was some relation, but it has been but recently. that careful study has been given to this subject. Like all the criteria used in this district, this relationship must be used with caution, for what-is true in one part of the district is not necessarily true in another.

Jan 1, 1928

By M. Rylatt, E. Legault-Seguin, C. Mohns

"With energy costs increasing and ore grades diminishing, the role of preconcentration in hard-rock mining operations has gained greater interest. Dense medium separation is a process that can be conducted at particle sizes from 250 to 0.50 mm with high separation efficiency, depending on liberation characteristics of the valuable minerals. Pilot-plant case studies conducted at the SGS Lakefield site are presented, including mineral systems such as spodumene, sulfide-bearing gold ores, and complex sulfide ores. These case studies demonstrate that, for amenable ores, mass rejection of 20–60% is possible while maintaining recoveries of greater than 90%.RÉSUMÉ Au vu de la hausse des coûts liés à l’énergie et du déclin de la teneur des minerais, le rôle de la préconcentration dans les exploitations minières en roche dure présente un intérêt croissant. La séparation (ou concentration) en milieu dense est un processus pouvant être mené sur des calibres de grains de 250 à 0.50 mm avec un rendement élevé de séparation, en fonction des caractéristiques de libération des constituants des minéraux métallifères. Sont présentées dans cet article des études de cas menées dans des usines pilotes du site de Lakefield de SGS, lesquelles incluent des systèmes de minéraux tels que le spodumène, les minerais aurifères sulfurés et les minerais sulfurés complexes. Ces études de cas montrent que pour les minerais présentant les caractéristiques de libération appropriées, il est possible d’atteindre un rejet en masse de 20 à 60 %, tout en maintenant des récupérations supérieures à 90 %.INTRODUCTIONPreconcentration is the process of rejecting gangue minerals while ensuring recovery of valuable minerals prior to more intensive, downstream processing. Preconcentration has been practiced in the industry for many years, and is gaining greater interest as the industry copes with processing lower grade, more difficult ores, which typically require finer grind sizes and incur higher energy costs.The benefits of preconcentration are:• lower mining costs, which allows for nonselective mining;• lower process capital and operating costs (e.g., resulting from reduced grinding, flotation, and fines disposal stages);• increased ore reserves, which provides the potential to treat lower grade ore;• increased mine production without expansion of the existing plant or concentrator;• reduced overall tailings impoundment by converting the reject into a byproduct (e.g., underground backfill or aggregate);• improved efficiency of downstream processes (e.g., silica removal in electric arc furnace feed, removal of softer sliming minerals prior to grinding);• potential application to brownfield operations and greenfield projects; and• a “green” process option, which reduces processing energy consumption;– reduces mill feed;– increases stage metal recovery (higher grade feed);– increases mill metal output per tonne processed;– reduces surface plant, tailings dump, and tailings pond requirements because the plant has a small footprint and can be installed underground; and– can be applied to retreatment of old tailings dumps to recover metal values and reduce environmental impacts (e.g., dissolved metal runoff, acid drainage)."

Jan 1, 2017

Monitoring systems can have numerous uses in the mine. They can aid in the efficient management of the mine by providing environmental trend data, production and maintenance control, and communications. In some cases, they can provide justification to petition the Mine Safety and Health Administration (MSHA) fog a variance of one of the mandatory safety standards. They may also increase the gross revenues of the mine by increasing the amount of coal produced or increase profits by reducing the cost of producing that coal. No single system will satisfy the requirement of all mines. Some may require simple hard-wired status-reporting systems; others, multipurpose computer-based systems that collect, analyze, and store data and perhaps control some mine functions. Even though systems vary in complexity, they are all composed of three functional components. The first component is sensors that measure the environmental or production parameters and produce an electrical signal that is fed into the telemetry. The second is telemetry devices that receive the signal from the sensors and transmit it in either analog or digital format to the third com¬ponent, analysis and display equipment. This equipment receives the transmitted signal and either stores it for later analysis or displays it. The analysis-display equipment ranges from simple strip chart recorders with preset alarms to computers, cathode-ray tubes (CRT&apos;s), and line printers that can also provide production reports. 4.2 Uses of a Mine Monitoring System A list of potential uses for mine monitoring systems, including both production-related functions and those related to health and safety, was used to develop a questionnaire. It was presented to representatives of the mining community to determine their current monitoring priorities. The responses indicated that the industry&apos;s priorities fall into the following two categories: First priority- Production and haulage Maintenance Second priority- Ventilation Communication Fire monitoring Personnel The survey shows that production-oriented systems were the most appealing to the questionnaire respondents. Since even small improvements in production efficiency and maintenance can have a large financial impact, the desirability of monitoring systems that focus on these areas is understandable. The results are summarized in table 4-1. The function that scored 100 was viewed as the most beneficial monitoring function.

Jan 1, 1984

By L. Yarborough, L. R. Smith

This paper presents results of a laboratory study of retrograde condensate recovery by revaporization into dry injection gas. Flow tests were performed in 10.6-ft long sand packs at 100F and 1,500 psi. In three runs methane revaporized the liquid from a n-pentane-methane mixture in the presence of immobile water. TWO of these tests were water-wet, and the third was totally oil-wet. In the three runs n-pentane recovery was complete after 2.5 hydrocarbon PV of injection. There was no significant performance difference between the two wettability extremes. In a fourth experiment, a methane-hydrogen sulfide mixture revaporized a synthetic light, sour condensate. No water saturation was present. Equilibrium compositions and volumetric data were obtained for the four-component condensate. The heavy component, n-beptane, was removed after 6 PV production. Comparison of the effluent fluid compositions with known equilibrium data shows that the flowing fluid was equilibrium vapor and that the mixing zone between equilibrium vapor and dry injection gas was short. Data indicated that complete recovery of retrograde liquid occurred after it was contacted by a sufficient quantity of dry gas. INTRODUCTION When pressure declines below the fluid dew point in a gas condensate reservoir, a liquid phase forms. In this process, referred to as retrograde condensation, the quantity of liquid formed is frequently small enough that the liquid is not a flowing phase. To prevent loss of valuable retrograde liquids, the process of dry gas cycling has been employed for several years as a more or less standard practice. In this procedure the reservoir pressure is maintained above the fluid dew point so that the liquid components may be produced as vapor and then separated at the surface. Although full pressure maintenance by gas cycling seems ideal in terms of preventing liquids loss, several factors can reduce the atuactiveness of such an operation. From a study of a condensate reservoir in Alberta, Canada, Havlena et a1.1 con-cluded that cycling under conditions of declining pressure leads to economic advantages and to a high recovery of hydrocarbon liquids. This study considered effects of volumetric sweep efficiency, retrograde behavior of the original wet gas and revaporization characteristics of the retrograde liquid when contacted by dry gas. The first major work concerning revaporization of liquid in a gas condensate system is that of Standing et a1.2 Calculations based upon the PVT behavior of a recombined gas condensate fluid indicated that all retrograde liquid can be recovered if it is contacted by a sufficient quantity of dry gas. The paper considered the effect of variable permeability upon the recovery of retrograde liquid. Standing et al. concluded that recovery of heavier components in the retrograde liquid is greatest if reservoir pressure is allowed to decline below the dew point prior to dry gas injection. Since the work of Standing et al., several laboratory studies have been reported which show that recovery of hydrocarbon liquids by vaporization into dry injected gas can contribute to increased recovery above that obtained by ordinary production practices. Vaporization from retrograde condensate,3 conventional oil4-7 and volatile oil8 reservoirs has been considered. There is little work that deals with revaporization recovery from condensate reservoirs. This study demonstrates that vapor-liquid equilibrium exists when a dry gas is injected into a porous medium containing retrograde condensate; investigates the effect of wettability on revaporization of retrograde condensate; and provides an indication of the amount of dry gas necessary to

Jan 1, 1969

By R. E. Zimmerman

ALTHOUGH flotation of coal is considered relatively new in the United States by coal-preparation engineers, actually it has been practiced to some extent for the past 30 years, It is practiced much more widely in Europe than in the United States. Commercial plants are operating in nearly all major coal-producing countries of the world. A froth flotation plant has been operating since 1930 at the Champion No, 1 preparation plant of the Pittsburgh Coal Co. Unfortunately the term flotation is widely used in the United States by coal-preparation engineers to designate dense medium processes of coal cleaning. As used here, flotation means those processes for cleaning fine sizes of coal in which the coal is collected in a froth or matte at or near the surface of a pulp. The refuse particles remain in the pulp. Two distinct types of flotation are practiced: froth flotation and agglomeration. FORMS OF FLOTATION The theory of the principles of flotation and of the physicochemical foundations surrounding this process has become a complex and scientific field and coal-preparation engineers contemplating use of flotation processes would do well to study the works of Gaudin, 2, 5 Taggart, 3 Zimmerman, 4 Wark, 6 Ralston, 7 Petersen. 8 Bulk Oil Flotation.-In this process the separation of mineral from gangue is accomplished by virtue of the fact that minerals of metallic lustre, as sulphides, or hydrocarbons, as coal and graphite, are wetted preferentially by oil in the presence of water and consequently pass into the interface between oil and water; while gangue or rock is wetted by water and remains in the medium. Beginning in 1860 with Haynes and later between 1897 and 1907, at least 25 patents were granted for bulk oil flotation. Large quantities of oil are required, generally 3 to 25 per cent by weight of feed, and recovery of such oil is a major problem. The Elmore process 3 (1901 and 1902) is an example of a bulk oil process, The Trent process (1902-25) has been used for the cleaning of coal on a commercial scale, According to E. W, Davidson 9 there were five such plants operating in the United States by 1925. They have since been abandoned.

Jan 1, 1950

By Howard C. Turnage, Dana T. Updyke

An evaluation was made of one of several improved underground communication systems sponsored by the U.S. Bureau of Mines. The system evaluated was installed in a typical metal/non-metal room and pillar mine and utilized UHF repeaters connected to a unique distributed antenna and passive reflector system which provided mine-wide communications. A microprocessor controlled data collection system was assembled and installed for the evaluation. Data consisting principally of times and durations of messages and identities of the originating transceivers was collected between February and August of 1982 (6 mos.). Analysis of the data shows that the principal benefits are reduction in time required for unscheduled maintenance and repair, enhancement of safety, and better coordination of production activities. A cost benefit analysis shows a net benefit over cost, although it is also concluded that the capacity of the system is greater than can be justified by current activity in the mine.

Jan 2, 1983

By W. Zheng

Pipelines can develop stress corrosion cracks in either intergranular or transgranular form. Since the mid-1980s, numerous colonies of transgranular cracks have been found across Canada and many other countries in the world. While the intergranular form of cracking has been well studied in the past 40 years, the mechanisms governing SCC in near-neutral pH environment, i.e., the transgranular form of the cracking, are yet to be understood in greater depth. Over the past ten years or so, a large number of research publications have been available on this subject and this paper summarize our latest progress in understanding the mechanistic aspect of the problem. Better understanding of the role of mill scale surface and the steel metallurgy in crack initiation has been indicated in the recent literature. However, the initiation of SCC in the lab research still relies on loading conditions that are far more aggressive than those encountered in the field. Most crack growth studies in the past are also performed under very aggressive mechanical conditions, which could have prevented the observation of environment effects. However, more recent research at lower K or Delta K ranges seems to suggest a strong role of the environment. Naturally, modeling of growth should reflect the effect of the environment, steel metallurgy, and the changing mechanical properties of the pipe steel with time. For a specific steel in a given environment, the crack growth rates tended to increase with the strain rate, indicated either by the nominal applied loading frequency or by the calculated crack tip opening rate. Future research needs to address the issue of concurrent growth of multiple interacting cracks. More attention should also be given to concurrent initiation of multiple cracks in a colony, as failure is usually caused by a coalesced crack not by an individual crack. The effect of soil environment should not be limited to the chemistry of soil solution; other factors such as cathodic processes, the variation of environment with time and physical conditions of coatings should also be considered as part of the study.

Jan 1, 2005

By J. B. Scuffham, G. Eggett, W. R. Hopkins

With solvent extraction now being accepted as a major method for recovering copper from leach liquors, the authors&apos; company decided that in tankhouse design full advantage was not being taken of the benefits available from sol- vent extraction produced electrolytes. Consequently, a major development program was undertaken to examine means of operating such tankhouses with current densities in excess of current electrowinning practice. Techniques investigated included high circulation of liquors, current reversal and the application of ultrasonics. At the same time there was a necessity for improving the quality of cathodes produced from electrolytes of high free acid content. The application of anodes which are capable of reducing or eliminating the lead content of cathodes is described in the paper. The other problem area in eletrowinning from solvent extraction produced electrolytes is the production of a higher degree of acid mist. Techniques for alleviating this problem are described bearing in mind their possible effects on the solvent extraction section of the plant.

Jan 1, 1973

By J. E. Lamar, J. S. Machin

INSULATING materials include a wide variety of nonmetallic mineral products such as exfoliated vermiculite, expanded gypsum, 85 pct magnesia, diatomite, asbestos, perlite, cellular glass, pumice, silica aerogel, expanded aggregates and mineral wool. Except mineral wool, most of these products, or the materials from which they are manufactured, are described in other chapters of this book. PROPERTIES OF INSULATING MATERIALS The insulating properties of the materials considered in this chapter result in general from entrapping extremely small pockets of air in such a manner that heat is not transferred by convection. The minimum heat conductivities of such insulating materials are slightly greater therefore than the conductivity of still air. In addition, conductivity varies with the overall density of the material, the temperature range in which the measurements are made, and the form into which the material is fabricated. However, the numerical value of heat conductivity should not be the sole criterion of an insulating material; for a particular application it may be advantageous to use a material of somewhat higher conductivity in order to secure other desirable engineering properties. This is especially true with certain materials that are used because of their refractoriness. Comparative insulating values of some commonly used insulating materials are shown in Table 1. In comparing the values presented in this table it should be borne in mind that heat conductivity varies with the mean temperature, with the overall density, and with the amount of moisture present. With fibrous or granular materials it varies with fiber or grain size and with the amount and kind of binder, if any is used. Under some circumstances it may vary with the arrangement of

Jan 1, 1949