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Effect of Iron on ash fusion temperature and waterwall deposits FeS, H2S on tube material corrosion and erosion [ ]

Jan 1, 2005

By B. Kahraman

About 70% of the world?s total boron reserves are located in Turkey. Boron minerals are typically concentrated by attrition scrubbing followed by screening and classification to remove clay minerals and other impurities. These wet concentration methods, however, result in a considerable amount of accumulated tailings in large tailings dams. The tailings are approximately 28% solids and contain 14% B2O3. Problems caused by these tailings can be minimized by employing dry beneficiation techniques involving heat treatment. This method has been successfully tested on laboratory and pilot scales. During heat treatment, borax undergoes expansion in volume. The amount of expansion is dependent on the particle size, temperature and duration of heat treatment. Because the optimum temperature and the duration of the heat treatment are not well defined, the boron ore acts as a calcined clay mineral and is discarded along with the gangue. It is important to predict such parameters using mathematical formulations. Thus, a mathematical model is used to predict the required temperature and duration period prior to heat treatment. In the experimental study presented here, a series of systematic thermal tests was carried out in a muffle furnace. Two variables, temperature and time, were studied in a response surface design. A quadratic regression model was chosen and regression coefficients were calculated. Using a regression equation, the volume expansion of the particles in various circumstances can be predicted. The mathematical test results are then correlated with the experimental results to relate the optimum expansion of borax with heating time and temperature and with borax grades and recoveries.

Jan 1, 2008

Particles of a complex nickel sulphide concentrate (containing pyrite, pyrrhotite, pentIandite, and violarite as the major mineralogical constituents) were entrained in a stream of hot gas the temperature of which was varied from 500 to -1000°C. Chemical analysis of the particulates collected from the furnace was used to detect the rapid change in sulphur content which accompanied the ignition temperature jump. X-ray diffraction analysis was used to characterize the oxidized material.These techniques showed that ignition was dependent on the mineralogical composition and occurred over the temperature range 500-900°C. Pyrite ignited first in the range 500-600°C; pyrrhotite was the least reactivemineral and required temperatures in excess of 800°C for ignition. The nickel minerals <pentIandite and violarite decomposed before ignition and ignited at temperatures intermediate to those required for the pyrite and pyrrhotite. The ignition temperature for the pyrite was found to be independent of particle size and concentration of oxygen in the atmosphere.Ignition temperatures determined by the simulated flash smelting method were compared with the results of differential thermal analysis (DTA) measurements performed on the same concentrate. Temperaturesdetermined in the DTA test as corresponding to the start of exothermic activity were shown to be at least 100°C below those determined by the simulation test.

Jan 1, 1978

Selective Removal of Arsenic from Acid Mine Drainage Containing Ferrous Ion Using Sulfide Precipitation Method

Sep 13, 2010

By A. D. Davis, J. L. Sorensen, C. J. Webb

Environmental impacts from acidic mine drainage are growing national concerns that are particularly acute in the headwaters of the Rocky Mountain region. In the Black Hills of South Dakota, approximately one thousand mines are inactive or abandoned, most of them in the headwaters of major drainages. This paper examines the Bear Butte Creek basin, a heavily mineralized watershed with significant historical mining impacts and a surface gold mine permitted in 1997. The watershed loses its surface discharge to swallow holes in the karstic Madison Limestone. The integrity of the aquatic ecosystem was monitored with a suite of sitespecific bio-indicators. Stream surveys covered the entire reach of Bear Butte Creek from near its headwaters to the swallow holes in the Madison aquifer. Data from the stream surveys, water-quality sampling, and bio-indicator surveys clearly showed that water-quality impacts are limited mainly to Strawberry Creek and to the area of Bear Butte Creek near and downstream of the town of Galena.

Jan 1, 1999

By R Bezuidenhout, J K. Claflin, S R. La Brooy, G M. Wardell-Johnson, A M. Claflin

Best practice gold (Au) recovery is not an accident. It is the result of proper operation of the adsorption circuit using good quality activated carbon. A conventional carbon ‘regeneration’ kiln cannot process carbon fouled with floatation chemicals and achieve best practice gold recovery. A high temperature, controlled atmosphere carbon ‘reactivation’ kiln is required. Carbon circuit design allows for low quality carbon by increasing the carbon advance rate, carbon inventory and setting an easily achieved and commercially prudent solution tails target of typically 0.02 ppm Au. These design criteria are important to ensure the commercial success of the gold operation in the first instance. Most carbon ‘regeneration’ kilns will produce carbon of sufficient quality to achieve a 0.02 ppm Au solution tail in the absence of flotation reagents.Best practice recovery is considered less than 0.005 ppm Au in solution reporting to tails. If the carbon is heavily fouled, as it will be if used for flotation leach circuits, then a conventional carbon ‘regeneration’ kiln cannot achieve world’s best practice recovery no matter how much carbon is advanced. World’s best practice gold recovery requires a carbon ‘reactivation’ kiln and the whole of the carbon circuit operated optimally.The competing reactions occurring in a carbon ‘reactivation’ kiln are presented and discussed in terms of kiln design and operation. New industrial and laboratory findings are presented to fill gaps in the body of knowledge and identify that a large reduction in residence time at temperature will not significantly impair reactivation, but can significantly reduce the size and cost of the kiln or permit significantly increased carbon throughput.The carbon circuit performance is modelled in terms of gold adsorption, as a function of carbon reactivation using ‘simulation of carbon-in-leach/carbon-in-pulp circuits’ (SIMCIL). An optimum carbon advance rate is identified as a function of optimum carbon ‘reactivation’ kiln operation to achieve 0.005 ppm Au in the tails solution. A conventional carbon ‘regeneration’ kiln is compared to a state-of-the-art carbon ‘reactivation’ kiln in terms of reactivation performance and gold recovery.CITATION:Claflin, J K, La Brooy, S R, Wardell-Johnson, G M, Bezuidenhout, R and Claflin, A M, 2017. Optimising carbon reactivation kiln operation, in Proceedings MetPlant 2017, pp 346–364 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 11, 2017

By Geoffrey C. Hebner

Augered, cast-in-place piles (ACIP) have become a very common foundation type in Atlanta and the Southern Piedmont Province as well as much of the United States in the past 20 years. Prior to the introduction of ACIP foundations in Atlanta, the most common deep foundation type was Raymond piles. Raymond piles are basically a driven, thin-walled step-tapered steel pile filled with concrete. Drilled piers were also relatively common and continue to be used, particularly in shallow bedrock or high column load situations. Driven piles, including pipes, H-sections, and timber piles were previously common with working loads typically in the 30 to 50-ton range. Initially, ACIP foundations had similar allowable capacities, however, over time improvements in installation techniques and equipment have resulted in an increase in allowable ACIP capacities. Correspondingly, they have become a more cost-effective and trusted foundation for geotechnical and structural engineers. Over the next several decades many other deep foundation alternatives began to lose popularity. ACIP are one of the predominant deep foundations in Atlanta and the Southern Piedmont today. Although ACIP foundations have widespread popularity in the private sector, they have not been readily accepted currently by government transportation agencies. ACIP may be used by some of the smaller municipalities, but to the author's knowledge, have not been used with regularity by larger, state agencies.

Jan 1, 2003

The purpose of this paper is to describe briefly the clean-up procedure adopted at the treatment plant of Paringa Mining & Exploration Co. Ltd. at Kalgoorlie, Western Australia.A clean-up is carried out at the end of each four-weekly period, and all figures subsequently quoted are taken from a summary of the results of the eight periods ending 8th April, 1941.STRAKING AND AMALGAMATIONOf the total gold won 22· 77 per cent. is recovered by straking and amalgamation.The discharges of both the primary and secondary ball mills are pumped over a common set of five ten feet long by three feet wide straking tables, set at an angle of 10 degrees, before passing to the 14 ft. diameter by 30 ft. by 8 ft. Dorr bowl classifier.This classifier is in closed circuit with both of the ball mills, hence the whole of the circulating load of the fine grinding circuit, which approximates to 800 per cent., is required to pass over the straking tables. For convenience in handling, corduroy cloths are used in lengths of 5 feet, and are picked up and replaced by clean cloths at four-hourly intervals. The avaHable straking area provided is, therefore, 900 square feet, or approximately 3·30 square feet per original ton per 24 hours. The density of the pulp passing over the tables is about 54 per cent. solids, the area provided per ton of pulp per 24 hours being approximately o· 2() square feet. Washing of the corduroy cloths is carried out on the day shift only, about 800 lb. of strake concentrate being obtained daily.This concentrate is sluiced from the washing trough on the elevated straking floor to the 4 ft. by 2 ft. diameter amalgamating barrel located in the gold room below.The barrel is of standard design and is rotated at 25 r.p.m. It is charged each day at 4 p.m., and grinding of the strake concentrate at approximately 70 per cent. solids is continued until 8 a.m. the following day. The barrel is then stopped, and the contents generously diluted with water, and after a few minutes rotation some of the slime is carefully poured off through the small discharge hole. This dilution and decantation is repeated until a good deal of the valueless slime has been removed.A further quantity of strake concentrate is then charged to the barrel, which is allowed a further 16 hours grinding period. After again diluting and decanting, approximately 25 lb. of mercury and 15 lb. of lime are added to the charge, which is then given an amalgamation period of 2 hours before cleaning up.By the process of grinding, diluting and removal of slime by decanting...

Jan 1, 1941

By Robert Gannicott

??A mining company without the burden of operating a mine ??Management focused on marketing a high-quality, run-of-mine range of Canadian diamonds ??Robust revenue stream ??Specialist diamond knowledge ??Canadian exploration and development expertise ??BUT ??Single asset revenue base from depleting ore reserve ??Limited influence on production plans

Apr 1, 2005

Measurement of densities, susceptibilities, permanent magnetization, and calculation of demagnetization factors has allowed computer modelling of gravity and magnetic data over the Middleback Range iron formations of South Australia. As well as providing structural information, the study emphasizes the effects of weathering on the interpretation of magnetic data.

Jan 1, 1975

By Tapio Leskinen

"l. IntroductionA reliable sampling system is the basis for an on-stream analyzer. This was realized in Outokumpu company when the development work of the Courier 300 On-Stream X-ray analysis system was started. Because Outokumpu Oy is a mining and mineral processing company, its engineers have been able to thoroughly test sampler prototypes in actual operating situations. The sampler development has been going for several years in close co-operation between company's concentrators, the Institute of Physics and the Instrument Division of Outokumpu Oy. The most active part of the work was done between 1969- 1972. Besides the reliable operation of a sampler special attention was paid to the representatively of the samples taken by the samplers. 2. The Courier 300 Sampling SystemThe sampling system comprises up to fourteen sampling circuits in one Courier analysis system. Each circuit consists of the following components:1. Primary sampler 2. Secondary sampler 3. Cleaner screen 4. Feeding tank5. Sample cell6. Timer-controlled sampler7. Pumps, sumps and pipesSecondary samplers, cleaner screen and feeding tanks are included in the secondary sct1npling system. The sample cells are located in the spectrometer cabinet of the analyzer."

Jan 1, 1976

By H J. Stedman

A Transient Electromagnetic (TEM) geophysical survey was trialled in Bowen Basin Permian coal measures overprinted by Cretaceous intrusion. The trial’s intention was to compare whether TEM could assess residual coal more accurately and economically than drilling.TEM results were promising but had limitations. TEM did not compare to drilling for defining coal thickness or relative level definition. However, TEM resolved conductive anomalies laterally; providing a qualitative picture of remnant coal.Three material types and associated conductivities occur within the trial area: overburden (sandstone/siltstone), intrusive sills and heat affected coal.Ground conductivity was analysed by measuring decay of residual current within the TEM loop. Fast decay related to resistive overburden and intrusion, attenuated decay related to conductive coal.Generally speaking, carbon content governs coal resistivity where good quality, low ash, bright coal is more resistive relative to dull, high ash coal. Though in the trial area, relative to intrusion and overburden, coal was found to be the most conductive of the three materials.By modelling conductive anomalies, a general picture emerged of remnant coal regions. Subsequent highwall exposure reconciled with conductive TEM anomalies.CITATION:Stedman, H J, 2017. Findings from a transient electromagnetic trial for heat-affected coal, in Proceedings Tenth International Mining Geology Conference 2017, pp 233–238 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 20, 2017

By Gabriel S. Esterhuizen

This paper addresses the need for a method to compare the effectiveness of different support systems when designing ground support in coal mines. At present, support design methods include empirical methods based on observations of past performance of installed support systems, analytical methods where the roof is typically simulated by elastic beams and numerical model analysis. The approach presented in this paper estimates the relative stability of a support design through geotechnical evaluation of the rock mass and numerical model analysis of the interaction between the rock mass and the support system. Models are used first to simulate the design performance at the expected rock conditions. The rock strength is then reduced until collapse is indicated in the model. The stability factor is then calculated as the ratio of the expected rock mass strength to the rock mass strength at the onset of collapse, and is similar to the well-known factor of safety used in engineering practice. The stability factor can be used to assist in developing a final support design by comparing the effectiveness of various support systems and the stability of excavations under various geological and loading conditions. Examples of the method?s application in three different geological settings are presented.

Jan 1, 2012

By Jan E. Nesset, James A. Finch, Wei Zhang

"Bubbles are unquestionably the heart of the flotation process. Their size and combined surface area are largely what drive the recovery process. This suggests that plant engineers should be aware of where their plants are operating with respect to what is achievable for these key parameters. The paper presents a model of how the key operating variables of frother type and concentration, gas rate, altitude (above sea level) and viscosity affect the Sauter mean bubble size (D32) and bubble surface area flux (Sb). The results are compared to a set of plant measurements that demonstrate the benchmarking capability of the approach. A case study is used to link hydrodynamic change to improved metallurgical performance.INTRODUCTION At the beginning of the 20th Century the early practitioners of flotation were aware of the importance of understanding bubble behaviour (Rickard, 1916) but measurement of individual bubble and gas behaviour in the industrial environment was not possible due to a lack of adequate sensors. This situation was not rectified until three quarters of a century later with the advent of industrially-robust sensors developed, notably, at the University of Queensland’s Julius Kruttschnitt Mineral Research Centre (JKMRC) (Schwarz & Alexander, 2006) and McGill University (Gomez & Finch, 2002). What emerged was not the chaotic environment perhaps expected, but defined relationships between gas rate, gas holdup, bubble size and the total surface area of bubbles. These relationships could be defined by mathematical expressions and predicted from an understanding of the key process variables (Gorain, Franzidis & Manlapig, 1997; 1999) (Hernandez-Aguilar, Gomez & Finch, 2002) (Gomez, Cortes-Lopez & Finch, 2003) (Nesset, Gomez & Finch, 2007). The early JKMRC work focused on a large pilot cell (3 m3) installed in plant environments, while the McGill work was initiated on flotation columns (Finch & Dobby, 1990) (Xu, Finch & Uribe-Sales, 1991) and later adapted to industrial mechanical cells (Cooper, Scott, Dahlke, Finch & Gomez, 2004) (Dahlke, Gomez & Finch, 2005) (Nesset, Gomez, Finch, Hernandez-Aguilar & Difeo, 2005). Yianatos of Santa Maria University (Chile), a graduate of the McGill research team, carried the work to industrial settings in South and Central America (Yianatos, Bergh, Condori & Aguilera, 2001). The methods of gas dispersion measurement are now well accepted and most major research centres and flotation cell manufacturers have adopted the technology (Pyecha, Sim, Lacouture, Hope & Stradling, 2006) (Yañez et al., 2009) (Collins, Schwarz & Alexander, 2009)."

Jan 1, 2012

"Horizontal grinding mills have been used in the mining industry for more than a century, and due to their operational and maintenance simplicity they remain a widely used technology for various stages of comminution. The relative ‘efficiency’ of horizontal grinding mills compared to other comminution equipment is often debated, and efforts to improve the energy efficiency of these mills is an on-going area of attention for process engineers.The discharge arrangement design affects the material transport characteristics within a horizontal grinding mill. Material transport plays a significant role on efficiency of horizontal grinding mills. The magnitude of benefits that can be achieved with efficient material transport in AG/SAG mills has been demonstrated in a Greenfield milling operation at Mirabela Mineração’s SantaRita Nickel operation in Brazil. This grinding circuit was commissioned in October 2009, which was designed as a typical SABC circuit to grind 4.6 mtpa (575tph) to produce a P80 of 125um with 10-12% ball charge in SAG mill. The nameplate design capacity has been achieved in few days in ABC circuit without grinding media in SAG mill, and has been operating in ABC mode. The through has gradually increased to an average of 800 tph and recently 7% ball charge has been introduced to increase the throughput to +900tph.This paper investigates improved material transport using Outotec’s TPL™ (Turbo Pulp Lifter) technology and the opportunities this technology presents when designing horizontal grinding mills. Operational data, with particular reference to energy and throughput optimization, is presented."

Jan 1, 2013

By Maya Kamenetsky, Khoi Nguyen, Natalee Bonnici, Steve Walters, Claire McMahon, Julie Hunt, Ron Berry

"The analysis of meso- and micro-scale textural attributes has been undertaken on ore samples from the Ernest Henry iron oxide-copper-gold (IOCG) deposit in NW QLD. Quantified textural data including grain size, shape and mineral association have been extracted from classified images of core with the aim to better predict potential mineral processing behaviours such as comminution, liberation and flotation. Data have been extracted from images of intact core at meso- and micro-scales using high resolution continuous images collected using automated core-logger technology, SEM-based and optical microscopy platforms.The results of this study will show examples of quantified size, shape and mineral association data from meso- and micro-scale classified images. Analysis of the data shows that there are domains of variable grain size and mineral association that can potentially be related to crushing and liberation behaviour. The trends that are observed at the drill-core (meso-) scale are consistent with those at the micro-scale. The results from the micro-scale analysis show that the domains defined at the core-scale have clearly different chalcopyrite sizes and shapes as well as variable bulk mineralogy.INTRODUCTIONInnovations in technology have allowed automated extraction of information about mineral shape, grain size and mineral association, i.e., texture, from meso- and micro-scale images of intact rocks. The overall aim of this research is to investigate trends in quantified textural data that can potentially give an early view of processing parameters such as predicted grind size and liberation behaviour."

Jan 1, 2009

Most analysts determining tungsten trioxide in low grade samples are aware that colorimetric procedures do not possess the inherent disadvantages of gravimetric methods operating on milligram quantities of tungsten trioxide. Apart from the inaccuracies associated with weighing four or five milligrams of ignited oxide in a platinum crucible of about 30 gm. weight with a large surface area to absorb moisture, using a 5 gm. charge on samples less than about 0·15 per cent tungsten trioxide, it is extremely difficult toget complete or pure precipitation of tungsten with cinchonine, cinchonine plus alpha benzoin oxime, rhodamine B or any other of the commonly used precipitants. Table 2', No. 8, illustrates the low results obtained by gravimetric as opposed to colorimetric procedures. In addition the colorimetric determination requires only a small portion of the time consumed by gravimetric practices and the increased accuracy obtainable in low ranges together with the saving in time made it highly desirable to develop a colorimetric method suitable for King Island ores.The most commonly used colorimetric method is that introduced by Feigl and Krumholz (1932), since modified by various investigators (Grimaldi and North, 1943; Sandell, 1946; Westwood and Mayer, 1947; Gentry and Sherrington, 1948; Freund, Wright and Brookshier, 1951; Grouthamel and Johnson, 1954; and others). Stannous chloride is used to reduce tungsten followed by colour development with a thiocyanate, usually sodium, potassium or ammonium.Other reducing agents have been proposed (Emery and Curtis, 1948), but only in recent years have the conditions governing maximum colour development been fully estab...

Jan 1, 1958

By Max J. Spendlove

The secondary copper industry is comprised of numerous enterprises which collectively employ many of the recovery and refining processes now used in primary plants as well as many other processes that are unique to the industry. Effective methods are used for identifying and segregating all types of scrap according to widely accepted standard classifications. Segregated scrap and waste materials usually require some preliminary processing to remove both valuable and deleterious associated constituents. Smelting, melting, alloying, and pyrorefining are common methods used for producing secondary metal, but operating techniques usually differ from primary metal operations because of the difference in physical and chemical properties of the respective raw materials. Some copper scrap is converted to copper chemicals rather than to refined metals or alloys. Recovery efficiencies of all processes are reasonably high, and the quality of products meets rigid specifications.

Jan 1, 1961

By S D. C Rabone

An elongate belt containing granodiorite stocks with associated stockwork molybdenum mineralisation in west Nelson is correlated with the I-type Separation Point Suite of mid Cretaceous age. Trace element characteristics of the 'Mo-granites', and the Separation Point Batholith strongly suggest a primitive, subcrustal origin for these granitoids, by partial melting of oceanic basaltic crust or upper mantle material in a subduction zone. They were emplaced in the upper crust without undergoing significant differentiation or contamination by sialic crust. Molybdenum, which is at levels of approximately 5 ppm in unaltered granite, is not significantly reduced in altered (but unmineralised) granite. This suggests the metallisation has a magmatic, subcrustal source and is not derived by hydrothermal leaching of upper crustal rocks or the granitic host rocks. Geochemistry of the 'Mo-granite' belt, in particular low K2O, calc-alkali to calcic Peacock Index, high Sr and TiO2, and low Rb, Nb and F, suggest classification as calcic granitoids similar to those which host porphyry copper deposits, indicating grades of mineralisation are likely to be low.

Jan 1, 1987

Innovative Technology for Optimised Thickening Sedimentation

Sep 13, 2010