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By B. W. Madsen

As part of a program to maintain an adequate supply of minerals and metals to meet national economic and strategic needs, the Bureau of Mines conducted research to determine the diffusion coefficients for ferric ions in synthetic copper leach solutions. Determination of ferric ion diffusion coefficients in typical dump leach solutions is necessary for predicting leaching rates of copper from large-scale leaching operations and for optimizing concentrations of ferric iron in solutions to maximize leaching efficiency. Derivative chronopotentiometry, an electroanalytical technique, was used to determine ferric ion diffusion coefficients. The diffusion coefficient decreased dramatically with increasing concentration of iron in solution. An empirical model was used to relate the ferric ion diffusion coefficient to the total amount of sulfate in solution. Measuring the diffusion coefficient dependence on temperature yielded an activation energy of 5.5 kcal/mole of ferric ion. Activity coefficients of ferric ions as a function of concentration were calculated from diffusion coefficient data.

Jan 1, 1981

By J. F. Leroux

The Gaspé smelter at Murdochville, Quebec, Canada introduced concentrate injection into elongated Peirce-Smith converters sized 1.96m x 12.5m (13 ft. by 41 ft.) in 1996, and commissioned a large, converter-like bath smelting vessel in April 1998. The new vessel, which is sized 4.27m x 16.1 5m (14ft. by 53ft.) has several interesting features designed to effectively utilize bath smelting technology for the requirements of the Gaspé smelter. For example, the vessel can operate on concentrate injection at upwards of 60-80 tph rate on an instantaneous basis, can operate as a large Peirce-Smith converter, while it is also fitted with matte and slag tapholes much akin to Noranda Process reactor, and includes a novel cold charge addition system. The new technology will eventually allow the capacity of the plant to increase from about 300,000 tonnes of concentrate per year to over 350,000 tonnes of concentrate per year while improving sulfur capture.

Jan 1, 1999

By Matthew S. Sanchez, Richard J. Lee, Matthew D. Zock, Drew R. Van Orden, Yumi Kamiya, Edward B. Ilgren

In many developing countries, asbestos is still used for friction products, insulation, and asbestoscement products. However, there is very limited modern data evaluating the airborne concentrations of asbestos fibers in operating asbestos plants. We have conducted an Industrial Hygiene survey, using state of the art PCM and TEM analysis, of a Bolivian asbestos cement plant that uses crocidolite during the production of roofing shingles and water tanks. The study is the first to use modern analytical measurements in an uncontrolled asbestos environment. Thus, this study offers insight into the historical airborne exposures at asbestos plants operating before modern dust control measures were introduced or airborne fiber levels regulated. The results suggest that fiber concentrations are far in excess of those for which current models would predict the onset of asbestos disease and mesothelioma. Significantly, the plant and community do not have an elevated incidence of asbestos disease or mesothelioma. Airborne fiber levels during comminution and fiber sizing ranged from 100 to as much as 1,000 f/cc. Fiber levels in the mixing, forming and finishing areas ranged from 0.5 to 9 f/cc. Based on the number of overloaded samples and estimates of their concentration, historical estimates of exposure may be underestimated by an order of magnitude. Also, an excellent correlation (1:1) between the PCM and TEM fiber concentrations (for fibers _0.25 um diameter) were obtained, raising questions about the conventional wisdom that the PCM systematically undercounts fibers. The results of this study further indicate that current models may overestimate the risk of asbestos disease and mesothelioma.

Jan 1, 2012

NIOSH recommends that exposures to respirable coal mine dust be limited to 1 mg/m3 as a TWA concentration for up to 10 hr/day during a 40-hr workweek, measured according to current MSHA methods (see Section 5.1 and Appendix J). NIOSH recommends that sampling be conducted with a device that operates in accordance with the NIOSH accuracy criteria [Busch 1977; Busch and Taylor 198 11 and the international definition of respirable dust [ACGIH 1994; CEN 1993; IS01993; Soderholm 1991a,b; 1989].* The REL represents the upper limit of exposure for each worker during each work shift. For single, full-shift samples used to determine noncompliance, NIOSH recommends that MSHA make no upward adjustment of the REL to account for measurement uncertainties [NIOSH 1994c] (see also Section 5.6.2). NIOSH further recommends that all reasonable efforts be made to reduce exposures to respirable coal mine dust below the REL through the use of engineering controls and work practices.

Jan 1, 1997

By Ryosuke Matsuoka

Keywords: Tantalum capacitor, Scrap, Recovery, Titanium, Chlorination A recycling process for tantalum from capacitor scraps using an oxidation process followed by mechanical separation and chemical treatment was investigated. This study demonstrates that sintered tantalum electrodes inside the capacitor scraps can be mechanically collected after the oxidation of the scraps in air, and high-purity tantalum oxide powder (Ta2O5) was efficiently recovered after chemical treatment. By reducing the Ta2O5 obtained through magnesiothermic reduction, tantalum powder with 99 mass-% purity was obtained. Using the chlorination for tantalum recovery was also investigated, and the tantalum or tantalum compounds were reacted with chloride wastes such as FeClx. It was found that tantalum was effectively separated and purified when tantalum powder is reacted with FeClx at 1100 K under an argon atmosphere. This recycling process utilizing chloride scrap has now been extended to other reactive metals such as titanium.

Jan 1, 2004

By Marcelo R. Esquivel

A MmNi5 alloy is synthesized by a combination of mechanical milling and low temperature heating processes. Synthesis time is 40 h for powders milled in a low energy ball mill at room temperature. A reduction in milling time is obtained if massive sample is mechanically milled at shorter times (2 h to 10 h) and heated at temperatures lower (600 ºC) than the usual temperatures used in equilibrium methods (>800 ºC). The alloy formation is detected even at a combination of temperatures as low as 200 ºC and milling times as short as 5 h. The temporal evolution of mechanical milling process was followed by both X-ray diffraction (XRD) and scanning electron microscopy (SEM) to detect the main stages of milling. Four stages were detected: Initial, Intermediate, Final and Completion. These stages were correlated to an enhancement of the synthesis method by combination of times of milling shorter than 10 h and temperatures of heating lower than 600 ºC.

Jan 1, 2006

By F. L. Wilke

Bong Mining Co. Ltd. in Liberia, West Africa, operates an iron ore open pit some 60 miles northeast of Monrovia. The production is at present about 40,000 t/d (metric tons/day) from which about 18,500 t/d concentrate with 65.5% Fe is produced. The ore waste ratio is about 1: 1.5 to 1:2. The technical layout and the equipment are very similar to those in many modern open-pit operations as described by Jacobs and Thomson (1967). As described by Lersch in detail (1966), the deposit is a very irregular one. The quality of the ore changes within very short distances with regard to both physical conditions (hardness) and chemical properties. Very soft and very hard ore as well as high-grade and low-grade ore are found adjacent to each other. In addition, there are enclosures of sterile rocks. For the purpose of identification and production scheduling, 12 different types of ore are distinguished.

Jan 1, 1979

By W. W. Wen, S. C. Sun

The objective of this investigation was to study the electrokinetic behavior of oxidized coals to indicate the feasibility of separating oxidized coals from ash materials and pyrite by an amine flotation process. The effects of soluble inorganic electrolyte products from coal oxidation were also examined. The electro-kinetic behavior of coals of different rank and degree of oxidation were studied by an electro-phoreses technique. Generally, increasing the oxidation increases the negative value of the zeta-potential and decreases the isoelectric point (IEP). Flotation results indicate that the flotation recovery increases with decreasing pH values, and that with ferrous sulfate at pH 6.5 the flotation recovery is optimum while the pyrite is depressed. Comparing the flotation results with the electokinetic results verified that in the presence of ferrous sulfate, the maximum hydro-phobicity of oxidized coal with dodecylamine and frother is near its IEP, which is around pH 6.5 to 7.0.

Jan 1, 1978

By G. A. Brady

Laboratory tests were conducted to determine the technical feasibility of separating anthracite particles from a water-anthracite slurry by atomizing the water and removing the resulting mist in an air current. Products containing 21 percent or less moisture were obtained from slurries made with minus 60-mesh anthracite. Typical recoveries ranged between 67 and 79 percent of the feed when the slurries were atomized in air currents with velocities below 70 ft/min.

Jan 1, 1967

By Dongxing Wang, Zhang Ting-an, Xiaolong Li, Yan Liu

Recent years, bottom blown oxygen copper smelting process has been widely used in China. Besides many advantages such as autothermal operation, this technology is still in developing stage. This topic aims at promoting the dispersion of materials charged into the bottom blown smelting furnace used in the process. Based on the similarity theory, a 1/5 scaled physical model of smelting furnace was constructed. Polypropene particles were used as charged materials. High-speed camera was used to record the phenomenon of the particles dispersion under different gas-flow rates, nozzle diameters and installation angles of nozzles. Image processing software was used for obtaining the particles concentration under different conditions. Results show that when the gas flow rate increases, charged materials disperse better. With the same gas flow, the increasing of nozzle diameter promotes the dispersion effect of materials. The effects of installation angles are opposite for nozzles with diameter of 2.50 and 5.92 mm.

Mar 1, 2017

By J. Brent Hiskey, Rebecca Grace Copp

The solvent extraction of yttrium and neodymium from copper pregnant leach solutions (PLS) using Primene JM-T, a primary aliphatic amine, has been studied. Effect of contact time, pH, sulfate concentration, and extractant concentration were investigated using synthetic and actual PLS systems. Standard experimental conditions were 5 minute contact time, pH ~2.5, and 10 % v/v Primene JM-T concentration. Distribution isotherms were constructed for the pure systems and for actual copper leach solutions. Synthetic solutions contained 100 ppm Y and ~75 ppm Nd. Samples of PLS contained 2 - 10 ppm Nd and 14 - 30 ppm Y. Results showed that complete extraction of both yttrium and neodymium occurred within five minutes and at pH values greater than 1. It was also found that sulfate concentration does not inhibit extraction at any concentration. Additionally, the distribution isotherms created show that extraction for these metals can operationally take place in one stage.

Jan 1, 2016

By L. W. Bahney

Many methods for the determination of gold or silver, or both, in cyanide solutions have been published, which with care in manipulation, and modification in some cases, will give results that are satisfactory. It is possible to classify or group these methods as follows: 1. Evaporating the solution in a porcelain or agate-ware dish containing litharge,l or in a "boat" made of lead foil. 2. Forming a lead sponge containing the precious metals by means of zinc shavings,2 zinc dust,3 or a piece of aluminum.4 3. Decomposing the cyanide solution with an acid and precipitating the precious metals by the use of one or a combination of some of the following: Copper sulphate,5 sodium sulphite,6 hydrogen sulphide,' cement copper.ll 4. Precipitating the silver by zinc dust held in a Gooch crucible and determination with a standard solution of sulphocyanate.9 5. Electrolysis.l0 . 6. Colorimetry.ll

Jan 1, 1915

By José Hugo de Carvalho Souza

Buscando melhorar a detecção das causas de falhas em equipamentos pela equipe no setor de trefilados e ampliados, o tempo de reparo de manutenção, diagnóstico de desempenho dos processos e melhoria na segurança operacional, foi criado um sistema de informação integrado de engenharia de manutenção e processos, com plataforma de carta de controle online e off-line integrada, monitorando aproximadamente quatro mil e trezentas variáveis de processos analógicas e digitais, adicionadas câmeras IP nos processos e desenvolvido um sistema de rastreabilidade de volumes produzidos que garante o correto apontamento de produção da área, minimizando dessa forma as divergências de inventário. A criação da rede integrada, permite unificar as comunicações de automação, possibilitando monitoramento e modificações das lógicas nos PLCs na central da automação, agilizando os diagnósticos e padronizando backups. A partir das implementações e projetos, foi possível aumentar no período de 12 meses em 5,5% a produtividade e otimizar em 2,9% o resultado de interrupção de manutenção dos equipamentos.

Aug 16, 2017

By P. A. Riveros, J. Binvignat, V. M. McNamara, D. Koren

The recovery of cyanide from a gold mill solution containing high levels of copper (400 mg/L to 900 mg/L) using the AVR process was evaluated. It was determined that acidification to pH 2 to 3 provides a suitable balance between HCN generation, copper precipitation and acid consumption. A short pilot plant campaign showed that ~75% of the feed WAD cyanide was recovered while the remainder precipitated along with copper upon acidification. The acid consumption averaged 3.5 g H2SO4 per litre of solution. The copper precipitate, consisting mostly of CuCN and CuSCN, was readily separated from the solution by gravity. The volatilization of HCN in countercurrent packed columns averaged 98.7% efficiency. Reabsorption of HCN was practically 100% in NaOH solutions and slightly lower in a lime slurry. Basic volatilizer design parameters applicable to a large-scale operation were determined, including the Henry’s Law constant and the mass transfer coefficient of HCN gas.

Jan 1, 1998

By Robert H. Peters

This report presents a literature review conducted by the U.S. Bureau of Mines. The review summarizes what has been learned from recent empirical studies of the relationship between mine safety and characteristics of miners, mine management, and mining companies. The review is based on literature published in the United States during the period from 1976 to 1988. In addition to summarizing the empirical findings, this report discusses the implications and limitations of these studies, and gives recommendations for improving mine safety. An annotated bibliography section appears in the appendix.

Jan 1, 2009

By J. R. Ross, J. B. Rosenbaum

Bureau of Mines research has resulted in the development of fluid- bed ion-exchange columns for recovering uranium from slime pulps. In pilot plant tests, slime slurries containing up to 6 percent solids were processed at flow rates of 10 gallons per square foot per minute with high uranium recoveries and efficient resin loadings. Uranium was effectively eluted in a laboratory fluid-bed elution column at eluate-to-resin ratios of less than 5:1 and eluate flow rates of 3 gallons per square foot per minute. Construction costs of mills using these improved ion exchange techniques are estimated to be 25 percent less than for mills using solvent extraction of clear solutions. For mills having a capacity of 2,000 to 2,500 tons of ore per day, the saving would be in the range of $2.5 million. In addition, a saving of about $0.80 per ton of ore in total operating costs is indicated.

Jan 1, 1973

By V. G. Papangelakis, M. Cheung, M. Dry

The high pressure acid leaching of laterite was modelled and simulated using a combination of two commercially available software packages, namely Aspen Plus 11.1 and the OLI Stream Analyzer. New kinetic parameters for the acid-controlled metal dissolution and precipitation reactions at temperature were first determined from previous experimental data on the leaching of limonite. A grain model with cylindrical pellets was used to model the solid-liquid dissolution reactions. Precipitation reactions were modeled via aqueous equilibrium chemistry. A dedicated thermodynamic database previously developed at the University of Toronto was used in conjunction with the OLI software to model the solution chemistry and calculate the concentration of hydrogen ions in solution at the leaching temperature. Mass balances were handled by Aspen Plus. The simulation gave good predictions of nickel dissolution under industrial and laboratory conditions, for the dissolution of limonite and limonite/saprolite blends. Computational

Jan 1, 2005

By W. E. Bruce, James Paone

Drillability or a measure of drilling performance has been based on ( 1 ) hardness and toughness of rocks , ( 2 ) power input to the drill compared with total volume of hole , and ( 3 ) penetration related to resistive forces of rock on the applied penetrative forces . An analysis of some representative previous work is made . Experimental drillability curves from AX- size diamond core bit performance in eight different rocks ranging from dense hard taconite to soft limestones are presented . Results show that in small bore diamond drilling , compressive strength and possibly other rock properties may be a useful parameter in predicting drilling rates .

Jan 1, 1963

By J. Hanna

The University of Alabama Mineral Resources Institute (MRI) has developed a unique process for selective fatty acid flotation of carbon-ate gangue from sedimentary apatites "francolite" in the pH range of 4-6 without collector conditioning of the pulp. The process, which does not require an apatite depressant, was modified to beneficiate a high Mgo siliceous phosphate matrix from south Florida. The modified process includes two flotation stages, one for carbonate removal, as mentioned above, and the other for phosphate recovery from the siliceous gangue. The selective flotation separation of the carbonate and phosphate, from siliceous constituents of the matrix at various pH levels and collector dosages are discussed. In the carbonate flotation stage, about 70% of the Mgo was rejected in the froth and the phosphate flotation stage produced concentrates analyzing about 31% P2O5,0.7% HgO and 4% insol. The overall P2O5 recovery in the two stages is about 85%.

Jan 1, 1989

By A. F. Matheson

"The Jellicoe is the most westerly mine in the Little Long Lac area with a record of gold production. The property is largely covered with overburden and the ore deposit was found by diamond drilling along the projected strike of a gold bearing zone at Magnet lake 1 ½ miles to the east on the property of Bankfield Consolidated Mines, Limited. In 1940-41 Jellicoe mined the whole orebody of approximately 14,000 tons, recovering 5,620 ounces of gold.The vein is in light-coloured greywacke. A mile-long dyke of fine-grained quartz feldspar porphyry 5 to 10 feet in width lies 100 feet south of the vein. A similar, even longer dyke lies 700 to 800 feet north of the vein. Some narrow diorite dykes are also rather closely associated. The porphyry dykes are gold bearing, but not ore. The vein material is quartz and silicified and brecciated greywacke. Mineralization consists of native gold, pyrite, arsenopyrite, and some sphalerite."

Jan 1, 1954