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By X. Tang, N. Ripepi

The Langmuir model has been widely used for the coal-methane sorption process through an isothermal test. However, even though the temperature-dependent Langmuir model was recognized theoretically and experimentally, the quantitative relationships between the Langmuir constants a and b and temperature have not been clarified and confirmed by laboratory test data. This paper collects 158 methane-coal sorption data under different temperatures that apply the Langmuir model to the relationships between the Langmuir constants a and b and temperature. Even though the Langmuir model cannot be used to show the physical state of methane adsorption on coal, it is widely used because of its simplicity and the reasonable explanation of its parameters a and b. The results from these published isothermal tests indicate that (1) there is no consistent relationship between Langmuir constant a and temperature, (2) the Langmuir model is a temperature-dependent model whose temperature-dependent feature is mainly shown by the relationship between the Langmuir constant b and temperature, and (3) the relationship between the Langmuir constant b and temperature can be described by both exponential and linear relationships with dried coal. This paper provides a database for the temperature-dependent Langmuir model that can be used for the reservoir simulation of coalbed methane reservoirs and for the coal seam degasification modeling of underground coal mines, considering the heating effects induced by geothermal and heat injection through factors such as hot water, hot steam and ultrasonics.

Jan 1, 2016

By H. P. Hamlin, W. A. Grosh

Samples of clays , shales , and argillites from 21 locations were subjected to preliminary bench- scale tests for bloating properties , and several samples were tested for ceramic properties . Samples showing favorable bloating properties were further tested in a pilot - plant - scale rotary kiln . Physical characteristics and concrete -making properties of the bloated products were determined . The Decorah shale from one area made a suitable material for a lightweight aggregate ; however , the limestone layers in the formation must be eliminated or the resulting activated lime must be controlled by quenching .

Jan 1, 1963

By Carl Rampacek, W. A. McKinney

The feasibility of leaching calcareous and siliceous oxidized copper ores by downward percolation with dilute acid was investigated in the laboratory and in a small continuous plant operated by the Federal Bureau of Mines . The crushed ore was leached in deep columns with solutions containing 1 or 5 percent sulfuric acid to dissolve the oxidized copper . Bench - scale laboratory tests on two calcareous ores from the same deposit indicated that a maximum copper extraction , about 72 percent , could be expected from heap leaching a feed as coarse as 1 inch . Laboratory tests on a siliceous ore showed that almost 70 percent of the copper could be extracted by leaching a 1 / 4 - inch feed . The bench - scale tests were supplemented by larger continuous runs wherein the copper was recovered from the leach liquors by precipitation on detinned scrap iron . Leaching the calcareous ore for approximately 10 days recovered 62 percent of the total copper . The sulfuric acid consumption was 9.6 pounds per pound of copper recovered . Treatment of the siliceous ore recovered 62.5 percent of the total copper in a 2.5 - day leach and the acid consumption was 3.7 pounds per pound of copper recovered . Cement copper products that assayed over 71 percent copper were obtained from the leach solutions by precipitation on scrap iron . The bench - scale and continuous tests demonstrated that downward percolation leaching of the calcareous ores was technically feasible but not economically practicable because of high acid consumption by the gangue . Leaching of the siliceous ore was rapid and the acid and water requirements were nominal . The downward percolation leach procedure is simple and requires a minimum of plant equipment .

Jul 1, 1960

By Y. J. Wang

In the mathematical analysis of electrical networks, the electrical devices are often modeled using idealized network elements such as current sources, voltage sources, and resistors. An analogous approach is outlined here for the modeling of mine ventilation networks, which can be considered nonlinear resistive networks. The modeling technique proposed uses five basic (non-reducible) elements: the H element, the Q element, the D element, the R element, and the N element. These elements are characterized by their (a) pressure gain or loss, (b) air quantity, and (c) pressure-versus-quantity relationship, each of which may be known or unknown. In addition to the definition of the basic elements, the necessary conditions for which there exists a unique solution are discussed. This is performed using theoretical developments derived from electrical circuit theory and illustrated in example networks. The proposed procedures are useful in the solution and characterization of mine ventilation networks.

Jan 1, 1996

Improved roof control in high deformation tailgate environments has been achieved over the last decade through development of stiffer and increased capacity standing support products. æThe CanÆ is one such development, being a steel cylinder containing a weak cementitious fill, designed to essentially fold in upon itself whilst maintaining strength. A laboratory study to better define the relative load contributions of the steel cylinder and fill, the confining interaction between these components and most importantly, the potential impact of varying the steel and/or fill properties is described. This would enable the support engineer to ædial-upÆ the desired strength and stiffness properties and optimise the standing support design with respect to load capacity, stiffness, weight (handling) and cost. Design curves to optimise strength based on steel casing thickness, fill strength (confined and unconfined) and æCanÆ geometry were established. Scaled-down (one-third) samples were used in the test program and found to adequately reflect the loading behaviour of full-scale versions, thereby providing significantly greater scope for further product development at less expense compared with testing full-scale products.

Jan 1, 2005

By Bruno Leonardy Sousa Lopes

Este trabalho tem como objetivo mostrar a correlação entre as fases constituintes do aço superdúplex SAF 2507 na junta soldada por processo MIG-MAG, considerando os efeitos da energia de soldagem nas propriedades mecânicas e de corrosão. Os resultados mostraram que a energia de soldagem causou mudanças no balanço das fases a/?, na formação pontual da fase s nos contornos de grãos ferriticos e mudanças de microdureza e tenacidade nas regiões da zona fundida (ZF) e zona termicamente afetada (ZTA), além de promover o aumento da fase ? e do índice de resistência à corrosão por pite (PREN?), quanto maior energia de soldagem. Entretanto, a tenacidade na ZF diminuiu mesmo com maior formação da fase ?, coalescimento dos grãos ferriticos, elevando a microdureza na ZTA sob baixa energia de soldagem. Assim, espera-se que estes resultados permitam estabelecer diretrizes para procedimentos de reparo em aços superdúplex sob processo de soldagem

Aug 17, 2017

By Ana Paula Gonçalves Chaves

A pesquisa relativa ao transporte ferroviário no Brasil tem se intensificado nos últimos anos visando principalmente a melhoria no desempenho do par roda-trilho. Isso se deve a demanda de se transportar cada vez mais carga por eixo visando uma redução no custo de transporte. Através de mudanças na microestrutura do material ou de mudanças na composição das ligas utilizadas na fabricação pode se aumentar a resistência do par roda-trilho. Neste trabalho foi analisada a influência de diferentes microestruturas (puramente perlíticas e perlíticas-bainíticas), obtidas através de tratamento térmico por dilatometria, nas propriedades de um aço alto carbono similar ao utilizado em rodas convencionais classe C destinadas a implementação pesada com altas cargas e baixas velocidades. Foram realizados tratamentos isotérmicos em dez temperaturas diferentes para um aço eutetóide. As análises incluíram técnicas metalográficas (definição de fases presentes e distância interlamelar da perlita), ensaios mecânicos de dureza e ensaios magnéticos (saturação magnética e ruído de Barkhausen).

Aug 17, 2017

Carbon injection into metallurgical slag is important in electric arc furnace (EAF) steelmaking for foamy slag practices and in nonferrous slag cleaning operations. The current publication presents kinetic data for coal injection into EAF slag to understand the interaction between injected carbon and metallurgical slag. Coal particles were injected into EAF slag and the kinetics were followed by gas and slag analysis. The results were analyzed, in terms of fundamental rate equations for each possible reaction step, as a function of temperature and slag composition.

Jan 1, 2003

By Raymond W. Hiteshue, Sam Friedman, Paul Dobransky, Robert Madden

A hvab coal was carbonized in a closed system at 600 ° C and 40 to 1 , 200 psig to produce a high- Btu gas and char . By retaining the volatiles within the system, it was possible to virtually eliminate production of tars and oils . Depending on pressure and residence time , yields of combustible gases (72 to 92 percent methane ) amounted to 4,000 to 6,000 cubic feet per ton of maf coal and gross heating values of these gases varied from 830 to 960 Btu per cubic foot . Yields of char (maf ) were about 1,600 pounds per ton of maf coal . Increased residence time favored production of gases but reduced their heating values , whereas increase in pressure resulted in somewhat higher heating values and lower production . Similar effects were observed from the carbonization of a low- temperature tar . If these results could be translated to an economical carbonization process for producing high- Btu gas from coal , the demand for coal could be expanded by 40 to 50 million tons per year . Because of large yields of char , a process of this type would obviously have to be integrated with coal - fired power plants . Fortunately , operations could be conducted at essentially atmospheric pressure as product gas under this condition can be obtained in satisfactory yields and with good quality .

Jan 1, 1964

By B Hannah, M Uriarte, F Labarca, C Madore, G Ganapathi, L Martin, T Haase

BechtelÆs Mining and Metals projects across the globe are executed in remote arid and semi-arid countries where providing even basic water supplies impose considerable challenges. Opportunities for water conservation measures using a Six Sigma initiative were proactively pursued to address the potential business impacts of limited availability of water resources. The initiative investigated areas driving water-optimisation during concrete operations and camp management. This paper details the water conservation evaluation of alternatives and cost/benefit analysis based on current and predicted water usage for development projects. Optimisation of water consumption through institutionalising more prescriptive standards for camp design and defining water conservation requirements have resulted in a new standard specification. Based on our projected mining project workload across the globe, it is estimated that for the period 2012 - 2015, a potential 5.5 M m3 water savings resulting in US$11 M could be realised for construction camps and savings of 4 M m3 of peripheral concrete process water resulting in potential cost savings of US$8 M could be achieved as a result of these revised standards.CITATION:Haase, T, Hannah, B, Ganapathi, G, Martin, L, Madore, C, Labarca, F and Uriarte, M, 2013. Water conservation at construction projects, in Proceedings Water in Mining 2013 , pp 251-258 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

By O. P. Sinha, Biswajit Mishra, A. K. Mandal, Raj Kumar Dishwar, G. S. Mahobia, Ram ji Omar

Most of the mineral deposits found in North-East India remain unexploited due to inadequate knowledge on their status, economic viability, and requisite mining technologies. The aimof this study is to characterize the multimetallic magnetite mineral deposit from the Nagaland area in India. The quality of iron ore was evaluated to establish its suitability as a raw material for iron production. Detailed studies were conducted to establish the composition and properties of the samples. X-ray diffraction (XRD), X-ray fluorescence (XRF), electron probe micro-analyzer (EPMA), and petrographic microscopy techniques were employed in the investigation. Shatter and tumbler test was performed for analyzing the mechanical properties of the ore. XRD studies indicated that magnetite is the major mineral with low amounts of martite, maghemite, and quartz. XRF/EPMA results indicated that magnetite contains 35–65 wt.% of iron and 1–5 wt.% of chromium. It also confirms the presence of Ni and Al up to 1 wt.% and Si up to 6 wt.%. Chromite-rich ore contains up to 30 wt.% Cr and 15–20 wt.% of Fe.

May 10, 2021

By R. D. Parker

Location The Frood ore-body is expressed on surface as a prominent gossan ridge, with a total length of approximately two miles. The original Frood (the old No. 3 mine of the Canadian Copper Company) is at the southwest end of this gossan; adjoining it on the northeast is the Frood Extension (until 1929 the property of i:he Mond Nickel Company), while at the extreme northeast end is the Stobie mine. The first two of these divisions of the ridge form the Frood mine as it is known today.? This lies in lots 6 and 7 of the sixth concession, township of McKim, and is two and a half miles north of the city of Sudbury. The general elevation is 1,000 feet above sea level. The Ore-Body The Frood-Stobie parallel offset(l), as its name implies, has no connection in the field with the main mass of the Sudbury nickel eruptive-a norite. It lies one mile to the southeast of that body, and, in general, parallels it in strike. The ore occurs as a more or less tabular structure in what is known locally as the Sudbury series. They are the oldest rocks of the district, and have been placed by Collins(2) as earlier than the lower Huronian, of pre-Cambrian time. The series is comprised of sediments, volcanics (both acid and basic flows), tuffs, agglomerates, breccias, and basic intrusives, all highly metamorphosed, yet all forming a more or less regular picture. The controlling feature of the area has been the attitude of the sedimentary strata, from which has arisen the present sill-like character of the flow rocks, the basic intrusives, and the ore-body itself.

Jan 1, 1932

By R. W. McCallum, B. Jensen, K. W. Dennis

"There are substantial challenges in the exploration of magnetic materials in the R-TM-X system (R =rare earth, TM= transition metal, X =stabilizing element) where Xis an element which has high vapor pressure, high reactivity, toxicity, or a refractory nature. This research focuses on discovering new phases with high anisotropy and high magnetization through closed diffusion couples inside high purity Fe crucibles. Either vapor-solid reactions or powder metallurgy techniques are then employed to isolate a stoichiometric sample based on a potentially magnetic phase found in the diffusion couple. For this research, X = F, Ca, Sr, Se, Zn, Bi or Cd, TM= Fe, and R = Nd. New ternary phases have been discovered with WDS and EDS, and magnetic transition temperatures have been measured with a SQUID magnetometer and VSM.IntroductionSince the discovery of the RCo5 compounds in the 1960s, rare earth- transition metal (R-TM) magnets have been the main focus of permanent magnetic research over the last five decades. Iron-based magnetic materials were studied next in attempts to avoid the unstable price of cobalt as well as the high price of Sm, the top performer in the RCos and RzC011 series. This hunt eventually led to the discovery of Nd2Fe14B with a theoretical BHmax of 64 MGOe, nearly double that of the previous samarium based magnets. The next few decades were devoted to enhancing the magnetic properties ofNd2Fe14B by the improvement of processing techniques and the additions of alloying elements. The only complete elemental substitution discovered in this system was R1Fe14C, which did not improve magnetic properties. It is probably safe to say that most ternary R-TM-X systems, where Xis any element that may stabilize a ternary phase, have been investigated if they may be prepared by conventional processes such as arc or induction melting. The present study offers a systematic approach to developing a novel diffusion couple technique in which the volatile, reactive or toxic alloying elements are laser welded inside a high purity Fe crucible. This experimental setup will prevent the oxidation of the rare earth element, as well as contain the volatile X element. As the goal of the research was to find new rare earth permanent magnets, only phases which contained greater than 60 wt% Fe were investigated. 247"

Jan 1, 2012

By Seth C. Schaefer

The Federal Bureau of Mines studied the Gibbs free energies of formation of chromous fluoride (CrF2), chromic fluoride (CrF3), and chromium (II,III) fluorides (CrF2.40 and CrF2.45) with high-temperature galvanic cells employing calcium fluoride doped with 1 mole-pct yttrium fluoride as the electrolyte. Free-energy changes were obtained from open-circuit potential measurements for the following cells: Cr, CrF2 // CaF2 // NiF2, Ni (a) NiO, NiF2 // CaF2 // CrF3 , Cr203 (b) CrF2 , CrF2.40 // CaF2 // NiF2, Ni (c) and CrF2 ?45 , CrF3 // CaF2 // NiF2, Ni (d) with the following overall reactions Cr(s) + NiF2 (s) = Ni(s) + CrF2 (s) (1) 3NiO(s) + 2CrF3 (s) = 3NiF2 (s) + Cr203 (s) (2) 5CrF2 (s) + NiF2 (s) = 5CrF2.4O (s) + Ni(s) (3) and 3.64CrF2.45 + NiF2 (s) = 3.64CrF3 (s) + Ni (s) . (4) These results were combined with the best available literature values of ?Gf° of NiF2, NiO, and Cr203 to deduce Gibbs free energies of formation for the chromium fluorides expressed as follows: ?Gf°(CrF2) = -179.31 + 24.33 X 10-3T ± 0.43 kcal-mole. (5) (858.1 - 964.9 K) ?Gf° (CrF3) _ -226.16 + 1.82 X 10-3T ± 0.79 kcal/mole (6) (880.8 - 957.8 K) ?Gf°(CrF2.40) _ -213.65 + 32.14 X 10-3T ± 0.44 kcal/mole (7) (0053.9 - 936.8 K) and ?Gf°(CrF2.45) _ -176.17 - 12.67 X 10-3T ± 0.80 kcal/mole (8) (875.1 - 937.6 K). Free energies and equilibrium fluorine pressures for three univariant and one bivariant equilibria are illustrated.

Jan 1, 1976

By Canterford J. H, Sparrow G. J, Dyson N. F

Pressure leaching of a bulk flotation concentrate prepared from a complex Cu-Pb-Zn sulphide ore was carried out at 150 and 190¦C under 1050 kPa oxygen overpressure in 1 L and 4 L titanium autoclaves to extract zinc, and to obtain residues for smelting tests and leach liquors for purification and recovery of the zinc by electrowinning. Dissolution of 95% of the zinc was achieved at both temperatures. Copper and iron dissolution and the degree of oxidation of the sulphide sulphur to elemental sulphur or sulphate depended on the temperature of the leach. At 190¦C, a jarosite (a basic iron sulphate) was the major iron-containing material in a residue that contained 17% total sulphur. Its formation was associated with dissolution of 18% of the iron. At 150¦C, oxidation of the sulphide sulphur and dissolution of the iron were significantly less. Only 7% of the iron was dissolved and a residue containing 25% total sulphur, present as a lead jarosite, lead sulphate, and elemental sulphur, was obtained. The formation of small pellets of unreacted sulphides coated with elemental sulphur caused problems during the leaching at 150¦C, and also during scale-up from the 1 L to the 4 L autoclave at 190¦C. At 150¦C the concentrate required two stages of leaching to achieve dissolution of over 90% of the zinc. These problems are discussed.

Jan 1, 1989

By A. E. M. Warner

Inco Limited has long and extensive experience in converting nickel-copper primary smelting mattes over a broad range of nickel/copper weight ratios and combined nickel-copper-cobalt contents. At the Copper Cliff Smelter, the composition of the converter product matte has to meet the requirements of the matte separation process; at the Thompson Smelter, converter matte of a different composition is cast into anodes for nickel electrorefining; and in Soroako, Indonesia, a very low copper product matte is granulated for the Japanese market. Recently, Inco has conducted pilot plant testing of three possible nickel-copper matte continuous converting routes, namely flash converting, oxygen top blowing-nitrogen bottom stirring, and tuyere blowing. This test work has generated substantial new information on nickel-copper matte converting chemistry. This overview paper reviews the metallurgy of nickel-copper matte converting, in particular the behaviour of cobalt and the operating conditions required to meet the iron and sulfur specifications of the product matte. The relevant thermodynamic information is used to discuss the industrial data.

Jan 1, 2003

By Zhucheng Huang, Yuanbo Zhang, Kecheng Zhang, Guanghui Li, Tao Jiang

"With rapid development of Iron and Steel industry, plenty of metallurgical dusts and sludges are generated, which have not been effectively utilized because of their poor hydrophilicity and bad ballability. Agglomeration and roasting of metallurgical dusts & sludges with a new-type composite binder are studied in this paper. The results indicate that the dosage of the new binders can be decreased to 2.5 wt% from 3.5 wt% when using the wet-grinding process. Under the optimal conditions of briquetting pressure 2070 N/cm2, briquetting moisture content 13 wt%, roasting temperature 1000 °C and roasting time 40 min, the qualities of the green, dry and roasted briquettes meet the requirements of the industry production. The finished products have the compression strength of more than 2000 N/cm2, which can be used as high-quality burdens for blast furnaces.IntroductionWith rapid development of Chinese Iron & Steel industry, there are more and more serious resource shortage and environmental pollution existing. Converter sludges, containing 30% ~ 40 wt% moistures, are typically difficult for recycling [1]. Foreign processing technologies for sludges treatment are relatively advanced including cold-bonded agglomerates for blast furnace, RHF reduction for the dusts and sludges with high content of Zn and Pb, smelting and reduction. Domestic iron and steel companies use a small amount of sludges in sintering. However, the sludges have the characteristics of high moisture and containing harmful impurities, which directly affect the sintering mixture permeability and product quality [2-5]. There are also other technologies such as production of metallized pellets, cooling agents for steelmaking, etc [6]. All of these deficiencies and applied are not in large-scale."

Jan 1, 2011

By R. G. Reddy

The Margules .equation is used for interpreting excess Gibbs energy of several ternary systems. In the present study activity coefficient of 'a dilute solute, 2, in a binary solvent 1-3 was derived. The derived expression is used to interpret logarithmic activity coefficient of oxygen and sulfur in several metallic systems. Self interaction parameter of the solute is derived from the partial function of solute using constant compositional path. An expression for logarithmic activity coefficient and self - interaction parameter of solute is also derived using Maclaurin infinite series. The derived equation is based on Maclaurin infinite series used successfully to deduce thermodynamics of self interaction of oxygen as a interstitial atom in two metallic systems. The predicted thermodynamic parameters values using Maclaurin infinite series and Margules. equations, are in excellent agreement with the experimental data and also our predictions are far more accurate than the predictions made by other models.

Jan 1, 1996

By Maria Rashidi, Maryam Ghodrat, Bijan Samali

Treatment of sharp medical waste (waste disposable syringes) produced in hospitals or health care facilities in an environmentally sound ways have raised concerns relating to public health and occupational safety. Life cycle assessment (LCA) is a decision-supporting tool in waste management practice; but relatively little research has been done on the evaluation of sharp medical waste treatment from a life cycle perspective. Our study assesses the environmental performances of medical waste incineration as a type of dominant technology for specific medical waste of average composition. Inventory models were used for waste incineration and residues land fill. Background data were derived from modelling performed in HSC Chemistry thermochemical package linked with GaBi environmental assessment tool. Two scenarios have been considered and compared: Waste disposable syringes partially replacing coke in Electric Arc Furnace (EAF) steelmaking (WSI) and conventional incineration with pure metallurgical coke without adding waste syringes (CI). The results of this study could support the medical waste hierarchy and indicate that from a life cycle perspective, replacing part of metallurgical coke with waste syringes in electric arc furnace steelmaking leads to fairly significant reduce in most of environmental impact categories.

Mar 1, 2017

By V. Sheikhzadeh, M. Saghaeian, N. Esmaeili, R. Hejazi, A. D. Ahmadabadi

The main challenges in most low grade iron ore deposits are finding the optimum flowsheet for beneficiation to achieve a final concentrate from both technical and economic viewpoints. Dry preconcentration techniques are being used to assist in reducing the amount of ROM feed to the plant. In this paper the benefits of utilising a dry cobbing magnetic separation technique for upgrading the product of HPGR in a closed circuit with dry screen 4 and 1.4 mm by performing a pilot scale test work was investigated. The experimental test work was done on two sample types of Yogi BIF magnetite iron ore located in Western Australia. Prior to magnetic separation studies, detailed characterisation of the feed materials including physical, chemical, mineralogical and magnetic properties were carried out. Furthermore, the effects of process parameters: drum rotation speed (1.5, 2.5 and 3.5 m/s), magnetic field intensity (1100 and 3800 gauss) and feed size (minus 4 and 1.4 mm) were investigated. The results revealed that sample type1 with 33.90% Fe could be upgraded to 41.51% Fe by using a stage of 1100 gauss dry magnetic separator with 69.12% weight recovery and 84.36% Fe recovery at a size of 4 mm. Also for sample type2, it is possible to increase Fe grade from 29.84% to above 36.68% with 75.58% weight recovery and 90.32% Fe recovery by applying one stage of 1100 gauss dry magnetic separator to a 4 mm size sample. Keywords: Banded iron formation (BIF), pre-concentration, dry cobbing technique, magnetic separator

Jan 1, 2020