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By G. L. Humphrey

Although silicon carbide has been an important manufacture refractory for many years, knowledge of its thermodynamic values has been seriously lacking. In fact, some of the very properties that make it a useful substance, particularly chemical inertness, obstruct determination of its heats of formation and reaction. This paper reports the results of new measurements of the heats of combustion and formation, low-temperature heat capacity, entropy at 298.16°K., and heat-content and entropy increments between 298° and l,800°K. Two varieties of silicon carbide were studied -the common, hexagonal (type II) and cubic. The data are combined to obtain heat and free-energy-of-formation functions, which are given in tabular form. It is shown that the cubic variety is the more stable at temperatures to at least 1,800°K but, because of the inherent difficulties and errors in the heat-of-formation determinations at 298°K, it was not found possible to specify the free-energy difference accurately. The mechanism of silicon carbide formation from silica and carbon is not known and is not ascertainable from thermodynamic data. It appears improbable, however, that it can be a single-step reaction. Some reactions involving silicon monoxide gas and metallic Silicon, as possible intermediates in silicon carbide formation, are considered and shown to be thermodynamically feasible.

Jan 1, 1952

By J. Sliwinski, H. Kikutani, J. Atwood, D. Larimer, J. Pyecha

"The Pogo mine start-up milling targets of 2005 are vastly different than the targets of today. Improvements have been driven by unintentional design oversight, continual circuit optimization or optimization due to changing mineralogy. The more significant process improvements to date have occurred in the gravity, flotation and leach/CIP unit operations. Details of the significant improvements are presented along with the impacts to the process.INTRODUCTION Deposit Overview Pogo mine is located along the Goodpaster River, southeast of Fairbanks, Alaska. This deposit sits in the center of the Tintina Gold Province (Figure 1), a region of similar Intrusion Related Gold deposits in Interior Alaska, the Yukon and British Columbia Canada (McCoy et al., 1997). The Pogo deposit is hosted in a rock sequence of amphibolite-grade gneisses intruded by mid-Cretaceous granitic plutons and dikes, which in turn, were cut by and host the auriferous quartz veins of the Pogo deposit.The Pogo deposit is comprised of three distinct zones of auriferous quartz veins spatially adjacent to each other. These are the Liese Zone, North Zone, and the East Deep Zone. The Liese Zone consists of three stacked, massive quartz veins, designated the L1, L2, and L3. Vein thickness averages 3.0 m, with variations from 0.3–18 m thick. The North Zone mineralization is comprised of four veins with more consistent thickness, between 1 and 1.5 m. The East Deep deposit lies northeast of the Liese Zone ore body. It is separated by a post mineralization, quartz diorite pluton. The East Deep Zone is comprised of two stacked massive quartz veins with similar orientation as the Liese Zone."

Jan 1, 2017

By Paul A. Farrar, Louis P. Stone, Harold Margolin

The Ti-Mo-0 system was investigated in the region 0 to 45 wt pet Mo and 0 to 10 wt pet 0, from 600° to 1400°C. Solidus data are also presented. Isothermal sections at 700°, 900°, 1100°, and 1300°C, and vertical sections at 1 and 28 wt pet Mo, and 1 and 10 wt pet 0 are included. STUDY of the Ti-Mo-0 system has been carried out as part of a general study of titanium phase diagrams. The binary Ti-Mo system has been investigated in whole or in part by several investigators.1-8 It was found that molybdenum and ß-tita-nium form a complete series of solid solutions and that the ß/a + ß transus is depressed to below 600°C at approximately 30 pet Mo.* The Ti-O system has been investigated partially or fully in the range 0 to 30 pet 0 by several investigators." Extensive solubility of oxygen occurs in the field. While a is

Jan 1, 1957

By Ernesto Sirvas Bello

El presente trabajo describe el proceso del proyecto de exploración por cobre y molibdeno en el centro del Perú. Para la aplicación del proyecto se necesita conocer las características geográficas de la zona y así luego señalar la efectividad de los métodos a utilizar. La topografía de la zona comprende sedimentos del Cretásico inferior y medio formados por cuarzitas y calizas, los cuales han sido intruídos por granodioritas que ocupan la parte central e inferior del área. La alteración en la zona estudiada se presenta en forma de sericitación, cloritización, kaolinitización y una débil silicificación. En la intrusiva, de acuerdo al grado de intensidad, se diferenciaron hasta cuatro grados de alteración. La mineralización en las sedimentarias prosiguió al metamorfismo y está formada por tetraedrita, galena, esfalerita y pirita distribuída en una ganga cuarzosa reemplazando capas delgadas de corta corrida. En la intrusiva, la mineralización está formada por molibdenita asociada con pirita, sericita y trazas de chalcopirita presentándose en diseminaciones y en vetillas. De otro lado, el empleo de métodos prospectivos geoquímicos y geofísicos para detallar anomalías en las concentraciones de mineralización, no logró el efecto esperado. Por ello, se utilizaron los procesos geoquímicos seguidos por el cobre y molibdeno, donde no se encontró zona de enriquecimiento secundario para el cobre ni concentraciones importantes de molibdeno.

Aug 20, 1963

By Sarkis G. Ampian

Published optical microscopic and X- ray diffraction characteristics of the following compounds are critically evaluated and compared with Bureau of Mines data : Tricalcium aluminate , calcium monoa luminate , dodecacalcium heptaluminate , dicalcium silicate , tricalcium silicate , and sodium aluminate . A recommended set of definitive optical and X- ray diffraction characteristics is presented . These values are used to identify products of the lime soda sinter process for production of alumina . Polymorphism of gamma- , beta- , and alpha prime - dicalcium silicate is reexamined , and new data are presented on polymorphism of tricalcium silicate and sodium aluminate by high- temperature X- ray diffractometry . Polymorphism is not observed for tricalcium aluminate , calcium monoaluminate , and dodecacalcium heptaluminate . Bureau of Mines data indicating a stoichiometry of 12Ca0.7A10 for the phase 5Ca0.3A1 0₂ are discussed . A critical review of the literature concerning calcium dia luminate and sodium undecaluminate ( 8 -A10 ) is also included .

Jan 1, 1964

By Vestre J, Kure K, Bergqvist I

Existing practical laboratory tests for comparative strength determination of commercial explosives consist of the lead block test, the ballistic mortar test, the bubble test etc. These tests are carried out in material with quite different properties compared to rock. The theoretical performance potentials of commercial explosives are traditionally described by weight-strength (WS). Some explosive producers use the Langefors formula for weight-strength calculation, where also the gas volume is considered. Neither the theoretical nor the practical methods for determination of explosive performance such as the above, give good enough prediction of fragmentation and heave in rock blasting. For these reasons a project was started for the purpose of finding a small scale test method which predicts how different explosive parameters affect fragmentation and heave. Small scale tests were carried out by using 50 cm cubical blocks, mainly of concrete, but a few also of rock. All blocks were blasted in a steel cylinder with a diameter of 1.2 meters. The velocity of detonation was monitored, and the velocity of fragments was derived from their time of arrival at the steel wall, which was registered by accelerometers. After blasting all fragments were screened. The charge diameter was 22 mm and the amount of explosive 78 grammes, resulting in a specific charge of 0.62 kg/m3. Explosive properties such as energy, gas, VOD and density were systematically changed.The results presented in this paper show how fragmentation and heave systematically change when the explosive properties like energy, gas, VOD and density are systematically changed. The results from the small scale tests are compared to full scale tests carried out in tunnel blasting, and during summer 1990 also in bench blasting.

Jan 1, 1990

By E. R. Mueller

The natural lives of machines and components vary tremendously! Maintenance managers struggle constantly to maximize their equipment lives while minimizing their maintenance costs, but they normally lack the tools and techniques they need to do this properly. This paper proposes a methodology based on probabilities of failure and expected values for repairs that recognizes the variation among individual machines and components as well as the high costs associated with catastrophic failures. It enables a user to determine the optimum change-out intervals for many types of equipment. The approach proposed here is sophisticated enough to be reliable but simple enough to be applied by the maintenance staff on the shop floor. It will complement existing preventive and predictive maintenance programs.

Jan 1, 1995

By S Hapugoda, J R. Manuel, M J. Peterson, A Poliakov, E Donskoi

The occurrence and deportment of manganese in a number of ferromanganese and Mn-bearing iron ore samples from supergene-upgraded deposits, as well as from magnetite banded iron formation (BIF) and magnetite skarn deposits, was characterised in order to provide a basis for improved understanding of the processing characteristics of different ore types and investigate the potential for development of a robust geometallurgical classification for Mn-oxide ores. An understanding of the Mn mineralogy in mixed Fe-Mn deposits is necessary to inform any attempt to separate the Fe and Mn during beneficiation and to understand and predict the behaviour of lump and fine ore products during processing.A suite of analytical techniques was utilised, including hand sorting of lump ore particles, optical microscopy, X-ray fluorescence (XRF)/inductively-coupled plasma mass spectrometry (ICP-MS) chemistry, X-ray diffraction (XRD), scanning electron microscopy (SEM)/electron probe microanalysis (EPMA) and gas and solid phase pycnometry, in order to elucidate manganese mineralogy, mineral chemistry and mineral textures. Manganomelane group minerals (eg cryptomelane, hollandite), pyrolusite and lithiophorite were the most common manganese oxides in the samples examined. From the microprobe work, there was evidence of probable substitution of Mn, as well as Al and Si, into the structures of goethite and hematite. Manganomelane minerals were often intimately associated with goethite, in particular, and a clarification of this association and the associated Si and Al impurities is fundamental for improved understanding of beneficiation and sintering behaviour of Mn-oxide ores. Due to the poor or very fine crystallinity of some supergene manganese deposits and of some Mn oxide minerals, in particular the extent of overlapping peaks and their variable mineral chemistry, XRD was a problematic technique to equivocally determine Mn mineralogy.For lower-grade, earthy, poorly microcrystalline ores the mineralogical and textural association between mixed Mn, Fe and Al (¦ Si) phases was also critical. The deportment and potential separation of these elements in these deposits, especially Al, was complex, as they were characterised by forms of æhydrousÆ cryptomelane with higher levels of Fe-Al-Si substitution, as well as intimate intergrowths of ochreous-earthy goethite (probably aluminous in part) with cryptomelane, lithiophorite and/or kaolinite.Trace amounts of alkali elements in ferromanganese deposits were considered likely to be preferentially structurally associated with Mn oxides, while lateritic deposits with significant amounts of lithiophorite could contain elevated levels of deleterious impurities; Co and Ni in particular.A combination of solid and gas phase pycnometry proved to be a useful technique for broadly discriminating hematitic, goethitic and mixed Mn oxide-goethite lump particles based upon differences in their envelope and apparent densities. Based upon these preliminary results and ongoing Raman spectroscopy work on manganese deposits sensu stricto, Raman spectroscopy is a technique considered to have promise during targeted research to better link the optical and compositional properties of ferromanganese ore particles. CT-scan (computed tomography scan) analysis could also be combined with Raman spectroscopy and pycnometry to link mineral composition, mineral texture, ore particle textures and particle porosity/permeability to the high-temperature processing behaviour of lump and fines products.CITATION:Peterson, M J, Hapugoda, S, Manuel, J R, Donskoi, E and Poliakov, A, 2013. Textural characterisation of manganese minerals to improve the geometallurgical characterisation of ferromanganese and iron ores, in Proceedings Iron Ore 2013 , pp 281-300 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By A. G. Pentland

PROSPECTING is popularly supposed to be surrounded with an air of romance and adventure. The word 'prospecting' brings to mind high mountains, northern lakes, and aeroplanes. A note of urgency has been added to this by the war, particularly in the case of strategic, minerals. Prospecting for strategic minerals in a modern mine in full production, although it may Jack the romance of travel in little-known places, has the advantage of having all the necessary machinery at hand and ready to go into action at a moment's notice. HISTORY Tin was discovered in the Sullivan ore in 1925, when a white streak was noticed on a pilot table which was being used to check the amount of galena in the tailing. The mineral which made up this streak was identified as cassiterite. The amount of tin in the ore is so small that, while of scientific interest, it was considered to be of very little economic importance. Nevertheless, several attempts were made to learn something of the occurrence during times when other work was nor pressing. These studies were dropped when anything came up that seemed more important.

Jan 1, 1943

Prefeasibility planning and cost estimation of conveyor systems has historically been undertaken by comparing fi xed plant transport requirements to that of similar systems in service. This paper describes the development of a prefeasibility conveyor technical design and cost estimation application using Microsoft Excel Visual Basic for Applications (VBA) platform. The application tool known as D-Convey (Dachshund Convey) was developed with the goal enabling the end user: to develop a technical model for conceptualised conveyor systems, to perform economic analysis on the developed technical model, and to conduct a comparative and risk analysis. An Excel VBA based platform was utilised to draw upon both the analytical and graphical capabilities of a spreadsheet. Some of the features of D-Convey system include a revolutionary dynamic graphical help system, known as the 'information pane' in lieu of traditional help fi les as well as the use of familiar graphical user interface elements such as the MS Offi ce 2007 task ribbon. The D-Convey system incorporates material database allowing for mass handling prefeasibility estimation in other industries; it has been validated at a local quarry.

Dec 6, 2010

By F. W. Robinson

THE temperature coefficient of electrical resistance of pure metals is high and therefore the resistance increases rapidly with rising temperature. In 1871, Siemens suggested the use of this property as an accurate means of temperature determination. Owing to practical difficulties, particularly the contamination of the metal and consequent permanent change in its resistance and its resistance-temperature relation, this method fell into disrepute as a practical standard until revived later by Callendar and Griffiths, and subsequently by Holborn and Wien, all of whom showed that the earlier difficulties were not inherent in the method but incident to the mode of protection of the resistance coils. Following .the work of these investigators, the problem of temperature measurement by this means has been the subject of careful study and has now assumed an importance second only in practical adoption to the thermo-electric method. It is generally recognized, both here and in Europe, that the standard temperature scale should be the thermodynamic as it permits the evaluation of high temperatures on the basis of the radiation laws of Stefan and Bolzmann, of Rayleigh, and of Wien and Planck, on a scale consistent with that obtained by means of the gas thermometer at low temperatures. Lord Kelvin showed that only. a very small correction, amounting to about +0.7° at 1000° C.-almost within the limits of experimental errors-is necessary to adjust the constant-volume nitrogen thermometer to the ideal thermodynamic scale.

Jan 9, 1919

By J. LeRoy Peterson

This paper presents some of the theoretical aspects as well as some results of actual plant operation of the Ty-Hukki Classifier. Dual classification steps within a unit vessel are achieved by controlled separation of the sand product under turbulant flow conditions, followed by further classification under strictly laminar flow conditions. Plant operation has shown some of the benefits of the superior sharpness of classification to be reduction of circulating load in grinding circuits, prevention of overgrinding, increase in mill feed rate and consequent reduction in cost per ton of ore.

Jan 1, 1966

By Foster Fraas

Almost all minerals show irreversible changes in electrical conductivity after heating in the temperature range 100° to 800° C. This effect can be detected with only a limited number of minerals with the standard ionizing-electrode-type separator, which differentiates between nonconductors and conductors in the single-particle resistivity range of 1011 to 1013 ohms. Tests outside this range with other type separators, such as the static field type, increase the number of minerals with which the effect can be detected to almost all that were tested. Irreversibility may be the result of an alteration of adsorption layers, volatilization of surface cations or anions, or an oxidation or reduction. One example is limonite, which decomposes to hematite and passes through two minima and two maxima in conductivity in the temperature range 100° to 900° C.

Jan 1, 1959

By Asbjørn Solheim

The service life for aluminium reduction cells is often limited by the cathode carbon, due to preferential wear along the periphery of the cell leading to the so-called "W" wear pattern. The reason for this preferential wear is not well understood. Two mechanisms are suggested in the present paper; 1) non-stationary dissolution of aluminium carbide into a layer of sludge that periodically forms and disappears, and 2) electrochemical formation and dissolution of aluminium carbide within an aluminium carbide layer containing bath-filled pores. The latter mechanism may be related to the high local current density at the periphery of the cathode.

Jan 1, 2011

By J. Wyn Prior

The seismic refraction technique is probably the most popular geophysical method of bedrock profiling in geotechnical site investigations but is somewhat restricted by the inherent assumptions in the method. This paper describes how Hales' method of profile interpretation is modified to overcome the assumptions of increasing velocity and layer thickness with depth when only first arrival data is available. A further expansion of Hales method enables presentation of refraction data in a form whereby bedrock features, such as changes in velocity, relief and dip in particular, are more readily recognized. Characteristic curves of the more common bedrock features are presented as an aid to bedrock feature recognition.

Jan 1, 1976

By William C. McBee

Specialized sulfur concretes were developed by the Federal Bureau of Mines as a result of research for the beneficial utilization of sulfur in construction materials. Materials were developed for use in acid and salt corrosive environments where portland cement concrete has been found to deteriorate. Because the mineral aggregates also come into contact with the corrosive media, concretes were developed utilizing both limestone and quartz aggregates. The sulfur binder used with both aggregates was modified by reaction with 5 pct dicyclopentadiene to improve product durability. Sulfur quartz aggregate concrete was found to have moderately high strength characteristics (6,000 psi compressive) and was extremely resistant to chemical attack by both acid and salt solutions. Sulfur limestone aggregate concrete exhibited very high strength characteristics (9,000 psi compressive) and was extremely resistant to chemical attack of salt solutions. Both types of concretes maintained their strength and integrity after long-term testing in acid and salt solutions and exhibited considerable resistance to damage by the action of freezing and thawing. Potential uses include leach tanks, electrolytic cells, thickeners, bridge decking, industrial flooring, pipe, and tile.

Jan 1, 1979

Jan 1, 1947

Jan 1, 1947

By R. M. Santmyers

Umber and sienna, like ocher, are naturally occurring mineral pig- ments composed largely of clay permeated with hydrated iron (ferric oxide), but they differ from ocher in that they also contain hydrated manganese oxide. The presence of manganese accounts for their browner color. In addition to silica and alumina (clay) and the coloring oxides of iron and manganese, these pigments often contain lime, barium, and other metallic salts as impurities. Sienna most nearly approaches ocher in chemical composition, and the chief distinction is its physical character. It grades into ocher with de- creasing iron content and into umber with increasing manganese content. Sienna is translucent rather than opaque and is more of a stain than a pigment; as the iron oxide content is rather high (often 60 to 80 per cent), the color is strong and rich and varies from pure brown to reddish brown. This pigment raw sienna, terra di Siena, and Italian earth. is known under several names: Burnt sienna is a pigment of an orange-brown tint made by cautionsly calcining raw sienna. It is divided into two grades; American, and Italian burnt sienna. American burnt sienna is a reddish-brown pigment containing from 25 to 60 per cent iron oxide (Fe2O3). One grade, found in Pennsylvania, analyses as high as 80 per cent and is mown as double strength sienna. Italian burnt sienna is a pigment generally containing more iron than the American product, averaging 60 to 75 per cent iron oxide.3 American pig- ments of the same iron content differ materially in shade, having a Havana- brown color, whereas the Italian is more of a maroon. Italian siennas when tinted with 20 per cent of white, show a bluish tint, whereas American siennas yield a brownish or yellowish hue. Raw umber, also known as Turkey umber, Levant umber, and terra ombra, is a greenish to yellowish brown siliceous and ferruginous earth, containing a considerable proportion of one or other of the higher oxides of manganese, Mng04 and MnO2." It is similar in many respects to raw sienna except that it is much coarser and contains more manganese oxide. All umbers contain over 5 per cent of manganese dioxide. Like sienna, umber is a permanent pigment, not being injured by light or by impure atmospheres. Burnt umber (velvet brown, chestnut brown, etc.), results from the calcination of raw umber. The color is much richer and warmer than that of the raw umber. The colors are equally permanent and can be used in conjunc- tion with all other durable pigments.

Sep 1, 1931

By Rolland L. Blake

Petrographic and mineralogical studies were made on unoxidized samples from the Cuyuna and Mesabi districts to study occurrence and properties of the iron phyllosilicate minerals . Examination of 96 thin sections from the thinbedded facies of the main iron - formation of the Cuyuna district indicates that the most abundant minerals are Mn - Mg - siderite , stilpnome lane , and minnesotaite . Reconstitution and recrystallization of minerals has occurred along certain beds , and textures indicate that some minnesotaite apparently formed at expense of stilpnomelane . Three samples of stilpnome lane and one of minnesotaite were concentrated from fracture - fillings within iron- formation . Results of chemical , optical , spectrographic , X- ray diffraction , and differential thermal analyses on these samples are reported . The detection of ammonia in stilpnome lane samples is the first such occurrence reported , and its significance is discussed . New mineral data are presented on greenalite and probable septechamosite from the Mesabi district .

Jan 1, 1964