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By Joseph Grumer

Theory pertaining to the exchangeability of fuel gases on appliances has been extended to exchanges of propane or butane with mixtures of these. In particular, new considerations were developed bearing on the hazard of an occasional emission of carbon monoxide and flashback and blowoff possibilities. The new considerations involve using current requirements for approval of liquefied petroleum gas appliances. These requirements were used to predict allowable tolerances in chemical composition of liquefied petroleum gases for existing appliances. In addition, changes in gasline pressure were computed which may be substituted in place of fuel exchanges during testing of appliances,

Jan 1, 1962

By Carl Bertrand, Patrice Nadeau, Claude Bazin

"Rio Tinto Fer et Titane processes the ore extracted from the Lac Tio orebody to concentrate the hemo-ilmenite (FeO.TiO2-Fe2O3) mineral that is subsequently smelted to produce pig iron and titanium oxide slag. The ore is crushed, heat treated (roasted) and concentrated using dry magnetic separators. This paper describes a model to predict the magnetic susceptibility of the roasted ore and its behaviour in the magnetic separation plant. The model uses a classification of the ore as a function of the size and magnetic susceptibility of the particles. A subsequent division into mineral species allows the simulation of the magnetic separation process. The model is used to assess various operating options when process disturbances occur.INTRODUCTIONOre processing operations consist of ore size reduction followed by the recovery of valuable species in a concentrate that is subsequently sold for its minerals or metal content. The concentration processes are based on the physical and/or chemical properties of the minerals contained in the ore. Flotation is typically used to recover minerals of base metals such as copper, zinc, lead or nickel. Iron ore and other dense minerals are typically concentrated by gravity separation processes. Magnetic separation uses the magnetic properties of the minerals to concentrate magnetite and other minerals, to clean coal concentrate and to recycle ferrosilicon for dense separation processes (Brophy, 1985).Magnetic separators can be divided into low and high intensity separators and high gradient magnetic separators (Gillet, 2008). Most of the low gradient magnetic separators are built as rotary drums that are operated in wet or dry conditions. Dry magnetic drum separators are used by Rio Tinto Fer et Titane in Sorel-Tracy, Canada to concentrate hemo-ilmenite from the ore extracted at the Lac Tio Lake mine near Havre St-Pierre, Canada. The analysis of production data suggests that process improvement could be achieved by identifying key variables for the control of the magnetic separation circuit and/or by modification to the circuit flowsheet. The use of a process model was considered to be an effective approach to conduct a preliminary analysis of the circuit with a view toward process optimization. However, the literature contains few detailed studies dealing with the modelling of magnetic separation processes."

Jan 1, 2011

By . Jaime G Tapia Aguirre

La Unidad Minera Rosaura del Grupo Glencore fue considerada la mina subterránea más segura del país durante los años 2005, 2006 y 2007. Sin embargo, cuando el Grupo Glencore adquirió la concesión de Rosaura, el panorama minero era de una mina marginal, de bajas leyes. Por esta razón, el único metodo a ejecutar para hacer de Rosaura una mina rentable era el de utilizar un método masivo. Em ese semtido, el presente texto señala la operación de mina cone el análisis y conocimiento de causa raíz en la prevención de caída de roca.

Sep 12, 2011

By M. Okido, W. Wei, L. Chai

The kinetics on the growth of Thiobacillus ferrooxidans was studied by use of series piezoelectric quartz crystal ( SPQC ). Arsenic ioninhibits the growth of Thiobacillus ferrooxidans, which is consistent with the previous results by other measuring method. This further demonstrates that the SPQC can monitor the chemical activity of the growth of Thiobacillus ferrooxidans. Cupric ion accelerates the growth of Thiobacillus ferrooxidans. The mechanism was discussed, it was considered that copper promotes the protein enzyme of Thiobacillus ferrooxidans, rustic yanin, to form over the range of cupric ion concentration studied. There action order of cupric ion in accelerating the bacterial growth is 0.067. The growth of Thiobacillus ferrooxidans is dependent on temperature, the apparent reaction activation energy decreases from25.56 kJ / mol to 18.32 kJ / mol because of the addition of 10 mg / L Cu(II) to the bacterial growth solution of pH 2.0 at initial inoculum of 10%.

Jan 1, 2000

By J. S. Mason

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Detailed paragenetic studies of the post-tectonic fracture-hosted vein mineralisation have demonstrated a complex paragenesis, reflecting a multi-phase combination of regional metallogenesis and tectonics through time. Previously published work regarding paragenesis and zoning was oversimplified. Two major epochs of mineralisation resulted in the emplacement of the A1 group of assemblages, from which lead, copper and silver were the main metals mined, and the A2 group, whose galena is only moderately argentiferous but which were major sources of lead and zinc. Tectonic and tentative isotopic evidence points to post-orogenic relaxation as the mechanism for development of the A1 assemblages in the early Devonian, whereas the A2 assemblages are believed to reflect Variscan extensional regimes and regional metallogenesis in the early Carboniferous and Permian

Jun 19, 1905

By A Prinsloo, R Tewu

Automatic control of semi-autogenous grinding (SAG) mills has often been considered complex. Recent experiences at Century Zinc (worldÆs second largest open pit zinc mine) refute this. Together with operating knowledge and appropriate control techniques high quality control is achievable. In this application model-based, constraint, and multiple output control were employed. The control was implemented using standard blocks in the plant DCS. The resulting overall control strategy fulfils the operating objectives and controls the mill with minimal operator involvement over 95 per cent of the time. Previous campaigns using expert systems and complex DCS based control have lacked durability. Their fall into disuse is briefly discussed.

Jan 1, 2009

The methods and equipment developed and used at the Mount Isa mine to obtain samples of uncemented hydraulic fill lying above major horizontal pillars are described. From existing underground development, samples were obtained at distances up to 50 m, of which up to 30 m was through hard rock. Samples were used to predict fill behaviour as it affected mining security during recovery of the pillars.Specialized equipment for difficult sampling situations and also other sampling exercises are described.

Jan 1, 1976

By P. Mbele

Iron ore concentrate is not easily transported to, or processed in, ironmaking plants, therefore it is necessary to agglomerate. This paper will determine the possibility of agglomerating Sishen concentrate into suitable ironmaking feedstock. Pelletizing is one of the conventional and preferred agglomeration processes for iron ore concentrate investigated at Kumba Value-In-Use Laboratories. Sishen concentrate was mixed with binder, and then pelletized using a laboratory pelletizing disc; afterwards the green pellets were indurated at high temperatures to give strength high enough to survive handling and lessen disintegration in the shaft during ironmaking. Sishen pellets have satisfactory physical and metallurgical properties which make them suitable feedstock for the direct reduction processes. These were tested under Midrex shaft operational conditions and performed well, with a metallization of 94.47% being attained.

Jan 1, 2012

By J. D. T. Steyl, C. A. Biley

"The chemistry of electrolyte systems containing iron remains generally poorly understood despite their prevalence in many natural and industrial processes, particularly in hydrometallurgy. These systems are typically challenging to study and model due to their affinity for complex formation and precipitation even at low pH. Recent developments in the hydrometallurgical processing of nickel laterites at Anglo American have called for a deeper understanding of the fundamental chemistry of the Fe2(SO4)3–FeSO4–H2SO4–H2O system. This paper details the development of an internally consistent, Pitzer ion-interaction model of this system, with explicit recognition of important contact ion pairs (CIPs). The primary application of this model is a thermodynamic framework for the interpretation of kinetic processes occurring during iron(III) reduction with SO2. Adopting a rigorous thermodynamic basis for the system chemistry facilitates the formulation of simple rate expressions that are capable of inherently capturing complex effects. While the iron(III) reduction case study remains the focus of this work, the developments have more universal applications and the thermodynamic speciation model can be extended into other systems containing acidic ferric sulfate.INTRODUCTIONIron is present in nearly all hydrometallurgical refining circuits typically as both a necessary and unwanted impurity and needs to be removed and disposed in a safe and efficient manner. This is generally performed by precipitation to form a range of solids such as hematite, goethite or jarosite. Numerous studies in the open literature have focussed on the removal of iron from refractory gold sulfide ore (Berezowsky & Weir, 1989; Berezowsky et al., 1991) and zinc pressure leaching (Buban, 1999; Ismael, 2003), and PGM matte sulfide circuits (Dutrizac & Monhemius, 1986). Moreover, since ferric iron is a strong oxidizing agent, it has been used extensively as a leaching agent for sulfide minerals (Dreisinger, 2006). Given the outlook of challenging economic conditions, declining ore grades and increasing levels of impurities, effective iron management is going to become increasingly critical to all hydrometallurgical processes.Against this background, and considering the widespread importance of acidic iron sulfate systems throughout natural and industrial processes, it is unexpected that the knowledge of the fundamental solution chemistry of these systems contains such significant gaps, particularly at the conditions typically found in hydrometallurgical applications. Existing literature describing the measurement and modelling of solution speciation in these systems have highlighted their significant chemical complexity (Magini & Caminiti, 1977; Magini, 1979; Lee & Tavlarides, 1985; Stipp, 1990; Papangelakis et al., 1994; Gil et al., 1995; Majzlan & Myneni, 2005; Kormanyos et al., 2008; Yue et al., 2014). Partially responsible for the lack of quantitative speciation measurements is the strong tendency of ferric to hydrolyse at even low pH (Flynn, 1984), complicating the laboratory study of such systems. Moreover, the large number of aqueous species that may co-exist simultaneously makes the study of individual species and the modelling of the numerous interactions between these species extremely difficult (Dry & Bryson, 1988; Stipp, 1990; Majzlan & Myeni, 2005; Kobylin et al., 2007)."

Jan 1, 2016

By N. S. Yet

This paper shall present the design and construction of bored pile and diaphragm wall for the proposed MHA complex in Singapore. The work was carried out by L&M Foundation Specialist Pte Ltd and PWD Consultants Pte Ltd was the consultant for this project. A brief description of the project is first presented to illustrate the scope and scale of the work involved, which includes the construction of bored piles and diaphragm walls and installation of steel stanchions in the bored piles. This is followed by a description of the methodology used to analyse and design the wall and bored piles. As both towers in this project are supported on bored piled foundation and are constructed by top down construction method, the analysis of the wall has taken into consideration the sequence of work phase by phase and this was carried out by means of a commercial finite element program called CRISP. Modelling of the problem will be briefly described and the findings from the numerical analysis will be presented. This is followed by a description of the structural and geotechnical design aspects of bored piles. The paper shall then describe the difficulties encountered for this project and solution used to solve the problem. The subsoil condition will be described with special mention on the encounter of very strong granitic rock at depth above the maximum excavation level of the basement at certain locations, hence necessitating the drilling of rock for a considerable depth for both bored piles and diaphragm wall. At this juncture, the construction method used to drill through the rock will be briefly described. For construction of bored piles, penetration of rock was carried out by chiselling or drilling using reverse circulation rigs. For construction of diaphragm wall, it requires the employment of Bauer hard rock cutter which uses cutting wheels fitted with roller bits and are capable of excavating into granitic rock of compressive strengths more than 100 MPa.

Jan 1, 2000

THE slide-rule, as a quick and convenient instrument for performing approximate calculations, is steadily growing more and more into favour with the engineer, and results obtained by it are considered close enough to enable him to satisfactorily dealwith a considerable portion of his work. To the surveyor, however, whose ordinary computations must be as precise as his measurements, the present makes of rule are insufficient, except for a very narrow margin of the scales and for rough work. Few will carry the rule when they can clearly see that it is unreliable for general routine, and the careful surveyor is inclined to look askance at those who do use it, recognizing the temptation there undtmbtedly must be to push it into work that the log book should be called upon to treat. From the fact that a surveyor's duties take him on the surface in all weathers, and underground in many wet and uncomfortable places, where the manipulation of a book of mathematical tables becomes both awkward and patience-trying, an efficient slide-rule must offer the mbst transparent advantages. Again, a surveyor being specially trained to read divided scales quickly and accurately, the slide-rule must commend itself as an apt addition to his outfit.

Jan 1, 1912

Analysis for pillar extraction potential (A-PEP) is an intelligent tool, which could be used as a preliminary output indicator when considering the secondary extraction of regional support pillars in the Witbank and Highveld coalfields of South Africa. The safe and economic extraction of underground coal pillars is of paramount significance and importance to the South African coalmining industry to ensure continuity of supply of this fossil fuel. Pillar extraction practices in South Africa have been responsible a significant proportion of safety and fatality statistics in relation to its relative output (less than 5 per cent of total South African coal production) and, as a result, research was undertaken in local pillar extraction operations and extended to similar operations in New South Wales, Australia to assess a way forward for pillar extraction in South Africa. It was found that, although little in the way of new technologies has emerged in this field in the recent past, significant contributions could be made in the field of risk analysis to obtain a generic design methodology for pillar extraction in South Africa. The resultant A-PEP tool to assess pillar extraction potential is based on certain physical, risk and economic factors, which combine to indicate operational success in terms of economic, health and safety attributes. At the time of A-PEP?s development there was alack of operating underground coal pillar extraction operations, which made it difficult to validate its applicability. Since then, however, A-PEP has been successfully tested and validated against two unique underground coal pillar operations, which is the discussion of this paper. One operation is situated in the Witbank coalfield and is extracting pillars, which are 20 years old and at a depth of 80 metres below surface, while the other operation is situated in the Highveld coalfield-which is extracting 6 month-old-pillars underneath a massive dolerite sill at a depth of 220 metres. A-PEP has shown that its predictive nature is consistent the workings at both operations, irrespective of their unique conditions, and as such it can be successfully used as a mine planning tool. The A-PEP mine planning tool thus represents a positive step toward an integrated approach to underground coal pillar extraction when considering legal and operational aspects, which could form the basis for legislative guidelines when considering the future of pillar extraction in South Africa.

Jan 1, 2005

By Zach Ahinga, Mike McRae, Dave Hopkins, Steve Klein

The San Vicente Pipeline project involves the construction of an 8-1/2 foot diameter water pipeline in an 11 mile long tunnel in San Diego, California. The tunnel will be excavated in extremely variable geologic conditions consisting of strong granitic and metamorphic rocks, weak sedimentary rocks, abrasive conglomerates, and mixed face conditions. This paper discusses the challenging geologic conditions and some of the key design evaluations for the project. Currently design work for the project has been completed and construction will be underway by mid-2005.

Jan 1, 2005

By David S. Yang

The Cement Deep Soil Mixing (CDSM) method introduces and mixes cementitious materials with in situ soils using hollow-stem rotating shafts equipped with a cutting tool at the tip and mixing paddles above the tip. CDSM generally produces a soil-cement panel consisting of three overlapping soil-cement columns. The soil-cement panel is then extended to form walls, which are effective for excavation support and groundwater control due to the continuity and low permeability of soil-cement walls. Two design approaches could be taken in the application of CDSM for excavation support: 1) single wall design and 2) gravity wall design. The former one is treated as a wall technology and the latter one is treated as a soil stabilization method. This paper will review the CDSM equipment and installation procedures for the construction of these two types of soil-cement walls. Four case examples are used to illustrate the design and application of these two types of soil-cement walls.

Jan 1, 2003

By V. Arslan

The primary advantage of using oxalic acid is in the formation during leaching of soluble complexes that are both photo-chemically and microbiologically degradable. In this study, chemical leaching and bioleaching methods were used for quartz sand. Using the ANOVA-Yates test technique, the effects of solids rate, temperature and oxalic acid rate were investigated using chemical leaching experiments. Solids rate and temperature were effective parameters on the chemical leaching. After the tests, the removal of Fe2O3 increased to 97.02%. Finally, the iron content decreased from 0.315% Fe2O3 to 0.0094% Fe2O3 in the leached quartz sand. The effect of pulp density was investigated on the bioleaching experiments. The bioleaching of iron oxides by Aspergillus niger resulted in removal of 47.70% of the total iron in the quartz sand, and suggested that this strain has not a good ability to remove iron impurities from quartz sand in comparison with chemical leaching. The iron content decreased from 0.315% Fe2O3 to 0.164% Fe2O3 in the bioleached quartz sand.

Jan 1, 2009

By Pengfu Tan

Xstrata Copper at Mount Isa in Australia has operated one copper Isasmelt furnace and four P-S converters. The phenomena of foaming occur in above 10% of converter operations. A thermodynamic model of copper P-S converter and a viscosity model of converter slag have been developed to simulate the slag blow and copper blow. The model predicts the chemistry and viscosity of copper skims during copper blow. The effects of oxygen potential, charge of dirty materials, slag carry-over, under-blowing, over-blowing, and temperature on the foaming and viscosity of copper skims have been discussed. Some improvements of the industrial operations have been presented.

Jan 1, 2006

Although auriferous beach and fore-dune sands at Five Mile Beach south of Okarito township had been intensively mined by hand and primative mechanical methods drilling of the sandspit by the Gold Development Corporation in 1929 indicated that the grade and quantity of undisturbed black and grey sand below the water table was sufficient to support a mining operation. Worked sand above the water table also contained fair prospects. The Okarito Five Mile Beach Gold Dredging Co Ltd, was formed and an hydraulically powered, bucket ladder, sluice box dredge built. In 13 years of operation (1931 - 1943) the dredge returned 556.39 kg (17 890 oz) of gold at a recovered grade of 225.4 mg/m3. A total of ú42 000 was distributed as dividends on the ú30 000 capital investment. Recent drill and bulk sampling at the northern end of the beach has confirmed that reworking of the historic tailings by a modern gravity recovery plant would not be economic.

Jan 1, 1993

By M. Hopf, E. Rossouw

Keywords: Pyrometallurgy, furnace, copper coolers, freeze lining, monitoring, Saveway The use of water-cooled copper components as sidewall elements of submerged arc furnaces and other pyrometallurgical applications has become increasingly common. The high cooling efficiency of copper has made it possible to increase the service life of furnace refractories when compared to conventional refractory linings. However even the self-healing effect of ?freezing? worn areas of the lining does not necessarily protect the copper coolers against wear or corrosion completely. In order to avoid furnace explosions, various methods have been used to monitor the wear of coolers. Unfortunately, these have not been able to consistently identify localized wear. Thos Begbie (South African) and SAVEWAY (German) jointly developed technology to embed a line sensor into the copper cooler during the casting process. This system allows an exhaustive monitoring of the copper cooler. A SAVELINE sensor is placed inside the copper-cooling panel between the water-cooling passage and the hot face of the panel. The sensor follows the meandering shape of the cooling water channels. In the first instance, the sensor provides analogue information as the thickness of the copper reduces. Secondly, this wear signal will be confirmed by a signal of interruption if the sensor is washed away. Because of the structure of the sensor, a self-diagnosis is possible and indications can be confirmed (double proofed). Subsequent to the manufacture of some test pieces, coolers for a large submerged arc furnace were manufactured. The sensorized coolers have been installed at the intermittent surface (slag line) where the largest amount of corrosion has been encountered. The system has been operating since December 2005 in what is considered one of the largest submerged arc furnaces in South Africa.

Jan 1, 2006

By M. J. Fairweather, J. R. Egan, W. A. Meekel

Cominco Metals, in cooperation with two Canadian Universities and the Government of Canada, is developing applications for column flotation in the treatment of lead and zinc ores. Plant scale results at Polaris and pilot plant studies of Sullivan, Pine Point and Red Dog ores show column flotation to have significant advantages over conventional mechanical flotation for lead and zinc cleaning. Results from these ongoing studies are discussed in relation to ore texture, mineral recovery, impurity behaviour, scale-up and control.

Jan 1, 1988

By A. Noble, R. Q. Honaker, J. Werner

Recovery of rare earth elements (REE) from coal-related resources has recently received significant interest due to supply concerns and their key roles in critical industries and defense-related technologies. An integrated flowsheet consisting of sorting, crushing/grinding, physical separation, acid leaching, solvent extraction, and selective precipitation was designed to achieve continuous production of rare earth products from various coal-related resources such as coarse refuse and acid mine drainage. A pilot plant was constructed that enabled continuous testing of the circuitry on a range of different coal-based feedstocks. Despite achieving significant success in producing high-grade rare earth oxide products, low REE recovery values and high operational costs necessitated a re-evaluation of the process flowsheet. This article describes the circuitry improvements that were based on both laboratory and pilot plant test results. Roasting as a pre-leach treatment was found to significantly improve the leaching rate and overall REE recovery values. After roasting West Kentucky No. 13 and Fire Clay coal refuse materials at 600 °C, REE recovery increased by 60 and 40 absolute percentage points, respectively. Rare earth concentration in the pregnant leachate solution (PLS) was increased to around 700 ppm prior to solvent extraction using a staged precipitation method. REEs in the precipitate were re-dissolved, purified, and extracted from the PLS using solvent extraction and selective precipitation to values of around 80%. As a result of the improvements, chemical consumption in the acid leaching and solvent extraction processes was significantly reduced. A techno-economical assessment of the improved flowsheet indicated significant commercialization potential.