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By Florian Kongoli

"Lime ferrite" slag with limited silica content has proven to be a valuable choice in the modem processes of copper smelting and converting due to several advantages that this slag offers compared to classical silicate slags. Nevertheless the liquidus surface of this slag has been experimentally measured only at low oxygen potentials such as in equilibrium with iron or hear it and in air. Although most of the smelting and converting processes that use this slag occur at intermediate oxygen potentials, the liquidus surface of this slag is not known at these conditions and the effect of oxygen potential and silica has not been correctly understood. This has brought some confusion in literature as well as in the industrial practice. In this work the liquidus surface of the calcium ferrite slags has been quantified by the means of a new thermophysicochemical model and a new type of liquidus surface diagrams which are very convenient for any industrial process that uses calcium ferrite slags. These diagrams can be easily used to select the lowest liquidus temperature of calcium ferrite slags at a minimum cost and can help design several fluxing strategies in copper smelting and converting processes. The effect of the oxygen potential and silica is also quantified and important industrially related conclusions are drawn.

Jan 1, 2003

By J. W. Merks

Spreadsheet software is used to convert test results for drill core samples into borehole statistics such as volumes and masses of in-situ ore, metal contents and variances of metal contents. The properties of variances and the sampling variogram play a pivotal role, The additive of property of variances gives a sound scientific basis to the calculation of confidence limits for metal contents and grades as a measure of the risks associated with estimating reserves and resources.

Jan 1, 2000

By P. Hr?enjak

Two groups of methods are usually used in design procedures of underground excavation of dimension stone: the analytical and numerical methods of analysis. In all of these methods the in situ rock mass strength represents the main problem. This is due to massive rocks in dimension stone deposits, consisting of large blocks of rock separated with particular discontinuities, for which the Hoek-Brown empirical criterion, developed for jointed rock masses, cannot be realistically used to estimate rock mass strength, especially for a particular block of rock mass or a particular pillar. On the basis of the regular underground excavation process of dimension stone by separating blocks with the flat jack application, we developed the in situ flexural strength testing method. We carried out numerical analyses and evaluation of uncertainty of measurement in order to validate the in situ flexural strength testing method. On the basis of very good validation results, as well as results of the in situ flexural strength testing of exploitable layers on the ?Kanfanar? quarry, we introduced a new coefficient of reduction, which can be used for correction of other strength parameters determined by laboratory testing for obtaining a realistic value of rock mass strength.

Aug 1, 2013

By José Arce

El presente texto señala la importancia de los métodos geofísicos en la exploración de yacimientos minerales del Perú. De acuerdo a las diferentes situaciones geológicas se elige el método más adecuado. Para el caso de vetas de gran buzamiento con sulfuros metálicos se utiliza el método electromagnético autopotencial, cuyo accesorio es la resistividad; para el caso de Mantos de bajo ángulo o bolsonadas con sulfuros metálicos, se cuenta con el método electromagnético y para la estructura de sulfuros diseminados Placeres Hierro, pirrotita, cobalto, níquel, se emplea la polarización inducida y el electromagnético, cuyo accesorio es la resistividad y gravimétrica.

Jan 1, 1972

By R. Padilla, M. C. Ruiz, R. Villa

"Bismuth is an impurity in copper minerals where it occurs mainly as the mineral bismuthinite (Bi2S3). In smelting of copper minerals, most of the bismuth reports to the white metal, as a result, a substantial amount of bismuth accompanies the copper to the electrorefined cathodes. Thus understanding the behavior of Bi2S3 at high temperatures is crucial to eliminate bismuth before electrorefining. In this paper, some experimental data on the decomposition/volatilization of bismuthinite in nitrogen- oxygen atmospheres is discussed. The results indicated that in nitrogen atmosphere, bismuth volatilization occurs through a fast decomposition of bismuthinite to metallic bismuth and sulfur with subsequent volatilization of bismuth in the range 850-1100 °C. Similarly, in the presence of oxygen, bismuthinite decomposes to bismuth too, followed by oxidation to the non-volatile bismuth trioxide at temperatures higher than 750 °C. Both, temperature and partial pressure of oxygen affect significantly the bismuth volatilization and the oxidation rates.IntroductionCopper sulfide minerals are the major source for the production of metallic copper by pyrometallurgical processes, which are the dominant processes in the production of copper by selectively oxidizing the sulfide sulfur to SO2 and the accompanying iron in the concentrates to iron oxide, which can be conveniently removed as a stable slag.Generally, copper concentrates contain some deleterious minor elements such as arsenic, antimony, bismuth and lead, which are present as sulfides. These elements depending on their concentration may originate problems in the copper smelting processes and they can ultimately lead to a final copper product with unacceptable high levels of impurities.During the treatment of these copper concentrates by smelting, the impurities generally distribute themselves in the condensed and gas phases and they are eliminated mainly through the gas phase [1-3]. Thus, smelter off gases contains substantial amounts of volatilized impurity elements. For example, in the case of bismuth, the estimated distribution of bismuth in flash furnace smelting [2] was 15 % in the matte, 5 % in the slag and 80 % in the gas phase, and recently, for Outokumpu flash smelting Davenport [3] reported the distribution of bismuth as 30-75% in matte, 5-30% in slag and 15 -65 % in the off gas."

Jan 1, 2011

By Richard H. Oitto

The Bureau of Mines and Kaiser Steel Corp. are cooperatively demonstrating the shield-type roof support in the longwall mining of a 10-1/2-foot-thick coalbed at the York Canyon mine near Raton, N. Mex. As part of the demonstration, the shield supports have been successfully and safely moved from a completed longwall face to a new longwall face. When these shield supports were moved in 1976 they were the largest and heaviest longwall support system in use in U.S. coal mines. The shield supports, preparations for moving them, the actual move, and installation at the new face are discussed.

Jan 1, 1977

By Muto S, Okada S

At Tamano Smelter, part of the furnace settler is electrically heated by electrodes placed internally. This practice provides good control of the settler conditions. The authors have been investigating improvements in furnace operations, especially to decrease the copper content in the slag discarded from the settler. The important operational points on the control of magnetite in liquid matte and slag are discussed on the basis of the thermodynamic calculation method developed by Prof. S. Goto. The behaviour of magnetite in the practical furnace has been studied by using a torsion magnetometer and a solid electrolyte oxygen-sensing cell.

Jan 1, 1980

By Brett D

Tailings disposal and water management are one of the most important environmental issues in mining projects. The nature and the method of disposal of the tailings will determine the long term environmental impacts and must be carefully considered at the planning stage so that final abandonment can be economically achieved. If not, long term and on-going treatment and amelioration may be required to achieve environmental standards. Final abandonment requires dam safety surveillance inspection to satisfy engineering stability and hazard requirements as well as environmental issues. Environmental issues include stability, as well as rehabilitation and long term contamination potential.

Jan 1, 1991

By W. A. Hoyer

A pulsed high-energy neturon-induced spectral logging tool has been built and field-tested. The reaction of deuterium on tritium is used to generate pulses of 14-Mev neutrons. By detecting only the prompt gamma rays produced by neutron inelastic reactions in the formation, the presence and relative abundance of carbon, oxygen, calcium, silicon and other important elements may be ascertained from a gamma-ray spectrum. Gamma-ray spectra obtained in a shallow test well and in experimental field use show that it is possible to identify formations and their contained fluids. INTRODUCTION The penetrating gamma rays from naturally occurring radioactive elements in subsurface formations have been used for a number of years in well logging as a means of characterizing and distinguishing strata. Still another nuclear logging method which has been employed for some years consists of the bombardment of strata with neutrons and the measurement of the number of gamma rays produced by neutron capture reactions involving elements in subsurface strata.' Since one of the principal elements entering into capture reactions is hydrogen, the latter procedure essentially results in a hydrogen log, whether the hydrogen be in combined form in either oil or water; thus, the log gives an indirect measure of porosity. These methods, with various refinements, have been developed to such an extent that they have become routine procedures in formation evaluation. Neither gamma-ray logging nor conventional neutron logging, however, yields sufficient information to permit unequivocal identification of the mineralogic composition of formations, and neither method gives information which may be used for the positive identification of hydrocarbons in strata. Accordingly, a number of efforts have been made in recent years to gain additional information from nuclear logs. Brannon and Osoba have shown that it is possible to identify naturally occurring radioactive elements in subsurface formations by spectral analysis of gamma rays emanating from these elements. Such an identification is of value in the characterization of strata. A simplified form of spectral analysis of gamma radiation resulting from neutron capture reactions between elements in earth materials and bombarding neutrons has been used with some suc- cess under favorable conditions to differentiate between petroleum and water. This method relies upon the relatively high energy of gamma radiation from neutron capture by chlorine and, in effect, furnishes a chlorine log. In areas in which interstitial water is of sufficiently high salinity, this log can give valuable information on water saturation and, thus, indirectly on hydrocarbon saturation. Still another approach to obtaining more information by nuclear techniques is "activation logging", in which certain elements yield short-lived radioactive isotopes on neutron activation and, thus, can be detected by gamma-ray spectral analysis. From the standpoint of determining by nuclear logging methods the mineralogic composition of strata and the presence or absence of hydrocarbons, it is essential that information be obtained on the presence and relative amounts of several elements such as carbon, oxygen, hydrogen, calcium, silica and others. Some elements, such as hydrogen, chlorine and sulfur, can be determined by spectral analysis of gamma radiation resulting from neutron capture reactions."" Others — carbon and oxygen, for example — do not enter readily into capture reactions but do yield gamma rays of characteristic energies from inelastic scattering reactions with high-energy neutrons. Accordingly, the latter reactions are of particular interest as a means of identifying hydrocarbons in subsurface strata. Several years ago it was recognized that information requisite to the identification of subsurface strata and of contained fluids could be obtained by pulsed operation of a subsurface neutron generator and associated gamma-ray detector. It was contemplated that pulsed operation would be effective in discriminating in time that gamma radiation which results predominantly from inelastic scattering reactions from that gamma radiation arising from neutron capture reactions. Accordingly, research was continued and construction of such a device was initiated. Although many problems were encountered, they were solved successfully. The following sections describe the tool which has evolved, its performance and the results which have been obtained with it to date. THEORY OF OPERATION OF NEUTRON-INDUCED GAMMA-RAY SPECTRAL LOGGING TOOL THEORY OF INDUCED NUCLEAR REACTIONS Of fundamental importance is the fact that an element, when bombarded with neutrons, emits gamma radiation of energy characteristic of that element. In theory, therefore, an element may be identified by

By Gary H. Higgins

The paper by Lewis and Braun l presents experimental and calculational evidence that primary chalcopyrite ores are rapidly oxidized by warm oxygen-bearing water. Resulting solutions contained copper sulfate products of the matrix rock decomposition such as magnesium sulfate and sulphuric acid. Iron was oxidized to insoluble hematite and hydrous iron sulfates. Oxygen injection near the base of a broken and permeable flooded ore deposit was calculated to cause circulation of oxidizing solutions to the entire permeable region. The rate of dissolution of copper and degree of oxygen saturation for given oxygen injection rates were presented. Their work suggests that in-situ recovery of deep, disseminate primary copper deposits is technically feasible. The actual feasibility depends on economics and environmental safety as well, and it is the purpose of this paper to address these two aspects.

Jan 1, 1972

By G. Bonifazi

In the present work the possibility to utilize the morphometrical and morphological characteristics of an articulate solids system in a slurry flow to monitorate and to control a continuous process is considered. This goal has been reached by mean of an optical system able to acquire, to handle and to process the pictorial information derived by a suitable hardware architecture designed to realize the best lighting, focusing and sampling conditions for the examined flow stream domain. The procedure has been tested using different flow stream slurries coming from different sections of a beneficiation plant. A suitable strategy and a consequent software architecture has been set up in order to assure to the system the necessary speed and the stability to achieve correct on-line measurements and control.

Jan 1, 1994

By S. W. Churchill

A digital computer was used to obtain an exact numerical solution for the transient behavior of the insulation and earth adjacent to an isothermal, submerged flat surface for a single set of parametric values. Comparison of the computed results with analytical solutions for limiting conditions revealed that a complete and general solution for all parametric values could be constructed from these limiting solutions. Complete and general solutions for insulated spheres and cylinders can also be constructed from limiting solutions. The procedure is illustrated in part for an insulated spherical tank. The heat flow was found to fall rapidly to a pseudo-steady state; after some time, it then decreased slowly to zero for a flat plate and cylinder, and to a low steady-state rate for a sphere. The accumulative heat flow during the initial falling-rate period may be a significant fraction of the heat flow during the entire first year. INTRODUCTION Underground storage of liquefied natural gas and liquefied petroleum gas has received considerable recent attention. The rate of heat flow from the earth to the storage cavity and the resulting temperature field in the earth are important factors in the technical and economic evaluation of such storage facilities. The objective of this paper is to indicate how complete solutions can be developed for the transient flux and temperature field for various geometrical configurations. The representative properties and dimensions, and the resulting parameters utilized in the illustrative results, are indicated in Table 1. The results presented herein are for dry earth. The effect of the latent heat of solidification of water in the soiI will be described in a subsequent paper. The temperature field in the insulation and earth is determined by energy balances, boundary conditions and initial conditions. The physical problem can be described mathematically with virtually no idealizations insofar as physical properties are known. It appears possible to solve the equations by numerical integration on a high-speed digital computer for any geometrical configuration and conditions. For complex situations, however, the computations are expensive and the results are highly specific. Analytical solutions have been developed for a few simple but important geometrical configurations and conditions, including one-dimensional heat transfer from (or to) earth at an initially uniform temperature to (or from) flat plates, spheres and circular cylinders. The solution for an insulated flat plate has also been derived but is in the form of a slowly converging series involving taklated functions. It was planned to use a computing machine to evaluate this series for a number of representative conditions. However, upon examination of the results of preliminary computations it was discovered that a complete, general and accurate solution could be developed by interpolation between several much simpler solutions for limiting conditions. This technique then was used to develop a a complete solution for an insulated sphere. The equations presented herein are derived in Carslaw and Jaegerl and other books on applied mathematics, or they are simple extensions of these previous results. Hence, all derivations are omitted. Emphasis is instead placed on the results and their

By Steven I. Baskin

Cyanides are utilized in many industrial applications including preparation of chemical intermediates, electroplating, and' mining, Cyanide has been utilized in chemical warfare operations as well Cyanide is also synthesized and found in plants and animals including man where it is thought to perform multiple functions. A variety of enzymes are known to detoxify cyanide under different conditions. These include rhodanese, 3-mercaptopyruvate-sulfur transferase, thiosulfate reductase, cystathionaseand albumin. Cyanide appears tQ exert its toxic effect primarily by inhibiting cytochrome oxidase? although other enzymes are also inhibited. Therapeutic antagonist categories to treat cyanide include methemoglobin formers such as nitrite, sulfane-sulfur donors such as thiosulfate, metal salts or complexes such as cobalt and cyanohydrin-forming compounds such as dihydroxyacetone or alpha keto-glutaric acid. Advantages and disadvantages of each category will be discussed. Newer compounds under development have been found that may allow for prophylactic therapy for cyanide poisoning with minimal side effects; In addition, portable co-oximetry devices may provide real-time measurement of cyanide in field units.

Jan 1, 1998

By Murray Jacobson

The Federal Coal Mine Health and Safety Act of 1969 established mandatory dust sampling of coal mines according to procedures prescribed in the Mandatory Health Standards, title 30, Code of Federal Regulations, part 70, published in the Federal Register on April 3, 1970. A laboratory was established in the Pittsburgh Field Health Group of the Bureau of Mines to process the coal mine dust samples collected by the mine operators. This paper describes the laboratory and presents the equipment and procedures used in processing these samples.

Jan 1, 1971

By Lan Li, Izaak Williamson

"The efficient separation and storage of CO2 from power plant flue gases can reduce the amount of CO2 released into the atmosphere and mitigate global warming. Potential candidates for industrial applications are solid sorbent materials. Crucial factors to control the efficiency of porous sorbent materials include the framework and pore structure, and the chemical and physical reactivity of CO2 within the pores. Computational modeling approaches, based on density functional theory (DFT) and van der Waals-DFT, have been applied to nanoporous solid – manganese dioxide a-MnO2. We found that the types and charges of cations as dopants in the a-MnO2 and the concentration of CO2 influence the structural features of a-MnO2, which control its CO2 selectivity performance within the flue gases.IntroductionCarbon capture and storage is a technique to separate large quantities of CO2 from power plant flue gases before being released into the atmosphere. Porous solids are a potential candidate as sorbents to “trap” CO2 through chemical or physical adsorption on their porous surfaces[1]. Such separation efficiency is determined by the size and shape of its pores and by the interaction between the porous surface and the gas adsorbates. The incorporation of cations into the pore can act as a means of structural support and alter the pore diameter to be comparable to the kinetic diameter of the gas adsorbate, such as CO2.A porous solid of particular interest for CCS is manganese dioxide a-MnO2, an octahedral molecular sieve (OMS) composed of edge-sharing MnO6 octahedra that are linked into a nanoporous framework[2]. The framework consists of (1×1) and (2×2) tunnels, referred to as OMS-2. Due to the larger tunnel size, cations and gas adsorbates prefer to reside along the (2×2) tunnel axis of the OMS-2. As seen in Figure 1, a potassium cation K+ is located in the (2×2) tunnel, known as cryptomelane-type MnO2. Its pore diameter of ~ 4.6 Å gives it a good CO2 selectivity performance, because the diameter is comparable to the kinetic diameter of 3.3 Å for CO2[3]. Alternatively, replacing potassium K+ with other cations, e.g. barium Ba2+, sodium Na+ or lithium Li+, in the OMS-2 tunnel is of great research interest, due to the effects of their concentrations, types and charges on the CO2 selectivity efficiency and sorption hysteresis phenomenon[2,4]."

Jan 1, 2014

By Robert C. Salak

The era of low-seam mining with continuous haulage has been here for quite some time. Typical tonnages in companies such as Terry Glenn Coal are currently averaging 405 tonnes per shift in .8m coal. JoAnn Coal has averaged 453.6 tonnes per shift in .775m to .825m coal for the past four years. John Chaney of Chaney Coal has averaged 297 tonnes per shift in .6m to .65m coal. There are many other mines that are experiencing similar success and with maintenance costs that are averaging $.10 to $.40 per tonne. These figures have been documented and can be verified by the operators.

Jan 1, 1981

Based upon specialised experience of rope mechanics spanning over 20 years, this paper reviews the processes of degradation and fatigue that are relevant to hoisting ropes in mines. The review is brought up to date with an account of the most recent work in this field, which identifies a torsional fatigue process and quantifies the impact of degradation upon the residual service life. A proper understanding of these processes is important in determining how different parameters of hoist design and operation interact to determine rope life. This knowledge is also important in informing decisions relating to rope discard based upon observed condition, as well is identifying the critical features that must be quantified reliably during inspection.

Jan 1, 2005

By S. C. Sun

Very little information is available concerning the magnetic properties of minerals and only recently has there been any attempt to correlate magnetic susceptibility with varying chemical composition1. The work described here covers a study of the relationship and chemical composition of both the rutile and sphene types of titanium minerals. The relationship between the magnetic susceptibility of three selected mineral specimens and the applied field strength is also presented. Experimental: The equipment and procedures used in this in- vestigation for crushing and cleaning the mineral specimens and for determining the magnetic susceptibilities were the same as that employed by Spokes and Mitchell1. The particle size of-the measured specimens was limited to 270/325 mesh.

Jan 1, 1959

By Jasper D. Ward

The Indiana Limestone Company has developed an insulated, thin and comparatively light-weight pane 1 suitable for use as a spandrel panel in a curtain wall. The panel is about four inches thick and is composed of limestone backed with insulation. The inner surface of the insulation is protected with asbestos-cement board or a metal pan, depending on the type of insulation, building-code requirements and appearance (if the surface is left exposed). The limestone is cut to the size of the spandrel openings and the insulation and backup is applied in the mill ready to be shipped and in- stalled in the wall grid, A mortarless and waterproof joint with the metal frame components is achieved through the use of neoprene, thiokol, and caulking, The limestone is "dirt-proofed" (waterproofed) in the mill to slow down discoloration. The panel weighs more than some presently used materials. However, ILCO's architects and engineers have found that curtain wall systems capable of withstanding imposed wind loads are made up of sections large enough to carry this extra load of stone with little or no modification to the size of the metal frame. Limestone, a traditionally sound material, can be used in this new way without losing any of its natural qualities of dimensional stability, resistance to fire, and permanence.

Jan 1, 1959

Caterpillar recently held two, two-day demonstration programs for its mining customers. The event, billed as MineDemo by Caterpillar, consisted of two sessions held on consecutive weeks at the company's Tinaja Hills proving ground south of Tucson, AZ. The program included several classroom sessions that focused on Caterpillar equipment applications, including the VIMS (vital information management system) and the CAES (computer-aided earthmoving system). Also included were field demonstrations and the opportunity to test drive mining-related heavy equipment, including dozers, trucks, graders, shovels and loaders. Featured at the event were the recently upgraded 785, 789 and 793 C-Series trucks. Caterpillar recently announced the availability of the 136-t (150-st) 785C and the 177-t (195-st) 789C. The upgraded haulers have replaced the respective B-Series models. The 218-t (240-st) 793C was introduced in 1996. It, too, has been upgraded but retains the C-Series designation. While attending the press event, the author had the opportunity to test drive the 793C at the Tinaja Hills test site. It was amazing how well the machine handled. The operation was smooth and the braking system was precise. The cab was extremely comfortable. To see a C-Series truck in action, the author also visited Newmont Mining's Mesquite Mine, located in Cali¬fornia, across the border from Yuma, AZ. The Mesquite Mine operates a new model 785C truck. At the mine, temperatures have been measured as high as 58° C (138° F) in the pit. Needless to say, the ability to operate dependably in extreme heat is an important consideration for the mine operators. An interview with the driver and later with management confirmed that the 785C has worked out well. The driver praised the comfort of the cab and the ease of operation. Management reported significant fuel savings and was impressed by the truck's maintenance features.

Jan 1, 1999