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By Petr Sulovsky, Jaroslava Ledererova, Miroslav Svoboda, Michaela Suchardova

"The thinning resources of natural raw materials necessitate an increased degree of waste material recycling. The building industry offers a range of technologies enabling incorporation of industrial wastes into building materials for construction purposes in an economically acceptable way. Our research is focused on finding the appropriate technologies for specific groups of industrial waste materials (IWM). The studied IWM involve coal combustion residues (CCR), desulphurization products, sludges, metallurgical slags, and various other wastes. Many of them contain increased amounts of toxic elements that can under certain conditions get released. In order to prevent this, each specific IWM requires finding the technology that best ensures the binding of toxic elements in the building matter are fixed for the long term.Introduction The sustainable development of mankind is more than ever viewed as a matter of resources. Many aspects of the switch from a throw-away to a recycling society concern one of the largest consumers of natural resources and producer of greenhouse gases, the building industry. One of the biggest tasks lying before the researchers in the field of building materials is to find substitute or alternative raw materials that would save the thinning reserves of natural resources. The most promising and natural way is to replace the traditional raw materials with rejected and unwanted products of industrial processes, classified as wastes. These of course are not produced with the primary intention of achieving some desired properties. The usage of industrial wastes therefore involves finding the optimal way of usage their existing positive (from the point of view of utilizations) properties and minimizing the impact of their undesired properties, i.e. from the perspective of the considered application."

Jan 1, 2008

By Vern L. Kegler

This paper is one off a series dealing with mining methods and costs, sponsored and published by the United States bureau of Mines. ACKNOWLEDGMENTS The author acknowledges the, constructive and helpful suggestions and criticism of W. F. Lamoreaux, vice-president, and general manager of the Ducktown Chemical & Iron Co. United States Geological Survey Professional Paper- 139, by W. H. Emmons and F. B. Laney, has been drawn upon for some of the information contained in the paragraphs or history and geology.

Jan 1, 1931

By T. P. Meloy

In the last decade increased and prolonged interest has been displayed in the use: of tunneling or rapid excavation to solve many of the urban and industrial problems confronting our society. There has been talk and action on the interurban rapid transit systems for major cities, and even preliminary designs for a Boston to Washington interurban transit system. Much of this interest stems from the search to the solution of our increasingly complex urban problems, where the surface area must be given over more and more to the inhabitants, and the subsurface for transit, utility and other services. While tunneling is not a panacea to urban ills it holds a real solution to many existing problems. There is also, among the tunneling experts, a growing confidence that technical problems of rapid tunneling can be solved. To solve these problems, R & D money must be invested. If it is to be money invested either by private industry or governments, there must be significant returns on the investment to justify the research and development need to bring about the breakthrough that will make tunneling a major contribution to the solution of urban problems. To make these economic studies more extensive and more accurate tunneling demand figures were needed. To this end, the Organization of Economic Cooperation & Development - OCED - included in its Conference on Tunneling a section on tunneling demand. As a result of the conference the organization for Economic Cooperation and Development issued a report entitled "The Advisory Conference on Tunneling - Report on Tunneling Demand 1960-1980. " This report was presented at the OCED Conference on Rapid Excavation, held at Washington, D.C. To obtain the data in the Report, questionnaires were sent to the OCED countries and 18 replies were received from Australia, Austria, Belgium, Canada, Denmark, France, Germany, Ireland, Italy, Japan, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland, United Kingdom, and the United States. While it is true, that data were missing, that sometimes the definitions were confused, and that several countries provided no cost estimates at all, in general, this report contains the most comprehensive gathering of data that ever existed in the field. All data in the OECD report is expressed in terms of meters or cubic meters, and costs are in U.S. dollars.

Jan 1, 1970

By C. D. Atkinson

The past few years have seen a much greater concern about air pollution in this country. This concern has led to increased legislation restricting the discharge of many substances such as sulfur dioxide and particulate matter to the atmosphere. In the future, it is anticipated the present permissible emission levels will be lowered. Current and impending restrictions on the emission of sulfur dioxide have brought out the fact that there is a shortage of available low-sulfur fuel for power plants and industrial use which promises to have an economic impact on the nation's energy picture (1) The Pittsburg & Midway Coal Mining Co., under the sponsorship of the Office of Coal Research, has developed a process to produce a fuel capable of meeting the energy requirements of this nation (2) The process is called "The Pittsburg & Midway Solvent Refined Coal Process". The principle product from the process is Solvent Refined Coal which is an ashless, low-sulfur fuel with 16,000 BTU per pound regardless of the rank coal from which it is produced. The product can be burned as either a solid or a liquid fuel. The process appears to be economically more attractive than other methods of alleviating the pollution problems of this nation. In addition to reducing the air pollution caused by stack gases, the product produced is potentially useful as a source of electrode coke and electrode binder pitch, as a gas turbine fuel, in the production of metallurigical coke and pavement asphalt, and as the first step in the overall process to produce distillate fuels and pipeline gas (3).

Jan 1, 1973

By W. H. MacLean

The Matagami district lies directly west of Chibougamau on the north side of the Abi tibi greens tone belt. Ores at Matagami are volcanogenic massive sulphides and occur in the dominantly rhyolitic Watson Lake group surrounding the Bell River Igneous Complex. Rhyolites and basalts of this group, and basalts of the overlying Wabassee group in the central part of the district, are tholeiitic; calc-alkaline Wabassee rocks occur in the western part. Massive sulphides occur associated with rhyolite domes that can be delineated by paleotopographic and isopach mapping. They are mainly distal deposits that formed over an extended period of time while several volcanic units were being deposited,

Jan 1, 1984

By Martin H. Stanezyk

The Bureau of Mines investigated leaching of selected copper sulfide minerals and a composite of impure flotation concentrates at elevated temperatures and pressures with ammoniacal solutions. Copper 1 (tractions of 96 percent were obtained by leaching chalcopyrite at 75° C under oxidizing conditions for 60 minutes. An extraction of 99 percent of the copper contained in the composite concentrate was obtained by leaching the product for 90 minutes at 75° C. In tests of bornite, chalcocite, and covellite, 90 to 97 percent of the copper was extracted at 20° C provided an 8-hour reaction period was used. At 75° C essentially complete dissolution of the copper from these three minerals was accomplished in 60 minutes. Additions of ammonium sulfate to the leach solutions were required to obtain high-percentage extractions of the copper from bornite, chalcocite, and covellite. Although ammonium sulfate was not required when digesting chalcopyrite, copper extraction was enhanced and less free ammonia was required when ammonium sulfate was added to the leach pulps. The chemistry of leaching copper minerals was studied. It was C, termined that chalcocite altered to covellite as one step in the dissolution When leaching iron-bearing copper sulfides, hydrated iron oxide formed on the mineral surfaces, indicating that a diffusion process prevailed. No evidence of covellite was detected.

Jan 1, 1966

By A. A. Rogozhin, E. G. Likhnikevich, S. I. Anufrieva, A. V. Kurkov

The Beloziminskoe deposit in Siberia is a large, potentially productive deposit of rare metals contained in ochreous apatite pyrochlore ores formed by weathering of a carbonatite. The ores are composed of pyrochlore, columbitized pyrochlore, monazite, apatite, magnetite, ferric and manganese hydroxide, titanic iron ore, zircon, hydromica, quartz, feldspar, and carbonates. A gravity-flotation enrichment flowsheet with application of cationic and anionic collectors has been developed. This flowsheet allows for obtaining a pyrochlore concentrate containing 44.3% Nb2O5 and 1.89% P2O5 with recovery of 55.83% Nb2O5 as well as an apatite concentrate containing 39.2% P2O5 and 1.05% TR2O3 with recovery of 62% P2O5 and 43.23% TR2O3 from ores containing 0.92% Nb2O5, 16.9% P2O5 and 0.6% TR2O3. Rare-earth concentrate containing 40% TR2O3 with recovery of approximately 10% TR2O3 was obtained at the same time. Major losses of valuable elements are related to slimes, which make up more than 50% of the ground ore. The niobium concentrate does not meet the phosphorus and radionuclide concentrations needed for the production of ferro-niobium. Acid leaching and sulfatization provided a high level of phosphorous and radionuclide removal. Conditions include hydrochloric acid pre-leaching at 75- 80°C with an 18% HCl solution for four hours and low-temperature sulfatization of acid-leached concentrate at 160-180°C for one hour followed by water leaching of the residue. The apatite concentrate could potentially be processed using nitric acid leaching. This technology is based on decomposition of apatite concentrate with 55-57% strength nitric acid with transfer of rare-earth metals into solution in the form of ammonium phosphate. This technology recovers a rare-earth concentrate containing 95% TR2O3 with extraction of 86%, and highly concentrated polynutrient fertilizer (ammophos) with phosphorus extraction of 95%. The completed research shows how complex multicomponent ores of residual soil may be processed for the extraction of niobium, phosphorus, and rare-earth products.

Jan 1, 2016

By William Bergeson

This paper presents the challenges of the Homestead Avenue Interceptor Extension (HAIE) project in downtown Hartford, Connecticut. The new 72-inch (1,830 mm) sewer pipeline project consists of installing approximately 3,010 linear feet (920 m) of PVC lined reinforced concrete pipe using pressurized face microtunneling. The entire alignment is located within soft to very soft, varved silt and clay. To the extent possible, the alignment was selected to avoid bedrock, glacial till, miscellaneous fill,buried steel piles, and utilities. Challenges for this project include low ground cover, crossing major transportation routes, and limiting settlement to prevent damage to historical buildings and critical utilities. The machine was selected for the ground conditions. Design calculations were performed for selecting the reinforced concrete pipe class and for evaluating settlement. The potential for settlement damage was evaluated using both conventional analysis and finite element analysis

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

6. Development of Mine Sealant Material Systems 6. 1 Introduction The preliminary evaluation of material systems described in Section 3 led to the selection of the following four promising systems for further development: System A: Aggregate, Fly Ash System System B: Aggregate, Fly Ash, Urethane Foam System System C: Aggregate, Bulkhead, Light Expansive Concrete System D: Aggregate, Self-Supporting Thick Slurry Preliminary laboratory tests indicated that the building of effective bulkheads from one borehole would be extremely difficult. Two extra boreholes would be required adding to the overall cost of the system and making the system less attractive. Tests with light expansive concrete showed that bulkheads would be required, the material would not support itself. As a result, further development of this system was terminated. Foam concrete was selected as the most suitable material to be developed into a self-supporting, rapid-setting slurry. A laboratory investigation of its use for mine sealing was conducted during this program; the results are summarized in Section 6. 5 and details of the laboratory program are presented in Appendix B.

Jan 1, 1973

By R. J. Sweigard

The effects of postmining land use planning are addressed in this paper. These effects may include savings in reclamation costs and increased value of reclaimed land. However, this may result in greater planning costs and possible delays in production. Therefore, an economic analysis was undertaken in an effort to determine the importance of each potential result and to quantify the overall economic impact of postmining land use planning. A discounted cash flow analysis was performed using a surface mine cost model to analyze the sensitivity of selling price to changes in various postmining land use planning parameters. As a result of this analysis it was determined that the profitability of a project is most sensitive to delays in production, particularly, if the delay occurs after major investments have been made. Many methods have been proposed for evaluating postmining land use alternatives (Sweigard and Ramani, 1981). Both quantitative methods, such as benefit-cost analysis (Brock and Brooks, 1968), and nonquantitative methods have been proposed. The application of one specific analytical method is pursued in this paper.

Jan 1, 1985

By William E. Ford, Edward Salisbury Dana

I. Anhydrous Chlorides, Bromides, Iodides; Fluorides. II. OxycMorides ; Oxyfluorides. III. Hydrous Chlorides; Hydrous Fluorides. The Fourth Class includes the haloids, that is, the compounds with the halogen elements, chlorine, bromine, iodine, and also the less closely related fluorine.

Jan 1, 1922

By David T. Day

In 1897 I published a proposed explanation for the variation in color and specific gravity of Pennsylvania oils. A resume of this subject mas also presented at the First International Petroleum Congress, in Paris, in 1900. Since that time

Jan 1, 1911

By Thomas M. Lynberg

WIDCO is a surface coal mine located near Centralia, Washington. The WIDCO preparation plant processes over 7 million tons of run- of-mine coal each year with a product yield averaging 72%. In the jig type preparation plant the fine refuse amounts to approximately 130 dry tons per hour of 28mesh by 0. This fine refuse material is thickened in a 160ft. diameter static thickener with the use of lime as a coagulant and organic polymer as a flocculant. Once thickened the fine refuse, which is predominately bentonitic clays, has been dewatered and disposed of using several different methods. These methods will be discussed and include vacuum disc filters, ponds, solid bowl centrifuges, belt filter presses and experiments with electrokinetic dewatering.

Jan 1, 1981

By M. M. Tilman

The Bureau of Mines conducted research into the dispersion strengthening of lead by the coprecipitation method. Commercially available reagents in water solutions were reacted to form homogeneous precipitates of lead and aluminum compounds. The resulting precipitates were roasted to oxides and reduced in hydrogen to form mixtures of lead powder and alumina. The powders were isostatically pressed into billets which were extruded into rods. The rods were rolled into strip to provide material for testing. Alloys containing 0.5, 1, 2, and 3 nominal volume-percent A1203 were tested in short-time tensile tests and in tensile creep tests. An alloy of Pb-3 volume-percent A1203 exhibited an average tensile strength of 8,570 psi after rolling to 75-percent reduction at 125° C but had no measurable elongation. Alloys of lower A1203 content provided a better compromise between tensile strength and ductility. For example, an alloy of Pb-0.5 volume-percent A1203 had an average tensile strength of 6,590 psi with 9-percent elongation after rolling to 75-percent reduction at 125° C. Creep rates of dispersion-strengthened Pb-A1203 alloys were below 1 percent in 10,000 hours at stresses of 2,000 to 4,000 psi.

Jan 1, 1971

By Adolph V. Mitterer

International Minerals and Chemical Corporation operates one of six potash mines in the Carlsbad potash basin. More than 90 percent of America's potash is produced at Carlsbad and IMC accounts for about one-fifth of that amount, Since the Company began operations in 1941 it has mined nearly 50 million tons of ore. Of the two types of ore mined at Carlsbad the principal tonnage is sylvinite in which sylvite-potassium chloride-is the ore mineral. It is produced by IMC as well as by all other mines in the area, In addition to sylvinite IMC is the exclusive producer of langbeinite ore--potassium-magnesium sulfate. From its two ores, International produces a spectrum of 8 high-quality agricultural and industrial chemical products.

Jan 1, 1959

By A. C. Fieldner

The Bureau of Mines has recently conducted a study of results obtained in analyzing similar samples of coal and coke by 25 laboratories throughout then country, in comparison with results obtained in the Bureau's coal laboratory at Pittsburgh. The purpose of this work was primarily to obtain a comparison of the methods of coal analysis used by the laboratories of the American Gas Association. Therefore, four standard samples of coal end one of coke ware prepared in the Bureau of Mines coal laboratory at Pittsburgh, and portions sent to each laboratory. At the same time, a like number of standard samples were submitted to 12 commercial laboratories rot affiliated with the Association, for the purpose of comparing their analyses with the results is obtained by the U. S. Bureau of Mines and the American Gas Association. Tire comparison is based on the average of 24 analyses by the Bureau of Mines on each kind of coal, and the accompanying curves show the deviation from this average analysis, together with deviations from the check limits of the American Society for Testing Materials.

Jan 1, 1923

By Filippo Maria Leoni, George Filz, Wesley Schmutzler, Matteo Bertoni

"The US Army Corps of Engineers selected the Deep Mixing Method (DMM) for the required stabilization at the LPV 111 Project (New Orleans, USA). DMM was used for ground improvement/foundation strengthening and consequently to stabilize and support the burden of the new levee. Two different technologies were used: Trevi Turbo Mix (TTM) and Contrivance Innovation Cement Mixing Columns (CI-CMC). LPV 111 is the largest soil mixing project to date in the USA with its more than 18,000 elements installed to a depth of up to 67 feet for a total of 1.7 million cubic yards of treated soil. The preparation and execution of the project presented many challenges from various points of view. The little time available to complete the job led to the simultaneous utilization of eight deep mixing rigs and batch plants which worked 24 hours per day, 5.5 days per week on a stretch of land approximately 5.3 miles long. Given the imposing geographical extent of the project, a four phase laboratory programme and five field validation test programmes, conducted in as many different areas of the project, were completed to design and optimize the grout mixes and the installation parameters. The massive quality control/quality assurance testing programme produced over 500 drilled core holes and over 5,000 tested specimens in order to determine unconfined compressive strength (UCS) and uniformity of the DMM elements. This paper has the purposes of describing the tremendous challenges encountered and providing valuableinformation that may be useful for other future projects, including details not previously published.INTRODUCTIONReach LPV-111 is part of the Lake Pontchartrain and Vicinity Hurricane Protection System designed to protect the city of New Orleans and the surrounding areas from the surge that would accompany a 100 year hurricane event. LPV-111 measures approximately 8.5 km (5.3 miles) long, of which 7.2 (4.5 miles) extend along the north bank of the Gulf Intracoastal Waterway (GIWW) and the remaining 1.3 (0.8 miles) run north and terminates at the CSX Railroad Gate. The Bayou Sauvage National Wildlife Refuge borders the levee on both sides (Fig. 1)."

Jan 1, 2015

By G. Thorsen

An alternative way to the normal practice of precipitation of jarosite, goethite, or hematite for removal of iron from zinc sulphate process liquors/ is to employ the techniques of solvent extraction. The process presented avoids the addition of any external alkali for the extraction of iron by integrating the leaching and solvent extraction steps in a hydrometallurgical zinc plant. By starting the leaching of zinc from the solid zinc calcine material with an organic solution of an acid liquid cation exchanger, the organic phase is loaded with the organic zinc salt from the direct reaction with zinc oxide. The residue from the organic leaching is transferred to a hot acid leach circuit where the remaining zinc oxide and the zinc ferrites will dissolve form¬ing an aqueous sulphate solution of zinc and iron. In the subsequent solvent extraction of iron from this aqueous leach solution, iron is exchanged with zinc from the organic phase. The commercial carboxylic acid Versatic 10 (Shell) is highly efficient for this integrated process of leaching and solvent extraction. The resulting iron-loaded organic phase is heated to 150-200 C in the presence of water whereby the iron will be directly precipitated from the organic phase as iron oxide of high purity and the regenerated organic acid is recycled to the organic leaching step for reloading with zinc.

Jan 1, 1980

By W. C. Shanks

The Pioche District of Lincoln County in southeastern Nevada (Figures 1 and 2) has been an historically important producer of silver, zinc, and lead. Economic geology of districts in the Pioche area is summarized most adequately in recent reports by Tschanz and Pampeyan (1) and Gemmill (2) and only a few major aspects will be discussed here. Production in the Pioche District began in 1869 and early mining concentrated on silver-bearing fissures in lower Cambrian quartzites. In the early 1870's the Pioche District was second only to the Comstock Lode in world silver production (3). More recent mining activities have centered on the other major ore type in the area, bedded replacement of lower Cambrian carbonates by Ag-Zn-Pb sulfide ore. Production of replacement ore peaked around 1950. The present study is focused on the Pan American Mine because it is an excellent example of low grade carbonate replacement deposits, because there is little structural dismemberment, and because access was readily available. Most previous workers have suggested that both the fissure vein deposits and the bedded replacement deposits of the Pioche districts are a result of spatially related Laramide igneous activity. The purpose of this study is to determine whether ore genesis is a result of igneous activity or if mineralization might be related to late diagenetic processes such as formed Mississippi Valley "type" deposits. Stable isotopes of sulfur, carbon, and oxygen in ore and gangue minerals have been studied to determine the probable isotopic composition of the ore fluid and paleomagnetic studies of the carbonate rocks have been utilized to determine timing of mineralization. Additionally, petrographic and field studies of carbonate lithologies were undertaken in an attempt to delineate non-structural controls on ore localization. These studies are still proceeding and the results presented herein are, therefore, preliminary in nature.

Jan 1, 1979

By L. Diels

About 45% of the contaminated sites are dealing with heavy metal problems. Metals are spread in the environment by mining activities, surface treatment and non ferrous processing. As heavy metals can not be degraded, removal or immobilization (leading to bioavailability reduction) are the only risk reducing measures that exist. The currently best available technique for remediation of heavy metal contaminated groundwater is to pump the contaminated water and to treat it in a wastewater treatment plant installed on the surface. Next to this often used, but expensive, pump and treat technologies, heavy metals can be immobilized by inducing sulfate reducing bacteria (SRB) to transform the sulfates, that are very often present in the same groundwater (due to the metal mining or processing activities), into sulfides. These sulfides will precipitate the metals as insoluble metal sulfides. At the moment several studies have demonstrated the feasibility of this In Situ Bioprecipitation Process (ISBP) for the removal of heavy metals from ground-water as well at lab scale (batch and column tests) as at field scale. However, some questions arise concerning the continuation of the process, the efficiency and the sustainability of the precipitates. The presented study will try to answer these questions. The study is based on more than 10 different studies, all done by the same authors, on different groundwaters and aquifer samples. The presentation will give an overview of the guidelines necessary for a correct and successful bioprecipitation process with stable metal sulfide precipitates. An important question in the ISBP is related to the sustainability of the heavy metal precipitates. It could be observed that the interruption in the carbon source delivery also stopped the in situ bioprecipitation process. Depending on the metal also some release from the precipitate could be observed. It was shown that release can occur with Co and Ni. Aquifers, on which the metals precipitated during the ISBP, were treated in a sequential extraction process under an-aerobic and aerobic conditions. It could be shown that especially under the anaerobic conditions the Zn and Cd precipitates changed from the leachable and the exchangeable fraction to the organic or Fe-Mn fraction (i.e. from the unstable to the stable fraction). The same could be observed for Co and Ni but still some fraction was present under a more available form. On the other hand it could be shown that large differences were observed concerning the heavy metal speciation on the aquifer in function of the used carbon source during the ISBP. The molasses treated systems showed a much more available heavy metal fraction on the aquifer compared to the lactate or HRC® treated groundwater. The different speciation forms based on the use of different carbon sources will be discussed in detail. It will pay attention to the influence of the carbon source, the efficiency of the induction of the bioprecipitation process, the influence on the competence between sulfate reducers and methanogenic bacteria and the influence of low pH on the ISBP. It seems that acetate, which is also a degradation product of fermentation of some carbon sources, can inhibit some sulfate reducers. Also the relation between slow release compounds and immediately available compounds will be explained. Finally a pilot study will be presented showing the problems that can be encountered during this process. Focus will be put on the induction of the process, the keeping on of the process and the follow up of the process by the installation of in situ mesocosm socks. These results will allow the correct implementation of the ISBP with an eye on longevity and sustainability of the process and present the ISBP as a much more sustainable alternative to the pump and treat technology as measure for heavy metals contaminated groundwaters.

Jan 1, 2006