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By Robert J. White

Strong's equation for calculating bottom-hole pressure reduction due to gas cutting of drilling mud is corrected, resulting in a simpler equation which is easier to use. Use of the equation is illustrated by examples. It is shown that reduction of weight of a 10 lb/gal mud by 50 per cent at the surface due to gas cutting produces only n 3 per cent decrease in hydrostatic head at the bottom of a 5,000-ft well. It is also shown that at the surface 5 volumes of air per volume of mud are required to reduce the apparent mud weight from 8.5 to 6.5 lh/gal in a 3,000-ft well. Illustrative graphs are included to show the effect of various degrees of gas cutting on apparent mud weight at depths of 2,000, .5,000 and 10,000 ft and to show variation of apparent mud weight, with depth for a 100 lb/cu ft (13.37 lb/gal) mud gas cut to 90 lb/cu ft (12.03 lb/gal) at the surface. INTRODUCTION In 1938, Strong' published the following equation for calculating reduction in bottom-hole pressure due to gas cutting of drilling mud h = 1/D [p + pn/100 In p + p(1-n/100)/p(1- n-100)] where: h = depth in feet P = pressure in atmospheres at depth h due to mud column only D = hydrostatic pressure in atmospheres of a col-umn of uncut mud 1 ft high p = back pressure at well-head (in atmospheres) n/100 = fraction by volume of gas in mud at well-head at back pres-sure p This equation was recently found to contain an error due to an incor-rect expression for variation of vol-ume fraction of gas with pressure. Values calculated by the original equation are close to the correct values for small percentages of gas for which it was derived but become increasingly erroneous as the gas content increases and are completely unusable at the very high gas con-tents employed in aerated mud. DERIVATION The nomenclature used is the same as in Strong's paper. The pres-sure dP exerted by a lamina of thickness dh at a depth h ft is ex-pressed by Eq. 1 where x = volume fraction of gas at depth h dP = D (l - x)dh . . . (1) When we express x in terms of the wellhead per cent gas n, the well-head pressure p and the pressure P at depth h, the result is Eq. 2. x = (np/p+p)/(100-n) + (np/P + p) When this is substituted in Eq. 1 and rearranged to separate the var-iables the result is dh = 1/D [dp + np/100-n dp/(P + p]. Integration between appropriate lim-its results in or if the wellhead is open so that p = 1 atm and we rearrange Eq. 4, the result is loss in head = hD — P = n/100-n In (P + 1) ...(5) Eq. 5 can be solved easily by successive approximation using hD as a first approximation for P on the right-hand side and calculating a first value for loss in head. This can then be used to get a new value of P using the left-hand side of the equation. Values converge very rap-idly even for quite large values of per cent by volume gas n. EXAMPLES The effect on bottom-hole pressure of 50 per cent gas cutting of the mud in a 5,000-ft well using 10 Ib/ gal mud will be calculated, we have: h = 5,000 ft 10 X 7.48 144 X 14.7 = 0.0353 atm/ft hD = 176.5 atm n = 50 Substituting these values in Eq. 5 and using hD as a first approxima-tion of P on the right, we have, approximate loss in head = 50/50 In (176.5 + 1) = 2.30 log 177.5 = 5.17 atm. We calculate a new value of P as follows:

Jan 1, 1958

By John A. Wolfe

The concepts of sea floor spreading and plate tectonics provide more logical explanations of some geologic processes than were possible a few years ago. I plan to premise my discussion of the regional features of Philippine porphyry copper deposits on this tectonic basis, recognizing that parts of the picture can be explained in other ways, but in the belief that this is the best explanation of the whole. The sequence of events which results in the formation of Porphyry deposits (Figure 1) can be summarized as the result of collision of crustal plates, subduction of the oceanic plate, emplacement of a serpentine ultrabasic diapir, formation of a dioritic magma at depths of 300 to 500 km, rise of the magma to a sub crustal or intra-crustal chamber, eruption of andesitic volcanoes, emplacement of diorite or differentiation of the magma into more acidic products, multiple intrusion of hypabyssal rocks and hydro-

Jan 1, 1973

By Raymond B. Ladoo

[Inquiries are frequently received by the Bureau of Minas relative to occurrence, mining, treatment and utilization of the natural hydrocarbons' such as gilsonite, elaterate, wurtzilite, grahamite, and ozokerite although have been known and used for many years, they are not yet well understood and the amount of recent literature dealing with them as comparatively small. This paper is intended merely to summarize the present knowledge The natural hydrocarbons included in this series are gilsonite, elaterite, wurtzilite, glance pitch, manjak, grahamite, albertite, arid ozokerite and many other minor varieties. With the exception of ozokerite and the other mineral waxes, then all more or less resemble asphalt in that they are dark brown or black bituminous substances of organic origin, generally with a resinous luster. Ozokerite usually light an color with a waxey luster, is closely allied to the others of the series, but is usually considered separately, Unfortunately authorities differ as to nomenclature so that determinations of physical and chemical properties from different sources may riot be readily compared. Abraham Herbert, Asphalts and Allied Substances, 1918, 606 pp. has made one of the most detailed studies of these subjects in recent years, and his classification is used in the main. The following definitions are given by him]

Jan 1, 1920

The Kaldo furnace smelting technique was developed for oxygen steel production by the late Prof. Bo Kalling, Domnarvet, Sweden. Development started in 1948, and production in 1956. Five million tons of steel were produced in TBRC's in 1973. Mainly due to high TBRC maintenance costs, the steel industry now prefers non-rotating converters. In non-ferrous metallurgy, however, qualified new applications of the TBRC technique have been realized or are being considered. Inco, Canada, succeeded to convert nickel matte to metal in the Domnarvet pilot plant in 1959, and have now installed a commercial plant in Copper Cliff. La Metallo-Chimique, Belgium, has pioneered secondary copper smelting and refining in the TBRC, operating plants in Beerse, since 1968, and Alton, U.S.A. Peko-Wallsend Ltd., Tennant Creek, Australia, was faced with the problem of producing saleable blister from concentrates containing 1.5-2.0% Bi. The flash smelting matte, containing 0.2% Bi, could not be refined to an acceptable limit of 0.03% Bi in the blister copper in a Peirce-Smith converter. Tests at Domnarvet indicated that a TBRC would achieve satisfactory bismuth elimina- tion. Two TBRC's were installed in Tennant Creek and operated for 14 months during 1974-75. The problems encountered and how they were over- come are described. Further TBRC applications have been studied in Sweden.

Jan 1, 1976

By S. J. Broderick

[The term "nonmetallic minerals,? as commonly used in the mining industry, refers to those minerals of industrial importance that are mined essentially for uses other than for the metals contained. The field comprises several hundred minerals of industrial importance, of which 70 have been adequately described in the textbook Industrial Minerals and Rocks.3/ A few of the more important nonmetallic products are sand and gravel, salt, phosphates, clays, refractories, linestone, and cement materials. Some of tic minerals, such as bauxite and pyrolusite, have both metallic and nonmetal is applications, but in this report only the nonmetallic mineral phases are considered. In the organic field of nonraetallics only coal is considered, as, the, others - petroleum, natural gas, natural bitumens, and hydrocarbons - are of no importance in water softening.]

Jan 1, 1941

By S. J. Broderick

[The term "nonmetallic minerals? as commonly used is the mining industry, refers to those minerals of industrial importance that are mined essentially for uses other than for the metals contained. The field comprises several hundred rod minerals of industrial importance, of which 70 have can adequately described in the textbook Industrial Minerals and Rocks. A few o f the more important nonmetallic products are sand and gravel, salt, phosphates, clays, refractories, limestone, and cement materials. Some of the minerals, such as bauxite and pyrolusive, have both metallic and nonmetallic applications, but in this report only the nonmetallic mineral phases are considered. In the organic field of nonmetallics only coal is considered, as, the others - petroleum, natural gas, natural bitumens, and hydrocarbons - are of no importance in water softening.]

Jan 1, 1941

By Arthur L. Raub

During the last decade, there haven't been any great innovations in the design features of a copper concentrator. What has worked well in the past continues to work well, so that major breakthroughs have been minimal. Conservatism in the ranks also plays an important part. As a copper concentrator is not designed and built everyday, Davy was elated to have an important part in this project. This is the story of the design of the oracle Ridge Project located north of Tucson on the back of Mt. Lemmon at an elevation of 5,900 feet on the N.E. slope of the Catalinas. The Oracle Ridge property, formerly known as the Control Mine, is owned by Oracle Ridge Mining Partners, a joint venture between Continental Materials Corp. of Chicago and Union Miniere of Brussels, Belgium; both or¬ganizations specializing in the non-ferrous metal industry.

Jan 1, 1979

By B. G. Thomas

"Mathematical process models can be applied in several different ways to serve industry by inducing beneficial changes to process operation. This paper attempts to summarize the different uses, types, and attributes of these models, and to offer some ideas to consider when developing, using, and reporting on them. Process models range from empirical to mechanistic in nature and vary in complexity from simple analytical solutions to coupled, 3-D transient numerical simulations. They are classified here according to the way in which they are implemented in practice, viz. fully-online models, semi-online models, off-line models, and literature models. The purpose of the model should dictate how choices are made during its development. Ways to validate and compare the model with experiments are suggested. Examples are taken in the context of the author's experience in modeling the continuous casting of steel.IntroductionThe objective of this paper is to provide a partial introduction for this symposium by discussing some basic aspects of the application of mathematical process models in industry. Essentially, the aim is to explore how process models are used to benefit industry, and to offer some general comments and suggestions, based on the experience of the author, on how models can best meet this goal.This work is concerned with process models, which consist of systems of mathematical equations and constants that are solved on a computer to make quantitative predictions about some aspect(s) of the process. The specific variables required as input data and generated as output data are important features of the model. The equations often derive from a numerical solution to one or more differential equations and their boundary conditions. The model also includes the constants, which represent material properties, empirical relationships, and other knowledge about the process, and usually require considerable effort to obtain. Thus, general purpose commercial software packages, (ie. finite-element or finite-difference based codes), are not models in this context. They are useful tools, however, serving as frameworks for the development of process models."

Jan 1, 1994

By Herman L. Bauer

The Robinson Mining District near Ely, Nevada, is one of the major porphyry copper districts in the world. Within the district is an east-trending zone of altered porphyry, metamorphosed sedimentary rocks, and sulphide mineralization surrounded by Paleozoic limestone, dolomite, shale and sandstone, Tertiary volcanics, and Quaternary alluvium. Six major disseminated ore deposits have been exploited in this eight-mile zone. About 20% of the district production has come from disseminated ore in metamorphosed sedimentary rocks found adjacent to altered quartz-monzonite porphyry. The following brief statements summarize the inter-relationship of porphyry, alteration, metamorphism, and mineralization: 1. Disseminated copper ore does not occur in unaltered porphyry or in unmetamorphosed sedimentary rocks 2. Sedimentary rocks have been only weakly metamorphosed where intruded, by unaltered porphyry. 3. Intensely metamorphosed sedimentary rocks are found only adjacent to, altered porphyry. 4. Many hydrothermal minerals are common to both altered porphyry and adjacent metamorphosed sediments. 5. Disseminated ore is found in altered porphyry and adjacent meta¬morphosed sedimentary rocks. 6. In general, there is a direct correlation between grade of ore in porphyry and copper content in the adjacent rocks. 7. Chemical changes in the altered porphyry facies and metamorphosed rock facies appear to be related:

Jan 1, 1963

By Benoit Gagnon

Mining of the Schefferville iron deposits began in 1954 on completion of the 574 km railway linking the mines and the St-Lawrence river port of Sept-Iles. Apart from crushing, no treatment of these ores was required before smelting. In the late 1950's, testwork began at Schefferville to develop a process for upgrading the extensive lower grade deposits containing 5l% iron with 15% silica (natural analysis). Engineering for 6.1 million tons per year Beneficiation Plant using cationic silica flotation and the A-C Grate kiln began in 1970 and the first pellets were produced in mid 1973. Production requirements and operating difficulties have restricted capacity to approximately 85% of design but ongoing improvements are being made continuously to attain design capacity.

Jan 1, 1980

By C. M. Diaz

The chemistry of the main unit processes in nickel extractive pyrometallurgy is reviewed. Key re1a ions between smelter feed composition and process selection are discussed, with particular reference to operating conditions, energy requirements and products. The paper a1 so includes a brief discussion of current nickel smelters, based on the results of a recent survey carried out by TMS.

Jan 1, 1988

By Garry G. Lowder

The regional geologic setting is essentially a volcanic island arc built upon an oceanic basement, consisting of basalt and minor pelagic sediments (the Tinombo Formation of Eocene - lower Miocene age. Trail et. al. 1974). -- An east-west chain of intermediate and acid calc-alkaline volcanoes (the Bilungala Volcanics) was built on the oceanic basement during the Miocene. The Bilungala Volcanics are flanked to the north largely by contemporaneous andesites and volcanoclastic sediments of the Dolokapa Formation. During middle to upper Miocene time the Bilungala Volcanics were invaded by large masses of predominantly dioritic intrusive rock and it is within one of these dioritic intrusive complexes, the Bone Diorite, that the cluster of porphyry copper systems occurs. Renewed volcanic activity in the Plio-Pleistocene produced acid pyroclastic rocks (the Pinogu Volcanicsi whose distribution is controlled by present-day topography. Structural trends, largely interpreted from SLR imagery, are pre- dominantly NW or NIWJ. The right-lateral Gorontalo Fault, which trends hW through the town of Gorontalo (Katili, 19691 is the most prominent structural feature. Many of the major structures in the Tapadaa district have similar orientations and may be sympathetically related to the Gorontalo Fault.

Jan 1, 1976

By Jill Dill Pasteris

Several mineralogical prospecting techniques are used in diamond exploration. Most are concerned with identifying indicator minerals such as garnet and ilmenite, which are derived from mantle xenoliths hosted by kimberlites. The first goal of such prospecting is to locate kimberlite intrusions; the second goal is to identify the diamond-bearing kimberlites. Explorationists have worked much less on the indigenous kimberlite phases. The kimberlitic opaque oxides, ilmenite and particularly spinels, promise to be useful in discriminating between intrusion episodes in identified kimberlites, and perhaps in the evaluation and prediction of diamond grades. Several petrologists have showed that spinel compositions and zoning patterns are specific to certain intrusive facies in South African and Canadian kimberlites. Careful evaluation may indicate a correlation between spinel parameters and diamond content.

Jan 1, 1983

By Mikiya Tanaka

This paper outlines our attempt to establish a recycle process of nickel in the spent baths and waste rinse water of electroless nickel plating plants using solvent extraction and solvent-impregnated support, Solvent extraction studies of nickel from actual spent baths revealed that (i) nickel is efficiently extracted by a hydroxyoxime extractant such as LIX84I at a pH greater than 6 and is readily stripped with sulfuric acid, and (ii) the mixtures of LIX63 and acidic organophosphorus extractants (D2ERP A, PC88A, and Cyanex 272) enhanee the nickel extraction efficiency to a sufficient degree without pH adjustment, but at the same time, reduce the stripping efficiency. The application of acidic organophosphorus extractants to selectively remove impurity metal ions (iron and zinc) from a real spent bath before extracting nickel lead to the finding that PC88A and Cyanex 272 effectively remove iron and zinc without pH adjustment leaving nickel in the raffinate. The removal of nickel from the waste rinse water was also studied. Solvent-impregnated supports with a macroporous resin and oil sorbents made of natural kapok fiber and synthetic fiber as supports were applied using D2EHPA and LIX860 as the extractants. During the batch operation, nickel is removed with a high efficiency without pH adjustment. During the column operation, however, the effective removal is hindered by (i) the dissolution of the nickel-D2EHPA complex into the aqueous phase in the high loading region, and (ii) the slow removal rate of the LIX860-impregnated support.

Jan 1, 2003

By J. C. Irvine

Meramec Mining Company is a joint venture by Bethlehem Steel Corp. and St. Joe Minerals Corp. which mines and pelletizes iron ore at the Pea Ridge Mine. The Pea Ridge property is located near Sullivan, Missouri, about 70 miles southwest of St. Louis. The orebody was delineated in the mid-1950's by St. Joe during a lead exploration program. The first test holes drilled on the Pea Ridge magnetic anomaly revealed the presence of a large magnetite deposit; further drilling in 1956 and 1957 confirmed that the orebody was mineable, Meramec Mining Co. was incorporated in 1957 and shaft sinking began late in the year. Production commenced in April 1964. The orebody is overlain by about 1300 feet of flat-bedded sediments. It is tabular, about 2600 feet long and up to 600 feet thick. It dips about 80° and is of unknown depth. The ore is mainly high grade magnetite with small zones of specular hematite. The wall rock is a Precambrian rhyolite porphyry. The mine was initially started with five major levels on 150 foot intervals. Crosscuts were driven across the orebody on 190 foot centers. Banks of scopes were mined between the crosscuts by a modified shrinkage stoping method. This was done by undercutting a 40 foot wide by 150 foot long block and blasting horizontal "lifts" drilled on 5 foot intervals. A 65 foot still was left between levels which contained the slushing drift, fingers, crown pillar, and adequate thickness for support. By 1971 a ?lattice? of pillars had been left and mining had progressed to the point that an orderly pillar recovery program was necessary.

Jan 1, 1976

By C. M. Mason

Bureau of Mines studies were made on the sensitivity of several ammonium nitrate-fuel oil (AN-FO) mixtures to bullet impact. The experimental work was done with one military rifle and two high-velocity sporting rifles with a variety of ammunition. For the three rifles used, the order of efficiency in initiating detonation in AN-FO mixtures was 220 Swift >300 Weatherby Magnum >30-&apos;06. The velocity of the bullet was found to be a decisive factor in the initiation. The sensitivity of various materials studied increased as follows: Clay-coated prills with 4 percent oil <fresh surfactant-coated prills with 4 or 6 percent oil <surfactant-coated prills with 4 or 6 percent oil and aged 270 days <crushed prills with 6 percent oil <very low-density, surfactant-coated prills (micronized), with 4 percent oil.

Jan 1, 1963

By Edgar W. Sawyer

Attapulgite and sepiolite are the clay minerals used to thicken ionically contaminated watzrs in the preparation of drilling fluids. They are nonsweliing clays that can be dispersed and reflocculated by mechanical means to increase the viscosity of fresh water and salt and gypsum contaminated waters. Those gelled in fresh water do not become excessively thick when contaminated with high salt concentrations or polyvalent cations encountered during drilling. Gels formed exhibit thixotropy and yield pseudoplastic rheological behavior due to the particle interactions and mechanical interferences of the flocculated gel structure.

Jan 1, 1983

By Mark W. Booth

THIS paper deals with the subject of inbye power as the mechanical . engineer sees it, and invites discussion, particularly from the electrical engineer. At the outset, it will be necessary to clear the ground a little by some definite statements. In this question of compressed air versus electricity for the transmission of power and driving of machinery in underground workings, we must see that there are definite fields that compressed air on the one hand, and electricity on the other, can fill to much greater advantage than the other, and in which there can be little or no direct competition, at least for the present. It is under conditions where these fields overlap, and as to where the line must be drawn between the two, that the respective merits of each must be considered. Steam was the first means used to transmit power from the surface of a mine to drive underground machinery, and so long as distances were short and means possible to ensure fairly efficient use of the steam, and where the fire hazard was not in evidence, it gave fairly efficient service. I have in mind an instance during my own connection with the mines-a duplex pump at the shaft bottom at Princess colliery, driven by steam, and which used the steam compound and condensing; and, but for the mechanical difficulties, it was a not inefficient proposition. The steam was taken direct from the surface boiler-plant through a line down the shaft, and used directly at the pump, being in effect a straight conversion from coal to steam to work done. It was the mechanical arrangement, and failure of the pump in that direction, that led to its removal and replacement by something better in the way of an electrically driven turbine pump. Given modern mechanical arrangements, such as a steam-turbine drive on a high-speed turbine pump, and all other parts made in accordance with best practice in the art of steam generation and use, a steam-driven unit fully as economical would have been obtained. But the central electric supply station, and all that that means or promises (not always the same), turned the scale against steam.

Jan 1, 1936

By Chao Zhang, Kexin Jiao, Yi Qian, Jianliang Zhang

Now low-grade iron ore were widely used. However, one prominent problem is that the content of trace elements is higher than that in high quality iron ore. For the requirement of the content of Mn, Cr, Ni, Cu, and Ti in hot-rolled steel sheet and strip, the upper limits of these elements in sinter will be studied in this paper. Using the activity model of aggregation of electronic phased slag composition, the distribution ratio of each element in converter is analyzed and the content of each element in hot metal is calculated. Furthermore, through the thermodynamics method, the distribution ratio of each element in BF is analyzed and the content of each element in raw material is calculated. The upper limits of Mn, Cr, Ni, Cu, and Ti in sinter can be determined by calculating, the values are as follows: Mn 0.767%; Cr 0.552%; Ni 0.055%; Cu 0.159%; Ti 0.108%.

Jan 1, 2015

By R. E. Coleman

Infrared spectroscopy, employing the internal reflection method in conjunction with solvent extraction techniques, was used to study surface reactions between aqueous potassium ethyl xanthate and both sphalerite and precipitated zinc sulfide each activated with aqueous copper sulfate. It was determined that reactions occurring on the sphalerite and zinc sulfide surfaces produce the reaction products ethyl dixanthogen and cuprous ethyl xanthate, some of which are ad¬sorbed on the mineral surfaces. According to infrared spectra showing the reaction to form these compounds, the ratio of cuprous ethyl xanthate to ethyl dixanthogen adsorbed is directly related to pH of the flotation solution.

Jan 1, 1967