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By Anette Mueller, Thomas Schnellert, Sérgio C. Angulo

"The use of automatically sorting technique, to separate gypsum components from recycled material of processed construction and demolition waste (C&DW), is motivated by environmental and economical aspects. Only if the gypsum can be separated the aggregates can fulfill the environmental requirements and also the structural characteristics according to the standards. Furthermore, the separation of red brick can also improve the quality of the aggregates.This paper aims at analyzing the separation of gypsum components and red brick by using the color sorting technique. The impacts on the composition and the envelope density of recycled aggregates are described. Depending on the gypsum content the application of two processing stages (rougher-cleaner) can be necessary to produce aggregates with sufficiently low gypsum content. Additionally, the separation of red brick and concrete is successful. So, the color sorting may be a promising technique to upgrade the quality of mixed C&DW aggregates.IntroductionConstruction and demolition waste (C&DW) is a mixture of different materials. Such mixtures can be used only in low grade applications. If the material is used as certified material for road construction or as aggregate in concrete the concrete particles must be separated from the other building materials. This paper aims at analyzing the separation of gypsum components and red brick by optical sorting. The needed stages of sorting for getting a product quality according to the German Standards are deduced.Gypsum is a building material that is increasingly used for interior works in Germany like it is shown in figure 1 [1]. At present the content of gypsum in C&DW is estimated at about 1 %. Assessments on the basis of material streams of gypsum and concrete and their life spans show that higher gypsum contents of about 3 % must be expected in future [2]. Also in other countries the use of gypsum has grown considerably in the last decades. From the characterization of C&DW available in some cities in Brazil, 4 to 15 % of total amount of C&DW that may arrive at the recycling plant to be processed is excessively contaminated by gypsum. In one of these cities, the average content of gypsum in the C&DW before processing was as high as 2.1 % [3]."

Jan 1, 2008

By Ariti J

The mineralogy and extractive metallurgy of platinum and palladium in ores and residues is examined and the relative reactivity of Pt, Pd, PtS and PdS in cyanide and chloride media at 20¦C is discussed. Electrochemical measurements establish that Pd is readily leached in chloride media but more slowly in cyanide media due to a passivating PdO film. The passivating oxide film on Pt prevents leaching in either system at ambient temperatures. The results of leaching Au, Pd and Pt from an iron oxide residue obtained from the Sherritt Gordon Process using CN/air and Cl-/H202 are compared. It appears that passivation is overcome either by roasting at ?600¦ or by leaching at >_100¦C.

Jan 1, 1991

Sublevel open stoping (S.L.O.S.) was introduced at Rosebery in 1972 in the wider ore blocks below 14 level, largely replacing cut and fill methods which had been in use up till that time. During 1973/74 the method produced 10% of primary stoping tonnes, and by 1981/82 it increased to 65%. Because of the increasing reliance placed on sublevel open stoping for primary stoping production, every effort was made in both planning and operating to: - maximise ore recovery and reduce dilution - increase productivity - reduce costs.

Jan 1, 1982

By R. J. Fruehan

The oxygen activity and concentration were measured in Fe-Cr-0 melts in equilibrium with an oxide phase at 1600°C (2912°F). The activity was determined by ,use of the following solid oxide -electrolyte galvanic cell CY-Cr8,(s) I ZrOz(CaO) I Fe-CY-G(saturated)(l) The oxygen concentration decreases with increasing Cr concentration to about 270 ppm 0 at about 7pct CY and then increases gradually. The activity coefficient of oxygen (fo) decreases with increasing Cr. In melts containing up to about 20 pct Cr, log f is approximately a linear function of wt pct Cr with a slope (e q 2) of —0.037. The activity of chromium was calculated and found to exhibit a small negative deviation from Raoult's law. From the activity and solubility data for low chromium melts, the free energy of formation of chromite, FeCr204, was found to be -79.8kcal per mole where pure liquid chromium and oxygen at I wt pct in Fe are the standard states. ThE effect of chromium on the chemical behavior of dissolved oxygen in liquid iron is of great importance in controlling the deoxidation of steels containing a significant amount of chromium. Chen and chipman' equilibrated Fe-Cr melts in the presence and absence of slag with hydrogen-water vapor mixtures. They concluded that at 1595°C chromite was the oxide phase in equilibrium with Fe-Cr alloys containing less than 5.5 pct Cr while at higher chromium concentration Cr,O, was the stable phase. In the composition range 0 to 10 pct Cr they found that the interaction coefficient, was equal to -0.041. Turk-dogan,' Schenck and Steinmetz,, and pargeter4 measured egr) in a similar manner and found the value to be -0.064,-0.04, and -0.052, respectively. McLean and Be11 evaluated egr) from their data on the equilibrium of Fe-Cr-Al-0 alloys with H2/H20 mixtures and found it to be -0.058. However, McLean and Bell's value should only be considered an estimate because the effect of aluminum on the activity coefficient of oxygen is about a hundred times greater than that of chromium. Consequently, an error in the value of egl) used, which at the present time is not well-known, or an error in aluminum analysis, which is present in very small quantities, will result in a significant error in egr). Fischer et a1.6 determined the interaction coefficient (eEr) in Fe-Cr-0 melts not in equilibrium with an oxide phase and containing less than 18 wt pct Cr at 1600°C electrochemically. They determined a value of -0.031 for egr). Hilty et aL7 measured the oxygen content of Fe-Cr melts in equilibrium with an oxide phase containing up to 50 pct Cr. They found that the solubility of oxygen decreased as the chromium content increased to about 6 pct Cr and then increased gradually. They concluded that the equilibrium oxide phase was chromite below 3 pct Cr, distorted spinel from 3 to 9 pct Cr, and Cr,04 above 9 pct Cr. Adachi and lwamotoa also investigated this system, but did not find Cr30,. They X-rayed the equilibrium oxide phases and did not find the presence of Cr,O,. They also X-rayed the oxide phase extracted from a 65 pct Cr melt which was heat treated and did not find metallic chromium as would be expected if Cr3O4 were the equilibrium oxide phase as indicated by the reaction : 3Cr3O4 — 4Cr2O:, + Cr [lj It was the purpose of the present investigation to determine the effect of chromium on the activity coefficient of oxygen in Fe-Cr melts by measuring the activity and solubility of oxygen equilibrated with an oxide phase in the composition range 0.18 to 50.5 wt pct Cr at 1600°C (2912°F). The activity of oxygen in the melts was determined by use of the following galvanic cell: The relationship between the partial pressure of oxygen in equilibrium with the melt and the reversible electromotive force of the cell (E) is where 11 = 4, F is the Faraday constant, pb, is the oxygen pressure in equilibrium with the meit and is the oxygen pressure in equilibrium with Cr203 as determined from the free energy data compiled by Elliott et al? The oxide phase in equilibrium with pure chromium was assumed to be Cr If Cr30, were the equilibrium phase the activities derived would be approximately the same, since the best estimated free energy of formation of Cr,O,, if it does exist, is approximately % the free energy of formation of The activity of chromium in Fe-Cr alloys at 1600° C was also determined from the measured electromotive force. The activity of chromium (aCr) is related to the electromotive force as follows: , The oxide phase in equilibrium with pure chromium and Fe-Cr melts from 10 to 52 pct is assumed to be Cr203 so that n equals three. If future work proves the existence of Crs04 in equilibrium with Fe-Cr melts and pure chromium, the experimental results can be reevaluated using a value of $ for n in Eq. 141. A value of ^ for n will make the activities about 10 pct higher. In order for Eqs. 131 and [4J to be valid the electrolyte, ZrOa(CaO), must exhibit predominantly ionic conduction at the temperature and oxygen partial pressure of its use. Previous work1' has demonstrated that ZrOz(Ca0) is predonlinantly an ionic conductor

Jan 1, 1970

Comalco Limited has recently completed construction of a $50 million kaolin plant at the site of its bauxite mining and industrial minerals operations at Weipa. The plant will produce 100,000 tonnes per annum of coating grade kaolin for the paper industry.Comalco produced the first coating kaolin from the deposit in 1979 on a trial basis. Since then a variety of quality coating grades with specific particle ize distributions and brightness values have been prepared.Extensive drilling and bulk sampling of the deposit over eight years has shown that the orebody is large and of a high grade suitable for the production of premium quality coating kaolins.The processing plant technology was developed by Comalco in association with the European kaolin and equipment producer Amberger Kaolinwerke GmbH (AKW).The Weipa kaolin plant is the first of this size to be built in the Pacific Basin region and it will offer the region's paper-coating mills a stable and reliable source of high-quality kaolin, shipped from an established bulk loading port. The paper provides an overview of the development of the kaolin investment, the nature of the production process and details the project management procedure used for the design, construction and commissioning of the plant. Three areas of significant interest, the gas turbine fired pray dryer, the moving bridge shiploader and the use of aerobelt conveyors on the project are detailed.

Jan 1, 1988

A review is given of progress made to- wards the development of personal gravimetric dust sampling for risk assessment on South African gold mines. The present strategy is critically examined on the basis of principles for assessing health hazard from dust exposure. Reasons are advanced for replacing the konimeter with a gravimetric system based on full shift personal sampling. Constraints imposed by local characteristics of gold mines are used to illustrate the difficulty in finding suitable instrumentation for measuring personal exposure to respirable silica.

Jan 1, 1988

By Shunli Z, Jin X, Guanzhou Q

Flotation behaviour can be controlled, due to diminishment of granula quality and extension of specific surface area, by adding coarse particles (high- grade concentrates) to condition pulp. It has been substantiated that coarse particles can intensify fine particle flotation and its mechanisms are effects of carrier, intermedium and assistant aggregation of coarse particles. Calculation and analysis of Reynolds numbers and their variation for different size particles, under specific turbulent dynamic conditions, reveal that agglomeration among granulae is subject to specific turbulent dynamic conditions. Furthermore, sizes and adhesion strength of flocculated particles are the function of specific physical and chemical factors. Based on this research an innovative ramification carrier flotation process has been developed, which has been applied to Fankou Lead- Zinc Mine, Guang Dong province, China, etc, with satisfactory results. These results shed light on distinction between conventional flotation and fine particle flotation, meanwhile, provide a basic approach for further solution of fine particle flotation problem.

Jan 1, 1993

By J. R. Kadambi, E. Kucukal, J. Furlan

"Hydrocyclones are used in various industrial applications, including mineral processing and tailings management, to separate or classify solid particles and/or liquid droplets from multiphase feed. The fluid flow in a hydrocyclone (used in mineral processing) was investigated numerically and experimentally using particle-image velocimetry (PIV) and refractive index matching techniques. Two turbulence models were used in the calculations: the k–? model and the Reynolds stress model. Particle image velocimetry measurements were taken at various spatial locations along the cyclone. Computational results were validated globally using pressure and flow-rate readings at the boundaries, and locally by comparing the PIV velocity-vector maps and profiles.RÉSUMÉ On utilise les hydrocyclones dans diverses applications industrielles, dont la minéralurgie et la gestion des résidus, pour séparer les particules solides et/ou les gouttelettes liquides de l’alimentation polyphasée, ou pour les classifier. Une étude numérique et expérimentale sur l’écoulement des fluides dans un hydrocyclone (dont on se sert en minéralurgie) a été menée à l’aide des techniques de vélocimétrie par images de particules (PIV, de l’anglais particle image velocimetry) et d’appariement des indices de réfraction. Deux modèles de turbulence ont été utilisés dans ces calculs, à savoir le modèle de turbulence k–? et le modèle aux tensions de Reynolds (RSM, de l’anglais Reynolds stress model). La valeur de la PIV a été mesurée à diverses positions spatiales le long du cyclone. Les résultats de ces calculs ont été validés globalement à l’aide de relevés des pressions et du coefficient d’écoulement d’une extrémité à l’autre de l’hydrocyclone, et localement à des coordonnées spatiales spécifiques en comparant les cartes et les profils du vecteur vitesse PIV."

Jan 1, 2017

By Carter NB

A statistically-designed experimental program has been used to study compositional and processing variables which influence the development of strength and reducibility of iron ore pellets. The effects of chemical composition and processing variables were investigated by indurating laboratory-made green pellets, of known composition, under approximately isothermal conditions in a pot- grate simulator. Some findings from a six- variable study are summarized in the form of contour diagrams and emphasize the importance of interactions between the variables. Production of strong, highly reducible pellets is possible over a considerable range of combinations of temperature and firing time. Abrasion index (AI) and cold compression strength (CCS) improve as both these variables increase, but reducibility (R) declines, so a compromise is required. When the lime level is too low to form enough slag for bonding, the AI and CCS may be inadequate. Larger additions of lime tend to improve AI and CCS, with only slight effects on R. Finer grinding of the balling feed (i.e. higher Blaine index) tends to improve Al and CCS without

Jan 1, 1980

The reduction in man's contribution to the Greenhouse effect will only be achieved by a number of small steps. Some steps will absorb carbon dioxide (CO2) from the atmosphere in slightly greater quantities, others will reduce the amount of carbon dioxide generated. This paper deals with the reduction of carbon dioxide by improving the combustion efficiency of petroleum fuels. Until recently most reductions in fuel consumption and air pollution have been brought about through mechanical adjustments to combustion equipment. Since the development of tetraethyl lead, little has been done to chemically modify combustion reactions to improve fuel efficiency or reduce emissions. During the past five years Australian laboratory and field trials with ferrous picrate treatment have demonstrated significant and economic gains in the combustion efficiency of diesel fuels. These studies have revealed that even under ideal conditions in diesel engines, carbon monoxide (CO) momentarily saturates the combustion chamber. This state reduces combustion rates, peak pressure and power and increases the risk of pollution. Theoretical, laboratory and field data are presented which support the mechanism by which the ferrous catalyst accelerates the oxidation of CO to the terminal CO2 thus reducing fuel consumption and the undesirable combustion products accompanying the CO saturation of combustion environments. While this paper deals principally with diesel fuels commonly used in mining operations, the catalytic effect of the ferrous ion is also shown to significantly reduce fuel consumption by petrol engines thereby promising a means to reduce the much larger contributions to the Greenhouse gases by automobiles.

Jan 1, 1989

By Magnus Troilius

SINCE the discussion on steel rails in America has forcibly drawn attention to the value of chemical analysis, if not as a necessary stipulation, at least as a guide to control the usual mechanical tests, some doubt has been thrown upon the accuracy of the analytical results obtained by different chemists. To any one having the least acquaintance with chemistry, it is quite clear that if exactly similar results are to be obtained from the same borings of steel, exactly the same methods must be used by the different analysts. Hence the necessity (if complications are to be avoided) of establishing what I may call standard or normal methods, to be used both by the inspectors and by the chemists at the works. Remembering that the application of chemistry to steelrail inspection is yet in its infancy, it is of great importance to possess a perfect acquaintance with the best methods in use. Being myself a grateful pupil of Professor Eggertz, of the School of Mines in Sweden, it occurred to me, two years ago, that I could not do better than start a laboratory of my own, and engage one of his pupils, Mr. Troilius, for the purpose of analyzing the steel borings from mechanically-tested rails, so that I might thus obtain without delay thoroughly accurate determinations. Moreover, in order to carry on the operations in perfect accordance with the methods used at the steel works in England and Germany, where I had to control the manufacture, I deemed it desirable to allow Mr. Troilius to go through a course of training at these works; and I gladly seize this opportunity of expressing my grateful acknowledgments to several works in England and in Germany for affording every facility for such an exchange of information as mas found necessary in arriving at the best analytical methods to be used.

Jan 1, 1882

THE great development of the mines and metallurgical works of this country during the last few years, accompanied as it has been by the investment of enormous sums of money in purchasing lands, and in the erection of improvements, requires that advantage should be taken of the accumulated knowledge of engineers, superintendents, and' others, in mastering &he problems which are constantly presenting themselves for our action. Among those may be mentioned the consideration of more economical systems of mining in our coal and metal-liferous mines, improved methods of transportation above and below ground, unwatering and ventilating mines, the mechanical preparation of coal and other minerals, the various metallurgical processes, and, in fact, every question tending to the attainment of two great objects : 1st. The more economical production of the useful minerals and metals. 2d. The greater safety and welfare of those employed in these industries. In European countries, where the arts of mining and metallurgy have long been the subject of the most careful study, no means have been found so effectual in attaining the end above proposed as the free interchange of experience among those actually engaged in these industries, and this object has been accomplished, mainly, through the medium of institutes, associations or societies, composed of those engaged in these occupations, and by the periodical publication of essays or papers, communicated to such societies by their members. I t must be evident to all practical men that the interchange of the varied experience of those engaged in such occupation in this country could not fail to advance very materially the desired objects; it is, therefore, proposed to establish an American Institute of Mining Engineers, which will hold its meetings periodically in the great mining and metallurgical centers, where works of interest, such as mines, machine shops, furnaces, and other metallurgical works, can be inspected, and the members exchange their views, and consult for mutual advantage upon the difficulties encountered by each; these transactions or proceedings, when published, would form a most valuable and greatly-needed addition to our professional literature. I t is proposed that a meeting of those sympathizing with the object above mentioned shall be called for the purpose of organizing such an association, the place and time of meeting being Wilkes-Barre, Pa., and the month of April or May. Communications indicating the opinion and wishes of all, both as to these points, and also as to the organization and objects of the Institute, will be gladly received by any of the undersigned, and a notice of the date of meeting, which will be arranged to suit the greater number, will be duly communicated. Any

By Chend J

Research conducted into backfill drainage at Mount Isa Mines since 1992 is described. Piping in draining backfilled scopes has been the primary cause of bulkhead failures and emphasis is placed on research into the piping mechanism. Laboratory and in situ tests aimed at understanding the piping mechanism have been conducted and the results are presented. A case history of piping in a draining bench scope fill mass is described and a technique for reducing the potential for bulkhead failures in hench stopes is presented. Hydraulic fill is produced by standard cycloning of tailings and the overflow (reject material) is sent to thickeners prior to placement in the tailings dams. Research into the partial introduction of thickener underflow into the backfill system and its influence on backfill drainage is also descrihed.

Jan 1, 1998

By Barro L

There is currently a world wide interest in coal-oil technology as the search continues for alternative energy sources to reduce the consumption of petroleum crude. An important aspect of this coal-oil technology study is to obtain information on the flow properties of coal-oil slurries. While some work has been reported on the flow behaviour of black coal-oil suspensions, very little work on brown coal-oil suspensions has been reported. In this paper flow charac- teristics of brown coal-oil suspensions for various coal concentration and temperatures have been presented. A Capillary rheometer, designed to handle settling suspension, has been used for deter- mining rheological properties. Brown coal of 0 0725 mm average particle diameter has been used in this work. The oil was a coal derived product having a boiling point range of 234¦- 319¦C, Apparent viscosity of all suspensions was found to increase on storage due to ageing. Ageing might have occurred due to physico- chemical interactions between coal and oil. Flow behaviour of some suspensions changed from Newtonian to non-Newtonian on storage.

Jan 1, 1980

By Mankosa MJ, Yoon R-H

A reliable scale-up procedure for column flotation must address three important areas of column design, ie column geometry, sparging system and wash water distribution network. The column geometry is dictated by the maximum froth carrying capacity (which determines column diameter) and the bubble-particle attachment rate and particle retention time (which determines column length). The most important factor in the scale-up of an air sparging system is the ability to produce small bubbles in both laboratory and full-scale columns. Other factors, such as energy consumption and maintenance requirements, should also be considered in the scale-up of bubble generators. It is also important to design a wash water distribution system that can properly control the froth stability and maximise the column throughput. Based on these criteria, a successful scale-up example is given.

Jan 1, 1993

By I. W. Alcorn

THE cost of drilling in the past few years of proration and ever decreasing allowables has received increasing thought and study. It seems to parallel the strides made with respect to pumping problems in 1932 and 1933. Low profit margins stimulate the search for economies. Any discussion of slim-hole drilling involves a multitude of abstract values, and the problem can be attacked only by a study of records and rational thinking. In a measure, traditional methods must be studied with a questioning attitude. The words "slim hole" may be somewhat misleading, as the term is entirely relative. For that reason I wish to define it as used in this discussion. On the Gulf Coast, I would define a normal hole as one in which 10 3/4-in. surface casing has been set and below which a 9 7/8-in. hole is dug. With this as a datum, holes of larger diameter below surface would be called "large holes," with 12 1/4 in. as the "extra large" class and holes of smaller diameter classed in the slim-hole range, 6 1/4 in. representing about the minimum size. The optimum size has not been definitely determined, but the preference is for a program that would call for setting 8 5/8-in. surface casing and digging a 7 3/4-in. hole. Different sections of the country might very properly deviate from this practice because of differences in depth, formations, regulations, or other factors. This paper will be confined to a discussion of the drilling of exploratory wells, as the drilling of this class of wells is quite a different problem from that of drilling a proven field, although many of the same considerations apply in both cases, as will be apparent. Although for many years shallow slim-hole and core-test holes of small diameter had been dug, it was not, I believe, until the fall of 1937 that serious consideration was given to its application in drilling wells 7000 ft., 8000 ft. and 9000 ft. deep on the Gulf Coast. This does not mean that nearly all such wells drilled on the Gulf Coast now are of the slim-hole variety, but only that efforts have been aimed in that direction with very encouraging results and there has been a very definite trend to reduce the size of holes, a trend that probably will continue. As to exploration policy, there appear to be two distinct and opposite views. The one usually followed in the past was more or less designed to "shoot the works" on one well. Generally on the Gulf Coast, the depth at which production might be obtained is limited by the drilling equipment and economics. With this thought in mind, wildcat wells are often planned with the idea of carrying the depth to 10,000 ft., or even 15,000 ft. All of the possible hazards are anticipated and the general drilling and casing programs are so predicated. Such wells contemplate the drilling of large-diameter holes; the setting of at least one protective string of casing and an extensive coring policy, all of which finally adds up to an expensive well. As opposed to this general policy is the slim hole. This, on the Gulf Coast, recognizes that new discoveries represent gam-

Jan 1, 1941

By Catherine T. Aimone-Martin, Kristen Kolden

In August of 2013 the USDA Forest Service (USFS) blasted bedrock at the base of a waterfall in Kanalku Creek within the Kootznoowoo Wilderness Area on Admiralty Island in the Tongass National Forest located in Southeast Alaska. The purpose of the blasting was to widen and deepen a plunge pool at the base of a waterfall complex considered to be a partial barrier to migrating sockeye salmon. Drilling and blasting to remove 12 to 15 cubic yards of rock occurred over a two day period.

Jan 1, 2015

By Xuexin Ding, Weijie Wei, Jinwang Zhang, Yi Chen, Shengli Yang

"Many ultra-thick coal seams exist in Xinjiang and the northern part of the Inner Mongolia. These coal seams are more than 30-40m thick. This kind of the thick coal seam is too difficult to extract in one slice, so the top-coal caving longwall mining method was designed for this purpose. In order to study the movement characteristics of the overburden strata and the development of the ""three zones"" in ultra-thick coal seams, the physical and numerical simulations were carried out based on the in-site condition of Baiyinhua coal mine. The result shows that, when extracting the upper part of the l 5m thick coal seams, the first weighting interval was 50-58m and the periodic weighting interval was I 8-20m. The caving zone, fractured zone and bending and sinking zone were 38m, 92m, and 50m respectively in height. The fractured zone height increased with the advancing distance of the face, but in some localities, a ladder-like distribution due to the periodic weighting existed. When extracting the lower part of the 25m thick coal seams, the roof was extremely broken and the collapse range of overlying strata continued to increase in irregular form.INTRODUCTIONThe thick coal seams occupy 44 percent of coal reserves in China and account for 45 percent of the gross domestic coal production. There are three main methods for extracting the thick coal seams: sublevel mining, large height mining, and longwall top-coal caving (LTCC) (Wang, 2009). Due to the rapid development of LTCC in the past two decades, it has become the most extensively used mining method. It possesses the advantages of high-production, high-efficiency, low development ratio, and low-cost (Yang, Zhang, Chen, and Zhengyang, 2016; Wang and Zhang, 2015). Baiyinhua coal mine's coal reserves are full of uniformly distributed thick coal seams, with the minable thickness of the main coal seam between 25 to 40m, i.e. the main coal seam is an ultra-thick coal seam. Sublevel longwall top-coal caving (SLTCC) which is an efficient method for extracting the ultrathick coal seams has led to multiple disturbances Xie, Chen, and Wang, 1999; Singh and Singh, 1999; Xie, Chang, and Yang, 2009. Therefore, using the case of Baiyinhua coal mine, the movement features of overburden strata and development characteristics of the three zones in ultra-thick coal seams were studied by physical and numerical simulations (Qian, et al, 2003; Qian, 1994)."

Jan 1, 2016

By E. L. J. Kleynhans, J. I. J. Fick, J. P. Beukes, P. G. van Zyl

"Ferrochrome (FeCr) is vital for the production of stainless and high-alloy ferritic steels, since it is the only source of new Cr units. FeCr production is an energy-intensive process. The pelletized chromite prereduction process is most likely the FeCr production process with the lowest specific electricity consumption (SEC), i.e. MWh/t, currently in operation. However, due to increases in costs, efficiency, and environmental pressures, FeCr producers are attempting to lower their overall energy consumption even further. Recently, it was proven that pre-oxidation of chromite ore prior to pelletization and prereduction significantly decreases both the SEC and lumpy carbonaceous reductants required for smelting. This paper presents the first attempt at conceptualizing the technoeconomic feasibility of integrating chromite pre-oxidation into the prereduction process. Financial modelling yielded a net present value (NPV) at a 10% discount rate of approximately R900 million and an internal rate of return (IRR) of approximatelyy 30.5% after tax, suggesting that the implementation of pre-oxidation prior to pellet prereduction may be financially viable. Sensitivity analysis indicated that the parameter with the greatest influence on project NPV and IRR is the level of prereduction. This indicates that the relationship between maintaining the optimum pre-oxidation temperature and the degree of prereduction is critical for maximium process efficiency. IntroductionStainless steel is a crucial alloy in modern society. Virgin chromium (Cr) units used in the manufacturing of stainless steel are obtained from ferrochrome (FeCr) – a relatively crude alloy consisting predominantly of Cr and iron (Fe) (Murthy, Tripathy, and Kumar, 2011; Beukes, van Zyl, and Ras, 2012). FeCr is produced mainly by the carbothermic reduction of chromite ore in submerged arc furnaces (SAFs) and direct current arc furnaces (DCFs) (Neizel et al., 2013; Beukes, Dawson, and van Zyl, 2010; Dwarapudi et al., 2013). The energy required to heat, smelt, and reduce the chromite ore to the metallized state is supplied by electricity (Pan, 2013). FeCr production is an energy-intensive process, with a specific electricity consumption (SEC) varying from 2.4 MWh/t to more than 4.0 MWh/t FeCr produced, depending on the process applied (Pan, 2013; Neizel et al., 2013). Daavittila, Honkaniemi, and Jokinen (2004) stated that the typical operational costs of FeCr smelters can be divided into four categories, i.e. chromite ore (30%), carbonaceous reductant (20%), electricity (30%), and other production costs (20%). This makes electricity consumption the joint largest factor that influences operational costs in FeCr production."

Jan 1, 2017

By D. Tait, M. A. Halim, V. I. Lakshmanan, R. Sridhar

Rare earth elements (REEs), nickel and cobalt find their use in developing strategic materials and their demand is consistently increasing in the world while the extractable ores of these metals are gradually depleting. Process Research ORTECH Inc. (PRO) has developed innovative mixed chloride leaching processes for the recovery of REEs from alumino-silicate ores, and nickel and cobalt from laterite ores. The addition of magnesium chloride in hydrochloric acid enhances the activity of the hydrogen ion by orders of magnitude, which permit rapid leaching rates at moderate temperature and atmospheric pressure, along with high metal recovery. Innovative solvent extraction process steps are used for the separation of these metals from pregnant leach solutions. PRO’s processes also produce value added by-product of high purity iron oxide and recycle chloride lixiviant to the leaching stage. This paper describes the leaching and separation reaction mechanisms and potential process flowsheets.

Mar 1, 2017