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?Podolsky Water treatment plant discharges to Norman North bog which drains into Whistle / Post Creek watershed and into Wanapitei Lake ?Whistle Mine closed and reclaimed but continues to treat and discharge water to Whistle Creek

May 1, 2009

By R. Pandher, R. Schonewille, N. Tripathi

Advanced process modelling tools were developed for the Xstrata Nickel Sudbury Smelter flow sheet using a combination of FACTSAGE TM METSIMTM and ARENATM software. These tools were employed to assist with plant optimisation, emission control, process design, troubleshooting and case studies as applied to the smelter. The development of process modelling tools in pyro-metallurgy commonly involves an in-depth study of the therm o-chemical properties (heat capacity, liquidus temperature, etc.) of all high temperature phases, usually matte and slag. The preferred tool for this purpose is FACTSAGETM, a well-known then-no-chemical modelling software package. The results from the therm o-chemical model have been subsequently incorporated into the development of a process model for the entire smelting facility using the METSIMTM platform. Such process model also includes a number of special features adopted to effectively simulate the complex industrial phases; matte and slag systems. To ensure the robustness and reliability of the process model, several process parameters and assumptions were verified with laboratory and plant data. Consequently, the model includes the ability to examine the impact of a number of plant parameters on potential plant performance. Primary variables are the percent sulphur elimination during concentrate roasting, furnace matte grade and degree of matte metallization. Key output parameters include operating temperature, furnace coke requirement, sulphuric acid production, CO2 emissions and overall energy requirements. Selected outputs from the process model (for example blowing time, slag production rate and matte converting rate) can then be utilised in the development of a discrete event model (DEM) for the smelter using ARENATM software. Incorporation of reliable and validated mass balance parameters enhances the robustness and reliability of the DEM model. The integration of then-no-chemical, process and DEM modeling tools has a distinct advantage in planning plant trials and examining process design initiatives at Xstrata Nickel's Sudbury Smelter. The present paper discusses the development of these three models and the synergies existing among them. Typical results from all three models are also presented.

Jan 1, 2011

By R. Pandher, R. Schonewille

Advanced process modelling tools were developed for the Xstrata Nickel Sudbury Smelter flow sheet using a combination of FACTSAGETH METSIMTM and ARENATM software. These tools were employed to assist with plant optimisation, emission control, process design, troubleshooting and case studies as applied to the smelter. The development of process modelling tools in pyro-metallurgy commonly involves an in-depth study of the therm o-chemical properties (heat capacity, liquidus temperature, etc.) of all high temperature phases, usually matte and slag. The preferred tool for this purpose is FACTSAGETM, a well-known then-no-chemical modelling software package. The results from the therm o-chemical model have been subsequently incorporated into the development of a process model for the entire smelting facility using the METSIMTM platform. Such process model also includes a number of special features adopted to effectively simulate the complex industrial phases; matte and slag systems. To ensure the robustness and reliability of the process model, several process parameters and assumptions were verified with laboratory and plant data. Consequently, the model includes the ability to examine the impact of a number of plant parameters on potential plant performance. Primary variables are the percent sulphur elimination during concentrate roasting, furnace matte grade and degree of matte metallization. Key output parameters include operating temperature, furnace coke requirement, sulphuric acid production, CO2 emissions and overall energy requirements. Selected outputs from the process model (for example blowing time, slag production rate and matte converting rate) can then be utilised in the development of a discrete event model (DEM) for the smelter using ARENATM software. Incorporation of reliable and validated mass balance parameters enhances the robustness and reliability of the DEM model. The integration of then-no-chemical, process and DEM modeling tools has a distinct advantage in planning plant trials and examining process design initiatives at Xstrata Nickel's Sudbury Smelter. The present paper discusses the development of these three models and the synergies existing among them. Typical results from all three models are also presented.

Jan 1, 2011

By M. Hao, S. Hu, X. Lyu, M. Lian, C. Anning, G. Yao, Z. Wang

The results revealed that the pozzolanic activity of the gold mine tailings and their main mineral phases improved by mechanical activation. Under the same activation conditions, the activated mica powders possessed the highest pozzolanic activity index, followed by the activated feldspar, and the activated quartz exhibited the lowest pozzolanic activity index. The addition of calcium oxide promoted the formation of amorphous C–(A)–S–H gel for all paste samples, and stratlingite and hydrotalcite were observed in calcium oxide activated mica paste. The addition of natural anhydrite promoted the formation of ettringite for the pastes of calcium oxide activated aluminosilicates materials (gold mine tailings, mica, and feldspar). Furthermore, the pozzolanic activity indexes of the mechanically activated gold mine tailings and their main mineral phases were tested to be qualified for use as supplementary cementitious material in cement. This paper provided an innovative approach for recycling gold mine tailings as supplementary cementitious materials in cement, which would be environmentally friendly and cost-effective. Keywords: Mechanical activation, gold mine tailings, supplementary cementitious material, hydration properties, pozzolanic activity

Jan 1, 2020

By K. Tangri, M. Chaturvedi

The addition of 0.5 wt pct Cu to Zr-2.5 Cb alloy increases the as -quenched hardness of the hexagonal martensitic a' phase, produced by water-quenching bccß-Zr phase, by about 35 pct. This strengthening has been attributed to the solid -solution hardening of the matrix. On aging ternary martensite, a' phase reverts to equilibrium a and Zr2Cu and ß-Cb precipitate out, mainly at the twin and grain boundaries, causing a secondary hardening of the matrix. COLD-worked Zircaloy-2 pressure tubes have been in use in power reactors for a considerable period of time. The search for a better material led to the development of Zr-2.5 wt pct Cb alloy which in the quench-aged condition develops 50 pct more strength than that of cold-worked Zircaloy-2, however, its corrosion resistance in water and steam in the temperature range of 316" to 400°C, in absence of neutron flux, is inferior to that of zircaloy-2.' Work carried out by Ells et al.1 and Dalgaard2 has shown that the corrosion properties of Zr-2.5 wt pct Cb alloy can be considerably improved by the ternary addition of 0.5 wt pct Cu. This paper is concerned with the effect of 0.5 wt pct Cu on the formation of martensitic a and its aging characteristics in a Zr-2.5 wt pct Cb alloy. MATERIALS AND EXPERIMENTAL TECHNIQUES Zr-2.5 Cb-0.5 Cu (referred to as the ternary alloy) and Zr-2.5 Cb (referred to as the binary alloy) alloys, supplied by the Chalk River Nuclear Laboratories of the AECL were used. The detailed chemical analysis is given in Table I. Cold rolling and swagging with frequent intermediate anneal of 1000°C were used for the initial fabrication of the alloys. All the heat treatments were carried out after the specimens were wrapped in zirconium foils and encapsulated in silica tubes under a vacuum of 5 x 10-6 mm of Hg. For optical metallography and hardness measurements specimens were mechanically and then chemically polished in a 45 pct HNOj, 45 pct HzO, and 10 pct HF solution. Hardness was measured on a Vickers hardness tester using a 10-kg load. For each specimen at least fifteen indentations were made in order to obtain a representative value. The phase identification and structural analysis were carried out using X-rays and electron diffraction techniques. Wires of 1.5 mm diam reduced to 0.12 mm diam by chemical etching were used for making Debye-Scherrer powder patterns using Cu Ka radiation in a 114.6 mm diam camera. Carbon extraction replicas were prepared by etching the specimens, after depositing a layer of carbon on the metallographic specimen, in one part HF and thirty parts ethyl alcohol. Thin films were prepared by electropolishing heat-treated 3/4 by 1/2 by 0.005 in. thick strips using a modified Bollman-Window technique. The 10 pct perchloric acid-90 pct methyl alcohol bath was kept at -50°C and polishing was done at 5 to 10 V. The thinned specimens were washed in ethyl alcohol at -30º to -40°C and dried between filter papers. Replicas and thin films were examined in a Phillips 300 G electron microscope. For resistivity measurements thin strip specimens 0.02 by 0.3 by 10.0 cm long were used. The potential leads were spot welded to the specimens in order to maintain a fixed length for the initial and the final resistivity measurements. The resistivity was measured by a Kelvin bridge in a temperature controlled room. The temperature was maintained at 72º ±1°F and the accuracy of the resistivity measurements was 0.03 µa-cm. RESULTS As-Quenched Structures. In order to produce a homogeneous matrix to study the precipitation reaction the solution-treatments of both the alloys were carried out in the -field region. From the Zr-Cb phase diagram due to Lundin and cox3 ß/a + ß phase boundary for Zr-2.5 wt pct Cb alloy is 820°C. Ells et al.1 have reported this boundary for Zr-2.5 Cb alloy containing 1100 ppm 0 to be at 920°C. Also, the addition of 0.5 wt pct Cu reduces this temperature by 50°C. Therefore, the solution-treatments were carried out at 1000°C to ensure that the alloys were in ß-phase region. The soaking time was 1 hr and the specimens were water-quenched. The as-quenched hardness of the binary alloy was 245 Vpn whereas, that of the ternary alloy was 330 Vpn. The X-ray diffraction studies indicated that the as-quenched structure of both the alloys consists of martensitic hexagonal phase a', with a c/a ratio of 1.591, and some retained ß-Zr. The presence of a' phase was further confirmed by thin film electron microscopy. Electron micrographs of typical ß-quenched structures of the ternary and the binary alloys are shown in Figs. 1 and 2, respectively. Fig. 3 shows the diffraction pattern from an area similar to that shown in Fig. 1. Although, the as-quenched hardness of the ternary alloy is about 35 pct greater than that of the binary alloy, the structure of both the alloys seems to be the same. The matrix of both alloys is heavily twinned and shows very few dislocations. Furthermore, there is no evidence of any precipitation taking place in either of the two specimens during quenching from the solution-treatment temperature. Aging Behavior of Martensitic a'. The aging kinetics of the ternary alloy were followed by resistivity and hardness measurements. The as-quenched values

Jan 1, 1970

By E. N. Aqua, C. M. Owens

The microstructure in cold-rolled Zircaloy-4 sheet has been characterized by transmission electron microscopy and X-ray diffraction line-broadening techniques. The rate of work hardening is measured in terms of microstrains, particle sizes, micro hardness, the tensile yield strength. The tensile yield strength of Prestrained (less than 10 pet) Zircaloy-4 sheet is found to be a linear function of the square root of the dislocation density, us predicted by work-hardening theories. ZIRCALOY is one of the most important structural alloys for nuclear reactor applications.''2 In order to understand the effects of the nuclear environment on Zircaloy structural members, the preirradiation microstructure must be characterized. This report will describe the substructure existing in cold-rolled Zircaloy-4 sheet as observed by electron microscopy and by X-ray diffractometry. I) EXPERIMENTAL PROCEDURE Commercial Zircaloy-4 strip was cold-rolled and annealed in argon at 760°C for 1 hr. The annealed sheet was again cold-rolled to a maximum of 50 pct reduction in thickness with segments of the strip being retained after 2.5, 5, 10, and 20 pct reductions. One-inch-square portions were chemically polished (50 parts HNO3, 50 parts H2O, 10 parts HF) and mounted onto lucite blocks using double-sided tape to prevent bending during handling. Thin foils suitable for transmission electron microscopy were prepared from each of the sheet samples. The sheets were mechanically polished through 600-grit paper to a 3 to 4 mil thickness and were chemically polished by immersion for 1 to 2 min in a solution containing: 50 parts HNO3, 50 parts H2O, and 10 parts HF, and rinsed in distilled water. The final metallographic procedure was to electropolish for less than 10 sec with an electrolyte of 10 parts perchloric acid and 90 parts glacial acetic acid, at 20 v, at room temperature using stainless-steel point cathodes and a vigorous stirring action. These foils were examined in a Philips EM 200 electron microscope using a 100-kv accelerating voltage.

Jan 1, 1968

By E. Miller, J. M. Eldridge, K. L. Komarek

Activities of magnesium in liquid Mg-Sn alloys have been determined between 5 and 90 at. pct Sn and 990" and 1290°K by an improved isopiestic method wherein tin specimens, heated in a temperature gradient and contained in crucibles of special geometry, were equilibrated with magnesium vapor in a closed titanium system. The crucibles were designed so that the equilibrium compositions of the specimens were satisfactorily preserved on termination of the experimental runs by quenching. The activity values are in excellent agreement with those predicated on the phase diagram and allowed a delineation of the solidus curve of the compound Mg2Sn near its melting point. EQUATIONS have been recently derived relating the chemical potentials of the components to the liquidus and enthalpy data for binary systems exhibiting one congruently melting compound.' The liquidus curve of the Mg-Sn system between the eutectics was carefully redetermined and the thermodynamic properties thus calculated were in reasonably good agreement with values derived from electromotive-force measurements of an,' but differed greatly from the iso-piestically determined values of Ashtakala and Pid-geon.3 The present study was initiated: a) to resolve the discrepancies; b) to develop a method for measuring activities in systems having volatile (and possibly highly reactive) components; and c) to use the method in a general investigation of the thermodynamic properties of the homologous series of Mg-Group IVb systems, i.e., Mg-Pb, Mg-Sn, Mg-Ge, and Mg-Si. This paper describes the results for the Mg-Sn system. An isopiestic technique, originally developed by Herasymenko 4 and adapted for alloys having a component of high reactivity and low volatility,5-8 was modified in this study by using crucibles designed to preserve the equilibrium composition of highly volatile liquid specimens on quenching from high temperatures. Tin specimens, contained in tightly covered graphite crucibles and heated in a temperature gradient, were equilibrated with magnesium vapor of fixed pressure from a magnesium reservoir kept at constant temperature in a previously evacuated and sealed titanium tube. During equilibration magne-

Jan 1, 1967

By J. R. Long, C. E. Armantrout, A. H. Roberson, T. R. Graham, R. S. Dean

THE general program of the Federal Bureau of Mines on the study of alloys made with electrolytic manganese has been extended to copper-manganese-aluminum alloys. The initial results of the work are presented in this report and concern a determination of the mutual solubilities of these three metals to form the alpha solid solution. The principal studies of this system, reported in the literature, have been focused on the Heusler alloys containing 10 to 30 per cent Mn with 9 to 15 per cent Al. These investigations concern the ferromagnetic properties and the determination of the crystallization contours, with little emphasis on the phases present in the solid state outside of this area. Heusler1 recognized a breakdown of the beta solid solution of the magnetic alloy, which he says decomposes into the alpha, beta, and gamma phases of the copper-aluminum system, somewhat modified by the presence of manganese. Rosenhain and Lantsberry2 examined alloys ranging up to 10 per cent Mn and io per cent Al but were unable to reach definite conclusions concerning the phase boundaries in that area. Krings and Ostmann3 made magnetic studies and examined the system by thermal analysis. They present contours of the liquidus surface but do not place any of the phase boundaries. Corson4 [ ] has drawn a hypothetical boundary for the alpha field with few data to support such construction. The binary systems involved have received considerable attention by numerous investigators, and their general features are well established. The hopper-aluminum system (Fig, I) has been thoroughly examined by Stockdale,5 who places the limit of solubility of aluminum in copper at 7.4 per cent at the liquidus and 9.5 per cent at room temperature. Smiths established the eutectoid temperature at 570°C. by a study of isothermal decomposition of the beta phase. The copper-manganese system (Fig. 2) has been recently reviewed by Dean and co-workers.7 Using high-purity alloys, they place the solubility of alpha man-

Jan 1, 1946

By Juan Carlos Zevallos

Ante un escenario incierto y de gran tensión como consecuencia de la pandemia del COVID-19, el sector minero peruano ha venido desarrollando tareas sociales fundamentales y comprometiendo grandes esfuerzos en ayuda económica, operativa y logística. Las acciones descritas en este artículo demuestran que en los últimos años las empresas mineras en el Perú han dado un salto importante en la dinámica de su relación con el entorno, la comunidad y el Estado, lo que ha facilitado coordinar aportes y establecer sinergias.

Aug 30, 2020

By R. L. Grayson, W. E. Wallace, M. D. Attfield, A. Q. Wearden, P. Bolsaitis, R. D. Kennedy, M. J. Keane, J. C. Harrison

"Respirable high-silica particles from four coal mines. a clay mine and a tunnelling site were analysed for silicon vs aluminum composition by performing scanning electron microscopy-energy dispersive X-ray analysis (SEM-EDS) at electron accelerating voltages of 20 kiloelectron volts (keV). The same particles were analysed at 5 keV to determine possible differences in surface vs bulk composition. In some cases high-silica particles exhibited a decrease in the ratio of silicon to aluminium K-alpha line intensities with decreasing electron beam accelerating voltage. This behaviour is consistent with aluminosilicate surface contamination or occlusion of a silica particle. Some 20 high-silica particles were analysed from each of 10 samples. Powdered aluminosilicate glass was used as a control for the behaviour of silica with a homogeneous distribution of aluminium in the particle. Significant differences were found between the control and sample means for an Illinois bituminous coal mine dust, two western and one central Pennsylvania bituminous coal mine dust low-temperature ashes. and a clay mine and mill dust sample, but not for an anthracite coal mine dust and two central Pennsylvania bituminous coal mine dust low-temperature ashes. INTRODUCTIONRESPIRABLE dust quartz content commonly is measured on bulk samples by using i.r. spectroscopy or X-ray diffraction. For research purposes, individual particle-by particle SEM-EDS analysis at 20-30 keV electron beam accelerating potential may be used also. Such measurements have not provided an unambiguous association of quartz content with occupational pulmonary disease prevalence in exposed workers (WALTON et al., 1977). Rather, there is evidence that coal rank modifies the relationship between dust exposure and pneumoconiosis development (WAL TON et al., 1977; ROBOCK and BAUER, 1990; ATTFIELD and MORRING, in press). SEM-EDS analysis was performed to measure the silicon fraction, Si/(Si +Ai), at 20 and at 5 keV on high-silica particles to determine if some respirable quartz particles generated by mining exhibit heterogenous composition with depth (WALLACE et al., 1990), which might affect the bioavailability of the quartz surface."

Dec 1, 1995

The Annual General Meeting of the Institute was held in Kelvin House, Johannesburg, on Wednesday, August 14th, 1974. Mr P. W. J. van Rensburg (President) was in the Chair. There were present 56 Fellows, 21 Members, 2 Graduates, 5 Associates, 16 Students, and 58 Visitors, making a total of 158. The President declared the Meeting open at 4.08 p.m. OBITUARIES The President: Ladies and gentlemen, before we start the business of the meeting, it is my sad duty to announce the deaths of the following members of the Institute since our last meeting: Dr O. A. E. Jackson, Honorary Life Fellow and Past President; C. Airth, T. L. Blunt, A. E. Frazer, C. L. Lamb, and K. Richardson, Life Fellows; and J. T. Beaumont, Fellow. As you know, there were a number of other deaths during the year, which were reported at previous General Meetings of the Institute. As a mark of respect to the memory of the deceased, and in sympathy with the bereaved, I ask you to rise and observe a few moments' silence. MINUTES The President: Ladies and gentlemen, the next item on your agenda is confirmation of the minutes of the General Meeting and Special General Meeting held on May 22nd, 1974. These will be published in the August issue of the Journal, and, since you have not yet received this, I must ask that they be held over to the next General Meeting. WELCOME The President: It is a very pleasant duty for me to welcome many members of our Institute and our guests, among whom we are particularly pleased to see the President of the Chamber of Mines, Mr Dolf Schumann, who is also Honorary President of this Institute. Mr Schumann, we are extremely pleased to have you with us today. And, we welcome an old friend of ours, Mr Dillon, Minister of Mines in Rhodesia, who has come down for our Annual General Meeting. Mr Dillon, we are very, very pleased to see you here this evening, and we look forward to seeing Mrs Dillon a little later. And we have with us, too, the presidents or representatives of many of our sister and brother associations, institutes, and societies. In particular, we welcome Mr Mike Gericke, President of the South African Council of Professional Engineers, and Professor Midgley, President of A. S. and T. S. We are also pleased to welcome the Presidents of the Mechanical Engineers, Electrical Engineers, Certificated Mechanical and Electrical Engineers, the Civil Engineers, the Joint Council of Scientific Societies, the Mine Ventilation Society, the South African Association of Consulting Engineers, the Association of Mine Managers, the Institute of Foundrymen, the Institute of Welding, the Federation of Societies of Professional Engineers, Mine Surveyors, Production Engineers (London), and the Institute of Production Engineering. We are very glad, too, to have with us a visitor from England, Professor Raynor and Mrs Raynor. Professor Raynor is Professor of Metallurgy at Birmingham University, and a very well-known metallurgist in Britain. We also have with us the Chairman of the Ferro-Alloys Association. We are expecting the Chairman of our Witbank/Middelburg Branch, the Chairman of the Engineers' Liaison Committee, Pretoria, the Director of the Witwatersrand College of Technical Education, and, of course, our old friend, Mr Eric Boden, the Manager of A.S. and T.S. It is a very great pleasure to have with us a number of persons who will receive honorary Life Fellowship at this meeting, and there are some Gold Medal winners and winners of our Student Prizes. We have apologies from a number of people who are away on business, and unfortunately some are ill. But we are extremely pleased to see those of you who are here, and we are also very pleased to see so many ladies. We expect to see many more of them later this evening, at our Cocktail Party. MEMBERSHIP The President: I have pleasure in announcing that, their names having been published in accordance with By-Law 5.2.2., the following have been elected by Council to membership in the following grades Fellows: B. Collins, D. W. Dixon, J. P. Dreyer, A. T. Hudson, and W. W. Pearce. Members: A. T. Fisher and I. F. Nagy. Associate Members : P. D. de Bruyn and H. C. Iverson. Graduates: D. P. O'Shaugnessy and M. F. Sadler. Associates: R. J. Bushell and A. MacDonald. Students : I. J. Barker, P. J. Charter, J. P. de Witt, G. S. Esterhuizen, N. Green, P. M. Jenner, M. J. R. Meyer, A. P. Nicol, W. J. C. Pothas, B. J. Robbetze, N. T. Sutherland, B. A. Statham, C. R. Thomas, N. C. Webb, M. Salamon, R. G. Jurd, and M. McChesney. Transfers to other grades of membership include the following: Member to Fellow: B. W. Holtzhousen. Graduate to Member: T. S. Schultz. Associate to Associate Member: C. L. Jordaan, H. J. L. Tomlinson, J. E. Forbes, G. H. S. Bamford, T. F. Carswell, J. W. Breidenhann, J. R. Garbutt, and L. S. Gibbs. Student to Graduate: C. J. Faueonnier and B. Lund. Student to Associate : G. P. Gooding. We welcome these new members

Jan 10, 1974

Henry C. Carlisle: This is a husband-and-wife act, in which Mary Carlisle is going to listen, and break in as often as she feels like it. I am going to describe my career as a mining engineer. We are at Nantucket, in the 75 Main St. house; The year is 1959. Q: This is something the boys and I have wanted you to do for a long time. Carlisle: After leaving Columbia in 1910, I arrived at Ray, Ariz., January 1, 1911, and rustled a job from Louis Cates, Ralph Nowland and Sprott Boyd, who were running the Ray mine. I went to work as a surveyor's helper, made $90 a month, and paid $35 a month board. I lived in a dormitory where about 25 other engineers, graduates from different colleges, were living. It was very social and you made a lot of young friends early in the game. I did not think much of the idea of being a surveyor, or even a surveyors, helper; the higher-up surveyors only got $125 a month, and had been there quite a long time. So, I asked to be changed to underground sampling, where I would see the mine faces every day and learn more about mining. In about three months, I became an underground sampler and remained at this for a year, but in three months I was promoted to head sampler, with six people under me.

Jan 10, 1963

By Allen D. Graham

The coal industry in South Africa is briefly outlined. Test- work carried out on bulk samples of coal in the laboratory and used in the design of the Van Dyks Drift washery are described. Factors affecting the selection of equipment and the designed capacity of the plant are discussed. A description of the crushing plant, washery and load out section is given together with performance data obtained in the final acceptance tests. New features incorporated in the Van Dyks Drift plant and in more recent plants of the Group are outlined.

Jan 1, 1982

By Jr. Schnakenberg

The automation (robotization) of coal mining activities at the face offers improvements in worker safety and productivity. The evolutionary introduction of autonomous, intelligent robotic machines to perform the most hazardous tasks may become a reality within the next 10 years. The U.S. Bureau of Mines Robotics and Automation research program is aggressively pursuing the development of the enabling technology necessary to achieve this goal. This program consists of both core and applications research, each focused on the fundamental issues of robotic technology. In the short term, the research is directed specifically to the robotization of present-day underground equipment and is being performed in a manner that can make incremental improvements in safety and productivity. The long-term goal is the development of intelligent autonomous mining systems.

Jan 1, 1990

By M. B. Kime, A. T. Kaniki

"Grinding tests were conducted on an oxidized copper-cobalt ore using a pear-shaped ball mill. Twelve mono-sized ore fractions were prepared and wet ground batchwise. The mill was run for 0.5 to 30 min intervals. The shortest interval provided data more closely related to the breakage function (B) because less secondary breakage was hypothesized. Some selection function (S) and B parameters were determined. Remaining parameters were estimated using a population balance model simulator. To evaluate the kinetics model, an unsized ore sample was also milled. Predicted and measured particle size distributions (PSDs) agreed well, suggesting that S and B parameters can be used for continuous operation mass balances.RÉSUMÉ Des essais de broyage ont été menés sur un minerai oxydé de cuivre-cobalt à l’aide d’un broyeur à boulets piriforme. Douze fractions de minerai de dimension unique ont été préparés et broyés en voie humide en lots. Le broyeur était mis en route à des intervalles de 0,5 à 30 minutes. L’intervalle le plus court fournissait des données plus étroitement liées à la fonction d’abattage (B) car d’après l’hypothèse avancée, le besoin d’abattage secondaire était moindre. Certains paramètres de la fonction de sélection (S) et de B ont été déterminés ; les paramètres restants ont été estimés à l’aide d’un simulateur de modèle d’équilibre de population. Pour évaluer le modèle de cinétique, un échantillon de minerai non calibré a également été broyé. Les compositions granulométriques (PSD, de l’anglais particle size distributions) prévues et mesurées correspondaient bien, ce qui laisse penser que l’on peut se servir des paramètres S et B dans le cadre d’équilibrages massiques en fonctionnement continu. INTRODUCTIONSize reduction of solids is a very energy intensive and highly inefficient process. It consumes approximately 5% of the electricity produced worldwide (Rhodes, 1998), and more than 50% of the total energy used in mineral processing plants (Walkiewicz, Lindroth, & Clark, 1996). An increase in grinding efficiency can therefore result in significant reductions in operating costs. This often amounts to determining the optimal design configurations for milling an ore sample in a laboratory mill under standard conditions. Prior to optimizing the milling stage, the requirements for downstream processing in terms of particle size distribution (PSD) need to be understood because low liberation and overgrinding will lead to future problems. Once this is done, it is also important to clearly understand the breakage properties of the ore. The kinetics of size reduction in tumbling mills are often determined using two probabilistic functions: selection and breakage (Austin & Luckie, 1972). Knowledge of the selection and breakage functions also enables the prediction of the PSD for a given ore sample."

Jan 1, 2017

Discussion WEDNESDAY AFTERNOON, FEBRUARY 21, 1951 Ralph E. Grim presiding R. E. GRIM, CHAIRMAN-Has anyone a particularly fruitful point to make or question to ask on any of the papers that have been presented at the two sessions held on Monday and one held this morning? GENESIS OF ENDELLITE T. S. LOVERING-I think we are all a little bit embarrassed when we are asked if we have any particularly fruitful point for discussion; I just have a point. I believe that yesterday Bates said that he had found endellite in only hydrothermally altered rocks-he did not find it in sedimentary rocks-but this morning I heard Victor Allen say something about it as the normal product of weathering, and I am confused. My question concerns the genesis of endellite. I want to know whether endellite is found as a normal product of weathering. I understood from the paper by Bates that it was not a product of weathering and in the paper by Victor Allen* endellite was said to be a product of normal weathering. Did I misinterpret these two papers? T. F. BATES-I did not intend to state or imply that endellite is formed only under hydrothermal conditions. We have been studying the North Carolina deposits extensively and I feel that they illustrate very well the result of normal weathering processes acting on pegmatitic material. The resulting clay seems to be largely endellite or halloysite, almost to the exclusion of kaolinite. I may have misled you in the statement I made toward the end of my talk, to the effect that of all the kaolinic clays we have investigated with the electron microscope, we have not yet found halloysite or endellite in samples from clay deposits that are definitely sedimentary in origin. R. E. GRIM, CHAIRMAN-Professor Allen, have you anything to say on the matter of bauxite?

Jan 1, 1952

By C. R. Sandberg, L. S. Gournay, R. F. Sippel

The effect of fluid-flow rate and fluid viscosity on oil-water relative permeability determinations was studied using the "dynamic flow technique." In this work relative per-nleability curves were obtained for homogeneous small core .samples from several sandstorle outcrop form-utions. Radio-tracers were used for the determination of fluid saturation and for the detection of saturation gradients. Cobalt-60 in the form of cobaltous chloride was used as a water-phase tracer in some of the experiments. Iodine-131 in the form of iodobenzene and Mercury-20-3 in the form of mercury diphenyl were used as oil-phase tracers in other experiments. Flow rates for each phase were varied within a range of 2.5 to 140.6 ml/hr. Oil-phase vis-cosities under flowing condition,> were varied from 0.398 to 1.683 cp. The relative permbilities ob-tained were found to he solely a function of saturation and independent of flow rare, provided there was no .Saturation gradient induced in the core sample by "boundary effect." Even though equilibrium with re-sped to flowing conditions was obtained at the lower flow rates, where a saturation gradient exists, this equilibrium is of a "contingent"-type rather than the "steady-state" equi-librium implicit in the relative per-meability concept. The only effect of increasing the oil or non-wetting phase viscosity was to decrease the flow rate required for the elimina-tion of the boundary effect. Fairly good agreement between experimentally determined and calculated values of the boundary effect was obtained when the non-wet-ring oil phase was the only Flowing phase. INTRODUCTION In the characterization of reservoir rock, as well as in the solution of reservoir production problems, it is most desirable to have reliablc rela-tive permeability measurements for the rock and fluids of interest. Many techniques have been developed for the laboratory determination of the relative permeability of both large and small core samples. In varying degree, difficulties attend the use of all of the methods. Each of the methods requires the metered flow of fluids of known viscosity through the core sample under conditions wherein the pressure drop in the individual flowing phases can be measured or closely approximated. Since the relative permeability is a function of the saturation and distribution of the flowing fluids, some means of obtaining such information is also required. The laboratory determination of the relative permeability of a sample should give the same relative permeability saturation relationship that would exist if the sample were in place in the oil reservoir. The attainment of this objective is complicated by the fact that the use of small core samples for laboratory measurements is usually necessary. As a result, errors in measuring the relative permeability arise from boundary effects at either the fluid input or output ends of the sample; no significant boundary effect is anticipated at the sides of the sample normal to direction of fluid flow. At the input end of the sample a boundary effect exists if the flow fluids are not com- mingled as they would be in the reservoir. At the output end of the sample a boundary effect exists as a result of discontinuity of the capillary properties of the system. Here the flowing fluids leave the small flow channels and enter a collecting system having much enlarged flow channels. Thus, there is a tendency for the wetting phase to be retained by the core sample because of the attraction of the core sample for the wetting fluid. No reference is made to these boundary effects in either Darcy's equation or in the relative permeability concept. As a consequence the saturation effect peculiar to the input end of the core sample may cause an error in the effective permeability measurement, since some portion of the core sample must be utilized for commingling of the flow fluids. At the output portion of the core sample a saturation gradient or a saturation change along the axis of flow results. Since relative permeability is a function of fluid saturation, this saturation gradient may cause a variable permeability measurement, especially since extent and character of the saturation gradient can vary with fluid-flow rate. The most convenient method of minimizing the boundary effect, especially at the output end of the sample, is to flow the fluids of interest through the core sample at such high rates that the capillary forces arc insignificant as compared to the viscous forces involved in the fluid flow. Since recent work of a preliminary nature has indicated that fluid dispersion in the porous medium increases with the flow rate, the high flow minimizes the boundary effect at the input end of the core sample by enhancing the mixing of the fluids.

By H. H. Bleakney

THIS paper presents evidence that in 3 1/2% nickel steel, the published temperature for the Ac1 transformation, l,275°F., represents the completion of that transformation, and that its inception occurs approximately 275°F. lower, at about l,000°F. The formation of austenite within this range, especially at the higher temperatures, and its subsequent decomposition to martensite, results in considerable impairment of the properties of the steel. That the solid solution found to occur below l,275°F. is austenite has been questioned, but the evidence herewith presented, while not decisive, appears to be reasonably convincing. INTRODUCTION The February, 1939, issue of Metals Technology contains a very interesting paper by I. N. Zavarine, Associate Professor of Metallurgical Engineering at the Massachusetts Institute of Technology. In that paper, Professor Zavarine presented photomicrographs illustrative of the microstructures produced by heating nickel steels to a temperature slightly below the carbon change point, and holding them at that temperature for various lengths of time. His illustrations show that the structures found after such treatment do not consist merely of ferrite and carbides, but are characterized by the presence of a third phase, which he describes as a' 'sub-critical solid solution'. The occurrence of this third phase in increasing amounts is accompanied by an increase in strength and a loss of ductility and impairment of elastic ratio of the steel. Some years ago, one of the authors encountered the above-mentioned phenomenon in treating large forgings of 3.5% nickel steel. After normalizing and then drawing at l,250°F., very poor mechanical properties were obtained. Investigation of the steel disclosed no inferiority in quality. Eventually, after considerable waste of time and money, a draw temperature of l,150°F. was tried. This treatment resulted in a very great increase in elastic ratio, over 5 per cent increase in percentage elongation, and proportionate improvement in reduction of area.

Jan 1, 1941

By G. Fazel Jahromi

Enargite, known as one of the major arsenic containing copper minerals, with approximately 19% arsenic, introduces challenges to typical processing options. In most hydrometallurgical processing methods, arsenic remediation occurs after the copper recovery in an autoclave or in a stepwise neutralization process. In this study, the in situ precipitation of scorodite was investigated during an atmospheric leaching process in the presence of carbon-based catalysts and chloride media. The effective parameters of initial ferric addition, temperature, catalyst addition, and oxygen sparging rate were studied and the ferric behaviour was monitored during the scorodite precipitation. The most influential parameters on efficient scorodite precipitation are found to be: initial ferric addition, catalyst to concentrate ratio, and temperature. A 99% scorodite precipitation yield was achieved in this process.

By Z. Hajnal

Three years ago a research program was initiated at the University of Saskatchewan to develop seismic surveying techniques for use in the Precambrian geological environment. The success of the reflection method in many younger geological settings suggested that this is the technique which would be the most suitable for experimentation. A successful adaptation of this technique to the Shield environment would make mapping of rock formations possible to much greater depth than is possible at the present time with any other applied geophysical technique. This presentation attempts to illustrate the advances which have been made in this program and will provide some insight into future plans. The field investigations were limited to the Flin Flon basin near to the town of Flin Flon, Manitoba (Fig. 1). This area was chosen because the surface geology has been mapped in great detail and it is a very important base metal producing region. It is an ancient sedimentary basin with some characteristics similar to areas where the reflection method has been successful.

Jan 1, 1976