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By B. A. Rogers

The problem of obtaining enough manganese for use in the manufacture of steel appears likely to recur when international relationships are disturbed and to become serious at any time when the United States is cut off from its customary supply. Some idea of the problems that an e under war conditions may be obtained from a description given by Ellicott3/ in 1918 before the American Iron and Steel Institute. This condition arises because in normal times there is an economic advantage in importing available high-grade foreign ores to the neglect of our own less satisfactory resources. That considerable low-grade manganese ore and a much smaller amount of high-grade material are available in this country is well known from geological surveys 4/ and has been confirmed by Bureau of Mines investigations. Locations of the various deposits are indicated in figure 1. The possibility of greatly expanding domestic production was actually demonstrated from 1913 to 1918, when the annual production of manganese from domestic ores rose from about 4 percent to approximately 35 percent 6/7/ of the total consumption of ferromanganese and spiegeleisen. In idea of how domestic production compares with total consumption in the United States can be obtained 1 from figure 2, taken from the Minerals Yearbook8/ for 1970. Assuming that it is possible to increase production of manganese ores sufficiently to supply all our needs, such a program presumably would require 2 or 3 years, and the cost of production would certainly rice considerably, for some time at least. For

Jan 1, 1941

By G. Marchand, R. H. Hay, E. C. Pearson

"AbstractA polishing .technique is described together with two anodic etching methods for aluminum and its alloys. Some of the optical and structural characteristics of the film formed by •these etching methods are discussed and it is shown to what degree these properties of the film are related to the crystallographic orientation of the metallic substrate. Applications to the study of recrystallization and twinning phenomena and to the study of plastic deformation, banding, and texture estimation are discussed. Micrographs are shown .to illustrate the manner in which the technique is particularly well suited to the study of such phenomena.IntroductionThe physical metallurgist is constantly faced with the problem of polishing and etching of metallic sections. Mechanical polishing is tedious, time consuming, and not applicable whenever a surface entirely free from plastic deformation is required. Etchants are generally required to reveal the grain structure in order to determine its size, shape, and regularity, or to bring up constituents. In the case of aluminum, the .most common etchant to reveal grains is a mixture of three acids: HC1, HN03, and HF. This etchant is fairly satisfactory on certain alloys and for certain metallurgical conditions but in general fails to give a good definition of the grain on castings, on highly alloyed products, and whenever the grain is smaller than 100 microns in diameter. Besides size and shape, a grain, or crystal, has an orientation and may be endowed with several types of imperfections."

Jan 1, 1952

By Juan Francisco Mori, Miguel Ángel Aucapoma, Pablo Zevallos

En este artículo se describe el prototipo de un equipamiento instrumentado digital cuya función es monitorear la condición de los techos de los socavones para evitar que se produzcan accidentes por desprendimientos generados por el debilitamiento de las estructuras que sostienen los techos, debido al corrimiento de las estructuras del macizo rocoso. Básicamente el sistema informa mediante la activación de alarmas pre-configuradas al interior de mina, con el propósito de prevenir y evacuar al personal.

Apr 30, 2020

By R. J. Reynik

A semiempirial small flunctation theory of diff- sion in liquids is presented, which employs a fluctuation energy assumed quadratic for a small atomic or molecular displacement and Einstein's random-iralh model. The resulting diffusion equation is given by In these equations. D is the diffusivity, is the average liquid shite coordination number (at interatomic distance d. cm. T is the absolute temperature, xu. em, is (the diffusive displacement. K, is the quadratic fluctuation energy force constant, and rg, cm, are the radii oj diffusing atoms A and B, respectively. The quantities Xn and K are calculated from the computer-filled values of the slope and intercept. respectively. The radius of self-diffusing atom or radii and of diffusing atoms A and B are eta United and compared with values reported in the literature.. The predicted linear variation of diffusivity with. It tempera lure htm been observed in approximately thirty-iire metallic liquid systems, and in over seventy-fiee other liquid systems, including the organic .alcohols, liquified inert gases, and the molten salts, ALTHOUGH the average density within a macroscopic volume element of liquid is constant for fixed total number of atoms. pressure. and temperature, there exist microscopic: density fluctuations within the respective volume element. As such the microscopic volume available to an atom and its Z first nearest neighbors at any instant of time fluctuates above and below the average volume available to these atoms. If one assumes that liquid state atoms vibrate as in a solid. and further postulates that the mean position of any atom in the liquid state is not stationary. but shifts during every .vibration a distance 0 5 j 5 xo. then every atom in the liquid state continuously undergoes diffusive displacements which vary in the range 0 5 j 5 ro. Mathematically. for a binary liquid system consisting of atcrms A and B. the maximum diffusive displacement. .YO, is defined by the equation: where d is the average liquid state interatomic distance at specified liquid state coordination number Z. and v~ \ and vg are the effective radii of diffusing atoms A and B: respectively. For self-diffusion. r^ equals rg , and Eq. [I.] reduces to: It is interesting to note that Eq. [l] or [2] can be used to compute the radii of the diffusing atoms, provided one had an experimental evaluation of xo. As such. the computed radii could be compared with metallic or crystallographic ionic radii to ascerlain the electronic character of the diffusing atoms. Thus it is proposed that in the liquid state the n~otion of an atom relative to its original equilibrium position of oscillation represents the thermal vibration of any atom and its Z first nearest neighbors. while the small and variable displacements. 0 5 1 5 xc,. of the centers of oscillation represent the complex diffusive motions of the atoms at constant temperature and pressure. This is consistent with data obtained from slow neutron scattering by liquids1 ' and resembles an itinerant oscillator model of the liquid state.'" It is further postulated that the atomic displacements characterizing the liquid state diffusion process are essentially a random-walk process. As such. it nlay be described by Einstein's equation:' where D is the diffusivity. sq cm sec-'. j2 is the mean square value of the diffusive displacement. and i> is the frequency of density fluctuations giving rise to diffusion. FORMULATION OF DIFFUSION EQUATION The effective spherical volume occupied by an atom, as a consequence of a microscopic density fluctuation which enlarges the volume available to any atom, exceeds its average liquid state atomic volume by an amount: where AV is the enlarged spherical volume, v is the radius of the diffusing atom. and j is the elementary displacement distance from the original center of oscillation of the vibrating atom to a new center of oscillation position. For small atomic displacements. where c is a constant whose value depends upon the assumed geometry of the enlarged volume. For a spherical increase in volume, c equals 4nr2. Following the treatment of Furthl' and ~walin." assuming the enlarged volu~nes AL7 for the diffusing atoms are distributed in a continuunl. the probability of finding a fluctuation in the size range 0 5 j 5 xo defined by Where c includes the geometric constant cl and Eij) is the fluctuation energy causing the volume change. But the proposed model assumes all the Z first nearest-neighbor atoms are centers of oscillation. and hence the probability that any of these atoms is adjacent to a fluctuation of magnitude 05j5xo is unity. Thus:

Jan 1, 1970

By F. N. Kissell

The applicability of the "direct method" for determining the methane content of virgin coalbeds was tested. Preliminary results indicate that the direct method, when applied to exploration cores, can be successfully used to estimate coalbed gas content and also approximately predict the total gas emission from a prospective mine located in the coalbed at the exploration site.

Jan 1, 1973

By Gary Raymond

The Similkameen Division of Newmont Mines Limited operates a low-grade open-pit copper mine in southern British Columbia. The copper mineralization is extremely erratic.As a result, over seven years of operation, ore control methods have evolved from standard flagging based on blast-hole assays, through an in-pit grab sampling system, to the present method of mining to computer-determined ore-waste boundaries based on geostatistics. These improved ore control methods have resulted in a gain of at least 25% on ore tonnage miffed, at the same grade as obtained using earlier techniques. At the same time, geostatistical ore reserve estimates are now within 7% of milled ore tonnage and grade on a yearly basis, whereas the original polygon ore reserves under-estimated mineable ore tonnage by 15% to 45% and over-estimated grade by about 20%. The author discusses why traditional ore estimation methods give poor results in erratically mineralized orebodies and describes the geostatistical approach to the problem.

Jan 1, 1979

By T. G. Rozgonyi

The basic goal of this investigation was to determine the degree of drying of high moisture lignite through the use of high temperature and pressure steam autoclaves. Specific items studied were: a) the effect of lignite particle size, b) steam temperature and pressure required, and c) the time of ahydration. Although removal of sodium, ash, sulfur and other ash-forming minerals was not the goal of this study, basic analysis of effluent water showed organic material and alkalai metal content. Removal of inherent moisture from run-of-mine lignite was tested by lock-feeding the lignite, which was previously sized by screening into 25 kg autoclaves. High pressure, up to 4.053 MPa (588 psi), saturated steam was then introduced into the pressure reactor. Reaction time, pressure, temperature, and depressurization rates were strictly controlled for each reactor test run. Results indicate that about 80% of lignite total moisture was removed, including some of the inherent moisture, yielding a non-oxidized, and thus stable, lignite product. As stated, a side benefit occurred as some reduction of non-combustible portions of the lignite also took place. The conclusion reached as a result of the tests is that the steam-drying process can be successfully applied to reducing moisture in lignite, and may be considered for additional studies on acceleration of the coalification process. On the basis of the data presented, the author believes that lignite can be economically upgraded in steam autoclaves by simultaneously reducing the moisture content by 80 percent and the sulfur content by at least 50 percent. Upgrading the lignite by this method will result in large energy and financial savings.

Jan 1, 1984

By Lightfoot. Nicholas, Na Liu

"Mining in multi-seam workings has been undertaken for many years in the VK Remnant pillars above and/or below current working areas have an important influence on retreat gateroad conditions at five of the remaining six deep coal mines. These interaction effects need lo be predicted ahead of mining so that longwall panels can be positioned to minimize roadway damage and to identify areas where additional support should be installed early into competent strata when and where it is most effective.Currently, three-dimensional elastic stress analysis using MAP3D is undertaken to predict local vertical and horizontal stress magnitudes during gateroad development and in front of the face on retreat. The predicted stress fields are often used as input to FLAC for roadway modelling.Using Maltby Colliery in South Yorkshire as a case study, this paper illustrates the MAP3D approach, together with its current limitations and uncertainties. Possible future improvements in the analysis method are proposed and the authors would welcome comments on these, or suggestions for alternative approaches.MODELLING OF MULTl-SEAM LAYOUT & MULTI-SEAM INTERACTIONThe remaining large coal mines in the UK arc operating at depths of 800-1, 150 m (2,625-3,773 ft). Production panels are now mined on retreat after the accompanying single entry access roadways have been completed. These gateroads are typically supported with a system of steel rock bolts and cable in the roof and steel bolts and glass re in forced polymer (G RP) dowels in the sidewalls.In addition to new panels being mined in the vicinity of old goafed districts, a significant amount of extraction has usually already taken place in coal seams above and/or below the current working areas. This means that there is also interaction between the current workings and the remnants of the old workings in other seams. As a consequence of the mining methods employed, old workings can have a complex geometry compri ing collapsed and partially collapsed excavations intersper ed with small and large pillars of unmined coal. The unmined coal pillar act as stress concentrators that carry the overburden load while the mined out excavations create stress shadows of varying degrees depending on how much collap e and reconsolidat ion has occurred. This is illustrated by a simple elastic model as shown in Figure I."

Jan 1, 2010

By L. B. Rothfeld

This paper presents preliminary results of a Bureau of Mines study of potential costs of compliance with the federal Resource Conservation and Recovery Act for copper heap and dump leaching. Specifically, estimates are given for the cost of compliance with possible technology standards that would require the use of liners and closure caps regardless of terrain and underlying geology and hydrology. This cost is compared to the co lit of compliance with present state requirements for terrain a typical of those found at existing copper leach sites in the Southwestern U.S.A. Incremental compliance costs are found to widely exceed screening criteria used by the Environmental Protection Agency to denote significant economic impact.

Jan 1, 1993

By T. Y. Yan

A method has been developed to remove calcite from the leaching circuit in the uranium in situ leaching system. The process involves injecting the leachate and a pH control agent tangentially into an inverted cone reactor containing calcite seed catalyst. The leachate can be treated at high throughput to obtain clear effluent containing 5 ppm or lower Ca. Both lime and ammonia are effective pH control agents and consumed according to stoichiometry.

Jan 1, 1983

By R. C. Moe

Pelletizing studies were conducted to find ways of improving the metallurgical properties of acid and fluxed pellets. In acid pellets, melting temperature was controlled by the formation of low melting temperature fayalite during reduction. Formation of a permeable metallic shell during reduction allows diffusion of reducing gas to the pellet core, decreasing fayalite formation. With fluxed pellets, slag chemistry had the main influence on metallurgical properties. Mineralogical, chemical and structural transformations that occur during reduction were studied at various intervals for a number of Mesabi Range pellet types. Six pellet types were selected for further investigation based on significant differences in softening/melting characteristics. Retention of porosity in the metallic shell was found to be the overriding factor in determining softening/melting behavior.

Jan 1, 1990

THE metal iron has physical and chemical properties which are somewhat different from those of steels, but a knowledge of the pure metal is a useful starting point in studying the behavior of steels. Solid iron exists in two different crystalline forms, called alpha (a) and gamma (?) iron, the former being the ordinary form at room temperature. When heated above the "A2 point," 1400°F. (760°C.), the metal becomes non-magnetic, and at the "As point," 1670°F. (910°C.), it undergoes a change in crystalline form to become gamma iron. In the range 1400 to 1670°F., it is sometimes called beta (0) iron to distinguish it from the magnetic alpha, but the two are identical in crystal structure. When gamma iron is further heated to 2550°F. (1400°C.), it changes into delta (d) iron, which is identical with beta or non-magnetic alpha iron. Pure iron melts (in a hydrogen atmosphere) at 2795°F. (1535°C.); the melting point is generally lowered by alloys or impurities. PROPERTIES OF IRON AT HIGH TEMPERATURES Many of the properties of iron undergo abrupt changes at the transition temperatures. (1) For example, in heating through the As point a sudden shrinkage in volume occurs. Similarly, melting is attended by sharp physical changes such as an increase in volume. Table 27 contains a summary of the measured physical properties of pure iron at several temperatures. Usually the properties change smoothly within the range of stability of a given form, but this is not always the case. For example, the specific heat reaches a sharp maximum at the A2 point although no transformation occurs. Solvent Powers of Liquid Iron. Liquid iron is capable of dissolving most of the other metals and many nonmetallic elements as well. Of the metals which are liquid at the melting point of iron only lead, silver, and bismuth refuse to dissolve to an appreciable extent. The non-metals presumably dissolve by virtue of the formation of an iron compound; for example, sulphur is thought to dissolve as the compound FeS. However, there is no satisfactory method of proving that this

Jan 1, 1944

By E A. G Marques, P M. Dight, T A. V Costa, K Mercer

Brazilian banded iron formation (BIF), known as ‘itabirite’, is the main host rock for iron ore in the Iron Quadrangle mines, Brazil. Their geneses are controversial and it is agreed that diagenetic, metamorphic and tectonic events, as well as weathering processes, were responsible for the iron concentration. In addition, it is understood that weathering processes are mainly responsible for reducing the original high intact rock strength, and for generating deep weathered profiles with low strength rocks commonly observed in Vale’s mines.A considerable amount of work has been done to correlate the macro and micro aspects of the itabirites as physical, chemical and geotechnical characteristics that directly or indirectly affect the intact rock strength; however, it is not yet clearly understood what effects the weathering processes have on the strength reduction of these rocks and its associated impact on pit slope stability. This forms a key focus of the lead author’s current research work.This paper presents a review of the geological, geotechnical and weathering characteristics of the itabirites, and early results for the evaluations of fresh itabirites from the PhD thesis research being undertaken by the authors at the Australian Centre for Geomechanics, School of Civil, Environmental and Mining Engineering, The University of Western Australia, sponsored by Vale SA.The results showed that to evaluate the density and unconfined compressive strength (UCS) correlation, not only the porosity but also the geological features should be considered, as they are responsible for data dispersion; however, the presented data suggested a trend that provides the confidence to develop advanced studies and a data population increment to establish proper correlations to support a reliable UCS method.CITATION:Costa, T A V, Dight, P M, Mercer, K and Marques, E A G, 2015. An overview of the weathering process, preliminary density and unconfined compressive strength correlations for fresh itabirites in vale mines on the western side of the Iron Quadrangle, Brazil, in Proceedings Iron Ore 2015, pp 241–254 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By A. W. Fletcher

A nickel-copper sulphide concentrate was treated in a pilot plant at Warren Spring Laboratory during 1961, by a hydrometallurgical roast-leach- solvent extraction process devised to cleanly separate the metal values, and produce acid sulphate liquors containing the metals. It is shown that 86 percent of the nickel and 95 percent of the copper could be leached from the calcine, after a sulphatizing roast on finely ground flotation concentrate. Iron was removed from the leach liquor by limestone neutralization with a small loss of values. Copper and nickel were separated by solvent extraction with naphthenic acid in kerosene after partial neutralization of the iron-free liquors with ammonium hydroxide. Hydrogen sulphide and chlorine were used to remove zinc (and residual copper) and cobalt impurities respectively. The recovery of pure copper and pure nickel, by electrowinning, from the acidic solvent extract strip liquors finally produced, appears technically feasible.

Jan 1, 1964

By A. D. Hahn

This report describes reconnaissance by the Bureau of Mines of titanium-bearing beach sands on Ship Island in the Gulf of Mexico off the south coast of Harrison County, Miss. The purpose was to determine the ilmenite, rutile, and associated heavy-mineral content of black-sand-bearing beach sands. The investigation was part of a survey of titanium resources of the United States. Ilmenite (FeTi03), an iron-titanium oxide, is the major titanium-bearing mineral consumed in the titanium pigment industry. Rutile (TiO2), titanium dioxide, is used mainly as a constituent in welding-rod coatings and in producing titanium metal. The major fieldwork was conducted during the first half of February 1961. Nine holes, totaling 220 feet of bore, from which 110 samples Her taken, were drilled at widely spaced intervals on the island.

Jan 1, 1962

By A T. Spathis, M L. Lawlor-O’Neill

A methodology for the inversion of a scaled charge weight superposition model to predict peak particle velocity (PPV) has been examined. The inversion involves two steps: first simulated annealing is used to get an initial estimate of the model parameters; and second, these parameters are used as input to a quasi-Newton non-linear optimisation method, used to refine the value of the parameters. The methodology recovers the three required parameters (two charge weight scaling parameters and a time window width) and does this directly from a single production blast for a given point of interest. It has been tested on a synthetic example and recovered the input model parameters successfully in the presence of introduced noise with a coefficient of variation ranging up to ten per cent. Another test used the vibration measurements of three tunnel blasts monitored during the construction of the Citybanan tunnel in Stockholm. In this case, the three model parameters are found from one blast and for a given point of interest, and the PPV at the same point of interest is predicted for the second and third blast fired in the same vicinity as the first blast. The three blasts used different firing sequences. The predicted PPV limits use a confidence interval determined from the scatter in the peak levels obtained from the single calibration blast. The methodology was able to predict an upper bound for the PPV in 21 of the 26 tunnel blast vibrations studied. These predictions improve on a previous study involving the same model but which did not use the inversion process above. Given this reasonable success, further testing of the method on other data sets and alternative forward prediction models is recommended.CITATION:Lawlor-O’Neill, M L and Spathis, A T, 2015. An inversion method for the prediction of peak particle velocity in blasting, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 97–108 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By T. A. Sullivan

The Bureau of Mines investigated modified sulfur concretes as one part of a program for utilizing sulfur in construction materials. The use of modified sulfur was studied as a means of preventing the stressing action in the concretes caused by the allotropic transformation of sulfur on solidification. Unmodified sulfur concretes have been prepared that have compression, flexural, and tensile strengths equivalent or better than Portland concretes. However, most of these concretes have been vulnerable to deterioration by weathering, temperature fluctuations, and freeze-thaw cycling. The sulfur was modified by reaction with dicyclopentadiene or dipentene before use as an aggregate binder. Sulfur concretes and modified sulfur concretes were pre-pared from acidic and basic type aggregates. Physical properties of the optimum mixtures were determined and compared with each other and with Portland cement concretes. The best results were obtained by reacting sulfur with 5 pct dicyclopentadiene to prepare modified sulfur concretes. Field testing of the concretes are in progress. Present results show that modified sulfur concretes are superior to unmodified sulfur concretes and equal or better than Portland concretes in compressive, flexural, and tensile strengths. Long-term aging characteristics of both modified and unmodified sulfur concretes are being determined.

Jan 1, 1976

By G. M. Card, K. D. Card, B. V. Sanford

Abstract-The Canadian Shield and its extensions are traversed by an orthogonal system of northwest and northeast trending arch-style uplifts. These basement arches were formed by repeated vertical movements along pre-existing structures during compressional and extensional tectonism connected with events in surrounding Proterozoic and Phanerozoic orogens and ocean basins. The arches influenced patterns of sedimentation and tectonism in the intervening epicratonic basins and marginal platforms throughout the Proterozoic and Phanerozoic. Movements on the arch structures also triggered minor magmatism and controlled the location and timing of alkalic rock-carbonatite, kimberlite, and related intrusions in the Canadian Shield, the Western Canada Sedimentary Basin, and West Greenland.

Jan 1, 1997

By G. M. Card, K. D. Card, B. V. Sanford

The Canadian Shield and its extensions are traversed by an orthogonal system of north-west and northeast trending arch-style uplifts. These basement arches were formed by repeated vertical movements along pre-existing structures during compressional and extensional tectonism connected with events in surrounding Proterozoic and Phanerozoic orogens and ocean basins. The arches in?uenced patterns of sedimentation and tectonism in the intervening epicratonic basins andmarginal platforms throughout the Proterozoic and Phanerozoic. Movements on the arch structuresalso triggered minor magmatism and controlled the location and timing of alkalic rock-carbonatite, kimberlite, and related intrusions in the Canadian Shield, the Western Canada Sedimentary Basin, and West Greenland.

Jan 1, 1997

By C. R. McCann

The Bureau of Mines conducted an experimental study of conditions needed to produce flames of pulverized coal when the heat needed for ignition is sup-plied only from the flame and hot furnace refractory. An electrically heated furnace which burned about 1 pound of coal per hour was designed and fabricated. A sheath of air, surrounding the primary coal and air stream, was used to prevent entry of hot gases from recirculating combustion products. Furnace temperatures needed for ignition ranged from about 1,8300 F for an Illinois coal to 2,250° F for a Beckley seam coal. Apparent flame velocities were about 2 to 5 feet per second, increasing with volatile content of the coal and with distance from the burner mouth to the flame. The time required for ignition, approximately 0.02 to 0.07 sec, was a better measure of flame behavior than was velocity.

Jan 1, 1969