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By Kang Wan, Lei Tang, Jianchao Li, Jieyu Zhang, Minqi Sheng, Jifang Xu

"The viscous flow phenomenon in slag close to the liquidus temperature was considered. A simple approach that liquidus temperatures of melt could be derived from viscosity data was employed. The potential of this method for estimating the liquidus temperatures of pure water and binary alloy was demonstrated. The liquidus temperatures of the CaO-Alz03 based slags obtained from the second derivative method depends upon the number of viscosity values available at different temperature intervals. The results indicated that plots start deviating from the straight-line behavior at temperature as expect, and the second derivatives show the break points at a certain temperature, which is the liquidus temperature. Comparisons among the present observations as well as the characteristic temperature of the selected slags, which measured by the hemisphere method and DSC, indicated that it is possible to get a reasonable idea of estimate the liquidus temperatures from activation energies for viscous flow.IntroductionThe liquidus temperature of slag, which has a significant effect on the kinetics of chemical reactions and the slag-metal separation, is extremely important for metallurgical operations. Experimental measurements of the liquidus temperatures of slags are difficult, since slags invariable supercool. In addition, behavior of a single constituent in a multi-component slag is different in different circumstances due to its interaction with other constituents. Hence, it is essential to study the liquidus temperature of each particular slag resulting from a special process. Usually, the compositions of the slags aimed to the single liquid region of the phase diagram. However, the phase diagram of many slag systems, which back often to the 1950's, involves considerable uncertainties. Many liquidus temperatures are given as dotted lines in Slag Atlas [1]. Disagreements between the phase diagram and the reality have been found [2]."

Jan 1, 2013

By John Durkin

The Bureau of Mines has conducted field studies in coal mines through- out the United States to determine the effectiveness of electromagnetic techniques in locating miners trapped underground following a mine accident. Data from these tests have been used to generate models of expected signal and noise distributions as found above mines throughout the coalfields. These distributions have aided in placing the expected performance of a through-the-earth electromagnetic communications technique into a probabilistic framework. Results show that at a 10-pct false alarm rate, the expected probability of detecting a miner's signal from a depth of 1,000 ft is 54 pct; at 500 ft it is 95 pct. These depths exceed the actual depths of 90 pct and 50 pct, respectively, of U.S. coal mines. Sensitivity studies have shown that at a depth of 1,000 ft, for every 3 db of improvement in signal-to-noise ratio, the probability of detection increases 6 to 8 pct.

Jan 1, 1982

By S. C. Termes

To help develop the basis for new fine-particle separation methods, the Bureau of Mines has investigated the use of cross-linked starches containing four chelating groups--carboxylate, iminodiacetate, dietha-nolamine, and xanthate--as flocculants for selected metal oxide and hydroxide mineral fines. It was found that those starches capable of interacting with the mineral surface by a chemisorpti,on mechanism (as indicated by zeta potential measurements) produced the highest recover-ies and'grades of the metal oxide or hydroxide when flocculated from a binary mixture with quartz. The effects of pH, dispersing agent, stirring rate, stirring time, and starch dosage on selective flocculation were studied for binary mixtures of hematite and chromite with quartz. Floc strength becomes important in achieving maximum recoveries by mechanical postflocculation separations.

Jan 1, 1985

By Edmund Shaw

This paper is one of a series being prepared by the United states Bureau of Mines describing mining and milling methods and costs at industrial mineral plants throughout the United states. These papers are designed to disseminate technical information regarding the methods and equipment used. The cost tabulations represent operating expenditures only and not total production costs. It is recognized that publication of total production costs might, in many instances, cause embarrassment to individual producers as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion and study of the methods employed. The attention' of the reader? is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue. P. J. Weisel, Inc., with office at La Habra and plant at Corona, Calif., is the only local company that produces sand for the Los Angeles glass factories, although silica sand for other purposes is produced in other parts of southern California and the adjacent portions of Nevada. The deposit at Corona consists of coarse sand imbedded in a whitish clay and differs greatly from the other deposits, which are fine-grained sandstone that must be crushed before it can be screened and washed. The preparation of Corona sand has to be thorough and includes grinding in tube mills, repeated washing and rinsing, removal of dust by air separation, and magnetic separation of iron and other minerals. This requires a plant with a complicated flow sheet. The first plant built did not make a. satisfactory glass sand, and many additions and changes were necessary. It is thought that the present flow sheet will remain substantially unchanged until a new plant is built. The design of a new plant would be simpler, but the process would be the same.

Jan 1, 1937

By Ángel Azañero Ortiz

Dada la abundancia de los minerales sulfurados polimétalicos, se realizó un estudio de su comportamiento frente a la flotación diferencial. En ese sentido, el presente texto define los conceptos teóricos de la flotación selectiva a través de un estudio mineralógico y químico de la muestra. Así, las pruebas de flotación bulk y la separación reportan buenos resultados. De otro lado, el mineral de cobre, plomo y zinc que se ha estudiado no presenta dificultad durante la flotación selectiva. La calidad y la eficiencia de separación de los concentrados pueden ser mejorados con mayor tiempo de flotación y más etapas de limpieza.

Sep 1, 2012

By Oluwasegun Samuel Odebiyi, Shaona Wang, Feng Gao, Biao Liu, Hao Du

Recovering vanadium from vanadium titanium-magnetite (VTM) ore using ( NH4)2C2O4 is a clean hydrometallurgical process, but the drawback is the low recovery and slow kinetics due to the formation of inhibitor. A novel energy-efficient mathematical model was derived for green leaching of VTM in which the mechanical activation (MA) removed the inhibitor “δ” (formation of impermeable product layer of CaC2O4) covering the reacting core of the CaV2O6 leaching process in ( NH4)2C2O4 solution. Before the MA processing, the formation of the CaC2O4 layer affects the kinetics (slow) and NH4VO3 leachability (low recovery). The dissolution rate enhancement and economic importance (in terms of leaching kinetic/recovery) of mechanical activation (MA) pretreatment in hydrometallurgical processing cannot be overemphasized. It is shown from the experimental and developed mathematical model results that the rotating speed of the ball mill (ωb) has a significant effect on the NH4VO3 recovery. At 360 rpm, the experimental result gave an 82% optimum recovery rate and a reaction rate constant of 0.01889s−1 with close correlation with the present models at 82.8% and 81% for liquid-to-solid layer diffusion and chemical reaction controls, respectively, with a reaction rate constant of 0.018883s−1. The close correlation between the experimental recovery rate results and the diffusion recovery rate model result justifies that the leaching process is diffusion control shrinking core kinetic with experimentally measured activation energy (Ea) value of 19.502 kJ/mol . This present model proved that MA enhances the dissolution rate regardless of the formation of a passivation layer on the material and best describes the kinetics of the MA hydrometallurgical processes compared to the shrinking core model.

Nov 3, 2023

By Simón Díaz-Quezada, HUMBERTO ESTAY

The heap leaching process has been widely used for recovering different metals since its first application at the end of the 1960s. In Chile, copper production via heap leaching has accounted for between 30 and 40% of annual copper production over the past 10 years. This level of production has been achieved through and supported by the use of a mathematical relation, known as the leaching ratio (LR) or irrigation ratio (IR), which relates operational parameters with metal extraction in a heap leaching operation. This ratio has been used to develop leaching column tests, to scale up results from the laboratory to industrial operations, to design new heap leaching plants, and in metallurgical control and production estimation. In spite of the widespread industrial use of this relation, few scientific studies mention it. This is due to its simplicity and basic theoretical foundations. This disparity between industrial practice and scientific research could lead to operational decisions which lack substantial theoretical support, and to scientific studies which have limited industrial impact. Against this background, several questions arise about the use of the LR: What are the constraints on the use of the LR? Are there practical advantages with respect to reported kinetic models? What is the main reason that industry prefers the use of the LR over kinetic models, which enjoy greater theoretical support? In order to guide its future use, this paper describes the leaching ratio and its current uses and limitations, through a literature review and case studies.

May 2, 2020

By Rodolfo V. de la Cruz

The in-situ deformability of a highly jointed basalt rock mass was determined by two distinctly different methods: one, by the NX- borehole jack method where the displacements of opposing curved platens were related to the applied hydraulic pressures, and; two, by the modified Goodman jack method where the tangential strains on the borehole walls were related to the induced tangential stresses. The modulus obtained by the modified Goodman jack method were much higher than those obtained by the NX- borehole jack method. To explain the discrepancy, the influence of fractures and test variables such as depth, orientation, hole number and applied pressure on the calculated modulus of the rock mass were analyzed by factorial analysis and it was found that the orientations and depths of measurement has statistically significant effects. The in-situ deformability values obtained by non-linear regression analysis were also found comparable with other measurements and empirically predicted values for the basalt rock mass.

Jan 1, 1982

By J. M. Figueiredo, A. R. Silva, M. C. Coelho, R. M. Guedes

"With the continuous depletion of conventional sources of non ferrous metals, low grade complex sulphide deposits have been regarded as an alternative source of supply of zinc, copper, lead and also silver and gold. In spite of very important efforts in research in this domain it is still a long way to go in order to achieve reliable technological solutions both in ore dressing and metallurgical treatments which enable these complex materials to be regarded as commodities. The RLE process to treat bulk concentrates such as those obtained from portuguese ores, under development at LNETI and QUIMIGAL premises, combines experienced unit operations and innovative configurations and is an effective contribution for the future use of these materials. The results of three years of experimental work and main conclusions on the overall feasibility of the process are presented.IntroductionIn spite of the very well-known problems associated to the development of complex sulphide deposits, the economical importance of the enormous reserves of these materials, widespread all over the world, is so evident that its future use as source of supply of basic and precious metals and other minor elements is almost unavoidable.Critical steps in that direction are mainly concerned with favourable economical conditions and sound metallurgical practice for the treatment of nonferrous metals concentrates, which are nowadays still considered as non-conventional raw materials.Since Portugal is one of the countries where these orebodies occur more extensively, Portuguese authorities have dedicated since the beginning of the seventies, a big effort on finding economical and reliable processes for the recovery of copper, lead, zinc and also gold and silver, and for this purpose, several alternatives on ore dressing and metallurgical processing were studied, however without full sucess.Five years ago LNETI, a research laboratory, and QUIMIGAL, a chemical company, both state owned, decided to launch a research programme for the development of a metallurgical process for the treatment of NFM concentrates, which received financial support from NATO under its programme ""Science for Stability""."

Jan 1, 1988

By EDWARD B. DURHAH

(San Francisco Meeting, UCtober, 1911.) THE refinery at the San Francisco Mint takes the bullion purchased by the receiving department, and carrying more than 200 parts of precious metals in 1000, or, in mint parlance; over 200 fine, and separates and refines the various metals contained therein, using electrolytic processes exclusively. Bullion containing silver is treated in cells charged with a nitric electrolyte. These cells produce fine silver and leave a residue rich in gold. The residue from the silver-cells, together with crude gold-bullion, is treated in cells having a chloride electrolyte. These produce fine gold and leave a residue containing silver chloride. The latter is reduced to the metallic state with zinc and is then treated in the silver-cells. The various waste solutions and the wash-waters, after being freed from the bulk of their precious metals, still contain copper and other metals. These are removed by scrap-iron, and are then treated in the copper-cells, having a sulphate electrolyte. These cells produce pure copper, and collect a residue containing lead, some gold and silver, and all the metals of the platinum group that were in the bullion. This residue is relatively small, and is melted into bars and stored until sufficient accumulates to warrant treating it for platinum, etc. The refinery occupies three large and three small rooms. The large ones are, a melting-room, 30 by 34 ft.; a cell-room, 39 by 46 ft.; and a wash-room, 30 by 33 ft. The small rooms are used as foreman's office, laboratory, and generator-room, respectively. The methods here described are those in use in December, 1909, when notes for the present paper were taken.

Oct 1, 1911

By J. R. Hoskins

Method - A direct approach to instrument users, initially by letter and later by telephone or personal contact was made. The resultant data was compiled to give specific use information on the seven instruments. During the course of the study attempts to evaluate the Griswold Gage were abandoned when it became apparent that the gage was not being commercially produced. One company is developing the gage for its own use. The information presented is the result of over 1200 inquiries.

Jan 1, 1973

By Wm. D. Jr. Sheldon

THIS paper presents practical data to aid in the selection of a mine ventilating fan, and outlines considerations to be made to ensure satisfactory operation and optimum efficiency of the fan. Much has been published on the general subject of mine ventilation, but the writer has found few specific data on factors and considerations which govern the selection of a fan-data which should be available to the operator if his fan is to give satisfactory service within the range of the high-efficiency portion of its performance curve and deliver the specified air capacity when operating against the anticipated range of resistance of the mine. The total quantity of fresh air furnished by the ventilation system must be adequate to provide, and to ensure at all times, safe and healthful working conditions in the mine. It is assumed that the mine operator is able to determine the air quantities required for the various parts of the mine.

Jan 1, 1941

By Armin D. Ebner

A hetero-f1occulation model is developed to calculate the net force exerted on a paramagnetic nanoparticle that is moving in the proximity of a magnetite particle that is fixed or supported within an open flow and magnetically energized packed bed. Important variables investigated include the size and surface charge of the particles, the magnetic field, the ,flow velocity, the electrolyte concentration and the magnetic susceptibility of ,the nanoparticle. The ?influence: of other naturally occurring forces, such as hydrodynamic and DLVO(Le., van der Waals and electrostatic) forces on the magnetic attractive forces between the magnetite particle and the nanoparticle are also examined. This model reveals the feasibility of using magnetite particles instead, of stainless steel as the energizable element for high gradient magnetic separation.

Jan 1, 1999

By L. G. Wang

The stability of foams and froth plays an important role in flotation, in which small amounts of relatively weak non-ionic surfactants (frothers) are used to produce air bubbles and foams. In the present work, factors affecting the stability of the foams produced in the presence of common frothers, such as n-pentanol, n-octanol, methyl isobutyl carbinol (MIBC), and polypropylene glycol (PPG), have been studied. We used the thin film pressure balance (TFPB) technique of Schelud-ko-Exerowa type to measure the equilibrium film thicknesses. The results were used to determine the contributions from the various surface forces to the disjoining pressures in the thin lamellae (foam) films formed between air bubbles. In addition, we used a model developed by Wang and Yoon (Colloids and Surfaces A: Physicochem. Eng. Aspects, 2006) to calculate the elasticities of the lamellae films at the critical thicknesses at which films rupture. The surface forces and elasticity da-ta were then compared with the foam stabilities in the presence of the various flotation frothers. It was found that foam stabilities are controlled by both film elasticity and surface forces, the relative contributions of which change with frother type and concentration. In general, surface forces play a more important role at relatively low frother concentrations, while elasticity plays a more important role at higher concentrations. At the frother additions usually employed in the mining industry, MIBC relies on surface forces while PPG-400 relies on film elasticity in producing stable foams. The former is capable of dampening the hydrophobic force, which is a major attractive force destabilizing lamellae films, while the latter is capable of reducing surface tensions at low concentrations.

Jan 1, 2014

By Víctor T. Mejía Campos

El presente texto describe el proceso de remolienda efectuado en el circuito de flotación de bulk en la concentradora Casapalca. Dicho estudio se basa en dos proyectos anteriores, donde se buscó mejorar la molienda inicial con la instalación de un molino de bolas Marcy - 64-1/2 y el uso cuatro ciclones tipo Krebs de lú11 (3 en trabajo permanente y uno de repuesto) y un clasificador tipo Dorr Duplex de 71 x 28-1/2' de 19 rastrilladas por minuto. Dado el éxito obtenido en el primer proyecto, se prosiguió con el segundo. Finalmente, el 6 de octubre entró en operación normal el nuevo circuito de remolienda de las partículas gruesas en el circuito de flotación de bulk donse se comparó los promedios de los resultados metalúrgicos obtenidos en el año 1960, contra los resultados obtenidos en el año 1962 y se evidenció que este proceso mejoró la recuperación, produciendo más toneladas adicionales de concentrados.

Aug 20, 1963

By M. S. Badollet

"IntroductionASBESTOS FLOATS may be defined briefly as blends of air-borne particles of fibrous asbestos and dusts produced during the milling stages and collected by Cottrell precipitators, dust sheds, or bag-houses.The various grades of asbestos floats on the market contain fibrous asbestos particles ranging in length from microscopic to approximately 1/4-inch. The fines or dusts present in the floats are from 40 microns to 2 microns or less in cross-section.Airborne asbestos particles are of diverse length because they are collected at numerous places in the mill. There are: (1) dusts removed from dry rock storage bins, (2) dusts removed from rock and fiber screens, (3) particles from the tops of collectors, and (4) fines removed by suction from the processing equipment. Sometimes the airborne particles are kept segregated, so that there is a partial separation by gravity. This is accomplished by a series of dust chambers enclosed in a long, rectangular building. The longest and heaviest particles fall nearest to the air flow entrance, the smallest at a point farthest away and nearest the exit. Sometimes the air from the dust chamber building is passed through a series of bag-houses or electric :precipitators ,to collect the extremely fine particles which normally escape to the atmosphere."

Jan 1, 1952

By Jianxin Zhang

A process, in which arsenic in the residue is transformed directly into scorodite and copper dissolves into the solution simultaneously, was studied. The process was carried out in acidic ferrous sulfate solution under oxygen pressure. The optimum conditions of the process were determined as follows: the initial H2SO4 concentration of 10 g/L; liquid/solid ratio of 10; Fe/As molar ratio in the feedstock of 1; the addition of calcium lignosulphonate was 1% of sludge; oxygen pressure, temperature and reaction time were 1.5 MPa, 150 °C and 6 h, respectively. Under these conditions, arsenic transformed to crystalline scorodite in size of 5–10 μm, and the transformation efficiency reached 97.60%; meanwhile, the copper was leached with a high efficiency of 93.34%. The stability of the leaching residue was evaluated by TCLP testing, and the results indicated the concentration of arsenic in the leaching solution was extremely low as 0.04 mg/L and met the standard of safe stockpile.

By Faruk Oksuz, Dave Schiemann, Matt Trotter, Mike Padilla, Carmen Scalise, Miquel Sanchez

"The McCook Main Tunnel system consists of a 10-m (33-ft) finished diameter, 490-m (1,600-ft) long, hard rock tunnel constructed from a 27.5-m (90- ft) diameter and 92-m (300-ft) deep main gate and tunnel construction access shaft. The gate shaft houses six, high-head 4.4 m by 9 m (14.5 ft by 29.5 ft) wheel gates to be installed in the bifurcated and steellined section of the tunnel. The tunnel also includes portal and energy dissipation structures as it daylights into the reservoir.The construction of the tunnel system has been divided into two contracts. The gate and construction access shaft was completed in August 2011. The tunnel excavation and concrete and steel lining was completed in September 2014. The remaining and undergoing construction include the tunnel connections to the reservoir and the Mainstream Tunnel and installation of gates and hydraulic cylinders. This article focuses on the live connection of the McCook Main Tunnel to the Mainstream Tunnel that was initiated in November 2014 and will continue through the seasonal drier weather conditions in Chicago approximately from October through April. Chicago TARP systemThe MWRD has been addressing combined sewer overflows (CSO) and flooding in Chicagoland since the late 1960s and formally adopted the tunnel and reservoir plan in 1972 to protect the region’s most precious drinking water supply, Lake Michigan. Phase I of TARP, which included construction of 175 km (109 miles) of deep storage and conveyance tunnels with diameters up to 10 m (33 ft), was completed in 2006. In addition to protection of Lake Michigan from CSO discharges, Phase I resulted in substantial improvements in surface water quality as well as the quality of life for lake and riverfront communities in Chicago. Water quality improvements and flooding mitigation will be further enhanced as Phase II reservoirs are placed in service, including the three large reservoir systems, McCook, Thornton and Majewski (Fig. 1).The McCook Reservoir is the largest reservoir in the TARP system. Once completed, this $700-million reservoir facility will receive 38 billion L (10 billion gal) of CSO and flood water via the McCook Main Tunnel, which connects the TARP Mainstream Tunnel to the McCook Reservoir, and from distribution and Des Plaines inflow tunnels which will bring flow from the Des Plaines Tunnel of TARP."

Sep 1, 2016

By Mahyera A, Sakashita B, Ahmed U, Abou-Sayed AS

Gas in U.S. coals is primarily composed of 90 to 99 percent methane and up to 10 per- cent carbon dioxide. In composition and heat- ing value, this coal-bed gas is similar to natural gas and can be introduced directly into commercial pipelines after standard condition- ing. The high permeability cleat system in the virgin coal can be exploited in order to drain the coal gas well in advance of mining. Two premining drainage methods have been extensive- ly evaluated in the U.S.; they are 1) horizon- tal boreholes collared from within the mine, and 2) vertical drilling from the surface with fracturing. Limited-size fracture treatments are advocated in order to prevent potential roof damage and the need for added support. An engineering approach to predicting gas flow for different drainage techniques near mining locations is presented. Results can be used in design, i.e. pipeline, compressor. Coal gas drainage from a horizontal borehole and a treated (contained fracture) vertical well for a 6 foot seam have been evaluated. Based on these results, it was concluded that selection of gas drainage techniques will depend primar

Jan 1, 1982

By N Haque, S Northey

Water in mining, mineral processing and metal production on a life cycle basis has been at the top of agendas for various industries, government agencies, research organisations, academic institutions and communities. As a result, a number of water footprint assessment methodologies have been developed. However, their practical applications in mining and mineral processing industries with specific case studies are still rare.A key objective of the Minerals Down Under Flagship is to contribute to the long-term sustainability of the Australian mining and mineral industries. Researchers in the Mineral Futures theme have developed robust assessment methods to evaluate the impact of mining and minerals technology development on the environment. The future of mining and the mineral industry is strongly linked with its sustainability - better water management strategies will need to be implemented.Life cycle assessment (LCA) has been a recognised method for measuring the environmental impacts of products, processes and services. It provides a scientifically sound method of comparing products and processes using a common basis and identifies so called æhot spotsÆ and opportunities for reducing environmental impacts. The water footprint of mining, mineral processing and metal production using an LCA basis is still scarce in the literature. Research methodology is now being applied in detail for copper, gold and nickel. A primary focus has been the relationship between ore grade and water use for which mathematical models are being developed. These types of models provide inputs for LCA of mining and mineral processing plants and can identify water saving opportunities through scenarios and process route analysis.CITATION:Northey, S and Haque, N, 2013. Life cycle based water footprints of selected mineral and metal processing routes, in Proceedings Water in Mining 2013 , pp 35-50 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013