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By P. Kawulka

An integrated pilot plant for the development of the S-C Copper Process was constructed at Fort Saskatchewan in 1975 and operated in 1976. The pilot plant was designed to treat 9 tonnes per day of a pyritic copper concentrate. A demonstration run conducted during the last quarter of 1976 averaged 90% on-stream time, and confirmed that the process is operable as a stable and integrated unit. The paper describes the parameters and equipment developed for thermal activation of chalcopyrite copper concentrates to make them amenable for the dissolution of iron and zinc, and their subsequent separation and recovery. The resulting high-grade copper sulphide was leached with return electrolyte and oxygen to extract 98.5% of the copper into solution. The copper was electrowon at 650 amps per square metre from purified solution, to produce cathodes analyzing 0.1 ppm Se, 0.1 ppm Bi, 4 ppm Pb and 10 ppm S. The electrical conductivity was >101% lACS and the spring elongation value [ ]350 mm. Elemental sulphur and gangue are removed from leach residues to make a concentrate containing over 95% of the silver and gold and most of the unleached copper. Conventional construction materials such as stainless steel, titanium, Hastelloy, acid brick, rubber and plastics performed well. The containment inherent in hydrometallurgy provided high standards of hygiene and safety.

Jan 1, 1978

By Sara Hornby

After almost half a century of experience in using DRI/HBI in electric arc furnaces (EAFs), and taking into account the decrease of natural gas cost in the USA, it is interesting to revisit some trends and controversial issues around this alternative iron source. This paper reviews aspects like the evolution of iron ore quality and its influence on EAF operation; DRI stockpiling and transport, regarding the risk for selfcombustion; optimum charge design; cold DRI/HBI charging (fifth hole, bucket, transporter); hot charging (ways and results); carbon content, metallization and silica in DRI/HBI, and its influence on EAF operation and performance; oxygen / carbon balance; chemical energy and DRI/HBI charge.

Aug 16, 2017

By W. W. Adams

"The results of the fourth annual safety contest, 'mown as the National Safety Competition, contacted by the United States Bureau of Mines are herein announced. A bronze trophy, ‘Sentinels of Safety’, the gift of the Explosives Engineer magazine, has been awarded to the leading mine in each of the five groups into which the mines and quarries that participated in the contest were arranged. These five groups were: anthracite mines, bituminous coal mines, metal mines, nonmetallic-mineral mines, and carries and open-pit mines. The leading plant in each group was the mine whose employee lost the smallest number of days from accidents in proportion to the total number of man hours worked. Where two or more mines operated without a lost-time accident, the winner was adjudged to be the plant which operated the largest number of man hours during the year.The contest was based upon reports of accidents and exposure sent by the competing companies to the Bureau of Mines. Records of the five leading companies in each group were made known to a Committee of Award, consisting of the following seven members: H. Poster Bain, Secretary of the American Institute of Mining and Metallurgical Engineers; James F. Callbreath, Secretary of the American Mining Congress; W. H. Cameron, Managing Director of the National Safety Council; H. L. Gandy, Secretary of the National Coal Association; A. T. Goldbeck, Director of the Engineering Bureau of the National Crushed Stone Association; William Green, President of the American Federation of Labor; and A. J. R. Curtis, Assistant to the General Manager of the Portland Cement Association. Members of the committee voted for the winning company in each group in accordance with the rules governing the contest.. A majority vote prevailed."

May 1, 1929

By John Chipman, Theodore B. Winkler

IN order to understand more fully the complexities of the reactions occurring between the liquid steel and the slag in the basic open-hearth steelmaking furnace, investigations in this country and abroad have turned to laboratory equilibrium studies. This paper is one of a series of reports on investigations being conducted at the Massachusetts Institute of Technology. The experimental work was completed early in 1942. The slag systems found in the basic open hearth are very complex, being made up of at least eight major components and as many others whose effect might be classified as minor. The first two papers of the series, by Fetters and Chipman,l,2 as well as the paper by Taylor and Chipman,3 dealt with the simplest possible slag system that would resemble those found in the basic open hearth-the slag system consisting of CaO-MgO-SiO2-FeO. (Taylor's rotating induction furnace eliminated the necessity of contamination of the slag by MgO.) Having arrived at some reasonable conclusions regarding the physical chemistry of the reactions between molten iron and the simple slags at equilibrium, the next step was to investigate more complex slag systems. The major purpose of the present investigation was to determine what factors control the distribution of phosphorus between molten iron and the more complex basic slags at equilibrium, and to what extent these factors are influential. The slags used contained CaO, MgO, Si02, FeO, Fe203, P205, MnO, A1203 and CaF2, but not all of the slag samples contained all of these components at one time. REVIEW OF LITERATURE Although a number of interesting papers have been published on the subject of dephosphorization of an iron bath, there are as yet no results from laboratory studies that give thoroughly reliable information on the dephosphorization reaction. Even for the supposedly simple Fe-O-P system involving iron-phosphorus melts and iron oxide-iron phosphate slags, the experimental results are contradictory and no formulas have been established that adequately fit the equilibrium conditions. The Fe-O-P system has been studied by Schackmann and Brings4' von Samson-Himmelstjerna,5 Oelsen and Maetz,6 Bischof and Maurer,7 Diepschlag and Schürmann,8 and Herty,9 and the results of their investigations appear in Table I. A number of different equilibrium constants and distribution ratios

Jan 1, 1946

By George P. Demopoulos

For more than 20 years the author had the privilege of working closely on a number of R&D projects with Lucy Rosato and her team at CEZinc. Several of these projects were driven from the sustainability agenda that Lucy Rosato championed as an innovation leader that supported research collaborations. Highlights from this highly rewarding collaboration are to be presented in this paper. In particular we will deal with the following works-topics: (a) iron control via solvent extraction as alternative to jarosite precipitation; (b) production of high-density gypsum by controlled neutralization of simulated zinc plant process/waste waters; (c) selenium removal from weak acid solutions; (d) electrolyte purification by cementation; and (e) manganese control by oxidative precipitation with SO2/O2.

Jan 1, 2015

By L. K. Weaver

The objective of this Bureau of Mines publication Is to present a nomograph that provides a fast, convenient method for estimating hydrocarbon lease bonus bids for offshore acreage in the Gulf of Mexico. Discounted cash flow analyses were computed from a model derived to show the costs necessary to explore, acquire, develop, produce, and abandon a 5,000-acre block of offshore acreage, and the estimated income from the sale of the hydrocarbons produced from the block. The range of the variables in the financial analyses used to construct the nomograph are prices of oil, $2.50 to $5.00; recoverable hydrocarbon reserves, 44,651,476 to 127,575,645 barrels; and discounted cash flow (DCF) rates of return, 5.0 to 57.2 percent. A total of 1,234 sets of DCF data were used to construct the nomograph. The range of bonus bids shown on the nomograph is from 2 to 90 million dollars ($400 to $18,000 per acre).

Jan 1, 1973

By R. L. Grayson, S. S. Peng

"Abstract. Sampling of respirable dust and analyses of samples have been partially completed for a longwall panel. Physical and compositional properties which have been characterized include:l. Respirable mass concentration, 2. Mineral composition,3. Particle size distribution by mineral,4. Particle shape distribution by mineral,5. Particle angularity distribution by mineral, and6. Respirable size distribution.Analytical techniques used in the characterization of samples are described, and results are reported with emphasis placed on relationships between the various characteristics and worker locations. Details of existing mining conditions, equipment arrangements, dust control methods and operating system parameters are presented.INTRODUCTIONThrough the work of many researchers worldwide, the health of coal miners in modern societies is now protected from dangerous exposure to respirable coal mine dust. A vast amount of research culminated in the exposure-response model of Jacobsen, et al. (1971) whi3h has been used to establish the 2mg/m exposure limit in the United States. According to the model, exposure to respirable dust for 35 years at this level or less would prevent the occurrence of a clinically significant case of coal workers' pneumoconiosis (CWP). The exposure limit, of course, must be adjusted whenever greater than five percent free silica exists in the respirable dust.The Jacobsen model was built around a mass concentration exposure, which showed the highest correlation with incidence and progression of CWP. As Morgan; et al. (1973) noted, howev.er, the quantity of respirable dust inhaled is not the only significant factor. It is noted that although mass of respirable dust correlates highest with the incidence of CWP, it is not a causal factor. Indeed, the insidious processes causing the disease occur on the cell-particle scale, requiring microscopic investigation."

Mar 1, 1989

By G. A. Bezuidenhout, S. Bradshaw, W. Malan

"Currently, the matted-based collection process is most widely used for platinum group metal (PGM) recovery. However, because PGM-containing concentrates are becoming more enriched with UG2 (Upper Group 2) low-grade concentrates, this is expected to be integrated or replaced with an alloy collection process.The reduction LG (low-grade) concentrates with silicon carbide (SiC) was investigated. The purpose of the study was to ascertain the feasibility of using SiC as reductant with regard to metal fall, PGM grade in the alloy, slag composition, and overall PGM recovery, and if possible, the integration of such a process in the current matte-based collection process. Rowland and Easterns LG concentrate samples from Lonmin were analysed by Xray diffraction (XRD), X-ray fluorescence (XRF), and inductively coupled plasma mass spectrometry (ICP-MS). It was found that SiO2 and MgO are the most abundant oxides and Pd is the most abundant of the PGMs. Sulphide-bearing minerals such as chalcopyrite were detected in low concentrations (below 1%), and Cr2O3 concentrations are between 2-4%. SiC reduction of Rowland and Easterns concentrate were conducted at 1600°C with reductant to concentrate ratios ranging from 2.5 to 3.5 kg SiC per 100 kg concentrate.The reduction experiments revealed that PGM recoveries from Rowland concentrate were poor. SEM images showed entrained metal prills in the slag phase. The slag viscosity at the end of the melt was calculated by using FactSage, and the results indicated that the viscosity was higher than 4 poise, which is above that of Easterns slag. PGM recoveries for Easterns concentrate were significantly better. More than 85% of the Ir and Pd and almost 60% of the Pt were recovered in a test with a reductant to concentrate ratio of 3.5 kg SiC per 100 kg Easterns concentrate. At this reductant to concentrate ratio, Fe recovery was also the highest, at 66%. SEM imaging of a slag sample revealed few or no metal prills entrained. The FeO content in the initial concentrate charge was then increased by adding Peirce-Smith converter slag in order to decrease the slag viscosity and further increase PGM recovery. A test was conducted with the addition of 10 kg converter slag per 100 kg Easterns concentrate. The reductant to concentrate ratio was kept at 3.5 kg SiC per 100 kg Easterns concentrate. The Ir and Pd recoveries were more than 95%, while Pt recovery was almost 70%. Fe recovery increased to 76%. On the basis of these results an optimum feed ratio between Easterns and Rowland concentrates and Peirce-Smith converter slag were calculated. FactSage predicted that the concentrate charge should consist of 70-80% Easterns concentrate with 20-30 kg converter slag per 100 kg LG concentrate. SiC reduction of this optimum LG concentrate charge is expected to recover more than 90% of all PGMs. Cr and Si concentrations in the alloy will be below 1% in total.The effectiveness of SiC as reductant was also compared to carbon reduction. Carbon reduction of an optimum concentrate charge at the same reductant to concentrate ratio resulted in a marginally higher metal fall than SiC reduction. However, gas emissions and energy requirements are higher for carbon reduction.The study has shown that base metals and PGMs can be recovered in an iron alloy by SiC reduction of LG concentrate with converter slag additions. Integration of such a process into the matte-based collection process could be considered as a future alternative for smelting UG2 LG concentrates."

Jan 1, 2014

"Acid resistant brick lined autoclaves and related vessels are utilized in pressure oxidation for the recovery of gold, copper, and other metals. The combination of the corrosion resistant membrane, acid resistant brick, mortar and steel shell is a composite system that requires a sophisticated stress analysis. In order to obtain meaningful results both the model and physical properties of the materials must be carefully selected. Evaluation of the calculated results requires an understanding of both the failure mechanisms of ceramics and experience with the performance of existing lining systems.INTRODUCTIONAcid brick lining systems are used in pressure oxidation autoclaves and related vessels to provide thermal and mechanical protection for corrosion resistant membranes that are applied directly to the interior of the vessel shell. The acid brick and mortar must be resistant to the process conditions and must provide a mechanically reliable structure.The construction of lined vessels incorporates a wide range of materials that can include the carbon steel vessel, austenitic weld overlay, lead lining, organic membrane, ceramic brick, mortars and other alloy components. The physical properties of the materials can vary by orders of magnitude and when combined in the construction of the lined vessel create a complex composite structure. The materials may be bonded together or act independently of each other. Stresses are induced into the lined vessel include pressure, thermal expansion, chemical expansion and mechanical loads.The complexity of these systems makes it is very difficult to account for all of the variables in the structural analysis of lined vessels. Historically calculations were simplified and designers primarily relied on experience with previous applications.The greatly improved tools for Finite Element Analysis (FEA) available today allow for detailed calculation of the stresses imposed on the vessel shell and lining. Koning & Lauzon (2004) presented a paper on design fundamentals including a discussion on the application of FEA methods at Pressure Hydrometallurgy 2004 in Banff. When a designer carefully constructs a model and selects the correct materials properties for the calculations, meaningful and useful results can be achieved."

Jan 1, 2012

By N Dube, K L. Sandvik, C Mutevhe

Trojan Nickel Mine is the largest producer of Ni, Cu and Co in Zimbabwe. The mine has operated a nickel flotation concentrator and base metal refinery continuously since 1969, creating 28 million tonnes of sulfide bearing tailings, five million tonnes of permanent waste rock and about seven million tonnes of smelter slag. Exposure of the sulfide bearing minerals renders them susceptible to oxidation in the presence of water and oxygen, resulting in acidic solutions with elevated concentrations of total dissolved solids, sulfate, metals and residual flotation chemicals in various waters draining from the mine site. These pollutants pose a direct threat to the environment and human health, and understanding their deportment and behaviour in the various waste streams is essential in the mineÆs environmental objectives to prevent or minimise adverse impacts arising from its operations. A geochemical assessment of the pollutants was carried out to compute a mass balance between the major sources of pollution and the distribution and fate of pollutants in waste streams from the mine site. Waste rock, tailings, surface water, ground water and sediments were sampled, tested and analysed. Mineral composition and water chemistry data show that geochemical reactions are responsible for the release of pollutants from waste rock, tailings and plant spills. Drainage from the mine area is near neutral due to buffering by magnesium carbonates in the fine fraction of the tailings. The natural wetlands that exist downstream of the waste rock and tailings dams are effective in reducing metal loadings to water courses. However, solutes and heavy metals are occasionally released to surface and ground water, when their concentrations peak during the dry season. The results demonstrate the necessity to understand the natural chemical processes that characterise the distribution of pollutants in nature and how such knowledge can be used to develop cost effective methods to remediate pollution in the natural environment.

Jan 1, 2006

By RAYMOND M. LARSEN

The area covered by this paper is the same as that covered in 1944. Colorado, Montana, Utah, and Wyoming are included in the discussion and statistics, and brief mention is made of activities in the adjoining states, except Nebraska and New Mexico, which are considered separately (see pp. 187-189). The other adjoining states, North and South Dakota, Arizona, Nevada, and Idaho, have had virtually no oil or gas production, except in the gas field of Cedar Creek. Montana, which extends into North Dakota; the Pierre field in South Dakota, where gas is produced and separated in gas-water wells, and the abandoned Payette area in western Idaho. Seven gas wells were drilled in North Dakota, but no wildcatting was reported. Several unsuccessful wildcats were drilled in South Dakota, and some were continuing at the end of the year. Activity in Idaho and Nevada was negligible.

Jan 1, 1946

By H. M. Lewis

The current status of the international zinc market is summarized, and a supply /demand outlook is presented for the next five years. A number of technical problems facing the industry are outlined. Introduction ZINC has sometimes been called the unknown metal. Considering that on a world basis it ranks third among non-ferrous metals in production and consumption, zinc retains a certain modesty. It has no distinctive colour like copper, lacks the low density of aluminum or magnesium and is not always easy to identify as a product. The 'spangle' of galvanized steel is probably zinc's most distinguishing feature. The purpose of this article is to develop an over-all review of zinc. Starting with the current position of the metal, the major factors that will shape its future will be described so that an assessment of the outlook for zinc can be made.

Jan 1, 1978

By Robert L. de Beauchamp

The Bureau of Mines reviewed aluminum chloride technology to determine the problems associated with its preparation from minerals, and to ascertain the best areas for research to solve these problems. Commercial AlC13 production processes are described and the ?state of the art? for the preparation of AlC13 from aluminous materials is evaluated. Areas for further research are indicated.

Jan 1, 1969

By David A. Campbell

There has been a long history of ironmaking on the North East coast of England centered around the River Tees. The industry developed here because of the availability of good coking coals to the North in Co. Durham, and the discovery in 1851 of ironstone in the nearby Cleveland Hills, South of the .River. Cleveland ironstone is relatively poor in quality, with an iron content not exceeding h% and high proportion of sulphur and phosphorous. The iron exists in chemical association with alumina and silica, and physical beneficiation processes involve a serious loss in iron unless the upgrading is limited, when the economics of the process become doubtful. Over the years, richer foreign ores have replaced the local ironstone, and the last operating mine was closed in 1964.

Jan 1, 1982

By A. Bakalarz, M. Duchnowska

"The copper sulfide ore from the Legnica-Glogow Copper Basin in Poland, which is processed by KGHM Polska Miedz S.A., consists of three lithological fractions: dolomitic, sandstone and shale. The copper ore, depending on the mining area, contains all fractions in different ratios. The lithological fractions differ in the particle-size distributions of their useful minerals. In the dolomitic part of the ore, most of the metal sulfide particles are 50-200 microns in size, while those in the sandstone and carbonaceous shale are 30-200 and 5-40 microns in size, respectively. This complex composition results in different mineralization, physicochemical properties and, in particular, upgrading selectivity. Due to the specific nature of the examined copper ore, two of the crucial parameters determining the beneficiation efficiency are size and liberation of sulfide particles. We analyzed the influence of grain size of feed on scavenging selectivity in one of the KGHM flotation plants and performed evaluation and analysis of the upgrading results of industrial beneficiation of the ore, containing mostly dolomite and shale. The upgrading efficiency was estimated using a selectivity indicator obtained by means of the Fuerstenau upgrading curve, which was then correlated with the particle-size distribution of the flotation feed.IntroductionFroth flotation is used extensively in commercial ore treatment flotation plants to separate minerals from gangue and to separate minerals from each other. The floatability of ores and their benefication selectivity are determined by many factors. One of them is particle size. The effect of particle size on flotation performance has been widely studied by many authors (Gaudin et al., 1931; Trahar, 1976; Trahar and Warren, 1976; Lynch et al., 1981; Pease et al., 2004). Particle size also plays a critical role in the probability of particle collision and attachment to bubbles (Solari and Gochin, 1992; Schulze, 1993), kinetic flotation (Taggart, 1956; Ahmed and Jameson, 1985; Debacher, 2002; Brozek and Mlynarczykowska, 2007; Potulska 2008), collector consumption (Sutherland and Wark, 1955; Vianna et al., 2003) and mechanical entrainment (Lynch et al., 1981; George et al., 2004; Konopacka, 2005). Most of the results have shown that there is an optimum particle size range for a given flotation system and that the simultaneous optimization of the recovery and concentrate grade of these particles in conventional flotation equipment is extremely difficult."

Jan 1, 2015

By M. A. A. de Klaver

Functional Description Figure 1 is a typical flowsheet for a system for solid fuel addition to filter cake. Solid fuel, coal, coal breeze, or charcoal, is fed from a,stockpile to a surge hopper. The solid fuel is metered into a grinding mill. The fuel is dried and ground in a grinding mill. The on-size particles are removed from the mill by air sweeping. The ground solid fuel is separated from the air stream by a cyclone and stored in a surge hopper. The ground solid fuel is then pneumatically conveyed to a small hopper in the balling area. The fuel is proportioned into the filter cake just prior to mixing. An efficient mixer is very important to have a successful operation. The exact flowsheet would depend on a number of factors including what fuel is used, how the fuel is received, and the cnaracteristics of the fuel as received. Availability of floor space in the plant may also affect the flowsheet. For example, drying air may be supplied from the pellet furnace if the grinding mill can be located near the grate, or the pneumatic conveying system and a surge hopper may be eliminated by placing the grinding mill adjacent .to the mixing area. Also, for a multiple line plant, a ball mill rather than a roller mill may be more suitable.

Jan 1, 1980

By José Luis Calderón Jiménez

"Dadas las limitaciones económicas de los gobiernos locales y poco apoyo del Estado, la mina Poderosa recibe presión de la población para cubrir el déficit de servicios que requiere el distrito de Pataz y mejorar la calidad de vida de sus pobladores influencia. En ese sentido, la mina desarrolló un modelo de organización que busca fortalecer las capacidades de gestión y presencia del Estadoa través del proyecto que implica el fortalecimiento de los CODECOS mediante reconocimiento municipal e inscripción en registros públicos y la capacitación a los líderes y autoridades en talleres, pasantías y encuentros con expertos. Así, se mejora la relación con la comunidad de forma sostenible y armoniosa."

Sep 1, 2016

By C. A. Hansen

The furnace used for experimental work is shown in Fig. 1. One fireclay sagger, or pot, was set within another and the space between the two filled with Silox heat insulation. The hearth is a cast-iron plate with an imbedded ribbon of nichrome wire; this wire heater is connected to a potential regulator, which permits a very close voltage control. A mechanically driven arm is fitted with rabble blades so arranged that a uniformly thick ore bed may be maintained indefinitely. This arm is usually driven at about one revolution per minute but its speed of rotation can be varied as desired. Compressed air is led into the furnace through a meter, and it was found necessary to preheat the air in order to secure the definitely isothermal conditions sought. With this arrangement, it is possible to maintain any desired temperature constant within about 5" C. for any desired length of time and to

Jan 1, 1921

In March, the Minister of Mines, Mrs. Judy Erola, released a mineral discussion paper at the annual meeting and convention in Toronto of the Prospectors and Developers Association. Among the mineral objectives discussed was the revitalization of the "junior" mining industry. That industry reportedly has seen its share of total exploration expenditures fall from 50% in 1969 to 10% in 1979. Some sources believe the reason to be the rise of exploration costs and more- restrictive legislation The junior mining industry reportedly was responsible for 40% of all mineral discoveries in the 1969-79 period. CZECHOSLOVAKIA Czechoslovakia expects its capacity for the recovery of gallium metal to increase from 1,650 kilograms to nearly 3,000 kilograms per year by the installation of new recovery equipment at the aluminum plant at Ziar Nad Hronom in Central Slovakia. World production data are not reported, but the United States consumed 8,000 kilograms (estimated) in 1981, of which 5,536 kilograms were imported. Gallium is recovered as a byproduct of the Bayer process for the conversion of bauxite to alumina, and from certain zinc processing wastes. It is used for electronic applications such as light-emitting diodes for visual display panels in calculators, clocks, and other instruments.

Jan 1, 1982

By E. S. Moore

Introduction The geology of the Sudbury nickel field has been studied extensively, but there are few reports dealing with the structure of the interior of the basin. It was not until the Treadwell-Yukon zinc-lead deposits were discovered that attention was strongly directed toward the large-scale faulting that has split the basin parallel to its long axis. This faulting has been responsible for the , ore deposits in the basin and it may be regarded in many ways as the most important geological event, next to the intrusion and differentiation of the nickel eruptive sheet, that has occurred in the Sudbury region. The early reports on the nickel region by Bell, and Barlow, were chiefly concerned with the nickel-copper ores and with the formations of the region. Coleman was the first geologist to map the nickel eruptive as a continuous sheet around the belt and to emphasize its basin character. On the map accompanying his later report, he shows an important offset in the nickel eruptive at its southwest end, where the large fault cuts this portion of the basin, but the fault was not traced into its interior, as little detailed work was clone in the basin at that time. No ore-bodies had been developed outside of the nickel-copper deposits associated with the norite when the map was prepared, and attention was mostly concentrated on the nickel eruptive. Coleman did, however, map and name the various formations found within the basin and, in general, his delineation of these has remained the standard for prospectors and other workers in the field until the present day.

Jan 1, 1930