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"El presente estudio describe el proceso de combate contra incendios efectuado por la mina de Cerro de Pasco. Dicho procedimiento incluye una revisión anterior al año 1936 en dos etapas, las técnicas actuales y los planes futuros preventivos sobre incendios. Anteriormente al año 1936, los siniestros ocurrían en los tajos del último tipo y la forma de contrarrestarlos era a través de tapones, aislando la zona de incendio y creando un enfriamiento por medio de chimeneas de ventilación. Sin embargo, esta forma de combate contra los incendios no resultó efectiva, dado que no evitaba completamente el ingreso del aire por medio de los tapones y a su vez, la proliferación de minerales con el tiempo volvía inaccesible la zona. Por tal motivo, la minera solicitó los servicios de un consultor, quien propuso tres sistemas: inundación de la zona del incendio, sofocación del incendiopor medio de anhdriddo carbónico y el sistema Plenum. De los tres sistemas, se consideró a este último pues mantenía la zona de incendio bajo presión de aire y no alteraba el resto de la zona de trabajo. Posteriormente se sugirió el uso del sistema ""Slimming"" o relleno de lodos, los cuales cubrían hidraúlicamente los espacios vacíos alrededor del incendio con un material inerte, adquierendo la forma de un fluído. La efectividad del método era suficiente que fue adoptada a partir de 1938 hasta el presente. Entre los procedimientos actuales se propuso el reemplazo del pino de oregón por la madera de eucalipto por su costo y composición menos inflamable. Asimismo el entablado del piso se sustituyó por una capa de concreto de tres pulgadas de espesor, limpieza del tajeo y equipamiento adecuado de las chimeneas, la ventilación adecuada, el entrenamiento permanente de las seis cuadrillas de combate, construcción de galerías y cruceros auxiliares de transporte, el relleno por lodo y el uso del sistema de alarma denominado ""Stench Mercaptan"", que se inyecta en las tuberías de aire comprimido y sistema telefónico. "

Jul 20, 1957

By T G. Callcott

Australian coking coals are either class 434<tlj534<2l, at Port Kembla, or 634<3> at Newcastle. The former yield good blast-furnace cokes; the latter yield poor ones. However, increases in conventional strength indices, by methods applicable with normal coking ovens, seem unlikely to be economically attractive. Characterization of the coals has enabled an "economic" blend to be developed in the Newcastle area, and this has affected mining, preparation and handling operations. Coking studies have led to a specification for the making of strong coke, especially from the high-volatile Newcastle coals. Continuous coking studies, developed from the efforts to make very strong coke, have taken two directions. Firstly, coking thin layers of coal on strands; secondly, coking, in various types of vessels, compacts of coals with or with-out the inclusion of non-coking coals, iron ores or other inert materials. Gas, "sand" and hot metal coking have been tested for use in compact coking. Particular attention has been paid to pellets of coal and ore. The probable industrial problems in adopting any of the ideas are presently being examined.

Jan 1, 1963

By D.W. Gentry

1. Book reviews Mine investment analysis, by D.W. Gentry and T.J. O&apos;Neil. Society of Mining Engineers (Caler No. D, Litleton, CO 80127, U.S.A.). US$50.Finance for the mineral industry, by C.R. Tinsley, M.E. Emerson, and W.D. Eppler. Society of Mining Engineers (Caler No. D, Litleton, CO 80127, U.S.A.). US$50. 2. Mintek reports The folowing reports are available from the Council for Mineral Technology, Private Bag X3015, Randburg, 2125 South Africa. They are free of charge to South African addressees, but there is a handling charge of US$25 per copy for reports sent to overseas destinations. Report M291D Removal of pebbles and pre-crushing of selected feed material in autogenous milling, by D.I. Hoyer. First issued Nov. 1986, reissued Apr. 1988. 16 pp Report M350 A survey of miling and mil-lining practice on South African gold mines, by M.S. Powel. Jun. 1988. 30 pp Report M356 The distribution of cobalt in mineral constituents of the Merensky Reef and UG-2 Chromitite Layer of the Bushveld Complex, by G. Smits. Jut. 1988. 13 pp Report M359 The development of a mobile laboratory for the monitoring of gold and cyanide in alkaline cyanide solutions, by R.V.D. Robert, C. Pohlandt-Watson, H.J. du Plessis, and G.D. Marshal. Aug. 1988. 17 pp. Productivity and technology The Metalurgical Society and Geselschaft Deutscher Metalhuten-und-Bergleute are sponsoring the Symposium on Productivity and Technology in the Metalurgical Industries, which is to be held in Cologne, West Germany, from 17th to 22nd September, 1989.Non-ferrous smelting Commemorating a centenary of lead smelting and refining at Port Pirie, the Conference on Non-ferous smelting wil be held at Port Pirie from 17th to 20thSeptember, 1989. International trade fairs From 20th to 26th May, 1989,4 major international trade fairs wil be held in Disseldorf, West Germany.

Jan 1, 1988

By A. C. Lane

Relations de la profondeur de plissement avec la gravita-tion et la hauteur des montagnes dans les Alpes. Par A. Heim (Zurich) 50me Anniversaire, Livre Jubilaire Soc. Geol. De Belgique, Rome, Fascicule 1, 17 to 28. Measurements show a negative anomaly, less densities of .the material below sea level. The author expresses it in terms of the thickness of rocks of an arbitrary density, 2.4, which might be considered wanting. The accordant heights of the summits, the depths of the folds, the deficiency in .gravity, and denudation he finds to be connected. The Alps float on the lightness of the folds of "sal" of weight 2.6 to 2.75 plunged into the heavier "Sima" according to a for-mula: P = h (2.7/2.8-2.7) where - P is the depth of fold-ing below sea level; 2.7 is the weight of the material accu-mulated in folding; 2.8 is the weight of the material dis-placed by it; and h is the mean height of the mountainous regions. For instance, between the valley of Saar and the Val de Bagne in Valais the depth of the folds according to Ar-gand&apos;s profiles is between 30 and 40 kilometers. The loss of gravity has been estimated in this region as 1450 X 2.4 = 3480 in units of weight. Obviously errors in the densities would profoundly affect the estimates of the thickness of folding, but his depths of folds are obtained from sections, and from them he works back to the densities. Of course other densities might be placed in the formula. Zur Dichte bestimmung von Tonen. By J. Koenigsberger, Berg u. Hüttenmannisches Jahrbuch, 75, I. Discusses Dr. B. Wilser&apos;s investigations as to the best way of obtaining the weight of rocks per unit volume. The use of mercury for rocks affected by water as there recom-mended may easily give too large volumes unless 1 to 3 atm. pressure is used. Thick machine oil is recommended for large lumps of clay.

Jan 4, 1928

By L. S. Richardson, N. J. Grant

REACTIONS of oxygen and nitrogen at low pressures with titanium have recently been studied by a number of investigators.1-3 Gulbransen and Andrew&apos; noted that the reaction with nitrogen followed the parabolic rate law whereas the reaction with oxygen deviated slightly from this law in the temperature range 300° to 800°C. In the work reported here, commercial titanium (75 A) was used as the test material. Cylinders 2.5 in. long and 0.25 in. in diameter were machined from heavier bar stock. The test pieces were given a metallographic finish, immersed for 30 min in cold concentrated HC1, washed in water, then acetone, and dried with lint-free cloth. Reaction rates were determined in a modified Sieverts type apparatus by measuring the decrease in gas pressure of the reacting gas contained in a constant volume. The amount of gas added could be measured in a calibrated gas burette to an accuracy of 0.01 mm. During the course of a run the temperature never varied by more than 10°C and then only for brief moments. After placing the specimen in the furnace, the system was first evacuated for 12 hr at room temperature, and then flushed with purified argon five times, adsorbed gases being discharged during this period from the glass system with a high frequency spark coil. The flushing and discharging were repeated at 400°C. This rather involved procedure was found necessary after a number of trial runs indicated extraneous effects traceable to the system. Reaction periods up to 2 hr were used, at initial gas pressures of 0.2 to 0.5 atm. Experimental Results Fig. 1 shows the decrease in oxygen pressure for tests at 0.5 atm at various temperatures as a function of the square root of the time. Deviations from linearity are minor and the parabolic rate law is obeyed. Fig. 2 shows the same plot for the nitrogen reaction. A definite deviation from linearity is noted; however, it is probable that the higher initial rates are caused by the presence of small amounts of oxygen contamination, the initial faster rate changing to the slower rate after about 5 to 10 min. Calculations of the rate constants were made on the basis of the latter portion of the curves. The parabolic rate law constants calculated from these curves are shown for oxygen and nitrogen in Fig. 3. In spite of some scatter the average curves are quite definite. Changes in gas pressure of the order of 20 pct did not result in a measurable change in the rate law constants. The activation energy for the oxygen reaction was calculated to be 47,400 cal per mol (above 700°C), which is not in agreement with the value quoted by Gulbransen and Andrew&apos; for lower temperatures, their value being 26,000 cal below 600°C. The activation energy for the nitrogen reaction was calculated to be 45,400 cal per mol above about

Jan 1, 1955

By Beth Robinson

Central Mexico&apos;s mining districts, opened centuries ago during the Spanish conquest, still form the backbone of metal mining in the country today. Beginning at Chihuahua City, the Second Mexican Mining Rail Excursion traveled southeast from camp to camp through this major mining area to Taxco. Improved exploration, exploitation, and beneficiation methods have permitted continuous mining of many old deposits, and led to the discovery of new ones. Minerals not sought by early miners-lead, zinc, copper, and fluorite-now contribute substantially to mining activity in central Mexico. Of Mexico&apos;s five physiographic provinces, the rail excursion passed through two: the Mesa Central, and the Sierra Madre Occidental. The Mesa Central province is a wide tableland with basin and range topography, containing important base metal deposits. Mining in this region is primarily of limestone replacement ore bodies. Massive deposits form horizontal mantos or vertical chimneys. In northern Zacatecas, the Santa Eulalia and Naica mines demonstrated this character. The Sierra Madre Occidental lies west of Mesa Central in northern states, then widens to almost the entire width of the country from outside Mexico City to the southern border. The area consists of volcanic beds, several kilometers thick. These intermediate volcanics are primarily andesitic, of Tertiary age. Resting on older strata of adjoining physiographic divisions, the volcanic beds are overlain by a thick series of acidic flows and tuffs. Economic mineralization in the Sierra Madre Occidental is vein-type, primarily gold and silver. Mines at Fresnillo, Guanajuato, Pachuca, and Taxco contribute to the claim that this region is the center for precious metals in Mexico. A third type of mineralization, contact metamorphic deposits, is commercial at Santa Eulalia. First Stop, Santa Eulalia Mine tours began with the Santa Eulalia unit, located 25 km east of Chihuahua City. Mining in the region dates back to the early 1700s. The oxidation zone was worked until 1790, but mining declined until Asarco arrived in the early 1900s, building a selective flotation plant for treating primary sulfides. Asarco still owns 34% of Industrial Minera Mexico, S.A. (IMMSA), operator of the Santa Eulalia mine. Santa Eulalia currently has a milling capacity of 850 t/d. The San Antonio and Buena Tierra mines provide feedstock. Head grades at San Antonio, the mine participants toured, average 80-120 g/t of silver, 1.5-4.5% lead, 4-16% zinc, and 0.1-2.5% copper. Tin and vanadium were also recovered between 1930 and 1940. Estimated proven and probable reserves total about 7.6 Mt, although 1.8 Mt of reserves are located in areas of high water pressure and volume, which makes extraction difficult. Water is a significant production problem at the San Antonio mine. In one area, an AX drill hole encountered 2.6 m3/min (700 gal/min) at a pressure of 2.5 kPa. Precautions are taken to cope with the problem: protective drilling in advance of blasting is performed;

Jan 2, 1982

By Steven Doyle

Presentation Outline ?Introduction to Brunswick Mine ?Mining Needs and Drilling Trends ?Maintenance Program ?Back to Basics ?Results ?Additional benefits Introduction Xstrata Zinc Brunswick Mine ?No. 12 deposit discovered in 1953, pilot mining 1957, u/g mining began in 1964 ?Zinc, copper, lead and bulk lead/zinc concentrates ?Since 2007, a fully owned division of Xstrata Zinc Canada ?Over 132Mt milled 3.4 % Pb, 8.8 % Zn and 102 g/t Ag ?Deposit dips approximately 70 degrees; strike length of 1200 m; currently mining from 250 m to 1125 m depth

Nov 1, 2011

By Jaime Tumialán de la Cruz

El presente trabajo describe las pautas para la selección del equipo de la operación minera subterránea como guía de referencia a futuro. Para ello, se utiliza una metodología en la selección del equipo minero que comprende el análisis de las características del depósito, análisis de los requerimientos de producción y las condiciones de trabajo, selección del equipo más adecuado a la determinación del trabajo, análisis de las características de los equipos y el cálculo de los costos de operación por hora y costo unitario. Asimismo se describen otros factores que influyen en la selección de equipo como standarización, mantenimiento, servicios, resultados de performance, etc.

Oct 14, 1980

By Bronson Stringham

The close area! relationship of Cretaceous or later intrusive porphyries to larger hydrothermal deposits of Pb, Zn, Au, fig, Cu, Mo, Hg,, and U of similar age in the Basin Range Province, was statistically shown in a recent paper (Stringham1) During the past year this study has been expanded to cover p11 of the larger hydrothermal deposits of similar nature occurring in the entire western United States. The sandstone type uranium deposits of the Colorado Plateau and Wyoming have been excluded since considerable controversy exists regarding their origin. The close relationship between intrusives in general and hydrothermal ore deposits has long been-recognized, but the association involving intrusive porphyry only, was suggested in 1954 when Sales concluded that the formation of porphyry may be an intermediate stage of activity between the development of granitoid rock and certain types of copper deposits. However: he applied this concept to only a few copper deposits. The relationship appears to be true also for a great majority of the hydrothermal deposits of the other metals mentioned above of Cretaceous and later age, at least in the western United States. This situation then leads to the conclusion then when exploring for similar types of hydrothermal deposits of the metals considered one may feel reasonably sure that if an intrusive porphyry of considerable size is. not present he may be facing much greater risk of finding an ore body than if a prophyry were presents Since, there are many intrusive porphyritic rocks which do not seem to be associated with hydrothermal deposit, it is believed that some distinct value can come from the recognition of intrusive porphyry which might be barren as well as the intrusive prophyry which might be productive This paper deals with that problem.

Jan 1, 1960

By G. R. Palmer

Preliminary studies by the Bureau of Mines were conducted to determine the feasibility of a multiple-compartment, ion-exchange (MCIX) column simulator for examining the effect of multiple-orifice plates in the column. A rectangular, five-orifice, three-compartment, MCIX simulator with a cross-sectional plate area of 0.66 ft2 was used for the investigation. Orifices with open areas of 1, 3, and 5 percent were used with various operating conditions. The study was separated into three separate sections: (1) solution flow effect, (2) fluidization effect, and (3) resin transfer effect. The solution flow and fluidization studies showed that for solution flow rates of about 3 gpm/ft2, a I-percent open area plate functioned best, while at solution flow rates of 9 and 15 gpm/ft2, the best open areas were 3 and 5 percent, respectively.

Jan 1, 1981

By Arka Jyoti Das, Prabhat Kumar Mandal

"Coal mining in India has a strategic importance for the energy security of the country. Presently, the majority of coal production is coming from open-cast mining. Due to the fast depletion of reserves amenable to open-cast mining, future coal production will depend primarily on underground production. In conventional bard-and-pillar/room and pillar mining as it is practiced in India, the percentage of extraction is very low. In fact, within most Indian coalfields, a large number of coal seams extract only 15- 20% of coal, but no pillar extraction is done due to the presence of surface or sub-surface structures leading to huge amount of coal being locked-up in underground. Spontaneous heating and fire, the accumulation of poisonous gases, severe stability issues, unsafe workings and environmental hazards are all major problems associated with these developed coal pillars, so there is a pressing need for technology in the mining industry to extract this huge amount of coal locked up under different constraints. In this study, we propose that the locked-up coal be extracted by replacing the developed coal pillars with artificial pillars. The paper briefly discusses the extraction methodology designed for this and its evaluation through numerical modeling for applied suitability underground.INTRODUCTIONDriven by rising populations and urbanization, an expanding economy and also a quest for improved quality of life, energy usage in India is expected to increase manifold in the coming years. As for India's energy scenario and its projected future plans, there is no doubt that coal will remain a prime source of energy, even over the next few decades.The majority of coal production in India comes from open-cast mining because of large-scale mechanization, but the coal reserves amenable to open-cast mining are gradually depleting - which may impose adverse impacts on the energy sector if underground production does not increase. Underground coal extraction, meanwhile, is going to become more complicated in near future due to the fast exhaustion of easily mineable coal reserves."

Jan 1, 2016

By B. K. Parekh

Economical dewatering of ultra-fine (minus 74 m) clean coal slurry produced in column flotation to a 20 percent or lower moisture level will be an important step in successful implementation of the advanced fine coal cleaning processes. The main objective of the present study was to evaluate efficiency and effectiveness of three dewatering techniques, namely, hyperbaric, vacuum and screen bowl centrifuge, in dewatering of ultra-fine (D50 -25 m) clean coal slurry produced by the &apos;Ken-Flote&apos; columns operating at the Powell Mountain Coal Company, St. Charles, Virginia. he hyperbaric filter using 3 bar pressure and 1650 cake formation angle, provided a filter cake with 23.6 percent moisture with a throughput of 800 Kg/m2-h and air consumption of 868 Nm3/t (460 scfm/t). The vacuum filter with 30 percent submergence provided a filter cake with 27.8 percent moisture with a throughput of 122 Kg/m2-h. The screen bowl centrifuge provided a dewatered product containing 32.9 percent moisture at a feed rate of 450 Kg/hr, however, the solids capture was only 65 percent. Addition of 1 Kg/t of a cationic surfactant provided filter cakes with 19.1 percent, 23 percent, and 34 percent moisture using hyperbaric, vacuum, and centrifuge, respectively. Similarly, addition of 0.5 Kg/ton of copper chloride lowered filter cake moisture to 20.7 percent and 24.8 percent, using hyperbaric and vacuum. With the centrifuge no improvement in filter cake moisture was noted. However, use of 80 Kg/ton of &apos;orimulsion&apos; in the centrifuge provided dewatered product containing 26 percent moisture, and the solids capture increased from 65 to 95 percent. The dewatered product appeared dry and was easily handleable.

Jan 1, 1999

By Raymond S. Suglo

Increasing depths of mining coupled with the mechanization of most underground mining operations have led to growing complexities in the mine environments with the production of large amounts of gaseous and particulate contaminants. Over 100,000 lives have been lost due methane gas and dust explosions in coal mine workings in both the US and Canada since 1900 when the methane concentrations exceeded stipulated levels in some workings. There is therefore the need to constantly assess and evaluate the performance of the existing mine ventilation systems to maintain safe and acceptable mine environmental conditions in workings to meet the requirements of federal, state or provincial laws. This paper uses the results of continuous monitoring of methane concentrations conducted in selected development headings in coal mines in North America to assess the effectiveness of existing auxiliary ventilation systems in the control of methane gas concentrations in the headings. The results show that the average quantities of fresh air required to dilute, disperse and remove methane concentrations within set levels of one minute varied from 5.43 m3/s in Heading #11 (Condition 2) to 27.97 m3/s in Heading #10 (Condition 1) and this represented about 12 to 26% of the quantities required to dilute methane concentrations to safe levels within one minute under Condition 1 and 32 to 139% under Condition 2. The average dilution times in the headings studied were less than 8 minutes. The forcing efficiencies of the auxiliary systems in the headings studied ranged from poor to excellent implying that the auxiliary ventilation systems were capable of controlling the methane concentrations below statutory levels but may not be able to cope with large and unusual methane concentrations in the headings. This study is important to prevent methane gas and coal dust explosions in coal mines and thus avoid any loss of lives and property.

May 1, 2001

Discussion of the paper of DAVID COLE, presented at the New York meeting, February, 1915, and printed in Bulletin No. 9S, February, 191.5, pp. 431 to 444. R. H. RICHARDS, Boston, Mass.-The Butchart riffle seems to violate, according to our preconceived notions, some of the very essential principles of the Wilfley riffle, and therefore ought not to succeed, but it does. On this account it must conform to other very important principles, or it would not succeed. It would beinteresting to know what these principles are which enable it to succeed. E. P. MATHEWSON, Butte, Mont.-I cannot, explain the principles on which this riffle acts, because I have not given it personal attention. All I can say is that I first saw the riffle in operation several years ago at the Steptoe Valley mill in Nevada, and I was told that a man had been around there guaranteeing that these riffles would make the table do twice as much work and do it better than with the ordinary Wilfley riffles. I heard nothing further about it for a long time. I heard about a year ago, from David Cole, the author of this paper, that the riffles were a success, and that he was using them at Morenci, and if, we were interested he would send the inventor to show us how they worked. As we knew of David Cole&apos;s reputation, we invited Mr. Butchart to come up and show us how his riffles worked. We did not have sufficient confidence in the invention to guarantee Mr. Butchart his traveling expenses, but lie came up entirely at his own expense and put in a set of the riffles on one table. It was known as a roughing table in our No.

Jan 5, 1915

By B. Voyzelle

The deterioration of highway and bridge infrastructure has received considerable attention in recent years because of the billions of dollars needed for repair and rehabilitation. A major factor contributing to this problem is the corrosion of steel reinforcement. Reinforcing steels with good corrosion resistance and relatively low price are therefore essential for maintenance, cost reduction and service-life extension of the steel-reinforced structures. This article describes the development of low-alloying steels that offers good corrosion resistance with reasonably low cost. Topics include steel microstructures, mechanical properties, corrosion performance, industrial applications and economic aspects.

Jan 1, 2005

By M. Muravyov, T. Kondrat’eva, A. Bulaev

Metallurgical treatments of sulfide ores containing copper and zinc are characterized by significant losses of base metals, particularly formation of the flotation tailings and slags during the dressing and pyrometallurgical treatment respectively. In addition, SO2 gas obtained during roasting and converting may be as raw material for sulfuric acid production. A treatment of the industrial metallurgical wastes has been investigated. Two samples of old pyrite tailings from two concentrators that contained 0.36% and 0.26% of copper and 0.23% and 0.22% of zinc were leached with 10% sulfuric acid in the column. Recovery of copper reached 47% and 38% while recovery of zinc was 47% and 41% from the first and second samples, respectively. The pregnant leach solutions contained 15.9 g/l and 10.5 g/l of ferric iron. Ferric iron is the strong oxidant and ferric containing pregnant leach solutions can be used for ferric leaching of different types of raw materials containing sulfide minerals. Therefore, ferric leaching of copper converter slag flotation tailings contained 0.53% of copper and 2.77% of zinc with the first pregnant leach solution was conducted. The effect of various experimental parameters on the leaching dynamics of copper, zinc, and iron under batch conditions was investigated. Under the best conditions (temperature 70oC, pulp density 30%) the recovery of copper and zinc reached 80% and 42%, respectively. Thus, it has been shown that acid leaching of base metals from old pyrite flotation tailings with using of the pregnant leach solution for the ferric leaching of copper converter slag flotation tailings is a prospective technique for the complex treatment of mining and metallurgical wastes. Investigated processes could be introduced into the technological flow-sheet of typical pyrometallurgical plants.

Jan 1, 2014

By T. B. Williams

A SEARCH of the records indicates that evidences of accumulations of petroleum and natural gas within the boundaries of British Columbia were discovered at approximately the same time as were those of Alberta. They probably would have been developed as soon bad it not been for the fact that they are in such uninhabited parts of the Province. Even today, the seeps of the Flathead area, and the later discovered extensive seeps of the Peace River area, have been seen by very few people. From the geological evidence, there is reason for believing that British Columbia soon will be a petroleum producing Province. Fifty-eight operators, both companies and individuals, are now backing the money and the effort which they have invested with us, for the most part within the last three years, in a belief that this is so. The promulgation of the Petroleum and Natural Gas Act in 1947 marked the beginning of a new phase with regard to the exploration and the development of our petroleum and natural gas resources. Since August 15th, 1947, the date on which the Act came into force, the area under exploration bas increased from a few thousand acres, held by lease under the Goal and Petroleum Act, 1986, to 10,460,115 acres, including all active permits, licences, and leases. In addition there are 192,720 acres under application, bringing the total under issue and application to 10,652,835 acres. The total area is comprised of 105 permits, 20 licences, and 26 leases under the 1986 Act. The permits and licences, which ?represent active exploration and development, are held by a total of 82 companies and 26 individuals.

Jan 1, 1951

By J. Menuge, G. Barker

"Liberation (QEM-SCAN) and surface chemical (time of flight secondary ion mass spectrometry -ToF-SIMS) analyses have been undertaken on plant Pb circuit flotation samples with the aim of defining the factors resulting in sub-optimal recovery. Lead flotation circuit feed, cleaner concentrate and tails samples were examined on a size-by-size basis using QEM-SCAN. Sulfide minerals accounted for approximately one third of the flotation feed with pyrite making up 16 wt.%, followed by sphalerite (13 wt.%) and galena (3 wt.%). Non-sulfide gangue minerals comprised calcium carbonates calcite (26 wt.%), dolomite (14 wt.%) with quartz, feldspars and barite all contributing > 5 wt.%. QEM-SCAN analysis indicated that liberation was not the primary cause of the poor flotation response. Principal component analysis was applied to the ToF-SIMS data derived from five samples (as for QEM-SCAN plus rougher concentrate and tails) to enable identification of correlated surface chemical components. Although a significant range of correlations were observed we focus here on those that show a discernible pattern throughout the float circuit. It was found that for the flotation feed the surface of galena were largely obscured but where Pb was observed there was a strong correlation to surface Fe. For the rougher and cleaner concentrates the galena surfaces were relatively clean with no correlation to Fe for the rougher concentrate and minor correlation in the cleaner concentrate. However, in the rougher and cleaner tails the clear correlation of galena with Fe was again apparent. These results suggest, in combination with prior studies of pyrite morphology, that the principal factor effecting grade is the rapid oxidation of the framboidal pyrite resulting in the contamination of the galena surface with a high loading of hydrophilic oxidised Fe species, thus depressing flotation."

Jan 1, 2014

By Keith A. Yarborough

INTRODUCTION The National Park Service (NPS) conducted a research program from mid-1975 to early 1978 to measure alpha radiation levels in natural caves which it administers. Subsequently, a long-term management program was developed which has conducted routine monitoring of radiation levels and has computed employee exposure accumulations in certain NPS caves. The overall program: research and management; was undertaken to evaluate the possible health hazard to cave visitors, interpreters, researchers, maintenance personnel, concessions employees and other workers and to protect their health. The results of this work have been reported extensively elsewhere (see References 1 through 3, 5, 6, 9 through 13, and 14 through 26). This paper deals with the relation of radon gas and daughter produced radiation levels to the cave air flows which mobilize them. These flows are a function of interior cave and exterior ambient air temperatures and pressures and of the cave&apos;s geophysical configuration. The low-level, ionizing radiation is produced by minute concentrations of radon and thoron gases which emanate from within caves. Because of confinement, the radiation levels are often appreciably higher than in surface atmospheres. Subsequent radioactive disintegration of the gases into their ionized "daughter" products, which are particulates, permits distribution of the alpha radiation throughout a cave system. The extent and character of this distribution depends upon the particular cave and the air flows which it produces. Thus, the alpha radiation serves as a "tracer" to describe the flows. The flow analysis is divided into two parts: 1) A qualitative description with respect to the two basic geophysical cave types over both long-term (annual) and short-term (diurnal to weekly) periods. 2) A quantitative description of the unsteady, uniform and non-uniform, one-dimensional, incompressible motions for both influent and effluent air flow situations in both basic geophysical cave types. A part of the qualitative description presents "Special Measurement" data: Tsivoglou [vs.] Kusnetz working levels, Tsivoglou individual daughter levels and free ion concentrations, radon gas concentrations, and equilibrium ratios. A great deal of important work has been carried out by Mr. Bobby C. Carson, Cave Radiation Technician at Mammoth Cave National Park, Kentucky. He reports these findings later in this conference (Ref. 6). Some of his results have been used here to establish the cave air flow analysis. Other National Park Service personnel have made measurements at others of the caves for which data are reported here. All of this work and cooperation has been vital to the success of this research program. It is very much appreciated. THEORETICAL FLOW DESCRIPTION Previously reported research (See Ref&apos;s. 20, 21, 23 and 25) has established the qualitative relationship between the alpha radiation in caves and their natural air flows. The radiation serves as a representation of these air flows. Changes in radiation with time represent changes in the main forces which produce the air flows. The quantitative data have substantiated that [all caves in which the primary cause of air flow is due to temperature produced gravity (density) gradients and also having minimal man-made disturbances, experience seasonal variations in airborne alpha radiation. The radiation levels increase in summer but decrease in winter], based upon seasonal air movements through each cave system which occur naturally. Two general types of physical cave configurations which control the air flows have been identified as: 1. Those which go up into a hillside or mountainside: Type I ("Upside-down" = USD). 2. Those which go down into the earth; Type II ("Right-side-up" = RSU). These act to control the air flows seasonally. The summer increase in Type I caves is due to increased air flows, whereas in Type II caves it results from stagnation or reduced air flows. This seeming paradox is explained by the physics of the air flow regime in each cave type and has been detailed elsewhere [Ref&apos;s. (20), (22) through (25)]. It[ i] true, in general, that air flow decreases airborne radiation in the [immediate vicinity] in which it occurs. Any paradox results from subsequent distribution throughout the case as to [ how] the air moves through a cave [system] with respect to time and space. Exceptions to the cave air flow "rule" are: 1. Caves in which pressure gradients and pressure fluctuations [predominate] in producing the air flows. 2. Caves in which man-made effects and management practices are superimposed on the natural air flow regime. Man-made disturbances which can alter the natural cave air flows are tunnels, elevator shafts, bore holes, sealed and closed portals, etc. If these are not properly sealed, the natural air flows which they change will totally alter the distribution and seasonal variations of the alpha radiation levels. These exceptions may act separately or in combination.

Jan 1, 1981

By M. S. Davis

The Tek Process can produce masonry products such as bricks, roof or wall tiles, and block from virtually any inorganic waste. In the process the aggregate raw materials, portland cement, water and common chemicals are first mixed together; then mechanically subjected to several thousand pound pressure per square inch. This causes a novel chemical reaction between the cement, chemicals and water; producing the "patented" Tek adhesive binder which holds the aggregate together in a stone-like mix. Simultaneously, the desired product shape is formed. The building modules can have strengths of 8000 p.s.i. (pounds per square inch) with completely sound aggregates utilizing air curing for a period of 28 days. With most aggregates, 3000 p.s.i. is achieved within 24 hours. Eventual strengths usually exceed 5000 p.s.i. with almost any raw material. Water absorption ranges from 5-7.5 percent. Both absorption and strength figures are superior to the most rigid of any and all A.S.T.M. specifications for the highest quality bricks. In most locations, the product (when brick shaped is called Tekbrik) can be produced significantly more economically than can comparable grades of clay or other bricks, be- cause almost any inorganic waste materials or pollutant can be used as a raw material. The process results in a lower manufacturing cost as compared to clay bricks; fuel cost to operate a clay kiln represents a substantial portion of the total cost. Capital expenditure for a Tek plant also is lower due to the large investment in clay kilns. Transportation savings also are important, clay brick factories must be very large because the kilns are uneconomical unless they are large. Most bricks are manufactured at the sites of clay deposits in relatively uninhabited areas. The cost of transportation to the job site represents a considerable percentage of the selling price.

Jan 1, 1974