Search Documents

By Zhihong Liu

Monodisperse micron size nickel oxalate particles with rhombohedron morphology were prepared from condensed Ni(OH)2 suspension by a novel gel-sol process proposed by one of the authors. Firstly, condensed nickel hydroxide gel was formed by fast adding 1 mol dm-3 NaOH solution into 0.2 mol dm-3 nickel chloride solution, and then oxalic acid solution with a concentration of 0.25 mol dm-3 was dropped into the gel drop wise through a pump equiped with a pH controller under preset pH value, and in this process, Ni(OH)2 gel was converted gradually into monodisperse nickel oxalate sol. The formation of the nickel oxalate particles was found to proceed through a dissolution-recrystallization mechanism from the nickel hydroxide gel. The product particles exhibited rhombohedron like shape with micron size long axis and sub-micron size short axis. The effects of such factors, as temperature, surfactants, et al, were evaluated experimentally on the particles sizes and morphologies.

Jan 1, 2006

By R. F. Abernethy

Analytical results, including ash fusibility data, are presented by the Bureau of Mines for 10 major constituents in coal ash from 373 samples of commercial U.S. coals. Determinations of Si02, Al2O3, Fe2O3, and P2O5 were made by colorimetric methods, Na2O and K2O by flame photometry, Ti02, CaO, and MgO by a spectrochemical method, and SO3 by a gravimetric method. In bituminous coal ashes the silicon, aluminum, and iron calculated as oxides often make up about 90 percent of the ash.

Jan 1, 1969

By Timothy W. Ellis, Abbas H. Mirza, R. David Prengaman

Recycled lead, i.e. material produced by the recycling of lead-acid batteries, has become the primary source of lead in much of the world. This has been important to the recycled lead industry as other uses have dwindled, e.g. lead based pigments, chemicals, fuel additives, solders and CRT glasses. Presently, battery manufacturing accounts for greater than 85% of lead consumption worldwide while recycled lead accounts for approximately the same market share of lead supply. Battery manufacturing and production of recycled lead are intimately coupled. In 2007, of all the industrial base metals, lead from lead-acid batteries had the highest recycling rate in North America at greater than 95%. In this paper we will review some of the processes and technologies used in a modern lead acid battery recycling facility, and how recycled lead has become the material of choice for battery construction through the development of a recovery and refining process that exceeds the industry requirements. We will also briefly review an advanced air emissions treatment system in a modern lead recycling plant that demonstrates the feasibility of a new maximum available control technology (MACT) for secondary lead smelters.

Jan 1, 2011

By Ross W. Smith

Microorganisms are increasingly finding use in mineral processing and hydrometallurgy both for the enhancement of mineral engineering operations and for the remediation of mineral industry wastes. Some of the applications, such as biologically assisted leaching of sulfide ores and biooxidation of refractory sulfide gold ores, are established commercial processes. Others, such as the use of organisms for the removal of heavy metal ions from dilute aqueous streams, are nearing commercial application. Other uses of microorganisms are potentially possible. These include use of microorganisms in leaching non-sulfide ores, the flocculation or flotation of minerals and remediation of toxic chemicals discharged from mineral engineering operations.

Jan 1, 1993

By J. L. Bowlby

Introduction In the following discussion, boiler-feed and mine waters will be considered from the point of view of the problems arising from the chemical nature of the mineral and gaseous impurities they contain. The theories underlying some of these problems will be reviewed for the purpose of getting a clearer concept of the problems themselves. Certain terms of a chemical nature, necessary to the discussion, will be explained on the assumption that they are not generally familiar to mining engineers. Finally, an attempt will be made to correlate theory and practice, with the abject of establishing certain limits to factors relevant to the problems, and to show that these limits are justified by practical experience. The general problems occasioned by the presence of mineral and gaseous impurities in boiler-feed and mine waters are: (1) Scale formation and corrosion in boiler systems. (2) Corrosion of mine pumps and pump fittings. These will be discussed separately. Boiler Scale Typical analyses of waters available for use in steam power-plants are given in the accompanying Table (Table I). All analytical data are expressed in grains per Imperial gallon. The bicarbonates of calcium and magnesium in the raw waters are shown as normal carbonates in the Table. Substances in the first five rows constitute the encrusting solids. All the waters listed in Table I would be classified as 'very good' in the schedule of classification for boiler waters adopted by the American Association of Railway Chemists in 1887. In spite of this classification, however, the waters contain sufficient encrusting solids to cause serious scale trouble after prolonged evaporation.

Jan 1, 1934

By Mark J. Klein, A. H. Clauer

The Snoek peak induced by solute nitrogen in chromium was studied. A rapid quenching rate is required to maintain nitvogen in solution in sufficient concentrations to be detectable by internal-friction techniques. An expression for the tertninal solubility, c, of nitrogen in weight pevcent is log,,c = -4130/T + 1.05. The diffusion of nitrogen in zhromium determined by internal friction is SNOEK&apos;S theory1 of the stress-induced ordering of interstitial solute elements in the bcc lattice has been used to deduce information on the behavior of interstitials in a number of bcc metals. Under the proper conditions, internal-friction studies of "Snoek peaks" permit a determination of diffu-sivities, solubilities, and precipitation kinetics of interstitial elements. Internal-friction studies of this type have been reviewed by Nowick,&apos; Wert,= Powers and Doyle,4 and others. The behavior of interstitial atoms in Group V-A metals and iron has been rather extensively studied in this way, and results are reasonably self-consistent. However, the study of interstitial elements using internal friction in the Group VI-A metals—tungsten, molybdenum, and chromium—is much less clear. Thus far, internal-friction studies have revealed a peak in tungsten tentatively attributed to carbon5 and a peak in chromium associated with nitrogen. In chromium, Bungardt and Preisendanz6 observed a peak at 180°C for a frequency of -1 cps which they associated with nitrogen. More recently, de Morton7 determined the diffusivity of nitrogen in chromium from studies of a nitrogen peak at 160°c for a frequency of -1 cps and from elastic aftereffect measurements. The objective of this investigation was to study the nitrogen peak in greater detail, to obtain information on the behavior of nitrogen in chromium. This information is of interest because nitrogen is known to have an embrittling effect on chromium. However, efforts to deduce the role played by nitrogen in influencing the mechanical behavior of chromium are handicapped by lack of information on its behavior and distribution in chromium. EXPERIMENTAL PROCEDURES The chromium wires used in these studies were drawn from arc-melted iodide-chromium stock that had been extruded, swaged, and centerless-ground to 0.25 in.-diameter rods. Internal-friction measurements were made in an evacuated torsional pendulum similar to the one described by Kê,8 utilizing wires 0.048 to 0.030 in. in diameter. A series of analyses of the fabricated wires showed that the major impurities were approximately 100 ppm Fe and a combined interstitial content of 50 to 100 ppm C, O, N, and H. A typical interstitial analysis of the wires after processing is 15 ppm C, 2 ppm H, 50 ppm O, and < 5 ppm N. Interstitial concentrations were determined by vacuum-fusion, combustion-conductimetric, and micro-Kjeldahl analyses. In general, vacuum-fusion analysis yielded a lower nitrogen concentration than did micro-Kjeldahl analysis. For consistency, the nitrogen concentrations reported in this investigation were determined by the former method. Heat treatments were carried out by encapsulating the specimens in quartz tubes containing argon. The fabricated wires were annealed at 1150°C for 1 hr to produce uniform recrystallized grain size of about 0.015 mm. Nitrogen and carbon were added to the fabricated wires by encapsulating them in a quartz tube containing ammonia or methane, and annealing them at 1150°C for 48 hr. In some instances, carbon was also introduced by coating the wires with carbon black prior to annealing.

Jan 1, 1965

By S. Martins

The aim of this work is to compare three different results of charge motion in a modified 5ft diameter lab mill and to identify differences and similarities in these results. The lab mill is modified from tumbling a ball charge to tumbling a charge of disks. This modification replicates 2D motion. This 2D condition is measured using an instrumented disk (iDisk) and analysed using a video imaging system. The iDisk is equipped with a 3D accelerometer array and rotation rate sensors. With the help of a video system, some measured quantities are also determined externally. The results of these three predictions or measurements are presented. A discussion is included.

Jan 1, 2014

Good morning. I am very pleased to be invited to present the Opening Address to this inaugural New Zealand Minerals &amp; Mining Conference. It is indeed a pleasure to see so many representatives of this industry, which is so important to New Zealand&apos;s economy, present here today. &nbsp; I extend a warm welcome to all delegates, particularly those from outside New Zealand. To those of you who have travelled from offshore, please closely observe our industry, and do not hesitate to ask Crown Minerals staff here for any further information you may want. I trust you will soon come to the same conclusion that my two following speakers have; that New Zealand is a good investment destination, and further that many of you will decide to invest in New Zealand&apos;s minerals and mining industry. &nbsp; In New Zealand the minerals industry - minerals, coal and petroleum - together constitute an approximate $2.5 billion per year business. In broad terms this is about 3% of our Gross Domestic Product.

Jan 1, 1997

Page The Cobaltchromium Binary System (paper by A. R. Elsea, A. B. \Yesterman, and G. K. Manning, Met. Tech. June, 1948, Mechanism of Precipitation in a Permanent Magnet Alloy (paper by A. H. Geisler and J. B. Newkirk, Met. Tech. Aug. 1948, Tp 2444)................................................................................................. 300 Some Effects of Applied Stresses on Precipitation Phenomena (~aper by W. L. Finlay and W. R. Hibbard, Jr., Met. Tech. Sept. 1948, Tp 2470)....................................................................................... 301 Diffusion of Carbon in Austenite with a Discontinuity in Composition (paper by L. S. Darken, Met. Tech. Sept. 1948, TP 2443) 304 An Electron Diffraction Study of Oxide Films Formed on Nickelchromium Alloys (paper by J. W. Hickman and E. A. Gul- bramen, Met. Tech. June 1948, Tp 2372)..................................................................... 305 An Electron Diffraction Study of Oxide Films Formed on Copper-nickel Alloys at Elevated Temperatures (paper by J. W. Hickman and E. A. Gulbransen, Met. Tech. June 1948, TP 2391)................................................ 307 Decarburization of Chrome Nickel Alloys by Their Surface Oxides in High Vacua and at Elevated Temperatures (paper by E. A. Gulbransen, W. S. Wysong, and K. Andrew, Met. Tech. Sept. 1948, TP 2438)................................ 307 Fractographic Study of Cast Molybdenum (paper by C. A. Zapffe, F. K. Landgraf and C. 0. Worden, Met. Tech. Aug. 1948, TP 2421)................................................................................................. 308 Effect of Composition on Grain Growth in Aluminum-magnesium Solid Solutions (paper by L. J. Demer and P. A. Beck. Met. Tech. June 1948, TP 2374)............................................................................. 309 Effect of a Dispersed Phase on Grain Growth in Al-Mn Alloys (paper by P. A. Beck, M. L. Holzworth and P. Sperry, Met. Tech. Sept. 1948, TP 2475)................................................................................. 310 Statistical Rate Theory of Metals—Mechanism of Flow and Application to Tensile Properties (paper by J. W. Fredrickson and H. Eyring, Met. Tech. Aug. 1948, TP 2423)............................................................... 315 Nucleation of Slip Bands (paper by J. G. Leschen, R. P. Carreker, and J. H. Hollomon, Met. Tech. Sept. 1948, TP 2476) and.. 318 Transient Plastic Deformation (paper by R. P. Carreker, J. G. Leschen, and J. D. Lubahn, Met. Tech. Sept. 1948, TP 2477).. 318 Plastic Deformation of Large Grained Copper Specimens (paper by W. R. Hibbard, Jr., Met. Tech. Sept. 1948, TP 2469). ... 323 Plastic Flow in Anisotropic Sheet Steel (paper by L. R. Jackson, K. F. Smith, and W. T. Lankford, Met. Tech. Aug. 1948, TP 2440)................................................................................................. 323 The Effect of Thermal-mechanical History on the Strain Hardening of Metals (paper by J. E. Dorn, A. Goldberg, and T. E. Tietz, Met. Tech. Sept. l948, TP 2445)....................................................................... 325 The Room and Elevated Temperature Properties of Some Sand Cast Magnesium-base Alloys Containing Zinc (paper by T. E. Leontis, Met. Tech. June 1948, TP 2371)..............................................................., 327 The Low Temperature Properties of Tin and Tin-lead Alloys (paper by H. S. Kalish and F. J. Dunkerley, Met. Tech. Sept. 1948, TP 2442)............................................................................................335 Thermal and Electrical Properties of Ductile Titanium (paper by E. S. Greiner and W. C. Ellis, Met. Tech. Sept. 1948, TP 2466).................................................................................................... 335 Property Changes during Aging (paper by A. H. Geisler, Met. Tech. Aug. 1948, TP 2436)............................... 337 Factors Affecting the Tensile Notch Sensitivity of Magnesium Alloy Extrusions (paper by I. Cornet, Met. Tech. Aug. 1948, TP 2419)................................................................................................. 338 Effect of Grain Size on Tensile Strength, Elongation and Endurance Limit of Deep Drawing Brass (paper by H. L. Walker and W. J. Craig, Met. Tech. Sept. 1948, TP 2478)............................................................. 339 A Copper-base Alloy Containing Iron as a High-strength, Highconductivity Wire Material (paper by W. Hodge, R. I. Jaffee, J. G. Dunleavy, and H. R. Ogden, Met. Tech. Aug. 1948, TP 2422).............................................. 340 A High Strength-High Conductivity Copper-silver Alloy Wire (paper by W. Hodge, R. I. Jaffee, J. G. Dunleavy, and H. R. Ogden, Mel. Tech. June 1948, TP 2366)...................................................................... 340 The Effect of Chronlium on the Ma Point (paper by J. B. Bassett and E. S. Rowland, Met. Tech. Aug. 1948, TP 2417.... 341 The Kappa Eutectoid Transformation in the Copper-silicon System (paper by W. R. Hibbard, Jr., G. H. Eichelman, Jr., and W. P. Saunders, Met. Tech. Sept. 1948, TP 2441).............................................................. 343 Stabilization of the Ausknite-martensite Transformation (paper by W. R. Harris, Jr. and M. Cohen, Met. Tech. Sept. 1948, TP 2446)................................................................................................ 344 Secondary Hardening of Tempered Martensitic Alloy Steel (paper by W. Crafts and J. L. Lamont. Mel. Tech. Sept. 194,8, TP 2439)................................................................................................. 345

Jan 1, 1950

Discussion of the paper of MANUEL EISSLER, presented at the New York meeting, February, 1915, and printed in Bulletin. No. 9.5, November, 1914, pp. 3661 to 2703. J. W. RICHARDS, So. Bethlehem, Pa.-I do not see in the paper a description of the Mabuki hearth as used for ore smelting. I noticed it described for concentrating matte, but I believe the older Japanese process was to use it for-smelting directly, by a pyritic smelting and Bessemerizing all in one operation, in the same simple hearth apparatus. There is a monograph published in German, on Copper-Ore Smelting in the Mabuki Hearth. At Ashio the practice of injecting bituminous coal at the, tuyères is noteworthy. It is very interesting to see two men load little cartridges on the end. of an iron rod with bituminous coal, and push them into the furnace tuyères, and with a piston inject 2 or 3 lb.. of bituminous

Jan 5, 1915

By M. J. Oliver, A. J. Nugent

Hydrogen Peroxide and Caro's Acid (H2so5) were used to treat cyanide containjng effluents. Significant reagent savings were achieved by using Caro's Acid. Weak Acid Dissociable (W.A.D.) cyanides were removed at near stoichiometric levels of Caro's Acid. Hydrogen Peroxide showed poorer efficiency in the presence of W.A.D. cyanide complexes, resulting in higher consumption rates. By using Caro's Acid, reaction catalyst requirements ar(! el.iminatnd, react.ion I.imes significant.I y rnduced and capita] costs for an effluent lreal.ment facility are minimal. The Efflox* Process ut ilisc�s this more efficienl oxidising reagent in a treatment system exhibiting a simple non proprietary control system with minimal peroxygen consumptions.

Jan 1, 1991

By Luciano Lobo de Almeida Baracho

O presente trabalho teve como foco principal à análise do efeito da adição padrão da liga inoculante (FeSi T2) no tratamento do ferro fundido nodular fabricado pela BR Metals Fundições (Barra do Piraí / RJ, Brasil). Avaliando-se assim, com análises químicas, as pastilhas retiradas associadas aos corpos de prova em formato de cunha, e análise metalográfica destes últimos, o efeito do processo de inoculação padrão através da correlação de amostras inicialmente não inoculadas e após o tratamento de inoculação e nodularização. Foi possível observar efeitos da inoculação em função do tempo de fading, que diminui a quantidade de nódulos (nódulos/mm²). Tendo como base os dados na literatura de produção de ferro fundido, onde indica que o tempo de fading faz com que ocorra a diminuição nas partículas ativas para nucleação de grafita livre.

Aug 16, 2017

Delivering Our Products On any given day in North America, 80 kilometers of rail cars are engaged in moving our product. Global Customer Base Our business accounts for more than 30% of all bulk goods moved through the Port of Vancouver

May 1, 2006

By A. A. Brant

Self-potential methods are based ?on measurements on the surface of voltage distributions caused by natural sub-surface oxidation phenomena. The attempt is made to. correlate voltage minima or maxima with the location of mineral materials or geological conditions which may give rise to such naturally produced spontaneous potentials. Any orebody undergoing oxidation is a source of electric current. Ground waters carrying free oxygen attack the upper surface of the body, rendering this the positive pole of a galvanic cell, with the lower portion of the body the negative pole and the surrounding weak acidic waters the electrolyte. Current flow is from positive to negative through the orebody and negative to positive through the electrolyte, i.e., through the surrounding rock. The upper end of a steeply dipping, tabular orebody is hence indicated as lying below the point on the surface where the largest negative potential is observed(l). From its basis, it is apparent that the self-potential method was developed primarily for ore exploration.

Jan 1, 1942

By A. T. Coumbe

The first survey 3/ covering sales of liquefied petroleum gases was made in 1930 by the Bureau of Mines, which at the time was under the United States Department of Commerce. This original canvass covered national totals for 1922 through 1929, and most of the supply came from natural gasoline plants. The 1930 report showed approximate totals for butane and propane and for butane-propane mixtures and pentane grouped together. No attempt was made to breakdown the national sales by various uses until 1931, when the quantities for domestic or household consumption, gas manufacturing, and industrial requirements, including miscellaneous uses were indicated. As the market for these liquid petroleum gases expanded and as new uses came into importance, their respective quantities were shown separately in the annual survey. Sales for internal-combustion engine fuel and for raw material for chemical plants were first taken out of the industrial total in 1936. During World War II liquefied petroleum gases became important as feed stock diverted to synthetic rubber plants, and consequently the survey was broadened to cover this particular demand, beginning in 1944. Pentane was dropped from the survey after 1943, as, being liquid at atmospheric pressure, it is not considered as one of the liquefied petroleum gases and furthermore, the quantity reported made up less than 1 percent of the total sales. Thirteen producing companies reported to the Bureau in the first survey made in 1930, and in the 1952 canvass about 130 producers--petroleum refiners and natural gasoline companies--and about 1,300 dealers cooperated by filing schedules showing a breakdown of their sales. Their 1952 deliveries of approximately 4.5 billion gallons of liquefied petroleum gases were equivalent to about 3.4 billion gallons of gasoline or 3.1 billion gallons of distillate fuel oil.

Jan 1, 1954

By N. Kanari

The kinetics of oxychlorination of MgO by Cl2+O2 was studied in the temperature range of 850 °C - 1025 °C, using thermogravimetric analysis. The effects of C12/02 ratio, gas velocity, temperature and partial pressure of reactive gases on the reaction rate were investigated. The oxychlorination process was characterized by an apparent activation energy of about 214 kJ/mol. The reaction orders with respect to C12+O2. C12 and O2 at 950 °C were about 0.65.0.98, and -0.37, respectively. Some data about oxychlorination kinetics of MgO, Cr2O3, and MgCr2O4 contained in chromite were compared. Efficiency of using oxychlorination for the removal of iron oxides contained in magnesia was demonstrated.

Jan 1, 1999

By Pedro Hugo Tumialán de la Cruz

Dado que el Perú es uno de los países que cuenta con muchos recursos de yacimientos polimetálicos, el presente texto señala los aspectos que comprenden su metalogenia. Dentro de la mineralización de polimetálicos tenemos los siguientes tipos de yacimientos: aquellos relacionados con inyección magmática de composición intermedia a félsica y a la posible inyección de magma ultrabásico, pórfidos de cobre-oro-molibdeno y de cobre-molibdeno, yacimientos de molibdeno, tipo skarn,de reemplazamiento y relleno en caliza, de diseminación de oro de grano muy fino en caliza tipo Carlín, de oro y plata en areniscas-cuarcitas-pizarras, los cordilleranos, de tungsteno, de estaño en intrusivo félsico, volcánicos continentales como los yacimientos filonianos epitermales de plata-oro, los diseminados de oro y plata de baja ley y alta sulfuración, de antimonio, diseminados de oro-plata en intrusivos de composición intermedia, los volcanogénicos marinos de sulfuros masivos tipo Kuroco, tipo Missippi Valley y los lavaderos de oro.Se considerancomo épocas metalogenéticas de estos yacimientos polimetálicos edades de mineralización del Pérmico, Cretáceo Medio, Cretáceo Superior, Paleógeno, Neógeno, Cuaternario.

Jan 1, 2014

By w. w. Milde

"Since its startup in 1975, the Rabbit Lake mill has been modified (0 process both increased tonnage and higher grade ore. Ore initially came from the Rabbit Lake pit . In 1985, a major mill expansion was commissioned to allow treatment of B-zone pit ore, which is mineralogically and metallurgically different fromRabbit Lake pit ore.Mill modifications, and the changing ore characteristics and processing targets which made them necessary, are described. Mill LocationThe mill complex, shown in Figure I, comprised of milling facilities, acid plant, power generation , warehouse and administration offices, is located approximately 1.5 Ian south of the Rabbit Lake pit, and about 8 Ian southwest of the B-zone open pit mine.Original Milling CircuitOre feed to the mill commenced June 10, 1975. The mill was designed to process 1500 tonnes per day , 483 000 tonnes per year with an average grade of O.44OJo Ups and an annual production of 2000 tonnes UPs&apos; Run-of-mine ore was dumped directly onto a 60 em square opening grizzly. Oversize was broken with an Ingersoll-Rand hydrauli c rock breaker. Minus 60 cm ore was fed to a 6 m diameter by 1.8 m long Hardinge semi-autogenous (SAG) grate discharge mill. Mill discharge was screened over a Tyler double-deck vibrating screen, with screen oversize returned to the SAG mill feed chute via conveyor belt. Screen undersize (minus 2.4 mm) was pumped to 51 cm diameter Krebs cyclones in closed circuit with the SAG mill. Cyclone overflow (about 50% minus 74 micron) was thickened to 55% solids in a 30 m diameter neutral thickener .Thickened pulp was stored in two mechanically-agitated wood stave tanks (5.5 m diameter by 6 m high), to which sulphuric acid was added to obtain a pH range of 1.5 to 2.0. The fmalleaching was carried out in five more identical tanks. Sulphuric acid and sodium chlorate were used to maintain a pH of 1.5 and a terminal emf of -450 to -500 mV. Steam sparge was utilized to obtain a temperature of 45°C."

Jan 1, 1989

By AIME AIME

THE petroleum engineers have the conference habit. They drop in, thresh things over, and drop out. No time is wasted. So it was at the Fort Worth meeting of the Petroleum Division, Thursday and Friday, Oct. 8 and 9; headquarters, Blackstone Hotel. Associate Chairman Albertson arrived the morning of the 7th, to tie in any loose ends of the technical program. S. M. Greenidge, chairman of the local committee, checked the arrangements with his committeemen at a luncheon that noon. By mid-afternoon the next day&apos;s attendance was anybody&apos;s guess-there were no noses to count. But when the gavel sounded Thursday morning 175 members and guests were present, also the official A.I.M.E. party consisting of President Lovejoy, Secretary Parsons, and George Otis Smith. Shortly after adjournment Friday afternoon all but a handful had vamoosed, lit out, disap¬peared. But, in the meantime, it was a grand conference, attendance maximum every session, and the discussion fast and furious. The discussion came from all over the floor, sometimes as good-natured sniping, sometimes in long volleys that were almost fatal to the reporter. Everyone knew his subject and few there were who had nothing to say.

Jan 1, 1936

By Tamas Kekesi, Gergo Rimaszeki, Tibor Kulcsar

The efficient purification of soldering waste material can be achieved in a single operational step by the electrolytic refining in pure hydrochloric acid - tin-chloride media. The complex formation of the ionic species may offer a beneficial level of natural inhibition. Using the PCR (periodic current reversal) technology, is efficient in affecting the morphology of the cathodic deposit. In order to optimize the process, the investigation of the solution stability and the electrode reactions is essential. The natural tendency of the Sn(II) oxidation and precipitation can be overcome by properly controlling the concentration of the main components and the ratio of Sn(IV)/Sn(II) in the electrolyte solution. Polarization curves were obtained for different concentrations tin and hydrochloric acid. Conclusions referring to the electrode reaction were derived from the overvoltage - current plots. The morphology of the deposit can be correlated with the exchange current density, also determined from the polarization curves. The cathodic current efficiency and the morphology of deposited metal are affected by the distribution of tin species and the principal electrolysis parameters.

Jan 1, 2011