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By W. W. Rudolph, L. N. Trevani, P. R. Tremaine

UV-visible spectroscopy, Raman spectroscopy, and vibrating tube densimetry have been used in our laboratory to determine equilibrium constants of aqueous species at temperatures as high as 325 °C. The UV-visible and Raman spectra of solutions containing metal complexes and ionized acids or bases can be used to yield formation constants by applying curve fitting methods to resolve the contribution of each species. Colorimetric pH indicators identified by Johnston and coworkers at the University of Texas (Austin) provide an alternative means of determining ionization constants and the pH of complex mixtures. High precision density measurements over the same range yield standard partial molar volumes, which are key parameters for "equations of state" for aqueous species. Examples are given for the copper-ammonia system, simple carboxylic acids, and the iron-sulphate system.

Jan 1, 2004

By Gökhan Çevikbilen, Ümit Karadoğan, Sevde Korkut, Berrak Teymur

This study proposes a methodology for dewatering of mine waste using a multistage process, combining geotextile tubes and anionic polyacrylamide (PAM), which accelerates the recycling process of water for aggregate mine waste facilities. For this purpose, waste from a rock quarry located in Istanbul was investigated. Flocculation tests revealed that the use of anionic PAM at an optimum dosage reduced sedimentation time and decreased turbidity. The compatibility of geotextiles and mine waste conditioned with different dosages of the effective PAM was evaluated by rapid dewatering tests, considering the water content of the filter cake, amount of infiltrated solid content, and rate of filtration. Geotextile dewatering tests were also performed on PAM-free and conditioned suspensions. The dewatering process was optimized by the use of a geotextile tube in two stages: (i) on the unconditioned suspension and (ii) on recovered PAM-conditioned leachate. Directing PAM-free non-hazardous soil-based material obtained in stage i to alternative beneficial uses is suggested, to minimize the volume of waste. Furthermore, recycling of the effluent obtained at the second stage of the proposed method will ensure more efficient water reuse

Sep 29, 2022

By Marquez W

Trace fossils have been found in Bolivian Silurian sediments in "La Iumhre" area close to La Paz-Bolivia.Tracks, are good indicators of depth and environment. A detailed study of the ichnogenus is made.The depth and environmental deposits are analyzed to determine the facies. It was shown that the trace fossils of Silurian sediments in La Paz belong to the Zoophvcos and Nereites facies.

Jan 1, 1990

The nickel operations at Kambalda consist of mining thin massive to disseminated Ni sulphide orebodies from 10 individual mines of variable grade.Daily sampling involves visual estimation of the grade of working faces based on geological parameters. This system of grade estimation is used as a guide for daily grade control only.Nickel metal allocation is based on an external sampling system. As all ore sources are blended at the primary crusher, only one calculated mill head grade is available. Therefore all sources are sampled prior to crushing. This system historically consisted of mechanically grab sampling ore from trucks as they passed over a weighbridge on arrival at the concentrator. Currently the system involves diverting one out of every ten trucks to its mine sample stockpile, which is crushed through the primary, secondary and tertiary crushing system fortnightly. The individual mine grades are re-combined to create a total sample grade. This is reconciled against the calculated mill head grade. The reconciliation factor is applied uniformly to all individual mine sample grades to calculate mill reconciled mine grades.

Jan 1, 1990

By Hara Y, Arino S, Nakamura M, Tachimori M

The theoretical and experimental studies have been done to clarify the hearth flow of iron and slag. The results of dissections show that the hearth can be treated as a packed bed of coke hav- ing good permeability with a coke-free layer at the bottom of the hearth. 3-dimensional numerical calculations of hearth flow with and without a coke-free layer are carried out, and the results are assured by a water model simulation. The influences of a coke-free layer on the iron flow and the discharge route of iron and slag are examined. The 3-dimensional flow pattern can be represented simply by the travelling time, which depends on characteristically the profile of coke-free layer and the quantity of iron in the hearth. Those flow parameters could be obtained by the results of radioisotope tracer test ( Co for iron flow, and Sc for slag flow) at several furnaces. As a result, it is found that the coke-free layer repeats the cycle of appearance and disappearance at several-month intervals. This cycle corres- ponds to large temperature fluctuation at the bottom of hearth. The relation between iron flow and skull (solidified iron, coke and deposited graphite mixed layer) on the hearth brick was studied by the model experiment and the thermal analysis based on the indications of thermocouples installed in the bottom of the hearth. If a thin coke-free layer is formed on the skull, a fast iron flow is generated in the layer, and melts away the skull. The growth and melting of skull produces the fluctuation of thermal load on a bottom brick, causing brick Damage.

Jan 1, 1981

The effectiveness of three different types of longwall chock under the three different types of geological conditions worked recently is outlined. Some provisional analyses of the variation of chock load under the shale roof con- dition are briefly discussed and some problems and solutions of gateway and road- head support outlined.

Jan 1, 1974

By Aureo D. V. Machado

An experimental study to obtain zirconia powders (ZrOz) from carboxylate zirconium solutions followed by hydrogen peroxide stripping and precipitation, has been carried out. Zirconium carboxylate was prepared by solvent extraction from a chloride aqueous phase using magnesium carboxylate as organic phase. The variables examined in the precipitation reaction were: Temperature: 25 - 90 ?C ? H202= concentration: 0.3 - 5% wt/wt - pH: 1 ? 9 Organic/Aqueous ratio (1/1) and reaction time (30 minutes) were maintained at constant levels. The optimum results (98% precipitation) were achieved at 25 °C, 5 % wt/wt H202=, and pH = 5. The precipitates were composed of large amorphous aggregates (<I00 micrometers). After calcination for 1 hour at 1000 OC, monoclinic ZrO2 with a large variation in particle size (1 -100 micrometers) was obtained.

Jan 1, 1991

By Askew JE

The large, massive low grade gold orebody at Mount Charlotte has demanded an innovative approach to mining engineering. In the last five years several advances occurred in the areas of rock mechanics, mass blasting, blasthole drilling and truck haulage.Successive crown pillar failures throughout the life of the mine had resulted in a continuous geotechnical program, mostly utilisingconsultants. The culmination of this workwas the development of a successful crown pillar support system. Several stopes have incorporated the technique and the most notable success has been the relatively large F3 crown pillar.In hole hammer drilling was introduced to the mine in 1979, but little work had been done to develop a blasting system to suit the 165mm diameter holes. A non-electric sequential blasting system was adapted for use at themine and up to 600,000 tonnes have been fired successfully in an individual blast. Problems with ground vibration were addressed although this work remains incomplete.

Jan 1, 1984

By Greenhalgh L. P H

The opportunities offered by an increasingly volatile world invite the international consultant or engineering services contractor to broaden attitudes, diversify interests, expand capabilities, retain and develop specialist skills and base judgements upon sound principles and solid experience. The wide-ranging scope of this review reflects such a change but the topics of discussion are not intended to be exhaustive or to detract from many other current developments.The subject of environmental protection, effluent control and pollution prevention is a primary consideration in the application of many mineral processing technologies but is not covered here. There is an array of developments relating to noxious gas emissions and toxic wastes and the paramount importance of this matter justifies comprehensive conferences dedicated solely to the application of suitable measures. This review concentrates therefore on the main stream processing techniques for the primary recovery of values.

Jan 1, 1993

By C. H. Mathewson

MicrOscopic metallography has been exploited quite well enough to bring about a very general understanding that the typical metal or alloy is composed of minute crystalline particles blended into a coherent rnicrostructural rnosaic. One does not have to be a specialist in metallography to realize that the properties of such an aggregate are essentially a summation in appropriate form of individual effects derived from the shape, size, placement or orientation and cohesive characteristics of the component particles. It is clearly of great importance to consider the various forms of discontinuity which may occur at the boundaries between these crystalline particles. When a number of particles each possessing the same orderly arrangement of atoms are brought together into a close-fitting system of purely haphazard contacts, not unlike a handful of snowflakes compacted into a snowball, the particles are said to possess random orientation. There are no generally accepted views concerning the arrangement of the atoms or the constitutional reaction between atoms where one crystal meets another, but these contact regions are characterized by strength rather than weakness and it is customary to require the presence of many rather than few boundaries in preparing metal for useful service. Under certain circumstances all of the particles in a metal may be nearly alike in orientation. Other general tendencies of orientation may be associated with particular forms of mechanical and thermal treatment. In contrast with these cases of fortuitous or statistical diversity of orientation, we often find adjacent particles united along a plane which possesses a grouping of atoms belonging equally well to both structures. This, of course, determines a fixed relationship between the two orientatjions and it is always possible to derive one from the other by some form of- rotation or reflection prescribed by the symmetry of the crystal structure under consideration. Particles united in this manner are known as twin crystals although the term refers to the form of association rather than the number of individuals concerned.

Jan 1, 1928

By D. L. Paulson

The Bureau of Mines studied the feasibility of producing copper matte in an electric furnace from blends of copper concentrate similar to those currently smelted in a gas-fired reverberatory system at an installation in Tacoma, Wash. A 800-kva electric-arc furnace was used to determine the distribution of constituents when arseniferous concentrates are being smelted in an electric-arc furnace. Test results from smelting 40 tons of materials indicated that electric smelting is more like a conventional gas-fired system than originally expected. Although gas composition over the molten bath is much different in an electric furnace, the secondary constituents such as arsenic, lead, zinc, and antimony behaved the same as in a reverberatory furnace. The results established that an electric furnace would be compatible with sulfur and particulate recovery facilities that are being used.

Jan 1, 1976

By Joaquim Luiz Monteiro de Barros Júnior

Este trabalho tem como objetivo principal apresentar de forma didática e com um exemplo prático a viabilidade da instalação de turbinas TRT, com a finalidade de gerar energia elétrica em plantas siderúrgicas.

Oct 30, 2017

By Larissa Koroznikova, Steve Durkin, Patrick Bouwmeester, Michael Tuck

In currently used mining methods, blasting techniques often causes dilution of valuable ore and results in costly processing requirements. In the context of narrow vein mining of thin and highly concentrated orebodies there is a need of a mining method that can reduce dilution in order to remain economically viable. This research project explored the viability of a new mining technology, thermal fragmentation, in narrow vein mining. Thermal fragmentation technology uses a flame jet to produce extreme heat that spalls the surrounding rock to a strategically located drill hole, as an alternative to traditional blasting. This paper creates a net present value (NPV) model of a mining method using thermal fragmentation, as well as for an existing method used for narrow vein mining; comparisons and evaluations were made regarding the feasibility of the new technology. It was found that while overall costs for thermal fragmentation were relatively high, reductions in wages, haulage and processing costs, as well as increased productivity and ore recovery, meant that the new method would improve the financial performance of any operation. These results identify that there is an opportunity to introduce the thermal fragmentation technology to narrow vein mines within Australia, in order to lower costs and increase profit.

By Yaniuk DW

The sampling of non-ferrous concentrates from trucks and trains has long been carried out either manually or by automatic spears. Very little use has been made of conventional sampling systems for sampling concentrates at transfer points, or cross-belt samplers for sampling from the belt as the concentrate moves along the conveyor.Due to the high value of base metal concentrates and the often extremely heterogeneous nature of the material it is imperative that the sampling procedures adopted are accurate and precise. The basic principle that all particles in the stream have an equal opportunity to be included in the final sample is not fulfilled by accepted traditional concentrate sampling procedures such as the spearing of wagons, trucks or streams. This may lead to significant bias being introduced into the final sample.Consequently, the application of correct sampling procedures, either with conventional cross-stream samplers or the newer cross-belt samplers, is of prime importance.SGS Australia has recently installed a number of cross-belt samplers for the sampling of base metal concentrates both in Australia and overseas. The application of these samplers will be discussed with emphasis on the benefits of their use.

Jan 1, 1976

By Nott M. C

The oxidation of xanthate collectors to xanthate/dixanthogen results in a higher hydrophobicity of sulphide minerals surfaces due to the action of dixanthogen. This higher hydrophobicity can be proved on a fundamental level by examining the st

Jan 1, 1994

By J. Mizrahi, A. M. Baniel, A. Mitzmager, S. Star

This article gives an account of the latest developments in the use of TBE for sink-float separation of silicate minerals. A number of minerals for which the process has been tested and found suitable are reviewed. Specific examples are discussed in relation to the particular problems of sink-float separation and recovery of TBE as compared with non-silicate minerals. The economic aspects are outlined. Silica and silicates comprise the most common and abundant group of minerals, and since they are present in variable amounts in most ores, they constitute an appropriate subject for the review and discussion of the recent developments in the use of TBE for mineral concentration. The silicates considered as a group have an extremely wide range of chemical and physical properties. Some of these properties, which are common to all minerals, are of importance to concentration by TBE and are discussed in some detail in this paper, as well as the development of methods and apparatus for concentration and recovery of TBE and several examples of concentration of silicates. PROPERTIES OF MINERALS WITH RESPECT TO CONCENTRATION BY TBE The properties considered as most important to concentration by TBE are specific gravity, structure, surface and shape. The specific gravity of a mineral is a fundamental property and is constant between very close limits for the same species of different sources if particles are pure and free from cavities or cracks. In many species, however, solid inclusions and changes in chemical composition due to replacement of elements cause variations in the specific gravity. The plagio-clase series of feldspars between albite and anorthite illustrate this point (specific gravity from 2.60 to 2.77). Fig. 1 shows the specific gravity distribution of some of the common silicate minerals.&apos; The highest specific gravity is about 4.7 (zircon) and the lowest is 2.0 (sepiolite), with most of them ranging between 2.6 and 3.5. Although most of the silicates given in Fig. 1 are found as constituents of rocks, those generally considered as rock making minerals are comparatively few. They include quartz, feldspars, nephelite, sodalite, leucite, mica, pyroxenes, amphiboles, chrysolite, kaolin, talc and serpentine. These minerals may appear in igneous rocks as coarse crystals in granites, syenites and diorites or as very fine grained dispersions in basalt and felsite. When the latter rocks occur in an ore, their specific gravities depend on the minerals present and structure. The same is true for the sedimentary and metamorphic rocks (sandstones, shales, gneiss, slate, schists). A comparison of specific gravities for the minerals listed in Fig. 1 with that of TBE (see Table I) shows that the important rock-forming minerals, with the exception of pyroxenes, amphiboles and chrysolite (olivine), lie in the specific gravity range of less than 2.96 and can therefore be separated by TBE. The ore structure is important both in determining the apparent specific gravity and the efficiency of TBE recovery. The structure can be compact (as in

Jan 1, 1963

Since the comprehensive review of the Persian fields presented by Sir John Cadman last year, operations have proceeded normally. No developments of especial importance fall to be recorded and it remains only to bring up to date the full information given at the beginning of 1933. Controlled production from the Masjid-i-Sulaiman and Haft Kel fields has been maintained at slightly higher rates than during 1932. The figures for the past five years are as follows: These represent crude oil and products piped to the coast but exclude products reinjected into the reservoir, a process that has been in continuous operation at Masjid-i-Sulaiman during the period under review. The systematic delimitation of the Haft Kel field has been continued during the past year and results have been sufficiently encouraging to justify the inception of a wider scheme for distribution of production. Drilling has been resumed recently in the Persian sector of the Naft Khaneh field, and preliminary survey work is in progress for the selection of a site for a refinery at Kermanshah arid the construction of a connecting pipe line. Investigations in connection with the scientific control of reservoir were dealt with in considerable detail in last year&apos;s review. This work has been steadily pursued during 1933 and certain of the investigations have been the subject of papers presented to the World Petroleum Congress held in London in July of last year.

Jan 1, 1934

By Murakami T, Tamiya M, Mizokawa T, Matsumoto T

In the expansion program of the iron ore pelletizing plant at Kakogawa Works of Kobe Steel Ltd., an automatic computer control of products fineness on grinding department is practised. The main problem of the process control of a grinding system is scattering of measured fineness values of products. The scattering comes from the inherent nature of grinding systems, sampled powders and measuring systems. A method is developed to presume the exact status of the plant from scattering products (fineness values and to achieve a stable con trollability of the plant by utilizing the computer. An on-line fineness analyzer, an automatic sampling device and vari-speed air separators are also developed to compose the automatic grinding plant. This report introduces the fundamental epts and results of the automatic fineness rol system of the grinding plant.

Jan 1, 1977

By Yongjun Peng, Yufan Mu

Pyrite depression in the flotation of copper ores is difficult due to the activation of Cu2+ ions on pyrite surface. In this study, the radical chain reaction involving the redox cycling of Cu(I/II) induced by sodium metabisulphite (MBS) was exploited to selectively depress the flotation of copper-activated pyrite at pH 8.0. Electrochemical measurements revealed that the presence of Cu2+ and O2 was essential to the formation of SO•− 5 through sulphite oxidation, the main entity to convert the activating species Cu(I)S on pyrite to Cu(II)-hydroxide/sulphate, causing deactivation of pyrite. The depression role ofMBS on pyrite flotation was closely associated with the type of grinding media which affected the electrochemical conditions of flotation. When forged steel was used as the grinding media, a high dosage of MBS was required to depress pyrite, but a low dosage of MBS could almost completely depressed pyrite when high chrome steel grinding media was used. This is because high chrome steel produced a stronger oxidation condition with a higher amount of Cu2+ and O2 which promoted the formation of SO•− 5

Jan 26, 2021

By GEORGE W. HARHIS

IN the earlier period of anthracite-ruining, much coal was wasted, both underground and in the culm-banks on the surface. Such waste is common in the development of new mining districts, in which, as a rule, only the richest material can be profitably treated. In the anthracite-region, special causes operated to increase this evil. The mines were generally operated under 20-year leases, and royalties were paid upon such coal only as was actually marketed. The lessees consequently cared for immediate profit only. They were- not bound to win all the coal they exposed, or to leave it in such condition that their successors could win it. Nor was it their interest or duty to educate consumers in the use of their product. The market called for coal of large sizes ; and such coal they furnished, throwing away the rest. Any pains taken by them to bring about a more rational use of coal by their consumers would have borne fruit, after their leases had expired, to the benefit of somebody else. A full statement of the situation wits given in 1893, in the report of the State Commission, appointed in 1889 to investigate the subject.` That body included the names of Heber S. Thompson, William Griffith and the late Eckley B. Coxe.2 Its report gives special attention to the utilization of the old culm-banks.

Nov 1, 1905