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By Jack L. Henry

The monocarbide region of the ternary system U-C-O has been investigated at 1,700° C as the first phase of a more extensive study of a portion of the four-component system U-C-O-N. An area bounded by the following compositional limits in atomic percent was studied: U, 44 to 55; C, 30 to 60; 0, 0.2 to 20. Compacts composed of mixtures of uranium, graphite, and uranium dioxide powders were sintered at 1,700° C under an equilibrium pressure of carbon monoxide to produce uranium oxycarbide specimens having a variety of compositions. Sintered specimens were evaluated by X-ray, chemical analysis, and ceramographic techniques. Solid-solution boundaries and phase relations have been established, and the effects of composition on the lattice parameter as well as the decomposition pressure have been investigated. Oxygen can be substituted for carbon in stoichiometric uranium monocarbide to the extent of about 17 atomic percent at 1,700° C. The composition range of the oxycarbide solid solution extends from about 48 to 51 atomic percent uranium in the low oxygen region. Above 10 atomic percent oxygen the composition range narrows to less than 1 atomic percent uranium. Carbon monoxide exists as a gaseous phase in equilibrium with all compositions which contain oxygen. Five separate phase fields were found bounding the solid-solution area. Other phases within this portion of the system include uranium, uranium dioxide, uranium dicarbide, and uranium sesquicarbide. Decomposition pressures of oxycarbide compositions at 1,700° C have been found to vary from a few microns for stoichiometric and uranium-rich compositions to 35 torr for carbon-oxygen-rich specimens. Lattice parameters were found to depend upon the U to C + 0 ratio as well upon the extent of substitution of oxygen into the stoichiometric monocarbide lattice.

Jan 1, 1967

By I. L. Feld

This Bureau of Mines report describes the development of a simple method of producing low-phosphorus hematite concentrates from certain submarginal southeastern iron ores. The investigation was undertaken to obtain additional information on the Clinton iron ore outcrops at the southwestern extremity of the Birmingham district of Alabama and to assist in the development of operating techniques that would make it profitable to use the marginal ores of this area for blast-furnace feed. Batch and continuous pilot-plant tests demonstrated that a relatively simple wet scrubbing treatment) followed by a desliming operation to reject argillaceous (clayey) gangue, consistently yielded a marketable granular hematite product. Iron losses were relatively high but could be tolerated in view of the low treatment cost.

Jan 1, 1960

By Keith D. Rosbury

The basic objective of this project was to determine the cost-effectiveness of dust control used on unpaved mine haul roads. Field testing was conducted at three surface coal mines (two in Wyoming, one in southern Illinois) for a total of 20 weeks. The highest control efficiency measured for a chemical dust suppressant, 82 percent, was for calcium chloride two weeks after application. Generally, however, the control efficiencies hovered in the 40 to 60 per-cent range over the first two weeks since application, and then decreased with time. After the fifth week, the limited number of data points suggest a control efficiency of less than 20 percent. Composite watering data were fairly uniform. Watering once per hour resulted in a TSP control efficiency of approximately 40 percent. Doubling that application rate increased the control effectiveness by about 15 percent to 55 percent. Chemical dust suppressants (primarily salts and lignons) can be shown to be more cost-effective than watering under some conditions. Delta summaries and the analysis of data are contained in Volume I. Volume II contains basic data.

Jan 1, 1983

The Lane Cove Tunnel (LCT) is an important infrastructure link in New South Wales (NSW) and runs from the end of the Gore Hill Freeway at Artarmon at its eastern extremity, to the end of the M2 at North Ryde at its western extremity.  The LCT is 3.6 km long and generally consists of twin two/three lane unidirectional tunnels running largely under Epping Road from just east of Mowbray Road, west to the western end of the Gore Hill Freeway. The tunnel opened in early 2007. The presentation will provide a summary of the traffic and emission modelling performed for selected representative surface road sections in the vicinity of the Lane Cove Tunnel. An assessment of the predicted impact of vehicle emissions on ambient air quality in the corridor as a result of changed traffic conditions due to the tunnel opening will be presented. The traffic modelling and emission calculations were undertaken for the following two scenarios: Year 2006 û Lane Cove Tunnel no-build option, and Year 2006 û Lane Cove Tunnel build option. Vehicle emission calculations for the four main pollutants from vehicles: CO, VOC, NOx and PM10 on the surface roads in the vicinity of the Lane Cove Tunnel were performed using the predicted daily traffic for the two cases (no-build and build). The analyses indicated that the vehicle emissions for all pollutants are expected to significantly reduce in the corridor with the building of the Lane Cove Tunnel, including the areas in the vicinity of all tunnel portals, when compared to vehicle emissions for the no-build case.  As a result of the decreased vehicle emissions on the surface roads, the study concluded that the actual ambient air quality is expected to improve in the corridor including the tunnel portal areas after the Lane Cove Tunnel opening.

Jan 1, 2008

By George D. Haley

This report will be given in two sections. The first sec¬tion outlines techniques and equipment to form almond shaped fluorspar briquettes by means of briquet presses, and the second section outlines techniques of the balling disc. PART I - BRIQUET PRESSES Fluorspar has been briquetted for a number of years and the so called "peach pit" briquet is known to many steelmen. Present production is estimated at over 100,000 tons annually. Slide 1 shows an assortment of various sizes and shapes of briquettes. It is possible to form fluorspar into almost any configuration of briquet. For safety on the melting floor, pillow type briquets are preferred. Ease of mechanical handling and durability of the product are facil¬itated by an almond shape. The dimensions of the almond can vary from 1-in. to 1-1/2-in. in length, from 13/16-in. to 1-in. in width and from 1/2-in. to 1-in. in thickness. The type of equipment to pro¬duce almond shaped fluorspar briquettes is shown in Slide 2. Here we have a Komarek-Greaves and Company 300 ton briquettor equipped with almond rolls. This machine is capable of producing fluorspar briquettes at a rats of 30 tons per hour with power consumption of 35 hp per ton par hour.

Jan 1, 1969

By Perry G. Cotter

The borides of the transition metals in Groups IV and VI exhibit, in addition to a certain degree of hardness, considerable resistance to heat and oxidation. They have high melting points (1,850°-3,060° C.) and low coefftcients of thermal expansion and can be bonded with other materials and hot-pressed to desired shape (cermets). Suggested uses for the borides include use in rockets and jet engines, as thermocouple protection tubes, as containers for molten metals in die casting, as flame-plated coatings on less refractory compositions to prevent erosion by hot gases, and as control rods and neutron shielding material in nuclear engineering, The Federal Bureau of Mines investigation of zirconium diboride started in 1950 at the Boulder City Nev,, Metallurgy Research Laboratory, Its purpose was to reduce the cost of raw materials for the production of zirconium diboride.

Jan 1, 1961

By William B. Plank

IN this paper are presented the results of a complete statistical survey of the enrolment, courses and degrees, and the employment situation of recent graduates in all of the 46 institutions in the United States, including Alaska, and four of the six schools in Canada that grant degrees in mineral technology. The data were collected by the writer by means of a questionnaire in December, 1933, to which all the institutions, except one, replied. Included also are data of a similar study made by the writer in May, 1933, for the S. P. E. E. summer session of mining and metallurgical teachers at the University of Wisconsin and published in the Journal of Engineering Education for December. 1933. Some of the data of a paper of the writer's entitled, "The Trend of Mineral Engineering Student Enrolment in the United States," read at the A. I. M. E. meeting on Feb. 16. 1931, are given for comparison. Acknowledgment is made to all the administrative officers of the institutions who took the time from their busy lives to supply the in- formation asked for. Their fine cooperation has alone made possible these two surveys with a completeness of detail never before attempted

Jan 1, 1934

By Hang Goo Kim

A computer simulation has been carried out to predict the distribution behavior of minor elements such as Pb. Zn, Bi, Sb and As in recently proposed copper smelting and converting processes with submerged oxygen injection in which tonnage oxygen is used with a shielding gas. In this study the technique of stepwise equilibrium modeling was employed and some of the thermodynamic data were updated or reassessed. The volatilization and slagging of undesirable elements were investigated in copper smelting (steady-state) system, copper matte converting (batch) system, and the combined (smelting + converting) system at extremly high oxygen-enrichment levels. The predicted minor-element behavior under high oxygen- enrichment was compared with that in the Noranda process (normally 42% oxygen-enrichment in smelting and 24% in converting) and the reverberatory process using air. The effects of various operating parameters such as temperature, the final matte grade in smelting, the initial matte grade in converting and the O/Fe ratio in slag on the behavior of minor elements are discussed.

Jan 1, 1991

By T. F. Dumm, O. Trass, V. R. Koka, L. G. Austin

"The size distributions of carefully screened 2 size fractions of ground materials were determined using a Microtrac laser dif-fractometer. The size distributions were fitted to the empirical function P(x) = 1/[1 + (x50/x)1] where P(x) is cumulative mass fraction less than Microtrac size, x. The standard deviation of A for a 50 second test time was approximately 0.5, so that seventeen test times give a mean with an estimated error within t 0.25 (95% confidence level). Values of were 5.44, 4.82, 4.40 for a coal ground under different conditions, indicating statistically different shape distributions; the average value for mica was 2.91 owing to the high aspect ratio of the particles. The ratio of x50 to the geometric mean sieve size was 1.2 for the coal and 0.70 for mica.1 IntroductionKoka and Trass have presented evidence [1,2] that materials ground in the Szego mill [3] give different shapes depending on the milling conditions. The variations in shape were deduced qualitatively by viewing SEM photomicrographs of selected 1/2 screen fractions. This paper quantifies their observed differences in shape by using measurements of the size distributions of screen fractions examined in a laser diffractometer [4] (Microtrac, Model 7991). The basic concept is that particles of 'a given ""screen"" size will give a wider distribution of ""Microtrac"" size when the particles are flaky with high aspect ratios, and a narrower distribution when the particles approach the cubical and spherical geometries.2 TheoryAustin and Shah [5] have shown that coal screened within a 1. 1/2 upper-to-lower sieve size range will give rise to a much wider distribution of Microtrac size. They found that the screen interval of irregular fragments of comminuted coals or quartz gave Microtrac size distributions which could be described by the simple function"

Jan 1, 1988

By P. J. Remington

Field measurements utilizing a seat pad accelerometer were made on 61 surface coal mining machines in order to quantify the vibration levels experienced by the operators. Those data were combined with information on the statistics of the operating times of those machines in order to compare the operator's vibration exposure to the criteria in ISO 2631, ?A Guide for the Evaluation of Human Exposure to Whole Body Vibration.? The comparison showed that about ha]f of all surface coal mining machine operators can be expected to be exposed to vibration exceeding the fatigue decreased proficiency criterion, whereas only on the order of 15% would be expected to experience vibration exceeding the exposure limit. Detailed exposure statistics are presented and the implications of the results are discussed.

Jan 1, 1983

By Chauncey Berrien

THE Hawkesworth detachable drill steel shank and bit were invented by A. L. Hawkesworth; while he was a mechanical foreman for the Anaconda Copper Mining Co., at Butte, Mont. Mr. Hawkesworth died on June 16, 1925, at the time that his invention was practically a proved success. The first application for patents was made by him in November, 1918, and the bit is now being manufactured under patents issued in 1922 and 1923. The credit, for its development in the early stages belongs to A. L. Hawkesworth, Roy S. Alley, Harry A. Gallwey, E. J. Bowman and various officials of the Anaconda Copper Mining Co. Later improvements, manufacturing problems and the direct usage in the mines were originated and perfected by the mechanical department under C. D. Woodward, E. R. Borcherdt, head of the Rock Drill Equipment Department, Robert E. Kelly of the Mechanical Department, and various operating department heads of the Anaconda Copper Mining Co. The author wishes to acknowledge the assistance of these officials in the preparation of this paper.

Jan 1, 1930

By D. R. Tesarik

The factor of safety, the traditional measure of stability for earth embankments, is graphically presented in factor of safety charts in this Bureau of Mines report. Factor of safety contours are drawn for homogeneous earth embankments for two contrasting situations: (1) no phreatic surface and (2) a phreatic surface that assumes 10-pct freeboard. The factor of safety can be read directly from the charts if the physical properties of the soil and the geometry of the embankment are known. The curves provide a quick first approximation of the "most stable" and "least stable" condition of the embankment. The Simplified Bishop Method was used for the safety factor calculations, and a sequence of least squares curve fitting steps was used to present the factor of safety in final chart form.

Jan 1, 1981

By R. L. Benner

The Bureau of Mines investigated the ZnO-Fe2O3-Fe3O4 system at 1,000°, 1,300°, and 1,400° C, with oxygen pressures between 1.0 and lx10-4 atmospheres. The results, divided into the thermodynamic properties as related to the spinel structure, and the thermodynamic properties as related to zinc concentrate roasting, were used to calculate the activities of ZnO, Fe2O4, and Fe3O4 within the spinel solid solution region of the ternary system, and the pseudo-binary activities of ZnFe2O4 and Fe304. The activities of both systems show large positive deviations from Raoult's Law, especially at high Fe3O4 concentrations. The free energies, the enthalpies, and the entropies of mixing for the binary system were calculated from the binary activities, and the entropies of mixing were compared with two statistical models, one representing an ideal solution, and one representing the mixing of a normal with an inverse spinel. The binary entropy of mixing seemed to be better represented by the latter statistical model, indicating that the tetrahedral and octahedral cations of the reactants tend to remain in the product, even at the high temperatures of the study. This comparison also indicated that the cations of the components are the major contributing factors to the thermodynamic properties.

Jan 1, 1966

By C. Leticia Hernández, P. Martín Reyes, D. Iván Alejandrox Reyes, L. Miguel Pérez, T. Julio Cesar Juárez, G. Mizraim Uriel Flores, T. Raúl Moreno, R. Aislinn Michelle Teja

This study shows the characterization of tailings from the mining district of Coscotitlán, State of Hidalgo, Mexico. Chemical analysis by Spectroscopy of atomic absorption (AAS) allowed to quantify the concentration of Fe, Mn, Zn, and Pb as the most abundant elements in the mineral sample; in addition to the presence of Sn, Te, Bi, Ni, Co, and Cd. The presence of precious metals as the Ag (64 g ton−1) and Au (0.65 g ton−1) were identified. The greater distribution of Ag was detected in particles with diameter of 74 lm. Species as pyrite (FeS2), galena (PbS) and hematite (Fe2O3) were observed in a matrix of quartz (SiO2) by Polarized Optical Microscopy (POM), these species were also identified by X-ray Diffraction (XRD). Both the elemental and mineralogical composition of tailings was corroborated by the technique Scanning Electron Microscopy - Energy Dispersive Microanalysis (SEM-EDS).

Mar 1, 2018

By Frank J. Cservenyak

Curtailment of bauxite importation by enemy activities during World War II focused attention on the necessity of developing domestic deposits of aluminous materials. Large quantities of aluminum ores such as kaolin, siliceous bauxites, high-iron bauxites, anorthosite, and diaspore clays are available but not readily amenable to Bayer processing because of excessive impurities. The Bayer process, which is the only commercial method in use in the United States for producing metallurgical-grade alumina, requires a high Al2O3 bauxite relatively low in SiO2 and Fe2O3. The Bureau of Mines was charged by Congress to investigate processes for the production of alumina from these low-grade ores. One part of the program was an investigation, in the laboratory and pilot plant, of the recovery of alumina by the lime-soda sinter process. Ores comprising kaolin, diasporic clays, anorthosite, and siliceous bauxites have been investigated and studied in the laboratory and pilot plant, and a series 'of reports covering these investigations has been prepared.

Jan 1, 1948

By A. Himsley, E. Byleveld

"With reference to the chemical constraints underlying the ion exchange process for uranium recovery, a generalized view is presented on the actual and the achievable efficiency of the process. The area considered is restricted to acid leach circuits in combination with nitrate, chloride or sulphuric acid elution.A comparison between actual plant results and the chemical requirements shows that:(a) Unless new and better ion exchange resins are developed, no dramatic change in equipment size and resin inventory is""anticipated. (b) Elution efficiency, especially for sulphuric acid, may be improved considerably. More concentrated eluates may beproduced at lower chemical consumption. A possibility of achieving additional purification solely by ion exchange is discussed.IntroductionThis paper presents a generalized view of the actual and the achievable efficiency of the ion exchange processes for urannium recovery. The study is restricted to acid leach circuits in combination with nitrate, chloride or sulphuric acid elution. The ultimate efficiency attainable with ion exchange is dietacted by the chemical reactions underlying the process. The most sophisticated technology cannot change the diffusion rates in the ion exchange resin nor make the uranium loading exceed its equilibrium valueThe design of an ion exchange plant for uranium recovery involves a considerable number of parameters as a result of the wide variety of pregnant solutions produced from different orebodies. Therefore, a generalized approach of the ion exchange process inevitably neglects some parameters which maylead to significant variations in apparently identical situations.The uranium concentration in the pregnant solution, together with its pH, are the principal variables which determine resin loading and residence rime in the ion exchange system. On the elution side, the type of eluant and its concentration will determine the contact time required and the amount of eluant needed to strip the resin. The temperature, the properties of the ion exchange resin, the total dissolved solids in the feed solution and the competing ions are other variables that affect the chemical performance; these, however, may be considered as a correction of the principal parameters if one is interested only in general trends."

Jan 1, 1980

By J. A. Venter

Mineralogical studies indicate the Pt-Pd-Bi-Te class to react poorly on the flotation stimuli and indications are that these minerals are slow floaters. However, recent studies performed on a number of minerals from this class indicated strong interactions with potassium ethyl xanthate resulting in the formation of dixanthogen (only one of several xanthate species). The poor flotation response is not a result of poor interaction of xanthate with the surface. It is proposed that the oxidation products of sulfides in the process water interact with the PGM surface. To test this, the effect of thiosulfate (an important oxidation product of sulfides) was investigated by employing electrochemical measurements and FTIR spectroscopy. The electrochemical investigations indicate no strong effect of thiosulfate on the interaction of xanthate with the minerals surface as well as the reduction of oxygenthiosulfate is likely not responsible for the poor flotation response of these minerals in industrial plants.

Jan 1, 2014

By Bernard G, Limpach R, Ulveling L

A major aspect in competitive ironmaking is to replace metallurgical coke by injecting alternative cheap fuels. Whereas in the past, heavy oil injection as well as on a lower scale natural gas injection have proved to be reliable, the progressing high price level of these fuels has prompted international interest in looking for alternative cheaper fuels, especially pulverized coal. Theoretical analysis and practical operations showed that for constant adiabatic flame temperature, potentially more coke may be replaced by injected coal than by heavy oil, because of less endothermic cracking of hydrogen components. Since about 1974, the ARBED-Group has been looking for alternative fuels and in 1976 came to conclusion to select for first trials pulverized lignite for the following reasons:

Jan 1, 1981

By J. S. Hansen

To advance technology that can conserve critical materials, the Bureau of Mines investigated a cast-on hard-surfacing that wear resistance and confines alloy additions to wear-prone surfaces. Wear-resistant material in form is on a polystyrene , the is embedded in a mold of unbonded s and the wear-resistant material is transferred to a cas surface at the time of For low-stress abrasion, derived from high-carbon ferro-chrome had higher wear resistance than did commercially available weld-hard. The microstructure of the was typi-white iron carbides. Free carbon added to the ferrochrome powder produced more M7C3 carbides than did material contained in surfacings made from ferrochrome alone, and improved the wear resistance. Several white iron powders with greatly reduced chromium contents also white iron contain-M7C3 carbides. One derived from white iron powder had wear resistance to that of weld-deposited hard facings. Among the parameters investigated, surfacing thickness was found to have a or influence on diffusion of elements out of the , microstructure, and wear resistance. The results of field tests on bucket-wheel excavator teeth and plowshares with cast-on hard surfacing are given.

Jan 1, 1985

By N. W. Johnson

The behavior of non-sulphide gangue in chaloopyrite flotation circuits has been investigated. Plant and laboratory tests were carried out on five different ores, and linear relationships were found to exist between the rates of recovery of water and free nonsulphide gangue in the concentrates although there was evidence from pilot plant tests that these were linear approximations to parabolic curves over the limited regions which were observed. There was evidence that the free non-sulphide gangue enters the concentrate by hydraulic classification and a classification function has been proposed to define this behavior. This function is suitable for inclusion in a mathematical model of the process.

Jan 1, 1972