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By J. D. Dixon

Procedures are given for calculating stresses in underground tunnel supports which accounts both for the structural behavior of the support and that of the adjacent rock mass. Stresses in the support are caused by service loads and rock reactions. Service loads are due to rock pressures, hydrostatic and hydraulic pressures, selfweight of the support, or other utilitarian-type loads. Rock reactions, equal and opposite those in the support, are due to the deformational interaction that results as service loads deform the tunnel support against the adjacent rock mass. The procedures developed for solving this problem are an application of matrix structural analysis. The principles involved in this method allow for the consideration of the deformable characteristics of most tunnel support systems and an iterative solution procedure is applied to determine the areas of support-rock interaction. Numerical results of example problems are given.

Jan 1, 1972

By John T. Awald

The Bradshaw Mountains of west-central Arizona cover an area of 1600 square miles and contain numerous old mines and prospects. The area has been geochemically sampled on a reconnaissance basis to relate mineralized areas to regional structure and rock types. Copper analyses of stream sediments have been classified and contoured to show the distribution of low and high backgrounds and low, intermediate, and highly anomalous areas. Contoured results are compared to geology and known mines. Several prospecting areas are indicated.

Jan 1, 1972

By C. C. Merrill

Columbium, tantalum, titanium, and zirconium are present in solid waste products generated by the chlorination of rutile used for production of titanium tetrachloride (TiC14). The columbium and tantalum were separated from titanium and zirconium by liquid-liquid extraction techniques using a secondary amine. Salts of these elements are in a leach liquor produced by water leaching of mineral waste from the chlorination of rutile. This waste, produced at the rate of approximately 50,000 tons per year, is about 40 wt pct water soluble. Leach liquors, separated by filtration, were further separated into a solid fraction and a liquid fraction by pressure hydrolysis, The solid fraction containing Cb, Ta, Ti, and Zr was dissolved in HC1-HF and used as a feed solution. Columbium and tantalum were removed from the organic extractant with 1 [N] HC1. A miniature 10-stage reactor showed that the columbium and tantalum present in solution could be separated with a continuous flow.

Jan 1, 1972

By Joseph L. Condon

High-speed movies were taken of crater experiments in two-dimensional plates of Tennessee marble to study craters being formed primarily by stress-wave action. The contribution of gas action to the cratering process was minimized because the two-dimensional models did not contain the expanding gases from the explosive. Four burdens were studied for solid plates and one burden for a segmented plate. After cratering, the plates were reassembled for dye penetrant studies of fracturing. Flyrock velocities were calculated and related to the degree of fracturing, and compared with those from quarry shots. In general, the smallest burdens produced the highest flyrock velocities and the least amount of fracturing. Flyrock velocities compared favorably with initial flyrock velocities in quarry blasts, but did not show step accelerations due to gas effects as did the quarry blasts. The test with a segmented plate was used to simulate cratering in a jointed material and showed that stress-wave effects can be important for crater formation in jointed rocks.

Jan 1, 1972

By Leon Y. Sadler

Equations which predict the unsteady-state response of the continuous froth flotation cell to changes in operating conditions are necessary for the rational design of an automatic flotation cell control system. Unfortunately application of automatic control to froth flotation separation equipment has lagged behind application to other types of separation equipment (for example distillation columns, absorbers, liquid-liquid extractors, etc). This may be due partly to the unavailability of suitable mathematical models for predicting the dynamics of continuous mechanical froth flotation cell. This paper presents the results of a comparison of four dynamic flotation models (in transfer function form) using the same set of unsteady-state continuous flotation data. One of the transfer functions tested has been presented previously in the literature (1), another (2) has been accepted for publication, and two are given here for the first time. In addition, data are presented which confirm earlier findings that the mixing in the rotor-stator type cell is nearly perfect. The specific purposes of this paper are to: (1) provide the automatic control systems designer with several alternative dynamic mathematical models of the continuous mechanical froth flotation cell (2) give some idea of the relative a¬bility of each model to predict unsteady-state behavior by fitting each model to the same set of experimental stimulus-response flotation data and (3) provide more insight into the macro-mechanisms prevailing in the continuous mechanical flotation cell. The dynamic models which are presented and tested here all relate the time variation of the concentration of a given floatable mineral in the tailings to a time-dependent disturbance in the same floatable mineral concentration in the feed to the flotation cell.

Jan 1, 1972

By Hill McDonald

Sand and gravel deposits may be explored by many different methods. The methods used by The Standard Slag Company are primarily two in nature. One is using an auger which is limited in depth by various soil conditions. The other is a heavy wall dry sampler and a heavy wall wet sampler. The heavy wall dry sampler takes continuous uncontaminated samples up to seven inches in diameter. The heavy wall wet sampler takes continuous uncontaminated samples up to six inches in diameter. For us, the maximum depth of the heavy wall samplers has been two hundred fifty feet of which one hundred feet was above the water table and one hundred fifty feet was below the water table.

Jan 1, 1972

By H. Reginald Hardy, Y. P. Chugh, Robert Stefanko

Many materials including rocks, ice, metals and their alloys, wood, etc., emit transient vibrations in the audible and subaudible range when stressed. In rocks, this phenomenon is referred to as "microseismic activity, " "rock noise, " or " seismo-acoustical activity. " In metals this phenomenon is often termed "acoustic emission." Each individual microseismic disturbance is generally referred to as a "microseismim" or an "elastic shock." The terms "microseismic activity" and "microseismim" will be employed exclusively in this chapter. Microseismic activity has been observed in many rocks loaded experimentally in the laboratory.1 The form of a group of typical microseismims is shown in Fig. 1. Quantitatively, the microseismic activity in rock under stress is most commonly described by the number of microseismims observed per unit time. This is commonly known as the "noise rate." The noise rate in general increases with increasing stress level and rises sharply just prior to failure of the material.2 The origin of microseismims is not well understood, but it appears to be related to processes of deformation and failure which are accompanied by a sudden release of strain energy. In a polycrystalline material, microseismims may originate at the micro-level as a result of dislocations or at the macro-level by twinning, grain boundary movement, or initiation and propagation of fractures through and between the grains. It is assumed that the sudden release of stored elastic strain energy accompanying these processes generates a stress wave which travels from the point of origin, within the material, to a boundary where it is observed as a

Jan 1, 1972

By Don Stevens

The Denali Prospect (147° 08' 20" W, 63° 08' 50" N) is located on the south flank of the Alaska Range in the Clearwater Mountains in south central Alaska. (See Figure 1). The mineralization was discovered in 1963 and surface explora¬tion began the following summer. Surface trenching and diamond drilling were used to locate and sample the mineralized zones. In 1969, an adit totalling approximately 1400 feet was completed. In 1970, a -15% grade decline approximately 1800 feet long was completed. Further diamond drilling was done along with both underground programs. Although much work remains to be done to properly evaluate the prospect, results from all the work to date are quite encouraging. This paper will consider the geology of the prospect and the surrounding area, some- aspects of the geochemistry of the sulfides, and the origin of the sulfide deposits. This paper includes data from this writer's Ph. D. dissertation, "Geology and Geochemistry of the Denali Prospect, Clearwater Mountains Alaska" from the University of Alaska and subsequent work.

Jan 1, 1972

By L. A. Neumeier

The Bureau of Mines evaluated creep properties of Zn-Cu-Ti alloys that were annealed after finish-rolling either cold) or at 480° F (249° C). Compositions ranged up to 1.25 pct Cu and 0.36 pct Ti. Most data are for sheet annealed after finish-rolling to 92-pct total reduction. Annealing times were varied at temperatures between 320° and 560° F (160° and 293° C). For a number of the alloys, annealing after hot-rolling at 480° F affects creep properties very differently in longitudinal and transverse sheet directions. The detrimental result is that the anisotropy in creep properties between the two directions can be vastly increased. Conversely, specific annealing treatments of certain heavily cold-rolled alloys result in surprisingly low anisotropy in creep properties and the low anisotropy coincides with excellent creep resistance for both directions. Supplemental data are presented on tensile, hardness, and thermal expansion properties, and microstructures.

Jan 1, 1972

By W. L. Price

I. INTRODUCTION Today, there are two conflicting trends facing the designer of the bulk material handling system. The first trend is the necessity to stockpile increasingly larger amounts of bulk material (coal, ore, stone etc.) as economically as possible. Fig. 1 illustrates such a typical large storage pile. The second trend is the increasing awareness of the ecological problems of today manifesting itself in a new concern over possible air pollution from storage pile surface particles. The conflict between these two trends can become dramatic when this bulk storage pile is located near a heavily populated area. Strong winds can easily create a severe local problem by blowing the particles from the pile surface toward residential and commercial areas, igniting a crisis in public relations. (2), (3), (4). To help define our combined subject and ecological culprit more accurately, Fig. 2 shows the commonly accepted size range of dust particles. A descrip¬tion of the present state-of-the-art of dust control for large storage piles is the intent of this paper. II. OPEN STORAGE PILE SYSTEMS - ALTERNATE CHOICES AND RELATIVE COSTS In discussing the open storage dust problem and possible solutions, one obvious question arises - what are the economics of placing large bulk storage under cover? Part or this answer will be found in Fig. 3 - an approximate unit capital cost comparison between several methods of storage. It will be noted that the cost curve(s) for the closed concrete silo storage illustrated in Fig. 4 is cheaper per ton at relatively small tonnage capacities, but as tonnage increases, the open pile storage unit cost (B) becomes more economical. Curve (T) covers the cost of open storage using the plow feeder arrangement shown in Fig. 5. A gravity draw-down pile with feeders at the base as shown in Fig. 6 represents yet another open storage choice.

Jan 1, 1972

By Marshall D. Himes

The Pima mine, 39,000 ton per day copper mine, is located 17 miles south of Tucson, Arizona. The mine is in a sequence of Paelozoic and Mesozoic sediments striking east-northeast and dipping southeasterly intruded by a Tertiary quartz monzonite porphyry. The Paleozoic Permian(?) dolo¬mites, limestones, and sandstones have been altered to talc-silicate skarn, marble and quartzite. The overlying Mesozoic Triassic(?) clastic sediments have undergone some recrystallization and hydro¬thermal alteration. The clastic metasediments are divided into three distinct lithologic units, lithic arenite, arkose, and inter¬bedded and overlying black argillite. Three types of hydrothermal alteration in the clastic rocks are propylitic alteration (epidote, chlorite and quartz, with or without sericite), quartz-sericite alteration, and potassic alteration (K-feldspar and quartz, with or without sericite and chlorite). The porphyry has undergone potassic alteration. Dominant structures are an east-west post mineral fault in the western part of the pit, and strong low angle faulting and shearing which truncates the ore body at depth. Two joint sets, one parallel to bedding and the other at right angles to bedding are prominent in the mine. Faulting is in two dominant directions, one striking northwest, dipping northeast and the other striking northeast, dipping northwest. Mineralization is predominantly disseminated pyrite and chalcopyrite, and molybdenite-quartz veinlets. There are lens important amounts of magnetite, hematite, sphalerite, galena, tennantite and bornite. Mineralization is believed to be both structurally and chemically controlled.

Jan 1, 1972

By W Frint

An area in Southwestern Wyoming is rapidly becoming the soda ash capitol of the world. Starting only 20 years ago from a unique deposit of trona, the out-put has rapidly increased until now about half of the soda ash produced in the United States comes from this area. Chemically, soda ash is sodium carbonate, a large tonnage, widely used alkali. The largest single industrial use is in glass manufacture, where 25 tons of soda ash are used in producing 100 tons of glass. Other big users are the detergent and chemical industries. The trona deposits in the Green River basin of Wyoming, were formed about 75 million years ago as part of a geologic period when an ancient lake alternately went through periods of being a large fresh water or smaller brine lake. Today these deposits lie from 800 to 3000 feet below the surface in a semi-arid, almost desert region just west of the Rocky Mountain Continental Divide at an elevation of 6200 feet. In this area there is a prevailing westerly breeze and almost every afternoon the velocity reaches very windy conditions. Rainfall is minimal, being only 6-8 inches of moisture per year with an evaporation rate exceeding 24-inches. Most of the moisture comes in winter snows or summer thunderstorms. Temperatures are low with below zero weather dur¬ing most of the winter and early morning frost is not uncommon during the summer months. There are many trona beds varying in thickness from a few inches up to 15 feet. The deposits now being mined vary from 8 to 10 feet in thickness. The ore is mined by driving tunnels either via conventional explosives or with continuous boring machines. It is transported to the shafts via conveyor belts

Jan 1, 1972

By R. Lyndon Arscott, P. Hackett

This chapter reviews the early stages of a study designed to investigate the physical behavior of the coal measure rocks around longwall panels over a relatively large area. The aim of the work is to attempt to explain a directional tendency for a certain type of underground fracture. The geological structure of the area is reasonably uniform but the effect of some local anomalies is also discussed. Although some definite tendencies have been recorded, the results so far achieved need confirmation by further experiments. The chapter deals first with some in-situ strain measurements carried out in longwall panels and continues with a discussion of the relationships between induced fractures and the natural variations in the structure of the rock mass. Finally, some light is shed upon the gas outburst phenomenon although eradication of the hazard is far from assured. STRESS AROUND A LONGWALL PANEL Considerable progress has been made during the last few years towards the determination of the mechanism of failure of small samples of rock under varying environmental conditions. Much more laboratory testing needs to be done in this field but an even greater amount of study needs to be devoted to the extrapolation of laboratory phenomena to failure around underground excavations. The problem is made more difficult because the stress redistribution around an excavation is often difficult to define, particularly when part of the rock mass fails and a

Jan 1, 1972

By F. G. Schwartz

The Bureau of Mines developed a rapid and precise method for predicting storage stability of motor gasolines. This method resulted from the investigation of many analytical techniques as well as a study of fuel composition and fuel component gum-forming mechanisms. The first section of this bulletin discusses the development of the prediction test through its several phases, including revision of the standard 110° F storage test; attempts to develop a modification of the ASTM D525 induction bomb test; and the ultimate abandonment of this procedure with the adoption of the 16-hour oven test that was both precise and rapid. The second section comprises a discussion of further studies of fuel com- position, including the reactivity of certain sulfur compounds and hydrocarbons to form gum. The compositions of various gums and inorganic deposits are reported in terms of elemental analysis and spectroscopic examinations. The reactions of tetraethyllead with selected hydrocarbons are also reported.

Jan 1, 1972

By F. W. Jessen

The Mechanism of solution of salt and mixed halites of sodium and potassium is reviewed. The variation in the rate of salt removal under both laminar and turbulent flow conditions is discussed. Many changes are possible in the development of solution cavities whether used for production of salts or for storage of hydrocarbons. The parameters influencing the type and shape of cavity formed with single well or multiple well systems are examined and information presented regarding field application of techniques developed and the means of controlling overall configuration of solution cavities.

Jan 1, 1972

By Larry A. Haas

Carbonyl sulfide (COS) was decomposed to sulfur and CO in a silent electrical discharge. A threshold of about 4 kv at 60 Hz was required to dissociate the gas in a laboratory ozonizer at 790 torr with electrode gaps between 1 and 5.5 mm. Above the threshold value, the reaction rate increased with increasing voltage with helium or nitrogen diluent. With the latter diluent, higher voltages had to be applied to obtain the same yield in the 4-to 12-kv range. The COS decomposition rate increased with COS concentration, but a saturation value was reached at about 10 pct COS. The reaction rate decreased at low linear gas velocities as obtained at lower gas flows, larger electrode gaps, or larger reactor volumes. Increasing gas temperature also decreased the decomposition rate. The presence of solid adsorbents such as quartz wool, bauxite, or charcoal had no significant effect on the reaction rate. The addition of S02 did not affect the COS decomposition rate, but small amounts of water decreased the reaction rate. Over 50 pct of the COS was decomposed at room temperature and atmospheric pressure in a l7-kv ozonizer using a gas containing 0.9 pct COS in helium flowing at a rate of 0.3 liter/min. The average current was less than 5 ma. This method has possible application in eliminating the toxic air pollutant, COS, which is generated in petroleum refineries and in processes involving reactions between sulfurous and carbonaceous materials. Carbon monoxide that is formed can be further oxidized to CO2 after the collection of elemental sulfur.

Jan 1, 1972

Multiple regression analysis was used to predict elemental concentrations of copper and nickel in soils from consideration of the concentration of these elements in vegetation in an ultrabasic complex in New Zealand. Regression equations were computed from sixteen independent variables involving concentrations of ten elements in plant ash, and various physical factors such as slope and altitude of the site, and height of the tree. One elemental and one physical variable were significant for nickel at the 90 per cent level of probability and five elemental and two physical variables were significant for copper at the same level. Use of the regression equations explained 32·5 per cent and 26·5 per cent of the variance in the respective relative accumulations (amount in plant divided by amount in soil) of copper and nickel.Predicted concentrations of copper and nickel in soils agreed more closely with the observed values in the soils than did the levels of these elements in plant ash.Although the results may specifically apply only to the test area, the principles should have universal application.

Jan 1, 1972

By Ted C. Briggs

A special high-pressure Burnett-type compressibility apparatus was constructed and used to determine compressibility factors for pure helium, pure nitrogen, and nine helium-nitrogen mixtures containing 89.47, 79.04, 69.69, 60.09, 49.24, 41.02, 30.99, 20.53, and 10.67 mole-percent helium. A total of 161 runs were made consisting of 2,355 observed pressures. Data were obtained at 0°, 25°, and 50° C and at pressures to 1,000 atmospheres. A power series in the reciprocal volume, commonly called a Leiden series, is used to represent the compressibility factors. Three parameters in the series are required to represent helium, five parameters to represent nitrogen, and from three to five parameters to represent the mixtures. Compressibility factors are believed to be accurate to better than 0.1 percent over the entire pressure, temperature, and composition range.

Jan 1, 1972

By T. E. Wayland

The general geology and mineralogy of bentonite, including pertinent technological details of clay minerals in the montmorillonite group, are summarized. Worldwide occurrences of bentonite deposits are reviewed, with emphasis on geologic methods and economic principles of evaluation. Active mining districts are described and areas with potential for current and future development are assessed. The production history of bentonite, principal producers, major consumers, and indicated trends are noted; also attention is directed to the hundreds of minor industrial uses of this versatile material, ranging from the manufacture of (A)cid neutralizers to (Z)eolite water softeners. Recent significant results of both basic and applied research are reported, with suggested lines of investigation for current and near-future consideration.

Jan 1, 1972

By Richard C. Fountain

The Central Florida Phosphate District is located in southwestern Polk, southeastern Hillsborough, Manatee, and Hardee Counties, Florida, flanking the.southern end of a major structural uplift known a the Ocala arch. Ore control problems here are varied and unique due to non-homogeneity of matrix and high volume mining operations. Overburden stripping and matrix mining are performed by large draglines, the matrix being slurrified and transported to the processing plants hydraulically. Production geologists' responsibilities include, 1) prediction of special mining problems, 2) prediction of ore quality and quantity, and 3) the physical control of the ore quality and recovery during mining. prediction is based on core drilling and visual inspection and analysis of the core samples. Basic economic, and physical minability criteria are thus established. Ore grade and tonnage recovery are of particular importance with emphasis being placed on coordination between mining and processing personnel. Routine inspection of the working pit face is of prime importance and both physical and quality variations are pointed out to the mining supervision. Physical problems in ore control occur due to erratic clay, dolomitic limestone and sand lenses. Near surface ground water is abundant, posing a threat to recovery. Contaminants of the phosphate ore are large quartz grains, pebbles of cemented quartz sand, clay balls, iron oxide laminac and dolomitic limestone particles. Success of the ore control program is predicated on a balance between predicted ore tonnages and grade and actual production. The geologists' primary attention is directed toward this balance.

Jan 1, 1972