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By R. Cavanagh

Studies relating to the fixation of sulfur by reaction of 4 to 8 mm diameter cylinders of calcined limestone or dolomite with high strength sulfur dioxide in the temperature range 880°C to 1020°C were undertaken. Dolomites are far superior in sulfate capacity and reactivity than dense limestones even at high strength SO2. The sulfation reaction was first order with respect to SO2 concentration below 100 percent. Zero reaction rate at 100 percent SO2 concentration indicates that sulfate was the exclusive reaction product and that sulfite had no role in the reaction. At relatively low SO2 concentrations gaseous diffusion through the reaction product layer has a marked effect on the rate. As SO2 concentrations were increased up to 100 percent more complex rate controlling mechanisms unfold. By sectioning partially reacted dolomitic limestone pellets a moving interface was observed. Reaction ceased because of pore plugging for dense non-porous limestones at 30% conversion. With dolomitic material virtually complete sulfation of the calcium was observed. S.E.M. analysis showed that the average atom ratio Ca:S was 1.01, thus supporting the argument that little if any of the magnesium was sulfated.

Jan 1, 1996

By Donald R. Sadoway

"Molten salt electrolysis is a proven technology for the extraction of metals -- all· the world's primary aluminum is produced in this manner. The unique properties of molten salts also make them excellent media in which to treat a variety of forms of waste. Of special note in this regard is electrolysis in molten oxides, a concept put forward by the author, initially as a ""clean technology"" for producing primary metal. However, in the context of waste treatment, electrolysis in molten oxides is a process offering the prospect of changing the-valence of dissolved heavy metals while making pure oxygen gas as the main by-product. Laboratory tests conducted at a temperature of 1550°C on chromate sludge dissolved in an melt composed of Al2O3, SiO2; CaO, and MgO have confirmed electrochemical production of oxygen on a carbon-free anode. IntroductionMolten salt electrolysis is the electrolytic decomposition of a compound dissolved in an ionic melt. The prime example of this process can be found in the production of aluminum. The compound, alumina (Al2O3)' derived from the mineral bauxite, is dissolved in an ionic melt comprising a multicomponent solution of cryolite (Na3AlF6)' aluminum fluoride (AlF3)' and calcium fluoride (CaF2,). The products of electrolysis are molten aluminum and carbon dioxide, the latter due to the attendant consumption of the carbon anode. Primary aluminum is produced in a reactor known as the Hall cell.' Alternatively, the compound undergoing electrolytic decomposition can be derived from waste. Processing in molten salts, with their capacity to dissolve materials to very high concentrations compared to those attainable in aqueous solutions, can be rather advantageous. High solubilities lead to high limiting current densities, and this, in tum, results in high productivities: For a primer on molten salt electrolysis and a review of the basic literature in the field of molten salts the reader is directed to an earlier publication of the author (1)."

Jan 1, 1996

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Jan 1, 1996

By Thierry Bernard, Pierre M. Vuillaume, Michel Kiszlo

In the context of its studies for the french ministry of the environment and for the French national coal board, INERIS (the French institute for the industrial environment and hazards, formerly CERCHAR) has made a complete critical survey of the methods generally used to reduce the levels of blasting vibrations.

Jan 1, 1996

By I. Bock

This presentation describes a technique under development referred to as Selective Blast Mining. The technique involves millisecond sequential blasting. It applies to mines where the gold bearing conglomerate band is clearly demarcated, and separated from the waste rock in the foot and hanging wall. The width of the conglomerate band should be less than ± 0,7 metres. A research program was initiated in August 1994 by Drs RE. Robinson and I.E. Bock. The objectives were to develop new blasting methods that can reduce: ? the losses of gold in narrow reef stoping. Losses of gold can be as much as 10-15% ? and to introduce selective mining to reduce ore dilution with waste rock.

Jan 1, 1996

By Lui Bin, Li Xinghua, Jiang Guoan

By employing decision support system and Borland C++ and Foxpro 2.58 For Windows as development means and tools, this system comprehensively applies the price decision theory, fore- casting and optimization techniques as a complete theoretical system, realizing the computerization of analysis, forecasting and decision process of coal price.

Jan 1, 1996

By Steve Kral

About 500 mineral-processing professionals from around the world gathered in San Francisco, CA in Oct. 22-27, 1995 for the XIX International Mineral Processing Congress (IMPC). Following the theme “Leading Mineral Processing into the 21st Century Through Advanced Technology,”186 speakers from 28 countries covered research and development activities and innovative processes. Subjects included comminution and simulation control, physical and chemical processing, flotation practices and fundamentals, precious metals processing and mineral waste and the environment.

Jan 1, 1996

By A. I. A. Salama

A computationally efficient technique for generating a balanced set of density or size separation data is developed. The technique proposed utilized minimization of a modified form of error squares to generate the optimum estimates of outputs mass yields (splits) and balanced direct mass distributions of feed and outputs. The estimated separation data set satisfies mass balance conditions of the streams mass distributions around the separator. The technique proposed avoids the generation of small negative values for the estimated feed and outputs direct mass distributions. Actual data are used to demonstrate the technique proposed.

Jan 1, 1996

By Madhira R. Madhav

In an alluvial deposit consisting of layers of sandy silt with clay and kankar nodules, driven cast in situ piles are provided. The piles end on a stiff bearing stratum To verify the available design capacities, compression, pull-out and lateral load tests are conducted in situ. The elastic continuum approach is used to estimate the equivalent modulus of deformation of the deposit. A comparison is made of the values from the three types of tests.

Jan 1, 1996

By P. M. Deshpande

An interactive short column system is evolved as alternative to deep foundation system in deep layers of marine clay, the interaction of encased stone column and marine clay carry load without causing conventional settlement. This paper presents concept of the system and its field application as foundation of culverts on marine clay layer of 15 to 17 M underlain by residual soil layer of 5 to 6 M, where conventional pile of 23 to 25 M would have been required.

Jan 1, 1996

By R. V. Ramani, S. Skankar

Available literature on the effect of re-entrainment on overall airborne dust concentration in mine airways or the fundamental mechanisms of coal dust re-entrainment in mine atmosphere is scant (Shankar and Ramani, 1991). Therefore, as part of the Respirable Dust Center's ongoing research, the following three-part study was undertaken: •a study of the re-entrainment phenomena of anthracite and bituminous coal dust particles in a wind tunnel under the influence of varying air velocities; •a study of the same in the Lake Lynn Laboratory Mine of the USBM with both air flow and walking by personnel causing re-entrainment; and •the mathematical modeling and computer simulation of the re-entrainment phenomenon. In this paper, results from the re-entrainment studies in the wind tunnel and the Lake Lynn Laboratory mine are presented. Comparing the results from the two studies, it was observed that increasing the air velocity increased the rate of re-entrainment (Shankar and Ramani, 1994a) and the rate of re-entrainment decreased with the time of exposure of the source dust to the flowing air. In addition, when the source dust was composed of particles of different sizes, the airborne dust concentrations due to re-entrainment were higher than when the source dust was composed of particles of the same size. The contribution of airborne dust concentration due to airflow was negligible compared to the contribution due to walking.

Jan 1, 1996

By G. D. Elliot, R. L. Grayson, G. L. Winn

For the years 1990 and 1991, West Virginia's underground coal small-mine fatality rate was approximately 10 times higher than the national coal-industry fatality rate. Although the number of fatalities went down from 22 in 1991 to 17 in 1992, West Virginia still led the nation in coal-mining fatalities. A team of mining and safety professionals from West Virginia, interfacing with the Mine Safety and Health Administration and the West Virginia Office of Miners' Health, Safety and Training, studied this problem. A clear path for formal intervention was determined and is presented here.

Jan 1, 1996

By B. Ramanathan

The results of a pile load test on a 1200 mm dia and 25 m long bored Cast-in-situ pile in soft rock is reported. The subsoil has a high N value of above 60 from 7 m to 21 m. The soft rock was observed below 21 m and N value exceeded 100. The theoretical calculations showed that the safe carrying capacity will be about 410 t. But the actual load test on the pile indicated that the allowable load is only about 140 t. This is attributed to the fact that the soil is cemented and loses strength due to remoulding caused by pile installation. It is concluded that great care should be exercised in determining the carrying capacity of piles in cemented soils and soft rocks and that 'N' value alone should not be used.

Jan 1, 1996

By Rowe P, Rogers D, Warren M

Pressure cyanidation of the minus 10 micron slimes fraction of the Fimiston flotation concentrates for the recovery of gold values has been evaluated as an alternative processing route to the roasting and atmospheric cyanide leaching of the calcine. Laboratory and pilot trials have demonstrated that gold extractions of greater than 94 per cent can be achieved at cyanide consumptions of 12-24 kg/t and oxygen consumptions of 0.1-0.3 Nm3/t with total pressures of 1000-2000 kPa. Economic and operational assessment of several reactor configurations suggests autoclaves may be preferred over pipe reactors at treatment rates of 10 t concentrate/h.

Jan 1, 1996

By C. DeRossett, K. F. Unrug

Sedimentary rock fractures commonly occur in the vicinity of outcrops. Mine highwalls and highway cuts provide excellent views of these near-surface joint systems. This paper explains the origin, characterization, distribution and extent of the these joint systems with reference to the lithologic composition of the rocks. The practical implications of these joint systems on the operation of a mine are described. Included are discussions of the discontinuous deformation that results from surface subsidence, the stability of mine portals and near-outcrop underground operations, and the stability of highwalls when using highwall miners and strip operations. Some design procedures are recommended to minimize the problems encountered within mining areas having intense joint systems.

Jan 1, 1996

By Susumu Okabe

Top blowing lances are employed by the Mitsubishi Continuous Copper Converter for the continuous supply Of reaction gases into moken bath. In order to minimize the refractory wear caused by the interaction between the furnace lining and the melt splash. optimum furnace design and blowing condition are? required. An empirical equation obtained by the physical model study enables the estimation of the splashing rate on a vel1ical plane at a certain distance from the lance.

Jan 1, 1996

By Andrew G. Hudson

The long-term economics of each of the four principal metals in marine manganese nodules (copper, nickel, cobalt and manganese) was evaluated to determine the anticipated viability of a nodule mining venture based on existing studies of the potential profitability of a nodule project. This included assessments of the lifetimes of land-based reserves, and examination and econometric modelling of the economic variables thought to affect nodule metal prices and demand. These analyses demonstrated that a) land-based reserves of the nodule metals were likely to last well into the future (100 400 years); b) average nodule metal paces were likely to stay a low levels for the foreseeable future; and c) the expected revenue stream from a twenty- ear nodule mining venture was substantially (42%) below that required to attract the necessary investment capital for such a high risk venture.

Jan 1, 1996

By L. Klinger, T. Werber, LA Levin, A Katsman

"The process of catastrophic carburization known as ""metal dusting"", whereby a solid metallic material is converted into fine particles in a carburizing atmosphere, was analyzed. It was shown that this conversion is the result of plastic deformation and subsequent fracture accompanying diffusional phase formation in the near-surface layer. The process is controlled by internal stresses arising during phase transformation. Competition between stress generation and relaxation may result in the attaining the ultimate strength in the near-surface layer and its fracture. Such a mechanism of metal disintegration may occur in a certain temperature interval depending on the kinetic and geometrical parameters of the system - the diffusivities of the alloy's components, the ratio between specific volumes of the new and the old phases, and the ultimate plastic strain. The temperature interval for disintegration of carbon steel, the rate of disintegration, and the period of the disintegration cycle, were evaluated and compared with experimental data. IntroductionCatastrophic carburization, known as ""metal dusting"", consists in conversion of a solid metallic material into fine particles. The process occurs in a carburizing atmosphere at elevated temperatures. The corrosion product, usually named ""coke"", consists of metallic particles dispersed in a loose carbon matrix. Under industrial conditions metal dusting takes place, for example, in a gas mixture of CO and H2 or in hydrocarbon environments. Steels, nickel- and cobalt alloys are susceptible to this kind of wastage in the temperature range 400-800°.A mechanism of metal dusting in steels was proposed by Hochman [1] and later developed by Grabke and coworkers [2-5]. According to the proposed model, the process consists of the following reaction steps:"

Jan 1, 1996

By C. Romero, R. Mendoza

The SX-EW plant consists of three parallel trains with two extraction and two stripping stages, with the mixing chambers situated on the same side of the settlers, using a coalescing launder to direct the solution flow to the outlet weirs in the side as the mixers. In the tankfarm the loaded organic tanks will include a coalescing packed column to separate the aqueous entrainment. Organic from gunk will be recovered in a packed column, instead of a centrifuge. The EW plant utilize polymer concrete cells with permanent stainless steel cathodes with edge strips on side and bottom, without wax.

Jan 1, 1996

By R. Y. Wan

Newmont Gold Company has advantageously used the capabilities of mineral oxidizing bacteria to develop a process for pretreatment of low grade sulfidic and carbonaceous-sulfidic refractory gold ores. The biooxidation process results in the oxidation of the sulfidic minerals with increased exposure of gold for subsequent gold recovery. The biooxidized carbonaceous-sulfidic ores cannot be heap leached with cyanide because of the "preg-robbing" characteristics of the carbonaceous matters in the ores. An alternative heap leach process using ammonium thiosulfate was developed to extract gold from the "preg-robbing" biooxidized ores. The ammonium thiosulfate leach process has been successfully practiced both in laboratory and pilot plant testing. Satisfactory test results encourage the continuation of process development.

Jan 1, 1996