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By L. Mabiza

Keywords: Pyrometallurgy, furnace, sulphur, SO2, off-gas, Zimplats Zimplats embarked on an off-gas sampling campaign in December 2009 to characterise the concentration of SO2 in the off-gas from their 13 MW furnace. In excess of forty isokinetic samples (US EPA Method 8) were taken over seven days. The aim of the sampling campaign was to increase the understanding of factors that influence sulphur release from sulphide concentrates in an electric furnace. Specifically, detailed monitoring was conducted over various operating conditions to evaluate: ? The relationship between SO2 and feed rate (i.e. furnace power) ? The relationship between SO2 and ingress (i.e. furnace freeboard pressure) ? The impact of concentrate bed thickness on SO2 (i.e. blacktop) ? The effect of events such as tapping and converter slag return on SO2 ? The desulphurization reactions that take place in the blacktop A model was developed to predict the SO2 content in furnace off-gas for a particular set of operating conditions. In order to evaluate the impact of random, uncorrelated changes in concentrate composition, ingress and power (feed rate) on the SO2 content of the off-gas, a Monte Carlo approach was adopted whereby concentrate composition, power, and ingress were allowed to vary randomly around selected set-points. The model is primarily based on the release of ?labile? sulphur from the partial thermal dissociation of sulphide minerals with an over-stoichiometric sulphur content (e.g., Fe7S8 decomposition to FeS and S). The main findings of this work suggest that labile sulphur does not fully account for the measured SO2 content of the off-gas, and that limited oxidation of sulphides during melting also contributes to the SO2 content. Details of sulphide oxidation reactions in the furnace remain unclear, and it is currently not possible to provide a theoretical framework for the relationship between the extent of oxidation and variables such as temperature, gas composition, particle size, and residence time in the furnace black top. Through the use of the Monte Carlo model it was, however, possible to constrain the extent of sulphide oxidation to about 1%. This work has shown in practice what was expected in concept, that SO2 in off-gas is proportional to furnace power and ingress rate. The model that was developed consistently slightly under-predicts the quantity of SO2 generated. It also highlights that more work is required to better understand the analytical methods used to analyse for SO2 in off-gas.

Jan 1, 2011

By R. P. van Hille, N. Mooruth

Remediation of acid rock drainage (ARD) was performed within a linear flow channel reactor (LFCR) via a floating sulphur biofilm (FSB). A full sulphur species material balance was conducted in order to characterize the sulphide oxidation. The reactor was able to achieve an 82% and 93% conversion of sulphide with a hydraulic residence time of 2 and 5 days respectively. 92% and 55.5% of the converted sulphide reported to the biofilm as sulphur for the 2 and 5 day residence times respectively. The mass transport limitations within the biofilm were identified via a dissolved oxygen gradient profiling system.

Jan 1, 2011

By E R. Ramanaidou, M S. Piggott

Transport to and handling of iron ore at Port Hedland, Western Australia, results in the generation of airborne particulates that contribute to the atmospheric dust load, with concerns about potential local environmental impacts (eg mangrove swamps) and possible human health implications. Mineral and chemical characteristics of the Background soil samples were contaminated with particles of iron ore as martite octahedra and grains of micro-platy hematite as detected by scanning electron microscopy (SEM) in the 2.5 - 10 ¦m and 10 - 50 ¦m size fractions. Fossilized wood fragments similar to those observed in Yandicoogina fines ore were also detected in some background soil samples. With a predicted increase in demand of channel iron deposits (CID) ores and the inherently dusty Marra Mamba ores (eg West Angelas, MAC, OB29/30/35, Marandoo), in conjunction with particulate emissions from hot-briquetted iron and direct reduced iron (HBI/DRI) processing plants, there is the potential for additional sources of anthropogenic dust to contribute to background levels. Mineralogical and chemical characterisation of the entire range of particulates that could be produced is necessary for a complete understanding of their potential impact on the local environment.

Jan 1, 2002

By B Godel, E R. Ramanaidou, M Verrall

Fortescue Metals Group Ltd Iron Bridge (IB) operation is a magnetite deposit located in the Pilbara region of Western Australia situated around 145 km south of Port Hedland. This Mesoarchean deposit belongs to the 3230 Ma Pincunah banded-iron formations (BIF), a member of the Kangaroo Caves Formation, Sulfur Springs Group (van Kranendonk, 2000).

Sep 18, 2023

By Bhattacharyya A. K

In this paper, the current methods for predicting surface subsidence due to underground coal mining are evaluated first. A single index, called a strata parameter (P), is then proposed to describe the overall character of the undermined strata in the context of surface subsidence. Based on the strata parameter, a method for predicting the maximum surface subsidence for various panel width (w)/depth (h) ratios is presented, which has been tested against specific empirical curves or data from several coalfields in different countries. From the data relating to several coalfields, a linear relationship between the reported average angle of draw and the strata parameter has been established. It has also been found that the strata parameter can be used for studying the locations of the inflection points and the shapes of transverse subsidence profiles.

Jan 1, 1995

By J. Temuujin

Mongolia has some of the world?s largest coal reserves with an estimated total coal reserve of over 150 billion tonnes. At present, over 90% of Mongolian electricity is produced by combined heat and thermal power stations. The main coal deposits used for Central power system's power stations are Baganuur, Shivee-ovoo lignite type coal and Shariin gol bituminous coal. In Mongolia almost 600,000 tonnes of coal combustion by-products are disposed of in waste ponds. In this research, we have thoroughly characterized Mongolian coal combustion by-products including fly ashes sourced directly from thermal power stations and ash retrieved from ponds. It was determined that fly ashes generated from Baganuur and Shivee-ovoo coal deposits are class C, while ash from Shariin gol coal is class F (according the ASTM C618). All ash products were characterized by chemical, mineralogical, granulometrical, porosity, FE-SEM and radiation methods. Fly ashes sourced directly from power stations were found to be more suitable for manufacture of geopolymers for building materials application and zeolite synthesis than ashes retrieved from ash ponds. The adsorption and porous properties of zeolitic compounds were measured and found to be suitable for adsorption of Cr6+ from simulated tannery waste water. Keywords: coal, coal combustion by products, synthesis, geopolymers, zeolitic compound

Sep 1, 2012

By Marco Barla, Mariacristina Bonini, Giovanni Barla

ABSTRACT: The paper describes the characterisation studies of Tectonised Clay Shales at laboratory and in situ scale. The interest relates to tunnelling under squeezing and swelling conditions, in Italy, along the Apennines. The results of monitoring during full face excavation are presented in conjunction with numerical modelling. RESUME: Cet article présente la caractérisation, à l'échelle du laboratoire et in situ, des Argiles Chaotiques. L'attention est portée sur le creusement, dans ces milieux gonflants, des tunnels, dans les zones montagneuses des Appennini, en Italie. Enfin, on présentera les résultats de la modélisation numérique et la comparaison de ces derniers avec les mesures effectuées in situ. KURZFASSUNG: Die Arbeit beschreibt die Charakterisierungsstudien von tektonisierten Schiefertonen, sowohl im Labor als auch vor Ort. Das Interesse gilt dem Tunnelbau unter Quetsch- und Schwellbedingungen in Italien entlang der Apenninen. Die Überwachungsergebnisse des ganzflächigen Ausbruchs werden mit numerischen Modellen präsentiert.

Jan 1, 2003

Understanding multiphase particulate systems is essential for the further advancement of mineral processing technology. Characterisation, analysis, and simulation of these complex systems provide a fundamental basis for the development of improved mineral processing technology. One of the more recent tools that can be used to help provide a foundation for improved mineral processing technology is high resolution cone beam X-ray micro computed tomography (CT). During the past ten years point-projection X-ray micro CT systems have been used for 3D visualisation and quantitative analysis of multiphase particulate systems. Analysis of packed particle beds containing as many as 30 000 particles can be accomplished in less than three hours with special software to establish the 3D characteristics of each particle in the population and the spatial organisation of the packed particle bed. Now, due to advances in X-ray optics, the resolution afforded with point-projection micro CT systems has been improved by at least an order of magnitude using a lens-based X-ray micro CT system. The development of software tools for the 3D characterisation, analysis, and simulation of packed particle beds using high resolution X-ray micro tomography (HRXMT) is discussed including examples of application in the areas of comminution (particle damage and preferential grain boundary fracture), exposure/liberation analysis (liberation-limited separation efficiency, including coal washability), and filtration/heap leaching (pore network structure of packed particle beds and simulated flow using the LB method of computational fluid dynamics).

Sep 13, 2010

By T. Schmidt, H. Assadi, F. Gartner, H. Kreye

Among all spraying processes, cold spraying has attracted a special attention in recent years, both as a coating - and more recently - as a rapid manufacturing technique. The interest in this process is mainly because of the fact that the deposition of spray material takes place at moderately low temperatures, and thus, oxidation and unfavourable microstructural changes can be alleviated. In this process, a highly compressed gas, flowing through a de Laval nozzle, accelerates the particles of the spray powder to high velocities of up to 1200 m/s. Although there is no melting of particles prior to impact on the substrate, cold-sprayed deposits can be denser and more tightly bonded as compared to the equivalent deposits produced by conventional thermal spraying methods. The present contribution focuses on this unique aspect of cold spraying. Modelling of particle impact, combined with various experimental observations, is employed to illustrate that bonding of particles and hence material deposition occurs through shear instability - associated with severe plastic deformation and localized heat generation - at the interacting surfaces of particles and substrate. The results of modelling also provide an insight to the influence of material and process parameters on the critical velocity and on the microstructural properties of cold-sprayed deposits.

Jan 1, 2006

By T Kon, K Ohno

Slag foaming is an important control item in the process of refining molten steel. This study aims to investigate the factors controlling slag foaming by observing the bubble formation behaviour resulting from the chemical reaction between iron oxide and Fe-C alloy in the slag. In this study, 0.06 g of Fe- C alloy was introduced at the bottom of a BN crucible, and 6.0 g of slag (SiO2:CaO:Fe2O3 = 40:40:30) was placed on top of it. The crucible was positioned inside an infrared image heating furnace, where the temperature was rapidly raised to 1370°C at a rate of 1000°C/min in a nitrogen stream, and then held at that temperature for a predetermined time before rapid cooling. Following rapid cooling, the internal structure of the sample was examined using a high-resolution X-ray CT device. The spherical equivalent volume was calculated based on the number of observed bubbles and their equivalent circle diameter. Additionally, the relationship between the volume ratio of small bubbles in the slag volume and the distance from the bottom of the crucible was determined, along with the calculation of bubble density and volume ratio. Under various experimental conditions, numerous bubbles with equivalent circular diameters ranging from 200 to 300 μm were consistently observed. The density and volume fraction of bubbles with circular equivalent diameters between 200 and 500 μm showed a tendency to increase as the distance from the bottom of the crucible increased. Bubbles with equivalent circular diameters of 500 μm or more consistently exhibited lower bubble densities, regardless of their height within the crucible. The formation of larger bubbles is attributed to a decrease in iron oxide concentration within the slag as the reaction progresses. However, this is believed to be due to their higher buoyancy, resulting in shorter residence times within the slag and a reduction in the number of encapsulated bubbles.

Aug 21, 2024

By M Khanal, J Qin, B Shen, Y Duan, X Luo

Gaining confidence in interpreting rock and strata properties of the coalmine roof is necessary for design, maintenance, modelling and optimisation of roadways supports. One of the key causes of roadway instabilities experienced in underground coalmines is an extreme variable nature (thickness, competence, discontinuities etc) of the coalmine roof. Normally, the thickness and strength of the roof are characterised with the geotechnical and geological data gathered from exploration boreholes, which are drilled often at considerable distances apart. This limited data cannot capture localised geological variations in the coalmine roof. With this background, this paper explores feasibility of using measurement while drilling concept to perform geotechnical characterisation of the coalmine roof. The parameters, for example, penetration rate, rotary speed, torque, sound, vibration, obtained during the drilling process can provide valuable insights into geotechnical properties. The paper describes the progress of the experimental work conducted at the laboratory on synthesized concrete samples representing various rock strata using a field-scale drilling machine. The samples with and without interfaces have been tested to replicate various underground roof strata. The signals returned from the drill machine, as the drill bit passes through the layers, have been analysed and interpreted to characterise whether the drill response data can differentiate various strengths associated with the rock layers. The initial laboratory results are promising as they show distinct responses of the various sample blocks in a controlled environment. The drilling data can differentiate the synthesized rock samples and detect ‘signatures’ of the roof strength variability and delineation of lithological interfaces (transitions). The weight and torque on the bit vary and show dependency on the strength of the blocks.

Nov 29, 2022

By I Lumsdaine

QNI Pty Ltd operates the Yabulu Refinery located 25 kilometres north of Townsville, North Queensland. The plant treats nickel laterite ores sourced from the Philippines, Indonesia and New Caledonia. The cobalt head grade and overall recovery expectations for the 2001/2002 financial year are 0.161 per cent and 53.8 per cent respectively. Cobalt is a valuable byproduct derived from the nickel refining operation which utilises the Caron Process. Any increases in cobalt recovery that are achieved from the existing relatively low level provide significant improvements to the bottom line of the operation. Towards the end of 2000, a project was undertaken to characterise cobalt losses with the sole purpose of improving cobalt recoveries using a variety of analysis techniques. The Time-of- Flight Secondary Ion Mass Spectrometry (TOF-SIMS û University of South Australia) method was used to verify the presence of surface bearing cobalt species, originating from either co-precipitation or adsorption mechanisms. Cross-section examinations were also performed using Scanning Electron Micrscopy (SEM) and Energy Dispersive X-ray Spectrometry (EDXS). These techniques indicated the presence of high cobalt concentrations (in the order of several per cent) within a select number of roasted and leached ore particles. The phenomenon of cobalt losses due to incomplete leaching within specific ore particles was not widely documented within the Refinery prior to these studies. In order to quantify losses via this mechanism, Mineral Liberation Analysis (MLA û JKTech Centre) was also performed on key samples. This paper serves to document a systematic approach in determining the source of significant valuable mineral losses in an established, operating plant. It discusses the use of a variety of analytical techniques, which have been adapted for the minerals processing industry, but are strongly relevant for plant investigations in the hydrometallurgical industry.

Jan 1, 2002

By G R. Ballantyne, V Souto, K Bartram

Particle sorting allows partially liberated minerals to be separated prior to energy intensive fine grinding. Sensors select particles for separation and air, water or mechanical ejectors are used to physically deflect those selected. To achieve effective separation there has to be sufficient liberation, accurate detection and presentation of a separated monolayer of particles. These three physical constraints determine the particle size limits, the sorting technology utilised, the separation efficiency, and the throughput that can be achieved. The combination of all these factors controls the effective limits on the degree to which sorting can reduce the specific comminution requirements and increasing energy efficiency. This paper will explore two case studies: the application of sorting in base metal mining and precious metal mining.CITATION:Ballantyne, G R, Hilden, M, Bartram, K and Souto, V, 2018. Characterising energy efficiency of particle sorting, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 531–540 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By C. Hunt, J. Vivas, D. M. Allen

"In this paper we present the results of a combined remote sensing - numerical modelling study to improve our understanding of groundwater seepage in open pit and natural rock slopes, and to investigate the interaction between groundwater, in-situ stress conditions and brittle fracture. The location of seepage is a key element in the characterisation of rock slope stability in open pits and natural slopes; definition of the fracture network geometry and its inter-relationship with seepage, however, remains a challenge in engineering practice. Current techniques used to characterize groundwater seepage locations require direct access to the rock slope for a detailed and exhaustive investigation, and can be severely limited due to access and the limited coverage of the survey methods both with respect to the height and length of the sampled rock slope. Herein, we describe remote sensing methods, which allow the collection of structural and seepage information over a wide spatial area. Remote sensing techniques are shown to have the potential to provide additional insights into the orientation and general connectivity of fractures that may play a major role in the general stability of a rock slope. A preliminary methodology for the use of remote sensing in the characterization of seepage zones in a natural slope through the application of ground-based LiDAR and Infrared Thermography (IRT) is presented.One of the most challenging problems in rock slope engineering is the realistic simulation of fluid flow through fractured and deforming rock slopes. Deformation and the development of brittle fractures can cause significant local changes in the permeability and strength of the rock mass, potentially affecting rock slope performance. Understanding fluid flow through fractured and deforming rock slopes, especially in highly-stressed environments is of great importance for slope stability analysis. Changes in the interconnectivity of fractures during slope failure are an important, yet are relatively unstudied in rock slope engineering. We present the results of hydromechanical UDEC-Trigon rock slope models focussing on the potential role of brittle fracture in rock slope failure, its interaction with groundwater pressures, and the influence of the assumed in-situ stress ratio. Damage intensity parameters are used to characterize damage within different regions of a biplanar slope failure."

Jan 1, 2015

By J Hunt

A critical aspect of geometallurgy is quantifying mineralogical and textural relationships that affect mineral processing (eg, liberation and recovery). However, to date, this has been an expensive and time consuming venture and only minimal amounts of this type of data are typically available to be included in the mine planning process. Our research is focused on developing methods that will produce the required mineralogical and textural data rapidly and inexpensively. New methods of characterising liberation potential from image analysis of coarse particulate material and direct small-scale flotation measurement are compared with measurement of liberation at final grind size (ie conventional tests on MLA). The new tests are designed to rank the liberation potential of samples in order to classify an ore deposit into domains of low, medium and high liberation potential. This parameter can then be used to adjust the cutoff used to differentiate ore from waste. Results to date show that all tests provide the same ranking for the samples. The measurement based on coarse particulate material compares favourably to the results from MLA analyses on the same samples. Further work is being carried out to determine which of the tests will be the most effective in terms of time, effort and cost

Sep 5, 2011

By X. Yuan

"The processing behaviours of ores such as their liberation characteristics in comminution and their response in separation processes are affected by their mineralogical characteristics. Key ore characteristics which are relevant to processing, such as mineral proportions, mineral grain size, grain shape and mineral associations are routinely measured at the micro-scale in polished section using optical microscopes and SEM-based automated mineralogy systems. The application of X-ray micro-tomography to mineral processing provides the means to quantify these important micro-textural characteristics in three dimensions, removing the stereological issues encountered when measuring volumetric information in two-dimensional polished sections. In this paper we present several examples of ore textures to illustrate where X-ray micro-tomography can be applied successfully to obtain quantitative measures of ore characteristics which are useful in a variety of process modelling applications.INTRODUCTION X-ray tomography has been used as a tool in medicine for some years and is being applied in a wider range of fields including geology, palaeontology and mineralogy. In this paper we present some applications of X-ray tomography in mineral processing applications being developed at JKMRC. The availability of SEM-based automated mineralogy systems such as MLA and QEMSCAN has seen the increased use of quantitative mineralogical data measured in two dimensions in the design, operation and simulation of mineral processing plants. When the ore is amenable to measurement by X-ray tomography this technique can provide quantitative data for characteristics such as mineral grain size, shape, mineral associations and liberation in three-dimensions. The advantage of measuring these characteristics in three-dimensions is that the stereological issues which bias measurements made on polished sections are removed. X-ray tomography also quantifies the location of mineral grains relative to one another in space - a useful descriptor of ore texture. Like many measurement techniques X-ray tomography has advantages and disadvantages when compared to other techniques. One limitation is that the ability of the X-ray tomography system to discriminate between minerals is a function of the X-ray attenuation of those minerals. While the X-ray attenuation of many common minerals is sufficiently different for X-ray tomography to distinguish between them, there are some where the overlap in X-ray attenuation makes discrimination on the basis of this characteristic alone impossible. An example of this would be chalcopyrite and magnetite. However where the ore mineralogy is suitable to apply X-ray tomography, the technique provides some exciting opportunities to explore the relationship between texture and ore processability."

Jan 1, 2012

By A Scott, I Onederra

A great deal of technical and research effort has been applied to the development of models to predict fragmentation from rock blasting. A number of quite useful empirical or engineering models are currently available to blasting engineers and consultants, while more sophisticated approaches using mechanistic and numerical descriptions of rock breakage continue to be developed and applied by researchers and explosives companies.The fragmentation resulting from any blast will be heavily dependent on the properties of the rock mass being blasted; however, most empirical models rely on ‘rock factors’ generated from simple rock mass properties to describe the influence of the rock on the blasting outcome. In contrast, mechanistic models need explicit rock mass properties that require sophisticated laboratory measurements and detailed structural data if realistic outcomes are to be generated. The fragmentation modeller is caught between excessively simple rock mass descriptions for the empirical models and excessively complex data requirements for the mechanistic models.This paper briefly reviews the basis of a range of fragmentation models and the rock mass properties on which they rely. Shortcomings in the way that the mining industry tends to characterise the blasting properties of rock are discussed and some practical approaches are described to quantify these properties in both operating and greenfield mining environments. Case studies are presented where specific additional breakage properties and modelling features have been needed to generate a useful description of the fragmentation achieved.CITATION:Scott, A and Onederra, I, 2015. Characterising rock mass properties for fragmentation modelling, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 149–160 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By D. Tang

The froth zone in a flotation cell is recognised as a region which contributes to the overall flotation performance. Froth recovery is a measure of the efficiency with which the froth phase delivers particles arriving at the pulp-froth interface to the concentrate. Poor froth recovery in scavenger stages is generally attributed to poor froth stability. The key indicators of froth performance: froth recovery, entrainment and water recovery were measured in an OK3 pilot cell installed at a zinc concentrator in Australia and supplied with scavenger feed. Cell hydrodynamic and pulp chemical conditions during the operation of the cell were also measured as well as bubble growth across the froth phase. The objective of the work was to assess the impact of a number of commercial frothers on the froth performance in the OK3 cell and assess the suitability of using bubble growth as an indicator of froth stability.

Jan 1, 2014

By A Scott, I Onederra

Most iron ores occur in mine benches as complex mixtures of lithologies and ore types. This significantly complicates their characterisation for both blast design and fragmentation modelling. A great deal of technical and research effort has been applied to the development of models to predict fragmentation from rock blasting. A number of quite useful engineering models are currently available to blasting engineers and consultants, and more sophisticated approaches using mechanistic descriptions of rock breakage continue to be developed and applied by researchers and explosives companies.The engineering or empirical models that are in more general use within the industry, such as the Kuz-Ram model, require appropriate data if they are to generate useful fragmentation predictions. Some of these models have reached significant sophistication and have made very useful contributions to both routine blasting operations and the exploration of new blasting paradigms. However, these models struggle to adequately deal with rock that is as complex as iron ore. This paper reviews the characteristics of the most successful blast fragmentation models available to the industry and discusses approaches to the derivation of suitable rock mass properties to adequately describe blast fragmentation in a range of iron ores.CITATION:Scott, A and Onederra, I, 2015. Characterising the blasting properties of iron ore, in Proceedings Iron Ore 2015, pp 481–490 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Bulelwa Ndlovu, Saeed Farrokhpay, Dee Bradshaw

The effects of phyllosilicate minerals on the flotation performance and froth stability of a copper ore was investigated. It was found that various phyllosilicate minerals affect the copper recovery differently however they all caused the flotation grade to be reduced. The effect of different phyllosilicate minerals on the froth stability followed the order of talc >> montmorillonite > muscovite > kaolinite > illite. The results demonstrated that there could be a relationship between the deleterious effect of phyllosilicate minerals on the flotation and froth stability. Talc and montmorillonite have both shown the highest effect on the flotation recovery and grade as well as froth stability. On the other hand, illite has the least effect on the both flotation performance and froth stability. Kaolinite and muscovite also affected the copper flotation grade (but not the recovery) while they also affected the froth stability. Therefore it is possible to control the flotation performance when phyllosilicate minerals are present via monitoring and controlling froth stability which needs to be investigated further.

Jan 1, 2014