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By Michael Farley, Paul Dufour

"Relationships, Partnerships,Marriages (RPM)RPM has a nice musical ring to it, but it is in fact synonymous with science and technology, university-government -corporate links and the more genera l issue of university roles in technology development. Pick up any report on one of these issues, and chances are that you will find one of these key words in the title. Play it, and you will find that the revolutions per minute are increasing. It is difficult to keep track of the wide variety of institutional experiments now developing in Canadian universities in attempts to marry science and research with technology commercialization and technology transfer.Why is the role of Canadian universities in this matter important? There are at least five good reasons:1. It is important because these knowledge institutions are producer s of scientific research, a major component of technology. Today the gap between the two is rapidly shrinking.2. It ' is important because Canadian industry is turning to universities for tech no logy development and new knowledge. Figure 1 shows that universities are becoming an important source of technology available to Canadian firm s; more important in fact than government. Figure 2 illustrates this trend more graphically in showing that university collaboration is one of the preferred methods of industry participating in co-operative R&D efforts:3. The role of Canadian universities in technology development is also important because the provincial and federal governments have embarked on various programs and policies for promoting the use of technology and science for economic benefit. Universities are playing an increasing role here. For example, the submission of IDEA Corporation (a venture capital operation funded by the government) in Ontario to the Bovey Commission on the Future Development of Ontario Universities clearly spelled out its ideas for commercialization of university research in Ontario . Among other things, the brief suggested that Ontario's universities need to be better equipped to transfer technology, and the reward structure in university research must incorporate industrial interests."

Jan 1, 1986

By K. M. Wild, C. D. Martin, F. Amann

Peak laboratory strength data obtained from low permeability clay shales/rocks often display a bilinear or non-linear failure envelope. In many of these tests pore pressures are not measured because of issues associated with back-saturation prior to confined compressive loading. In such tests the effective state of stress at failure remains unknown and provides room for speculation. The non-linear shape of the failure envelope may have several reasons including the influence of capillary forces or the tendency of a saturated clay shale to dilate as the confining stress is changed. The former stems from sample preservation, preparation or core unloading effects and represents a partly saturated state (i.e., not representative for the in-situ state); the latter represents the response of a saturated material. This contribution discusses these issues based on a data set obtained from Opalinus Clay specimens, and concludes that without a careful back-saturation processes knowledge of the underpinning reasons for the non-linear failure envelope cannot be obtained.

Jan 1, 2015

Chemicals derived from petroleum raw materials satisfy so much of our industrial needs today that it is good to pause and realise two things -ò the petroleum chemical industry is so new, and the use of chemicals is a very old one.Petroleum is such an'abundant and convenient source of raw material that in little more than 30 years it has become the major source of supplyfor chemical rdanuf ctiree This paperw~l'l 'disc'uss t1.e main 'r`easons' for this rapid development by considering the : sub jest -under tkzree headings ea. Source of Raw Materials.b. The Impact of Petroleum Chemicals on Plant Design and Processes. ce Scme of the Major Chemicals Used Today.

Jan 1, 1962

Chlorination of organic matter by direct injection of chlorine gas or hypochlorite has been investigated metallurgically worldwide with little understanding of the basic chemistry of the passivation mechanisms in- volved. In this paper, chlorination of carbon is attributed to oxidation-reduc- tions, resulting in surface halogenation of graphitic or amorphous carbon. It is proposed that chlorine and carbon interact to form thin coatings of chioro-carbon complexes that block the adsorption of gold cyanide com- plexes, thus passivating the gold adsorption sites of carbonaceous matter. Analytical, spectrographic, microscopic and electron-optical methods have been applied to demonstrate the proposed mechanism of chlorine-carbon bonding, as well as to evaluate the advantages and limitations of chlorination in the pretreatment of refractory carbonaceous gold ores.

Jan 1, 1991

By N. Sahin, K. Baris, A. Ozarslan

This paper aims to assess the current and future role of coal in energy strategy of Turkey and evaluates the compatibility of the policies to the EU energy policy and strategy. The Turkish government set targets to utilize more coal reserves of the country in next decades. However, the country is also in the process of becoming an EU Member State, hence, it is expected that the energy policies have to comply with the EU. Moreover, Turkey ratified Kyoto Protocol, thus the country should limit greenhouse gas emissions. Clean Coal, Carbon Capture and Storage (CCS) technologies are expected to become an important instrument for the mid-term reduction of CO2 emissions from coal-fired power plants. An alternative technique to the conventional CCS methods is CO2 sequestration by mineral carbonation. Turkey has significant resources of magnesium silicate minerals (olivine, serpentine) deposits which can be utilised in CO2 sequestration by mineral carbonation method.

Jan 1, 2011

By N. V. Mel'nikov

This paper discusses the reserves of oil, natural gas and coal in the USSR, with particular attention to the future role to be played by coal in supplying the energy fuel resources of the country.

Jan 1, 1972

By O. E. Humeniuk, A. I. A. Salama, M. W. Mikhail

"Performance testing of prepartion plants is referred to as plant audit. It evaluates plant performance under normal operating conditions and is aimed at improving yield through knowledge of actual process performance and interactions between different processes in a plant.This paper describes the program to evaluate the performance of several Canadian preparation plants. The performance test requires the planning of a sampling campaign that would include all circuits in the plant. Samples are analyzed to determine washing characteristics (screen and float-sink), ash and per cent solids of feed and products of separation units in the plant. Performance characteristics are established based on analysis and material balance. Specific recommendations can then be made to improve recovery, and identify and explain potential causes of apparent deficiencies.The objectives of the program are to reduce the cost of production by improving recovery of clean coal and, in tum, to reduce disposed tailings, establish baseline information on coal preparation plants performance in Canada, and define R&D work needed to optimize plant operation."

Jan 1, 1993

By C. L. Jiang

The role of iron ions (Fe2+ and Fe3+) in the flotation of both ore-and coal-pyrite with ethyl xanthate was comparatively investigated. The complete/partial depression of ore-and coal-pyrite in neutral to weakly alkaline solution is due to the formation of ferric dihydroxy ethyl xanthate between xanthate and the oxidation products of pyrite, ferric and ferrous ions. With xanthate as collector, coal-pyrite was found to be nonfloatable above pH6. In the presence of iron ions and between pH6-9.5, the flotation of ore-pyrite was significantly depressed. Ferrous ions have a stronger effect on pyrite flotation than ferric ions in neutral to weakly alkaline solutions.

Jan 1, 1996

By Wenying Liu, Marek Pawlik

Long-chain ionic surfactants, with fatty acids and amines as the most important representatives, are widely used as collectors in froth flotation. These surfactants, generally referred to as weak electrolyte collectors, frequently form solid insoluble precipitates within a certain pH range. However, the action and behavior of these colloidal precipitates in froth flotation systems are not well understood and has not been well decoupled from those of dissolved forms. The objective of this study was to understand and compare the role of colloidal precipitates with that of the dissolved forms at gas-liquid and gas-liquid-solid interfaces. Using primary amine as the model surfactant, experiments were carried out to measure: the maximum volume of bubbles generated in the presence of dissolved and precipitated forms of the surfactant; surface tension for both forms of the surfactant using the drop shape and maximum bubble pressure methods; and contact angle using the sessile drop method. The experimental results showed that: in the presence of the precipitate, bubble volume was smaller, which was correlated with the lower surface tension and higher contact angle measured; the surface tension of solutions containing surfactant precipitate was affected by the surface age of liquid droplets. This study enhances understanding of the interfacial behavior of long-chain ionic surfactants under different conditions, which would help improve the efficiency of reagent utilization in froth flotation.

Jan 1, 2014

By de Vaux. Deryck, Natalie J. Shackleton, Vratislav Malysiak Cyril T. O. Connor

"The major losses of PGM and base metals in the beneficiation of platinum group deposits occur during the separation of gangue from the value minerals by selective flotation. A number of studies have shown that this negative impact on flotation is due to surface passivation, caused by various ions that may originate from the external water supply or, as is likely in the majority of cases, from the oxidation of the mineral surfaces and the grinding media. This investigation aimed at reducing surface passivation of pentlandite and inadvertent activation of pyroxene, thereby improving ultimate valuable mineral recovery and selectivity. Both synthetic minerals and plant ores were studied in order to determine the effect surface passivation and inadvertent activation have on mineral surface alteration and floatability. Zeta potential determinations, microflotation, ToF-SIMS (Time of Flight Secondary Ion Mass Spectrometry) analyses, laboratory batch flotation tests and continuous flotation testwork were used as tools to study the surface alteration and/or floatability.Zeta potential determinations and ToF-SIMS analyses showed that copper adsorption is non-selective. Both pentlandite and pyroxene become copper (II)-activated in the presence of copper sulphate and subsequently, in the presence of xanthate, adsorption of the collector will occur onto copper activated mineral surfaces. Zeta potential determinations also showed an alteration of the surface charge in the presence of polyphosphate, thereby inhibiting surface passivation of sulphides by slime coatings due to surface repulsion.The addition of diethylenetriamine (DETA) reduces the copper concentration on both minerals, predominantly on the pyroxene surfaces and polyphosphate further enhances the selectivity at pH 6.The microflotation and batch flotation data obtained has shown a significant improvement in the ultimate flotation response of valuable mineral recovery and concentrate grade compared to the standard reagent regime, while the continuous flotation results significantly improved the selectivity, however, at a similar ultimate recovery."

Jan 1, 2003

By Natalie J. Shackleton, Deryck de Vaux, Cyril T. O’Connor, Vratislav Malysiak

"The major losses of PGM and base metals in the beneficiation of platinum group deposits occur during the separation of gangue from the value minerals by selective flotation. A number of studies have shown that this negative impact on flotation is due to surface passivation, caused by various ions that may originate from the external water supply or, as is likely in the majority of cases, from the oxidation of the mineral surfaces and the grinding media. The objective of the study was to investigate the effect surface passivation and inadvertent activation have on flotation and how this can be managed so as to increase the separation of pentlandite and pyroxene. The aim was to minimise the percentage pyroxene reporting to the concentrate and simultaneously maximise the pentlandite recovery. The testwork incorporates the addition of an activator (copper sulphate), a complexing agent, such as DETA (diethylenetriamine) and a dispersant (polyphosphate) at pH 6 and pH 9 in an attempt to alleviate the surface passivation of pentlandite and inadvertent activation of pyroxene. Both synthetic minerals and plant ores were studied in order to determine the effect surface passivation and inadvertent activation have on mineral surface alteration and floatability. Zeta potential determinations, microflotation, ToF-SIMS (Time of Flight Secondary Ion Mass Spectrometry) analyses, laboratory batch flotation tests and continuous flotation testwork were used as tools to study the surface alteration and/or floatability.Zeta potential determinations and ToF-SIMS analyses showed that copper adsorption is non-selective. Both pentlandite and pyroxene become copper (II)-activated in the presence of copper sulphate and subsequently, in the presence of xanthate, adsorption of the collector will occur onto copper activated mineral surfaces. Zeta potential determinations also showed an alteration of the surface charge in the presence of polyphosphate, thereby inhibiting surface passivation of sulphides by slime coatings due to surface repulsion."

Jan 1, 2003

By A. J. Reynolds

In recent years, rapid depletion of the higher grade reserves, allied to decreases in paylimits, has led to the exploitation of secondary, erratically mineralized placer horizons on various marginal and low grade gold mines. On Blyvooruitzicht Mine, the rich Carbon Leader Reef has limited reserves, necessitating exploration of the lower grade Middelvlei Reef. This placer has always presented evaluation and exploration problems, to such an extent that it was, at one stage, considered uneconomic. Despite an extensive underground drilling programme no ore reserve targets of reasonable size were apparent. However, when a certain degree of parallelism between sedimentological trends in the Middelvlei Reef and the underlying Carbon Leader was recognized, a meaningful exploration model could be developed. Firstly, all historical sampling records for the Carbon Leader were entered into a computerized system; the database comprised in excess of 340 000 data points. Variables captured consisted of gold value, uranium value, con- glomerate thickness and total reef thickness. The raw data were then averaged into blocks, and plots of different variables were computer-generated for further analysis. This enabled the Carbon Leader to be modelled sedimentologically and, thereby, exploration targets for the Middelvlei Reef were generated, based on the Carbon Leader facies trends. Geostatistical analysis of sampling data in exposed areas of the Middelvlei Reef underground has confirmed the sedimentological breakdown of the placer into distinct facies areas. A facies model relating value distribution patterns to depositional trends, both for the Carbon Leader and the Middelvlei Reef, has thus been incorporated into a mine planning strategy.

Jan 1, 1987

A philosophy is presented that new graduates in mining and metallurgy should be equipped to use computers during their under- graduate courses, should be aware of the capabilities and costs of a wide range of computing equipment, and should receive sufficient stimulus to become involved in applying computers for the benefit of the mineral industry. A program is presented in which computer applications and "hands on" involvement with computers are integrated into the progressive stages of the undergraduate courses in Mining and Metallurgy. In this respect, the role of the computer is to assist the student by performing time consuming tasks, to demonstrate the industrial applications of computing, to extend the scope and complexity of the tutorial, assignment and project work which can be undertaken by the student, and to provide the essential first stepping stones toward continued useful involvement with computers during the graduate's working life.

Jan 1, 1977

By K. L. Riemer

The West Wits Line first began yielding gold in the mid-1930s and is among South Africa's leading gold-producing areas. Gold mining operations are carried out amidst the occurrence of seismic events which cause both damage to underground excavations and injury and loss of life to production personnel. The feasibility of establishing a system to minotor the seismicity on all the Gold Fields mines was investigated during the early 1980s. This led to the establishment of a centralized seismic network in 1981. The system was structured around three major objectives. It uses Perkin Elmer (now Concurrent Computer Corporation) 16 and 32 bit mini-computers. The hardware in use at both the central and remote sites is outlined, giving a good insight into the role of computers in the system. The system software reveals the fast flow of data through the network; it can be divided into three categories: (1) data logging and transmission - remote sites, (2) data capture and communications - central site, (3) applications and research - central site. Several examples are given which show how the system is measuring up to its objectives. These case studies also indicate how the computers are effective in representing the seismic data collected. It is concluded that the use of computers enables the pin-pointing of seismic events on the West Wits Line within about 3 -4 minutes of their occurrence. The choice of hardware is largely dependent on the objectives of system, and the Gold Fields Network has chosen mini-computers because of the speed of communication and the large amount of data and storage required for research applications.

Jan 1, 1987

The effect of conditioning energy input on the metallurgical results of an emulsion flotation process has been attributed by previous authors to a detergency process. This publication shows that such a process does not explain the data and that an attrition mechanism is more appropriate.

Jan 1, 1969

The effect of conditioning energy input on the metallurgical results of an emulsion flotation process has beenattributed by previous authors to a detergency process.This paper shows that such a process does not explain the data and that an attrition mechanism is more appropriate.

Jan 1, 1970

By Turner W. G, Trundle R. S, Medland D. G

Contracting has evolved from basically a tradesman providing a service for an `employer' to a multi disciplined organisation providing an all compassing service for a client.Having commenced its activities as Thiess Bros Pty Ltd, providing simple earthmoving services in rural Queensland, Thiess Contractors Pty Ltd which provides a wide range of services for Governments and Industry is used as an example of an experienced multi-disciplined Contractor.

Jan 1, 1992

By D. B. Dreisinger, V. van der Pas

Zinc sulphate electrolyte used for zinc electrowinning must be purified for cObalt ions. The cobalt is removed in a cementation stage by the addition of zinc dust. Copper arid antimony are frequently used additives which enhance the cementation of cobalt. This paper aims at a better understanding of how copper and antimony promote the removal of cobalt. Initial experiments were done in a batch cementation reactor. Copper and antimony precipitated in the early stages of cementation indicating that a preferential substrate was formed. The individual role of copper and antimony was further investigated in an electrochemical cell. On a microsca1e, the , growth process, morphology and the composition of the precipitates were examined with SEM and XRD. It was found that cobalt could not be deposited in its pure form but as a cobalt-zinc alloy with zinc as the prime constituent. Copper increases the cathodic surface area of zinc dust by precipitating as numerous dendrites. Antimony acts as a cathodic surface onto which a cobalt-zinc alloy with an increased cobalt content is deposited.

Jan 1, 1997

By T. K. Dichmann, J. A. Finch

"Microflotation, laboratory batch, and in-plant minicell continuous tests were conducted to determine if copper ions not only activate sphalerite but also depress pyrite when the minerals are together. Microflotation tests showed that pyrite recovery increased with addition of copper ions in the pH range of 5-10 when alone, but decreased when sphalerite was also present. Batch flotation tests (Red Dog ore) showed that upon addition of copper, pyrite recovery decreased significantly. The continuous tests (Louvicourt Mine) confirmed this and indicated that with excess copper pyrite recovery can increase. The results suggest there is competition for copper and xanthate in favour of sphalerite. To take advantage of this competition it may be necessary to control the sequence and rate of copper, collector, and lime addition. INTRODUCTIONFlotation, in common with all physical separations, is an imperfect process that results in misplacement of minerals. One source of this imperfection is accidental activation by contaminating metal ions. An important practical example is the misplacement of pyrite to zinc concentrates. Flotation of sphalerite generally requires activation by copper ions, added as copper sulphate. Copper ions are also used to activate pyrite [l] hence there is the suspicion that accidental activation contributes to the recovery of pyrite (Py) with the sphalerite (Sp). However, recent literature has shown that copper ions may make Py less floatable if Sp is also present. Xu et al. [2] conducted continuous minicell tests in-plant at Kidd Creek Operations (division of Falconbridge Ltd.) and showed that while the addition of copper sulphate improved zinc/iron selectivity, it did so as much by reducing the recovery of pyrite as increasing zinc recovery (Figure 1)."

Jan 1, 2000

By Jean-Paul Simoes

The development of the blast furnace over the last years lead to a substantial increase in production capacity and productivity. This development triggered an evolution of the cooling systems in order to cope with the raising heat loads. The excellent protection of the shell by copper staves allowed blast furnace operators to achieve campaign lifetimes of more than 20 years. However in recent years some blast furnaces have experienced severe wear of the copper staves due to abrasion. The influences of the blast furnace design as well as of the operation conditions on this premature wear have been analysed and the mechanisms leading to the wear will be explained. New developments in the copper stave technology are part of the solution for avoiding premature wear during periods with less favourable conditions. The protection mechanisms made available by the new design extend the inherent protection mechanisms of copper staves to these periods. BFXpert® system is the ideal tool for the monitoring of the process data, the process models and the recommendations given by Sachem® support the operator in choosing efficient operation points. The charging with a Bell Less Top® (BLT) allows an accurate controlling of the blast furnace with regard to the optimization of the gas distribution. High performance operation together with long campaign lifetimes are thus made possible.

Aug 1, 2018